CA2366406A1 - Double silver low-emissivity and solar control coatings - Google Patents
Double silver low-emissivity and solar control coatings Download PDFInfo
- Publication number
- CA2366406A1 CA2366406A1 CA002366406A CA2366406A CA2366406A1 CA 2366406 A1 CA2366406 A1 CA 2366406A1 CA 002366406 A CA002366406 A CA 002366406A CA 2366406 A CA2366406 A CA 2366406A CA 2366406 A1 CA2366406 A1 CA 2366406A1
- Authority
- CA
- Canada
- Prior art keywords
- layer
- sublayer
- layer including
- coating
- silicon nitride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract 30
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title 1
- 229910052709 silver Inorganic materials 0.000 title 1
- 239000004332 silver Substances 0.000 title 1
- 239000011248 coating agent Substances 0.000 claims abstract 28
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract 14
- 239000000758 substrate Substances 0.000 claims abstract 14
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract 13
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract 12
- 229910052751 metal Inorganic materials 0.000 claims abstract 10
- 239000002184 metal Substances 0.000 claims abstract 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract 8
- 239000011787 zinc oxide Substances 0.000 claims abstract 7
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000001301 oxygen Substances 0.000 claims abstract 2
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 2
- 230000005855 radiation Effects 0.000 claims 6
- 229910018487 Ni—Cr Inorganic materials 0.000 claims 3
- 229910045601 alloy Inorganic materials 0.000 claims 3
- 239000000956 alloy Substances 0.000 claims 3
- 238000000151 deposition Methods 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000005728 strengthening Methods 0.000 claims 2
- 238000005299 abrasion Methods 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 238000004544 sputter deposition Methods 0.000 claims 1
- 230000004888 barrier function Effects 0.000 abstract 1
- 238000009792 diffusion process Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
- G02B5/281—Interference filters designed for the infrared light
- G02B5/282—Interference filters designed for the infrared light reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
- Y10T428/12618—Plural oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Abstract
A low-emissivity multilayer coating includes, in order outward from the substrate, a first layer including a layer containing titanium oxide, a layer containing silicon nitride, or a sublayer layer containing titanium oxide in combination with a sublayer containing silicon nitride; a second layer including Ag; a third layer including at least one layer selected from titanium oxide layers and silicon nitride layers; a fourth layer including Ag;
and a fifth layer including silicon nitride. The color of the coatings can be varied over a wide range by controlling the thicknesses of the layers of titanium oxide, silicon nitride and Ag. A diffusion barrier of oxidized metal protects relatively thin, high electrical conductivity, pinhole free Ag films grown preferentially on zinc oxide substrates. Oxygen and/or nitrogen in the Ag films improves the thermal and mechanical stability of the Ag. Dividing the first layer of titanium oxide, the Ag layers, and/or the third layer with a sublayer of oxidized metal can provide greater thermal and mechanical stability to the respective layers.
and a fifth layer including silicon nitride. The color of the coatings can be varied over a wide range by controlling the thicknesses of the layers of titanium oxide, silicon nitride and Ag. A diffusion barrier of oxidized metal protects relatively thin, high electrical conductivity, pinhole free Ag films grown preferentially on zinc oxide substrates. Oxygen and/or nitrogen in the Ag films improves the thermal and mechanical stability of the Ag. Dividing the first layer of titanium oxide, the Ag layers, and/or the third layer with a sublayer of oxidized metal can provide greater thermal and mechanical stability to the respective layers.
Claims (22)
1. A low-emissivity coating on a substrate, the coating comprising, in numerical order outward from the substrate, a first layer including at least one layer selected from titanium oxide layers and silicon nitride layers;
a second layer including Ag;
a third layer including at least one layer selected from titanium oxide layers and silicon nitride layers;
a fourth layer including Ag; and a fifth layer including silicon nitride.
a second layer including Ag;
a third layer including at least one layer selected from titanium oxide layers and silicon nitride layers;
a fourth layer including Ag; and a fifth layer including silicon nitride.
2. The coating according to Claim 1, wherein the first layer is from 5 to 30 nm thick.
3. The coating according to Claim 1, wherein the titanium oxide in the first layer is amorphous.
4. The coating according to Claim 1, wherein the third layer comprises at least one of a TiO2 layer and a Si3N4 layer.
5. The coating according to Claim 1, wherein the third layer comprises a superlattice of titanium oxide and silicon nitride.
6. The coating according to Claim 1, wherein at least one of the second layer and the fourth layer consists of, in numerical order outward from the substrate, a first sublayer including a zinc oxide;
a second sublayer including Ag; and a third sublayer including an oxidized metal.
a second sublayer including Ag; and a third sublayer including an oxidized metal.
7. The coating according to Claim 6, wherein the zinc oxide comprises nitrogen.
8. The coating according to Claim 6; wherein the oxidized metal comprises an at least partially oxidized Ni-Cr alloy.
9. The coating according to Claim 1, wherein the Ag in at least one of the second layer and the fourth layer further comprises at least one of oxygen and nitrogen.
10. The coating according to Claim 1, wherein the Ag in at least one of the second layer and the fourth layer further comprises a means for strengthening the Ag against thermally induced changes.
11. The coating according to Claim 1, wherein at least one of the first layer, the second layer, the third layer, and the fourth layer is divided by a layer of an oxidized metal.
12. The coating according to Claim 11, wherein the oxidized metal is an at least partially oxidized Ni-Cr alloy.
13. The coating according to Claim 1, wherein at least one layer of the first layer, the second layer, the third layer, and the fourth layer is divided by layer including a means for strengthening the at least one layer against thermally induced changes.
14. A method of making a low-emissivity coating on a substrate, the method comprising depositing at least one layer including Ag; and forming the coating of Claim 1.
15. The method according to Claim 14, wherein the depositing comprises sputtering.
16. A method of making a low-emissivity coating on a substrate, the method comprising a step for depositing at least one layer including Ag on a substrate; and forming the coating of Claim 1.
17. A low-emissivity coating on a substrate, the coating comprising, in numerical order outward from the substrate, a first layer including at least one layer selected from titanium oxide layers and silicon nitride layers;
a second layer including a first means for reflecting infrared radiation;
a third layer having an index of refraction greater than or equal to 1.9 at a wavelength of 550 nm;
a fourth layer including a second means for reflecting infrared radiation; and a fifth layer including a means for protecting the coating from abrasion.
a second layer including a first means for reflecting infrared radiation;
a third layer having an index of refraction greater than or equal to 1.9 at a wavelength of 550 nm;
a fourth layer including a second means for reflecting infrared radiation; and a fifth layer including a means for protecting the coating from abrasion.
18. The coating according to Claim 17, wherein at least one of the first means for reflecting infrared radiation and the second means for reflecting infrared radiation consists of, in numerical order outward from the substrate, a first sublayer, a second sublayer including Ag, and a third sublayer;
the first sublayer includes a means for preferentially orienting a crystal structure of the second sublayer; and the third sublayer includes an oxidized metal.
the first sublayer includes a means for preferentially orienting a crystal structure of the second sublayer; and the third sublayer includes an oxidized metal.
19. The coating according to Claim 18, wherein the oxidized metal comprises an at least partially oxidized Ni-Cr alloy.
20. The coating according to Claim 17, wherein at least one of the first means for reflecting infrared radiation and the second means for reflecting infrared radiation consists of, in numerical order outward from the substrate, a first sublayer, a second sublayer including Ag, and a third sublayer;
the first sublayer includes a zinc oxide; and the third sublayer includes a means for preventing the Ag in the second sublayer from corroding.
the first sublayer includes a zinc oxide; and the third sublayer includes a means for preventing the Ag in the second sublayer from corroding.
21. The coating according to Claim 19, wherein the zinc oxide comprises nitrogen.
22. A low-emissivity coating on a transparent substrate, the coating comprising, in numerical order outward from the substrate, a first layer including at least one layer selected from titanium oxide layers and silicon nitride layers;
a second layer including a zinc oxide;
a third layer including Ag;
a fourth layer including a first oxidized metal;
a fifth layer including at least one layer selected from titanium oxide layers and silicon nitride layers;
a sixth layer including a zinc oxide;
a seventh layer including Ag;
an eight layer including a second oxidized metal; and a ninth layer including silicon nitride.
a second layer including a zinc oxide;
a third layer including Ag;
a fourth layer including a first oxidized metal;
a fifth layer including at least one layer selected from titanium oxide layers and silicon nitride layers;
a sixth layer including a zinc oxide;
a seventh layer including Ag;
an eight layer including a second oxidized metal; and a ninth layer including silicon nitride.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/944,372 | 2001-09-04 | ||
US09/944,372 US20030049464A1 (en) | 2001-09-04 | 2001-09-04 | Double silver low-emissivity and solar control coatings |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2366406A1 true CA2366406A1 (en) | 2003-03-04 |
CA2366406C CA2366406C (en) | 2011-05-24 |
Family
ID=25481274
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2366406A Expired - Lifetime CA2366406C (en) | 2001-09-04 | 2001-12-28 | Double silver low-emissivity and solar control coatings |
Country Status (2)
Country | Link |
---|---|
US (6) | US20030049464A1 (en) |
CA (1) | CA2366406C (en) |
Families Citing this family (102)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7879448B2 (en) * | 2000-07-11 | 2011-02-01 | Guardian Industires Corp. | Coated article with low-E coating including IR reflecting layer(s) and corresponding method |
US7344782B2 (en) * | 2000-07-10 | 2008-03-18 | Guardian Industries Corp. | Coated article with low-E coating including IR reflecting layer(s) and corresponding method |
US7462397B2 (en) | 2000-07-10 | 2008-12-09 | Guardian Industries Corp. | Coated article with silicon nitride inclusive layer adjacent glass |
US6887575B2 (en) * | 2001-10-17 | 2005-05-03 | Guardian Industries Corp. | Heat treatable coated article with zinc oxide inclusive contact layer(s) |
US7462398B2 (en) * | 2004-02-27 | 2008-12-09 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with zinc oxide over IR reflecting layer and corresponding method |
US20030049464A1 (en) * | 2001-09-04 | 2003-03-13 | Afg Industries, Inc. | Double silver low-emissivity and solar control coatings |
US6936347B2 (en) | 2001-10-17 | 2005-08-30 | Guardian Industries Corp. | Coated article with high visible transmission and low emissivity |
US6942923B2 (en) | 2001-12-21 | 2005-09-13 | Guardian Industries Corp. | Low-e coating with high visible transmission |
US6749941B2 (en) | 2002-03-14 | 2004-06-15 | Guardian Industries Corp. | Insulating glass (IG) window unit including heat treatable coating with silicon-rich silicon nitride layer |
US7067195B2 (en) * | 2002-04-29 | 2006-06-27 | Cardinal Cg Company | Coatings having low emissivity and low solar reflectance |
US7122252B2 (en) | 2002-05-16 | 2006-10-17 | Cardinal Cg Company | High shading performance coatings |
JP4298654B2 (en) * | 2002-07-31 | 2009-07-22 | 日本板硝子株式会社 | Quenchable high light-shielding coating |
US6787005B2 (en) | 2002-09-04 | 2004-09-07 | Guardian Industries Corp. | Methods of making coated articles by sputtering silver in oxygen inclusive atmosphere |
US20040121146A1 (en) * | 2002-12-20 | 2004-06-24 | Xiao-Ming He | Composite barrier films and method |
US7005190B2 (en) | 2002-12-20 | 2006-02-28 | Guardian Industries Corp. | Heat treatable coated article with reduced color shift at high viewing angles |
US6967060B2 (en) | 2003-05-09 | 2005-11-22 | Guardian Industries Corp. | Coated article with niobium zirconium inclusive layer(s) and method of making same |
NL1023880C2 (en) * | 2003-07-10 | 2005-01-11 | Tno | Emission-enhancing coating, article on which the coating has been applied, and method for applying the coating to a surface. |
FR2859721B1 (en) * | 2003-09-17 | 2006-08-25 | Saint Gobain | TRANSPARENT SUBSTRATE WITH THIN FILM STACK FOR ELECTROMAGNETIC SHIELDING |
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US7294402B2 (en) * | 2004-03-05 | 2007-11-13 | Guardian Industries Corp. | Coated article with absorbing layer |
FR2869898B1 (en) * | 2004-05-05 | 2007-03-30 | Saint Gobain | SUBSTRATE PROVIDED WITH A STACK WITH THERMAL PROPERTIES |
US7115182B2 (en) * | 2004-06-15 | 2006-10-03 | Agency For Science, Technology And Research | Anodic bonding process for ceramics |
US7229533B2 (en) * | 2004-06-25 | 2007-06-12 | Guardian Industries Corp. | Method of making coated article having low-E coating with ion beam treated and/or formed IR reflecting layer |
US7563347B2 (en) * | 2004-06-25 | 2009-07-21 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Method of forming coated article using sputtering target(s) and ion source(s) and corresponding apparatus |
US20090258222A1 (en) * | 2004-11-08 | 2009-10-15 | Agc Flat Glass Europe S.A. | Glazing panel |
US20060211272A1 (en) * | 2005-03-17 | 2006-09-21 | The Regents Of The University Of California | Architecture for high efficiency polymer photovoltaic cells using an optical spacer |
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MX2007014164A (en) * | 2005-05-12 | 2008-02-25 | Agc Flat Glass North America | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same. |
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FR2757151B1 (en) * | 1996-12-12 | 1999-01-08 | Saint Gobain Vitrage | GLAZING COMPRISING A SUBSTRATE PROVIDED WITH A STACK OF THIN FILMS FOR SUN PROTECTION AND / OR THERMAL INSULATION |
FR2759362B1 (en) * | 1997-02-10 | 1999-03-12 | Saint Gobain Vitrage | TRANSPARENT SUBSTRATE EQUIPPED WITH AT LEAST ONE THIN LAYER BASED ON SILICON NITRIDE OR OXYNITRIDE AND ITS PROCESS FOR OBTAINING IT |
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US20030049464A1 (en) * | 2001-09-04 | 2003-03-13 | Afg Industries, Inc. | Double silver low-emissivity and solar control coatings |
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-
2001
- 2001-09-04 US US09/944,372 patent/US20030049464A1/en not_active Abandoned
- 2001-12-28 CA CA2366406A patent/CA2366406C/en not_active Expired - Lifetime
-
2003
- 2003-01-31 US US10/355,018 patent/US20030148115A1/en not_active Abandoned
-
2006
- 2006-03-02 US US11/365,528 patent/US20060147727A1/en not_active Abandoned
-
2007
- 2007-05-07 US US11/745,243 patent/US7632572B2/en not_active Expired - Lifetime
-
2009
- 2009-02-27 US US12/394,119 patent/US20090214889A1/en not_active Abandoned
-
2012
- 2012-01-13 US US13/350,334 patent/US8512883B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US20060147727A1 (en) | 2006-07-06 |
US8512883B2 (en) | 2013-08-20 |
US7632572B2 (en) | 2009-12-15 |
CA2366406C (en) | 2011-05-24 |
US20030049464A1 (en) | 2003-03-13 |
US20070207327A1 (en) | 2007-09-06 |
US20090214889A1 (en) | 2009-08-27 |
US20030148115A1 (en) | 2003-08-07 |
US20120321867A1 (en) | 2012-12-20 |
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