CA2393525A1 - Controlled release anti-microbial wipe for hard surfaces - Google Patents

Controlled release anti-microbial wipe for hard surfaces Download PDF

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Publication number
CA2393525A1
CA2393525A1 CA002393525A CA2393525A CA2393525A1 CA 2393525 A1 CA2393525 A1 CA 2393525A1 CA 002393525 A CA002393525 A CA 002393525A CA 2393525 A CA2393525 A CA 2393525A CA 2393525 A1 CA2393525 A1 CA 2393525A1
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CA
Canada
Prior art keywords
wiper
microbial agent
fibrous
microbial
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002393525A
Other languages
French (fr)
Other versions
CA2393525C (en
Inventor
Fred R. Radwanski
Ralph L. Anderson
James W. Clark
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kimberly Clark Worldwide Inc
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2393525A1 publication Critical patent/CA2393525A1/en
Application granted granted Critical
Publication of CA2393525C publication Critical patent/CA2393525C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16—Cloths; Pads; Sponges
    • A47L13/17—Cloths; Pads; Sponges containing cleaning agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/23—Solid substances, e.g. granules, powders, blocks, tablets
    • A61L2/238—Metals or alloys, e.g. oligodynamic metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3953—Inorganic bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0223—Vinyl resin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B32B2262/067—Wood fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/10—Fibres of continuous length
    • B32B2305/20—Fibres of continuous length in the form of a non-woven mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/30—Fillers, e.g. particles, powders, beads, flakes, spheres, chips
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/73—Hydrophobic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2432/00—Cleaning articles, e.g. mops, wipes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3707—Woven fabric including a nonwoven fabric layer other than paper
    • Y10T442/378—Coated, impregnated, or autogenously bonded
    • Y10T442/3846—Including particulate material other than fiber

Abstract

A wiper that provides a controlled release anti-microbial agent has a substrate layer to which the anti-microbial agent is adhered. In addition, t he wiper will have one or more laminate layers, at least one of which will be absorbent. Various anti-microbial agents such as silver containing additives , calcium hypochlorite, and chlorine dioxide generating compounds may be employed. The substrate layer may be a poly(ethylene vinyl acetate) meltblow n web and the laminate layer may be a hydroentangled composite absorbent fabri c.

Claims (38)

1. A wiper for disinfecting hard surfaces comprising:
a fibrous laminate layer, said fibrous laminate layer being capable of absorbing a liquid when contacted therewith;
a fibrous substrate layer, said fibrous substrate layer being adhered to said fibrous laminate layer; and an anti-microbial agent adhered to said fibrous substrate layer, said anti-microbial agent being capable of activation when contacted with a liquid, said activation including the release of a portion of said anti-microbial agent into said liquid that is contained within the wiper such that an anti-microbial solution forms therefrom, the anti-microbial agent being adapted to provide that the rate of said release is sufficient to ensure that an anti-microbial solution is formed in the liquid within the wiper after said wiper has been subjected to at least five rinsing cycles.
2. A wiper as defined in claim 1, wherein said anti-microbial agent comprises hypochlorite particles.
3. A wiper as defined in claim 2, wherein said hypochlorite particles are at least partially encapsulated to provide further control over said release into said liquid.
4. A wiper as defined in claim 2, wherein said hypochlorite particles are at least partially coated with a polymer to provide further control over said release into said liquid.
5. A wiper as defined in claim 2, wherein said hypochlorite particles comprise calcium hypochlorite.
6. A wiper as defined in claim 1, further including anti-microbial agents in the form of particles, wherein said particles have different particle sizes such that release of said anti-microbial agent is controlled by the presence of different sizes of anti-microbial agent particles.
7. A wiper as defined in claim 1, wherein the fibrous substrate layer comprises a hydrophobic material.
8. A wiper as defined in claim 1, wherein said fibrous substrate layer comprises a meltblown material selected from the group consisting of poly(ethylene vinyl acetate), polypropylene and polyethylene.
9. A wiper as defined in claim 1, wherein said fibrous laminate layer comprises a nonwoven fabric.
10. A wiper as defined in claim 9, wherein said nonwoven fabric includes pulp fibers.
11. A wiper as defined in claim 1, wherein said anti-microbial agent comprises a chlorine dioxide-generating formulation.
12. A wiper as defined in claim 11, wherein said anti-microbial agent comprises sodium chlorate and an acid moiety.
13. A wiper as defined in claim 1, wherein said anti-microbial agent comprises a silver-containing additive.
14. A wiper as defined in claim 13, wherein said anti-microbial agent comprises silver zeolite.
15. A wiper as defined in claim 1, wherein said anti-microbial agent comprises quaternary amines.
16. A wiper as defined in claim 1, wherein said anti-microbial agent comprises a peroxide.
17. A wiper as defined in claim 1, wherein said anti-microbial agent is encapsulated to provide further control over the release of said anti-microbial agent.
18. A wiper as defined in claim 1, wherein said anti-microbial agent is polymer-encapsulated to provide further control over the release of said anti-microbial agent.
19. A wiper as defined in claim 1, wherein said wiper further comprises a surfactant.
20. A wiper as defined in claim 1, wherein said wiper further comprises a saponin.
21. A wiper as defined in claim 1, wherein said wiper further comprises a visual sensor to detect the exhaustion of said anti-microbial agent.
22. A wiper as defined in claim 1, comprising an additional fibrous laminate layer adhered to said fibrous substrate layer such that said fibrous substrate layer is positioned between two fibrous laminate layers.
23. A wiper as defined in claim 1, wherein said fibrous laminate layer has a basis weight of more than about 10 grams per square meter.
24. A wiper for disinfecting hard surfaces comprising:
a first fibrous laminate layer, said first fibrous laminate layer being capable of absorbing a liquid when contacted therewith, said first fibrous laminate layer being made from a nonwoven fabric having a basis weight of more than about 10 grams per square meter;
a second fibrous laminate layer, said second fibrous laminate layer being capable of absorbing a liquid when contacted therewith, said second fibrous laminate layer being made from a nonwoven fabric having a basis weight of more than about 10 grams per square meter;
a fibrous substrate layer, said fibrous substrate layer being positioned between and adhered to said first fibrous laminate layer and said second fibrous laminate layer, said fibrous substrate layer being hydrophobic; and an anti-microbial agent incorporated in a stabilized solid state within said fibrous substrate layer, said anti-microbial agent being capable of activation when contacted with water, said activation including the release of a portion of said anti-microbial agent into said liquid that is contained within the wiper such that an anti-microbial solution forms therefrom, the anti-microbial agent being adapted to provide that the rate of said release is such that said anti-microbial agent is released into said liquid in an amount sufficient to form an anti-microbial solution of the liquid within the wiper after said wiper has been repeatedly contacted with water.
25. A wiper as defined in claim 24, wherein said fibrous substrate layer comprises meltblown poly(ethylene vinyl acetate).
26. A wiper as defined in claim 24, wherein said anti-microbial agent comprises calcium hypochlorite.
27. A method of forming an anti-microbial wiper for disinfecting hard surfaces, said method comprising the steps of:
providing fibers that are capable of forming a web;
adding an anti-microbial agent to said fibers while said fibers are in an unsolidified state;
allowing said fibers to solidify into a fibrous web, wherein said anti-microbial agent is adhered to said fibrous web, said anti-microbial agent being capable of activation when contacted with water, said activation including the release of a portion of said anti-microbial agent into water contained in said fibrous web such that an anti-microbial solution forms therefrom after a normal rinse cycle, said anti-microbial agent being capable of forming said anti-microbial solution after numerous rinse cycles; and laminating said fibrous web containing said anti-microbial agent to a laminate layer, wherein said laminate layer is capable of absorbing a liquid when contacted therewith.
28. A method as defined in claim 27, wherein said fibers are hydrophobic.
29. A method as defined in claim 28, wherein said hydrophobic fibers comprise poly(ethylene vinyl acetate).
30. A method as defined in claim 28, wherein said fibrous web comprising meltblown hydrophobic fibers.
31 31. A wiper as defined in claim 27, wherein said laminate layer is made from a nonwoven composite fabric, said nonwoven composite fabric comprising pulp fibers.
32. A wiper having at least two layers, one of said layers being a fibrous hydrophobic sheet comprising fibers, said sheet having an anti-microbial agent bonded to said fibers with sufficient adhesion so that said anti-microbial agent will remain substantially bonded within said sheet until contacted repeatedly with a liquid, the other of said layers being an absorbent fibrous sheet laminated to said fibrous hydrophobic sheet.
33. A wiper as defined in claim 32, further comprising an additional sheet laminated to said fibrous hydrophobic sheet.
34. A wiper as defined in claim 33, wherein said additional sheet is absorbent.
35. A wiper as defined in claim 33, wherein said additional sheet is hydrophobic.
36. A wiper as defined in claim 1, wherein said substrate layer is self-adhered to said laminate layer.
37. A wiper as defined in claim 1 that will withstand at least 10 rinse cycles without substantially losing its ability to cause the liquid within the wiper after a rinse cycle to become an anti-microbial solution.
38. A wiper as defined in claim 1 that will withstand at least 20 rinse cycles without substantially losing its ability to cause the liquid within the wiper after a rinse cycle to become an anti-microbial solution.
CA2393525A 1999-12-28 2000-12-22 Controlled release anti-microbial wipe for hard surfaces Expired - Fee Related CA2393525C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US17322499P 1999-12-28 1999-12-28
US60/173,224 1999-12-28
US09/746,720 2000-12-22
US09/746,720 US6734157B2 (en) 1999-12-28 2000-12-22 Controlled release anti-microbial hard surface wiper
PCT/US2000/034930 WO2001047705A1 (en) 1999-12-28 2000-12-22 Controlled release anti-microbial wipe for hard surfaces

Publications (2)

Publication Number Publication Date
CA2393525A1 true CA2393525A1 (en) 2001-07-05
CA2393525C CA2393525C (en) 2010-09-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2393525A Expired - Fee Related CA2393525C (en) 1999-12-28 2000-12-22 Controlled release anti-microbial wipe for hard surfaces

Country Status (14)

Country Link
US (1) US6734157B2 (en)
EP (1) EP1255640B1 (en)
JP (1) JP2003527168A (en)
KR (1) KR100805588B1 (en)
CN (1) CN1414902A (en)
AT (1) ATE396038T1 (en)
AU (1) AU774686B2 (en)
BR (1) BR0016015B1 (en)
CA (1) CA2393525C (en)
DE (1) DE60038980D1 (en)
HK (1) HK1049131A1 (en)
IL (1) IL149752A0 (en)
MX (1) MXPA02006424A (en)
WO (1) WO2001047705A1 (en)

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AU2590501A (en) 2001-07-09
KR20020062993A (en) 2002-07-31
ATE396038T1 (en) 2008-06-15
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CA2393525C (en) 2010-09-14
HK1049131A1 (en) 2003-05-02
KR100805588B1 (en) 2008-02-20
US6734157B2 (en) 2004-05-11
MXPA02006424A (en) 2002-11-29
EP1255640A1 (en) 2002-11-13
CN1414902A (en) 2003-04-30
EP1255640B1 (en) 2008-05-21
WO2001047705A1 (en) 2001-07-05
US20020006887A1 (en) 2002-01-17
JP2003527168A (en) 2003-09-16
DE60038980D1 (en) 2008-07-03
IL149752A0 (en) 2002-11-10
AU774686B2 (en) 2004-07-01

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