CA2277063A1 - Propylene polymers incorporating polyethylene macromers - Google Patents

Propylene polymers incorporating polyethylene macromers Download PDF

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Publication number
CA2277063A1
CA2277063A1 CA002277063A CA2277063A CA2277063A1 CA 2277063 A1 CA2277063 A1 CA 2277063A1 CA 002277063 A CA002277063 A CA 002277063A CA 2277063 A CA2277063 A CA 2277063A CA 2277063 A1 CA2277063 A1 CA 2277063A1
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Prior art keywords
olefin copolymer
branched olefin
optionally
isotactic polypropylene
copolymerizable monomers
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CA002277063A
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French (fr)
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CA2277063C (en
Inventor
Weiqing Weng
Armen H. Dekmezian
Eric J. Markel
Avinash Chandrakant Gadkari
Jean-Marc Dekoninck
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ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents, Inc.
Weiqing Weng
Armen H. Dekmezian
Eric J. Markel
Avinash Chandrakant Gadkari
Jean-Marc Dekoninck
Exxonmobil Chemical Patents Inc.
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Application filed by Exxon Chemical Patents, Inc., Weiqing Weng, Armen H. Dekmezian, Eric J. Markel, Avinash Chandrakant Gadkari, Jean-Marc Dekoninck, Exxonmobil Chemical Patents Inc. filed Critical Exxon Chemical Patents, Inc.
Publication of CA2277063A1 publication Critical patent/CA2277063A1/en
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Publication of CA2277063C publication Critical patent/CA2277063C/en
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/005—Homopolymers or copolymers obtained by polymerisation of macromolecular compounds terminated by a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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    • C08F2/00—Processes of polymerisation
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
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    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
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    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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    • C08F4/00—Polymerisation catalysts
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
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    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
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Abstract

A polyolefin product is provided which comprises a branched olefin copolymer having an isotactic polypropylene backbone, polyethylene branches and, optionally, one or more comonomers. The total comonomer content of the branched olefin copolymer is from 0 to 20 mole percent. Also, the mass ratio of the isotactic polypropylene to the polyethylene ranges from 99.9:0.1 to 50:50. Additionally, a process is provided for preparing a branched olefin copolymer which comprises: a) copolymerizing ethylene, optionally with one or more copolymerizable monomers, in a polymerization reaction under conditions sufficient to form copolymer having greater than 40 % chain end-group unsaturation; b) copolymerizing the product of a) with propylene and, optionally, one or more copolymerizable monomers, in a polymerization reactor under suitable polypropylene polymerization conditions using a chiral, stereorigid transition metal catalyst capable of producing isotactic polypropylene; and c) recovering a branched olefin copolymer.
CA002277063A 1997-02-07 1998-02-06 Propylene polymers incorporating polyethylene macromers Expired - Fee Related CA2277063C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US3732397P 1997-02-07 1997-02-07
US60/037,323 1997-02-07
US4681297P 1997-05-02 1997-05-02
US60/046,812 1997-05-02
US6778297P 1997-12-10 1997-12-10
US60/067,782 1997-12-10
PCT/US1998/002736 WO1998034971A1 (en) 1997-02-07 1998-02-06 Propylene polymers incorporating polyethylene macromers

Publications (2)

Publication Number Publication Date
CA2277063A1 true CA2277063A1 (en) 1998-08-13
CA2277063C CA2277063C (en) 2007-03-20

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CA002277063A Expired - Fee Related CA2277063C (en) 1997-02-07 1998-02-06 Propylene polymers incorporating polyethylene macromers
CA002277111A Abandoned CA2277111A1 (en) 1997-02-07 1998-02-06 Thermoplastic elastomer compositions from branched olefin copolymers

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CA002277111A Abandoned CA2277111A1 (en) 1997-02-07 1998-02-06 Thermoplastic elastomer compositions from branched olefin copolymers

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US (4) US6660809B1 (en)
EP (2) EP0958313B1 (en)
JP (2) JP4218988B2 (en)
KR (2) KR100564500B1 (en)
CN (2) CN1130406C (en)
BR (2) BR9807672A (en)
CA (2) CA2277063C (en)
DE (2) DE69808243T2 (en)
ES (2) ES2187005T3 (en)
WO (2) WO1998034971A1 (en)

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