CA2316325A1 - Fast-fluidized bed reactor for mto process - Google Patents

Fast-fluidized bed reactor for mto process Download PDF

Info

Publication number
CA2316325A1
CA2316325A1 CA002316325A CA2316325A CA2316325A1 CA 2316325 A1 CA2316325 A1 CA 2316325A1 CA 002316325 A CA002316325 A CA 002316325A CA 2316325 A CA2316325 A CA 2316325A CA 2316325 A1 CA2316325 A1 CA 2316325A1
Authority
CA
Canada
Prior art keywords
zone
fast
disengaging
fluidized bed
bed reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002316325A
Other languages
French (fr)
Other versions
CA2316325C (en
Inventor
Lawrence W. Miller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Publication of CA2316325A1 publication Critical patent/CA2316325A1/en
Application granted granted Critical
Publication of CA2316325C publication Critical patent/CA2316325C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/48Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/45Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/57Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds according to the fluidised bed technique
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80Additives
    • C10G2300/802Diluents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production

Abstract

An oxygenate conversion process and fast-fluidized bed reactor are disclosed having an upper disengaging zone and a lower reaction zone. The process is carried out in a reaction zone having a dense phase zone in the lower reaction zone and a transition zone which extends into the disengaging zone. A portion of the catalyst is withdrawn from above the transition zone in the disengaging zone, at least partially regenerated, and returned to a point above the dense phase zone, while catalyst is continuously circulated from the disengaging zone to the lower reaction zone. The process provides a method for carrying out the overall conversion reaction with a significantly reduced catalyst inventory compared to conventional bubbling bed reactors.
CA002316325A 1999-08-20 2000-08-18 Fast-fluidized bed reactor for mto process Expired - Lifetime CA2316325C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/378,416 1999-08-20
US09/378,416 US6166282A (en) 1999-08-20 1999-08-20 Fast-fluidized bed reactor for MTO process

Publications (2)

Publication Number Publication Date
CA2316325A1 true CA2316325A1 (en) 2001-02-20
CA2316325C CA2316325C (en) 2009-07-14

Family

ID=23493057

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002316325A Expired - Lifetime CA2316325C (en) 1999-08-20 2000-08-18 Fast-fluidized bed reactor for mto process

Country Status (9)

Country Link
US (1) US6166282A (en)
AR (1) AR025327A1 (en)
AU (1) AU770811B2 (en)
CA (1) CA2316325C (en)
EA (1) EA002261B1 (en)
EG (1) EG22398A (en)
GC (1) GC0000138A (en)
NL (1) NL1015957C2 (en)
NO (1) NO20004156L (en)

Families Citing this family (196)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6552240B1 (en) 1997-07-03 2003-04-22 Exxonmobil Chemical Patents Inc. Method for converting oxygenates to olefins
US6455747B1 (en) 1998-05-21 2002-09-24 Exxonmobil Chemical Patents Inc. Method for converting oxygenates to olefins
RO114524B1 (en) 1997-10-02 1999-05-28 Sc Zecasin Sa Process for producing olefins with low molecular mass by fluidized bed catalytic conversion of methanol
US6482999B2 (en) 1999-02-17 2002-11-19 Exxonmobil Chemical Patents, Inc. Method for improving light olefin selectivity in an oxygenate conversion reaction
US6444868B1 (en) 1999-02-17 2002-09-03 Exxon Mobil Chemical Patents Inc. Process to control conversion of C4+ and heavier stream to lighter products in oxygenate conversion reactions
US20040104149A1 (en) * 1999-08-20 2004-06-03 Lomas David A. Controllable volume reactor and process
US6869521B2 (en) * 2002-04-18 2005-03-22 Uop Llc Process and apparatus for upgrading FCC product with additional reactor with thorough mixing
US7169293B2 (en) * 1999-08-20 2007-01-30 Uop Llc Controllable space velocity reactor and process
US6743747B1 (en) 2000-02-24 2004-06-01 Exxonmobil Chemical Patents Inc. Catalyst pretreatment in an oxgenate to olefins reaction system
US7102050B1 (en) 2000-05-04 2006-09-05 Exxonmobil Chemical Patents Inc. Multiple riser reactor
US6613950B1 (en) * 2000-06-06 2003-09-02 Exxonmobil Chemical Patents Inc. Stripping hydrocarbon in an oxygenate conversion process
US6441261B1 (en) 2000-07-28 2002-08-27 Exxonmobil Chemical Patents Inc. High pressure oxygenate conversion process via diluent co-feed
US6486219B1 (en) 2000-09-27 2002-11-26 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US6441262B1 (en) 2001-02-16 2002-08-27 Exxonmobil Chemical Patents, Inc. Method for converting an oxygenate feed to an olefin product
US6518475B2 (en) 2001-02-16 2003-02-11 Exxonmobil Chemical Patents Inc. Process for making ethylene and propylene
US6673978B2 (en) * 2001-05-11 2004-01-06 Exxonmobil Chemical Patents Inc. Process for making olefins
EP1421044B1 (en) * 2001-07-02 2007-03-07 Exxonmobil Chemical Patents Inc. Inhibiting catalyst coke formation in the manufacture of an olefin
US6870072B2 (en) * 2001-10-30 2005-03-22 Exxonmobil Chemical Patents Inc. Heat recovery in an olefin production process
US6660682B2 (en) * 2001-11-30 2003-12-09 Exxon Mobil Chemical Patents Inc. Method of synthesizing molecular sieves
US7227048B2 (en) 2001-12-31 2007-06-05 Exxonmobil Chemical Patents Inc. Converting oxygenates to olefins over a catalyst comprising acidic molecular sieve of controlled carbon atom to acid site ratio
US6768036B2 (en) 2001-12-31 2004-07-27 Exxonmobil Chemical Patents Inc. Method for adding heat to a reactor system used to convert oxygenates to olefins
AU2002367007A1 (en) 2002-01-03 2003-07-30 Exxon Mobil Chemical Patents Inc. Stabilisation of acid catalysts
US7053260B2 (en) * 2002-01-07 2006-05-30 Exxonmobil Chemical Patents Inc. Reducing temperature differences within the regenerator of an oxygenate to olefin process
US7307196B2 (en) * 2002-02-28 2007-12-11 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US6906232B2 (en) * 2002-08-09 2005-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US6995111B2 (en) 2002-02-28 2006-02-07 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US7208442B2 (en) * 2002-02-28 2007-04-24 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US7319178B2 (en) * 2002-02-28 2008-01-15 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US6759360B2 (en) * 2002-03-29 2004-07-06 Exxonmobil Chemical Patent Inc. Interior surface modifications of molecular sieves with organometallic reagents and the use thereof for the conversion of oxygenates to olefins
US6866771B2 (en) * 2002-04-18 2005-03-15 Uop Llc Process and apparatus for upgrading FCC product with additional reactor with catalyst recycle
US7034196B2 (en) * 2002-06-19 2006-04-25 Exxonmobil Chemical Patents Inc. Method and apparatus for reducing decomposition byproducts in a methanol to olefin reactor system
EP1515795A2 (en) * 2002-06-21 2005-03-23 ExxonMobil Chemical Patents Inc. Controlling solids circulation in a gas-solids reaction system
US7396971B2 (en) * 2002-08-01 2008-07-08 Exxonmobil Chemical Patents Inc. Two stage hydrocarbon conversion reaction system
WO2004016574A1 (en) 2002-08-14 2004-02-26 Exxonmobil Chemical Patents Inc. Process for preparing olefins from oxygenates
US7238846B2 (en) * 2002-08-14 2007-07-03 Exxonmobil Chemical Patents Inc. Conversion process
US7030284B2 (en) * 2002-08-20 2006-04-18 Exxonmobil Chemical Patents Inc. Method and reactor system for converting oxygenate contaminants in an MTO reactor system product effluent to hydrocarbons
US7122160B2 (en) * 2002-09-24 2006-10-17 Exxonmobil Chemical Patents Inc. Reactor with multiple risers and consolidated transport
US20040064007A1 (en) * 2002-09-30 2004-04-01 Beech James H. Method and system for regenerating catalyst from a plurality of hydrocarbon conversion apparatuses
US7083762B2 (en) * 2002-10-18 2006-08-01 Exxonmobil Chemical Patents Inc. Multiple riser reactor with centralized catalyst return
US6737556B2 (en) * 2002-10-21 2004-05-18 Exxonmobil Chemical Patents Inc. Method and system for reducing decomposition byproducts in a methanol to olefin reactor system
US7273960B2 (en) * 2002-10-25 2007-09-25 Exxonmobil Chemical Patents Inc Fluid bed oxygenates to olefins reactor apparatus and process of controlling same
US7007701B2 (en) * 2002-10-28 2006-03-07 Exxonmobil Chemical Patents Inc. Processor for removing contaminants from a compressor in a methanol to olefin separation system
US6899046B2 (en) * 2002-11-26 2005-05-31 Exxonmobil Chemical Patents Inc. Shipping methanol for a methanol to olefin unit in non-methanol carriers
US7214843B2 (en) * 2002-11-26 2007-05-08 Exxon Mobil Chemical Patents Inc. Treating oxygenate containing feedstreams in the conversion of oxygenates to olefins
US6846966B2 (en) * 2002-11-26 2005-01-25 Exxonmobil Chemical Patents Inc. Method and apparatus for treating oxygenate-containing feeds and their use in conversion of oxygenates to olefins
US7074979B2 (en) * 2002-12-31 2006-07-11 Exxonmobil Chemical Patents Inc. Processing a contaminated oxygenate-containing feed stream in an oxygenate to olefin reaction system
US7115791B2 (en) * 2002-12-19 2006-10-03 Exxonmobil Chemical Patents Inc. Method and apparatus for controlling effluent composition in oxygenates to olefins conversion
US7026267B2 (en) * 2002-12-20 2006-04-11 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its production and use in conversion processes
JP4764820B2 (en) * 2003-06-23 2011-09-07 バクスター・インターナショナル・インコーポレイテッド Vaccine carrier protein
US6872867B1 (en) 2003-07-17 2005-03-29 Uop Llc Start-up of a methanol-to-olefin process
US6951830B2 (en) * 2003-08-05 2005-10-04 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, their production and use in conversion processes
US7241713B2 (en) * 2003-10-02 2007-07-10 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
US7084319B2 (en) * 2003-12-05 2006-08-01 Exxonmobil Chemical Patents Inc. Catalyst fluidization in oxygenate to olefin reaction systems
US7619127B2 (en) * 2003-12-23 2009-11-17 Exxonmobil Chemical Patents Inc. Method of operating a riser reactor
US7033971B2 (en) * 2004-02-09 2006-04-25 Exxonmobil Chemical Patents Inc. Method for using stabilizing catalyst activity during MTO unit operation
US7329790B2 (en) * 2004-04-15 2008-02-12 Uop Llc Wet scrubbing and recycle of effluent-contaminating catalyst particles in an oxygenate-to-olefin process
US7199278B2 (en) * 2004-07-30 2007-04-03 Exxonmobil Chemical Patents Inc. Conversion of oxygenates to olefins
US7186875B2 (en) * 2004-07-30 2007-03-06 Exxon Mobil Chemical Patents Inc. Conversion of oxygenates to olefins
US7166757B2 (en) * 2004-07-30 2007-01-23 Exxonmobil Chemical Patents Inc. Conversion of oxygenates to olefins
RU2399648C2 (en) * 2004-08-10 2010-09-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method for obtaining middle-distillate product and low molecular weight olefins from hydrocarbon raw material and device for its implementation
US7582203B2 (en) 2004-08-10 2009-09-01 Shell Oil Company Hydrocarbon cracking process for converting gas oil preferentially to middle distillate and lower olefins
US20060040821A1 (en) * 2004-08-18 2006-02-23 Pujado Peter R Treatment of air to a catalyst regenerator to maintain catalyst activity
US7309383B2 (en) * 2004-09-23 2007-12-18 Exxonmobil Chemical Patents Inc. Process for removing solid particles from a gas-solids flow
US7622625B2 (en) * 2004-11-01 2009-11-24 Uop Llc Purge gas streams to stagnant zones within oxygenate-to-olefin reactor
US7622626B2 (en) * 2004-11-01 2009-11-24 Uop Llc Purge gas streams to stagnant zones within oxygenate-to-olefin reactor
US7208649B2 (en) * 2004-11-01 2007-04-24 Uop Llc External second stage cyclones in olefin production process
US7138558B2 (en) * 2004-11-01 2006-11-21 Uop Llc Direct return of oxygenate recycle stream in olefin production process
US20050203326A1 (en) * 2004-12-16 2005-09-15 Miller Lawrence W. Process for containment of catalyst particles in a oxygenate-to-olefin process
US7423191B2 (en) * 2004-12-16 2008-09-09 Uop Llc Method and system for catalytically converting oxygenates and regenerating and stripping catalyst
US7465845B2 (en) * 2004-12-22 2008-12-16 Exxonmobil Chemical Patents Inc. Increasing ethylene and/or propylene production in an oxygenate to olefins reaction systems
US20060149108A1 (en) * 2004-12-30 2006-07-06 Miller Lawrence W Oxygenate conversion reactor catalyst coolers
US7829030B2 (en) * 2004-12-30 2010-11-09 Exxonmobil Chemical Patents Inc. Fluidizing a population of catalyst particles having a low catalyst fines content
US7829750B2 (en) * 2004-12-30 2010-11-09 Exxonmobil Chemical Patents Inc. Fluidizing a population of catalyst particles having a low catalyst fines content
WO2006083423A1 (en) 2005-01-31 2006-08-10 Exxonmobil Chemical Patents, Inc. Molecular sieve catalyst composition, its making and use in conversion processes
EA200702526A1 (en) * 2005-05-27 2008-06-30 Эксонмобил Кемикэл Пейтентс Инк. TRANSFORMATION OF OXYGENATE TO OLEFINS IN A FITTED REACTOR REACTOR
US7578987B2 (en) * 2005-06-20 2009-08-25 Uop Llc Synthesis of SAPO-34 with essentially pure CHA framework
WO2007021394A2 (en) * 2005-08-18 2007-02-22 Exxonmobil Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
FR2894849B1 (en) * 2005-12-20 2008-05-16 Inst Francais Du Petrole NEW REACTOR WITH TWO REACTIONAL ZONES FLUIDIZED WITH INTEGRATED GAS / SOLID SEPARATION SYSTEM
FR2894842B1 (en) * 2005-12-21 2008-02-01 Inst Francais Du Petrole NEW SOLID GAS SEPARATION AND STRIPING SYSTEM FOR FLUIDIZED BED CATALYTIC CRACKING UNITS
US7763766B2 (en) * 2005-12-22 2010-07-27 Uop Llc Methanol-to-olefins process with reduced coking
US7547427B2 (en) * 2005-12-22 2009-06-16 Uop Llc Multiple stage separator vessel
ES2298013A1 (en) * 2005-12-29 2008-05-01 Uop Llc Catalyst cooler for conversion reactor of oxygenated compounds to light olefins, includes catalyst, where load flow of oxygenated compounds comes into contact with catalyst and becomes light olefins and part of catalyst is regenerated
US7594953B2 (en) * 2006-01-31 2009-09-29 Exxonmobil Chemical Patents Inc. Separating solid particles from gas in a fluid bed reactor
EP2004776A1 (en) 2006-03-31 2008-12-24 ExxonMobil Chemical Patents Inc. Product recovery in gas-solids reactors
US7744746B2 (en) 2006-03-31 2010-06-29 Exxonmobil Research And Engineering Company FCC catalyst stripper configuration
US7335621B2 (en) * 2006-04-19 2008-02-26 Exxonmobil Chemical Patents Inc. Catalyst compositions and preparation thereof
US7595275B2 (en) * 2006-08-15 2009-09-29 Exxonmobil Chemical Patents Inc. Catalyst compositions and their synthesis
CN101165025B (en) * 2006-10-20 2010-12-08 中国石油化工股份有限公司 Method for producing ethylene and propylene from methanol or dimethyl ether
CN101165026B (en) * 2006-10-20 2011-01-19 中国石油化工股份有限公司上海石油化工研究院 Method for producing ethylene and propylene from methanol and dimethyl ether
CN101165019B (en) * 2006-10-20 2010-06-16 中国石油化工股份有限公司 Method for producing ethylene and propylene
CN101165018B (en) * 2006-10-20 2010-05-12 中国石油化工股份有限公司 Method for producing ethylene and propylene
FR2909897B1 (en) * 2006-12-13 2009-06-26 Inst Francais Du Petrole NEW SOLID GAS SEPARATION SYSTEM FOR REGENERATORS OF FLUIDIZED BED CATALYTIC CRACKING UNITS
US7935650B2 (en) 2006-12-18 2011-05-03 Uop Llc Neutralization of quench stream in a process for handling catalyst from an oxygenate-to-olefin reaction
CN101239868B (en) * 2007-02-07 2011-05-18 中国石油化工股份有限公司 Method for increasing yield of ethylene and propylene
CN101239871B (en) * 2007-02-07 2011-05-18 中国石油化工股份有限公司 Method for increasing selectivity of low-carbon olefins in methanol or dimethyl ether converting process
CN101279874B (en) * 2007-04-04 2011-04-27 中国石油化工股份有限公司 Method for preparing low-carbon olefin hydrocarbon with methanol or dimethyl ether
CA2684223A1 (en) * 2007-04-13 2008-10-23 Shell International Research Maatschappij B.V. Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
KR20100017363A (en) * 2007-04-30 2010-02-16 쉘 인터내셔날 리써취 마트샤피지 비.브이. Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock
CN101306969B (en) * 2007-05-16 2011-11-30 中国石油化工股份有限公司 Reaction device for preparing low-carbon olefin from oxygen-containing compounds
CN101348404B (en) * 2007-07-18 2011-11-30 中国石油化工股份有限公司 Method for improving ethylene and propene yield in methyl alcohol or dimethyl ether conversion process
RU2474606C2 (en) * 2007-10-10 2013-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Systems and methods for obtaining middle distillates and low molecular weight olefins from hydrocarbon raw material
US20090163756A1 (en) * 2007-12-19 2009-06-25 Uop Llc, A Corporation Of The State Of Delaware Reactor cooler
CN101514134B (en) * 2008-02-23 2012-08-22 中国石化集团洛阳石油化工工程公司 Method for adjusting feed temperature in reaction of transforming compound containing oxygen into olefin
CN101270019B (en) * 2008-04-11 2011-05-18 中国石油化工股份有限公司 Method for preparing low carbon olefin hydrocarbon with methanol or dimethyl ether
CN101328103B (en) * 2008-06-12 2012-06-27 中国石油化工股份有限公司 Method for converting methanol or dimethyl ether into low carbon alkene
CN101333140B (en) * 2008-07-08 2012-05-23 中国石油化工股份有限公司 Reaction device for preparing low carbon olefin from methanol or dimethyl ether
CN102924210B (en) * 2008-07-26 2015-06-03 中石化洛阳工程有限公司 Conversion method of C4 and heavier components
EP2163310A3 (en) 2008-09-10 2014-06-04 East China University of Science and Technology Method for purifying quench water and scrubbing water from MTO (methanol-to-olefin process) by mini-hydrocyclone and apparatus used for same
CN101402538B (en) * 2008-11-21 2013-01-09 中国石油化工股份有限公司 Method for improving yield of light olefins
CN101811072B (en) * 2009-02-19 2011-12-21 中国石油化工股份有限公司 Regeneration control method in methanol-to-olefins reaction process
CN101898927B (en) * 2009-05-27 2013-11-06 中国石油化工股份有限公司 Method for preparing light olefins from alcohols
CN101941876B (en) * 2009-07-06 2013-07-31 中国石油化工股份有限公司 Method for increasing production of light olefin
CN102020523B (en) * 2009-09-10 2013-06-05 中国石油化工股份有限公司 Operating method for olefin conversion device
CN102190538B (en) * 2010-03-03 2014-07-02 中国石油化工股份有限公司 Method for Catalytic pyrolysis of hydrocarbons with more than 4 carbon atoms in process of preparing olefins from methanol
CN102190550B (en) * 2010-03-03 2016-02-10 中国石油化工股份有限公司 The production method of low-carbon alkene
CN102190548B (en) * 2010-03-03 2014-07-02 中国石油化工股份有限公司 Method for enhancing yield of light olefins in MTO technology
CN102190545A (en) * 2010-03-03 2011-09-21 中国石油化工股份有限公司 Method for utilizing byproducts in the process of preparing olefins from methanol
US9126174B2 (en) * 2010-03-31 2015-09-08 Uop Llc Hydroprocessing method, or an apparatus relating thereto
BR112012017962B1 (en) 2010-03-31 2018-08-07 Dow Global Technologies Llc Process for converting methanol into olefins
US9233885B2 (en) 2010-06-03 2016-01-12 Uop Llc Two stage oxygenate conversion reactor with improved selectivity
CN102276400B (en) * 2010-06-11 2014-05-28 中国石油化工股份有限公司 Low carbon olefin reaction-regeneration device by using methanol
CN102276390A (en) * 2010-06-11 2011-12-14 中国石油化工股份有限公司 Method for adjusting product proportion in process of preparing olefin from methanol
CN102276401B (en) * 2010-06-11 2013-12-25 中国石油化工股份有限公司 Method for removing catalyst from product gas of alkene prepared from methanol
CN102276393A (en) * 2010-06-11 2011-12-14 中国石油化工股份有限公司 Method for getting regenerated catalyst back to reactor in regeneration system of reaction for preparing alkene from methanol
CN102276386B (en) 2010-06-11 2013-12-25 中国石油化工股份有限公司 Production method of light olefins
CN102276384B (en) * 2010-06-11 2013-12-04 中国石油化工股份有限公司 Method for keeping stable selectivity of lower olefins
CN102276399B (en) * 2010-06-11 2013-10-16 中国石油化工股份有限公司 Method for producing lower olefins from methanol and naphtha
CN102295504B (en) * 2010-06-24 2013-12-25 中国石油化工股份有限公司 Method for preparing low-carbon olefin by using methanol
CN102295505B (en) * 2010-06-24 2014-05-28 中国石油化工股份有限公司 Reaction device for preparing low-carbon olefin from methanol
CN101891576A (en) * 2010-07-12 2010-11-24 兆威兴业有限公司 Process and device for preparing low-carbon olefin by methanol and/or dimethyl ether
US8419835B2 (en) 2010-08-10 2013-04-16 Uop Llc Apparatuses and methods for gas-solid separations using cyclones
CN102372540A (en) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 Method for conversing methanol to light olefin
CN102093153B (en) 2010-11-05 2014-04-09 华东理工大学 Optimal combination method and device for purifying and separating MTO (Methanol To Olefins) reaction gas containing catalyst micropowder
CN102463080A (en) * 2010-11-17 2012-05-23 中国石油化工股份有限公司 Reaction device for producing low-carbon olefin by using methanol as raw materials
CN102464532B (en) 2010-11-17 2014-07-02 中国石油化工股份有限公司 Method for preparing low-carbon olefins
CN102464527B (en) * 2010-11-17 2013-12-25 中国石油化工股份有限公司 Method for producing low-carbon olefins from low-carbon alcohols
US9085501B2 (en) 2010-11-17 2015-07-21 China Petroleum & Chemical Corporation Processes for increasing the yield of ethylene and propylene
CN102463154B (en) * 2010-11-17 2014-01-22 中国石油化工股份有限公司 Method for discharging carbonized fluid catalyst
CN102649706B (en) * 2011-02-25 2015-04-08 中国石油化工股份有限公司 Method for preparing ethylene glycol through gas phase hydrogenation of oxalate
CN102649707A (en) * 2011-02-25 2012-08-29 中国石油化工股份有限公司 Method for preparing ethylene glycol by gas-phase hydrogenating oxalate
CN102814151B (en) 2011-06-08 2014-02-26 富德(北京)能源化工有限公司 Fluidized bed reactor and method for preparing alkene from oxygen-containing compound
CN102875305B (en) * 2011-07-12 2014-08-13 中国石油化工股份有限公司 Method for preparing low carbon olefins from methanol
CN102875280B (en) * 2011-07-12 2016-05-18 中国石油化工股份有限公司 Methanol conversion is the reaction unit of low-carbon alkene
CN102875292B (en) * 2011-07-12 2016-04-13 中国石油化工股份有限公司 By the reaction unit of preparing low carbon olefin hydrocarbon with methanol
CN102875281B (en) * 2011-07-12 2015-05-13 中国石油化工股份有限公司 Method for catalytically converting methanol to low-carbon olefins
CN102875296B (en) * 2011-07-12 2015-01-07 中国石油化工股份有限公司 Reaction unit for preparing low-carbon olefins
CN102875291B (en) * 2011-07-12 2014-11-26 中国石油化工股份有限公司 Method for producing low-carbon olefins from methanol
CN102875283B (en) * 2011-07-12 2015-11-18 中国石油化工股份有限公司 The method of low-carbon alkene is prepared by methyl alcohol and petroleum naphtha
CN102875289B (en) * 2011-07-12 2014-12-10 中国石油化工股份有限公司 Method for preparing low-carbon olefins
CN102344328B (en) * 2011-07-25 2014-03-12 浙江大学 Semi-continuous method for converting methyl alcohol into propylene by using moving bed technology
CN103073377B (en) * 2011-10-25 2015-11-25 中国石油化工股份有限公司 A kind of oxygenatedchemicals catalyzed conversion prepares the method for low-carbon alkene
CN103121890B (en) * 2011-11-18 2015-01-07 中国石油化工股份有限公司 Method for producing low carbon olefin with oxygen compound
CN103193574B (en) 2012-01-10 2015-01-07 中国石油化工股份有限公司 On-stream method of methanol to light olefin reaction-regeneration device
CN103772103A (en) * 2012-10-25 2014-05-07 中国石油化工股份有限公司 Method for increasing yields of ethylene and propylene in reaction process of preparing olefin by methanol
US9023285B2 (en) 2012-11-20 2015-05-05 Uop Llc Counter-current fluidized bed reactor for the dehydrogenation of olefins
US9150466B2 (en) 2012-11-20 2015-10-06 Uop Llc Counter-current fluidized bed reactor for the dehydrogenation of olefins
US20150099913A1 (en) 2013-10-04 2015-04-09 Exxonmobil Research And Engineering Company Methanol conversion process
US9399603B2 (en) * 2013-11-25 2016-07-26 Uop Llc Increased conversion of recycled oxygenates in MTO
WO2015081484A1 (en) 2013-12-03 2015-06-11 中国科学院大连化学物理研究所 Method for preparing a light olefin using an oxygen-containing compound, and device for use thereof
CN104672045B (en) * 2013-12-03 2016-06-08 中国科学院大连化学物理研究所 A kind of reaction unit for methanol and/or dimethyl ether low-carbon alkene
RU2632905C1 (en) * 2013-12-03 2017-10-11 Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайенсез Method of producing light olefins by oxygen-containing compound
CN104672044B (en) * 2013-12-03 2016-06-08 中国科学院大连化学物理研究所 A kind of method of preparing low-carbon olefin from oxygen-containing compounds
CN104672040B (en) * 2013-12-03 2017-06-16 中国科学院大连化学物理研究所 A kind of method of preparing low-carbon olefin from oxygen-containing compounds and its equipment for using
DK3078414T3 (en) 2013-12-03 2018-10-22 Dalian Inst Chem & Physics Cas REACTION DEVICE FOR THE PREPARATION OF LIGHT OLEFINES FROM METHANOL AND / OR DIMETHYLETHER
US9370783B2 (en) 2014-03-28 2016-06-21 Uop Llc Apparatuses and methods for gas-solid separations using cyclones
US8945283B1 (en) 2014-03-28 2015-02-03 Uop Llc Apparatuses and methods for gas-solid separations using cyclones
KR101616827B1 (en) 2014-05-15 2016-04-29 한국화학연구원 Process preparing light olefins and apparatus for preparing the same
TWI661867B (en) 2014-10-14 2019-06-11 大陸商中國石油化工科技開發有限公司 Fluidized bed reactor, reaction regeneration equipment, method for preparing olefin, and method for preparing aromatic hydrocarbon
CN105505456B (en) * 2014-10-20 2017-09-29 中国石油化工股份有限公司 A kind of catalytic cracking unit and a kind of method of catalytic cracking gasoline hydrocarbon
EP3040401A1 (en) 2014-12-30 2016-07-06 Shell Internationale Research Maatschappij B.V. An oxygenate to olefins conversion reactor system and process for use thereof
US9809519B1 (en) 2016-05-26 2017-11-07 Exxonmobil Chemical Patents Inc. Oxygenate synthesis and homologation
CN106045808B (en) * 2016-06-01 2019-07-26 石宝珍 Methanol hydrocarbon products reaction method and device
MY197197A (en) * 2016-10-19 2023-05-31 Dalian Inst Chem & Physics Cas Fast fluidized-bed reactor, device, and method using oxygen-containing compound for manufacturing propene or c4 hydrocarbon
AR109884A1 (en) 2016-11-02 2019-01-30 Dow Global Technologies Llc METHODS FOR DESIGNING EXPANDED FLUID CATALYTIC REACTORS
WO2018085084A1 (en) 2016-11-02 2018-05-11 Dow Global Technologies Llc Fluid catalytic reactors which include flow directors
CN106890602A (en) * 2017-03-25 2017-06-27 青岛京润石化设计研究院有限公司 A kind of gas-solid fluidized bed reactor gas-solid preseparator
CN106914191A (en) * 2017-03-25 2017-07-04 青岛京润石化设计研究院有限公司 The hydrocarbons fluidised-bed reaction method of methyl alcohol system
US10307721B2 (en) * 2017-04-01 2019-06-04 China University Of Petroleum (East China) Reaction-regeneration device and process for alkane dehydrogenation to alkene
RU2652195C1 (en) * 2017-07-04 2018-04-25 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Distributor catalyst and transport gas for the reactor - reclaimer system of the c3-c5 paraffin hydrocarbon dehydrogenation plants with the fluidized bed
RU2652198C1 (en) * 2017-07-04 2018-04-25 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Distributor of the catalyst for the reactor-reclaimer system of c3-c5 paraffin hydrocarbon dehydration of with fluidized bed
AR112516A1 (en) 2017-07-31 2019-11-06 Dow Global Technologies Llc METHODS AND APPARATUS FOR PROCESSING GAS CURRENTS
CN109420468B (en) * 2017-08-31 2023-10-31 中国石油化工股份有限公司 Reaction apparatus and use thereof
US10589264B2 (en) 2018-08-10 2020-03-17 Uop Llc Processes for controlling the partial regeneration of spent catalyst from an MTO reaction
US10647623B2 (en) 2018-08-10 2020-05-12 Uop Llc Processes for reduced oxygenated recycle in an MTO conversion
US10646792B2 (en) 2018-08-10 2020-05-12 Uop Llc Processes for separating an MTO effluent
SE542646C2 (en) 2018-08-16 2020-06-23 Rise Res Institutes Of Sweden Ab Concept for the production of food with reduced environmental impact
CA3112833A1 (en) 2018-09-25 2020-04-02 Exxonmobil Research And Engineering Company Co-processing hydrothermal liquefaction oil and co-feed to produce biofuels
CN110950729B (en) * 2018-09-27 2022-06-07 中石化洛阳工程有限公司 Method and equipment for improving selectivity of low-carbon olefin
CN110950730B (en) * 2018-09-27 2022-06-07 中石化洛阳工程有限公司 Method and equipment for improving selectivity of low-carbon olefin
CN111056891B (en) * 2018-10-17 2022-07-08 中国石油化工股份有限公司 Reaction system and reaction method for oxide recycling in methanol conversion process
CN111250006B (en) * 2018-11-30 2021-11-23 中国科学院大连化学物理研究所 Coal-based ethanol-to-ethylene fast fluidized bed reactor and coal-based ethanol-to-ethylene method
CN112774735A (en) 2019-11-09 2021-05-11 洛阳维达石化工程有限公司 Method and equipment for pre-hydrocarbon pooling of catalyst
CN111018646A (en) 2019-11-09 2020-04-17 洛阳维达石化工程有限公司 Method and device for improving selectivity of low-carbon olefin prepared by converting oxygen-containing compound
CN114405416B (en) * 2021-12-30 2022-10-04 无锡碳谷科技有限公司 Cracking catalytic circulation method for three reaction chambers

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928483A (en) * 1974-09-23 1975-12-23 Mobil Oil Corp Production of gasoline hydrocarbons
US4025575A (en) * 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
US4252479A (en) * 1979-08-15 1981-02-24 Dynamic Air Inc. Rotary diverter valves
US4328384A (en) * 1979-10-30 1982-05-04 Mobil Oil Corporation Fluid zeolite catalyst conversion of alcohols and oxygenated derivatives to hydrocarbons by controlling exothermic reaction heat
FR2519335B1 (en) * 1982-01-04 1986-05-02 Azote & Prod Chim PRODUCTION OF HYDROCARBONS FROM METHANOL IN THE PRESENCE OF ZEOLITE TYPE CATALYSTS
US4499314A (en) * 1982-03-31 1985-02-12 Imperial Chemical Industries Plc Methanol conversion to hydrocarbons with zeolites and cocatalysts
NZ203629A (en) * 1982-04-08 1985-07-12 Mobil Oil Corp Process and apparatus for conversion of oxygenated compounds to hydrocarbons
ZA834412B (en) * 1982-07-20 1985-02-27 Mobil Oil Corp Two-stage,zeolite catalyzed process for the conversion of alcohols to hydrocarbons
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US4499327A (en) * 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
US4677242A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins
US4496786A (en) * 1983-09-30 1985-01-29 Chevron Research Company Selective conversion of methanol to low molecular weight olefins over high silica SSZ-13 zeolite
JPS6147421A (en) * 1984-08-15 1986-03-07 Satoyuki Inui Production of olefinic hydrocarbon from methanol
US4547616A (en) * 1984-12-28 1985-10-15 Mobil Oil Corporation Conversion of oxygenates to lower olefins in a turbulent fluidized catalyst bed
US4849091A (en) * 1986-09-17 1989-07-18 Uop Partial CO combustion with staged regeneration of catalyst
US4861938A (en) * 1987-07-07 1989-08-29 Uop Chemical conversion process
US4873390A (en) * 1987-07-07 1989-10-10 Uop Chemical conversion process
US4973792A (en) * 1987-07-07 1990-11-27 Uop Chemical conversion process
US4929780A (en) * 1988-05-12 1990-05-29 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons and ethene
US5177279A (en) * 1990-10-23 1993-01-05 Mobil Oil Corporation Integrated process for converting methanol to gasoline and distillates
US5095163A (en) * 1991-02-28 1992-03-10 Uop Methanol conversion process using SAPO catalysts
US5191141A (en) * 1991-11-13 1993-03-02 Uop Process for converting methanol to olefins using an improved metal aluminophosphate catalyst
US5126308A (en) * 1991-11-13 1992-06-30 Uop Metal aluminophosphate catalyst for converting methanol to light olefins
US6023005A (en) * 1997-07-03 2000-02-08 Exxon Chemicals Patents Inc. Process for converting oxygenates to olefins using molecular sieve catalysts comprising desirable carbonaceous deposits
RO114524B1 (en) * 1997-10-02 1999-05-28 Sc Zecasin Sa Process for producing olefins with low molecular mass by fluidized bed catalytic conversion of methanol

Also Published As

Publication number Publication date
AU5349100A (en) 2001-02-22
NO20004156L (en) 2001-02-21
GC0000138A (en) 2005-06-29
AU770811B2 (en) 2004-03-04
NL1015957A1 (en) 2001-02-23
CA2316325C (en) 2009-07-14
NL1015957C2 (en) 2002-12-30
EA200000780A2 (en) 2001-02-26
EA002261B1 (en) 2002-02-28
EG22398A (en) 2003-01-29
NO20004156D0 (en) 2000-08-18
AR025327A1 (en) 2002-11-20
EA200000780A3 (en) 2001-06-25
US6166282A (en) 2000-12-26

Similar Documents

Publication Publication Date Title
CA2316325A1 (en) Fast-fluidized bed reactor for mto process
KR101763864B1 (en) Reaction device for preparing light olefins from methanol and/or dimethyl ether
WO1999057108A3 (en) Method for the continuous production of 1,3-dioxolan-2-ones
MY139227A (en) Partial dehydrogenation method using continuous heterogeneous catalysis
JPH1066859A (en) Operation method of bubble three-phase column accompanied by adaptation to fischer-tropsch synthesis and apparatus therefor
MY121141A (en) Method for the catalytic gas-phase oxidation of propene into acrolein
AU2591088A (en) Production of olefins
WO2006012150A3 (en) Conversion of oxygenate to propylene using moving bed technology
CA2254694A1 (en) Method for in-situ modernization of a hetero-geneous exothermic synthesis reactor
ES8703812A1 (en) Process for reducing energy consumption of reactors for heterogeneous catalytic synthesis and relative reactors.
CA2136625A1 (en) Use of Acid Extracted Molecular Sieve Catalysts in Oxygenate Conversion
WO1991012224A3 (en) Circulating bed cofeed conversion reactor and method for converting light hydrocarbons to olefins, gasoline and methanol
CA2068115A1 (en) Improved gas conversion process
CA2334569A1 (en) Production of mibk using catalytic distillation technology
CA2315719A1 (en) Process for production of hydrogen peroxide
CA2281377A1 (en) Improved process for the production of vinyl acetate
TW370524B (en) Process for the acetoxylation of olefins
DE68908339D1 (en) CATALYTIC REFORMING PROCESS IN A MULTIPLE NUMBER OF COMBINED REACTION ZONES WITH A MOVABLE BED.
MY117733A (en) Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
CA2093441A1 (en) Method for preparing cobalt-containing hydrocarbon synthesis catalyst
MXPA02012665A (en) Oxirane production using a peroxidized compound.
WO2009131663A3 (en) Reactor systems and processes for using the same
MY123679A (en) Process for carrying out catalytic multiphase reactions, in particular vinylations of carboxylic acids.
MXPA98008036A (en) Processes for the manufacture of methylmercaptopropanal.
EP0494316A4 (en) Process for producing polyolefin

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20200818