CA2304724C - Shampoo and conditioner hair care rinse-off compositions containing silicone - Google Patents
Shampoo and conditioner hair care rinse-off compositions containing silicone Download PDFInfo
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- CA2304724C CA2304724C CA002304724A CA2304724A CA2304724C CA 2304724 C CA2304724 C CA 2304724C CA 002304724 A CA002304724 A CA 002304724A CA 2304724 A CA2304724 A CA 2304724A CA 2304724 C CA2304724 C CA 2304724C
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
Abstract
This invention relates to a method for thermal conditioning of hair which comprises: (a) applying to hair a rinse-off composition comprising (1) a nonvolatile silicone conditioning agent; and (2) a carrier; (b) rinsing the composition from the hair with water; (c) applying heat via a heating appliance to the composition treated hair to dry or style the hair and wherein a reduction in the bending modulus caused by the silicone conditioning agent is at least 1.00 %, and wherein the method of the invention results in the deposition on the hair of at least 30 microgram silicone/1 g of hair.
Description
HEAT-MEDIATED CONDITIONING FROM SHAMPOO AND CONDITIONER HAIR
CARE COMPOSITIONS CONTAINING SILICONE
BACKGROUND OF INVENTION AND PRIOR ART
There is sufficient evidence both from both consumer and clinical testing that the use of heat styling appliances is damaging to human hair.
For consumers that heat style, their primary concern is to use a shampoo or conditioner treatment that can protect and improve the condition of their hair. Shampoos and conditioners containing silicone conditioning agents are able to deliver these benefits by 1) coating the hair with a conforming layer of silicone that smoothes the hair's imperfections such as roughness, cracks, cuticle uplift, or cuticle removal, and, 2) helping to protect the hair from extreme internal water loss with heat. As a result of coating the hair with conditioning agents, shampoo and conditioner treatments often impart increased softness, better combing characteristics, luster, and in general, improve the appearance of one's hair.
The claimed invention not only protects the hair from the damaging action of heat, but in addition, uses heat to mediate increased conditioning or softness dependent on the delivery and deposition of conditioning agent between certain specified levels.
- la -Silicones are well known and widely used as conditioning agents for hair in rinse-off formulations such as shampoos and conditioners. Such formulations are disclosed in, for example, DE 32 06 448A, US 5 346 642, WO 98 16189A, US 3 964 500, US 5 612 301 and JP O1 132 509A. However, it is not suggested in these documents that a heat-mediated increase in hair conditioning benefit might be achievable by the use of a heating appliance in conjunction with a silicone containing composition. The use of heatirLg appliances is normally considered injurious to hair, causing dryness, brittleness and damage. Consequently, formulations have to date been developed with the stated aim of protecting aga,~nst or ameliorating the effect of heat (for example as ir~ E.P C 681 826 A2) rather than using it to COn:.ultlOn hair.
Z
p~rE~pED SH~E~
t _ ~~~~
CARE COMPOSITIONS CONTAINING SILICONE
BACKGROUND OF INVENTION AND PRIOR ART
There is sufficient evidence both from both consumer and clinical testing that the use of heat styling appliances is damaging to human hair.
For consumers that heat style, their primary concern is to use a shampoo or conditioner treatment that can protect and improve the condition of their hair. Shampoos and conditioners containing silicone conditioning agents are able to deliver these benefits by 1) coating the hair with a conforming layer of silicone that smoothes the hair's imperfections such as roughness, cracks, cuticle uplift, or cuticle removal, and, 2) helping to protect the hair from extreme internal water loss with heat. As a result of coating the hair with conditioning agents, shampoo and conditioner treatments often impart increased softness, better combing characteristics, luster, and in general, improve the appearance of one's hair.
The claimed invention not only protects the hair from the damaging action of heat, but in addition, uses heat to mediate increased conditioning or softness dependent on the delivery and deposition of conditioning agent between certain specified levels.
- la -Silicones are well known and widely used as conditioning agents for hair in rinse-off formulations such as shampoos and conditioners. Such formulations are disclosed in, for example, DE 32 06 448A, US 5 346 642, WO 98 16189A, US 3 964 500, US 5 612 301 and JP O1 132 509A. However, it is not suggested in these documents that a heat-mediated increase in hair conditioning benefit might be achievable by the use of a heating appliance in conjunction with a silicone containing composition. The use of heatirLg appliances is normally considered injurious to hair, causing dryness, brittleness and damage. Consequently, formulations have to date been developed with the stated aim of protecting aga,~nst or ameliorating the effect of heat (for example as ir~ E.P C 681 826 A2) rather than using it to COn:.ultlOn hair.
Z
p~rE~pED SH~E~
t _ ~~~~
Sum~arv of the Invention The invention is the use of silicone based conditioairg agents in shampoos, conditioners or the like, to elicit a heat - mediated reduction urn: benda.ng modulus, or softening, or conditioning to hair, as compared to air dried, treated hair. The heat required to elicit the effect would be the heat exposure of a blow dryer or styling appliance, measured at point of origin of the appliance to be typically between ~200°F to ~ 400 °F.
In brief , the present inventioxZ is directed to the use of a silicone conditioning agent to elicit a heat-mediated reduction ~ in bending modulus, or softening or conditioning to hair, as compared to air-dxied treated hair, in a method fox thermal conditioning hair Which comprises:
(a) applying to hair a xinse-off composition contprisizig (1) a nonvolaLi.le. silicone conditioning agent;
and (2) a carrier;
(b) rinsing the Composition from the hair with rpater;
2S (c) applying heat via a heating appiiaace to the composition treated hair to dry or sty3.e the hair and wherein a reduction ire, the bending modilus caused by the silicone conditioning agent ~'_s at least l.Oa~k, and wherein the method for thermal conditioning hair results ire the deposition on the hair of at least 30 microgram silicone/1g of hair.
In brief , the present inventioxZ is directed to the use of a silicone conditioning agent to elicit a heat-mediated reduction ~ in bending modulus, or softening or conditioning to hair, as compared to air-dxied treated hair, in a method fox thermal conditioning hair Which comprises:
(a) applying to hair a xinse-off composition contprisizig (1) a nonvolaLi.le. silicone conditioning agent;
and (2) a carrier;
(b) rinsing the Composition from the hair with rpater;
2S (c) applying heat via a heating appiiaace to the composition treated hair to dry or sty3.e the hair and wherein a reduction ire, the bending modilus caused by the silicone conditioning agent ~'_s at least l.Oa~k, and wherein the method for thermal conditioning hair results ire the deposition on the hair of at least 30 microgram silicone/1g of hair.
DETAILED DESCRIPTION OF THE INVENTION
As used herein nonvolatile, silicone conditioning agent means any silicone having a boiling point of 200qC or greater, typically this would include silicones within a broad range of molecular weight, and having viscosities of between 5 centistokes to 1 million centistokes.
As used herein, SLES means sodium lauryl ether sulfate.
As used herein, heating device means heating appliance.
As used herein, ~ means weight ~ unless otherwise indicated.
Heat activation is defined as some change that is mediated by use of the composition of the invention with heat, from styling appliances such as a blow dryer, curling iron, hot curler, hot brush, hot comb, hot rollers, crimper, or hair dryer. From internal testing of various appliances this average temperature can range on the "hot" setting to be 2008 to 400~F.
Any nonvolatile silicone conditioning agent which will deposit silicone on hair may be used in the compositions and methods of the present invention. Silicone agents in the compositions of the present invention include dimethicone, dimethiconol, phenyl trimethicone, dimethicone copolyols, amino functional silicones, organically modified silicone resins such as stearyl siloxysilicate and lauric siloxysilicate, silicone gums, silicone elastomers, and cross-linked siloxane polymers which may be either linear or branched.
Silicone conditioning agents are responsible for a heat-induced reduction in bending modulus or softening of the hair. The preferred non-volatile silicone conditioning agents are dimethiconol, dimethicone, amodimethicone which are added to a composition of the present invention in an amount sufficient to provide improved combing and improved feel (softness) to the hair after shampooing.
Preferred silicones include linear and branched polydimethylsiloxanes, of the following general formula: (CHj) 3 Si0-- [Si (CH;) ZO] n--Si (CH 3) 3, wherein n is from 7 to 15,000, preferably from 7 to 9,000.
Silicones useful in compositions of the present invention are available from a variety of commercial sources, including General Electric Company and Dow Corning. In addition to the linear and branched polydimethylsiloxanes, the polydimethylsiloxanes can be organically modified to include amine, hydroxyl, alkyl, alkyl aryl, ethoxylated, and propoxylated functionalities.
In accordance with one important embodiment, the composition of the present invention also includes from 0.1~ to 10~, particularly 0.5~k to 10~, and preferably from 1.0~ to 5.0~, by weight of a non-volatile silicone compound or other conditioning agent(s), preferably a water-insoluble, emulsifiable conditioning agent. Any nonvolatile silicone agent will work in the compositions and methods of the invention provided that the silicone agent deposits sufficient silicone onto the hair.
Deposition of silicone onto the hair may be quantitated by extraction of silicone from hair treated with the composition followed by spectroscopic analysis for the element silicon. Comparison against a standard (i.e a solution of the silicone of known concentration) then gives an amout of silicone which may be converted into micrograms of silicone/gram of hair.
Using compositions and methods of the invention, the nonvolatile, silicone conditioning agent was present in the compositions at an active range of 0.1 to 2.0~, depositing on hair in the range of 30microgram/g to 1200microgram/g hair. In these just above mentioned compositions, the nonvolatile, silicone conditioning agents were as follows:
Dimethiconol containing silicone emulsions such as, Dimethiconol (and) TEA- Dodecylbenzenesulfonate (and) Polyethylene Oxide Laurel Ether. Non-emulsion forms of silicone conditioning agents include dimethicone; and amodimethicone.
The surface active agent can be anionic, cationic, nonionic, zwitterionic or amphoteric. Typically useful surface active agents contain at least one fatty, carbon atom, chain. The individual surface active agents can also be used in mixtures of two or more surface active agents or their salts.
Exemplary anionic surface active agents include but are not limited to alkali metal and ammonium salts of fatty alkyl sulfates and fatty alpha-olefin sulfonates such as ammonium lauryl sulfate and the sodium alpha-olefin sulfonate prepared from mixed olefins having 12 to 18 carbon atoms in the fatty chain, alkali metal and ammonium soaps such as potassium oleate and ammonium palmitate, alkali metal ethoxylated fatty alkanol sulfates and phosphates such as sodium polyoxyethylene myristyl sulfate arid potassium polyoxyethylene lauryl phosphate in which there are an average of 1 to 4 oxyethylene units per molecule, and the like.
Exemplary nonionic surface active agents include but are not limited to polyoxyethylene derivatives of fatty alcohols containing 4 to 25 oxyethylene units per molecule such as polyoxyethylene (20) cetyl ether and polyoxyethylene (4) lauryl ether, polyoxyethylene w.
derivatives of octyl- and nonylphenols containing an average of 4 to 25 oxyethylene units such as polyoxyethylene (9) octylphenyl ether and polyoxyethylene (15) nonylphenyl ether, mono- and dialkanol amides of fatty acids such as N-(2-hydroxyethyl) tallow acid amide and N,N-bis-(2-hydroxyethyl) coco fatty acid amide, and the like.
WO 99/17713 PCT/EP9$/06243 _ Exemplary cationic surface active agents include but are not limited to quaternary nitrogen-containing compounds that include the following structures: (1) one fatty chain and three lower alkyl (one to four carbon atoms) substituents on the quaternary nitrogen such as stearyltrimethylammonium chloride and cetyldimethylethylammonium bromide; (2) one fatty chain, two lower alkyl groups and a benzyl group such as cetyldimethylbenzylammonium bromide; (3) two fatty chains and two lower alkyl groups such as dimethyldi-(hydrogenated tallow)-ammonium chloride; (4) three fatty chains and one lower alkyl group such as tricetylmethylammonium chloride;
and the like.
Exemplary zwitterionic surface active agents include but are not limited to betaine and sultaine derivatives such as stearyldimethylglycine, cocamidopropyldimethylglycine, cocamidopropyldimethyl sultaine, cocamidopropylbetaine and the like, as well as fatty tertiary amine oxides such as dimethylcocoamine oxide and dimethylstearylamine oxide.
Illustrative amphoteric surface active agents include but are not limited to fatty chain derivatives of mono- and dicarboxy substituted imidazolines such as 2-heptadecyl-1-carboxymethyl-1-(2-hydroxyethyl)-2-imidazolinium chloride, 2-undecyl-1-(sodium carboxymethyl)-1-(2-hydroxyethyl)-2-imidazolinium hydroxide. Also included among the amphoteric surface active agents are fatty derivatives of glycine such as lauryl aminopropylglycine.
g _ The word "fatty" is used herein to refer to carbon atom chains that contain 12 to 18 carbon atoms. The word "fatty" is also used in conjunction with carbon atom chains that are derived from chains of 12 to 18 carbon atoms, wherein at least one atom of the chain is within a ring structure, rather than being pendant from that ring structure, as is the case for one imidazoline derivative discussed hereinbefore.
The composition also can include a suspending agent for the conditioning agent, in an amount of 0.5~ to 10~, by total weight of the composition. The particular suspending agent is not critical and can be selected from any materials known to suspend water-insoluble liquids in shampoo or conditioner compositions. Suitable suspending agents are for example, distearyl amate (distearyl phthalamic acid);
fatty acid alkanolamides; esters of polyols and sugars;
polyethyleneglycols; the ethoxylated or propoxylated alkylphenols; ethoxylated or propoxylated fatty alcohols;
and the condensation products of ethylene oxide with long chain amides. These suspending agents, as well as numerous others not cited herein, are well known in the art and are fully described in the literature, such as McCUTCHEON'S
DETERGENTS AND EMULSIFIERS, 1989 Annual, published by McCutcheon Division, MC Publishing Co.
A nonionic alkanolamide also is optionally included in an amount of 0.1~ to 5~ by weight in the shampoo or conditioner compositions that include a conditioning agent to provide exceptionally stable emulsification of i _ _ ' CA 02304724 2002-02-18 WO 99/17713 P~~P,~~~3 _ g _ water-insoluble conditioning agents and to aid in thickening and foam stability.
Suitable alkanolamides include, but are not limited to, those known in the art of hair care formulations, such as cocamide monoethanolamide (MEA), cocamide diethanolamide (DEA), soyamide DEA, lauramide DEA, oleamide monoisopropylamide (MIPA), stearamide MEA, myristamide MEA, lauramide MEA, capramide DEA, ricinoleamide DEA, myristamide DEA, stearamide DEA, oleylamide DEA, tallowamide DEA, lauramide MIPA, tallowamide MEA, isostearamide DEA, isostearamide MEA and combinations thereof. Other suitable suspending agents are disclosed in Oh et al. U:S. Pat. No. 4,704,272 Grote et al. U.S. Pat.
No. 4,741,855: and Bolich, Jr. et al. U. S. Pat. No.
4,788,006. , Other useful suspending and thickening agents can be used instead of the alkanolamides such as monosodium glutamate, sodium alginate: guar gum; xanthan gum; gum arabic; cellulose derivatives, such as carbomer, ,.
methylcellulose, hydroxybutylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and carboxymethylcellulose; and various synthetic polymeric thickeners, such as, the polyacrylic acid derivatives.
Emulsion stabilizers also may be used in compositions of the invention. Useful ~es include, such cot~ounds as polyethylene glycol, silicone copolyols, polyvinyl WO 99/17713 PCT/EP98/06243 _ alcohol, sorbitan monostearate, oleth-2, sorbitan monolaurate, and nonionic block copolymers of ethylene oxide and propylene oxide such as those marketed by BASF
Wyandotte under the name PLURONICS(R). When present, such stabilizers comprise from 0.05 to 1$, preferably from 0.1~ to 0.8~, by weight of the composition.
Other common cosmetic additives can be incorporated with the essential ingredients of the present invention, as long as the basic properties of the shampoo and conditioners or the like are not adversely affected. These additives include, but are not limited to, commonly used fragrances, dyes, opacifiers, pearlescing agents, foam stabilizers, preservatives, water softening agents, acids, bases, sequestering agents, buffers, protein, amino acids, other non-silicone conditioning agents and the like; and will usually be present in weight percentages of less than 1~ each, and 2~ to 5~ in total.
The composition vehicle, or carrier, is predominantly water but organic solvents also can be added to the composition in order to solubilize compounds that are not sufficiently soluble in water. Suitable solvents include the lower alcohols like ethanol and isopropanol; polyols like glycerol; glycols or glycol ethers, like 2-butoxyethanol, ethylene glycol, ethylene glycol monoethyl ether, propylene glycol and diethylene glycol monomethyl ether; and mixtures thereof. These solvents can be present in the shampoo or conditioner or the like composition of the present invention in an amount from WO 99/17713 PC'T/EP98106243 _ 1~ to 85~ by weight and, in particular, from 5~ to 50~ by weight, relative to the total weight of the composition.
Hair serums are included within the compositions of the invention.
w FORMULATION EXAMPLES
As shown in the data below, nonvolatile silicone conditioning agents, contained within the formulations of the invention and depositing silicone within certain ranges, are responsible for the heat-mediated reduction in bending modulus, or hair softening, or conditioning.
Shampoo formulations were tested for heat induced bending modulus changes. The formulas ranged from base shampoo detergent in water, next, to the addition of carbopol, propylene glycol, jaguar, and anionic silicone emulsion (DC1784), to base detergent and water with DC1784. The shampoo formulations and results are presented in Table I.
Only hair arrays treated with the formulas of the invention containing silicone with jaguar(D, F) and silicone alone (E) exhibit any statistical change in modulus, a reduction of approximately 8.00, 6.00, and 7.00, respectively.
WO 99/17713 PCT/EP98/06243 _ TABLE I
SHAMPOO COMPOSITIONS, INGREDIENTS, WT $, AND BENDING MODULUS
RESULT(P>.05) SHAMPOO INGREDIENTS WT% BENDING
FORMULATION MODULUS
Formula A SLES -2 moles 56.00 No change Cocamidopropyl 6.7 Betaine q.s.
Water Formula B SLES -2 moles 56.00 No Change Cocamidopropyl 6.7 Betaine 20.00 Carbopol Slurry' q.s.
Water Formula C SLES -2 moles 56.00 No Change Cocamidopropyl 6.7 Betaine 20.00 Carbopol Slurry 0.1 JaguarZ 0.5 Propylene Glycol q.s.
Water Formula D SLES -2 moles 56.00 Approxima Cocamidopropyl 6.7 to Betaine 20.00 Reduction Carbopol Slurry 0.1 of 8.00 Jaguar 0.5 Propylene Glycol 4.0 Dimethiconol q.s.
(DC1784) Water Formula E SLES -2 moles 56.00 Approxima Cocamidopropyl 6.7 to Betaine 20.00 Reduction Carbopol Slurry 4.0 of Dimethiconol q.s. 7.00 (DC1784) Water FORMULA F SLES -2 moles 56.00 Approxima Cocamidopropyl 6.7 to Betaine 20.00 Reduction Carbopol Slurry 0.1 of WO 99/17713 PCT/EP98/06243 _ Jaguar 0.5 6.00 Propylene Glycol 1.5 Dimethiconol q.s.
(DC1784) Water * q.s. - quantity sufficient for the formula weight percentage to equal 100.
12~ Carbomer slurry 2 Jaguar is guar-hydroxypropyltrimmonium chloride WO 99/17713 PCT/EP98/06243 _ Conditioner formulations were tested for heat induced bending modulus changes. The compositions and bending modulus results are listed in Table II.
TABLE II. CONDITIONER COMPOSITIONS, INGREDIENTS, WT $, AND
BENDING MODULUS RESULT(P>.05) CONDITIONER G INGREDIENTS BENDING MODULUS
INGREDIENTS RESULT
water, soft q.s.* Reduction of 4.00 cetrimonium chloride 4.65 cetyl/stearyl alcohol 3.75 cetyl alcohol 3.75 paraffin wax 1.25 stearyl stearate 0.50 dimethiconol 2.50 (DC 1784) fragrance/ 0.90 preservatives * q.s. - quantity sufficient for the total formula weight percentage to equal 100.
w WO 99/17713 PCT/EP98/06243 _ CONDITIONER H WEIGHT % BENDING~MODULUS
INGREDIENTS RESULT
water, soft q.s.* Approximate Reduction of 5.00 natrosol ( 250 HHR) 0.2500000 stearylamidopropyl 0.5000000 dimethylamine liquid citric acid 0.1850000 50$
stearyl octyldimonium 1.7500000 methosulfate cetyl alcohol 2.7500000 stearyl alcohol 1.2500000 behenamidopropyl 0.7200000 ethyldimonium ethosulfate preservatives 0.2800000 amodimethicone 1.2500000 (DC929) cyclomethicone 1.6000000 fragrance 0.6000000 ajidew ( N-50) 0.0200000 glycerin USP 0.0500000 solu-soy (EN-25) 0.0450000 potassium hydroxide 0.1000000 (liquid 50~) * q.s. - quantity sufficient for the total formula weight percentage to equal 100.
.~.
CONDITIONER I H1EIGHT % BENDING MODULUS
INGREDIENTS _ RESULT
water, soft q.s. Approximate Reduction of 3.00 propylene glycol 0.5000000 stearylamidopropyl 0.5000000 dimethyl amine liquid citric acid 0.1850000 (50~ liquid) dicetyldimonium 2.1000000 chloride cetyl alcohol 3.7500000 stearyl alcohol 1.0000000 disodium EDTA 0.1000000 preservative 0.1800000 dimethicone 0.1000000 cyclomethicone 1.8000000 fragrance 0.6000000 * q.s. - quantity sufficient for the total formula weight percentage to equal 100.
WO 99/17713 PCT/EP98/06243 _ TESTING METHODS
Quantitation of Silicone Deposited on Treated Tresses A one gram sampling of a tress that has been treated with the test composition is extracted with two 50 ml aliquots of chloroform using sonication to aid the extraction. The extracts are combined and evaporated to dryness. The residue is dissolved in 10 ml of chloroform.
This solution is analyzed by aspiration into an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) using a solution of known concentration of silicone as the one point standard. This instrument is an elemental analyzer, so the element, silicon, is being quantitated. The amount of silicone in the extract can be calculated using the known silicon fraction in the silicone.
Dynamic mechanical testing of bending modulus Dynamic mechanical testing of the force or modulus to bend a bundle of hair fibers characterizes the stiffness of the hair .w array, i.e., its resistance to a controlled normal force imposed on the array in the vertical direction. If the modulus increases with treatment the array is stiffer. If the modulus decreases with treatment the array is less stiff;
softer; fibers have reduced interfiber friction.
WO 99/17713 PCT/EP98/06243 _ The measurement of bending modulus is not unique to analysis of the physical properties of hair, but reported works had been exclusively devoted to the properties of single hair fiber ( see Bobbins, Clarence R., Chemical and Physical Behavior of Hair, Third edition. Springer-Verlag, New York.
1993) and therefore never addressed the characteristics of multiple fibers. In addition, the bending modulus was calculated from the deflection of a single fiber in a static not dynamic mode as used in this test method and reported in the literature for other materials (Lee, T.H., Boey, F.Y., and Loh, N.L..
Characterization of Fibre-Reinforced PPS Composite By Dynamic Mechanical Analysis: Effect of Aspect Ratio and Static Stress. Composites Science and Technology 49 (1993 217-223).
~. 5 Instruments are commercially available to measure the mechanical properties of a variety of materials, hair included. The Perkin Elmer DMA ? Dynamic Mechanical Analyzer, used at Helene Curtis R&D, is equipped to perform three point bending modulus, and was used for thermal studies of bending modulus of treated hair. The use of a hair bundle or array allows eva~.uation of multiple fiber changes and/or fiber interaction in contrast to single fiber effect.
~5 Two hundred fifty fibers of the same length are selected from a regular brown hair tress. The fibers are wetted and aligned on a flat surface to form a ribbon-like swatch. A single drop of water proof adhe~cive is placed at five spots on the swatch.
WO 99/17713 PCT/Ep98/06243 The distance between each junction is about 1 inch. When dry, four bundles are cut from one swatch.
Eight hair bundles are treated with a composition per treatment group. The weight of each hair bundle is measured prior to the test in order to assure that the amount of composition applied remains at a constant proportion to the mass of hair of 1:10 for shampoos and 3:5 with respect to conditioners. For rinse-off products such as shampoos and conditioners, the desired amount of product is applied with a micropipette to the wet hair, worked in for 30 seconds and rinsed out in warm water for 30 seconds. All samples are air dried in the instrument at 72F and a controlled humidity of 30~. To heat the sample in the testing chamber the DMA
furnace is engaged to 200 F, and the sample is heated for approximately 7 minutes.
Bendinct Modulus Results: Thermally-Induced Changes to the Bending Modulus of Formulas of the Invention- Treated Hair Arrays.
~a The results of testing are presented in Tables I and II.
Hair arrays treated with the shampoo and conditioner formulations of the invention, exhibit a statistically significant reduction in bending modulus (p<.05), following heat treatment. Measurement of the storage bending modulus of untreated, air dried hair vs. heated hair reveals that untreated hair will exhibit an increase in bending modulus of approximately +8.00, probably due to water loss. All decreases in bending modulus listed in Tables I and II are statistically significant at >95~ confidence level using a t-test to compare the means of the treated air-dried samples vs. treated, heated samples.
As used herein nonvolatile, silicone conditioning agent means any silicone having a boiling point of 200qC or greater, typically this would include silicones within a broad range of molecular weight, and having viscosities of between 5 centistokes to 1 million centistokes.
As used herein, SLES means sodium lauryl ether sulfate.
As used herein, heating device means heating appliance.
As used herein, ~ means weight ~ unless otherwise indicated.
Heat activation is defined as some change that is mediated by use of the composition of the invention with heat, from styling appliances such as a blow dryer, curling iron, hot curler, hot brush, hot comb, hot rollers, crimper, or hair dryer. From internal testing of various appliances this average temperature can range on the "hot" setting to be 2008 to 400~F.
Any nonvolatile silicone conditioning agent which will deposit silicone on hair may be used in the compositions and methods of the present invention. Silicone agents in the compositions of the present invention include dimethicone, dimethiconol, phenyl trimethicone, dimethicone copolyols, amino functional silicones, organically modified silicone resins such as stearyl siloxysilicate and lauric siloxysilicate, silicone gums, silicone elastomers, and cross-linked siloxane polymers which may be either linear or branched.
Silicone conditioning agents are responsible for a heat-induced reduction in bending modulus or softening of the hair. The preferred non-volatile silicone conditioning agents are dimethiconol, dimethicone, amodimethicone which are added to a composition of the present invention in an amount sufficient to provide improved combing and improved feel (softness) to the hair after shampooing.
Preferred silicones include linear and branched polydimethylsiloxanes, of the following general formula: (CHj) 3 Si0-- [Si (CH;) ZO] n--Si (CH 3) 3, wherein n is from 7 to 15,000, preferably from 7 to 9,000.
Silicones useful in compositions of the present invention are available from a variety of commercial sources, including General Electric Company and Dow Corning. In addition to the linear and branched polydimethylsiloxanes, the polydimethylsiloxanes can be organically modified to include amine, hydroxyl, alkyl, alkyl aryl, ethoxylated, and propoxylated functionalities.
In accordance with one important embodiment, the composition of the present invention also includes from 0.1~ to 10~, particularly 0.5~k to 10~, and preferably from 1.0~ to 5.0~, by weight of a non-volatile silicone compound or other conditioning agent(s), preferably a water-insoluble, emulsifiable conditioning agent. Any nonvolatile silicone agent will work in the compositions and methods of the invention provided that the silicone agent deposits sufficient silicone onto the hair.
Deposition of silicone onto the hair may be quantitated by extraction of silicone from hair treated with the composition followed by spectroscopic analysis for the element silicon. Comparison against a standard (i.e a solution of the silicone of known concentration) then gives an amout of silicone which may be converted into micrograms of silicone/gram of hair.
Using compositions and methods of the invention, the nonvolatile, silicone conditioning agent was present in the compositions at an active range of 0.1 to 2.0~, depositing on hair in the range of 30microgram/g to 1200microgram/g hair. In these just above mentioned compositions, the nonvolatile, silicone conditioning agents were as follows:
Dimethiconol containing silicone emulsions such as, Dimethiconol (and) TEA- Dodecylbenzenesulfonate (and) Polyethylene Oxide Laurel Ether. Non-emulsion forms of silicone conditioning agents include dimethicone; and amodimethicone.
The surface active agent can be anionic, cationic, nonionic, zwitterionic or amphoteric. Typically useful surface active agents contain at least one fatty, carbon atom, chain. The individual surface active agents can also be used in mixtures of two or more surface active agents or their salts.
Exemplary anionic surface active agents include but are not limited to alkali metal and ammonium salts of fatty alkyl sulfates and fatty alpha-olefin sulfonates such as ammonium lauryl sulfate and the sodium alpha-olefin sulfonate prepared from mixed olefins having 12 to 18 carbon atoms in the fatty chain, alkali metal and ammonium soaps such as potassium oleate and ammonium palmitate, alkali metal ethoxylated fatty alkanol sulfates and phosphates such as sodium polyoxyethylene myristyl sulfate arid potassium polyoxyethylene lauryl phosphate in which there are an average of 1 to 4 oxyethylene units per molecule, and the like.
Exemplary nonionic surface active agents include but are not limited to polyoxyethylene derivatives of fatty alcohols containing 4 to 25 oxyethylene units per molecule such as polyoxyethylene (20) cetyl ether and polyoxyethylene (4) lauryl ether, polyoxyethylene w.
derivatives of octyl- and nonylphenols containing an average of 4 to 25 oxyethylene units such as polyoxyethylene (9) octylphenyl ether and polyoxyethylene (15) nonylphenyl ether, mono- and dialkanol amides of fatty acids such as N-(2-hydroxyethyl) tallow acid amide and N,N-bis-(2-hydroxyethyl) coco fatty acid amide, and the like.
WO 99/17713 PCT/EP9$/06243 _ Exemplary cationic surface active agents include but are not limited to quaternary nitrogen-containing compounds that include the following structures: (1) one fatty chain and three lower alkyl (one to four carbon atoms) substituents on the quaternary nitrogen such as stearyltrimethylammonium chloride and cetyldimethylethylammonium bromide; (2) one fatty chain, two lower alkyl groups and a benzyl group such as cetyldimethylbenzylammonium bromide; (3) two fatty chains and two lower alkyl groups such as dimethyldi-(hydrogenated tallow)-ammonium chloride; (4) three fatty chains and one lower alkyl group such as tricetylmethylammonium chloride;
and the like.
Exemplary zwitterionic surface active agents include but are not limited to betaine and sultaine derivatives such as stearyldimethylglycine, cocamidopropyldimethylglycine, cocamidopropyldimethyl sultaine, cocamidopropylbetaine and the like, as well as fatty tertiary amine oxides such as dimethylcocoamine oxide and dimethylstearylamine oxide.
Illustrative amphoteric surface active agents include but are not limited to fatty chain derivatives of mono- and dicarboxy substituted imidazolines such as 2-heptadecyl-1-carboxymethyl-1-(2-hydroxyethyl)-2-imidazolinium chloride, 2-undecyl-1-(sodium carboxymethyl)-1-(2-hydroxyethyl)-2-imidazolinium hydroxide. Also included among the amphoteric surface active agents are fatty derivatives of glycine such as lauryl aminopropylglycine.
g _ The word "fatty" is used herein to refer to carbon atom chains that contain 12 to 18 carbon atoms. The word "fatty" is also used in conjunction with carbon atom chains that are derived from chains of 12 to 18 carbon atoms, wherein at least one atom of the chain is within a ring structure, rather than being pendant from that ring structure, as is the case for one imidazoline derivative discussed hereinbefore.
The composition also can include a suspending agent for the conditioning agent, in an amount of 0.5~ to 10~, by total weight of the composition. The particular suspending agent is not critical and can be selected from any materials known to suspend water-insoluble liquids in shampoo or conditioner compositions. Suitable suspending agents are for example, distearyl amate (distearyl phthalamic acid);
fatty acid alkanolamides; esters of polyols and sugars;
polyethyleneglycols; the ethoxylated or propoxylated alkylphenols; ethoxylated or propoxylated fatty alcohols;
and the condensation products of ethylene oxide with long chain amides. These suspending agents, as well as numerous others not cited herein, are well known in the art and are fully described in the literature, such as McCUTCHEON'S
DETERGENTS AND EMULSIFIERS, 1989 Annual, published by McCutcheon Division, MC Publishing Co.
A nonionic alkanolamide also is optionally included in an amount of 0.1~ to 5~ by weight in the shampoo or conditioner compositions that include a conditioning agent to provide exceptionally stable emulsification of i _ _ ' CA 02304724 2002-02-18 WO 99/17713 P~~P,~~~3 _ g _ water-insoluble conditioning agents and to aid in thickening and foam stability.
Suitable alkanolamides include, but are not limited to, those known in the art of hair care formulations, such as cocamide monoethanolamide (MEA), cocamide diethanolamide (DEA), soyamide DEA, lauramide DEA, oleamide monoisopropylamide (MIPA), stearamide MEA, myristamide MEA, lauramide MEA, capramide DEA, ricinoleamide DEA, myristamide DEA, stearamide DEA, oleylamide DEA, tallowamide DEA, lauramide MIPA, tallowamide MEA, isostearamide DEA, isostearamide MEA and combinations thereof. Other suitable suspending agents are disclosed in Oh et al. U:S. Pat. No. 4,704,272 Grote et al. U.S. Pat.
No. 4,741,855: and Bolich, Jr. et al. U. S. Pat. No.
4,788,006. , Other useful suspending and thickening agents can be used instead of the alkanolamides such as monosodium glutamate, sodium alginate: guar gum; xanthan gum; gum arabic; cellulose derivatives, such as carbomer, ,.
methylcellulose, hydroxybutylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and carboxymethylcellulose; and various synthetic polymeric thickeners, such as, the polyacrylic acid derivatives.
Emulsion stabilizers also may be used in compositions of the invention. Useful ~es include, such cot~ounds as polyethylene glycol, silicone copolyols, polyvinyl WO 99/17713 PCT/EP98/06243 _ alcohol, sorbitan monostearate, oleth-2, sorbitan monolaurate, and nonionic block copolymers of ethylene oxide and propylene oxide such as those marketed by BASF
Wyandotte under the name PLURONICS(R). When present, such stabilizers comprise from 0.05 to 1$, preferably from 0.1~ to 0.8~, by weight of the composition.
Other common cosmetic additives can be incorporated with the essential ingredients of the present invention, as long as the basic properties of the shampoo and conditioners or the like are not adversely affected. These additives include, but are not limited to, commonly used fragrances, dyes, opacifiers, pearlescing agents, foam stabilizers, preservatives, water softening agents, acids, bases, sequestering agents, buffers, protein, amino acids, other non-silicone conditioning agents and the like; and will usually be present in weight percentages of less than 1~ each, and 2~ to 5~ in total.
The composition vehicle, or carrier, is predominantly water but organic solvents also can be added to the composition in order to solubilize compounds that are not sufficiently soluble in water. Suitable solvents include the lower alcohols like ethanol and isopropanol; polyols like glycerol; glycols or glycol ethers, like 2-butoxyethanol, ethylene glycol, ethylene glycol monoethyl ether, propylene glycol and diethylene glycol monomethyl ether; and mixtures thereof. These solvents can be present in the shampoo or conditioner or the like composition of the present invention in an amount from WO 99/17713 PC'T/EP98106243 _ 1~ to 85~ by weight and, in particular, from 5~ to 50~ by weight, relative to the total weight of the composition.
Hair serums are included within the compositions of the invention.
w FORMULATION EXAMPLES
As shown in the data below, nonvolatile silicone conditioning agents, contained within the formulations of the invention and depositing silicone within certain ranges, are responsible for the heat-mediated reduction in bending modulus, or hair softening, or conditioning.
Shampoo formulations were tested for heat induced bending modulus changes. The formulas ranged from base shampoo detergent in water, next, to the addition of carbopol, propylene glycol, jaguar, and anionic silicone emulsion (DC1784), to base detergent and water with DC1784. The shampoo formulations and results are presented in Table I.
Only hair arrays treated with the formulas of the invention containing silicone with jaguar(D, F) and silicone alone (E) exhibit any statistical change in modulus, a reduction of approximately 8.00, 6.00, and 7.00, respectively.
WO 99/17713 PCT/EP98/06243 _ TABLE I
SHAMPOO COMPOSITIONS, INGREDIENTS, WT $, AND BENDING MODULUS
RESULT(P>.05) SHAMPOO INGREDIENTS WT% BENDING
FORMULATION MODULUS
Formula A SLES -2 moles 56.00 No change Cocamidopropyl 6.7 Betaine q.s.
Water Formula B SLES -2 moles 56.00 No Change Cocamidopropyl 6.7 Betaine 20.00 Carbopol Slurry' q.s.
Water Formula C SLES -2 moles 56.00 No Change Cocamidopropyl 6.7 Betaine 20.00 Carbopol Slurry 0.1 JaguarZ 0.5 Propylene Glycol q.s.
Water Formula D SLES -2 moles 56.00 Approxima Cocamidopropyl 6.7 to Betaine 20.00 Reduction Carbopol Slurry 0.1 of 8.00 Jaguar 0.5 Propylene Glycol 4.0 Dimethiconol q.s.
(DC1784) Water Formula E SLES -2 moles 56.00 Approxima Cocamidopropyl 6.7 to Betaine 20.00 Reduction Carbopol Slurry 4.0 of Dimethiconol q.s. 7.00 (DC1784) Water FORMULA F SLES -2 moles 56.00 Approxima Cocamidopropyl 6.7 to Betaine 20.00 Reduction Carbopol Slurry 0.1 of WO 99/17713 PCT/EP98/06243 _ Jaguar 0.5 6.00 Propylene Glycol 1.5 Dimethiconol q.s.
(DC1784) Water * q.s. - quantity sufficient for the formula weight percentage to equal 100.
12~ Carbomer slurry 2 Jaguar is guar-hydroxypropyltrimmonium chloride WO 99/17713 PCT/EP98/06243 _ Conditioner formulations were tested for heat induced bending modulus changes. The compositions and bending modulus results are listed in Table II.
TABLE II. CONDITIONER COMPOSITIONS, INGREDIENTS, WT $, AND
BENDING MODULUS RESULT(P>.05) CONDITIONER G INGREDIENTS BENDING MODULUS
INGREDIENTS RESULT
water, soft q.s.* Reduction of 4.00 cetrimonium chloride 4.65 cetyl/stearyl alcohol 3.75 cetyl alcohol 3.75 paraffin wax 1.25 stearyl stearate 0.50 dimethiconol 2.50 (DC 1784) fragrance/ 0.90 preservatives * q.s. - quantity sufficient for the total formula weight percentage to equal 100.
w WO 99/17713 PCT/EP98/06243 _ CONDITIONER H WEIGHT % BENDING~MODULUS
INGREDIENTS RESULT
water, soft q.s.* Approximate Reduction of 5.00 natrosol ( 250 HHR) 0.2500000 stearylamidopropyl 0.5000000 dimethylamine liquid citric acid 0.1850000 50$
stearyl octyldimonium 1.7500000 methosulfate cetyl alcohol 2.7500000 stearyl alcohol 1.2500000 behenamidopropyl 0.7200000 ethyldimonium ethosulfate preservatives 0.2800000 amodimethicone 1.2500000 (DC929) cyclomethicone 1.6000000 fragrance 0.6000000 ajidew ( N-50) 0.0200000 glycerin USP 0.0500000 solu-soy (EN-25) 0.0450000 potassium hydroxide 0.1000000 (liquid 50~) * q.s. - quantity sufficient for the total formula weight percentage to equal 100.
.~.
CONDITIONER I H1EIGHT % BENDING MODULUS
INGREDIENTS _ RESULT
water, soft q.s. Approximate Reduction of 3.00 propylene glycol 0.5000000 stearylamidopropyl 0.5000000 dimethyl amine liquid citric acid 0.1850000 (50~ liquid) dicetyldimonium 2.1000000 chloride cetyl alcohol 3.7500000 stearyl alcohol 1.0000000 disodium EDTA 0.1000000 preservative 0.1800000 dimethicone 0.1000000 cyclomethicone 1.8000000 fragrance 0.6000000 * q.s. - quantity sufficient for the total formula weight percentage to equal 100.
WO 99/17713 PCT/EP98/06243 _ TESTING METHODS
Quantitation of Silicone Deposited on Treated Tresses A one gram sampling of a tress that has been treated with the test composition is extracted with two 50 ml aliquots of chloroform using sonication to aid the extraction. The extracts are combined and evaporated to dryness. The residue is dissolved in 10 ml of chloroform.
This solution is analyzed by aspiration into an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) using a solution of known concentration of silicone as the one point standard. This instrument is an elemental analyzer, so the element, silicon, is being quantitated. The amount of silicone in the extract can be calculated using the known silicon fraction in the silicone.
Dynamic mechanical testing of bending modulus Dynamic mechanical testing of the force or modulus to bend a bundle of hair fibers characterizes the stiffness of the hair .w array, i.e., its resistance to a controlled normal force imposed on the array in the vertical direction. If the modulus increases with treatment the array is stiffer. If the modulus decreases with treatment the array is less stiff;
softer; fibers have reduced interfiber friction.
WO 99/17713 PCT/EP98/06243 _ The measurement of bending modulus is not unique to analysis of the physical properties of hair, but reported works had been exclusively devoted to the properties of single hair fiber ( see Bobbins, Clarence R., Chemical and Physical Behavior of Hair, Third edition. Springer-Verlag, New York.
1993) and therefore never addressed the characteristics of multiple fibers. In addition, the bending modulus was calculated from the deflection of a single fiber in a static not dynamic mode as used in this test method and reported in the literature for other materials (Lee, T.H., Boey, F.Y., and Loh, N.L..
Characterization of Fibre-Reinforced PPS Composite By Dynamic Mechanical Analysis: Effect of Aspect Ratio and Static Stress. Composites Science and Technology 49 (1993 217-223).
~. 5 Instruments are commercially available to measure the mechanical properties of a variety of materials, hair included. The Perkin Elmer DMA ? Dynamic Mechanical Analyzer, used at Helene Curtis R&D, is equipped to perform three point bending modulus, and was used for thermal studies of bending modulus of treated hair. The use of a hair bundle or array allows eva~.uation of multiple fiber changes and/or fiber interaction in contrast to single fiber effect.
~5 Two hundred fifty fibers of the same length are selected from a regular brown hair tress. The fibers are wetted and aligned on a flat surface to form a ribbon-like swatch. A single drop of water proof adhe~cive is placed at five spots on the swatch.
WO 99/17713 PCT/Ep98/06243 The distance between each junction is about 1 inch. When dry, four bundles are cut from one swatch.
Eight hair bundles are treated with a composition per treatment group. The weight of each hair bundle is measured prior to the test in order to assure that the amount of composition applied remains at a constant proportion to the mass of hair of 1:10 for shampoos and 3:5 with respect to conditioners. For rinse-off products such as shampoos and conditioners, the desired amount of product is applied with a micropipette to the wet hair, worked in for 30 seconds and rinsed out in warm water for 30 seconds. All samples are air dried in the instrument at 72F and a controlled humidity of 30~. To heat the sample in the testing chamber the DMA
furnace is engaged to 200 F, and the sample is heated for approximately 7 minutes.
Bendinct Modulus Results: Thermally-Induced Changes to the Bending Modulus of Formulas of the Invention- Treated Hair Arrays.
~a The results of testing are presented in Tables I and II.
Hair arrays treated with the shampoo and conditioner formulations of the invention, exhibit a statistically significant reduction in bending modulus (p<.05), following heat treatment. Measurement of the storage bending modulus of untreated, air dried hair vs. heated hair reveals that untreated hair will exhibit an increase in bending modulus of approximately +8.00, probably due to water loss. All decreases in bending modulus listed in Tables I and II are statistically significant at >95~ confidence level using a t-test to compare the means of the treated air-dried samples vs. treated, heated samples.
Claims (24)
1. A method for thermal conditioning hair which comprises:
(a) applying to hair a rinse-off composition comprising:
(1) a nonvolatile, silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein a reduction in the bending modulus caused by the silicone conditioning agent is at least 1.00%.
(a) applying to hair a rinse-off composition comprising:
(1) a nonvolatile, silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein a reduction in the bending modulus caused by the silicone conditioning agent is at least 1.00%.
2. A method according to claim 1, wherein the silicone conditioning agent is any silicone having a boiling point of 200°C or greater.
3. A method according to claim 1, wherein the nonvolatile, silicone conditioning agent is in an emulsion.
4. A method according to claim 1, wherein the nonvolatile, silicone conditioning agent is selected from the group consisting of dimethicone, dimethiconol, phenyl trimethicone, dimethicone copolyols, amino functional silicones, organically modified silicone resins such as stearyl siloxysilicate and lauric siloxysilicate, silicone gums, silicone elastomers, and crosslinked siloxane polymers which may be either linear or branched.
5. A method according to claim 1, wherein the heating appliance or device is a blow-dryer, curling iron, hot comb, hot curlers, hot rollers, hot brush, crimper, or hair dryer.
6. A method according to claim 1, wherein the hair being conditioned is in a hairpiece, extension, or wig.
7. A method for thermal conditioning hair which comprises:
(a) applying to hair a rinse-off composition comprising:
(1) a nonvolatile, silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein the method of the invention results in the deposition on the hair of at least 30 microgram silicone/1g of hair.
(a) applying to hair a rinse-off composition comprising:
(1) a nonvolatile, silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein the method of the invention results in the deposition on the hair of at least 30 microgram silicone/1g of hair.
8. A method according to claim 7, wherein the silicone conditioning agent has a boiling point of at least 200°C.
9. A method according to claim 7, wherein the silicone conditioning agent is selected from the group consisting dimethicone, dimethiconol, phenyl trimethicone, dimethicone copolyols, amino functional silicones, organically modified silicone resins such as stearyl siloxysilicate and lauric siloxysilicate, silicone gums, silicone elastomers, and crosslinked siloxane polymers which may be either linear or branched.
10. A method according to claim 7, wherein the silicone conditioning agent is in an emulsion.
11. A method according to claim 7, wherein the heating appliance is a blow-dryer, curling iron, hot comb, hot curlers, hot rollers, hot brush, crimper or hair dryer.
12. A method according to claim 7, wherein the hair being conditioned is in a hairpiece, extension, or wig.
13. A method for thermal conditioning hair which comprises:
(a) applying to hair a rinse-off composition comprising:
(1) a nonvolatile silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein a reduction in the bending modulus caused by the silicone conditioning agent is at least 1.00%; and wherein the method of the invention results in the deposition on the hair of at least 30 microgram silicone/1g of hair.
(a) applying to hair a rinse-off composition comprising:
(1) a nonvolatile silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein a reduction in the bending modulus caused by the silicone conditioning agent is at least 1.00%; and wherein the method of the invention results in the deposition on the hair of at least 30 microgram silicone/1g of hair.
14. A method for conditioning hair according to claim 1 wherein the reduction in the bending modulus caused by the silicone conditioning agent is at least 2.00%.
15. A method for thermal conditioning hair according to claim 1 wherein the amount of silicone deposited on the hair is at least 60 microgram silicone/1g of hair.
16. A kit comprising a composition according to claim 1 and a heating appliance.
17. The use of a silicone conditioning agent to elicit a heat-mediated reduction in bending modulus, or softening or conditioning to hair, as compared to air-dried, treated hair, in a method for thermal conditioning hair which comprises:
(a) applying to hair a rinse-off composition comprising:
(1) non-volatile, silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein a reduction in the bending modulus caused by the silicone conditioning agent is at least 1.00%; and wherein the method for thermal conditioning hair results in the deposition on the hair of at least 30 microgram silicone/1g of hair.
(a) applying to hair a rinse-off composition comprising:
(1) non-volatile, silicone conditioning agent; and (2) a carrier;
(b) rinsing the composition from the hair with water;
(c) applying heat via a heating appliance to the composition treated hair to dry or style the hair wherein the temperature of the heating appliance during the heating step is from 200°F to 400°F at the point of origin of the heating appliance and wherein a reduction in the bending modulus caused by the silicone conditioning agent is at least 1.00%; and wherein the method for thermal conditioning hair results in the deposition on the hair of at least 30 microgram silicone/1g of hair.
18. Use according to claim 17, wherein the silicone conditioning agent is any silicone having a boiling point of 200°C or greater.
19. Use according to claim 17, wherein the non-volatile, silicone conditioning agent is in an emulsion.
20. Use according to claim 17, wherein the non-volatile, silicone conditioning agent is selected from the group consisting of dimethicone, dimethiconol, phenyl trimethicone, dimethicone copolyols, amino functional silicones, organically modified silicone resins such as stearyl siloxysilicate and lauric siloxysilicate, silicone gums, silicone elastomers, and crosslinked siloxane polymers which may be either linear or branched.
21. Use according to claim 17, wherein the heating appliance or device is a blow-dryer, curling iron, hot comb, hot curlers, hot rollers, hot brush, crimper, or hair dryer.
22. Use according to claim 17, wherein the hair being conditioned is in a hairpiece, extension, or wig.
23. Use according to claim 17 wherein the reduction in the bending modulus caused by the silicone conditioning agent is at least 2.00%.
24. Use according to claim 17, wherein the amount of silicone deposited on the hair is at least 60 microgram silicone/1g of hair.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US08/943,610 US5968286A (en) | 1997-10-03 | 1997-10-03 | Heat-mediated conditioning from shampoo and conditioner hair care compositions containing silicone |
US08/943610 | 1997-10-03 | ||
PCT/EP1998/006243 WO1999017713A2 (en) | 1997-10-03 | 1998-09-30 | Shampoo and conditioner hair care rinse-off compositions containing silicone |
Publications (2)
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CA2304724A1 CA2304724A1 (en) | 1999-04-15 |
CA2304724C true CA2304724C (en) | 2003-02-04 |
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CA002304724A Expired - Fee Related CA2304724C (en) | 1997-10-03 | 1998-09-30 | Shampoo and conditioner hair care rinse-off compositions containing silicone |
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EP (1) | EP1019014A2 (en) |
JP (1) | JP2001518486A (en) |
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AU (1) | AU9747998A (en) |
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WO (1) | WO1999017713A2 (en) |
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US5968286A (en) * | 1997-10-03 | 1999-10-19 | Helene Curtis, Inc. | Heat-mediated conditioning from shampoo and conditioner hair care compositions containing silicone |
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US6432394B2 (en) * | 1999-04-19 | 2002-08-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc | Hair conditioning compositions comprising one or more dibasic amino acids |
US6808701B2 (en) | 2000-03-21 | 2004-10-26 | Johnson & Johnson Consumer Companies, Inc. | Conditioning compositions |
US6429261B1 (en) | 2000-05-04 | 2002-08-06 | Kimberly-Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
US6444214B1 (en) | 2000-05-04 | 2002-09-03 | Kimberly-Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
US6548592B1 (en) | 2000-05-04 | 2003-04-15 | Kimberly-Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
US6537663B1 (en) | 2000-05-04 | 2003-03-25 | Kimberly-Clark Worldwide, Inc. | Ion-sensitive hard water dispersible polymers and applications therefor |
US6653406B1 (en) | 2000-05-04 | 2003-11-25 | Kimberly Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
US6599848B1 (en) | 2000-05-04 | 2003-07-29 | Kimberly-Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
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US6683143B1 (en) | 2000-05-04 | 2004-01-27 | Kimberly Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
US6586529B2 (en) | 2001-02-01 | 2003-07-01 | Kimberly-Clark Worldwide, Inc. | Water-dispersible polymers, a method of making same and items using same |
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1997
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-
1998
- 1998-09-30 EP EP98951485A patent/EP1019014A2/en not_active Withdrawn
- 1998-09-30 AU AU97479/98A patent/AU9747998A/en not_active Abandoned
- 1998-09-30 WO PCT/EP1998/006243 patent/WO1999017713A2/en not_active Application Discontinuation
- 1998-09-30 JP JP2000514606A patent/JP2001518486A/en active Pending
- 1998-09-30 CA CA002304724A patent/CA2304724C/en not_active Expired - Fee Related
- 1998-10-05 AR ARP980104951A patent/AR018510A1/en not_active Application Discontinuation
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1999
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WO1999017713A2 (en) | 1999-04-15 |
US6211125B1 (en) | 2001-04-03 |
WO1999017713A3 (en) | 1999-06-17 |
AR018510A1 (en) | 2001-11-28 |
US5968286A (en) | 1999-10-19 |
AU9747998A (en) | 1999-04-27 |
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