CA2335748A1 - Corrosion prevention of metals using bis-functional polysulfur silanes - Google Patents

Corrosion prevention of metals using bis-functional polysulfur silanes Download PDF

Info

Publication number
CA2335748A1
CA2335748A1 CA002335748A CA2335748A CA2335748A1 CA 2335748 A1 CA2335748 A1 CA 2335748A1 CA 002335748 A CA002335748 A CA 002335748A CA 2335748 A CA2335748 A CA 2335748A CA 2335748 A1 CA2335748 A1 CA 2335748A1
Authority
CA
Canada
Prior art keywords
bis
metals
corrosion prevention
metal surface
functional polysulfur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002335748A
Other languages
French (fr)
Other versions
CA2335748C (en
Inventor
Wim J. Van Ooij
Vijay Subramanian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Cincinnati
Original Assignee
University Of Cincinnati
Wim J. Van Ooij
Vijay Subramanian
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University Of Cincinnati, Wim J. Van Ooij, Vijay Subramanian filed Critical University Of Cincinnati
Publication of CA2335748A1 publication Critical patent/CA2335748A1/en
Application granted granted Critical
Publication of CA2335748C publication Critical patent/CA2335748C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/53—Treatment of zinc or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/52—Treatment of copper or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/56—Treatment of aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/16—Sulfur-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20—Use of solutions containing silanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

Abstract

A method of preventing corrosion of metals using bis-functional polysulfur silanes. The method includes providing a metal surface, and applying a treatment solution onto the metal surface. The treatment solution includes at least one hydrolyzed bis-functional polysulfur silane of formula (I); wherein each R is an alkyl or an acetyl group, and Z is either -S x or -Q-S x-Q-, wherein each Q is an aliphatic or aromatic group, and x is an integer of from 2 to 9. A
treatment solution and metal surface having improved corrosion resistance are also provided.
CA 2335748 1998-06-24 1999-06-24 Corrosion prevention of metals using bis-functional polysulfur silanes Expired - Lifetime CA2335748C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/104,260 US6162547A (en) 1998-06-24 1998-06-24 Corrosion prevention of metals using bis-functional polysulfur silanes
US09/104,260 1998-06-24
PCT/EP1999/004371 WO1999067444A1 (en) 1998-06-24 1999-06-24 Corrosion prevention of metals using bis-functional polysulfur silanes

Publications (2)

Publication Number Publication Date
CA2335748A1 true CA2335748A1 (en) 1999-12-29
CA2335748C CA2335748C (en) 2008-01-08

Family

ID=22299491

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2335748 Expired - Lifetime CA2335748C (en) 1998-06-24 1999-06-24 Corrosion prevention of metals using bis-functional polysulfur silanes

Country Status (17)

Country Link
US (1) US6162547A (en)
EP (1) EP1097259B1 (en)
JP (1) JP4122135B2 (en)
KR (1) KR20010071546A (en)
CN (1) CN1204294C (en)
AT (1) ATE291108T1 (en)
AU (1) AU4776799A (en)
BR (1) BR9911491A (en)
CA (1) CA2335748C (en)
DE (1) DE69924256T2 (en)
ES (1) ES2237118T3 (en)
IL (1) IL140191A0 (en)
MX (1) MXPA00012445A (en)
PL (1) PL345182A1 (en)
TR (1) TR200003826T2 (en)
TW (1) TW452506B (en)
WO (1) WO1999067444A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010025567A1 (en) * 2008-09-05 2010-03-11 National Research Council Of Canada Corrosion inhibitor for mg and mg-alloys

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6416869B1 (en) * 1999-07-19 2002-07-09 University Of Cincinnati Silane coatings for bonding rubber to metals
DE19983867T1 (en) * 1998-12-30 2002-02-28 Univ Cincinnati Cincinnati Silane coatings for binding rubber to metals
DE10084461T1 (en) * 1999-04-14 2002-03-21 Univ Cincinnati Cincinnati Silane treatments for corrosion resistance and adhesion
AU4556200A (en) * 1999-04-14 2000-11-02 University Of Cincinnati, The Silane coatings for adhesion promotion
US6827981B2 (en) 1999-07-19 2004-12-07 The University Of Cincinnati Silane coatings for metal
JP2001240977A (en) * 2000-02-29 2001-09-04 Nippon Paint Co Ltd Metallic surface treatment method
DE60235927D1 (en) * 2001-06-28 2010-05-20 Alonim Holding Agricultural Co Surface treatment to improve the corrosion resistance of magnesium
JP2008510061A (en) * 2004-08-16 2008-04-03 ハネウェル・インターナショナル・インコーポレーテッド Method for preventing the formation of freezing and facilitating the removal of winter preparations on the windshield, and compositions for use in this method
TW200626358A (en) 2004-11-30 2006-08-01 Nippon Steel Chemical Co Copper-clad laminate
ES2626229T3 (en) 2005-03-24 2017-07-24 Bridgestone Corporation Silica-reinforced rubber compound with low emission of volatile organic compounds (VOCs)
US10041176B2 (en) 2005-04-07 2018-08-07 Momentive Performance Materials Inc. No-rinse pretreatment methods and compositions
DE102005045034A1 (en) * 2005-09-21 2007-03-29 Rasselstein Gmbh Method for passivating the surface of coated metal strips and device for applying the passive layer to a metal-coated steel strip
DE102006054761A1 (en) * 2006-11-14 2008-05-15 Hansgrohe Ag Provision of water-bearing components from brass alloys with reduced metal ion release
FR2914631B1 (en) 2007-04-06 2009-07-03 Eads Europ Aeronautic Defence PARTICULAR NANOSTRUCTURE MATERIAL, AS PROTECTIVE COATING OF METAL SURFACES.
US7915368B2 (en) 2007-05-23 2011-03-29 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes
US8501895B2 (en) 2007-05-23 2013-08-06 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes
US8962746B2 (en) 2007-12-27 2015-02-24 Bridgestone Corporation Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds
US8513371B2 (en) 2007-12-31 2013-08-20 Bridgestone Corporation Amino alkoxy-modified silsesquioxanes and method of preparation
US8794282B2 (en) 2007-12-31 2014-08-05 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
US8642691B2 (en) 2009-12-28 2014-02-04 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
US20120267011A1 (en) * 2011-04-25 2012-10-25 Lawrence Benjamin L Sulfur treatment for copper zinc alloys
US9829122B2 (en) 2011-11-07 2017-11-28 Nibco Inc. Leach-resistant leaded copper alloys
JP2013221210A (en) 2012-04-19 2013-10-28 Hitachi Ltd Corrosion-proof aluminum material and method for producing the same
US8970034B2 (en) * 2012-05-09 2015-03-03 Micron Technology, Inc. Semiconductor assemblies and structures
DE102013202286B3 (en) * 2013-02-13 2014-01-30 Chemetall Gmbh Use of a silane, silanol or / and siloxane additive to prevent specks on zinc-containing metal surfaces and use of the coated metal substrates
CN104497871B (en) * 2014-12-22 2017-07-28 江苏兴达钢帘线股份有限公司 A kind of water base primary coat liquid for steel bead wire plating posttreatment
JP6772143B2 (en) 2014-12-31 2020-10-21 株式会社ブリヂストン Aminoalkoxy-modified silsesquioxane adhesive for bonding alloy steel to rubber

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR435781A (en) * 1911-10-28 1912-03-09 Jules Rene Prochasson Adjustable self-induction cable for fast telegraphy and telephony
US3392182A (en) * 1963-02-28 1968-07-09 Goldschmidt Ag Th Novel organosilicon compounds and process for their preparation
US3978103A (en) * 1971-08-17 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sulfur containing organosilicon compounds
US4015044A (en) * 1975-03-27 1977-03-29 Union Carbide Corporation Process of bonding polyurethane-sealants and caulks
US4000347A (en) * 1975-03-27 1976-12-28 Union Carbide Corporation Process of bonding polysulfide sealant and caulk compositions
JPS51139831A (en) * 1975-05-29 1976-12-02 Shin Etsu Chem Co Ltd Primer composition
DE2658368C2 (en) * 1976-12-23 1982-09-23 Degussa Ag, 6000 Frankfurt Organosilicon compounds containing sulfur and phosphorus, process for their preparation and their use
US4243718A (en) * 1978-11-24 1981-01-06 Toshiba Silicone Co. Ltd. Primer compositions for Si-H-olefin platinum catalyzed silicone compositions
US4315970A (en) * 1980-02-11 1982-02-16 Dow Corning Corporation Adhesion of metals to solid substrates
JPS5765758A (en) * 1980-10-09 1982-04-21 Toray Silicone Co Ltd Primer composition for bonding
JPS57159865A (en) * 1981-03-27 1982-10-02 Toray Silicone Co Ltd Primer composition for bonding
DE3119151A1 (en) * 1981-05-14 1982-12-02 Bayer Ag, 5090 Leverkusen METHOD FOR SPLITTER-SAFE COATING OF GLASS SURFACES
US4364509A (en) * 1981-06-25 1982-12-21 The Mead Corporation Article carrier with dispensing feature
US4457970A (en) * 1982-06-21 1984-07-03 Ppg Industries, Inc. Glass fiber reinforced thermoplastics
JPS6081256A (en) * 1983-10-12 1985-05-09 Shin Etsu Chem Co Ltd Coating composition
US4618688A (en) * 1985-04-12 1986-10-21 Scm Corporation Silane compositions
JPS61237636A (en) * 1985-04-15 1986-10-22 大同鋼板株式会社 Coated steel plate
JPS61278582A (en) * 1985-06-03 1986-12-09 Toray Silicone Co Ltd Primer composition for bonding
US4689085A (en) * 1986-06-30 1987-08-25 Dow Corning Corporation Coupling agent compositions
JPS6397266A (en) * 1986-10-09 1988-04-27 Kawasaki Steel Corp Precoat steel sheet having excellent workability and corrosion resistance at its worked part
US5108793A (en) * 1990-12-24 1992-04-28 Armco Steel Company, L.P. Steel sheet with enhanced corrosion resistance having a silane treated silicate coating
US5200275A (en) * 1990-12-24 1993-04-06 Armco Steel Company, L.P. Steel sheet with enhanced corrosion resistance having a silane treated silicate coating
US5221371A (en) * 1991-09-03 1993-06-22 Lockheed Corporation Non-toxic corrosion resistant conversion coating for aluminum and aluminum alloys and the process for making the same
US5217751A (en) * 1991-11-27 1993-06-08 Mcgean-Rohco, Inc. Stabilized spray displacement plating process
US5455080A (en) * 1992-08-26 1995-10-03 Armco Inc. Metal substrate with enhanced corrosion resistance and improved paint adhesion
US5292549A (en) * 1992-10-23 1994-03-08 Armco Inc. Metallic coated steel having a siloxane film providing temporary corrosion protection and method therefor
US5326594A (en) * 1992-12-02 1994-07-05 Armco Inc. Metal pretreated with an inorganic/organic composite coating with enhanced paint adhesion
US5322713A (en) * 1993-03-24 1994-06-21 Armco Inc. Metal sheet with enhanced corrosion resistance having a silane treated aluminate coating
US5393353A (en) * 1993-09-16 1995-02-28 Mcgean-Rohco, Inc. Chromium-free black zinc-nickel alloy surfaces
US5389405A (en) * 1993-11-16 1995-02-14 Betz Laboratories, Inc. Composition and process for treating metal surfaces
IL111497A (en) * 1993-12-08 2001-01-28 Rohco Inc Mcgean Silane compositions useful as adhesives
US5433976A (en) * 1994-03-07 1995-07-18 Armco, Inc. Metal pretreated with an aqueous solution containing a dissolved inorganic silicate or aluminate, an organofuctional silane and a non-functional silane for enhanced corrosion resistance
US5405985A (en) * 1994-07-08 1995-04-11 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5468893A (en) * 1994-07-08 1995-11-21 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5466848A (en) * 1994-09-28 1995-11-14 Osi Specialties, Inc. Process for the preparation of silane polysulfides
FR2732364A1 (en) * 1995-03-29 1996-10-04 Michelin & Cie PROCESS FOR TREATING A STAINLESS STEEL BODY SO AS TO PROMOTE ITS ADHESION TO A RUBBER COMPOSITION
US5700523A (en) * 1996-06-03 1997-12-23 Bulk Chemicals, Inc. Method for treating metal surfaces using a silicate solution and a silane solution
US5750197A (en) * 1997-01-09 1998-05-12 The University Of Cincinnati Method of preventing corrosion of metals using silanes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010025567A1 (en) * 2008-09-05 2010-03-11 National Research Council Of Canada Corrosion inhibitor for mg and mg-alloys

Also Published As

Publication number Publication date
ATE291108T1 (en) 2005-04-15
PL345182A1 (en) 2001-12-03
EP1097259B1 (en) 2005-03-16
TR200003826T2 (en) 2001-06-21
CN1306586A (en) 2001-08-01
CN1204294C (en) 2005-06-01
JP4122135B2 (en) 2008-07-23
KR20010071546A (en) 2001-07-28
MXPA00012445A (en) 2002-04-24
EP1097259A1 (en) 2001-05-09
DE69924256T2 (en) 2005-08-04
WO1999067444A1 (en) 1999-12-29
IL140191A0 (en) 2002-02-10
CA2335748C (en) 2008-01-08
DE69924256D1 (en) 2005-04-21
US6162547A (en) 2000-12-19
TW452506B (en) 2001-09-01
JP2002519505A (en) 2002-07-02
AU4776799A (en) 2000-01-10
ES2237118T3 (en) 2005-07-16
BR9911491A (en) 2001-03-20

Similar Documents

Publication Publication Date Title
CA2335748A1 (en) Corrosion prevention of metals using bis-functional polysulfur silanes
CA2304240A1 (en) Improved methods and compositions for preventing corrosion of metal substrates
TW357196B (en) Corrosion resistant treatment for metal surfaces
CA2273249A1 (en) Method of preventing corrosion of metals using silanes
AU7407000A (en) Mixed silane coatings
CA2270879A1 (en) Method of preventing corrosion of metal sheet using vinyl silanes
ZA964211B (en) Coating compositions having improved adhesion to substrate
EP0811669A4 (en) Antifouling agent and nonaqueous coating composition containing said agent
WO2000039177A3 (en) Silane treatment for electrocoated metals
AU7448596A (en) Non-chrome post-rinse composition for phosphated metal substrates
AU7915491A (en) Phenyl mercaptotetrazole/tolyltriazole corrosion inhibiting compositions
AU2413200A (en) Inorganic conversion coatings for ferrous substrates
EP0921561A3 (en) Composition for film formation and film
AU3083995A (en) Antifouling coating compositions
JPS57128752A (en) Metal surface treating agent composition
EP1055675A3 (en) Method for making alkylhalosilanes
CA2150165A1 (en) Boron Nitride-Silicate Sealant
AU2336499A (en) Method for stripping paint from non-ferrous substrates
AU2313099A (en) Process for improving the corrosion resistance of a metal surface
EP1101767A3 (en) Oligosiloxane and method of preparing same
EP0786460A3 (en) 2-Arylquinolines and process for producing the same
ZA931026B (en) Coating composition for inhibiting corrosion of metal substrates.
Dolphin An introduction to hot dip galvanizing
MX9602081A (en) Autophobic water repellent surface treatment.
ES8308350A1 (en) Novel complexes, coating and adhesive compositions, and methods.

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20190625