CA2422478A1 - Fischer-tropsch process - Google Patents
Fischer-tropsch process Download PDFInfo
- Publication number
- CA2422478A1 CA2422478A1 CA002422478A CA2422478A CA2422478A1 CA 2422478 A1 CA2422478 A1 CA 2422478A1 CA 002422478 A CA002422478 A CA 002422478A CA 2422478 A CA2422478 A CA 2422478A CA 2422478 A1 CA2422478 A1 CA 2422478A1
- Authority
- CA
- Canada
- Prior art keywords
- reaction vessel
- slurry
- particles
- particle size
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
Abstract
A process for producing a liquid hydrocarbon product from hydrogen and carbon monoxide comprises: (a) providing a reaction vessel containing a slurry of particles of a particulates Fischer Tropsch catalyst in a liquid medium comprising a hydrocarbon, the particles of catalyst having a particle size range such that no more than about 10% by weight of the particles of catalyst have a particle size which lies in an upper particle size range extending up to a maximum particle size, (b) supplying hydrogen and carbon monoxide to the reaction vessel, (c) maintaining in the reaction vessel reaction conditions effective for conversion of hydrogen and carbon monoxide to a liquid hydrocarbon product by the Fischer Tropsch reaction, (d) maintaining mixing conditions in the reaction vessel sufficient to establish a circulation pattern throughout the reaction vessel including an upflowing path for slurry and a downflowing path for slurry, the upward velocity of the slurry in the upflowing slurry path being greater than about 75% of the mean downward velocity of the particles of catalyst of the upper particle size range when measured in stagant liquid medium, the reaction vessel being substantially devoid of stagnant zones wherein the catalyst particles can settle out of the slurry, (e) recovering from the reaction vessel a liquid stream comprising the liquid hydrocarbon product; and (f) recovering from the reaction vessel an offgas stream comprising methane as well as unreacted hydrogen and carbon monoxide.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0023781.8 | 2000-09-28 | ||
GBGB0023781.8A GB0023781D0 (en) | 2000-09-28 | 2000-09-28 | Process |
PCT/GB2001/004372 WO2002026667A1 (en) | 2000-09-28 | 2001-09-28 | Fischer-tropsch process |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2422478A1 true CA2422478A1 (en) | 2002-04-04 |
CA2422478C CA2422478C (en) | 2007-09-11 |
Family
ID=9900300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002422478A Expired - Fee Related CA2422478C (en) | 2000-09-28 | 2001-09-28 | Fischer-tropsch process |
Country Status (16)
Country | Link |
---|---|
US (1) | US6914083B2 (en) |
EP (1) | EP1322575B1 (en) |
JP (1) | JP5154730B2 (en) |
CN (1) | CN1246267C (en) |
AR (1) | AR030764A1 (en) |
AU (2) | AU9204501A (en) |
BR (1) | BR0114256B1 (en) |
CA (1) | CA2422478C (en) |
DZ (1) | DZ3419A1 (en) |
EA (1) | EA005789B1 (en) |
GB (1) | GB0023781D0 (en) |
GC (1) | GC0000305A (en) |
NO (1) | NO333831B1 (en) |
OA (1) | OA12371A (en) |
WO (1) | WO2002026667A1 (en) |
ZA (1) | ZA200301534B (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004088227A2 (en) * | 2003-03-28 | 2004-10-14 | Conocophillips Company | Process and apparatus for controlling flow in a multiphase reactor |
FR2870544B1 (en) * | 2004-05-19 | 2006-06-30 | Inst Francais Du Petrole | FISCHER-TROPSCH SYNTHESIS PROCESS INCLUDING IMPROVED REGULATION |
US20090100752A1 (en) * | 2004-06-26 | 2009-04-23 | Sessa John P | Device for converting carbonaceous matter into synthesis gas and associated methods |
RU2394871C2 (en) * | 2005-03-16 | 2010-07-20 | ФЬЮЭЛКОР ЭлЭлСи | Systems, methods and compositions for producing synthetic hydrocarbon compounds |
UA92006C2 (en) * | 2005-03-23 | 2010-09-27 | Юниверсити Оф Зе Витватерсренд, Йоханнесбург | Method for producing of synthesis gas |
EP1746143A1 (en) * | 2005-07-20 | 2007-01-24 | Shell Internationale Research Maatschappij B.V. | Fischer-Tropsch process |
US8026403B2 (en) | 2007-06-27 | 2011-09-27 | H R D Corporation | System and process for production of liquid product from light gas |
US8394861B2 (en) | 2007-06-27 | 2013-03-12 | Hrd Corporation | Gasification of carbonaceous materials and gas to liquid processes |
GB0800792D0 (en) * | 2008-01-16 | 2008-02-27 | Lancer Gb Llp | Liquid dispensing system |
FR2933391B3 (en) * | 2008-07-03 | 2012-02-03 | Physiques Ecp Et Chimiques | CONVERSION OF GLYCEROL TO CLEAN AND RENEWABLE LIQUID FUEL |
AU2009299343B2 (en) * | 2008-09-30 | 2013-06-06 | Cosmo Oil Co., Ltd. | Hydrocarbon compound synthesis reaction unit and operating method thereof |
US20100084350A1 (en) * | 2008-10-06 | 2010-04-08 | Jing Liu | Systems and Methods for Continuous Multiphase Reaction and Separation |
EP2485833A2 (en) * | 2009-10-09 | 2012-08-15 | Dow Global Technologies LLC | Adiabatic plug flow reactors and process for producing a chlorinated and/or fluorinated propene and higher alkene |
US8592492B2 (en) * | 2010-03-08 | 2013-11-26 | Praxair Technology, Inc. | Using fossil fuels to increase biomass-based fuel benefits |
GB201019940D0 (en) * | 2010-11-24 | 2011-01-05 | Davy Process Techn Ltd | Process |
JP5703096B2 (en) * | 2011-03-31 | 2015-04-15 | 独立行政法人石油天然ガス・金属鉱物資源機構 | Method for estimating content of fine particles in slurry and method for producing hydrocarbon oil |
PE20141999A1 (en) * | 2011-06-07 | 2014-12-24 | Sasol Technology Propietary Ltd | PROCESS FOR THE PRODUCTION OF AT LEAST ONE PRODUCT FROM AT LEAST ONE GASEOUS REAGENT IN A SUSPENSION BED |
AU2013223680B2 (en) | 2012-02-24 | 2017-03-23 | Sasol Technology (Proprietary) Limited | Fischer-tropsch synthesis |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4729981A (en) | 1981-10-13 | 1988-03-08 | Shell Internationale Research Maatschappij B.V. | ROR-activated catalyst for synthesis gas conversion |
US4624967A (en) | 1985-12-06 | 1986-11-25 | Exxon Research & Engineering Company | Fe-Co catalyst slurry system for use in alpha olefin production |
GB8623233D0 (en) | 1986-09-26 | 1986-10-29 | British Petroleum Co Plc | Syngas conversion catalyst |
US5545674A (en) | 1987-05-07 | 1996-08-13 | Exxon Research And Engineering Company | Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts |
US4874732A (en) | 1987-07-13 | 1989-10-17 | Uop | Cobalt Fischer-Tropsch catalysts having improved selectivity |
US5102851A (en) | 1988-12-28 | 1992-04-07 | Den Norske Stats Oljeselskap A.S. | Supported catalyst for hydrocarbon synthesis |
US5348982A (en) | 1990-04-04 | 1994-09-20 | Exxon Research & Engineering Co. | Slurry bubble column (C-2391) |
CA2038773C (en) | 1990-04-04 | 1999-06-08 | Kym B. Arcuri | Slurry fischer-tropsch process with co/ti02 catalyst |
CA2105940C (en) | 1992-10-05 | 2001-12-25 | Robert M. Koros | Bubble column, tube side slurry process and apparatus |
US6069179A (en) | 1993-02-24 | 2000-05-30 | Den Norske Stats Oljeselskap As | Method of conducting catalytic converter multi-phase reaction |
FR2741064B1 (en) | 1995-11-10 | 1997-12-12 | Inst Francais Du Petrole | PROCESS FOR THE CONVERSION OF SYNTHESIS GAS TO HYDROCARBONS |
US5900159A (en) | 1996-02-29 | 1999-05-04 | Shell Oil Company | Method for separating liquid from a slurry |
FR2751564B1 (en) * | 1996-07-26 | 2001-10-12 | Inst Francais Du Petrole | METHOD AND DEVICE FOR THE OPERATION OF A THREE-PHASE BUBBLE COLUMN WITH FISCHER-TROPSCH SYNTHESIS APPLICATION |
IT1283774B1 (en) | 1996-08-07 | 1998-04-30 | Agip Petroli | FISCHER-TROPSCH PROCESS WITH MULTISTAGE BUBBLE COLUMN REACTOR |
US5863856A (en) | 1997-04-22 | 1999-01-26 | Exxon Research And Engineering Company | Preparation of high activity catalysts the catalysts and their use |
US6068760A (en) | 1997-08-08 | 2000-05-30 | Rentech, Inc. | Catalyst/wax separation device for slurry Fischer-Tropsch reactor |
US6076810A (en) | 1997-10-21 | 2000-06-20 | Exxon Research And Engineering Co. | Throat and cone gas injector and gas distribution grid for slurry reactor |
US6117814A (en) | 1998-02-10 | 2000-09-12 | Exxon Research And Engineering Co. | Titania catalysts their preparation and use in fischer-tropsch synthesis |
US5973012A (en) | 1998-10-30 | 1999-10-26 | Exxon Research And Engineering Co. | Hydrocarbon synthesis catalyst slurry rejuvenation with gas disengagement (LAW 783) |
US5977192A (en) * | 1998-11-13 | 1999-11-02 | Exxon Research And Engineering Co. | Small catalyst particle addition to slurry reactor |
US6100304A (en) | 1999-05-26 | 2000-08-08 | Energy International Corportion | Processes and palladium-promoted catalysts for conducting Fischer-Tropsch synthesis |
-
2000
- 2000-09-28 GB GBGB0023781.8A patent/GB0023781D0/en not_active Ceased
-
2001
- 2001-09-19 AR ARP010104419A patent/AR030764A1/en not_active Application Discontinuation
- 2001-09-25 GC GCP20011640 patent/GC0000305A/en active
- 2001-09-28 EP EP01972265A patent/EP1322575B1/en not_active Expired - Lifetime
- 2001-09-28 CN CNB018157505A patent/CN1246267C/en not_active Expired - Fee Related
- 2001-09-28 OA OA1200300055A patent/OA12371A/en unknown
- 2001-09-28 CA CA002422478A patent/CA2422478C/en not_active Expired - Fee Related
- 2001-09-28 EA EA200300411A patent/EA005789B1/en not_active IP Right Cessation
- 2001-09-28 AU AU9204501A patent/AU9204501A/en active Pending
- 2001-09-28 US US10/363,417 patent/US6914083B2/en not_active Expired - Fee Related
- 2001-09-28 DZ DZ013419A patent/DZ3419A1/en active
- 2001-09-28 JP JP2002531056A patent/JP5154730B2/en not_active Expired - Fee Related
- 2001-09-28 WO PCT/GB2001/004372 patent/WO2002026667A1/en active IP Right Grant
- 2001-09-28 BR BRPI0114256-9A patent/BR0114256B1/en not_active IP Right Cessation
- 2001-09-28 AU AU2001292045A patent/AU2001292045B2/en not_active Ceased
-
2003
- 2003-02-25 ZA ZA200301534A patent/ZA200301534B/en unknown
- 2003-03-27 NO NO20031417A patent/NO333831B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1322575B1 (en) | 2012-08-08 |
US20040014825A1 (en) | 2004-01-22 |
AU2001292045B2 (en) | 2006-01-12 |
GC0000305A (en) | 2006-11-01 |
BR0114256B1 (en) | 2012-11-27 |
ZA200301534B (en) | 2004-02-25 |
NO20031417D0 (en) | 2003-03-27 |
BR0114256A (en) | 2003-12-09 |
EP1322575A1 (en) | 2003-07-02 |
OA12371A (en) | 2004-03-19 |
NO333831B1 (en) | 2013-09-30 |
CN1458914A (en) | 2003-11-26 |
JP5154730B2 (en) | 2013-02-27 |
DZ3419A1 (en) | 2002-04-04 |
CN1246267C (en) | 2006-03-22 |
GB0023781D0 (en) | 2000-11-08 |
CA2422478C (en) | 2007-09-11 |
US6914083B2 (en) | 2005-07-05 |
JP2004509935A (en) | 2004-04-02 |
NO20031417L (en) | 2003-05-27 |
WO2002026667A1 (en) | 2002-04-04 |
EA200300411A1 (en) | 2003-08-28 |
AU9204501A (en) | 2002-04-08 |
AR030764A1 (en) | 2003-09-03 |
EA005789B1 (en) | 2005-06-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2422478A1 (en) | Fischer-tropsch process | |
AU2002240450B2 (en) | Slurry catalyst rejuvenation in-situ in slurry reactor | |
CA2284939C (en) | Catalyst rejuvenation in hydrocarbon synthesis slurry with reduced slurry recontamination | |
AU2002318378B2 (en) | Direct production of high purity fischer-tropsch wax | |
CA2267569A1 (en) | Process for the preparation of hydrocarbons from synthesis gas | |
EG25400A (en) | Process for the charging of a catalyst into a reactor suitable for reactions in heterogeneous phase. | |
AU2002240450A1 (en) | Slurry catalyst rejuvenation in-situ in slurry reactor | |
AU2002318378A1 (en) | Direct production of high purity fischer-tropsch wax | |
GB0112786D0 (en) | Process | |
AU2003262193A1 (en) | Hydrocarbon synthesis process using an alkali promoted iron catalyst | |
AU2001292045A1 (en) | Fischer-tropsch process | |
CA2466009A1 (en) | Slurry hydrocarbon synthesis with external hydroisomerization in downcomer reactor loop | |
KR100975390B1 (en) | Composite reaction system for Fisher-Tropsch synthesis | |
WO2002096837A3 (en) | Fischer-tropsch process | |
ZA200209733B (en) | Fischer tropsch process. | |
RU2294913C2 (en) | Synthesis gas conversion process in sequentially connected reactors | |
WO2002096836A3 (en) | Fischer-tropsch process | |
NO20003090L (en) | Process for optimizing the production of heavy hydrocarbons in accordance with the Fisher-Tropsch process | |
CN103313786B (en) | Method for activation of chromium containing catalyst precursor for polymerization and the resulting polymerization catalyst | |
TH18206C3 (en) | Process for the preparation of hydrocarbons from synthetic gases. | |
TH48782A3 (en) | Process for the preparation of hydrocarbons from synthetic gases. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20170928 |