CA2273741A1 - Compositions and processes for a low-foam hard surface cleaner containing an aromatic sulfonate and a sulfosuccinate - Google Patents
Compositions and processes for a low-foam hard surface cleaner containing an aromatic sulfonate and a sulfosuccinate Download PDFInfo
- Publication number
- CA2273741A1 CA2273741A1 CA002273741A CA2273741A CA2273741A1 CA 2273741 A1 CA2273741 A1 CA 2273741A1 CA 002273741 A CA002273741 A CA 002273741A CA 2273741 A CA2273741 A CA 2273741A CA 2273741 A1 CA2273741 A1 CA 2273741A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- cleaner
- surfactant
- hard surface
- independently
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract 41
- 238000000034 method Methods 0.000 title claims abstract 14
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 title claims 12
- 125000003118 aryl group Chemical group 0.000 title claims 11
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 title claims 4
- 239000006260 foam Substances 0.000 title claims 3
- 239000002689 soil Substances 0.000 claims abstract 11
- 238000004140 cleaning Methods 0.000 claims abstract 3
- 229910052751 metal Inorganic materials 0.000 claims abstract 3
- 239000002184 metal Substances 0.000 claims abstract 3
- 239000011521 glass Substances 0.000 claims abstract 2
- -1 alkali metal cation Chemical class 0.000 claims 27
- 239000004094 surface-active agent Substances 0.000 claims 16
- 125000000217 alkyl group Chemical group 0.000 claims 13
- 125000001931 aliphatic group Chemical group 0.000 claims 10
- 239000002904 solvent Substances 0.000 claims 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 6
- 229910052783 alkali metal Inorganic materials 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 239000003021 water soluble solvent Substances 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 4
- 239000003085 diluting agent Substances 0.000 claims 3
- 239000002736 nonionic surfactant Substances 0.000 claims 3
- 229960004418 trolamine Drugs 0.000 claims 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 239000004599 antimicrobial Substances 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 239000000919 ceramic Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 150000002009 diols Chemical class 0.000 claims 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 239000003352 sequestering agent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C11D2111/14—
Abstract
Hard surfaces such as tile, metal, glass, etc. typically in hospitality locations can be cleaned to a bright, shiny, residue-free appearance using a process comprising cleaning the surface with a first cleaning composition and removing the resulting cleaner residue with a finish cleaner composition. The finish cleaner composition removes all trace of soil and cleaner from the first step and dries to a bright, shiny, spot-free, streak-free, and film-free appearance without a need for a final wipe step.
Claims (31)
1. An aqueous low-foam hard surface finish cleaner composition, that can be used to remove soil residue from a hard surface leaving a clean shiny surface, the cleaner comprising:
(a) an effective soil removing amount of an aromatic sulfonate of the formula:
wherein R1 is a C1-12 aliphatic group, and R2 is independently H+, an alkali metal cation, NH4+, or a mono-, di- or tri-alkanol amine cation.
(b) an effective amount of a sulfonate ester of the formula:
wherein each R3 or R4 is independently a C1-14 aliphatic group, and R2 is H+, an alkali metal cation, NH4+, or a mono-, di- or trialkanol amine cation;
(c) an effective defoaming amount of a nonionic defoaming surfactant; and (d) a major proportion of an aqueous diluent;
wherein after application of the hard surface cleaner, the hard surface dries to a clean, spot-, streak- and film-free appearance.
(a) an effective soil removing amount of an aromatic sulfonate of the formula:
wherein R1 is a C1-12 aliphatic group, and R2 is independently H+, an alkali metal cation, NH4+, or a mono-, di- or tri-alkanol amine cation.
(b) an effective amount of a sulfonate ester of the formula:
wherein each R3 or R4 is independently a C1-14 aliphatic group, and R2 is H+, an alkali metal cation, NH4+, or a mono-, di- or trialkanol amine cation;
(c) an effective defoaming amount of a nonionic defoaming surfactant; and (d) a major proportion of an aqueous diluent;
wherein after application of the hard surface cleaner, the hard surface dries to a clean, spot-, streak- and film-free appearance.
2. The composition of claim 1 wherein the cleaner composition additionally comprises an effective soil removing amount of a water soluble solvent.
3. The composition of claim 1 wherein the composition comprises about 0.15 to 15 wt% of the aromatic sulfonate surfactant; about 0.3 to 18 wt% of the sulfonate ester surfactant; about 0.1 to 11 wt% of the defoaming nonionic surfactant and about 0.1 to 15 wt% of a water soluble solvent.
4. The composition of claim 3 wherein the solvent comprises a solvent of the formula:
wherein x is an integer of about 1 to 6, R5 is a C1-12 aliphatic group and R6 is H or CH3.
wherein x is an integer of about 1 to 6, R5 is a C1-12 aliphatic group and R6 is H or CH3.
5. The composition of claim 4 wherein the solvent comprises a mixture of a lower alkanol selected from the group consisting of methanol, ethanol, isopropanol, n-propanol and mixtures thereof and an aliphatic glycol monoalkylether wherein is an aliphatic group of 1 to 8 carbon atoms, the ratio between the lower alkanol and the aliphatic glycol monoalkylether being about 0.1 to 1 to about 2 to 1.
6. The composition of claim 1 wherein R1 is selected from the group consisting of a C4-C10 aliphatic group.
7. The composition of claim 1 wherein R3 and R4 are each independently a branched C6-C14 alkyl group.
8. The composition of claim 1 wherein R3 and R4 are each independently a C6-14 straight chain alkyl group.
9. The composition of claim 4, comprising about 0.15 to 15 wt% of the aromatic sulfonate; about 0.3 to 18 wt% of a sodium dialkyl sulfosuccinate wherein R3 and R4 are each independently a C6-14 aliphatic group; about 0.1 to 11 wt%
of an ethoxylated decyne diol; about 1 to 15 wt% of an aliphatic glycol monoalkylether wherein R5 is an alkyl of 1-8 carbon atoms; about 0 to 10 wt% of a lower alkanol, and the balance being water.
of an ethoxylated decyne diol; about 1 to 15 wt% of an aliphatic glycol monoalkylether wherein R5 is an alkyl of 1-8 carbon atoms; about 0 to 10 wt% of a lower alkanol, and the balance being water.
10. The composition of claim 1 which also comprises an effective amount of a sequestrant.
11. The composition of claim 1 which also comprises an effective amount of an antimicrobial agent.
12. An aqueous low-foam hard surface finish cleaner composition, that can be used to remove soil residue from a hard surface leaving a clean shiny surface, the cleaner comprising:
(a) an effective soil removing amount of an aromatic sulfonate surfactant;
(b) an effective amount of a sulfonate ester of the formula:
wherein R3 or R4 are each independently a C1-14 aliphatic group, and R2 is H+, an alkali metal cation, NH4+, or a mono-, di- or triethanol amine cation;
(c) an effective defoaming amount of a nonionic defoaming surfactant; and (d) a major proportion of an aqueous diluent;
wherein after application of the hard surface cleaner, the hard surface dries to a clean, spot-, streak- and film-free appearance.
(a) an effective soil removing amount of an aromatic sulfonate surfactant;
(b) an effective amount of a sulfonate ester of the formula:
wherein R3 or R4 are each independently a C1-14 aliphatic group, and R2 is H+, an alkali metal cation, NH4+, or a mono-, di- or triethanol amine cation;
(c) an effective defoaming amount of a nonionic defoaming surfactant; and (d) a major proportion of an aqueous diluent;
wherein after application of the hard surface cleaner, the hard surface dries to a clean, spot-, streak- and film-free appearance.
13. The composition of claim 12 wherein the composition additionally comprises an effective soil removing amount of a water soluble or miscible solvent.
14. The composition of claim 12 wherein the composition comprises about 0.15 to 15 wt% of the aromatic sulfonate surfactant; about 0.3 to 18 wt% of the sulfonate ester surfactant; about 0.1 to 11 wt% of the defoaming nonionic surfactant, and about 0.1 to 15 wt% of a water soluble solvent.
15. The composition of claim 14 wherein the solvent comprises a solvent of the formula:
wherein x is an integer of about 1 to 6, R5 is a C1-12 aliphatic group and R6 is H or CH3.
wherein x is an integer of about 1 to 6, R5 is a C1-12 aliphatic group and R6 is H or CH3.
16. The composition of claim 15 wherein the solvent comprises a mixture of a lower alkanol selected from the group consisting of methanol, ethanol, isopropanol, n-propanol and mixtures thereof and an aliphatic glycol monoalkylether wherein R5 is an alkyl of 1 to 8 carbon atoms; the ratio between the lower alkanol and the aliphatic glycol monoalkylether is about 0 to 1 to about 2 to 1.
17. The composition of claim 12 wherein the aromatic sulfonate is an alkyl diphenyl disulfonate.
18. The composition of claim 12 wherein R3 and R4 are each independently a branched C5-C14 alkyl group.
19. The composition of claim 12 wherein R3 and R4 are each independently a C6-14 straight chain alkyl group.
20. The composition of claim 15 comprising about 0.15 to 15 wt% of the aromatic sulfonate; about 0.3 to 18 wt% of a sodium dialkyl sulfosuccinate wherein R3 and R4 are each independently a C6-14 alkyl group; about 0.1 to 11 wt% of an ethoxylated decyne diol; about 0.1 to 15 wt% of an aliphatic glycol monoalkylether wherein R5 is an alkyl of 1 to 8 carbon atoms; about 0 to 10 wt% of a lower alkanol, and the balance being water.
21. A process for cleaning a hard surface, the surface comprising metal;
painted metal, glass, composite or ceramic, to remove soil, the process comprising the steps of:
(a) applying to the hard surface an aqueous cleaner composition producing a treated surface having a cleaner residue; and (b) applying to the treated surface having a cleaner residue, an aqueous finish cleaner composition, that can be used to remove soil from the treated surface, the cleaner comprising:
(i) an effective soil removing amount of an aromatic sulfonate surfactant;
(ii) an effective amount of a sulfonate ester of the formula:
wherein R3 or R4 are each independently a C1-14 aliphatic group, and R2 is H+, an alkali metal canon, NH4+, or a mono-, di- or triethanol amine cation;
(iii) an effective defoaming amount of a nonionic defoaming surfactant; and (iv) a major proportion of an aqueous diluent;
wherein after application of the hard surface finish cleaner, the process is substantially free of hand wiping and the hard surface dries to a clean, spot-free, streak-free and film-free appearance.
painted metal, glass, composite or ceramic, to remove soil, the process comprising the steps of:
(a) applying to the hard surface an aqueous cleaner composition producing a treated surface having a cleaner residue; and (b) applying to the treated surface having a cleaner residue, an aqueous finish cleaner composition, that can be used to remove soil from the treated surface, the cleaner comprising:
(i) an effective soil removing amount of an aromatic sulfonate surfactant;
(ii) an effective amount of a sulfonate ester of the formula:
wherein R3 or R4 are each independently a C1-14 aliphatic group, and R2 is H+, an alkali metal canon, NH4+, or a mono-, di- or triethanol amine cation;
(iii) an effective defoaming amount of a nonionic defoaming surfactant; and (iv) a major proportion of an aqueous diluent;
wherein after application of the hard surface finish cleaner, the process is substantially free of hand wiping and the hard surface dries to a clean, spot-free, streak-free and film-free appearance.
22. The process of claim 21 wherein there are about 20 to 200 parts by weight of an alkyl diphenyl oxide sulfonate surfactant for each one million parts of the aqueous hard surface cleaner.
23. The process of claim 21 wherein there are about 35 to 300 parts by weight of the sulfonate ester for each one million parts of the hard surface cleaner.
24. The process of claim 21 wherein the nonionic defoaming surfactant comprises an alkoxylated C4-20 alkyn diol.
25. The process of claim 21 wherein the nonionic defoaming surfactant comprises a surfactant of the formula (PO)x(EO)y(PO)z wherein x ranges from about 5 to about 21, y ranges from about 4 to about 60 and z ranges from about 5 to about 21, or a surfactant of the formula wherein x ranges from about 8 to about 30 and y ranges from about 1 to about 124, or a mixture thereof.
26. The process of claim 21 wherein the cleaner composition additionally comprises an effective soil removing amount of a water soluble solvent.
27. The process of claim 21 wherein the composition comprises about 0.15 to 15 wt% of the aromatic sulfonate surfactant; about 0.3 to 18 wt% of the sulfonate ester surfactant; about 0.1 to 11 wt% of the defoaming nonionic surfactant and about 0.1 to 15 wt% of a water soluble solvent.
28 28. The process of claim 27 wherein the solvent comprises a solvent of the formula wherein x is an integer of about 1 to 6, R5 is a C1-8 aliphatic group and R6 is H or CH3.
29. The cleaner composition of claim 28 wherein the solvent comprises a mixture of a lower alkanol selected from the group consisting of methanol, ethanol, isopropanol, n-propanol and mixtures thereof, and an aliphatic glycol monoalkylether wherein R5 is an alkyl of 2 to 8 carbon atoms; the ratio between the lower alkanol and the aliphatic glycol monoalkylether is about 0 to 1 to about 2 to 1.
30. The process of claim 21 wherein R3 and R4 are each independently a C6-12 straight chain alkyl group.
31. The process of claim 21 wherein the cleaner composition comprises about 0.15 to 15 wt% of the aromatic sulfonate; about 0.3 to 18 wt% of a dialkyl sulfosuccinate wherein R3 and R4 are each independently a C6-12 alkyl group and R2 is H+, an alkali metal cation, NH4+, or a mono-, di- or triethanol amine canon; about 0.1 to 11 wt% of an ethoxylated decyne diol; about 0.1 to 15 wt% of an aliphatic glycol monoalkylether wherein the alkyl group is a C1-6 alkyl group; about 0.5 to 10 wt% of a lower alkanol, and the balance being water.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/093,321 US6017872A (en) | 1998-06-08 | 1998-06-08 | Compositions and process for cleaning and finishing hard surfaces |
| US09/093,321 | 1998-06-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2273741A1 true CA2273741A1 (en) | 1999-12-08 |
| CA2273741C CA2273741C (en) | 2010-12-14 |
Family
ID=22238297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2273741A Expired - Lifetime CA2273741C (en) | 1998-06-08 | 1999-06-07 | Compositions and processes for a low-foam hard surface cleaner containing an aromatic sulfonate and a sulfosuccinate |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6017872A (en) |
| EP (1) | EP0964056A3 (en) |
| JP (1) | JP4163814B2 (en) |
| AU (1) | AU756776B2 (en) |
| CA (1) | CA2273741C (en) |
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| US5106416A (en) * | 1991-08-28 | 1992-04-21 | Hewlett-Packard Company | Bleed alleviation using zwitterionic surfactants and cationic dyes |
| US5698087A (en) * | 1992-03-11 | 1997-12-16 | Mcgean-Rohco, Inc. | Plating bath and method for electroplating tin and/or lead |
| JP2521630B2 (en) * | 1992-12-10 | 1996-08-07 | 花王株式会社 | Cleaning composition for hard surfaces |
| US5589099A (en) * | 1993-04-20 | 1996-12-31 | Ecolab Inc. | Low foaming rinse agents comprising ethylene oxide/propylene oxide block copolymer |
| US5417893A (en) * | 1993-08-27 | 1995-05-23 | The Procter & Gamble Company | Concentrated liquid or gel light duty dishwashing detergent compositions containing calcium ions and disulfonate surfactants |
| CA2170024C (en) * | 1993-09-14 | 2000-01-11 | Mark Hsiang-Kuen Mao | Light duty liquid or gel dishwashing detergent compositions containing protease |
| US5536452A (en) * | 1993-12-07 | 1996-07-16 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
| US5561106A (en) * | 1994-02-07 | 1996-10-01 | Erilli; Rita | High foaming light duty liquid detergent composition comprising partially esterified ethoxylated polyhydric alcohol solubilizing agent |
| AU1355995A (en) * | 1994-03-14 | 1995-09-21 | Colgate-Palmolive Company, The | Microemulsion all purpose liquid cleaning compositions |
| WO1996018711A1 (en) * | 1994-12-16 | 1996-06-20 | The Procter & Gamble Company | Hard surface cleaners comprising highly ethoxylated guerbet alcohols |
| US5599586A (en) * | 1995-04-18 | 1997-02-04 | Israel; Michael G. | Chemical maintenance systems for residential roofing materials |
| US5736256A (en) * | 1995-05-31 | 1998-04-07 | Howard A. Fromson | Lithographic printing plate treated with organo-phosphonic acid chelating compounds and processes relating thereto |
| GB2306499A (en) * | 1995-10-25 | 1997-05-07 | Reckitt & Colman Inc | Hard surface cleaning compositions |
| US5837664A (en) * | 1996-07-16 | 1998-11-17 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
-
1998
- 1998-06-08 US US09/093,321 patent/US6017872A/en not_active Expired - Lifetime
-
1999
- 1999-05-18 AU AU29097/99A patent/AU756776B2/en not_active Expired
- 1999-06-07 CA CA2273741A patent/CA2273741C/en not_active Expired - Lifetime
- 1999-06-07 EP EP99110844A patent/EP0964056A3/en not_active Withdrawn
- 1999-06-08 JP JP16105299A patent/JP4163814B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0964056A3 (en) | 2000-01-05 |
| AU2909799A (en) | 1999-12-16 |
| US6017872A (en) | 2000-01-25 |
| JP4163814B2 (en) | 2008-10-08 |
| AU756776B2 (en) | 2003-01-23 |
| JP2000087092A (en) | 2000-03-28 |
| EP0964056A2 (en) | 1999-12-15 |
| CA2273741C (en) | 2010-12-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20190607 |