CA2422534A1 - Products produced from rapid thermal processing of heavy hydrocarbon feedstocks - Google Patents
Products produced from rapid thermal processing of heavy hydrocarbon feedstocks Download PDFInfo
- Publication number
- CA2422534A1 CA2422534A1 CA002422534A CA2422534A CA2422534A1 CA 2422534 A1 CA2422534 A1 CA 2422534A1 CA 002422534 A CA002422534 A CA 002422534A CA 2422534 A CA2422534 A CA 2422534A CA 2422534 A1 CA2422534 A1 CA 2422534A1
- Authority
- CA
- Canada
- Prior art keywords
- feedstock
- heat carrier
- heavy hydrocarbon
- liquid product
- simulated distillation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/28—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
- C10G9/32—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material according to the "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/06—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/28—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/301—Boiling range
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/302—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/308—Gravity, density, e.g. API
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This proce ss selectively removes metals, salts, water and nitrogen from the feedstock, while at the same time maximizes the yield of the liquid product, and minimizes coke and gas production. Furthermore, this process reduces the viscosity of the feedstock in order to permit pipeline transport, if desired , of the upgraded feedstock with little or no addition of diluents. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of th e particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence tim e of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particula te heat carrier, and collecting a gaseous and liquid product from the product stream. This invention also pertains to the products produced by the method.
Claims (5)
1. An upgraded heavy oil characterized by the following properties:
i) an API gravity from about 13 to about 23;
ii) a density at 15°C from about 0.92 g/ml to about 0.98 g/ml;
iii) a viscosity at 40°C, cSt, from about 15 to about 300;
iv) a reduced Vanadium content of about 60 to about 100 ppm; and v) a reduced Nickel content of about 10 to about 50 ppm.
i) an API gravity from about 13 to about 23;
ii) a density at 15°C from about 0.92 g/ml to about 0.98 g/ml;
iii) a viscosity at 40°C, cSt, from about 15 to about 300;
iv) a reduced Vanadium content of about 60 to about 100 ppm; and v) a reduced Nickel content of about 10 to about 50 ppm.
2. An upgraded bitumen characterized by the following properties:
i) an API gravity from about 10 to about 21;
ii) a density at 15°C from about 0.93 g/ml to about 1.0 g/ml;
iii) a viscosity at 40°C, cSt, from about 15 to about 300;
iv) a reduced Vanadium content of about 60 to about 100 ppm; and v) a reduced Nickel content of about 10 to about 50 ppm.
i) an API gravity from about 10 to about 21;
ii) a density at 15°C from about 0.93 g/ml to about 1.0 g/ml;
iii) a viscosity at 40°C, cSt, from about 15 to about 300;
iv) a reduced Vanadium content of about 60 to about 100 ppm; and v) a reduced Nickel content of about 10 to about 50 ppm.
3. A liquid product characterized in having at least one of the following properties:
i) less than 50% of the components evolving at temperatures above 538°C
during simulated distillation;
ii) from about 60% to about 95% of the product evolving below 538°
during simulated distillation;
iii) from about 1.0% to about 10% of the liquid product evolve below 193°C
during simulated distillation;
iv) from about 2% to about 6% of the liquid product evolve between 193-232°C during simulated distillation;
v) from about 10% to about 25% of the liquid product evolve between 232-327°C during simulated distillation;
vi) from about 6% to about 15% of the liquid product evolve between 327-360°C during simulated distillation; and vii) from about 34.5% to about 60% of the liquid product evolve between 360-538°C during simulated distillation.
i) less than 50% of the components evolving at temperatures above 538°C
during simulated distillation;
ii) from about 60% to about 95% of the product evolving below 538°
during simulated distillation;
iii) from about 1.0% to about 10% of the liquid product evolve below 193°C
during simulated distillation;
iv) from about 2% to about 6% of the liquid product evolve between 193-232°C during simulated distillation;
v) from about 10% to about 25% of the liquid product evolve between 232-327°C during simulated distillation;
vi) from about 6% to about 15% of the liquid product evolve between 327-360°C during simulated distillation; and vii) from about 34.5% to about 60% of the liquid product evolve between 360-538°C during simulated distillation.
4. A VGO characterised with a measured analine point from about 110°F
to about 130°F, and a calculated analine point from about 125°F to about 170°F.
to about 130°F, and a calculated analine point from about 125°F to about 170°F.
5. The VGO of claim 4, further characterized by having a hydrocarbon profile comprising about 38% mono-aromatics.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US23335400P | 2000-09-18 | 2000-09-18 | |
US60/233,354 | 2000-09-18 | ||
PCT/CA2001/001316 WO2002024835A2 (en) | 2000-09-18 | 2001-09-18 | Products produced from rapid thermal processing of heavy hydrocarbon feedstocks |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2422534A1 true CA2422534A1 (en) | 2002-03-28 |
CA2422534C CA2422534C (en) | 2012-05-22 |
Family
ID=22876886
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2422534A Expired - Fee Related CA2422534C (en) | 2000-09-18 | 2001-09-18 | Products produced from rapid thermal processing of heavy hydrocarbon feedstocks |
Country Status (13)
Country | Link |
---|---|
US (1) | US7270743B2 (en) |
EP (2) | EP2275513A3 (en) |
AR (1) | AR033838A1 (en) |
AT (1) | ATE532842T1 (en) |
AU (1) | AU2001291563A1 (en) |
BR (1) | BR0113937A (en) |
CA (1) | CA2422534C (en) |
DK (1) | DK1332199T3 (en) |
ES (1) | ES2395116T3 (en) |
MX (1) | MXPA03002341A (en) |
NO (1) | NO330786B1 (en) |
PT (1) | PT1332199E (en) |
WO (1) | WO2002024835A2 (en) |
Families Citing this family (46)
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US8105482B1 (en) * | 1999-04-07 | 2012-01-31 | Ivanhoe Energy, Inc. | Rapid thermal processing of heavy hydrocarbon feedstocks |
US8062503B2 (en) * | 2001-09-18 | 2011-11-22 | Ivanhoe Energy Inc. | Products produced from rapid thermal processing of heavy hydrocarbon feedstocks |
US7270743B2 (en) | 2000-09-18 | 2007-09-18 | Ivanhoe Energy, Inc. | Products produced form rapid thermal processing of heavy hydrocarbon feedstocks |
US7572362B2 (en) * | 2002-10-11 | 2009-08-11 | Ivanhoe Energy, Inc. | Modified thermal processing of heavy hydrocarbon feedstocks |
US7572365B2 (en) * | 2002-10-11 | 2009-08-11 | Ivanhoe Energy, Inc. | Modified thermal processing of heavy hydrocarbon feedstocks |
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US7758746B2 (en) | 2006-10-06 | 2010-07-20 | Vary Petrochem, Llc | Separating compositions and methods of use |
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-
2001
- 2001-09-18 US US09/955,267 patent/US7270743B2/en not_active Expired - Fee Related
- 2001-09-18 PT PT01971568T patent/PT1332199E/en unknown
- 2001-09-18 AR ARP010104414A patent/AR033838A1/en not_active Application Discontinuation
- 2001-09-18 EP EP10075528A patent/EP2275513A3/en not_active Withdrawn
- 2001-09-18 DK DK01971568.9T patent/DK1332199T3/en active
- 2001-09-18 AT AT01971568T patent/ATE532842T1/en active
- 2001-09-18 CA CA2422534A patent/CA2422534C/en not_active Expired - Fee Related
- 2001-09-18 ES ES01971568T patent/ES2395116T3/en not_active Expired - Lifetime
- 2001-09-18 WO PCT/CA2001/001316 patent/WO2002024835A2/en active Application Filing
- 2001-09-18 MX MXPA03002341A patent/MXPA03002341A/en active IP Right Grant
- 2001-09-18 EP EP01971568A patent/EP1332199B8/en not_active Expired - Lifetime
- 2001-09-18 AU AU2001291563A patent/AU2001291563A1/en not_active Abandoned
- 2001-09-18 BR BR0113937-1A patent/BR0113937A/en not_active IP Right Cessation
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ES2395116T3 (en) | 2013-02-08 |
EP2275513A2 (en) | 2011-01-19 |
AU2001291563A1 (en) | 2002-04-02 |
WO2002024835A2 (en) | 2002-03-28 |
AR033838A1 (en) | 2004-01-07 |
NO20031230D0 (en) | 2003-03-17 |
NO20031230L (en) | 2003-05-19 |
US7270743B2 (en) | 2007-09-18 |
EP1332199A2 (en) | 2003-08-06 |
WO2002024835A3 (en) | 2002-10-31 |
EP1332199B1 (en) | 2011-11-09 |
EP2275513A3 (en) | 2011-04-13 |
BR0113937A (en) | 2004-01-13 |
PT1332199E (en) | 2012-02-06 |
DK1332199T3 (en) | 2012-02-06 |
CA2422534C (en) | 2012-05-22 |
ATE532842T1 (en) | 2011-11-15 |
MXPA03002341A (en) | 2003-10-06 |
US20020100711A1 (en) | 2002-08-01 |
NO330786B1 (en) | 2011-07-18 |
EP1332199B8 (en) | 2012-03-14 |
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