CA2277125A1 - Stable solid block detergent composition - Google Patents

Stable solid block detergent composition Download PDF

Info

Publication number
CA2277125A1
CA2277125A1 CA002277125A CA2277125A CA2277125A1 CA 2277125 A1 CA2277125 A1 CA 2277125A1 CA 002277125 A CA002277125 A CA 002277125A CA 2277125 A CA2277125 A CA 2277125A CA 2277125 A1 CA2277125 A1 CA 2277125A1
Authority
CA
Canada
Prior art keywords
solid block
detergent composition
stable solid
block detergent
dimensionally stable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002277125A
Other languages
French (fr)
Other versions
CA2277125C (en
Inventor
Steven E. Lentsch
Keith E. Olson
G. Jason Wei
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab Inc
Original Assignee
Ecolab Inc.
Steven E. Lentsch
Keith E. Olson
G. Jason Wei
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Inc., Steven E. Lentsch, Keith E. Olson, G. Jason Wei filed Critical Ecolab Inc.
Publication of CA2277125A1 publication Critical patent/CA2277125A1/en
Application granted granted Critical
Publication of CA2277125C publication Critical patent/CA2277125C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0052—Cast detergent compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/12—Carbonates bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/36—Organic compounds containing phosphorus

Abstract

The dimensionally stable alkaline solid block warewashing detergent uses an E-form binder forming a solid comprising a sodium carbonate source of alkalinity, a sequestrant, a surfactant package and other optional material. The solid block is dimensionally stable and highly effective in removing soil from the surfaces of dishware in the institutional and industrial environment. The E-form hydrate comprises an organic phosphonate and a hydrated carbonate.
CA002277125A 1997-01-13 1998-01-06 Stable solid block detergent composition Expired - Lifetime CA2277125C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/781,493 US6177392B1 (en) 1997-01-13 1997-01-13 Stable solid block detergent composition
US08/781,493 1997-12-12
PCT/US1998/000112 WO1998030674A1 (en) 1997-01-13 1998-01-06 Stable solid block detergent composition

Publications (2)

Publication Number Publication Date
CA2277125A1 true CA2277125A1 (en) 1998-07-16
CA2277125C CA2277125C (en) 2007-05-29

Family

ID=25122924

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002277125A Expired - Lifetime CA2277125C (en) 1997-01-13 1998-01-06 Stable solid block detergent composition

Country Status (13)

Country Link
US (4) US6177392B1 (en)
EP (1) EP1019483B1 (en)
JP (2) JP2001508106A (en)
CN (1) CN1205328C (en)
AR (1) AR011071A1 (en)
AU (1) AU728271B2 (en)
BR (1) BR9808887A (en)
CA (1) CA2277125C (en)
DE (1) DE69829864T2 (en)
MY (1) MY120135A (en)
TW (1) TW438885B (en)
WO (1) WO1998030674A1 (en)
ZA (2) ZA9710545B (en)

Families Citing this family (94)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3135066B2 (en) * 1991-05-14 2001-02-13 エコラボ インコーポレイテッド Two-part drug concentrate
US6177392B1 (en) * 1997-01-13 2001-01-23 Ecolab Inc. Stable solid block detergent composition
US6258765B1 (en) * 1997-01-13 2001-07-10 Ecolab Inc. Binding agent for solid block functional material
US6150324A (en) * 1997-01-13 2000-11-21 Ecolab, Inc. Alkaline detergent containing mixed organic and inorganic sequestrants resulting in improved soil removal
US6156715A (en) * 1997-01-13 2000-12-05 Ecolab Inc. Stable solid block metal protecting warewashing detergent composition
ES2367505T3 (en) 1997-10-23 2011-11-04 Danisco Us Inc. PROTEASE VARIANTS WITH MULTIPLE SUBSTITUTIONS WITH ALTERED NET LOAD FOR USE IN DETERGENTS.
MA24811A1 (en) * 1997-10-23 1999-12-31 Procter & Gamble WASHING COMPOSITIONS CONTAINING MULTISUBSTITUTED PROTEASE VARIANTS
US6387870B1 (en) * 1999-03-29 2002-05-14 Ecolab Inc. Solid pot and pan detergent
US20050130868A1 (en) 1999-11-10 2005-06-16 Evans K D. Multiuse, solid cleaning device and composition
US6730653B1 (en) * 2000-06-01 2004-05-04 Ecolab Inc. Method for manufacturing a molded detergent composition
US7037886B2 (en) 2000-06-01 2006-05-02 Ecolab Inc. Method for manufacturing a molded detergent composition
US6503875B1 (en) 2000-08-18 2003-01-07 Ecolab Inc. Stabilized oxalic acid sour
US6638902B2 (en) * 2001-02-01 2003-10-28 Ecolab Inc. Stable solid enzyme compositions and methods employing them
FR2820823B1 (en) * 2001-02-09 2004-04-23 Inst Francais Du Petrole METHOD AND DEVICE FOR EVALUATING THE CAPACITY OF WELL FLUIDS TO FORM HYDRATES DURING DRILLING
US20020159917A1 (en) * 2001-04-27 2002-10-31 Swart Sally Kay System and method for cleaning, high level disinfection, or sterilization of medical or dental instruments or devices
US20030109403A1 (en) * 2001-06-05 2003-06-12 Ecolab, Inc. Solid cleaning composition including stabilized active oxygen component
US20030162685A1 (en) * 2001-06-05 2003-08-28 Man Victor Fuk-Pong Solid cleaning composition including stabilized active oxygen component
US20030139310A1 (en) * 2001-08-07 2003-07-24 Smith Kim R. Peroxygen compositions and methods for carpet or upholstery cleaning or sanitizing
US7153820B2 (en) * 2001-08-13 2006-12-26 Ecolab Inc. Solid detergent composition and method for solidifying a detergent composition
US20030136942A1 (en) * 2001-11-30 2003-07-24 Smith Kim R. Stabilized active oxygen compositions
US8110537B2 (en) * 2003-01-14 2012-02-07 Ecolab Usa Inc. Liquid detergent composition and methods for using
US7179379B2 (en) * 2003-03-28 2007-02-20 Ab-Cwt, Llc Apparatus for separating particulates from a suspension, and uses thereof
US7135448B2 (en) * 2003-07-02 2006-11-14 Ecolab Inc. Warewashing composition for use in automatic dishwashing machines, comprising a mixture of aluminum and zinc ions
US7196044B2 (en) 2003-07-02 2007-03-27 Ecolab, Inc. Warewashing composition for use in automatic dishwashing machines, comprising a zinc ion and aluminum ion corrosion inhibitor
US7423005B2 (en) * 2003-11-20 2008-09-09 Ecolab Inc. Binding agent for solidification matrix
US7442679B2 (en) 2004-04-15 2008-10-28 Ecolab Inc. Binding agent for solidification matrix comprising MGDA
US20050244315A1 (en) * 2004-04-30 2005-11-03 Greaves Michael D Solid product dissolver and method of use thereof
AR049538A1 (en) * 2004-06-29 2006-08-09 Procter & Gamble DETERGENT COMPOSITIONS FOR LAUNDRY WITH EFFICIENT DYING COLOR
US7977299B2 (en) * 2004-08-18 2011-07-12 Ecolab Usa Inc. Treated oxidizing agent, detergent composition containing a treated oxidizing agent, and methods for producing
US20060174883A1 (en) * 2005-02-09 2006-08-10 Acoba, Llc Method and system of leak detection in application of positive airway pressure
US20060191851A1 (en) * 2005-02-25 2006-08-31 Mizuno William G Method for treating feedwater, feedwater treatment composition, and apparatus for treating feedwater
US20060252666A1 (en) * 2005-05-09 2006-11-09 Dennis Sheirs Household cleaning composition
DE102006029840A1 (en) * 2006-06-27 2008-01-03 Henkel Kgaa Detergent or treatment agent portion I
US7759299B2 (en) * 2006-07-24 2010-07-20 Ecolab Inc. Warewashing composition for use in automatic dishwashing machines
EP1918360A1 (en) * 2006-10-11 2008-05-07 Mifa Ag Frenkendorf Dosed or dosable washing agent
EP1911833B1 (en) * 2006-10-11 2013-07-03 Mifa Ag Frenkendorf Dosed or dosable washing agent
WO2008043379A1 (en) * 2006-10-11 2008-04-17 Mifa Ag Frenkendorf Automatic dosing system
US20080108537A1 (en) * 2006-11-03 2008-05-08 Rees Wayne M Corrosion inhibitor system for mildly acidic to ph neutral halogen bleach-containing cleaning compositions
US8093200B2 (en) 2007-02-15 2012-01-10 Ecolab Usa Inc. Fast dissolving solid detergent
US20100311633A1 (en) * 2007-02-15 2010-12-09 Ecolab Usa Inc. Detergent composition for removing fish soil
EP2190969B1 (en) * 2007-05-04 2014-08-20 Ecolab Inc. Pressed, self-solidifying, solid cleaning compositions and methods of making them
US7763576B2 (en) 2008-01-04 2010-07-27 Ecolab Inc. Solidification matrix using a polycarboxylic acid polymer
US7893012B2 (en) 2007-05-04 2011-02-22 Ecolab Inc. Solidification matrix
US7888303B2 (en) * 2007-05-04 2011-02-15 Ecolab Inc. Solidification matrix
US8338352B2 (en) * 2007-05-07 2012-12-25 Ecolab Usa Inc. Solidification matrix
US8759269B2 (en) * 2007-07-02 2014-06-24 Ecolab Usa Inc. Solidification matrix including a salt of a straight chain saturated mono-, di-, and tri- carboxylic acid
US7759300B2 (en) 2007-07-02 2010-07-20 Ecolab Inc. Solidification matrix including a salt of a straight chain saturated mono-, di-, or tri- carboxylic acid
US20090032063A1 (en) * 2007-07-30 2009-02-05 Haas Geoffrey R Solid cleaning composition and method of use
US8889048B2 (en) * 2007-10-18 2014-11-18 Ecolab Inc. Pressed, self-solidifying, solid cleaning compositions and methods of making them
WO2009050684A2 (en) * 2007-10-18 2009-04-23 Ecolab Inc. Pressed, waxy, solid cleaning compositions and methods of making them
US8198228B2 (en) * 2008-01-04 2012-06-12 Ecolab Usa Inc. Solidification matrix using an aminocarboxylate
US8772221B2 (en) 2008-01-04 2014-07-08 Ecolab Usa Inc. Solidification matrices using phosphonocarboxylic acid copolymers and phosphonopolyacrylic acid homopolymers
US8138138B2 (en) 2008-01-04 2012-03-20 Ecolab Usa Inc. Solidification matrix using a polycarboxylic acid polymer
US20100093596A1 (en) 2008-04-07 2010-04-15 Ecolab Inc. Ultra-concentrated liquid degreaser composition
EP3263691A1 (en) * 2009-05-26 2018-01-03 Ecolab USA Inc. Pot and pan soaking composition
US20110017945A1 (en) * 2009-07-27 2011-01-27 Ecolab Inc. Novel formulation of a ware washing solid controlling hardness
US20110021410A1 (en) * 2009-07-27 2011-01-27 Ecolab Usa Inc. Novel formulation of a ware washing solid controlling hardness
US8883035B2 (en) 2009-07-27 2014-11-11 Ecolab Usa Inc. Formulation of a ware washing solid controlling hardness
US8530403B2 (en) * 2009-11-20 2013-09-10 Ecolab Usa Inc. Solidification matrix using a maleic-containing terpolymer binding agent
US20110124547A1 (en) * 2009-11-23 2011-05-26 Ecolab Inc. Solidification matrix using a sulfonated/carboxylated polymer binding agent
US8399393B2 (en) 2010-05-03 2013-03-19 Ecolab Usa Inc. Combination of soluble lithium salt and soluble aluminum or silicate salt as a glass etching inhibitor
EP2880144A4 (en) 2012-08-03 2016-03-16 Ecolab Usa Inc Biodegradable stability binding agent for a solid detergent
CN103911225B (en) 2013-01-04 2017-12-12 艺康美国股份有限公司 Solid tablet unit dose stove cleaning agent
BR112015027512B1 (en) 2013-05-02 2021-09-08 Ecolab Usa Inc CONCENTRATED DETERGENT COMPOSITION, AND, USE OF A CONCENTRATED DETERGENT COMPOSITION
EP3068861B1 (en) 2013-11-11 2020-03-18 Ecolab USA Inc. Multiuse, enzymatic detergent and methods of stabilizing a use solution
AU2015225441B2 (en) 2014-03-07 2017-12-21 Ecolab Usa Inc. Detergent composition that performs both a cleaning and rinsing function
US10549245B2 (en) 2014-08-05 2020-02-04 Ecolab Usa Inc. Apparatus and method for dispensing solutions from solid products
US10280386B2 (en) 2015-04-03 2019-05-07 Ecolab Usa Inc. Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid
US9783766B2 (en) 2015-04-03 2017-10-10 Ecolab Usa Inc. Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid
US10017714B2 (en) 2015-05-19 2018-07-10 Ecolab Usa Inc. Efficient surfactant system on plastic and all types of ware
US10118137B2 (en) 2015-07-23 2018-11-06 Ecolab Usa Inc. Solid product dispenser for small volume applications
JP6730426B2 (en) 2015-09-17 2020-07-29 エコラボ ユーエスエー インコーポレイティド Method for making triamine solids
WO2017049076A1 (en) 2015-09-17 2017-03-23 Ecolab Usa Inc. Triamine solidification using diacids
CN106701351A (en) * 2015-11-12 2017-05-24 艺康美国股份有限公司 Low-foaming vessel cleaning agent and mixed cationic/nonionic surfactant system for enhancing removal of oil-containing dirt
CN109563452B (en) * 2016-09-07 2021-11-30 埃科莱布美国股份有限公司 Detergent compositions containing enzymes stabilized by phosphonic acids
CN110382679B (en) 2017-03-01 2022-04-22 埃科莱布美国股份有限公司 Interaction mechanism of urea/solid acid under storage conditions and storage stable solid composition comprising urea and acid
CN110603312B (en) * 2017-05-04 2021-10-15 联合利华知识产权控股有限公司 Detergent composition
US11937602B2 (en) 2017-09-26 2024-03-26 Ecolab Usa Inc. Solid acid/anionic antimicrobial and virucidal compositions and uses thereof
BR112020015147A2 (en) 2018-01-26 2021-01-05 Ecolab Usa Inc. COMPOSITIONS OF SOLIDIFIED LIQUID SURFACE AND SOLID CLEANING AND METHODS FOR PREPARING A SOLIDIFIED SURFACE COMPOSITION AND FOR CLEANING A SURFACE
CN111655830A (en) 2018-01-26 2020-09-11 埃科莱布美国股份有限公司 Solidified liquid anionic surfactants
MX2020007911A (en) 2018-01-26 2020-09-07 Ecolab Usa Inc Solid cleaning composition.
KR20200115538A (en) 2018-01-26 2020-10-07 에코랍 유에스에이 인코퍼레이티드 Solidification of liquid amine oxide, betaine, and/or sultaine surfactants using binders and optional carriers
SG11202007457PA (en) 2018-02-05 2020-09-29 Ecolab Usa Inc Packaging and docking system for non-contact chemical dispensing
EP3752281B1 (en) 2018-02-13 2022-04-27 Ecolab USA, Inc. System and method for dissolving solid chemicals and generating liquid solutions
US11278922B2 (en) 2018-02-13 2022-03-22 Ecolab Usa Inc. Portable solid product dispenser
WO2019182856A1 (en) 2018-03-19 2019-09-26 Ecolab Usa Inc. Liquid detergent compositions containing bleach catalyst
SG11202108520XA (en) 2019-02-05 2021-09-29 Ecolab Usa Inc Packaging and docking system for non-contact chemical dispensing
AU2020296116B2 (en) 2019-06-21 2023-09-21 Ecolab Usa Inc. Solid nonionic surfactant compositions
US11845910B2 (en) 2019-07-03 2023-12-19 Ecolab Usa Inc. Hard surface cleaning compositions with reduced surface tension
US20210071108A1 (en) 2019-09-06 2021-03-11 Ecolab Usa Inc. Concentrated surfactant systems for rinse aid and other applications
CN114222808A (en) 2019-09-27 2022-03-22 埃科莱布美国股份有限公司 Concentrated two-in-one dishwasher detergent and rinse aid
WO2021126956A1 (en) 2019-12-16 2021-06-24 Ecolab Usa Inc. Anionic surfactant impact on virucidal efficacy
CA3175529A1 (en) 2020-04-30 2021-11-04 Derrick Anderson Low foam cleaning compositions
JP2024514162A (en) 2021-04-15 2024-03-28 エコラボ ユーエスエー インコーポレイティド Enzyme bed cleaning composition

Family Cites Families (137)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US400080A (en) * 1889-03-26 Feed-trough
US1580576A (en) 1924-03-08 1926-04-13 Weidner Edmund Perfumed soap cake
US1949264A (en) 1929-03-20 1934-02-27 R M Hollingshead Co Method of making soap solution
US2412819A (en) 1945-07-21 1946-12-17 Mathieson Alkali Works Inc Detergent briquette
GB687075A (en) 1949-04-28 1953-02-04 George Franklyn Hicks Improvements in detergent briquettes and in method of and apparatus for making same
US2927900A (en) 1951-07-10 1960-03-08 Gen Aniline & Film Corp Solid detergent composition and process for preparation thereof
US2987483A (en) 1956-07-02 1961-06-06 Pennsalt Chemicals Corp Cleaning composition
US2920417A (en) 1958-01-22 1960-01-12 Sylvia T Wertheimer Detergent-solution dispensing container
US3048548A (en) 1959-05-26 1962-08-07 Economics Lab Defoaming detergent composition
NL285082A (en) 1962-02-28
NL293412A (en) 1962-06-06
US3392121A (en) 1962-11-05 1968-07-09 Procter & Gamble Built detergent compositions
US3382558A (en) * 1966-02-02 1968-05-14 Itt Electrical connector captivated rear release tool
US3356612A (en) 1965-02-01 1967-12-05 Petrolite Corp Stable detergent compositions
US3390092A (en) 1965-03-30 1968-06-25 Fmc Corp Dishwashing detergent preparations containing sodium or potassium dichloroisocyanurate
US3306858A (en) 1965-06-17 1967-02-28 Economics Lab Process for the preparation of storage stable detergent composition
US3441511A (en) 1965-12-20 1969-04-29 Wyandotte Chemicals Corp Alkali metal hydroxide-containing agglomerates
CA813301A (en) * 1966-09-06 1969-05-20 E. Zimmerer Roger Detergent composition
US3442242A (en) * 1967-06-05 1969-05-06 Algonquin Shipping & Trading Stopping and manoeuvering means for large vessels
US3557003A (en) 1967-06-21 1971-01-19 Procter & Gamble Detergent tablet
GB1240058A (en) 1968-04-12 1971-07-21 Procter & Gamble Enzyme-containing detergent compositions
US3639286A (en) 1968-05-28 1972-02-01 Mario Ballestra Synthetic detergent in bar or cake form and the method to manufacture same
US3491028A (en) 1969-06-03 1970-01-20 Grace W R & Co Chlorine stable machine dishwashing composition
JPS4835329B1 (en) 1969-12-03 1973-10-27
US3856932A (en) 1969-12-16 1974-12-24 M May Tablet of a chlorine releasing solid compound
CA959370A (en) 1970-09-08 1974-12-17 William G. Mizuno Machine dishwashing detergent having a reduced condensed phosphate content
US3846346A (en) 1971-01-25 1974-11-05 Philadelphia Quartz Co Detergent composition with controlled alkalinity
US3941710A (en) 1972-04-24 1976-03-02 Lever Brothers Company Phosphate - free dishwashing compositions containing an alkyl polyether carboxylate surfactant
US3816320A (en) 1972-11-24 1974-06-11 Fmc Corp Stable dishwashing compositions containing sodium dichloroisocyanurate dihydrate
US4605509A (en) 1973-05-11 1986-08-12 The Procter & Gamble Company Detergent compositions containing sodium aluminosilicate builders
US3933670A (en) 1973-11-12 1976-01-20 Economic Laboratories, Inc. Process for making agglomerated detergents
US4274975A (en) 1974-03-11 1981-06-23 The Procter & Gamble Company Detergent composition
US3985669A (en) 1974-06-17 1976-10-12 The Procter & Gamble Company Detergent compositions
US4148603A (en) 1974-10-04 1979-04-10 Henkel Kommanditgesellschaft Auf Aktien Method of washing textiles and composition containing inorganic silicates and polycarboxylates and/or polyphosphonates
US4000080A (en) 1974-10-11 1976-12-28 The Procter & Gamble Company Low phosphate content detergent composition
GB1516848A (en) 1974-11-13 1978-07-05 Procter & Gamble Ltd Detergent composition
FR2298599A2 (en) 1975-01-24 1976-08-20 Sifrance NEW SOLID NON-CORROSIVE DETERGENT COMPOSITIONS
US3939386A (en) 1975-01-30 1976-02-17 Xerox Corporation Technique for charging dielectric surfaces to high voltage
US3961754A (en) 1975-09-12 1976-06-08 Economics Laboratory, Inc. Spray and foam producing nozzle apparatus
GB1527706A (en) 1976-02-23 1978-10-11 Chemed Corp Detergent composition and its use in a dishwashing machin
US4105573A (en) 1976-10-01 1978-08-08 The Procter & Gamble Company Dishwasher detergent composition
DE2810999A1 (en) 1977-03-17 1978-09-21 Unilever Nv Liq. aq. dishwashing compsn. for e.g. removing tea and coffee stains - contain potassium hydroxide, an alkali metal tri:poly-phosphate and a sequestering agent
GB1596756A (en) 1977-04-22 1981-08-26 Procter & Gamble Ltd Detergent compositions
CA1120819A (en) 1977-06-01 1982-03-30 Jurgen W.K. Gromer Detergent tablet
US4329246A (en) 1977-11-07 1982-05-11 The Procter & Gamble Company Alkaline dishwasher detergent
USRE32818E (en) 1978-02-07 1989-01-03 Ecolab Inc. Cast detergent-containing article and method of using
USRE32763E (en) 1978-02-07 1988-10-11 Ecolab Inc. Cast detergent-containing article and method of making and using
US4212761A (en) 1978-03-06 1980-07-15 Novo Laboratories, Inc. Method and composition for cleaning dairy equipment
US4238345A (en) 1978-05-22 1980-12-09 Economics Laboratory, Inc. Stabilized liquid enzyme-containing detergent compositions
MX151028A (en) 1978-11-17 1984-09-11 Unilever Nv IMPROVEMENTS IN INSOLUBLE BAG BUT PERMEABLE TO WATER THAT HAS A DISPERSIBLE PROTECTIVE LAYER OR SOLUBLE IN WATER, WHICH CONTAINS A PARTICULATE DETERGENT COMPOSITION
US4211517A (en) 1978-11-27 1980-07-08 Bender Machine Works, Inc. Detergent supply control for automatic dishwasher
US4426362A (en) 1978-12-05 1984-01-17 Economics Laboratory, Inc. Solid block detergent dispenser
US4216125A (en) 1978-12-07 1980-08-05 Pq Corporation Detergent compositions with silane-zeolite silicate builder
US4243543A (en) 1979-05-11 1981-01-06 Economics Laboratory, Inc. Stabilized liquid enzyme-containing detergent compositions
US4261868A (en) 1979-08-08 1981-04-14 Lever Brothers Company Stabilized enzymatic liquid detergent composition containing a polyalkanolamine and a boron compound
US4284532A (en) 1979-10-11 1981-08-18 The Procter & Gamble Company Stable liquid detergent compositions
US4276205A (en) 1980-02-04 1981-06-30 The Procter & Gamble Company Detergent compositions containing amine oxide and nonionic surfactants and polyethylene glycol
US4268406A (en) 1980-02-19 1981-05-19 The Procter & Gamble Company Liquid detergent composition
US4481167A (en) 1980-04-11 1984-11-06 The Dow Chemical Company Sanitizing complexes of polyoxazolines or polyoxazines and polyhalide anions
US4692494A (en) 1980-12-15 1987-09-08 Colgate-Palmolive Company Water soluble films of polyvinyl alcohol and polyacrylic acid and packages comprising same
US4359413A (en) 1981-03-17 1982-11-16 The Procter & Gamble Company Solid detergent compositions containing alpha-amine oxide surfactants
DE3277730D1 (en) 1981-09-25 1988-01-07 Procter & Gamble LIQUID DETERGENT COMPOSITIONS CONTAINING AMINO-SILANES
DE3232616A1 (en) 1982-09-02 1984-03-08 Henkel KGaA, 4000 Düsseldorf LIQUID, INORGANIC FRUIT SALT, IN ESSENTIAL FREE DETERGENT AND CLEANING AGENT
US4664848A (en) 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
DE3315950A1 (en) 1983-05-02 1984-11-15 Henkel KGaA, 4000 Düsseldorf METHOD FOR PRODUCING DETERGENT TABLETS
US4474976A (en) 1983-08-29 1984-10-02 General Electric Company Method of producing phenyl silanes
JPS60189108A (en) 1984-03-08 1985-09-26 日本石油化学株式会社 Electrically insulating oil and oil-immersed electric device
US4537706A (en) 1984-05-14 1985-08-27 The Procter & Gamble Company Liquid detergents containing boric acid to stabilize enzymes
DE3418494A1 (en) 1984-05-18 1985-11-21 Hoechst Ag, 6230 Frankfurt DETERGENT AND CLEANING AGENT
GB8415302D0 (en) 1984-06-15 1984-07-18 Unilever Plc Fabric washing process
US4594175A (en) 1984-08-29 1986-06-10 Economics Laboratory, Inc. Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen
JPS6187800A (en) 1984-10-05 1986-05-06 ジヨンソン株式会社 Container filling type solid detergent composition
US4680134A (en) 1984-10-18 1987-07-14 Ecolab Inc. Method for forming solid detergent compositions
US4595520A (en) 1984-10-18 1986-06-17 Economics Laboratory, Inc. Method for forming solid detergent compositions
US5254287A (en) 1985-08-21 1993-10-19 The Clorox Company Encapsulated enzyme in dry bleach composition
US4677130A (en) 1985-10-07 1987-06-30 Great Lakes Chemical Corporation Process of densification of N-halohydantoin compositions and products thereof
US4715979A (en) 1985-10-09 1987-12-29 The Procter & Gamble Company Granular detergent compositions having improved solubility
US4858449A (en) 1986-01-09 1989-08-22 Ecolab Inc. Chemical solution dispenser apparatus and method of using
US4687121A (en) 1986-01-09 1987-08-18 Ecolab Inc. Solid block chemical dispenser for cleaning systems
US4836951A (en) 1986-02-19 1989-06-06 Union Carbide Corporation Random polyether foam control agents
US4725376A (en) 1986-04-23 1988-02-16 Ecolab Inc. Method of making solid cast alkaline detergent composition
US4826661A (en) 1986-05-01 1989-05-02 Ecolab, Inc. Solid block chemical dispenser for cleaning systems
US4698181A (en) 1986-06-30 1987-10-06 The Procter & Gamble Company Detergent compositions containing triethylenetetraminehexaacetic acid
US4753755A (en) 1986-08-25 1988-06-28 Diversey Wyandotte Corporation Solid alkaline detergent and process for making the same
US4845965A (en) 1986-12-23 1989-07-11 Ecolab Inc. Method and apparatus for dispensing solutions
US5019292A (en) 1987-06-30 1991-05-28 The Procter & Gamble Company Detergent compositions
US5078301A (en) 1987-10-02 1992-01-07 Ecolab Inc. Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use
US5034147A (en) 1988-01-19 1991-07-23 Colgate-Palmolive Company Process for manufacture of built synthetic organic detergent composition patties
US5080819A (en) 1988-05-27 1992-01-14 Ecolab Inc. Low temperature cast detergent-containing article and method of making and using
US4846993A (en) * 1988-07-11 1989-07-11 Ecolab Inc. Zero phosphate warewashing detergent composition
US4970058A (en) 1988-10-06 1990-11-13 Fmc Corporation Soda ash peroxygen carrier
US4966762A (en) 1988-10-06 1990-10-30 Fmc Corporation Process for manufacturing a soda ash peroxygen carrier
CA1322703C (en) * 1988-10-12 1993-10-05 William L. Smith High-carbonate automatic dishwashing detergent with decreased calcium salt deposition
DE4010533A1 (en) 1990-04-02 1991-10-10 Henkel Kgaa Prodn. of high-density detergent granules
US4983315A (en) 1989-08-10 1991-01-08 The Procter & Gamble Company N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions
US5061392A (en) 1990-02-07 1991-10-29 Dubois Chemicals, Inc. Method of making paste detergent and product produced
DE4007601A1 (en) 1990-03-09 1991-09-12 Henkel Kgaa METHOD FOR PRODUCING GRANULES OF A DETERGENT OR CLEANING AGENT
US5064561A (en) 1990-05-09 1991-11-12 Diversey Corporation Two-part clean-in-place system
US5358653A (en) 1990-06-25 1994-10-25 Ecolab, Inc. Chlorinated solid rinse aid
CA2084991C (en) 1990-07-13 2001-10-16 Richard E. Steindorf Solid rinse aid from food grade components
US5122538A (en) 1990-07-23 1992-06-16 Ecolab Inc. Peroxy acid generator
US5118426A (en) 1990-07-26 1992-06-02 Olin Corporation Process for purifying impotable water with hypochlorous acid
WO1992002611A1 (en) 1990-08-06 1992-02-20 Ecolab Inc. Manufacture of solid, cast non-swelling detergent compositions
EP0496361B1 (en) 1991-01-22 1999-08-18 Kao Corporation Detergent composition
JPH04271785A (en) 1991-02-28 1992-09-28 Kao Corp Enzymic solid pharmaceutical and its production
DE4112075A1 (en) * 1991-04-12 1992-10-15 Henkel Kgaa METHOD FOR PRODUCING STABLE, BIFUNCTIONAL, PHOSPATE AND METASILICATE-FREE LOW-ALKALINE DETERGENT TABLETS FOR THE MACHINE DISHWASHER
US5316688A (en) 1991-05-14 1994-05-31 Ecolab Inc. Water soluble or dispersible film covered alkaline composition
US5173207A (en) 1991-05-31 1992-12-22 Colgate-Palmolive Company Powered automatic dishwashing composition containing enzymes
US5234719A (en) 1991-06-04 1993-08-10 Ecolab Inc. Food additive sanitizing compositions
DE4134078A1 (en) 1991-10-15 1993-04-22 Henkel Kgaa CONCENTRATED AQUEOUS LIQUID DETERGENT
US5559089A (en) 1992-03-12 1996-09-24 The Procter & Gamble Company Low-dosage automatic dishwashing detergent with monopersulfate and enzymes
US5223179A (en) 1992-03-26 1993-06-29 The Procter & Gamble Company Cleaning compositions with glycerol amides
US5516449A (en) 1992-04-03 1996-05-14 The Procter & Gamble Company Detergent compositions
US5691292A (en) 1992-04-13 1997-11-25 The Procter & Gamble Company Thixotropic liquid automatic dishwashing composition with enzyme
GB9220669D0 (en) 1992-09-30 1992-11-11 Unilever Plc Detergent composition
US5292525A (en) 1992-10-14 1994-03-08 Merck & Co., Inc. Method and composition for removing an alginate from a cutaneous substrate
US5858299A (en) 1993-05-05 1999-01-12 Ecolab, Inc. Process for consolidating particulate solids
US5370729A (en) 1993-09-15 1994-12-06 Ecolab Inc. Food safe composition to facilitate soil removal
US5494817A (en) 1993-12-06 1996-02-27 Allergan, Inc. Sugar-based protease composition for use with constant-PH borate buffers
JP4031031B2 (en) 1993-12-30 2008-01-09 エコラボ インコーポレイテッド Stable hygroscopic detergent product
WO1995018214A1 (en) * 1993-12-30 1995-07-06 Ecolab Inc. Method of making non-caustic solid cleaning compositions
US5474698A (en) 1993-12-30 1995-12-12 Ecolab Inc. Urea-based solid alkaline cleaning composition
US5578134A (en) 1994-04-19 1996-11-26 Ecolab Inc. Method of sanitizing and destaining tableware
ES2132687T3 (en) 1994-07-04 1999-08-16 Unilever Nv WASHING COMPOSITION AND PROCEDURE.
US5419850A (en) 1994-07-22 1995-05-30 Monsanto Company Block detergent containing nitrilotriacetic acid
US5665694A (en) 1994-07-22 1997-09-09 Monsanto Company Block detergent containing nitrilotriacetic acid
US5861366A (en) 1994-08-31 1999-01-19 Ecolab Inc. Proteolytic enzyme cleaner
US5858117A (en) 1994-08-31 1999-01-12 Ecolab Inc. Proteolytic enzyme cleaner
NZ305268A (en) 1995-04-17 1999-07-29 Procter & Gamble Detergent cleaning composition comprising diacyl peroxide particulates, and preparation thereof
WO1997033957A1 (en) 1996-03-15 1997-09-18 Amway Corporation Powder detergent composition having improved solubility
MA25183A1 (en) 1996-05-17 2001-07-02 Arthur Jacques Kami Christiaan DETERGENT COMPOSITIONS
US6258765B1 (en) * 1997-01-13 2001-07-10 Ecolab Inc. Binding agent for solid block functional material
US6150324A (en) * 1997-01-13 2000-11-21 Ecolab, Inc. Alkaline detergent containing mixed organic and inorganic sequestrants resulting in improved soil removal
US6177392B1 (en) * 1997-01-13 2001-01-23 Ecolab Inc. Stable solid block detergent composition
US6156715A (en) * 1997-01-13 2000-12-05 Ecolab Inc. Stable solid block metal protecting warewashing detergent composition
US5876514A (en) 1997-01-23 1999-03-02 Ecolab Inc. Warewashing system containing nonionic surfactant that performs both a cleaning and sheeting function and a method of warewashing
US6017864A (en) 1997-12-30 2000-01-25 Ecolab Inc. Alkaline solid block composition

Also Published As

Publication number Publication date
AU728271B2 (en) 2001-01-04
EP1019483A1 (en) 2000-07-19
US20050119149A1 (en) 2005-06-02
DE69829864T2 (en) 2005-09-15
JP4299808B2 (en) 2009-07-22
CN1243539A (en) 2000-02-02
AR011071A1 (en) 2000-08-02
US6831054B2 (en) 2004-12-14
MY120135A (en) 2005-09-30
CA2277125C (en) 2007-05-29
US6177392B1 (en) 2001-01-23
ZA9710545B (en) 1999-05-24
US7094746B2 (en) 2006-08-22
US6583094B1 (en) 2003-06-24
DE69829864D1 (en) 2005-05-25
CN1205328C (en) 2005-06-08
AU5731898A (en) 1998-08-03
WO1998030674A1 (en) 1998-07-16
EP1019483B1 (en) 2005-04-20
JP2001508106A (en) 2001-06-19
TW438885B (en) 2001-06-07
BR9808887A (en) 2000-10-03
US20030216279A1 (en) 2003-11-20
ZA98165B (en) 1999-07-09
JP2005264168A (en) 2005-09-29

Similar Documents

Publication Publication Date Title
CA2277125A1 (en) Stable solid block detergent composition
ZA993700B (en) Stable solid block metal protecting warewashing detergent composition.
CA2277148A1 (en) Binding agent for solid block functional material
HN1999000019A (en) HOMOGENEOUS GRANULES COMPOSED OF SODIUM TRIPOLYPHOSPHATE, SODIUM SULPHATE AND SODIUM CARBONATE PROCEDURE FOR ITS MANUFACTURE AND APPLICATIONS IN DETERGENTS AND WASHING AGENTS.
PT1121410E (en) DETERGENT
MA24612A1 (en) DETERGENT COMPOSITIONS CONTAINING INTERRUPTED CRYSTALINITY SURFACTANT MIXTURES
HUP0202325A3 (en) Detergent compositions containing modified alkylaryl sulfonate surfactants
CA2231617A1 (en) A crystalline calcium carbonate builder encapsulated with a hydrotrope for use in detergent compositions
CA2276428A1 (en) Detergent
AU1555100A (en) Particulate laundry detergent compositions containing anionic surfactant granules
CA2145420A1 (en) Cleaning compositions containing novel alkaline proteases
CA2255854A1 (en) Detergent composition
AU1943199A (en) Low foaming surfactant compositions useful in highly alkaline caustic cleaners
DE69413055D1 (en) CALCIUM CARBONATE DEPOSITION CONTROL IN DISHWASHER
DE69425753D1 (en) CALCIUM CARBONATE DEPOSITION IN THE MACHINE DISHWASHER
CA2296354A1 (en) Detergent compositions
CA2234407A1 (en) Hard surface cleaning compositions
MX9701084A (en) Detergent composition.
CA2231646A1 (en) An encapsulated crystalline calcium carbonate builder for use in detergent compositions
MX169823B (en) IMPROVEMENTS TO DETERGENT POWDER FOR AUTOMATIC DISH WASHING
GB2363800A (en) Detergent compositions
ZA993758B (en) Detergent compositions comprising a mannanase and a mid-branched anionic surfactant.
CA2305216A1 (en) A detergent composition
MY133398A (en) Fabric cleaning composition containing zeolite
TR27773A (en) Aqueous, hard surface cleaner detergent compositions containing calcium ions.

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20180108