CA2423963A1 - Method and device for producing singlet oxygen - Google Patents
Method and device for producing singlet oxygen Download PDFInfo
- Publication number
- CA2423963A1 CA2423963A1 CA002423963A CA2423963A CA2423963A1 CA 2423963 A1 CA2423963 A1 CA 2423963A1 CA 002423963 A CA002423963 A CA 002423963A CA 2423963 A CA2423963 A CA 2423963A CA 2423963 A1 CA2423963 A1 CA 2423963A1
- Authority
- CA
- Canada
- Prior art keywords
- dye
- substrate
- finely roughened
- covered
- roughened surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/127—Sunlight; Visible light
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0873—Materials to be treated
- B01J2219/0877—Liquid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
Abstract
The invention relates to a device for producing singulet oxygen, comprising a housing (1) forming a chamber which has at least two opposite surfaces. One (4) of said surfaces is transparent and the other is covered by a coating made from a dye excited by light, and a light source (3) for radiating the surface (6) coated with the dye. The surface (6) coated with the dye is formed by a substrate comprising a finely roughened surface. The dye is introduced in the indentations of the finely roughened surface by polishing. The light source can be formed by luminous diodes (3), whose light emission comprises a wavelength located within the range of maximum radiation absorption of the dye of the coated surface (6).
Claims (17)
1. A device for producing singlet oxygen, comprising a housing (1) farming a chamber which has at least two opposite surfaces, one (4) of these surfaces being transparent, whereas the other (B) is covered by a coating made from a dye exitable by light and a light source (3) for irradiating the surface (6) covered with the dye, characterized in that said surface (6) covered with the dye is formed by a substrate comprising a finely roughened surface, and in that said dye is introduced into the indentations of the finely roughened surface by polishing.
2. Device according to claim 1, characterized in that said light source is formed by light emitting diodess (3) whose light emission comprises a wavelength located within the range of maximum radiation absorption of the dye of the coated surface (6).
3. Device according to claim 1 or 2, characterized in that said dye is phthalocyanine.
4. Device according to claim 3, characterized in that the dye is green phthalocyanine.
5. Device according to claim 3, characterized in that the dye is blue phthalocyanine.
6. Device according to claim 1 or 2, characterized in that the dye is methylene blue.
7. Device according to claim 1 or 2, characterized in that the dye is rose bengal.
8. Device according to claim 1 or 2, characterized in that the dye is porphyrin (zinc tetraphenylporphyrin).
9. Device according to claim 1 or 2, characterized in that the dye is eosin,
10. Device according to any of the preceding claims, characterized in that the light emission of the light emitting diodes is located in a spectral region between about 600 nm and 680 nm.
11.Device according to any of the preceding claims, characterized in that the substrate comprises a plexiglass disc.
12.Device according to any of the claims 1 to 11, characterized in that the substrate comprises a glass disc.
13.Device according to any of the claims 1 to 11, characterized in that the substrate comprises an anodized aluminum plate.
14.A method for producing a dye coated surface for a device according to any of the preceding claims, characterized in that a substrate is provided with a finely roughened surface on which the dye is uniformly distributed and is introduced into the pores of the finely roughened surface by exerting pressure and polishing.
15.A method according to claim 14, characterized in that for uniformly distributing the dye, the dye is solved in a solvent and is is uniformly distributed on said surface within an electromagnetic field.
16.A method according to claim 14, characterized in that for uniformly distributing the dye, the substrate is electrostatically charged and exposed to a dye mist.
17.A method according to any of the claims 14 to 18, characterized in that a plastic material disc is used as substrate and is roughened by a sand blasting method.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10048153.1 | 2000-09-28 | ||
DE10048153A DE10048153A1 (en) | 2000-09-28 | 2000-09-28 | Device for generating singlet oxygen |
PCT/EP2001/011255 WO2002026621A1 (en) | 2000-09-28 | 2001-09-28 | Method and device for producing singulet oxygen |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2423963A1 true CA2423963A1 (en) | 2003-03-28 |
CA2423963C CA2423963C (en) | 2010-08-24 |
Family
ID=7658012
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2423963A Expired - Fee Related CA2423963C (en) | 2000-09-28 | 2001-09-28 | Method and device for producing singlet oxygen |
Country Status (23)
Country | Link |
---|---|
US (1) | US6991831B2 (en) |
EP (1) | EP1328469B1 (en) |
JP (1) | JP5166667B2 (en) |
KR (1) | KR100826852B1 (en) |
CN (1) | CN1190358C (en) |
AT (1) | ATE355254T1 (en) |
AU (2) | AU1499802A (en) |
BR (1) | BR0114255B1 (en) |
CA (1) | CA2423963C (en) |
CY (1) | CY1107492T1 (en) |
CZ (1) | CZ303183B6 (en) |
DE (2) | DE10048153A1 (en) |
DK (1) | DK1328469T3 (en) |
EE (1) | EE05060B1 (en) |
ES (1) | ES2283445T3 (en) |
HU (1) | HU225663B1 (en) |
IL (2) | IL155114A0 (en) |
MX (1) | MXPA03002733A (en) |
NO (1) | NO20031449L (en) |
PL (1) | PL198831B1 (en) |
PT (1) | PT1328469E (en) |
RU (1) | RU2290364C2 (en) |
WO (1) | WO2002026621A1 (en) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0424294D0 (en) * | 2004-11-03 | 2004-12-01 | Elam T Ltd | Buffer layer |
US8998884B2 (en) * | 2005-11-09 | 2015-04-07 | The Invention Science Fund I, Llc | Remote controlled in situ reaction method |
US8992511B2 (en) * | 2005-11-09 | 2015-03-31 | The Invention Science Fund I, Llc | Acoustically controlled substance delivery device |
US8273071B2 (en) * | 2006-01-18 | 2012-09-25 | The Invention Science Fund I, Llc | Remote controller for substance delivery system |
US8936590B2 (en) | 2005-11-09 | 2015-01-20 | The Invention Science Fund I, Llc | Acoustically controlled reaction device |
US7699834B2 (en) * | 2005-11-09 | 2010-04-20 | Searete Llc | Method and system for control of osmotic pump device |
US8083710B2 (en) * | 2006-03-09 | 2011-12-27 | The Invention Science Fund I, Llc | Acoustically controlled substance delivery device |
US9067047B2 (en) * | 2005-11-09 | 2015-06-30 | The Invention Science Fund I, Llc | Injectable controlled release fluid delivery system |
US7942867B2 (en) * | 2005-11-09 | 2011-05-17 | The Invention Science Fund I, Llc | Remotely controlled substance delivery device |
US20070106277A1 (en) * | 2005-11-09 | 2007-05-10 | Searete Llc, A Limited Liability Corporation Of The State Of Delaware | Remote controller for substance delivery system |
US20080140057A1 (en) | 2006-03-09 | 2008-06-12 | Searete Llc, A Limited Liability Corporation Of State Of The Delaware | Injectable controlled release fluid delivery system |
EP1852391A1 (en) * | 2006-05-02 | 2007-11-07 | Medical Biophysics GmbH | Apparatus and process for the generation of fluid activated by singlet oxygen |
JP4970542B2 (en) * | 2006-08-16 | 2012-07-11 | ノバルティス アーゲー | Temporal photobleaching of colored lens care solutions and their use |
CZ301755B6 (en) * | 2006-08-31 | 2010-06-16 | Fyzikální ústav AV CR, v.v.i. | Generation process of oxygen in singlet delta state and generator for making the same |
KR100974947B1 (en) * | 2007-07-05 | 2010-08-10 | 권기병 | A hidden Type Deck Clip and A fixd Structure of Wood Panel |
US20090043065A1 (en) * | 2007-08-07 | 2009-02-12 | Olga Khabashesku | Singlet oxygen oxidized materials and methods of making and using same |
WO2009030477A1 (en) * | 2007-09-07 | 2009-03-12 | Valkion Ab | Device for producing a singlet oxygen by irradiating a light- sensitive material |
US20090090478A1 (en) * | 2007-10-05 | 2009-04-09 | Hollomon Martha G | Selectivity improvement in oxygen delignification and bleaching of lignocellulose pulp using singlet oxygen |
KR200451912Y1 (en) * | 2009-07-31 | 2011-01-18 | 변항구 | Flour board mounting apparatus |
DE102010017892A1 (en) | 2010-04-21 | 2011-10-27 | Kirsten Klemm | Device, useful for highly efficient production of singlet oxygen in a gaseous aggregate state, comprises a housing, which forms two rooms respectively arranged at least in two opposite surfaces |
GB201018204D0 (en) | 2010-10-28 | 2010-12-15 | Soe Health Ltd | Apparatus for producing singlet oxygen |
JP5649407B2 (en) * | 2010-10-29 | 2015-01-07 | 国立大学法人長岡技術科学大学 | How to generate singlet oxygen |
DE102011015344A1 (en) * | 2011-03-28 | 2012-10-04 | Krones Aktiengesellschaft | Method and device for sterilizing packaging materials |
CN103323564B (en) * | 2013-06-28 | 2015-01-14 | 北京大学 | Research device for generating singlet oxygen through natural organic matter, and control method of research device |
DE102013220210A1 (en) | 2013-10-07 | 2015-04-09 | Lr Health & Beauty Systems Gmbh | Apparatus and method for generating singlet oxygen |
JP2018502807A (en) * | 2014-11-20 | 2018-02-01 | ゼット5 グローバル グループ リミテッド | Production of oxidants |
GB201500512D0 (en) | 2015-01-13 | 2015-02-25 | Soe Health Ltd | Therapeutic treatment methods, and apparatus for use therein |
CN112062094A (en) * | 2020-09-03 | 2020-12-11 | 自然空气能量解决方案有限公司 | Singlet oxygen preparation device and singlet oxygen preparation method |
DE102020213665A1 (en) | 2020-10-30 | 2022-05-05 | Verein zur Förderung von Innovationen durch Forschung, Entwicklung und Technologietransfer e.V. (Verein INNOVENT e.V.) | Surface element and device for generating singlet oxygen |
EP4098307A1 (en) | 2021-06-03 | 2022-12-07 | Hellstern Stiftung | Device and method for preparing and providing singlet oxygen in the treatment process |
DE102021114704B3 (en) * | 2021-06-08 | 2022-09-08 | Jassen - Kunststoffzentrum Gmbh - Apparatebau, Zuschnitte Und Formung | Apparatus and method for converting ammonia from an aqueous liquid containing ammonia into molecular nitrogen |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3795443A (en) * | 1968-08-26 | 1974-03-05 | Xerox Corp | Xerographic development |
DE2826363C2 (en) * | 1978-06-16 | 1984-08-16 | Merck Patent Gmbh, 6100 Darmstadt | Cover sheet for use in microscopic dyeing processes and processes for their manufacture |
US4579837A (en) * | 1984-10-22 | 1986-04-01 | Kms Fusion, Inc. | Solid phase photosensitizer for generation of singlet oxygen |
JP2725312B2 (en) * | 1988-10-14 | 1998-03-11 | 大日本インキ化学工業株式会社 | Porous hollow fiber membrane type gas-liquid contactor |
US4921589A (en) * | 1988-12-20 | 1990-05-01 | Allied-Signal Inc. | Polysiloxane bound photosensitizer for producing singlet oxygen |
JPH08273687A (en) * | 1995-03-30 | 1996-10-18 | Mazda Motor Corp | Supply gas humidifier of fuel cell |
NO304735B1 (en) * | 1996-02-07 | 1999-02-08 | Singlet Oxygen Technologies As | Apparatus for providing a singlet oxygen-activated oxygen-containing gas stream |
JPH09249811A (en) * | 1996-03-18 | 1997-09-22 | Toyo Ink Mfg Co Ltd | Curable resin composition, varnish and printing ink using the same |
US5698161A (en) | 1996-08-26 | 1997-12-16 | Michigan Critical Care Consultants, Inc. | Hollow, multi-dimensional array membrane |
DE19835457A1 (en) * | 1998-08-05 | 2000-02-17 | Fraunhofer Ges Forschung | Device for the photoactivated production of singlet oxygen and method for producing the device |
DE19835456C1 (en) * | 1998-08-05 | 1999-10-28 | Fraunhofer Ges Forschung | Apparatus to generate local singlet oxygen for cancer therapy |
JP4026037B2 (en) * | 1998-09-10 | 2007-12-26 | 大日本インキ化学工業株式会社 | Hollow fiber membrane gas-liquid gas exchange device and gas exchange method thereof |
JP2001216986A (en) * | 2000-01-31 | 2001-08-10 | Honda Motor Co Ltd | Humidifying system for fuel cell |
-
2000
- 2000-09-28 DE DE10048153A patent/DE10048153A1/en not_active Withdrawn
-
2001
- 2001-09-28 CN CNB018164552A patent/CN1190358C/en not_active Expired - Fee Related
- 2001-09-28 PL PL361202A patent/PL198831B1/en not_active IP Right Cessation
- 2001-09-28 KR KR1020037004491A patent/KR100826852B1/en not_active IP Right Cessation
- 2001-09-28 CZ CZ20030903A patent/CZ303183B6/en not_active IP Right Cessation
- 2001-09-28 WO PCT/EP2001/011255 patent/WO2002026621A1/en active IP Right Grant
- 2001-09-28 BR BRPI0114255-0A patent/BR0114255B1/en not_active IP Right Cessation
- 2001-09-28 HU HU0301221A patent/HU225663B1/en not_active IP Right Cessation
- 2001-09-28 DE DE50112131T patent/DE50112131D1/en not_active Expired - Lifetime
- 2001-09-28 AU AU1499802A patent/AU1499802A/en active Pending
- 2001-09-28 AT AT01983512T patent/ATE355254T1/en active
- 2001-09-28 IL IL15511401A patent/IL155114A0/en active IP Right Grant
- 2001-09-28 MX MXPA03002733A patent/MXPA03002733A/en active IP Right Grant
- 2001-09-28 US US10/381,759 patent/US6991831B2/en not_active Expired - Lifetime
- 2001-09-28 DK DK01983512T patent/DK1328469T3/en active
- 2001-09-28 PT PT01983512T patent/PT1328469E/en unknown
- 2001-09-28 RU RU2003112214/15A patent/RU2290364C2/en not_active IP Right Cessation
- 2001-09-28 JP JP2002530412A patent/JP5166667B2/en not_active Expired - Fee Related
- 2001-09-28 ES ES01983512T patent/ES2283445T3/en not_active Expired - Lifetime
- 2001-09-28 EP EP01983512A patent/EP1328469B1/en not_active Expired - Lifetime
- 2001-09-28 CA CA2423963A patent/CA2423963C/en not_active Expired - Fee Related
- 2001-09-28 AU AU2002214998A patent/AU2002214998B2/en not_active Ceased
- 2001-09-28 EE EEP200300120A patent/EE05060B1/en not_active IP Right Cessation
-
2003
- 2003-03-27 IL IL155114A patent/IL155114A/en not_active IP Right Cessation
- 2003-03-28 NO NO20031449A patent/NO20031449L/en not_active Application Discontinuation
-
2007
- 2007-05-29 CY CY20071100721T patent/CY1107492T1/en unknown
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20180928 |
|
MKLA | Lapsed |
Effective date: 20180928 |