CA2306999A1 - Two-phase hydrogen permeation membrane - Google Patents

Two-phase hydrogen permeation membrane Download PDF

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Publication number
CA2306999A1
CA2306999A1 CA002306999A CA2306999A CA2306999A1 CA 2306999 A1 CA2306999 A1 CA 2306999A1 CA 002306999 A CA002306999 A CA 002306999A CA 2306999 A CA2306999 A CA 2306999A CA 2306999 A1 CA2306999 A1 CA 2306999A1
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CA
Canada
Prior art keywords
hydrogen permeation
permeation membrane
phase hydrogen
phase
palladium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002306999A
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French (fr)
Other versions
CA2306999C (en
Inventor
Eric D. Wachsman
Naixiong Jiang
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Canada Minister of Natural Resources
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Canada Minister of Natural Resources
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Publication of CA2306999A1 publication Critical patent/CA2306999A1/en
Application granted granted Critical
Publication of CA2306999C publication Critical patent/CA2306999C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02231—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/0271—Perovskites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C01B3/505—Membranes containing palladium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
    • C01F17/32—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 oxide or hydroxide being the only anion, e.g. NaCeO2 or MgxCayEuO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/26—Electrical properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/34—Three-dimensional structures perovskite-type (ABO3)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Abstract

A two-phase proton and electron conductor is described which comprises (a) a proton conductive oxides represented by the formula: ABO3 where A is selected from the group consisting of Ba, Ca, Mg and Sr and B is Ce1-x M x or Zr1-x M x, where x has a value greater than zero and less than one and M is an element selected from the group consisting of Y, Yb, In, Gd, Nd, Eu, Sm and Tb, in combination with (b) an electron conductor comprising palladium. The palladium may be coated on particles of the oxide in the form of an oxide powder. This novel two-phase conductor is particularly useful as a mixed hydrogen ion and electronic conducting membrane for separating hydrogen from a hydrogen-containing gas.
CA002306999A 1999-04-30 2000-04-27 Two-phase hydrogen permeation membrane Expired - Lifetime CA2306999C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/302,786 1999-04-30
US09/302,786 US6235417B1 (en) 1999-04-30 1999-04-30 Two-phase hydrogen permeation membrane

Publications (2)

Publication Number Publication Date
CA2306999A1 true CA2306999A1 (en) 2000-10-30
CA2306999C CA2306999C (en) 2008-03-11

Family

ID=23169204

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002306999A Expired - Lifetime CA2306999C (en) 1999-04-30 2000-04-27 Two-phase hydrogen permeation membrane

Country Status (6)

Country Link
US (1) US6235417B1 (en)
EP (1) EP1048614B1 (en)
AT (1) ATE253016T1 (en)
CA (1) CA2306999C (en)
DE (1) DE60006181T2 (en)
DK (1) DK1048614T3 (en)

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US6517693B2 (en) * 2000-02-14 2003-02-11 Matsushita Electric Industrial Co., Ltd. Ion conductor
DE10013895A1 (en) * 2000-03-21 2001-10-04 Dmc2 Degussa Metals Catalysts Cerdec Ag Water gas shift reaction, useful in mobile unit in vehicle for removing carbon monoxide from gas mixture containing hydrogen for fuel cell, uses catalyst based on noble metal coating on inert carrier
US6468499B1 (en) * 2000-06-09 2002-10-22 Argonne National Laboratory Method of generating hydrogen by catalytic decomposition of water
US20020179887A1 (en) * 2001-05-01 2002-12-05 Yongxian Zeng Supported perovskite-type oxides and methods for preparation thereof
MXPA03011640A (en) * 2001-06-15 2005-10-05 David Systems & Technology S L Catalytic membrane reactor that is used for the decomposition of hydrogen sulphide into hydrogen and sulphur and the separation of the products of said decomposition.
US6569226B1 (en) * 2001-09-28 2003-05-27 The United States Of America As Represented By The United States Department Of Energy Metal/ceramic composites with high hydrogen permeability
AU2003220048A1 (en) * 2002-03-05 2003-09-22 Eltron Research, Inc. Hydrogen transport membranes
US7001446B2 (en) * 2002-03-05 2006-02-21 Eltron Research, Inc. Dense, layered membranes for hydrogen separation
US20050241477A1 (en) * 2002-03-05 2005-11-03 Mundschau Michael V Hydrogen transport membranes
AU2003224931A1 (en) * 2002-04-18 2003-11-03 Trustees Of Boston University Hydrogen separation using oxygen ion-electron mixed conducting membranes
US7045231B2 (en) * 2002-05-22 2006-05-16 Protonetics International, Inc. Direct hydrocarbon reforming in protonic ceramic fuel cells by electrolyte steam permeation
US6726893B2 (en) * 2002-09-17 2004-04-27 The University Of Chicago Hydrogen production by high-temperature water splitting using electron-conducting membranes
US7087211B2 (en) * 2002-09-17 2006-08-08 The University Of Chicago Hydrogen production by high temperature water splitting using electron conducting membranes
US7332237B2 (en) * 2003-01-27 2008-02-19 Protonetics International, Inc. Stream reforming of solid carbon in protonic ceramic fuel cells
WO2004102588A1 (en) * 2003-05-16 2004-11-25 Kabushikikaisha Equos Research Mixed conductor
WO2005015658A2 (en) * 2003-08-07 2005-02-17 Cbh2 Technologies, Inc. Hypergolic hydrogen generation system for fuel cell power plants
US20050039400A1 (en) * 2003-08-22 2005-02-24 Francis Lau Hydrogen production process from carbonaceous materials using membrane gasifier
US7258820B2 (en) * 2004-03-05 2007-08-21 Ceramatec, Inc. Ceramic mixed protonic/electronic conducting membranes for hydrogen separation
US8012380B2 (en) * 2004-03-05 2011-09-06 Ceramatec, Inc. Proton conducting ceramic membranes for hydrogen separation
JP4193750B2 (en) * 2004-04-26 2008-12-10 トヨタ自動車株式会社 Hydrogen separation membrane, fuel cell, and method for producing the hydrogen separation membrane and fuel cell
US20050252853A1 (en) * 2004-05-13 2005-11-17 Berland Brian S Novel proton conducting materials and devices incorporating them
US7255949B2 (en) 2004-05-25 2007-08-14 Protonetics International, Inc. Systems and methods to generate hydrogen and electrical power in a reversible compound fuel cell
US7419648B2 (en) * 2004-07-16 2008-09-02 Shell Oil Company Process for the production of hydrogen and carbon dioxide
KR20070083978A (en) * 2004-10-05 2007-08-24 씨티피 히드로젠 코포레이션 Conducting ceramics for electrochemical systems
EP1814646A2 (en) * 2004-11-23 2007-08-08 Trustees Of Boston University Composite mixed oxide ionic and electronic conductors for hydrogen separation
KR100691645B1 (en) 2005-07-07 2007-03-09 요업기술원 Hydrogen filtering membrane and method for preparing the same
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US7744675B2 (en) * 2006-11-08 2010-06-29 Shell Oil Company Gas separation membrane comprising a substrate with a layer of coated inorganic oxide particles and an overlayer of a gas-selective material, and its manufacture and use
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Also Published As

Publication number Publication date
CA2306999C (en) 2008-03-11
ATE253016T1 (en) 2003-11-15
DE60006181T2 (en) 2004-08-12
EP1048614A1 (en) 2000-11-02
DE60006181D1 (en) 2003-12-04
US6235417B1 (en) 2001-05-22
EP1048614B1 (en) 2003-10-29
DK1048614T3 (en) 2004-02-16

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Effective date: 20200427