CA2338094A1 - Catalyst for olefin polymerization - Google Patents

Catalyst for olefin polymerization Download PDF

Info

Publication number
CA2338094A1
CA2338094A1 CA002338094A CA2338094A CA2338094A1 CA 2338094 A1 CA2338094 A1 CA 2338094A1 CA 002338094 A CA002338094 A CA 002338094A CA 2338094 A CA2338094 A CA 2338094A CA 2338094 A1 CA2338094 A1 CA 2338094A1
Authority
CA
Canada
Prior art keywords
olefin polymerization
metal oxide
sulfated
catalyst
supported catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002338094A
Other languages
French (fr)
Other versions
CA2338094C (en
Inventor
Xiaoliang Gao
P. Scott Chisholm
Matthew Gerald Kowalchuk
Robert D. Donaldson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals Corp
Original Assignee
Nova Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA002338094A priority Critical patent/CA2338094C/en
Application filed by Nova Chemicals Corp filed Critical Nova Chemicals Corp
Priority to BRPI0207175-4A priority patent/BR0207175B1/en
Priority to KR1020037010970A priority patent/KR100833385B1/en
Priority to DE60208003T priority patent/DE60208003T2/en
Priority to EP02711710A priority patent/EP1370592B1/en
Priority to CNB028054369A priority patent/CN1275988C/en
Priority to JP2002566237A priority patent/JP4237494B2/en
Priority to ES02711710T priority patent/ES2254656T3/en
Priority to AT02711710T priority patent/ATE312853T1/en
Priority to PCT/CA2002/000157 priority patent/WO2002066524A1/en
Priority to US10/074,662 priority patent/US6734266B2/en
Publication of CA2338094A1 publication Critical patent/CA2338094A1/en
Application granted granted Critical
Publication of CA2338094C publication Critical patent/CA2338094C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Abstract

A supported catalyst for olefin polymerization comprises a combination of a sulfated metal oxide support, an aluminoxane and an organometallic complex of a group 4 metal. The sulfated metal oxide may be quickly and conveniently prepared by, for example, contacting the precursor metal oxide with a sulfuric acid. The supported catalyst of this invention is highly active for olefin polymerization in comparison to conventional catalysts which are prepared with non-sulfated supports.
CA002338094A 2001-02-23 2001-02-23 Catalyst for olefin polymerization Expired - Lifetime CA2338094C (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CA002338094A CA2338094C (en) 2001-02-23 2001-02-23 Catalyst for olefin polymerization
AT02711710T ATE312853T1 (en) 2001-02-23 2002-02-11 CATALYST FOR OLEFIN POLYMERIZATION
DE60208003T DE60208003T2 (en) 2001-02-23 2002-02-11 CATALYST FOR OLEFIN POLYMERIZATION
EP02711710A EP1370592B1 (en) 2001-02-23 2002-02-11 Catalyst for olefin polymerization
CNB028054369A CN1275988C (en) 2001-02-23 2002-02-11 Catalyst for olefin polymerization
JP2002566237A JP4237494B2 (en) 2001-02-23 2002-02-11 Olefin polymerization catalyst
BRPI0207175-4A BR0207175B1 (en) 2001-02-23 2002-02-11 catalyst system for olefin polymerization, process for preparing said system and olefin polymerization process.
KR1020037010970A KR100833385B1 (en) 2001-02-23 2002-02-11 Catalyst for olefin polymerization
PCT/CA2002/000157 WO2002066524A1 (en) 2001-02-23 2002-02-11 Catalyst for olefin polymerization
ES02711710T ES2254656T3 (en) 2001-02-23 2002-02-11 CATALYST USED FOR OLEOPHINE POLYMERIZATIONS.
US10/074,662 US6734266B2 (en) 2001-02-23 2002-02-13 Catalyst for olefin polymerization

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA002338094A CA2338094C (en) 2001-02-23 2001-02-23 Catalyst for olefin polymerization

Publications (2)

Publication Number Publication Date
CA2338094A1 true CA2338094A1 (en) 2002-08-23
CA2338094C CA2338094C (en) 2009-09-15

Family

ID=4168428

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002338094A Expired - Lifetime CA2338094C (en) 2001-02-23 2001-02-23 Catalyst for olefin polymerization

Country Status (11)

Country Link
US (1) US6734266B2 (en)
EP (1) EP1370592B1 (en)
JP (1) JP4237494B2 (en)
KR (1) KR100833385B1 (en)
CN (1) CN1275988C (en)
AT (1) ATE312853T1 (en)
BR (1) BR0207175B1 (en)
CA (1) CA2338094C (en)
DE (1) DE60208003T2 (en)
ES (1) ES2254656T3 (en)
WO (1) WO2002066524A1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7273912B2 (en) 2002-12-17 2007-09-25 Innovene Europe Limited Supported olefin polymerization catalyst
GB0402959D0 (en) * 2004-02-11 2004-03-17 Bp Chem Int Ltd Supported polymerisation catalysts
US7112643B2 (en) * 2004-04-22 2006-09-26 Chevron Phillips Chemical Company Lp Polymers having low levels of long chain branching and methods of making the same
US7214642B2 (en) * 2004-04-22 2007-05-08 Chevron Phillips Chemical Company Lp Methods of preparing active chromium/alumina catalysts via treatment with sulfate
WO2005107943A1 (en) * 2004-04-22 2005-11-17 Chevron Phillips Chemical Company Lp Methods of preparing active chromium/alumina catalysts via treatment with sulfate and polymers produced using the chromium/alumina catalysts
KR101011497B1 (en) * 2007-01-29 2011-01-31 주식회사 엘지화학 Process for the preparation of very low density polyolefin copolymers
US7897539B2 (en) * 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
KR101271055B1 (en) * 2008-03-28 2013-06-04 에스케이종합화학 주식회사 Metallocene catalyst compositions and process for preparing polyolefines
JP2009270976A (en) * 2008-05-08 2009-11-19 Hitachi High-Technologies Corp Flaw reviewing method and flaw reviewing apparatus
US8524846B1 (en) 2009-07-02 2013-09-03 The University Of Toledo Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
CA2716772C (en) * 2009-10-20 2017-09-05 Nova Chemicals Corporation Improved reactor continuity
EP2513160B1 (en) * 2009-12-18 2014-03-12 Total Research & Technology Feluy Method for improving ethylene polymerization reaction
CA2704934C (en) 2010-05-21 2018-01-23 Nova Chemicals Corporation Supported phosphinimine catalysts for reduced reactor fouling
CA2736443C (en) 2011-04-06 2018-07-10 Nova Chemicals Corporation Improved reactor continuity
CA2736674C (en) * 2011-04-07 2018-05-01 Nova Chemicals Corporation Supported phosphinimine catalyst systems
CA2736685C (en) * 2011-04-07 2018-07-10 Nova Chemicals Corporation Supported phosphinimine-heteroligand catalyst systems
CA2739969C (en) * 2011-05-11 2018-08-21 Nova Chemicals Corporation Improving reactor operability in a gas phase polymerization process
US9441063B2 (en) 2014-10-09 2016-09-13 Chevron Phillips Chemical Company Lp Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports
JP2018504478A (en) 2014-12-15 2018-02-15 アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップＡｋｚｏ Ｎｏｂｅｌ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． Weatherproof waterborne wood coating

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3231550A (en) 1964-06-04 1966-01-25 Union Carbide Corp Olefin polymerization
DE3007725A1 (en) 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn METHOD FOR PRODUCING POLYETHYLENE, POLYPROPYLENE AND COPOLYMERS
US4364839A (en) 1980-12-31 1982-12-21 Phillips Petroleum Company Catalyst comprising chromium on silica/phosphate support
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4444966A (en) 1982-05-05 1984-04-24 Phillips Petroleum Company Polymerization using phosphated alumina or aluminum phosphate chromium catalyst
US4619980A (en) 1985-04-01 1986-10-28 Phillips Petroleum Company Polymerization catalyst, method of making and use therefor
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5434116A (en) 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
KR0132766B1 (en) * 1992-11-19 1998-04-13 Mitsui Petrochemical Ind Ethylene copolymer composition
CA2103380C (en) * 1992-11-19 2002-07-02 Mitsui Chemicals, Inc. Ethylene/.alpha.-olefin copolymer composition, graft modified ethylene/.alpha.-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process
JP3355572B2 (en) * 1994-08-23 2002-12-09 新日本石油株式会社 Olefin polymerization catalyst and method for producing polyolefin using the same
US5554775A (en) 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
SG64939A1 (en) * 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
JP3506563B2 (en) * 1995-07-17 2004-03-15 三井化学株式会社 Olefin polymerization catalyst, method for producing olefin polymer, and olefin polymer
US6300271B1 (en) * 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
US6235918B1 (en) * 1998-07-29 2001-05-22 Northwestern University Supported organometallic catalysts for hydrogenation and Olefin Polymerization

Also Published As

Publication number Publication date
WO2002066524A1 (en) 2002-08-29
DE60208003T2 (en) 2006-07-27
US6734266B2 (en) 2004-05-11
KR20040014462A (en) 2004-02-14
JP2004527601A (en) 2004-09-09
BR0207175A (en) 2004-03-30
ES2254656T3 (en) 2006-06-16
EP1370592A1 (en) 2003-12-17
CN1275988C (en) 2006-09-20
US20030087754A1 (en) 2003-05-08
JP4237494B2 (en) 2009-03-11
CA2338094C (en) 2009-09-15
BR0207175B1 (en) 2012-08-07
CN1492883A (en) 2004-04-28
ATE312853T1 (en) 2005-12-15
EP1370592B1 (en) 2005-12-14
DE60208003D1 (en) 2006-01-19
KR100833385B1 (en) 2008-05-28

Similar Documents

Publication Publication Date Title
CA2338094A1 (en) Catalyst for olefin polymerization
WO2003025027A3 (en) Supported phosphinimine polymerization catalyst
IT1254279B (en) PROCEDURE FOR THE GAS PHASE POLYMERIZATION OF OLEFINS
CA2294588A1 (en) Multistage polymerization process using a catalyst having different catalytically active sites
BR0010232A (en) Catalyst and process for the preparation of vinyl acetate
AU5637899A (en) Polymerisation catalyst
ES2196594T3 (en) CYCLOPENTAFENANTRENIL TITANIUM COMPLEXES AND POLYMERIZATION PROCEDURE.
CA2447644A1 (en) Preparation of olefin polymerisation catalyst component
CA2324923A1 (en) Catalyst for the production of .alpha.-olefin and .alpha.-olefin production method
CA2243009A1 (en) Epoxidation of olefins using a catalyst containing titanostannosilicalites
CA2177008A1 (en) Oligomerization
WO2002060963A8 (en) Dual-site olefin polymerisation catalyst composition
WO2004007572A8 (en) Supported polymerization catalyst
WO2005001954A3 (en) Catalyst for fuel cell oxygen electrodes
MXPA04001416A (en) Method for making late transition metal catalysts for olefin polymerization.
WO2002055195A3 (en) Asymmetric ruthenium hydrogenation catalysts and processes
WO2004007570A3 (en) Preparation of supported catalyst systems
WO2001092346A3 (en) Catalyst for the production of olefin polymers
WO2004047971A3 (en) Processes of producing fluorided catalysts from nitrogenous metallocenes
MY124057A (en) Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process
CA2497568A1 (en) Process for reducing fluoride impurities resulting from use of fluorophosphite catalysts
WO2005011862A8 (en) Catalyst for gas phase oxidations
ATE315053T1 (en) ACTIVE, HETEROGENEOUS, SUPPORTED BI- OR TRIDENDATE POLYMERIZATION CATALYSTS
DE69600988D1 (en) Supported catalyst for olefin polymerization
CA2254512A1 (en) Slurry polymerization process using an unsupported phosphinimine catalyst

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20210223