CA2341343A1 - Conditioning compositions - Google Patents
Conditioning compositions Download PDFInfo
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- CA2341343A1 CA2341343A1 CA002341343A CA2341343A CA2341343A1 CA 2341343 A1 CA2341343 A1 CA 2341343A1 CA 002341343 A CA002341343 A CA 002341343A CA 2341343 A CA2341343 A CA 2341343A CA 2341343 A1 CA2341343 A1 CA 2341343A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Abstract
A conditioning composition comprised of a mixture of anionic, amphoteric, and nonionic surfactants, branched quaternary polymers, and silicone which imparts cleansing, wet detangling, dry detangling and manageability to hair and which is relatively non-irritating and thus suitable for use by young children and adults having sensitive skin and eyes. The conditioning composition is able to provide such benefits in an aesthetically pleasing formulation without the need for suspending agents, opacifiers, or pearlizing agents.
Claims (31)
1. A conditioning composition comprising:
a surfactant portion comprising:
1. a nonionic surfactant;
a surfactant portion comprising:
1. a nonionic surfactant;
2. an amphoteric surfactant; and
3. an anionic surfactant; and a conditioner portion comprising:
1. a branched quaternary cationic polymer; and 2. a silicone.
2. The conditioning composition of claim 1 wherein the surfactant portion is present in an amount, based upon the total weight of the conditioning composition, of from about 5 percent to about 20 percent.
3. The conditioning composition of claim 1 wherein the conditioner portion is present in an amount, based upon the total weight of the detergent composition, from about 0.1 percent to about 6.0 percent.
1. a branched quaternary cationic polymer; and 2. a silicone.
2. The conditioning composition of claim 1 wherein the surfactant portion is present in an amount, based upon the total weight of the conditioning composition, of from about 5 percent to about 20 percent.
3. The conditioning composition of claim 1 wherein the conditioner portion is present in an amount, based upon the total weight of the detergent composition, from about 0.1 percent to about 6.0 percent.
4. The conditioning composition of claim 1 wherein the conditioner portion is present in an amount, based upon the total weight of the detergent composition, from about 0.5 percent to about 4.0 percent.
5. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning composition, from about 5 percent to about 20 percent of the surfactant portion and from about 1.0 percent to about 3:0 percent of the conditioning portion.
6. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning composition, from about 5 percent to about 15 percent of the surfactant portion and from about 1.0 percent to about 3.0 percent of the conditioning portion.
7. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning composition, from about 0.001 percent to .about 5.0 percent of the branched quaternary polymer.
8. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning composition, from about 0.01 percent to about 3.0 percent of the branched quaternary polymer.
9. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning composition, from about 0.01 percent to about 8.0 percent of the silicone.
10. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning composition, from about 0.1 percent to about 5.0 percent of the silicone.
11. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning portion, from about 6 percent to about 25 percent of the branched quaternary polymer.
12. The conditioning composition of claim 1 comprised of, based upon the total weight of the conditioning portion, from about 10 percent to about 22 percent of a branched quaternary polymer comprised of vinylpyrrolidonelvinylimidazolium copolymers.
13. The conditioning composition of claim 1 wherein the branched quaternary polymer is selected from the group consisting of polyquaternium 44, polyquaternium 16, and mixtures thereof.
14. The conditioning composition of claim 13 wherein the branched quaternary polymer contains, based upon the total weight of branched quaternary polymer, from about 70 percent to about 90 percent of polyquaternium 44 and from about 30 percent to about 10 percent polyquaternium 16.
15. The conditioning composition of claim 1 wherein the silicone is a non volatile silicone selected from the group consisting of trimethylsilylamodimethicone, dimethicone copolyol, and mixtures thereof.
16. The conditioning composition of claim 1 wherein the silicone is a volatile silicone selected from the group consisting of trimethylsilylamodimethicone, phenyl trimethicone, polydimethylsiloxane having a viscosity less than about 5 cSt, polydimethylcyclosiloxane, hexamethyldisiloxane, cyclomethicone fluids and mixtures thereof.
17. The conditioning composition of claim 1 wherein the silicone is a non-volatile silicone selected from the group consisting of cetyl dimethicone; cetyl triethylammonium dimethicone copolyol phthalate; dimethicone copolyol; dimethicone copolyol lactate; hydrolyzed soy proteinldimethicone copolyol acetate; silicone quaternium 13; stearalkonium dimethicone copolyol phthalate;
stearamidopropyl dimethicone; phenyl trimethicone; amodimethicones;
polyalkylarylsiloxanes; and derivatives there of and mixtures thereof.
stearamidopropyl dimethicone; phenyl trimethicone; amodimethicones;
polyalkylarylsiloxanes; and derivatives there of and mixtures thereof.
18. The conditioning composition of claim 1, wherein the silicoine is selected from, based upon the total weight of the silicone, from about 60 to about 40 percent dimethicone copolyol and from about 40 percent to about 60 percent trimethylsilylamodimethicone.
19. The conditioning composition of claim 1 wherein the silicone is a non-volatile silicone having a viscosity of from about 10 to about 5000 centistokes at 25°C.
20. The conditioning composition of claim 1 wherein branched quaternary polymer has a cationic charge density of about 1.0 meq/gram to about 6.5 meq/gram.
21. The detergent composition of claim 1 wherein the nonionic surfactant comprises:
a) a polyoxyethylene derivative of a polyol ester 1. derived from a fatty acid containing from about 8 to about 22 carbon atoms and a polyol selected from sorbitol, sorbitan, glucose, .alpha.-methyl glucoside, polyglucose having an average of about 1 to about 3 glucose residues, glycerine, pentaerythritol and mixtures thereof, 2. containing an average of from about 10 to about 120 oxyethylene units, and 3. having an average of from about 1 to about 3 fatty acid residues per molecule of the polyoxyethylene derivative of polyol ester, b) an alkyl glucoside having an alkyl group containing from about 6 to about
a) a polyoxyethylene derivative of a polyol ester 1. derived from a fatty acid containing from about 8 to about 22 carbon atoms and a polyol selected from sorbitol, sorbitan, glucose, .alpha.-methyl glucoside, polyglucose having an average of about 1 to about 3 glucose residues, glycerine, pentaerythritol and mixtures thereof, 2. containing an average of from about 10 to about 120 oxyethylene units, and 3. having an average of from about 1 to about 3 fatty acid residues per molecule of the polyoxyethylene derivative of polyol ester, b) an alkyl glucoside having an alkyl group containing from about 6 to about
22 carbon atoms and having from about 1 to about 6 glucose residues pier molecule of alkyl glucoside, or c) mixtures thereof, wherein the nonionic surfactant is present in an amount, based upon the total weight of the detergent composition, of from about 0.1 percent to about 10 percent.
22. The detergent composition of claim 1 wherein the amphoteric surfactant comprises:
a. an amphocarboxylate compound of the formula:
A-CONH(CH2)x N4R5R6R7 wherein A is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
x is an integer of from about 2 to about 6;
R5 is hydrogen or a car6oxyalkyl group containing from about 2 to about 3 carbon atoms;
R6 is a hydroxyalkyl group containing from about 2 to about 3 carbon atoms or is a group of the formula:
R8-O-(CH2)n CO2 wherein R8 is an alkylene group having from about 2 to about 3 carbon atoms and n is 1 or 2; and R7 is a carboxyalkyl group containing from about 2 to about 3 carbon atoms;
b. an alkyl betaine of the formula:
B-N+R9R10(CH2)p CO2 wherein B is an alkyl or alkenyl group having from about 8 to about 22 carbon atoms;
R9 and R10 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
and p is 1 or 2;
c. an amidoalkyl betaine of the formula:
D-CO-NH(CH2)q-N+R11R12(CH2)m CO2 wherein D is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
R11 and R12 are each independently an alkyl or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
q is an integer from about 2 to about 6; and m is 1 or 2;
d. an amidoalkyl sultaine of the formula:
wherein E is an alkyl group or alkenyl group having from about 7 to about 21 carbon atoms;
R14 and R15 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
r is an integer from about 2 to about 6; and R13 is an alkylene or hydroxyalkylene group having from about 2 to about 3 carbon atoms;
e. an amphophosphate compound of formula:
wherein G is an alkyl group or alkenyl group having about 7 to about 21 carbon atoms;
s is an integer from about 2 to about 6;
R16 is hydrogen or a carboxyalkyl group containing from about 2 to about 3 carbon atoms;
R17 is a hydroxyalkyl group containing from about 2 to about 3 carbon atoms or is a group of the formula:
R19-O-(CH2)t -CO2 wherein R19 is an alkylene group having from about 2 to about 3 carbon atoms and t is 1 or 2; and R18 is an alkylene or hydroxyalkylene group having from about 2 to about 3 carbon atoms;
f. a phosphobetaine compound of formula wherein E, r, R1, R2, R3, are as defined above;
g. a pyrophosphobetaine compound of formula wherein E, r, R1, R2, R3, are as defined above;
h. a carboxyalkyl alkylpolyamine of formula:
wherein I is an alkyl or alkenyl group containing from about 8 to about 22 carbon atoms;
R22 is a carboxyalkyl group having from about 2 to about 3 carbon atoms;
R21 is an alkylene group having from about 2 to about 3 carbon atoms and a is an integer from about 1 to about 4; or i.) mixtures thereof, wherein the amphoteric surfactant is present in an amount, based upon the total weight of the detergent composition, of from about 0.5 percent to about 10 percent.
22. The detergent composition of claim 1 wherein the amphoteric surfactant comprises:
a. an amphocarboxylate compound of the formula:
A-CONH(CH2)x N4R5R6R7 wherein A is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
x is an integer of from about 2 to about 6;
R5 is hydrogen or a car6oxyalkyl group containing from about 2 to about 3 carbon atoms;
R6 is a hydroxyalkyl group containing from about 2 to about 3 carbon atoms or is a group of the formula:
R8-O-(CH2)n CO2 wherein R8 is an alkylene group having from about 2 to about 3 carbon atoms and n is 1 or 2; and R7 is a carboxyalkyl group containing from about 2 to about 3 carbon atoms;
b. an alkyl betaine of the formula:
B-N+R9R10(CH2)p CO2 wherein B is an alkyl or alkenyl group having from about 8 to about 22 carbon atoms;
R9 and R10 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
and p is 1 or 2;
c. an amidoalkyl betaine of the formula:
D-CO-NH(CH2)q-N+R11R12(CH2)m CO2 wherein D is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
R11 and R12 are each independently an alkyl or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
q is an integer from about 2 to about 6; and m is 1 or 2;
d. an amidoalkyl sultaine of the formula:
wherein E is an alkyl group or alkenyl group having from about 7 to about 21 carbon atoms;
R14 and R15 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
r is an integer from about 2 to about 6; and R13 is an alkylene or hydroxyalkylene group having from about 2 to about 3 carbon atoms;
e. an amphophosphate compound of formula:
wherein G is an alkyl group or alkenyl group having about 7 to about 21 carbon atoms;
s is an integer from about 2 to about 6;
R16 is hydrogen or a carboxyalkyl group containing from about 2 to about 3 carbon atoms;
R17 is a hydroxyalkyl group containing from about 2 to about 3 carbon atoms or is a group of the formula:
R19-O-(CH2)t -CO2 wherein R19 is an alkylene group having from about 2 to about 3 carbon atoms and t is 1 or 2; and R18 is an alkylene or hydroxyalkylene group having from about 2 to about 3 carbon atoms;
f. a phosphobetaine compound of formula wherein E, r, R1, R2, R3, are as defined above;
g. a pyrophosphobetaine compound of formula wherein E, r, R1, R2, R3, are as defined above;
h. a carboxyalkyl alkylpolyamine of formula:
wherein I is an alkyl or alkenyl group containing from about 8 to about 22 carbon atoms;
R22 is a carboxyalkyl group having from about 2 to about 3 carbon atoms;
R21 is an alkylene group having from about 2 to about 3 carbon atoms and a is an integer from about 1 to about 4; or i.) mixtures thereof, wherein the amphoteric surfactant is present in an amount, based upon the total weight of the detergent composition, of from about 0.5 percent to about 10 percent.
23. The detergent composition of claim 12 wherein R5 is hydrogen.
24. The detergent composition of claim 12 wherein the amphoteric surfactant comprises, based upon the total weight of the detergent composition, from about 0.5 percent to about 9.5 percent of an alkyl betaine, amidoalkyl betaine, or mixtures thereof, the alkyl group having from about 8 to about 22 carbon atoms; and about 0.5 percent to about 9.5 percent of an amphocarboxylate.
25. The detergent composition of claim 1 wherein the anionic surfactant comprises:
an alkyl sulfate of the formula R1-CH2OSO3X1;
an alkyl ether sulfate of the formula R1(OCH2CH2)v OSO3X1;
an alkyl monoglyceryl ether sulfate of the formula an alkyl monoglyceride sulfate of the formula an alkyl monoglyceride sulfonate of the formula an alkyl sulfonate of the formula R1-SO3X;
an alkylaryl sulfonate of the formula an alkyl sulfosuccinate of the formula:
an alkyl ether sulfosuccinate of the formula:
an alkyl sulfosuccinamate of the formula:
an alkyl amidosulfosuccinate of the formula an alkyl carboxylate of the formula:
R'-(OCH2CH2)w -OCH2CO2X';
an alkyl amidoethercarboxylate of the formula:
an alkyl succinate of the formula:
a fatty acyl sarcosinate of the formula:
a fatty acyl amino acid of the formula:
a fatty acyl taurate of the formula:
a fatty alkyl sulfoacetate of the formula:
an alkyl phosphate of the formula:
or mixtures thereof wherein R' is an alkyl group having from about 7 to about 22 carbon atoms, R'1 is an alkyl group having from about 1 to about 18 carbon atoms, R'2 is a substituent of a natural or synthetic .alpha.-amino acid, X' is selected from the group consisting of alkali metal ions, alkaline earth metal ions, ammonium ions, and ammonium ions substituted with from about 1 to about 3 substituents, each of the substituents may be the same or different and are selected from alkyl groups having from 1 to 4 carbon atoms and hydroxyalkyl groups having from about 2 to about 4 carbon atoms and v is an integer from 1 to 6;
w is an integer from 0 to 20;
wherein the anionic surfactant is present in an amount, based upon the total weight of the shampoo composition of from about 1 percent to about 10 percent.
an alkyl sulfate of the formula R1-CH2OSO3X1;
an alkyl ether sulfate of the formula R1(OCH2CH2)v OSO3X1;
an alkyl monoglyceryl ether sulfate of the formula an alkyl monoglyceride sulfate of the formula an alkyl monoglyceride sulfonate of the formula an alkyl sulfonate of the formula R1-SO3X;
an alkylaryl sulfonate of the formula an alkyl sulfosuccinate of the formula:
an alkyl ether sulfosuccinate of the formula:
an alkyl sulfosuccinamate of the formula:
an alkyl amidosulfosuccinate of the formula an alkyl carboxylate of the formula:
R'-(OCH2CH2)w -OCH2CO2X';
an alkyl amidoethercarboxylate of the formula:
an alkyl succinate of the formula:
a fatty acyl sarcosinate of the formula:
a fatty acyl amino acid of the formula:
a fatty acyl taurate of the formula:
a fatty alkyl sulfoacetate of the formula:
an alkyl phosphate of the formula:
or mixtures thereof wherein R' is an alkyl group having from about 7 to about 22 carbon atoms, R'1 is an alkyl group having from about 1 to about 18 carbon atoms, R'2 is a substituent of a natural or synthetic .alpha.-amino acid, X' is selected from the group consisting of alkali metal ions, alkaline earth metal ions, ammonium ions, and ammonium ions substituted with from about 1 to about 3 substituents, each of the substituents may be the same or different and are selected from alkyl groups having from 1 to 4 carbon atoms and hydroxyalkyl groups having from about 2 to about 4 carbon atoms and v is an integer from 1 to 6;
w is an integer from 0 to 20;
wherein the anionic surfactant is present in an amount, based upon the total weight of the shampoo composition of from about 1 percent to about 10 percent.
26. A conditioning detergent composition comprising, based upon the total weight of the detergent composition:
a. from about 1 percent to about 10 percent of nonionic; surfactants comprising:
1) a polyoxyethylene derivative of a polyol ester a. derived from a fatty acid containing from about 8 to about 22 carbon atoms and a polyol selected from sorbitol, sorbitan, glucose, a-methyl glucoside, polyglucose having an average of about 1 to about 3 glucose residues, glycerine, pentaerythritol and mixtures thereof, b. containing an average of from about 10 to about 120 oxyethylene units, and c. having an average of from about 1 to about 3 fatty acid residues per molecule of the polyoxyethylene derivative of polyol ester, 2) an alkyl glucoside having an alkyl group containing from about 6 to about carbon atoms and having from about 1 to about 6 glucose residues per molecule of alkyl glucoside, or 3) mixtures thereof, and b. from about 0.5 percent to about 10 percent of one or more amphocarboxylate amphoteric surfactants of the formula:
A-CONH(CH2)x N4R5R6R7 wherein A is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
x is an integer of from about 2 to about 6;
R5 is hydrogen or a carboxyalkyl group containing from about 2 to about 3 carbon atoms;
R6 is a hydroxyalkyl group containing from about 2 to about 3 carbon atoms or a group of the formula:
R6-O-(CH2)n CO2 wherein R6 is an alkylene group having from about 2 to about 3 carbon atoms and n is 1 or 2; and R7 is a carboxyalkyl group containing from about 2 to about 3 carbon atoms, c. from about 0.5 percent to about 10 percent of one or more betaine amphoteric surfactants selected from:
1) an alkyl betaine of the formula:
B-N+R9R10(CH2)p CO2 wherein B is an alkyl or alkenyl group having from about 8 to about 22 carbon atoms;
R9 and R10 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms; and p is 1 or 2; or 2) an amidoalkyl betaine of the formula:
D-CO-NH(CH2)q N+R11R12(CH2)m CO2-wherein D is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
R11 and R12 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
q is an integer from about 2 to about 6; and m is 1 or 2;
d. from about 1 percent to about 10 percent of one or more anionic alkyl ether sulfate surfactants of the formula R'(OCH2CH2)y OSO3X', wherein R' is an alkyl or alkenyl group having from about 7 to about 22 carbon atoms, X' is selected from the group consisting of alkali metal ions, alkaline earth metal ions, ammonium ions, ammonium ions substituted with from 1 to 3 substituents, each of the substituents may be the same or different and are selected from alkyl groups having from about 1 to about 4 carbon atoms and hydroxyalkyl groups having from about 2 to about 4 carbon atoms, and v is an integer from 1 to 6;
e. from about 0.001 percent to about 5.0 percent of polyquaternium 44; and f. from about 0.01 percent to about 8.0 percent of silicone;
wherein the surfactants in a through d are present in an amount, based upon the total weight of the detergent composition, from about 5 percent to about 20 percent.
a. from about 1 percent to about 10 percent of nonionic; surfactants comprising:
1) a polyoxyethylene derivative of a polyol ester a. derived from a fatty acid containing from about 8 to about 22 carbon atoms and a polyol selected from sorbitol, sorbitan, glucose, a-methyl glucoside, polyglucose having an average of about 1 to about 3 glucose residues, glycerine, pentaerythritol and mixtures thereof, b. containing an average of from about 10 to about 120 oxyethylene units, and c. having an average of from about 1 to about 3 fatty acid residues per molecule of the polyoxyethylene derivative of polyol ester, 2) an alkyl glucoside having an alkyl group containing from about 6 to about carbon atoms and having from about 1 to about 6 glucose residues per molecule of alkyl glucoside, or 3) mixtures thereof, and b. from about 0.5 percent to about 10 percent of one or more amphocarboxylate amphoteric surfactants of the formula:
A-CONH(CH2)x N4R5R6R7 wherein A is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
x is an integer of from about 2 to about 6;
R5 is hydrogen or a carboxyalkyl group containing from about 2 to about 3 carbon atoms;
R6 is a hydroxyalkyl group containing from about 2 to about 3 carbon atoms or a group of the formula:
R6-O-(CH2)n CO2 wherein R6 is an alkylene group having from about 2 to about 3 carbon atoms and n is 1 or 2; and R7 is a carboxyalkyl group containing from about 2 to about 3 carbon atoms, c. from about 0.5 percent to about 10 percent of one or more betaine amphoteric surfactants selected from:
1) an alkyl betaine of the formula:
B-N+R9R10(CH2)p CO2 wherein B is an alkyl or alkenyl group having from about 8 to about 22 carbon atoms;
R9 and R10 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms; and p is 1 or 2; or 2) an amidoalkyl betaine of the formula:
D-CO-NH(CH2)q N+R11R12(CH2)m CO2-wherein D is an alkyl or alkenyl group having from about 7 to about 21 carbon atoms;
R11 and R12 are each independently an alkyl group or a hydroxyalkyl group having from about 1 to about 4 carbon atoms;
q is an integer from about 2 to about 6; and m is 1 or 2;
d. from about 1 percent to about 10 percent of one or more anionic alkyl ether sulfate surfactants of the formula R'(OCH2CH2)y OSO3X', wherein R' is an alkyl or alkenyl group having from about 7 to about 22 carbon atoms, X' is selected from the group consisting of alkali metal ions, alkaline earth metal ions, ammonium ions, ammonium ions substituted with from 1 to 3 substituents, each of the substituents may be the same or different and are selected from alkyl groups having from about 1 to about 4 carbon atoms and hydroxyalkyl groups having from about 2 to about 4 carbon atoms, and v is an integer from 1 to 6;
e. from about 0.001 percent to about 5.0 percent of polyquaternium 44; and f. from about 0.01 percent to about 8.0 percent of silicone;
wherein the surfactants in a through d are present in an amount, based upon the total weight of the detergent composition, from about 5 percent to about 20 percent.
27. The detergent composition of claim 26 further comprising from about 0.5 percent to about 5 percent, based upon the total weight of the detergent composition, of a humectant comprising glycerine.
28. A conditioning detergent composition comprising, based upon the total weight of the detergent composition:
a. from about 2 percent to about 10 percent of a polyoxyethylene derivative of polyol ester nonionic surfactant derived from 1) a polyol comprised of sorbitol, sorbitan, and mixtures thereof, and 2) lauric acid, containing an average of from about 20 to about 80 oxyethylene units per molecule of a polyoxyethylene derivative of polyol ester, and having an average of from about 1 to about 2 lauric acid residues per molecule of a polyoxyethylene derivative of polyol ester, and mixtures thereof;
b. from about 0.5 percent to about 5 percent of an amphocarboxylate amphoteric surfactant of the formula A-CONH(CH2)x N+R5R6R7 wherein A is an alkyl group having about 11 carbon atoms, x is 2, R1 is hydrogen, R5 is a group of the formula R8-O-(CH2)n CO2-wherein R8 is a 2 carbon alkylene group; and n is 1; and R7 is a carboxymethyl group, and mixtures thereof;
c. from about 0.5 percent to about 8 percent of a betaine surfactant selected from:
1) an alkyl betaine of the formula B-N+R9R10CH2CO2 wherein B is a lauryl group having 12 carbon atoms, and R1 and R2 are each methyl groups, 2) an amidoalkyl betaine of the formula D-CO-NH(CH2)q-N+R11R12CH2CO2 wherein DCO represents a fatty acid derived from coconut oil, q is 3 and R11 and R12 are each methyl groups, and 3) mixtures thereof;
d. from about 2 percent to about 8 percent of an alkyl ether sulfate anionic surfactant of the formula R'(OCH2CH2)Y OSO3X', wherein R' is an alkyl group having from about 12 to about 13 carbon atoms, X' is a sodium ion; and v is an integer from 1 to 4, and mixtures thereof;
e. from about 0.001 percent to about 5.0 percent of Polyquaternium-44;
f. from about 0.01 percent to about 8.0 percent of trimethylsilylamodimethicone, dimethicone copolyol, or mixtures thereof.;
wherein the surfactants a through d are present in an amount, based upon the total weight of the detergent composition, of from about 5 percent to about 20 percent.
a. from about 2 percent to about 10 percent of a polyoxyethylene derivative of polyol ester nonionic surfactant derived from 1) a polyol comprised of sorbitol, sorbitan, and mixtures thereof, and 2) lauric acid, containing an average of from about 20 to about 80 oxyethylene units per molecule of a polyoxyethylene derivative of polyol ester, and having an average of from about 1 to about 2 lauric acid residues per molecule of a polyoxyethylene derivative of polyol ester, and mixtures thereof;
b. from about 0.5 percent to about 5 percent of an amphocarboxylate amphoteric surfactant of the formula A-CONH(CH2)x N+R5R6R7 wherein A is an alkyl group having about 11 carbon atoms, x is 2, R1 is hydrogen, R5 is a group of the formula R8-O-(CH2)n CO2-wherein R8 is a 2 carbon alkylene group; and n is 1; and R7 is a carboxymethyl group, and mixtures thereof;
c. from about 0.5 percent to about 8 percent of a betaine surfactant selected from:
1) an alkyl betaine of the formula B-N+R9R10CH2CO2 wherein B is a lauryl group having 12 carbon atoms, and R1 and R2 are each methyl groups, 2) an amidoalkyl betaine of the formula D-CO-NH(CH2)q-N+R11R12CH2CO2 wherein DCO represents a fatty acid derived from coconut oil, q is 3 and R11 and R12 are each methyl groups, and 3) mixtures thereof;
d. from about 2 percent to about 8 percent of an alkyl ether sulfate anionic surfactant of the formula R'(OCH2CH2)Y OSO3X', wherein R' is an alkyl group having from about 12 to about 13 carbon atoms, X' is a sodium ion; and v is an integer from 1 to 4, and mixtures thereof;
e. from about 0.001 percent to about 5.0 percent of Polyquaternium-44;
f. from about 0.01 percent to about 8.0 percent of trimethylsilylamodimethicone, dimethicone copolyol, or mixtures thereof.;
wherein the surfactants a through d are present in an amount, based upon the total weight of the detergent composition, of from about 5 percent to about 20 percent.
29. The composition of claim 1 in the form of a shampoo, a conditioner, a body wash, a shower gel, or a bath.
30. A method for making an aesthetically pleasing conditioning detergent composition in the substantial absence of suspending agents, opacifiers, and pearlizers comprising:
a) adding an effective amount of a branched quaternary cationic polymer to at least one surfactant.
a) adding an effective amount of a branched quaternary cationic polymer to at least one surfactant.
31. A conditioning composition comprised of a) at least one surfactant selected from the group consisting of anionic surfactants, non-ionic surfactants, amphoteric surfactants, zwitterionic surfactants, cationic surfactants, betaine surfactants, and mixtures thereof, and b) a conditioning portion comprised of 1) a branched quaternary cationic polymer containing polyquaternium 44; and 2) a silicone.
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US09/804,810 | 2001-03-13 |
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-
2001
- 2001-03-13 US US09/804,810 patent/US6808701B2/en not_active Expired - Lifetime
- 2001-03-20 CA CA2341343A patent/CA2341343C/en not_active Expired - Lifetime
- 2001-03-20 MY MYPI20011323A patent/MY130643A/en unknown
- 2001-03-20 EP EP01302571A patent/EP1136066B1/en not_active Revoked
- 2001-03-21 CN CN011168595A patent/CN1325682B/en not_active Expired - Lifetime
- 2001-03-21 JP JP2001081408A patent/JP2001302464A/en active Pending
- 2001-12-20 HK HK01108938.7A patent/HK1037979A1/en not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4039334A4 (en) * | 2019-09-30 | 2023-11-29 | Kao Corporation | Cleaning agent |
EP4039336A4 (en) * | 2019-09-30 | 2023-11-29 | Kao Corporation | Detergent |
Also Published As
Publication number | Publication date |
---|---|
EP1136066A2 (en) | 2001-09-26 |
CA2341343C (en) | 2012-02-07 |
EP1136066A3 (en) | 2003-08-13 |
HK1037979A1 (en) | 2002-03-01 |
CN1325682B (en) | 2011-11-16 |
JP2001302464A (en) | 2001-10-31 |
EP1136066B1 (en) | 2011-08-10 |
MY130643A (en) | 2007-07-31 |
US6808701B2 (en) | 2004-10-26 |
CN1325682A (en) | 2001-12-12 |
US20010051142A1 (en) | 2001-12-13 |
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