CA2277148A1 - Binding agent for solid block functional material - Google Patents

Binding agent for solid block functional material Download PDF

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Publication number
CA2277148A1
CA2277148A1 CA002277148A CA2277148A CA2277148A1 CA 2277148 A1 CA2277148 A1 CA 2277148A1 CA 002277148 A CA002277148 A CA 002277148A CA 2277148 A CA2277148 A CA 2277148A CA 2277148 A1 CA2277148 A1 CA 2277148A1
Authority
CA
Canada
Prior art keywords
binding agent
solid block
agent
solid
functional material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002277148A
Other languages
French (fr)
Other versions
CA2277148C (en
Inventor
G. Jason Wei
Steven E. Lentsch
Keith E. Olson
Victor F. Man
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab Inc
Original Assignee
Ecolab Inc.
G. Jason Wei
Steven E. Lentsch
Keith E. Olson
Victor F. Man
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/781,493 external-priority patent/US6177392B1/en
Application filed by Ecolab Inc., G. Jason Wei, Steven E. Lentsch, Keith E. Olson, Victor F. Man filed Critical Ecolab Inc.
Publication of CA2277148A1 publication Critical patent/CA2277148A1/en
Application granted granted Critical
Publication of CA2277148C publication Critical patent/CA2277148C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0052—Cast detergent compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen

Abstract

A solid functional material comprises a functional agent such as a cleaning composition, a sanitizing agent, a rinse agent, etc. in a solid block format. The solid block is formed by a binding agent that forms the active ingredients into a solid block. The binding agent comprises a phosphonate or amino acetate sequestrant, a carbonate salt and water in an E-Form hydrate. These materials at a specific mole ratio form a novel binding agent that can form functional materials into a solid matrix form.
CA002277148A 1997-01-13 1998-01-06 Binding agent for solid block functional material Expired - Lifetime CA2277148C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US3493197P 1997-01-13 1997-01-13
US08/781,493 US6177392B1 (en) 1997-01-13 1997-01-13 Stable solid block detergent composition
US08/781,493 1997-01-13
US60/034,931 1997-01-13
US08/989,824 1997-12-12
US08/989,824 US6258765B1 (en) 1997-01-13 1997-12-12 Binding agent for solid block functional material
PCT/US1998/000453 WO1998030675A1 (en) 1997-01-13 1998-01-06 Binding agent for solid block functional material

Publications (2)

Publication Number Publication Date
CA2277148A1 true CA2277148A1 (en) 1998-07-16
CA2277148C CA2277148C (en) 2007-04-24

Family

ID=27364764

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002277148A Expired - Lifetime CA2277148C (en) 1997-01-13 1998-01-06 Binding agent for solid block functional material

Country Status (17)

Country Link
US (4) US6258765B1 (en)
EP (1) EP0975732B1 (en)
JP (1) JP3913788B2 (en)
KR (1) KR100465279B1 (en)
CN (1) CN1194082C (en)
AR (1) AR011401A1 (en)
AT (1) ATE248910T1 (en)
AU (1) AU724117B2 (en)
BR (1) BR9806953A (en)
CA (1) CA2277148C (en)
DE (1) DE69817799T2 (en)
ES (1) ES2206883T3 (en)
ID (1) ID22588A (en)
MY (1) MY118699A (en)
NZ (1) NZ336348A (en)
TW (1) TW416983B (en)
WO (1) WO1998030675A1 (en)

Families Citing this family (97)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6258765B1 (en) * 1997-01-13 2001-07-10 Ecolab Inc. Binding agent for solid block functional material
US6177392B1 (en) * 1997-01-13 2001-01-23 Ecolab Inc. Stable solid block detergent composition
US6156715A (en) * 1997-01-13 2000-12-05 Ecolab Inc. Stable solid block metal protecting warewashing detergent composition
US6150324A (en) * 1997-01-13 2000-11-21 Ecolab, Inc. Alkaline detergent containing mixed organic and inorganic sequestrants resulting in improved soil removal
US6369021B1 (en) * 1999-05-07 2002-04-09 Ecolab Inc. Detergent composition and method for removing soil
US6730653B1 (en) * 2000-06-01 2004-05-04 Ecolab Inc. Method for manufacturing a molded detergent composition
US7037886B2 (en) * 2000-06-01 2006-05-02 Ecolab Inc. Method for manufacturing a molded detergent composition
US7795199B2 (en) * 2000-06-29 2010-09-14 Ecolab Inc. Stable antimicrobial compositions including spore, bacteria, fungi, and/or enzyme
US6503875B1 (en) 2000-08-18 2003-01-07 Ecolab Inc. Stabilized oxalic acid sour
FR2820823B1 (en) * 2001-02-09 2004-04-23 Inst Francais Du Petrole METHOD AND DEVICE FOR EVALUATING THE CAPACITY OF WELL FLUIDS TO FORM HYDRATES DURING DRILLING
JP2002348594A (en) * 2001-05-25 2002-12-04 Asahi Denka Kogyo Kk Solid block detergent composition and method for producing the same
US20030109403A1 (en) * 2001-06-05 2003-06-12 Ecolab, Inc. Solid cleaning composition including stabilized active oxygen component
US20030162685A1 (en) * 2001-06-05 2003-08-28 Man Victor Fuk-Pong Solid cleaning composition including stabilized active oxygen component
US20030139310A1 (en) * 2001-08-07 2003-07-24 Smith Kim R. Peroxygen compositions and methods for carpet or upholstery cleaning or sanitizing
US7153820B2 (en) 2001-08-13 2006-12-26 Ecolab Inc. Solid detergent composition and method for solidifying a detergent composition
US20030136942A1 (en) * 2001-11-30 2003-07-24 Smith Kim R. Stabilized active oxygen compositions
US6855328B2 (en) * 2002-03-28 2005-02-15 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
US6861154B2 (en) * 2002-09-26 2005-03-01 Ecolab, Inc. Coating wear indicator
US8110537B2 (en) * 2003-01-14 2012-02-07 Ecolab Usa Inc. Liquid detergent composition and methods for using
US7135448B2 (en) 2003-07-02 2006-11-14 Ecolab Inc. Warewashing composition for use in automatic dishwashing machines, comprising a mixture of aluminum and zinc ions
US7196044B2 (en) * 2003-07-02 2007-03-27 Ecolab, Inc. Warewashing composition for use in automatic dishwashing machines, comprising a zinc ion and aluminum ion corrosion inhibitor
US7279455B2 (en) * 2003-11-06 2007-10-09 Ecolab, Inc. Rinse aid composition and method of rising a substrate
US7423005B2 (en) * 2003-11-20 2008-09-09 Ecolab Inc. Binding agent for solidification matrix
US7442679B2 (en) * 2004-04-15 2008-10-28 Ecolab Inc. Binding agent for solidification matrix comprising MGDA
US8063010B2 (en) * 2004-08-02 2011-11-22 Ecolab Usa Inc. Solid detergent composition and methods for manufacturing and using
US7977299B2 (en) * 2004-08-18 2011-07-12 Ecolab Usa Inc. Treated oxidizing agent, detergent composition containing a treated oxidizing agent, and methods for producing
US20060174883A1 (en) * 2005-02-09 2006-08-10 Acoba, Llc Method and system of leak detection in application of positive airway pressure
US20060191851A1 (en) * 2005-02-25 2006-08-31 Mizuno William G Method for treating feedwater, feedwater treatment composition, and apparatus for treating feedwater
AU2006227692B2 (en) * 2005-03-18 2011-07-21 3M Innovative Properties Company Solid cleaners for heated food preparation surfaces
US20060293212A1 (en) * 2005-05-05 2006-12-28 Ecolab Inc. Stable solid compositions of spores, bacteria, fungi and/or enzyme
CN101421383B (en) * 2006-03-02 2011-12-14 金克克国际有限公司 surface active bleach and dynamic pH
US7759299B2 (en) * 2006-07-24 2010-07-20 Ecolab Inc. Warewashing composition for use in automatic dishwashing machines
US8093200B2 (en) 2007-02-15 2012-01-10 Ecolab Usa Inc. Fast dissolving solid detergent
US20100311633A1 (en) * 2007-02-15 2010-12-09 Ecolab Usa Inc. Detergent composition for removing fish soil
US8754264B2 (en) * 2007-04-05 2014-06-17 Nippon Shokubai Co., Ltd. Production method of unsaturated (poly)alkylene glycol ether monomer and production method of (poly)alkylene glycol chain-containing polymer
EP2190969B1 (en) * 2007-05-04 2014-08-20 Ecolab Inc. Pressed, self-solidifying, solid cleaning compositions and methods of making them
US7893012B2 (en) 2007-05-04 2011-02-22 Ecolab Inc. Solidification matrix
US7888303B2 (en) * 2007-05-04 2011-02-15 Ecolab Inc. Solidification matrix
US7763576B2 (en) * 2008-01-04 2010-07-27 Ecolab Inc. Solidification matrix using a polycarboxylic acid polymer
US8338352B2 (en) * 2007-05-07 2012-12-25 Ecolab Usa Inc. Solidification matrix
US7521412B2 (en) 2007-05-25 2009-04-21 Ecolab Inc. Dimensionally stable solid rinse aid
US8383570B2 (en) 2007-05-25 2013-02-26 Ecolab Usa Inc. Enhanced melting point rinse aid solid compositions with synergistic preservative
US20110108068A1 (en) 2007-05-25 2011-05-12 Ecolab Usa Inc. Enhanced melting point rinse aid solids
US8759269B2 (en) * 2007-07-02 2014-06-24 Ecolab Usa Inc. Solidification matrix including a salt of a straight chain saturated mono-, di-, and tri- carboxylic acid
US7759300B2 (en) 2007-07-02 2010-07-20 Ecolab Inc. Solidification matrix including a salt of a straight chain saturated mono-, di-, or tri- carboxylic acid
US8889048B2 (en) 2007-10-18 2014-11-18 Ecolab Inc. Pressed, self-solidifying, solid cleaning compositions and methods of making them
US8138138B2 (en) 2008-01-04 2012-03-20 Ecolab Usa Inc. Solidification matrix using a polycarboxylic acid polymer
US8772221B2 (en) 2008-01-04 2014-07-08 Ecolab Usa Inc. Solidification matrices using phosphonocarboxylic acid copolymers and phosphonopolyacrylic acid homopolymers
US8198228B2 (en) 2008-01-04 2012-06-12 Ecolab Usa Inc. Solidification matrix using an aminocarboxylate
CA2715690C (en) 2008-04-07 2016-09-06 Ecolab Inc. Ultra-concentrated liquid degreaser composition
US7838484B2 (en) * 2008-04-18 2010-11-23 Ecolab Inc. Cleaner concentrate comprising ethanoldiglycine and a tertiary surfactant mixture
US7723281B1 (en) 2009-01-20 2010-05-25 Ecolab Inc. Stable aqueous antimicrobial enzyme compositions comprising a tertiary amine antimicrobial
US7964548B2 (en) 2009-01-20 2011-06-21 Ecolab Usa Inc. Stable aqueous antimicrobial enzyme compositions
PL3425035T3 (en) 2009-05-12 2021-12-20 Ecolab Usa Inc. Fast drying and fast draining rinse aid
US8192553B2 (en) * 2009-05-26 2012-06-05 Ecolab Usa Inc. Pot and pan soaking composition
EP3480132A1 (en) 2009-05-28 2019-05-08 Ecolab USA Inc. Wetting agents for aseptic filling
US8530403B2 (en) * 2009-11-20 2013-09-10 Ecolab Usa Inc. Solidification matrix using a maleic-containing terpolymer binding agent
US20110124547A1 (en) * 2009-11-23 2011-05-26 Ecolab Inc. Solidification matrix using a sulfonated/carboxylated polymer binding agent
US8399393B2 (en) 2010-05-03 2013-03-19 Ecolab Usa Inc. Combination of soluble lithium salt and soluble aluminum or silicate salt as a glass etching inhibitor
US8361952B2 (en) 2010-07-28 2013-01-29 Ecolab Usa Inc. Stability enhancement agent for solid detergent compositions
US8636918B2 (en) 2011-08-05 2014-01-28 Ecolab Usa Inc. Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale
US8853144B2 (en) 2011-08-05 2014-10-07 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage
US8841246B2 (en) 2011-08-05 2014-09-23 Ecolab Usa Inc. Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage
US8679366B2 (en) 2011-08-05 2014-03-25 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale
US9567551B2 (en) 2012-06-22 2017-02-14 Ecolab Usa Inc. Solid rinse aid composition and method of making same
US9011610B2 (en) 2012-06-22 2015-04-21 Ecolab Usa Inc. Solid fast draining/drying rinse aid for high total dissolved solid water conditions
US8945314B2 (en) 2012-07-30 2015-02-03 Ecolab Usa Inc. Biodegradable stability binding agent for a solid detergent
WO2014021902A1 (en) 2012-08-03 2014-02-06 Ecolab Usa Inc. Biodegradable stability binding agent for a solid detergent
CN103911225B (en) 2013-01-04 2017-12-12 艺康美国股份有限公司 Solid tablet unit dose stove cleaning agent
US10184097B2 (en) 2013-02-08 2019-01-22 Ecolab Usa Inc. Protective coatings for detersive agents and methods of forming and detecting the same
CN113736588A (en) 2014-03-07 2021-12-03 艺康美国股份有限公司 Detergent composition exhibiting both cleaning and rinsing functions
US9365805B2 (en) 2014-05-15 2016-06-14 Ecolab Usa Inc. Bio-based pot and pan pre-soak
KR102040032B1 (en) 2014-08-29 2019-11-27 에코랍 유에스에이 인코퍼레이티드 Solid rinse aid composition comprising polyacrylic acid
US9982220B2 (en) 2015-05-19 2018-05-29 Ecolab Usa Inc. Efficient surfactant system on plastic and all types of ware
CN107922894B (en) 2015-08-21 2021-08-10 艺康美国股份有限公司 Pyrithione preservative system in solid rinse aid products
EP3350156B1 (en) 2015-09-17 2022-12-28 Ecolab USA Inc. Methods of making triamine solids
US10463041B2 (en) 2015-09-17 2019-11-05 Ecolab Usa Inc. Triamine solidification using diacids
US10221376B2 (en) * 2016-04-18 2019-03-05 Ecolab Usa Inc. Solidification process using low levels of coupler/hydrotrope
AU2017272086B2 (en) 2016-05-23 2019-06-27 Ecolab Usa Inc. Reduced misting alkaline and neutral cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers
WO2017205339A1 (en) 2016-05-23 2017-11-30 Ecolab Usa Inc. Reduced misting acidic cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers
CA3054827C (en) 2017-03-01 2023-02-14 Ecolab Usa Inc. Reduced inhalation hazard sanitizers and disinfectants via high molecular weight polymers
EP4043541B1 (en) 2017-03-01 2024-02-21 Ecolab USA Inc. Mechanism of urea/solid acid interaction under storage conditions and method of making storage stable solid compositions comprising urea and acid
SG11202002632VA (en) 2017-09-26 2020-04-29 Ecolab Usa Inc Acidic/anionic antimicrobial and virucidal compositions and uses thereof
CA3089557A1 (en) 2018-01-26 2019-08-01 Ecolab Usa Inc. Solidifying liquid anionic surfactants
CN111788287A (en) 2018-01-26 2020-10-16 埃科莱布美国股份有限公司 Solid cleaning composition
CN111655828A (en) 2018-01-26 2020-09-11 埃科莱布美国股份有限公司 Curing liquid amine oxide, betaine and/or sulfobetaine surfactants with a carrier
WO2019148076A1 (en) 2018-01-26 2019-08-01 Ecolab Usa Inc. Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a binder and optional carrier
EP3827069A1 (en) 2018-07-25 2021-06-02 Ecolab USA Inc. Rinse aid formulation for cleaning automotive parts
WO2020257749A1 (en) 2019-06-21 2020-12-24 Ecolab Usa Inc. Solid nonionic surfactant compositions
CA3145679A1 (en) 2019-07-03 2021-01-07 Ecolab Usa Inc. Hard surface cleaning compositions with reduced surface tension
BR112022000446A2 (en) 2019-07-12 2022-03-03 Ecolab Usa Inc Sprayable cleaning composition, system for applying sprayable cleaning composition with reduced mist production, and method of cleaning a hard surface using a sprayable cleaning composition with reduced mist production
US20210071108A1 (en) 2019-09-06 2021-03-11 Ecolab Usa Inc. Concentrated surfactant systems for rinse aid and other applications
CA3151823A1 (en) 2019-09-27 2021-04-01 Ecolab Usa Inc. Concentrated 2 in 1 dishmachine detergent and rinse aid
AU2020408331B2 (en) 2019-12-16 2023-12-14 Ecolab Usa Inc. Anionic surfactant impact on virucidal efficacy
CN115038333A (en) 2020-03-23 2022-09-09 埃科莱布美国股份有限公司 Novel 2 in 1 germicidal rinse aid compositions using amine based surfactants in warewashing
WO2021222510A1 (en) 2020-04-30 2021-11-04 Ecolab Usa Inc. Low foam cleaning compositions
JP2024514162A (en) 2021-04-15 2024-03-28 エコラボ ユーエスエー インコーポレイティド Enzyme bed cleaning composition

Family Cites Families (160)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US538425A (en) * 1895-04-30 Cooper n
US32763A (en) * 1861-07-09 Machine fob
US32818A (en) * 1861-07-16 Improvement in iron tses for cotton-bales
US32762A (en) * 1861-07-09 London
US1580576A (en) 1924-03-08 1926-04-13 Weidner Edmund Perfumed soap cake
US1949264A (en) 1929-03-20 1934-02-27 R M Hollingshead Co Method of making soap solution
US2412819A (en) 1945-07-21 1946-12-17 Mathieson Alkali Works Inc Detergent briquette
GB687075A (en) 1949-04-28 1953-02-04 George Franklyn Hicks Improvements in detergent briquettes and in method of and apparatus for making same
US2927900A (en) 1951-07-10 1960-03-08 Gen Aniline & Film Corp Solid detergent composition and process for preparation thereof
US2987483A (en) 1956-07-02 1961-06-06 Pennsalt Chemicals Corp Cleaning composition
US2920417A (en) 1958-01-22 1960-01-12 Sylvia T Wertheimer Detergent-solution dispensing container
US3052652A (en) 1958-02-26 1962-09-04 Borden Co Alkoxylated polyvinyl alcohol
US3048548A (en) 1959-05-26 1962-08-07 Economics Lab Defoaming detergent composition
US3280037A (en) 1961-05-12 1966-10-18 Borden Co Alkoxylated polyvinyl alcohol and alkoxylated amine compositions
US3277009A (en) 1961-10-03 1966-10-04 Gen Aniline & Film Corp Water-soluble package and method for making and using same
NL128174C (en) 1962-02-28
GB1053384A (en) 1962-06-06
US3392121A (en) 1962-11-05 1968-07-09 Procter & Gamble Built detergent compositions
US3356612A (en) 1965-02-01 1967-12-05 Petrolite Corp Stable detergent compositions
US3390092A (en) 1965-03-30 1968-06-25 Fmc Corp Dishwashing detergent preparations containing sodium or potassium dichloroisocyanurate
US3306858A (en) 1965-06-17 1967-02-28 Economics Lab Process for the preparation of storage stable detergent composition
US3441511A (en) 1965-12-20 1969-04-29 Wyandotte Chemicals Corp Alkali metal hydroxide-containing agglomerates
CA813301A (en) 1966-09-06 1969-05-20 E. Zimmerer Roger Detergent composition
US3442242A (en) * 1967-06-05 1969-05-06 Algonquin Shipping & Trading Stopping and manoeuvering means for large vessels
US3557003A (en) 1967-06-21 1971-01-19 Procter & Gamble Detergent tablet
US3534851A (en) 1968-03-18 1970-10-20 Us Health Education & Welfare Urine preservation package
GB1240058A (en) 1968-04-12 1971-07-21 Procter & Gamble Enzyme-containing detergent compositions
US3639286A (en) 1968-05-28 1972-02-01 Mario Ballestra Synthetic detergent in bar or cake form and the method to manufacture same
US3491028A (en) 1969-06-03 1970-01-20 Grace W R & Co Chlorine stable machine dishwashing composition
JPS4835329B1 (en) 1969-12-03 1973-10-27
US3856932A (en) 1969-12-16 1974-12-24 M May Tablet of a chlorine releasing solid compound
US4046507A (en) 1970-02-06 1977-09-06 Ciba-Geigy Ag Commercial packages containing dyestuffs
US3695989A (en) 1970-08-12 1972-10-03 Robert E Albert Cold water soluble foam plastic package
CA959370A (en) 1970-09-08 1974-12-17 William G. Mizuno Machine dishwashing detergent having a reduced condensed phosphate content
US3846346A (en) 1971-01-25 1974-11-05 Philadelphia Quartz Co Detergent composition with controlled alkalinity
US3941710A (en) 1972-04-24 1976-03-02 Lever Brothers Company Phosphate - free dishwashing compositions containing an alkyl polyether carboxylate surfactant
US3816320A (en) 1972-11-24 1974-06-11 Fmc Corp Stable dishwashing compositions containing sodium dichloroisocyanurate dihydrate
US4605509A (en) 1973-05-11 1986-08-12 The Procter & Gamble Company Detergent compositions containing sodium aluminosilicate builders
US3933670A (en) 1973-11-12 1976-01-20 Economic Laboratories, Inc. Process for making agglomerated detergents
US4274975A (en) 1974-03-11 1981-06-23 The Procter & Gamble Company Detergent composition
US3985669A (en) 1974-06-17 1976-10-12 The Procter & Gamble Company Detergent compositions
US4148603A (en) 1974-10-04 1979-04-10 Henkel Kommanditgesellschaft Auf Aktien Method of washing textiles and composition containing inorganic silicates and polycarboxylates and/or polyphosphonates
US4000080A (en) 1974-10-11 1976-12-28 The Procter & Gamble Company Low phosphate content detergent composition
GB1516848A (en) 1974-11-13 1978-07-05 Procter & Gamble Ltd Detergent composition
FR2298599A2 (en) 1975-01-24 1976-08-20 Sifrance NEW SOLID NON-CORROSIVE DETERGENT COMPOSITIONS
US3961754A (en) 1975-09-12 1976-06-08 Economics Laboratory, Inc. Spray and foam producing nozzle apparatus
GB1527706A (en) 1976-02-23 1978-10-11 Chemed Corp Detergent composition and its use in a dishwashing machin
US4105573A (en) 1976-10-01 1978-08-08 The Procter & Gamble Company Dishwasher detergent composition
USRE32762E (en) 1977-01-17 1988-10-11 Ballantine Laboratories, Inc. Adjustable instrument case
DE2810999A1 (en) 1977-03-17 1978-09-21 Unilever Nv Liq. aq. dishwashing compsn. for e.g. removing tea and coffee stains - contain potassium hydroxide, an alkali metal tri:poly-phosphate and a sequestering agent
GB1596756A (en) 1977-04-22 1981-08-26 Procter & Gamble Ltd Detergent compositions
CA1120819A (en) 1977-06-01 1982-03-30 Jurgen W.K. Gromer Detergent tablet
US4329246A (en) 1977-11-07 1982-05-11 The Procter & Gamble Company Alkaline dishwasher detergent
USRE32818E (en) 1978-02-07 1989-01-03 Ecolab Inc. Cast detergent-containing article and method of using
USRE32763E (en) 1978-02-07 1988-10-11 Ecolab Inc. Cast detergent-containing article and method of making and using
US4212761A (en) 1978-03-06 1980-07-15 Novo Laboratories, Inc. Method and composition for cleaning dairy equipment
US4238345A (en) 1978-05-22 1980-12-09 Economics Laboratory, Inc. Stabilized liquid enzyme-containing detergent compositions
US4289815A (en) 1978-06-26 1981-09-15 Airwick Industries, Inc. Cold water-insoluble polyvinyl alcohol pouch for the controlled release of active ingredients
MX151028A (en) 1978-11-17 1984-09-11 Unilever Nv IMPROVEMENTS IN INSOLUBLE BAG BUT PERMEABLE TO WATER THAT HAS A DISPERSIBLE PROTECTIVE LAYER OR SOLUBLE IN WATER, WHICH CONTAINS A PARTICULATE DETERGENT COMPOSITION
US4211517A (en) 1978-11-27 1980-07-08 Bender Machine Works, Inc. Detergent supply control for automatic dishwasher
US4426362A (en) 1978-12-05 1984-01-17 Economics Laboratory, Inc. Solid block detergent dispenser
US4216125A (en) 1978-12-07 1980-08-05 Pq Corporation Detergent compositions with silane-zeolite silicate builder
US4243543A (en) 1979-05-11 1981-01-06 Economics Laboratory, Inc. Stabilized liquid enzyme-containing detergent compositions
US4261868A (en) 1979-08-08 1981-04-14 Lever Brothers Company Stabilized enzymatic liquid detergent composition containing a polyalkanolamine and a boron compound
US4284532A (en) 1979-10-11 1981-08-18 The Procter & Gamble Company Stable liquid detergent compositions
US4276205A (en) 1980-02-04 1981-06-30 The Procter & Gamble Company Detergent compositions containing amine oxide and nonionic surfactants and polyethylene glycol
US4268406A (en) 1980-02-19 1981-05-19 The Procter & Gamble Company Liquid detergent composition
US4481167A (en) 1980-04-11 1984-11-06 The Dow Chemical Company Sanitizing complexes of polyoxazolines or polyoxazines and polyhalide anions
US4692494A (en) 1980-12-15 1987-09-08 Colgate-Palmolive Company Water soluble films of polyvinyl alcohol and polyacrylic acid and packages comprising same
US4359413A (en) 1981-03-17 1982-11-16 The Procter & Gamble Company Solid detergent compositions containing alpha-amine oxide surfactants
EP0075988B1 (en) 1981-09-25 1987-11-25 THE PROCTER & GAMBLE COMPANY Liquid detergent compositions containing amino-silanes
JPS591598A (en) * 1982-06-25 1984-01-06 花王株式会社 Detergent composition
DE3232616A1 (en) 1982-09-02 1984-03-08 Henkel KGaA, 4000 Düsseldorf LIQUID, INORGANIC FRUIT SALT, IN ESSENTIAL FREE DETERGENT AND CLEANING AGENT
US4664848A (en) 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
DE3315950A1 (en) 1983-05-02 1984-11-15 Henkel KGaA, 4000 Düsseldorf METHOD FOR PRODUCING DETERGENT TABLETS
US4474976A (en) 1983-08-29 1984-10-02 General Electric Company Method of producing phenyl silanes
JPS60189108A (en) 1984-03-08 1985-09-26 日本石油化学株式会社 Electrically insulating oil and oil-immersed electric device
US4608187A (en) * 1984-04-02 1986-08-26 The Clorox Company Rubber toughened polyvinyl alcohol film compositions
US4537706A (en) 1984-05-14 1985-08-27 The Procter & Gamble Company Liquid detergents containing boric acid to stabilize enzymes
DE3418494A1 (en) 1984-05-18 1985-11-21 Hoechst Ag, 6230 Frankfurt DETERGENT AND CLEANING AGENT
GB8415302D0 (en) 1984-06-15 1984-07-18 Unilever Plc Fabric washing process
US4594175A (en) 1984-08-29 1986-06-10 Economics Laboratory, Inc. Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen
JPS6187800A (en) 1984-10-05 1986-05-06 ジヨンソン株式会社 Container filling type solid detergent composition
US4680134A (en) 1984-10-18 1987-07-14 Ecolab Inc. Method for forming solid detergent compositions
US4595520A (en) 1984-10-18 1986-06-17 Economics Laboratory, Inc. Method for forming solid detergent compositions
DE3689826T2 (en) * 1985-02-26 1994-09-08 Sumitomo Chemical Co POLARIZING FILM.
US5254287A (en) 1985-08-21 1993-10-19 The Clorox Company Encapsulated enzyme in dry bleach composition
US4677130A (en) 1985-10-07 1987-06-30 Great Lakes Chemical Corporation Process of densification of N-halohydantoin compositions and products thereof
US4715979A (en) 1985-10-09 1987-12-29 The Procter & Gamble Company Granular detergent compositions having improved solubility
US4690305A (en) 1985-11-06 1987-09-01 Ecolab Inc. Solid block chemical dispenser for cleaning systems
US4687121A (en) 1986-01-09 1987-08-18 Ecolab Inc. Solid block chemical dispenser for cleaning systems
US4858449A (en) 1986-01-09 1989-08-22 Ecolab Inc. Chemical solution dispenser apparatus and method of using
US4836951A (en) 1986-02-19 1989-06-06 Union Carbide Corporation Random polyether foam control agents
US4725376A (en) 1986-04-23 1988-02-16 Ecolab Inc. Method of making solid cast alkaline detergent composition
US4826661A (en) 1986-05-01 1989-05-02 Ecolab, Inc. Solid block chemical dispenser for cleaning systems
US4698181A (en) 1986-06-30 1987-10-06 The Procter & Gamble Company Detergent compositions containing triethylenetetraminehexaacetic acid
US4753755A (en) 1986-08-25 1988-06-28 Diversey Wyandotte Corporation Solid alkaline detergent and process for making the same
US4845965A (en) 1986-12-23 1989-07-11 Ecolab Inc. Method and apparatus for dispensing solutions
US4965012A (en) 1987-04-17 1990-10-23 Olson Keith E Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches
US5019292A (en) 1987-06-30 1991-05-28 The Procter & Gamble Company Detergent compositions
US4830773A (en) * 1987-07-10 1989-05-16 Ecolab Inc. Encapsulated bleaches
US5198198A (en) * 1987-10-02 1993-03-30 Ecolab Inc. Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use
US5078301A (en) 1987-10-02 1992-01-07 Ecolab Inc. Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use
US5034147A (en) 1988-01-19 1991-07-23 Colgate-Palmolive Company Process for manufacture of built synthetic organic detergent composition patties
US4895667A (en) 1988-05-24 1990-01-23 The Dial Corporation Fabric treating compositions
US5080819A (en) 1988-05-27 1992-01-14 Ecolab Inc. Low temperature cast detergent-containing article and method of making and using
US4846993A (en) 1988-07-11 1989-07-11 Ecolab Inc. Zero phosphate warewashing detergent composition
US4966762A (en) 1988-10-06 1990-10-30 Fmc Corporation Process for manufacturing a soda ash peroxygen carrier
US4970058A (en) 1988-10-06 1990-11-13 Fmc Corporation Soda ash peroxygen carrier
DE4010533A1 (en) 1990-04-02 1991-10-10 Henkel Kgaa Prodn. of high-density detergent granules
US4983315A (en) 1989-08-10 1991-01-08 The Procter & Gamble Company N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions
US5061392A (en) 1990-02-07 1991-10-29 Dubois Chemicals, Inc. Method of making paste detergent and product produced
DE4007601A1 (en) 1990-03-09 1991-09-12 Henkel Kgaa METHOD FOR PRODUCING GRANULES OF A DETERGENT OR CLEANING AGENT
DE69133154T2 (en) * 1990-04-05 2003-07-24 Kao Corp Detergent Composition
GB2244220B (en) * 1990-05-01 1994-10-12 Courtaulds Films & Packaging Packaging materials
US5064561A (en) 1990-05-09 1991-11-12 Diversey Corporation Two-part clean-in-place system
US5358653A (en) 1990-06-25 1994-10-25 Ecolab, Inc. Chlorinated solid rinse aid
DK0539378T3 (en) 1990-07-13 1994-09-12 Ecolab Inc Solid food grade fabric softener
US5122538A (en) 1990-07-23 1992-06-16 Ecolab Inc. Peroxy acid generator
US5118426A (en) 1990-07-26 1992-06-02 Olin Corporation Process for purifying impotable water with hypochlorous acid
WO1992002611A1 (en) 1990-08-06 1992-02-20 Ecolab Inc. Manufacture of solid, cast non-swelling detergent compositions
US5312561A (en) 1991-01-22 1994-05-17 Kao Corporation Detergent composition
NZ239112A (en) 1991-01-29 1994-12-22 Ecolab Inc Solid alkaline compositions containing the reaction product in water of alkali metal hydroxide and alkali metal silicate; process of manufacture
JPH04271785A (en) 1991-02-28 1992-09-28 Kao Corp Enzymic solid pharmaceutical and its production
US5316688A (en) 1991-05-14 1994-05-31 Ecolab Inc. Water soluble or dispersible film covered alkaline composition
US5173207A (en) 1991-05-31 1992-12-22 Colgate-Palmolive Company Powered automatic dishwashing composition containing enzymes
US5234719A (en) 1991-06-04 1993-08-10 Ecolab Inc. Food additive sanitizing compositions
US5249737A (en) * 1991-09-09 1993-10-05 Ecolab Inc. Method for dispensing moisture-sensitive unit dose packages
DE4134078A1 (en) 1991-10-15 1993-04-22 Henkel Kgaa CONCENTRATED AQUEOUS LIQUID DETERGENT
US5559089A (en) 1992-03-12 1996-09-24 The Procter & Gamble Company Low-dosage automatic dishwashing detergent with monopersulfate and enzymes
US5223179A (en) 1992-03-26 1993-06-29 The Procter & Gamble Company Cleaning compositions with glycerol amides
US5516449A (en) 1992-04-03 1996-05-14 The Procter & Gamble Company Detergent compositions
US5691292A (en) 1992-04-13 1997-11-25 The Procter & Gamble Company Thixotropic liquid automatic dishwashing composition with enzyme
GB9220669D0 (en) 1992-09-30 1992-11-11 Unilever Plc Detergent composition
US5292525A (en) 1992-10-14 1994-03-08 Merck & Co., Inc. Method and composition for removing an alginate from a cutaneous substrate
US5858299A (en) 1993-05-05 1999-01-12 Ecolab, Inc. Process for consolidating particulate solids
US5370729A (en) 1993-09-15 1994-12-06 Ecolab Inc. Food safe composition to facilitate soil removal
US5494817A (en) 1993-12-06 1996-02-27 Allergan, Inc. Sugar-based protease composition for use with constant-PH borate buffers
AU1516795A (en) 1993-12-30 1995-07-17 Ecolab Inc. Method of making non-caustic solid cleaning compositions
BR9407783A (en) 1993-12-30 1997-03-11 Ecolab Inc Solid detergent article packaged coated detergent article method of dispensing an alkaline solid detergent article and method of dispensing and producing a detergent article
US5474698A (en) 1993-12-30 1995-12-12 Ecolab Inc. Urea-based solid alkaline cleaning composition
US5578134A (en) 1994-04-19 1996-11-26 Ecolab Inc. Method of sanitizing and destaining tableware
EP0770121B1 (en) 1994-07-04 1999-05-06 Unilever N.V. Washing process and composition
US5419850A (en) 1994-07-22 1995-05-30 Monsanto Company Block detergent containing nitrilotriacetic acid
US5665694A (en) 1994-07-22 1997-09-09 Monsanto Company Block detergent containing nitrilotriacetic acid
US5861366A (en) 1994-08-31 1999-01-19 Ecolab Inc. Proteolytic enzyme cleaner
US5858117A (en) 1994-08-31 1999-01-12 Ecolab Inc. Proteolytic enzyme cleaner
ES2148746T3 (en) 1995-04-17 2000-10-16 Procter & Gamble PREPARATION AND USE OF PARTICLES OF COMPOSITE MATERIAL CONTAINING DIACIL PEROXIDE.
JP3519532B2 (en) 1996-02-13 2004-04-19 ティーポールディバーシー株式会社 Solid detergent and its production method
AU2074397A (en) 1996-03-15 1997-10-01 Amway Corporation Powder detergent composition having improved solubility
MA25183A1 (en) 1996-05-17 2001-07-02 Arthur Jacques Kami Christiaan DETERGENT COMPOSITIONS
US5900395A (en) * 1996-12-23 1999-05-04 Lever Brothers Company Machine dishwashing tablets containing an oxygen bleach system
US6150324A (en) * 1997-01-13 2000-11-21 Ecolab, Inc. Alkaline detergent containing mixed organic and inorganic sequestrants resulting in improved soil removal
US6156715A (en) * 1997-01-13 2000-12-05 Ecolab Inc. Stable solid block metal protecting warewashing detergent composition
US6258765B1 (en) * 1997-01-13 2001-07-10 Ecolab Inc. Binding agent for solid block functional material
US6177392B1 (en) * 1997-01-13 2001-01-23 Ecolab Inc. Stable solid block detergent composition
US5876514A (en) 1997-01-23 1999-03-02 Ecolab Inc. Warewashing system containing nonionic surfactant that performs both a cleaning and sheeting function and a method of warewashing
US6017864A (en) 1997-12-30 2000-01-25 Ecolab Inc. Alkaline solid block composition
USD406635S (en) * 1998-01-13 1999-03-09 Ecolab, Inc. Bi-lobal solid block machine detergent
GB2365018A (en) * 2000-07-24 2002-02-13 Procter & Gamble Water soluble pouches

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