CA2356909A1 - Hydroprocessing using bulk group viii/group vib catalysts - Google Patents

Hydroprocessing using bulk group viii/group vib catalysts Download PDF

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CA2356909A1
CA2356909A1 CA002356909A CA2356909A CA2356909A1 CA 2356909 A1 CA2356909 A1 CA 2356909A1 CA 002356909 A CA002356909 A CA 002356909A CA 2356909 A CA2356909 A CA 2356909A CA 2356909 A1 CA2356909 A1 CA 2356909A1
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group
group viii
group vib
hydroprocessing
noble metal
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CA2356909C (en
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Stuart Leon Soled
Sabato Miseo
Roman Krycak
Hilda B. Vroman
Teh Chung Ho
Kenneth Lloyd Riley
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ExxonMobil Technology and Engineering Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
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    • C08F8/00—Chemical modification by after-treatment
    • C08F8/50—Partial depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
    • C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/04—Oxides
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    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/08—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a hydrogenation of the aromatic hydrocarbons
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    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/14—White oil, eating oil

Abstract

A process fo hydroprocessing petroleum and chemical feedstocks by use of a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least one, preferably two Group VIB metal wherein the ratio of Group VIB metal to Group VIII metal is from about 10:1 to 1:10.

Claims (8)

1. A process for hydroprocessing a petroleum feedstock, which feedstock contains both nitrogen and sulfur, which process comprises contacting a feedstock with a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least one Group VIB metals and wherein the ratio of Group VIB metal to Group VIII non-noble metal is from about 10:1 to about 1:10.
2. The process of claim 1 wherein the Group VIII non-noble metal is selected from Ni and Co and the Group VIB metals are selected from Mo and W.
3. The process of claim 1 wherein two Group VIB metals are present as Mo and W and the ratio of Mo to W is about 9:1 to about 1:9.
4. The process of claim 1 wherein the bulk multimetallic is represented by the formula:

(X)h (Mo)c (W)d O z wherein X is a Group VIII non-noble metal, and the molar ratio of b: (c+d) is 0.5/1 to 3/1.
5. The process of claim 3 wherein the molar ratio of b:(c+d) is 0.75/1 to 1.5/1.
6. The process of claim 3 wherein the molar ratio of c:d is > 0.01/1.
7. The process of claim 1 wherein the bulk multimetallic catalyst is essentially an amorphous material having a unique X-ray diffraction pattern showing crystalline peaks at d = 2.53 Angstroms and d = 1.70 Angstroms.
8. The process of claim 1 wherein the feedstock is comprised of at least 50 wt.% of distillate product from an atmospheric distillation process.
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Families Citing this family (237)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989008819A1 (en) * 1988-03-15 1989-09-21 Divetronic Ag Process and device for compensating errors of measurement
US7229548B2 (en) * 1997-07-15 2007-06-12 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US6758963B1 (en) * 1997-07-15 2004-07-06 Exxonmobil Research And Engineering Company Hydroprocessing using bulk group VIII/group vib catalysts
US6582590B1 (en) * 1997-07-15 2003-06-24 Exxonmobil Research And Engineering Company Multistage hydroprocessing using bulk multimetallic catalyst
US7232515B1 (en) * 1997-07-15 2007-06-19 Exxonmobil Research And Engineering Company Hydrofining process using bulk group VIII/Group VIB catalysts
US6863803B1 (en) * 1997-07-15 2005-03-08 Exxonmobil Research And Engineering Company Production of low sulfur/low nitrogen hydrocrackates
US7513989B1 (en) * 1997-07-15 2009-04-07 Exxonmobil Research And Engineering Company Hydrocracking process using bulk group VIII/Group VIB catalysts
US6620313B1 (en) * 1997-07-15 2003-09-16 Exxonmobil Research And Engineering Company Hydroconversion process using bulk group VIII/Group VIB catalysts
US6755963B2 (en) * 1997-07-15 2004-06-29 Exxonmobil Chemical Patents Inc. Hydrogenation process for hydrocarbon resins
US6162350A (en) * 1997-07-15 2000-12-19 Exxon Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901)
US7288182B1 (en) * 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
US6712955B1 (en) * 1997-07-15 2004-03-30 Exxonmobil Research And Engineering Company Slurry hydroprocessing using bulk multimetallic catalysts
US6783663B1 (en) * 1997-07-15 2004-08-31 Exxonmobil Research And Engineering Company Hydrotreating using bulk multimetallic catalysts
US6534437B2 (en) 1999-01-15 2003-03-18 Akzo Nobel N.V. Process for preparing a mixed metal catalyst composition
US6281158B1 (en) * 1999-02-15 2001-08-28 Shell Oil Company Preparation of a co-containing hydrotreating catalyst precursor and catalyst
US6417422B1 (en) * 1999-02-22 2002-07-09 Symyx Technologies, Inc. Ni catalysts and methods for alkane dehydrogenation
US6841512B1 (en) * 1999-04-12 2005-01-11 Ovonic Battery Company, Inc. Finely divided metal catalyst and method for making same
US6372125B1 (en) * 1999-08-23 2002-04-16 Institut Francais Du Petrole Catalyst comprising a group VIB metal carbide, phosphorous and its use for hydrodesulphurisation and hydrogenation of gas oils
ES2362349T3 (en) * 2000-07-12 2011-07-01 Albemarle Netherlands B.V. MIXED METAL CATALYST THAT INCLUDES A COMBUSTIBLE BINDER.
DE60134140D1 (en) * 2000-07-12 2008-07-03 Albemarle Netherlands Bv METHOD FOR PRODUCING AN ADDITIVELY CONTAINING MIXED METAL CATALYST
US6632414B2 (en) * 2001-03-30 2003-10-14 Corning Incorporated Mini-structured catalyst beds for three-phase chemical processing
US6515034B2 (en) 2001-05-11 2003-02-04 Chevron U.S.A. Inc. Co-hydroprocessing of Fischer-Tropsch products and crude oil fractions
US6515033B2 (en) 2001-05-11 2003-02-04 Chevron U.S.A. Inc. Methods for optimizing fischer-tropsch synthesis hydrocarbons in the distillate fuel range
FR2838743A1 (en) * 2002-04-18 2003-10-24 Centre Nat Rech Scient Conversion of branched (co)polymers into other (co)polymers, e.g. waste polypropylene into usable polyethylene, by metal hydride or organometallic complex-catalyzed cleavage of branches
WO2004000731A2 (en) * 2002-06-25 2003-12-31 Akzo Nobel N.V. Use of cationic layered materials, compositions comprising these materials, and the preparation of cationic layered materials
FR2842202A1 (en) * 2002-07-11 2004-01-16 Bp Lavera Snc STYRENE TERPOLYMER AND METHOD FOR THE CONTROLLED TRANSFORMATION OF HYDROCARBON POLYMERS
US7173160B2 (en) 2002-07-18 2007-02-06 Chevron U.S.A. Inc. Processes for concentrating higher diamondoids
FR2843050B1 (en) * 2002-08-01 2005-04-15 Inst Francais Du Petrole METAL CATALYST OF GROUP VI AND GROUP VIII AT LEAST IN PART IN THE FORM OF HETEROPOLYANIONS IN THE OXIDE PRECURSOR
AR043242A1 (en) * 2003-02-24 2005-07-20 Shell Int Research PREPARATION AND USE OF A CATALYST COMPOSITION
TW200418570A (en) * 2003-02-24 2004-10-01 Shell Int Research Catalyst composition, its preparation and use
US7598202B2 (en) * 2003-06-24 2009-10-06 Albemarle Netherlands B.V. Use of cationic layered materials, compositions comprising these materials, and the preparation of cationic layered materials
US6951830B2 (en) * 2003-08-05 2005-10-04 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, their production and use in conversion processes
CA2540517A1 (en) * 2003-10-02 2006-03-28 Exxonmobil Research And Engineering Company Process for upgrading naphtha
WO2005047433A1 (en) * 2003-11-10 2005-05-26 Exxonmobil Research And Engineering Company A hydrotreating catalyst system suitable for use in hydrotreating hydrocarbonaceous feedstreams
US20050109679A1 (en) * 2003-11-10 2005-05-26 Schleicher Gary P. Process for making lube oil basestocks
US7816299B2 (en) * 2003-11-10 2010-10-19 Exxonmobil Research And Engineering Company Hydrotreating catalyst system suitable for use in hydrotreating hydrocarbonaceous feedstreams
US20050113250A1 (en) * 2003-11-10 2005-05-26 Schleicher Gary P. Hydrotreating catalyst system suitable for use in hydrotreating hydrocarbonaceous feedstreams
US20100098602A1 (en) 2003-12-19 2010-04-22 Opinder Kishan Bhan Systems, methods, and catalysts for producing a crude product
US7745369B2 (en) 2003-12-19 2010-06-29 Shell Oil Company Method and catalyst for producing a crude product with minimal hydrogen uptake
BRPI0405566A (en) * 2003-12-19 2005-09-20 Shell Int Research Methods of Producing a Transportable Fuel and Crude Oil Product, Heating Fuel, Lubricants or Chemicals, and Crude Oil Product
US20050133405A1 (en) 2003-12-19 2005-06-23 Wellington Scott L. Systems and methods of producing a crude product
US7648625B2 (en) 2003-12-19 2010-01-19 Shell Oil Company Systems, methods, and catalysts for producing a crude product
CN1894381A (en) * 2003-12-19 2007-01-10 国际壳牌研究有限公司 Systems, methods, and catalysts for producing a crude product
CA2455011C (en) 2004-01-09 2011-04-05 Suncor Energy Inc. Bituminous froth inline steam injection processing
CA2455149C (en) * 2004-01-22 2006-04-11 Suncor Energy Inc. In-line hydrotreatment process for low tan synthetic crude oil production from oil sand
US7691257B2 (en) * 2004-04-22 2010-04-06 Exxonmobil Research And Engineering Company Process to manufacture low sulfur diesel fuels
US7780845B2 (en) * 2004-04-22 2010-08-24 Exxonmobil Research And Engineering Company Process to manufacture low sulfur distillates
US7776205B2 (en) * 2004-04-22 2010-08-17 Exxonmobil Research And Engineering Company Process to upgrade hydrocarbonaceous feedstreams
WO2005123881A2 (en) * 2004-06-22 2005-12-29 Albemarle Netherlands B.V. Process for upgrading liquid hydrocarbon feeds
US7629289B2 (en) * 2004-06-23 2009-12-08 Uop Llc Selective naphtha desulfurization process and catalyst
CN101035881B (en) * 2004-09-08 2010-10-13 国际壳牌研究有限公司 Hydrocracking catalyst composition
US7678732B2 (en) 2004-09-10 2010-03-16 Chevron Usa Inc. Highly active slurry catalyst composition
US7737072B2 (en) * 2004-09-10 2010-06-15 Chevron Usa Inc. Hydroprocessing bulk catalyst and uses thereof
US7972499B2 (en) 2004-09-10 2011-07-05 Chevron U.S.A. Inc. Process for recycling an active slurry catalyst composition in heavy oil upgrading
EP1791639A1 (en) * 2004-09-22 2007-06-06 Exxonmobil Research And Engineering Company BULK Ni-Mo-W CATALYSTS MADE FROM PRECURSORS CONTAINING AN ORGANIC AGENT
CA2539666C (en) * 2005-03-24 2011-06-28 University Of Regina Catalysts for hydrogen production
BRPI0609411A2 (en) * 2005-04-11 2011-10-11 Shell Int Research method to produce a gross product
BRPI0610670B1 (en) * 2005-04-11 2016-01-19 Shell Int Research method for producing a crude product, catalyst for producing a crude product, and method for producing a catalyst
BRPI0609416A2 (en) 2005-04-11 2011-10-11 Shell Int Research method to produce a gross product
CA2605505C (en) * 2005-04-21 2015-06-16 China Petroleum & Chemical Corporation A hydrogenation catalyst and use thereof
MXPA05009283A (en) 2005-08-31 2007-02-27 Mexicano Inst Petrol Method of preparing a catalytic composition for the hydroprocessing of petroleum fractions.
CN101340973B (en) * 2005-10-26 2013-08-07 埃克森美孚研究工程公司 Hydroprocessing using hydrothermally-prepared bulk multimetallic catalysts
HUE046591T2 (en) * 2005-10-26 2020-03-30 Albemarle Netherlands Bv A bulk catalyst comprising nickel tungsten metal oxidic particles and a method of preparation thereof
DK1957197T3 (en) * 2005-10-26 2016-09-12 Albemarle Netherlands Bv Bulk-katalysatorsammensætning og fremgangsmåde til fremstilling deraf.
WO2007059621A1 (en) * 2005-11-23 2007-05-31 Pedro Pereira-Almao Ultradispersed catalyst compositions and methods of preparation
US7938954B2 (en) 2005-12-16 2011-05-10 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US8372266B2 (en) 2005-12-16 2013-02-12 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US7931796B2 (en) 2008-09-18 2011-04-26 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US8048292B2 (en) * 2005-12-16 2011-11-01 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US7943036B2 (en) * 2009-07-21 2011-05-17 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US8435400B2 (en) 2005-12-16 2013-05-07 Chevron U.S.A. Systems and methods for producing a crude product
US7431822B2 (en) 2005-12-16 2008-10-07 Chevron U.S.A. Inc. Process for upgrading heavy oil using a reactor with a novel reactor separation system
US7713407B2 (en) 2006-06-02 2010-05-11 Exxonmobil Research & Engineering Company Production of low sulfur fuels using improved hydrocracker post-treatment catalyst
CA2655718A1 (en) * 2006-07-06 2008-01-10 W.R. Grace & Co. -Conn. Aluminum sulfate bound catalysts
TWI311498B (en) * 2006-07-19 2009-07-01 Lg Chemical Ltd Catalyst for partial oxidation of methylbenzenes, method for preparing the same, and method for producing aromatic aldehydes using the same
US20080087578A1 (en) 2006-10-06 2008-04-17 Bhan Opinder K Methods for producing a crude product and compositions thereof
US7951746B2 (en) 2006-10-11 2011-05-31 Exxonmobil Research And Engineering Company Bulk group VIII/group VIB metal catalysts and method of preparing same
AR063262A1 (en) 2006-10-11 2009-01-14 Exxonmobil Res & Eng Co METHODS OF HYDROPROCESSING WITH METAL CATALYSTS OF GROUP VIII / VIB
US20080139380A1 (en) * 2006-12-06 2008-06-12 Chevron U.S.A. Inc. Concentration of active catalyst slurry
US7615509B2 (en) * 2006-12-19 2009-11-10 Exxonmobil Research And Engineering Company High activity supported distillate hydroprocessing catalysts
US8013195B2 (en) * 2007-06-15 2011-09-06 Uop Llc Enhancing conversion of lignocellulosic biomass
US8158842B2 (en) * 2007-06-15 2012-04-17 Uop Llc Production of chemicals from pyrolysis oil
US7960520B2 (en) 2007-06-15 2011-06-14 Uop Llc Conversion of lignocellulosic biomass to chemicals and fuels
US8206575B2 (en) * 2007-10-31 2012-06-26 Chevron U.S.A. Inc. Hydroconversion processes employing multi-metallic catalysts and method for making thereof
CA2703137C (en) * 2007-10-31 2016-05-24 Chevron U.S.A. Inc. Hydroprocessing bulk catalyst and uses thereof
US20090107880A1 (en) * 2007-10-31 2009-04-30 Chevron U.S.A. Inc. Method of upgrading heavy hydrocarbon streams to jet products
CN101909747B (en) 2007-11-09 2014-10-22 埃克森美孚研究工程公司 Preparation of bulk metallic group viii/group vib metal catalysts
JP2011503316A (en) * 2007-11-19 2011-01-27 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー How to start a catalytic process
CN101932381B (en) * 2007-12-04 2014-04-30 埃克森美孚研究工程公司 Hydrocarbon hydroprocessing using bulk catalyst composition
US7594991B2 (en) 2007-12-28 2009-09-29 Exxonmobil Research And Engineering Company All catalytic medicinal white oil production
FR2927267B1 (en) * 2008-02-07 2010-04-16 Inst Francais Du Petrole SELECTIVE HYDROGENATION CATALYST AND PROCESS FOR PREPARING THE SAME
CN101544904B (en) * 2008-03-28 2012-11-14 中国科学院大连化学物理研究所 Composite metal oxide catalyst, preparation and application thereof
US20090271306A1 (en) * 2008-04-29 2009-10-29 Iovation Inc. System and Method to Facilitate Secure Payment of Digital Transactions
US20090023965A1 (en) * 2008-05-01 2009-01-22 Intevep, S.A. Dispersed metal sulfide-based catalysts
US7897036B2 (en) 2008-09-18 2011-03-01 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US8236169B2 (en) 2009-07-21 2012-08-07 Chevron U.S.A. Inc Systems and methods for producing a crude product
US7897035B2 (en) 2008-09-18 2011-03-01 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US20110017637A1 (en) * 2009-07-21 2011-01-27 Bruce Reynolds Systems and Methods for Producing a Crude Product
US7931797B2 (en) * 2009-07-21 2011-04-26 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US7935243B2 (en) 2008-09-18 2011-05-03 Chevron U.S.A. Inc. Systems and methods for producing a crude product
FR2940313B1 (en) * 2008-12-18 2011-10-28 Inst Francais Du Petrole HYDROCRACKING PROCESS INCLUDING PERMUTABLE REACTORS WITH LOADS CONTAINING 200PPM WEIGHT-2% WEIGHT OF ASPHALTENES
FR2940143B1 (en) * 2008-12-18 2015-12-11 Inst Francais Du Petrole HYDRODEMETALLATION AND HYDRODESULFURIZATION CATALYSTS AND IMPLEMENTATION IN A SINGLE FORMULATION CHAINING PROCESS
WO2010126691A2 (en) * 2009-04-29 2010-11-04 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7964526B2 (en) * 2009-04-29 2011-06-21 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7964524B2 (en) * 2009-04-29 2011-06-21 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7931799B2 (en) * 2009-04-29 2011-04-26 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8080492B2 (en) * 2009-04-29 2011-12-20 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8383543B2 (en) * 2009-04-29 2013-02-26 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7964525B2 (en) * 2009-04-29 2011-06-21 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8058203B2 (en) * 2009-04-29 2011-11-15 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8686203B2 (en) * 2009-06-12 2014-04-01 Exxonmobil Research And Engineering Company Process for preparing diesel fuels using vegetable oils or fatty acid derivatives
US8734638B2 (en) 2009-06-19 2014-05-27 Exxonmobil Research And Engineering Company Ebullating bed methods for treatment of biocomponent feedstocks
JP2012533655A (en) 2009-07-17 2012-12-27 エクソンモービル リサーチ アンド エンジニアリング カンパニー Hydrogen treatment of bio-component raw materials with FCC off-gas
US9068132B2 (en) 2009-07-21 2015-06-30 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US8759242B2 (en) 2009-07-21 2014-06-24 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US8927448B2 (en) 2009-07-21 2015-01-06 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
CN102762694A (en) * 2009-08-28 2012-10-31 埃克森美孚研究工程公司 Reducing hydrogen consumption in hydrotreating of biocomponent feeds
JP2013503946A (en) * 2009-09-08 2013-02-04 エクソンモービル リサーチ アンド エンジニアリング カンパニー Fuel production from feedstock containing lipid materials
US20110072715A1 (en) * 2009-09-25 2011-03-31 Exxonmobil Research And Engineering Company Fuel production from feedstock containing triglyceride and/or fatty acid alkyl ester
IT1398288B1 (en) 2009-09-30 2013-02-22 Eni Spa TRANSITIONAL METAL-MIXED OXIDES, TREATMENT CATALYSTS OBTAINED BY THEM, AND PREPARATION PROCESS INCLUDING SOL-GEL PROCEDURES
SG10201406264PA (en) * 2009-10-05 2014-11-27 Exxonmobil Res & Eng Co Stacking of low activity or regenerated catalyst above higher activity catalyst
US8212099B2 (en) * 2009-11-05 2012-07-03 Chevron U.S.A. Inc. N-paraffin selective hydroconversion process using borosilicate ZSM-48 molecular sieves
EP2499111B1 (en) 2009-11-11 2018-07-04 Dow Global Technologies LLC Reductive hydroformylation of an alkylene to an alkanol
CA2781893C (en) 2009-12-08 2016-10-04 Exxonmobil Research And Engineering Company Hydroprocessing of high nitrogen feed using bulk catalyst
US8784647B2 (en) * 2009-12-18 2014-07-22 ExxonMobil Research and Egineering Company Hydroprocessing catalysts and their production
US8853474B2 (en) 2009-12-29 2014-10-07 Exxonmobil Research And Engineering Company Hydroprocessing of biocomponent feedstocks with low purity hydrogen-containing streams
EP2547642B1 (en) * 2010-03-15 2016-01-13 ExxonMobil Chemical Patents Inc. Processes for the production of alcohols
US20120016167A1 (en) 2010-07-15 2012-01-19 Exxonmobil Research And Engineering Company Hydroprocessing of biocomponent feeds with low pressure hydrogen-containing streams
US8557106B2 (en) 2010-09-30 2013-10-15 Exxonmobil Research And Engineering Company Hydrocracking process selective for improved distillate and improved lube yield and properties
US10144882B2 (en) 2010-10-28 2018-12-04 E I Du Pont De Nemours And Company Hydroprocessing of heavy hydrocarbon feeds in liquid-full reactors
AU2011325472B2 (en) 2010-11-04 2017-03-16 Albemarle Europe Sprl Hydrodeoxygenation of pyrolysis oil in presence of admixed alcohol
US8697594B2 (en) 2010-12-30 2014-04-15 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US9109176B2 (en) 2011-03-28 2015-08-18 Exxonmobil Research And Engineering Company Method for making marine bunker fuels
ITMI20110510A1 (en) * 2011-03-30 2012-10-01 Eni Spa TRANSITIONAL METAL MIXED OXIDES, TREATMENT CATALYSTS OBTAINED BY THEM, AND PREPARATION PROCESS
WO2012156294A1 (en) * 2011-05-13 2012-11-22 Shell Internationale Research Maatschappij B.V. Hydrotreating catalyst comprising a group viii and/or group vib metal silicide compound
KR101924414B1 (en) 2011-06-09 2018-12-03 마이크로마이다스, 인코포레이티드 Utilizing a multiphase reactor for the conversion of biomass to produce substituted furans
US8222464B2 (en) 2011-07-28 2012-07-17 Uop Llc Catalytic process for continuously generating polyols
US8222462B2 (en) 2011-07-28 2012-07-17 Uop Llc Process for generation of polyols from saccharides
US8222463B2 (en) 2011-07-28 2012-07-17 Uop Llc Process for generation of polyols from saccharide containing feedstock
US8410319B2 (en) 2011-07-28 2013-04-02 Uop Llc Continuous catalytic generation of polyols from cellulose with recycle
US8323937B2 (en) 2011-07-28 2012-12-04 Uop Llc Continuous catalytic generation of polyols from cellulose
US8222465B2 (en) 2011-07-28 2012-07-17 Uop Llc Catalytic process for continuously generating polyols
RU2468864C1 (en) * 2011-10-25 2012-12-10 Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации Catalyst, method of its preparation and method of hydrorefining diesel distillates
US8704007B2 (en) 2011-12-09 2014-04-22 Chevron U.S.A. Inc. Hydroconversion of renewable feedstocks
US8884077B2 (en) 2011-12-09 2014-11-11 Chevron U.S.A. Inc. Hydroconversion of renewable feedstocks
US9035115B2 (en) * 2011-12-09 2015-05-19 Chevron U.S.A. Inc. Hydroconversion of renewable feedstocks
US20130150641A1 (en) * 2011-12-09 2013-06-13 Chevron U.S.A. Inc. Hydroconversion of renewable feedstocks
US9199909B2 (en) * 2011-12-09 2015-12-01 Chevron U.S.A. Inc. Hydroconversion of renewable feedstocks
JP6254165B2 (en) 2012-09-05 2017-12-27 シェブロン ユー．エス．エー． インコーポレイテッド HYDROGEN CONVERSION MULTIMETAL CATALYST AND METHOD FOR PREPARING THE SAME
US9388151B2 (en) 2012-10-26 2016-07-12 Micromidas, Inc. Methods for producing 5-(halomethyl) furfural
US9321037B2 (en) 2012-12-14 2016-04-26 Chevron U.S.A., Inc. Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units
US9687823B2 (en) 2012-12-14 2017-06-27 Chevron U.S.A. Inc. Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units
JP6433434B2 (en) * 2013-01-08 2018-12-05 サウジ アラビアン オイル カンパニーＳａｕｄｉ Ａｒａｂｉａｎ Ｏｉｌ Ｃｏｍｐａｎｙ Method for optimizing catalyst packing for hydrocracking processes
US20140206915A1 (en) 2013-01-18 2014-07-24 Chevron U.S.A. Inc. Paraffinic jet and diesel fuels and base oils from vegetable oils via a combination of hydrotreating, paraffin disproportionation and hydroisomerization
US9650312B2 (en) 2013-03-14 2017-05-16 Lummus Technology Inc. Integration of residue hydrocracking and hydrotreating
EP2970167A4 (en) * 2013-03-14 2016-11-16 Micromidas Inc Solid forms of 5-(halomethyl) furfural and methods for preparing thereof
WO2014159741A1 (en) 2013-03-14 2014-10-02 Micromidas, Inc. Methods for purifying 5-(halomethyl)furfural
TWI637001B (en) * 2013-07-17 2018-10-01 巴地斯公司 Process and catalyst for resin hydrogenation
TW201527289A (en) 2013-09-20 2015-07-16 Micromidas Inc Methods for producing 5-(halomethyl)furfural
KR102278425B1 (en) * 2013-11-15 2021-07-19 셰브런 유.에스.에이.인크. Lubricating base oil production
RU2544996C1 (en) * 2013-11-27 2015-03-20 Общество с ограниченной ответственностью "ЛУКОЙЛ-Нижегороднефтеоргсинтез" (ООО "ЛУКОЙЛ-Нижегороднефтеоргсинтез") Method of producing high-viscosity index base oils
US10273420B2 (en) 2014-10-27 2019-04-30 Uop Llc Process for hydrotreating a hydrocarbons stream
CN104530317B (en) * 2014-11-27 2017-12-29 宁波职业技术学院 A kind of preparation method for being hydrogenated with indene resin
KR20170092620A (en) 2014-12-04 2017-08-11 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 Low sulfur marine bunker fuels and methods of making same
CN104693359B (en) * 2015-02-15 2017-08-29 广西大学 Trans-critical cycle reaction system hydrogenation modification rosin and C9/C5 Petropols method and devices
CN104815697A (en) * 2015-05-20 2015-08-05 南开大学 Preparation method for preparing biological aviation kerosene ultra-dispersed hydrodeoxygenation and hydroisomerization catalysts from castor oil
US10232357B2 (en) 2015-12-15 2019-03-19 Uop Llc Crystalline ammonia transition metal molybdate
US10322404B2 (en) 2015-12-15 2019-06-18 Uop Llc Crystalline transition metal oxy-hydroxide molybdate
US10052616B2 (en) 2015-12-15 2018-08-21 Uop Llc Crystalline ammonia transition metal molybdotungstate
US10053637B2 (en) 2015-12-15 2018-08-21 Uop Llc Transition metal tungsten oxy-hydroxide
US10400181B2 (en) * 2015-12-15 2019-09-03 Uop Llc Crystalline bis-ammonia metal molybdate
US10449523B2 (en) 2015-12-15 2019-10-22 Uop Llc Crystalline bis-ammonia transition metal molybdotungstate
US10399063B2 (en) 2015-12-15 2019-09-03 Uop Llc Mixed metal oxides
US10052614B2 (en) 2015-12-15 2018-08-21 Uop Llc Mixed metal oxides
US10005812B2 (en) 2015-12-15 2018-06-26 Uop Llc Transition metal molybdotungsten oxy-hydroxide
US10046315B2 (en) 2015-12-15 2018-08-14 Uop Llc Crystalline transition metal molybdotungstate
US10399065B2 (en) 2015-12-15 2019-09-03 Uop Llc Crystalline transition metal tungstate
US10233398B2 (en) 2015-12-15 2019-03-19 Uop Llc Crystalline transition metal oxy-hydroxide molybdotungstate
CN106994350B (en) * 2016-01-22 2019-12-20 中国科学院大连化学物理研究所 Gasoline selective hydrodesulfurization bulk phase catalyst and preparation and application thereof
US10457877B2 (en) 2016-03-31 2019-10-29 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
EP3458552A1 (en) 2016-05-17 2019-03-27 Exxonmobil Research And Engineering Company Jet and diesel selective hydrocracking
US20180105761A1 (en) 2016-10-14 2018-04-19 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
WO2018083715A1 (en) * 2016-11-07 2018-05-11 Hindustan Petroleum Corporation Limited Process for producing lighter distillates
CN106693997B (en) * 2017-01-10 2019-05-31 中国石油大学(华东) A kind of diesel hydrogenation for removal sulphur catalyst and its preparation method and application
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US20180230389A1 (en) 2017-02-12 2018-08-16 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
SG11201912425YA (en) 2017-08-03 2020-02-27 Exxonmobil Res & Eng Co Blocked operation for group ii and group iii lubricant production
CA3069467A1 (en) 2017-08-03 2019-02-07 Exxonmobil Research And Engineering Company Activation of noble metal catalysts on siliceous supports with water-containing gas stream
RU2665484C1 (en) * 2017-08-25 2018-08-30 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Method for producing catalyst and method for hydrogening oil-polymeric resins at its presence
US10882030B2 (en) 2017-08-25 2021-01-05 Uop Llc Crystalline transition metal tungstate
US10773245B2 (en) 2017-08-25 2020-09-15 Uop Llc Crystalline transition metal molybdotungstate
US10995013B2 (en) 2017-12-20 2021-05-04 Uop Llc Mixed transition metal tungstate
US10822247B2 (en) 2017-12-20 2020-11-03 Uop Llc Highly active trimetallic materials using short-chain alkyl quaternary ammonium compounds
US10843176B2 (en) * 2017-12-20 2020-11-24 Uop Llc Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds
US11034591B2 (en) 2017-12-20 2021-06-15 Uop Llc Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds
US11078088B2 (en) 2017-12-20 2021-08-03 Uop Llc Highly active multimetallic materials using short-chain alkyl quaternary ammonium compounds
US10875013B2 (en) 2017-12-20 2020-12-29 Uop Llc Crystalline oxy-hydroxide transition metal molybdotungstate
US11007515B2 (en) 2017-12-20 2021-05-18 Uop Llc Highly active trimetallic materials using short-chain alkyl quaternary ammonium compounds
US11117811B2 (en) 2017-12-20 2021-09-14 Uop Llc Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds
TW201930575A (en) 2017-12-21 2019-08-01 美商艾克頌美孚研究工程公司 Lubricant compositions having improved low temperature performance
TW201934734A (en) 2017-12-21 2019-09-01 美商艾克頌美孚研究工程公司 Lubricant compositions having improved oxidation performance
TW201934731A (en) 2017-12-21 2019-09-01 美商艾克頌美孚研究工程公司 Group III base stocks and lubricant compositions
TW201932583A (en) 2017-12-21 2019-08-16 美商艾克頌美孚研究工程公司 Group III base stocks and lubricant compositions
US10808189B2 (en) 2018-05-07 2020-10-20 Exxonmobil Research And Engineering Company Process for production of base stocks
US10737248B2 (en) 2018-06-26 2020-08-11 Uop Llc Crystalline transition metal tungstate
EP3814456A1 (en) 2018-06-26 2021-05-05 ExxonMobil Research and Engineering Company Production of improved base stocks
US10737249B2 (en) 2018-06-26 2020-08-11 Uop Llc Crystalline transition metal molybdotungstate
US10688479B2 (en) 2018-06-26 2020-06-23 Uop Llc Crystalline transition metal tungstate
US10682632B2 (en) 2018-06-26 2020-06-16 Uop Llc Transition metal tungstate material
US11033883B2 (en) 2018-06-26 2021-06-15 Uop Llc Transition metal molybdotungstate material
US10737246B2 (en) 2018-06-29 2020-08-11 Uop Llc Poorly crystalline transition metal tungstate
US10981151B2 (en) 2018-06-29 2021-04-20 Uop Llc Poorly crystalline transition metal molybdotungstate
RU2675361C1 (en) * 2018-08-06 2018-12-19 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Method for producing catalyst and method for hydrogenating oil-polymeric resins at its presence
US11213803B2 (en) 2018-12-13 2022-01-04 Uop Llc Ammonia-free synthesis for Al or Si based multimetallic materials
US10933407B2 (en) 2018-12-13 2021-03-02 Uop Llc Ammonia-free synthesis for Al or Si based multimetallic materials
WO2020171965A1 (en) * 2019-02-22 2020-08-27 Exxonmobil Research And Engineering Company Hydroprocessing feedstocks having silicon content
US11426711B2 (en) 2019-05-22 2022-08-30 Uop Llc Method of making highly active metal oxide and metal sulfide materials
US20220325011A1 (en) * 2019-06-03 2022-10-13 Hanwha Solutions Corporatiopn Preparation method of hydrogenated petroleum resin
EP4013837A1 (en) 2019-08-12 2022-06-22 Chevron U.S.A. Inc. Process for improving base oil yields
AU2019470001A1 (en) 2019-10-11 2022-05-12 Vector Vitale Ip Llc Rubidium and/or zinc compounds for treating Parkinson's and other neurodegenerative diseases
US11185850B2 (en) 2019-12-02 2021-11-30 Saudi Arabian Oil Company Dual functional composite catalyst for olefin metathesis and cracking
CN110961127A (en) * 2019-12-09 2020-04-07 大连理工大学 Method for preparing loaded DCPD resin hydrogenation catalyst by using hydrotalcite-like compound as precursor
CN111333752B (en) * 2020-02-28 2021-06-08 宁波工程学院 Hydrogenation catalysis method of carbon nine resin
FR3111827B1 (en) 2020-06-29 2022-08-19 Ifp Energies Now TRIMETALLIC CATALYST BASED ON NICKEL, MOLYBDENUM AND TUNGSTEN AND ITS USE IN A HYDROTREATING AND/OR HYDROCRACKING PROCESS
US11826738B2 (en) 2020-07-27 2023-11-28 Uop Llc High activity and high distillate yield hydrocracking catalysts with intimate interaction between unsupported metal oxide and zeolite
US20230235237A1 (en) 2020-08-07 2023-07-27 Totalenergies Onetech Process for the production of white oils
CN116171314A (en) 2020-08-07 2023-05-26 道达尔能源技术公司 Process for producing white oil
CN111825846B (en) * 2020-08-12 2021-10-22 广西壮族自治区林业科学研究院 Light-colored high-stability water-soluble rosin resin and preparation method thereof
WO2022039730A1 (en) * 2020-08-19 2022-02-24 Exxonmobil Research And Engineering Company Tungsten-containing bulk catalysts, method of making the same, and their use in low pressure diesel hydroprocessing
BR112023014889A2 (en) 2021-01-26 2023-10-10 Chevron Usa Inc PROCESS FOR PRODUCING BRIGHT STOCK BASE OIL PRODUCTS
JP2024506820A (en) 2021-01-26 2024-02-15 シェブロン ユー．エス．エー． インコーポレイテッド Process for manufacturing heavy grade base oil products
US11384297B1 (en) * 2021-02-04 2022-07-12 Saudi Arabian Oil Company Systems and methods for upgrading pyrolysis oil to light aromatics over mixed metal oxide catalysts
WO2023015168A1 (en) 2021-08-06 2023-02-09 ExxonMobil Technology and Engineering Company Hydro-dealkylation process to generate high quality fuels, base stocks and waxes
WO2023114839A1 (en) 2021-12-15 2023-06-22 ExxonMobil Technology and Engineering Company Bulk cobalt-molybdenum catalyst compositions and synthesis methods
US11746299B1 (en) 2022-07-11 2023-09-05 Saudi Arabian Oil Company Methods and systems for upgrading mixed pyrolysis oil to light aromatics over mixed metal oxide catalysts
CN115475644B (en) * 2022-09-15 2023-09-19 青岛科技大学 Method for preparing hydrogenated rosin by rosin hydrogenation and catalyst thereof

Family Cites Families (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US480563A (en) * 1892-08-09 Sectional horseshoe
NL78907C (en) * 1951-08-31
US3520796A (en) * 1968-08-21 1970-07-14 Gulf Research Development Co Making lubricating oils by hydrotreating and dewaxing
US3678124A (en) * 1968-10-24 1972-07-18 Gennady Arkadievich Stepanov Process for the production of mono- and diolefin hydrocarbons
US3619414A (en) * 1969-02-19 1971-11-09 Sun Oil Co Catalytic hydrofinishing of petroleum distillates in the lubricating oil boiling range
US3861005A (en) * 1969-05-28 1975-01-21 Sun Oil Co Pennsylvania Catalytic isomerization of lube streams and waxes
US3901828A (en) * 1971-11-08 1975-08-26 Heraeus Gmbh W C Oxidation catalyst for combustibles in gas mixtures
GB1408759A (en) * 1971-12-07 1975-10-01 Shell Int Research Catalytic hydrodesulphurisation process
US3850746A (en) * 1972-03-09 1974-11-26 Exxon Research Engineering Co Hydrodenitrogenation of hydrocarbon feedstocks with a catalyst composite of chrysotile and hydrogenation metal
JPS5714333B2 (en) * 1973-07-05 1982-03-24
IT1001977B (en) * 1973-11-28 1976-04-30 Sir Soc Italiana Resine Spa PROCEDURE FOR THE PREPARATION OF METHYL ACRYLATE OR MIXTURES OF METHYL ACRYLATE AND ACRILIC ACID
US4102822A (en) * 1976-07-26 1978-07-25 Chevron Research Company Hydrocarbon hydroconversion catalyst and the method for its preparation
US4388223A (en) * 1981-04-06 1983-06-14 Euteco Impianti S.P.A. Catalyst for the conversion of unsaturated hydrocarbons into diolefins or unsaturated aldehydes and nitriles, and process for preparing the same
US4395328A (en) * 1981-06-17 1983-07-26 Standard Oil Company (Indiana) Catalyst and support, their methods of preparation, and processes employing same
US4857496A (en) * 1983-08-29 1989-08-15 Chevron Research Company Heavy oil hydroprocessing with Group VI metal slurry catalyst
US4824821A (en) * 1983-08-29 1989-04-25 Chevron Research Company Dispersed group VIB metal sulfide catalyst promoted with Group VIII metal
FR2553680B1 (en) * 1983-10-25 1987-09-18 Inst Francais Du Petrole CATALYSTS BASED ON GROUP VIII AND GROUP VIB METAL SULFIDES FOR HYDROPROCESSING REACTIONS OF SULFUR-CONTAINING HYDROCARBON CUTS
EP0169054A3 (en) * 1984-07-18 1987-12-16 The University Of Newcastle Upon Tyne Composite materials and products
US4591429A (en) * 1984-09-28 1986-05-27 Exxon Research And Engineering Co. Hydrotreating process employing catalysts comprising a supported mixture of a sulfide of a promoter metal, trivalent chromium and molybdenum or tungsten
US4721558A (en) * 1984-09-28 1988-01-26 Exxon Research And Engineering Company Hydrotreating catalysts comprising a mixture of a sulfide of a promoter metal amorphous sulfide of trivalent chromium and microcrystalline molybdenum or tungsten sulfide
US4666878A (en) * 1984-12-28 1987-05-19 Exxon Research And Engineering Company Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and uses thereof
GB8518940D0 (en) * 1985-07-26 1985-09-04 Shell Int Research Manufacture of lubricating base oils
EP0215989A1 (en) * 1985-08-06 1987-04-01 Exxon Research And Engineering Company Amorphous, iron promoted mo and w sulfide hydroprocessing catalysts and uses thereof
US4808563A (en) * 1986-03-24 1989-02-28 The Standard Oil Company Molybdenum-tungsten-containing catalyst for methane conversion process
JPS62199687A (en) * 1986-04-28 1987-09-03 ユニオン・オイル・コンパニ−・オブ・カリフオルニア Hydrogenation using catalyst having large pores
US4849093A (en) * 1987-02-02 1989-07-18 Union Oil Company Of California Catalytic aromatic saturation of hydrocarbons
US4875992A (en) * 1987-12-18 1989-10-24 Exxon Research And Engineering Company Process for the production of high density jet fuel from fused multi-ring aromatics and hydroaromatics
US4952306A (en) * 1989-09-22 1990-08-28 Exxon Research And Engineering Company Slurry hydroprocessing process
GB8925980D0 (en) * 1989-11-16 1990-01-04 Shell Int Research Process for converting hydrocarbon oils
US5122258A (en) * 1991-05-16 1992-06-16 Exxon Research And Engineering Company Increasing VI of lube oil by hydrotreating using bulk Ni/Mn/Mo or Ni/Cr/Mo sulfide catalysts prepared from ligated metal complexes
JPH04365526A (en) * 1991-06-12 1992-12-17 Kiwa Giken Kk Grinding method and device thereof
US5320741A (en) * 1992-04-09 1994-06-14 Stone & Webster Engineering Corporation Combination process for the pretreatment and hydroconversion of heavy residual oils
RU2030444C1 (en) * 1992-07-20 1995-03-10 Акционерное общество открытого типа "ЛУКойл-Пермнефтеоргсинтез" Method of hydrotreatment of petroleum distillate fractions
JP3065816B2 (en) * 1992-10-02 2000-07-17 日石三菱株式会社 Production method of high viscosity index low viscosity lubricating base oil
JP3057125B2 (en) * 1992-10-02 2000-06-26 日石三菱株式会社 Method for producing high viscosity index low viscosity lubricating base oil
US5306848A (en) * 1992-10-16 1994-04-26 Exxon Chemical Patents Inc. Hydrogenation catalyst for oxo alcohol process
DE4302991A1 (en) * 1993-02-03 1994-08-04 Basf Ag Multimetal oxide materials
JPH06262084A (en) * 1993-03-12 1994-09-20 Agency Of Ind Science & Technol Hydrocracking catalyst of hydrocarbon oil
JPH0782573A (en) * 1993-07-23 1995-03-28 Jgc Corp Method and apparatus for treating petroleum
US5399793A (en) * 1993-11-29 1995-03-21 Exxon Chemical Patents Inc. Hydrogenation catalyst for oxo alcohol process
US5382715A (en) * 1993-11-29 1995-01-17 Exxon Chemical Patents Inc. Hydrogenation catalyst with low phosphorous content for oxo alcohol process
US5510309A (en) * 1994-05-02 1996-04-23 Mobil Oil Corporation Method for preparing a modified solid oxide
TW309513B (en) * 1994-05-31 1997-07-01 Nippon Catalytic Chem Ind
IT1275447B (en) * 1995-05-26 1997-08-07 Snam Progetti PROCEDURE FOR THE CONVERSION OF HEAVY CRUDE AND DISTILLATION DISTILLATION RESIDUES
JP3676849B2 (en) * 1995-06-10 2005-07-27 財団法人石油産業活性化センター Gas oil hydrodesulfurization catalyst
US5911874A (en) * 1996-06-28 1999-06-15 Exxon Research And Engineering Co. Raffinate hydroconversion process
US5976353A (en) * 1996-06-28 1999-11-02 Exxon Research And Engineering Co Raffinate hydroconversion process (JHT-9601)
EP0912660A1 (en) * 1996-07-15 1999-05-06 Chevron U.S.A. Inc. Layered catalyst system for lube oil hydroconversion
CZ297084B6 (en) * 1996-07-16 2006-09-13 Chevron U. S. A. Inc. Process for producing lubricating oil base stock
US6096189A (en) * 1996-12-17 2000-08-01 Exxon Research And Engineering Co. Hydroconversion process for making lubricating oil basestocks
US6162350A (en) * 1997-07-15 2000-12-19 Exxon Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901)
US6156695A (en) * 1997-07-15 2000-12-05 Exxon Research And Engineering Company Nickel molybdotungstate hydrotreating catalysts
CN1055955C (en) * 1997-11-24 2000-08-30 中国石油化工总公司 Hydrogenation catalyst and preparation thereof
US5968346A (en) * 1998-09-16 1999-10-19 Exxon Research And Engineering Co. Two stage hydroprocessing with vapor-liquid interstage contacting for vapor heteroatom removal

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WO2000042125A1 (en) 2000-07-20
WO2000042120A8 (en) 2001-04-12
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CA2357022C (en) 2011-03-15
NO20013488D0 (en) 2001-07-13
BR0007558A (en) 2001-10-23
NO20013492D0 (en) 2001-07-13
EP1157083B1 (en) 2004-09-22
CA2356920C (en) 2010-06-01
JP4625582B2 (en) 2011-02-02
WO2000042121A1 (en) 2000-07-20
DK1169414T3 (en) 2009-02-16
AU2727600A (en) 2000-08-01
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AU757716B2 (en) 2003-03-06
JP2002534583A (en) 2002-10-15
NO20013487L (en) 2001-09-14
AU2966700A (en) 2000-08-01
NO20013492L (en) 2001-08-31
WO2000042121A8 (en) 2001-04-12
ES2246828T3 (en) 2006-03-01
ATE302831T1 (en) 2005-09-15
NO20013424L (en) 2001-07-10
EP1144351A1 (en) 2001-10-17
NO20013488L (en) 2001-09-13
NO329318B1 (en) 2010-09-27
JP4766747B2 (en) 2011-09-07
JP4766746B2 (en) 2011-09-07
EP1153046A1 (en) 2001-11-14
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EP1169415A1 (en) 2002-01-09
CA2357024A1 (en) 2000-07-20
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US6162350A (en) 2000-12-19
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AU2966200A (en) 2000-08-01
NO331510B1 (en) 2012-01-16
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CA2359192C (en) 2011-03-15
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AU759864B2 (en) 2003-05-01
WO2000042126A1 (en) 2000-07-20
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EP1171549A1 (en) 2002-01-16
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