CA2263878A1 - Tissue paper containing a vegetable oil based quaternary ammonium compound - Google Patents
Tissue paper containing a vegetable oil based quaternary ammonium compoundInfo
- Publication number
- CA2263878A1 CA2263878A1 CA002263878A CA2263878A CA2263878A1 CA 2263878 A1 CA2263878 A1 CA 2263878A1 CA 002263878 A CA002263878 A CA 002263878A CA 2263878 A CA2263878 A CA 2263878A CA 2263878 A1 CA2263878 A1 CA 2263878A1
- Authority
- CA
- Canada
- Prior art keywords
- quaternary ammonium
- vegetable oil
- oil based
- acyl groups
- based quaternary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
Abstract
Fibrous cellulose materials useful in the manufacture of soft, absorbent paper products such as paper towels, facial tissues, and toilet tissue are disclosed. The paper products contain a vegetable oil based quaternary ammonium chemical softening compound. Examples of preferred vegetable oil based quaternary ammonium chemical softening compounds include diester di(oleyl)dimethyl ammonium chloride (DEDODMAC) (i.e., di(octadec-z-9-eneoyloxyethyl)dimethyl) ammonium chloride) derived from canola oil and/or high oleic safflower oil.
Variables that need to be adjusted to maximize the fluidity of vegetable oil based acyl groups include the cis/transisomer ratio or the lodine Value (IV) of the fatty acyl groups. The tissue softness is further enhanced by controlling the purity of the fatty acyl groups and the di-substituted versus mono-substituted long chain hydrocarbyl substitutent ratio in the quaternary ammonium compounds.
Variables that need to be adjusted to maximize the fluidity of vegetable oil based acyl groups include the cis/transisomer ratio or the lodine Value (IV) of the fatty acyl groups. The tissue softness is further enhanced by controlling the purity of the fatty acyl groups and the di-substituted versus mono-substituted long chain hydrocarbyl substitutent ratio in the quaternary ammonium compounds.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/700,952 | 1996-08-21 | ||
US08/700,952 US5698076A (en) | 1996-08-21 | 1996-08-21 | Tissue paper containing a vegetable oil based quaternary ammonium compound |
PCT/US1997/013800 WO1998007927A1 (en) | 1996-08-21 | 1997-08-08 | Tissue paper containing a vegetable oil based quaternary ammonium compound |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2263878A1 true CA2263878A1 (en) | 1998-02-26 |
CA2263878C CA2263878C (en) | 2006-09-19 |
Family
ID=24815489
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002263878A Expired - Lifetime CA2263878C (en) | 1996-08-21 | 1997-08-08 | Tissue paper containing a vegetable oil based quaternary ammonium compound |
Country Status (13)
Country | Link |
---|---|
US (1) | US5698076A (en) |
EP (1) | EP0920553B1 (en) |
JP (1) | JP2000501461A (en) |
KR (1) | KR100318061B1 (en) |
CN (1) | CN1119458C (en) |
AT (1) | ATE229108T1 (en) |
AU (1) | AU3909197A (en) |
BR (1) | BR9711344A (en) |
CA (1) | CA2263878C (en) |
DE (1) | DE69717636T2 (en) |
ES (1) | ES2185040T3 (en) |
WO (1) | WO1998007927A1 (en) |
ZA (1) | ZA977447B (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU734821B2 (en) * | 1996-09-19 | 2001-06-21 | Procter & Gamble Company, The | Fabric softeners having increased performance |
US6261580B1 (en) * | 1997-10-22 | 2001-07-17 | The Procter & Gamble Company | Tissue paper with enhanced lotion transfer |
US6103308A (en) * | 1998-04-23 | 2000-08-15 | Gencorp Inc. | Paper coating lubricant |
EP1012391A1 (en) * | 1998-06-12 | 2000-06-28 | Fort James Corporation | Method of making a paper web having a high internal void volume of secondary fibers and a product made by the process |
US6969443B1 (en) | 1998-12-21 | 2005-11-29 | Fort James Corporation | Method of making absorbent sheet from recycle furnish |
MY125123A (en) * | 1999-05-07 | 2006-07-31 | Evonik Goldschmidt Corp | Novel quaternary compounds, compositions containing them, and uses thereof |
US6458343B1 (en) | 1999-05-07 | 2002-10-01 | Goldschmidt Chemical Corporation | Quaternary compounds, compositions containing them, and uses thereof |
WO2001031122A1 (en) * | 1999-10-25 | 2001-05-03 | Kimberly-Clark Worldwide, Inc. | High wet performance paper using anionic polymeric compounds and process for producing the same |
US6322665B1 (en) | 1999-10-25 | 2001-11-27 | Kimberly-Clark Corporation | Reactive compounds to fibrous webs |
EP1180559A1 (en) * | 2000-08-04 | 2002-02-20 | Armstrong World Industries, Inc. | Binder composition for fibrous sheet |
AU2003228467A1 (en) * | 2002-04-19 | 2003-11-03 | Evco Research, Llc | Moisture resistant, repulpable paper products and method of making same |
US7658819B2 (en) | 2004-12-30 | 2010-02-09 | Akzo Nobel N.V. | Composition |
US7604715B2 (en) * | 2005-11-17 | 2009-10-20 | Akzo Nobel N.V. | Papermaking process |
MY162376A (en) | 2009-08-05 | 2017-06-15 | Shell Int Research | Method for monitoring a well |
PL2845949T3 (en) | 2009-08-05 | 2023-09-11 | International Paper Company | Process for applying composition containing a cationic trivalent metal and debonder and fluff pulp sheet made from same |
ES2529104T3 (en) * | 2009-08-05 | 2015-02-16 | International Paper Company | Additive for dried sheets of spongy paper pulp |
US8518214B2 (en) * | 2011-07-18 | 2013-08-27 | Nalco Company | Debonder and softener compositions |
US9822285B2 (en) | 2015-01-28 | 2017-11-21 | Gpcp Ip Holdings Llc | Glue-bonded multi-ply absorbent sheet |
US10774476B2 (en) | 2016-01-19 | 2020-09-15 | Gpcp Ip Holdings Llc | Absorbent sheet tail-sealed with nanofibrillated cellulose-containing tail-seal adhesives |
CN106638115A (en) * | 2016-11-16 | 2017-05-10 | 宁霄 | Supersoft household paper and manufacturing method thereof |
US10697123B2 (en) | 2017-01-17 | 2020-06-30 | Gpcp Ip Holdings Llc | Zwitterionic imidazolinium surfactant and use in the manufacture of absorbent paper |
US11124920B2 (en) | 2019-09-16 | 2021-09-21 | Gpcp Ip Holdings Llc | Tissue with nanofibrillar cellulose surface layer |
Family Cites Families (47)
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---|---|---|---|---|
US2683087A (en) * | 1948-02-10 | 1954-07-06 | American Cyanamid Co | Absorbent cellulosic products |
US2683088A (en) * | 1952-06-10 | 1954-07-06 | American Cyanamid Co | Soft bibulous sheet |
US3301746A (en) * | 1964-04-13 | 1967-01-31 | Procter & Gamble | Process for forming absorbent paper by imprinting a fabric knuckle pattern thereon prior to drying and paper thereof |
US3554862A (en) * | 1968-06-25 | 1971-01-12 | Riegel Textile Corp | Method for producing a fiber pulp sheet by impregnation with a long chain cationic debonding agent |
CA978465A (en) * | 1970-04-13 | 1975-11-25 | Scott Paper Company | Fibrous sheet material and method and apparatus for forming same |
US3844880A (en) * | 1971-01-21 | 1974-10-29 | Scott Paper Co | Sequential addition of a cationic debonder, resin and deposition aid to a cellulosic fibrous slurry |
US3755220A (en) * | 1971-10-13 | 1973-08-28 | Scott Paper Co | Cellulosic sheet material having a thermosetting resin bonder and a surfactant debonder and method for producing same |
US3817827A (en) * | 1972-03-30 | 1974-06-18 | Scott Paper Co | Soft absorbent fibrous webs containing elastomeric bonding material and formed by creping and embossing |
US3974025A (en) * | 1974-04-01 | 1976-08-10 | The Procter & Gamble Company | Absorbent paper having imprinted thereon a semi-twill, fabric knuckle pattern prior to final drying |
US3994771A (en) * | 1975-05-30 | 1976-11-30 | The Procter & Gamble Company | Process for forming a layered paper web having improved bulk, tactile impression and absorbency and paper thereof |
US4144122A (en) * | 1976-10-22 | 1979-03-13 | Berol Kemi Ab | Quaternary ammonium compounds and treatment of cellulose pulp and paper therewith |
SE425512B (en) * | 1978-07-21 | 1982-10-04 | Berol Kemi Ab | SET FOR THE PREPARATION OF ABSORPENT CELLULOSAMAS USING NONJONIC SUBSTANCES AND CATIONIC RETENTION AGENTS AND MEANS FOR IMPLEMENTING THE SET |
US4191609A (en) * | 1979-03-09 | 1980-03-04 | The Procter & Gamble Company | Soft absorbent imprinted paper sheet and method of manufacture thereof |
US4300981A (en) * | 1979-11-13 | 1981-11-17 | The Procter & Gamble Company | Layered paper having a soft and smooth velutinous surface, and method of making such paper |
US4432833A (en) * | 1980-05-19 | 1984-02-21 | Kimberly-Clark Corporation | Pulp containing hydrophilic debonder and process for its application |
US4441962A (en) * | 1980-10-15 | 1984-04-10 | The Procter & Gamble Company | Soft, absorbent tissue paper |
US4351699A (en) * | 1980-10-15 | 1982-09-28 | The Procter & Gamble Company | Soft, absorbent tissue paper |
US4425186A (en) * | 1981-03-24 | 1984-01-10 | Buckman Laboratories, Inc. | Dimethylamide and cationic surfactant debonding compositions and the use thereof in the production of fluff pulp |
US4377543A (en) * | 1981-10-13 | 1983-03-22 | Kimberly-Clark Corporation | Strength and softness control of dry formed sheets |
US4447294A (en) * | 1981-12-30 | 1984-05-08 | The Procter & Gamble Company | Process for making absorbent tissue paper with high wet strength and low dry strength |
US4637859A (en) * | 1983-08-23 | 1987-01-20 | The Procter & Gamble Company | Tissue paper |
US4529480A (en) * | 1983-08-23 | 1985-07-16 | The Procter & Gamble Company | Tissue paper |
US4795530A (en) * | 1985-11-05 | 1989-01-03 | Kimberly-Clark Corporation | Process for making soft, strong cellulosic sheet and products made thereby |
US4853086A (en) * | 1986-12-15 | 1989-08-01 | Weyerhaeuser Company | Hydrophilic cellulose product and method of its manufacture |
US4959125A (en) * | 1988-12-05 | 1990-09-25 | The Procter & Gamble Company | Soft tissue paper containing noncationic surfactant |
US4940513A (en) * | 1988-12-05 | 1990-07-10 | The Procter & Gamble Company | Process for preparing soft tissue paper treated with noncationic surfactant |
US4981557A (en) * | 1988-07-05 | 1991-01-01 | The Procter & Gamble Company | Temporary wet strength resins with nitrogen heterocyclic nonnucleophilic functionalities and paper products containing same |
US5066414A (en) * | 1989-03-06 | 1991-11-19 | The Procter & Gamble Co. | Stable biodegradable fabric softening compositions containing linear alkoxylated alcohols |
JPH04100995A (en) * | 1990-08-10 | 1992-04-02 | Nippon Oil & Fats Co Ltd | Softening agent composition for paper |
US5223096A (en) * | 1991-11-01 | 1993-06-29 | Procter & Gamble Company | Soft absorbent tissue paper with high permanent wet strength |
US5217576A (en) * | 1991-11-01 | 1993-06-08 | Dean Van Phan | Soft absorbent tissue paper with high temporary wet strength |
US5264082A (en) * | 1992-04-09 | 1993-11-23 | Procter & Gamble Company | Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a permanent wet strength resin |
US5262007A (en) * | 1992-04-09 | 1993-11-16 | Procter & Gamble Company | Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a temporary wet strength resin |
US5427696A (en) * | 1992-04-09 | 1995-06-27 | The Procter & Gamble Company | Biodegradable chemical softening composition useful in fibrous cellulosic materials |
US5279767A (en) * | 1992-10-27 | 1994-01-18 | The Procter & Gamble Company | Chemical softening composition useful in fibrous cellulosic materials |
US5474689A (en) * | 1992-10-27 | 1995-12-12 | The Procter & Gamble Company | Waterless self-emulsifiable chemical softening composition useful in fibrous cellulosic materials |
US5240562A (en) * | 1992-10-27 | 1993-08-31 | Procter & Gamble Company | Paper products containing a chemical softening composition |
US5543067A (en) * | 1992-10-27 | 1996-08-06 | The Procter & Gamble Company | Waterless self-emulsiviable biodegradable chemical softening composition useful in fibrous cellulosic materials |
US5312522A (en) * | 1993-01-14 | 1994-05-17 | Procter & Gamble Company | Paper products containing a biodegradable chemical softening composition |
US5405501A (en) * | 1993-06-30 | 1995-04-11 | The Procter & Gamble Company | Multi-layered tissue paper web comprising chemical softening compositions and binder materials and process for making the same |
US5389168A (en) * | 1993-06-30 | 1995-02-14 | The Procter & Gamble Company | Method of making an elastomeric adhesive foam and of elasticizing garments |
US5437766A (en) * | 1993-10-22 | 1995-08-01 | The Procter & Gamble Company | Multi-ply facial tissue paper product comprising biodegradable chemical softening compositions and binder materials |
US5397435A (en) * | 1993-10-22 | 1995-03-14 | Procter & Gamble Company | Multi-ply facial tissue paper product comprising chemical softening compositions and binder materials |
US5415737A (en) * | 1994-09-20 | 1995-05-16 | The Procter & Gamble Company | Paper products containing a biodegradable vegetable oil based chemical softening composition |
US5510000A (en) * | 1994-09-20 | 1996-04-23 | The Procter & Gamble Company | Paper products containing a vegetable oil based chemical softening composition |
US5487813A (en) * | 1994-12-02 | 1996-01-30 | The Procter & Gamble Company | Strong and soft creped tissue paper and process for making the same by use of biodegradable crepe facilitating compositions |
US5538595A (en) * | 1995-05-17 | 1996-07-23 | The Proctor & Gamble Company | Chemically softened tissue paper products containing a ploysiloxane and an ester-functional ammonium compound |
-
1996
- 1996-08-21 US US08/700,952 patent/US5698076A/en not_active Expired - Lifetime
-
1997
- 1997-08-08 WO PCT/US1997/013800 patent/WO1998007927A1/en active IP Right Grant
- 1997-08-08 CA CA002263878A patent/CA2263878C/en not_active Expired - Lifetime
- 1997-08-08 AT AT97936415T patent/ATE229108T1/en not_active IP Right Cessation
- 1997-08-08 KR KR1019997001410A patent/KR100318061B1/en not_active IP Right Cessation
- 1997-08-08 AU AU39091/97A patent/AU3909197A/en not_active Abandoned
- 1997-08-08 BR BR9711344A patent/BR9711344A/en unknown
- 1997-08-08 EP EP97936415A patent/EP0920553B1/en not_active Expired - Lifetime
- 1997-08-08 CN CN97199008A patent/CN1119458C/en not_active Expired - Fee Related
- 1997-08-08 JP JP10510776A patent/JP2000501461A/en active Pending
- 1997-08-08 DE DE69717636T patent/DE69717636T2/en not_active Expired - Fee Related
- 1997-08-08 ES ES97936415T patent/ES2185040T3/en not_active Expired - Lifetime
- 1997-08-19 ZA ZA9707447A patent/ZA977447B/en unknown
Also Published As
Publication number | Publication date |
---|---|
ES2185040T3 (en) | 2003-04-16 |
ATE229108T1 (en) | 2002-12-15 |
CN1119458C (en) | 2003-08-27 |
EP0920553A1 (en) | 1999-06-09 |
CN1234085A (en) | 1999-11-03 |
WO1998007927A1 (en) | 1998-02-26 |
BR9711344A (en) | 1999-08-17 |
AU3909197A (en) | 1998-03-06 |
KR20000068272A (en) | 2000-11-25 |
EP0920553B1 (en) | 2002-12-04 |
US5698076A (en) | 1997-12-16 |
KR100318061B1 (en) | 2001-12-22 |
ZA977447B (en) | 1998-02-19 |
DE69717636T2 (en) | 2003-09-11 |
DE69717636D1 (en) | 2003-01-16 |
CA2263878C (en) | 2006-09-19 |
JP2000501461A (en) | 2000-02-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKEX | Expiry |
Effective date: 20170808 |