CA2279515A1 - Polymerization catalyst systems comprising heterocyclic fused cyclopentadienide ligands - Google Patents

Polymerization catalyst systems comprising heterocyclic fused cyclopentadienide ligands Download PDF

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Publication number
CA2279515A1
CA2279515A1 CA002279515A CA2279515A CA2279515A1 CA 2279515 A1 CA2279515 A1 CA 2279515A1 CA 002279515 A CA002279515 A CA 002279515A CA 2279515 A CA2279515 A CA 2279515A CA 2279515 A1 CA2279515 A1 CA 2279515A1
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CA
Canada
Prior art keywords
group
heterocyclic fused
catalyst systems
polymerization catalyst
periodic table
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002279515A
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French (fr)
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CA2279515C (en
Inventor
Richard A. Fischer
Rolf B. Temme
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents, Inc.
Richard A. Fischer
Rolf B. Temme
Exxonmobil Chemical Patents Inc.
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Application filed by Exxon Chemical Patents, Inc., Richard A. Fischer, Rolf B. Temme, Exxonmobil Chemical Patents Inc. filed Critical Exxon Chemical Patents, Inc.
Publication of CA2279515A1 publication Critical patent/CA2279515A1/en
Application granted granted Critical
Publication of CA2279515C publication Critical patent/CA2279515C/en
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

The invention relates to a polymerization catalyst system comprising a catalytic complex formed by activating a transition metal compound which comprises a metal selected from group 3 through 10 of the periodic table, preferably from group 4, 5, or 6 of the periodic table, and a group 13, 15, or 16 heterocyclic fused cyclopentadienide ligand.
In one embodiment the inventive transition metal compound is represented by the [L]m M[A]n(S)o wherein M is a transition metal selected from grups 3 through 10 of the periodic table, and at least one of L is group 13, 15, or 16 heterocyclic fused cyclopentadienide ligand. Also disclosed is a polymerization process utilizing the catalyst systems of the invention. Ethylene polymerizations or copolymerizations with dimethyl (.eta.5-pentamethylcyclopentadienyl)(1-azaindenyl) zirconium and bis(5-methyl-cyclopenta[b]thiophene)zirconium dichloride, activated by tris(pentafluorophenyl) boron and methylalumoxane, respectively, are illustrated.
CA002279515A 1997-02-25 1998-02-24 Polymerization catalyst systems comprising heterocyclic fused cyclopentadienide ligands Expired - Fee Related CA2279515C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US80618197A 1997-02-25 1997-02-25
US08/806,181 1997-02-25
US08/999,214 1997-12-29
US08/999,214 US6451938B1 (en) 1997-02-25 1997-12-29 Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
PCT/US1998/003622 WO1998037106A1 (en) 1997-02-25 1998-02-24 Polymerization catalyst systems comprising heterocyclic fused cyclopentadienide ligands

Publications (2)

Publication Number Publication Date
CA2279515A1 true CA2279515A1 (en) 1998-08-27
CA2279515C CA2279515C (en) 2008-04-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA002279515A Expired - Fee Related CA2279515C (en) 1997-02-25 1998-02-24 Polymerization catalyst systems comprising heterocyclic fused cyclopentadienide ligands

Country Status (7)

Country Link
US (1) US6451938B1 (en)
EP (1) EP0963382B2 (en)
JP (1) JP4237263B2 (en)
CA (1) CA2279515C (en)
DE (1) DE69802500T3 (en)
ES (1) ES2167870T5 (en)
WO (1) WO1998037106A1 (en)

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US7667064B2 (en) * 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
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US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
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KR101384450B1 (en) 2010-04-12 2014-04-25 롯데케미칼 주식회사 Process for preparing olefin-diene copolymer using transition metal compound comprising thiophene-fused cyclopentadienyl ligand
JP5567208B2 (en) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション Olefin polymerization catalyst composition and method for producing polyolefin using the same
JP5468708B2 (en) 2010-04-12 2014-04-09 ロッテ ケミカル コーポレーション Process for producing olefin-diene copolymer using transition metal compound containing thiophene-fused ring cyclopentadienyl ligand
KR100986301B1 (en) * 2010-04-12 2010-10-07 아주대학교산학협력단 Group 4 metal complexes of thiophene-fused cyclopentadienyl ligand derived from tetrahydroquinoline derivatives and olefin polymerizations therewith
JP5567209B2 (en) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション Supported catalyst for olefin polymerization and process for producing polyolefin using the same
CN105916870A (en) * 2013-11-19 2016-08-31 莫门蒂夫性能材料股份有限公司 Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
CN114702531A (en) * 2021-01-01 2022-07-05 中国石油化工股份有限公司 Metallocene, catalyst containing same, synthesis and application thereof
CN114702532A (en) * 2021-01-01 2022-07-05 中国石油化工股份有限公司 Metallocene, catalyst containing same, synthesis and application thereof
CN114716485A (en) * 2021-01-04 2022-07-08 中国石油化工股份有限公司 Metallocene, catalyst composition and application of catalyst composition in synthesis of base oil
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Also Published As

Publication number Publication date
EP0963382B1 (en) 2001-11-14
EP0963382B2 (en) 2008-07-02
JP4237263B2 (en) 2009-03-11
DE69802500T3 (en) 2009-02-26
WO1998037106A1 (en) 1998-08-27
DE69802500T2 (en) 2002-06-27
ES2167870T5 (en) 2008-12-01
US6451938B1 (en) 2002-09-17
JP2001512523A (en) 2001-08-21
EP0963382A1 (en) 1999-12-15
ES2167870T3 (en) 2002-05-16
DE69802500D1 (en) 2001-12-20
CA2279515C (en) 2008-04-15

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