CA2433324A1 - Hydroprocessing catalyst and use thereof - Google Patents
Hydroprocessing catalyst and use thereof Download PDFInfo
- Publication number
- CA2433324A1 CA2433324A1 CA002433324A CA2433324A CA2433324A1 CA 2433324 A1 CA2433324 A1 CA 2433324A1 CA 002433324 A CA002433324 A CA 002433324A CA 2433324 A CA2433324 A CA 2433324A CA 2433324 A1 CA2433324 A1 CA 2433324A1
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- ang
- hydroprocessing
- heavy hydrocarbon
- calculated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract 16
- 229910052751 metal Inorganic materials 0.000 claims abstract 7
- 239000002184 metal Substances 0.000 claims abstract 7
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 5
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 5
- 238000000034 method Methods 0.000 claims abstract 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 3
- 238000006243 chemical reaction Methods 0.000 claims abstract 3
- 239000003921 oil Substances 0.000 claims abstract 2
- 239000011148 porous material Substances 0.000 claims abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 6
- 239000000377 silicon dioxide Substances 0.000 claims 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 230000000704 physical effect Effects 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000013049 sediment Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- B01J35/60—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
-
- B01J35/615—
-
- B01J35/635—
-
- B01J35/647—
-
- B01J35/651—
Abstract
The invention pertains to a hydroprocessing catalyst suitable for the conversion of heavy hydrocarbon oils, which comprises 7-20wt.% of Group VI metal, Calculated as trioxide, and 0.5-6 wt.% of Group VIII metal, calculated as oxide, on a carrier comprising alumina, the catalyst having a surface area of 100-180 m2/g, a total pore volume of 0.55 ml/g or more, a %PV(>200 .ANG. d) of at least 50%, a %PV(>1,000 .ANG. d) of at least 5%, a %PV(100-1,200 .ANG. d) of at least 85%, a %PV(> 4,000 .ANG. d) of 0-2%, and a %PV(> 10,000 .ANG. d) of 0-1%. The catalyst of the present invention shows improved metals and asphaltene removal, combined with appropriate sulfur, nitrogen, and Conradson carbon removal. Additionally, the catalyst shows a decrease in sediment formation and an improved conversion in ebullating bed operations. In fixed bed operation, the catalyst produces product with an improved storage stability. The invention also pertains to a process for hydroprocessing heavy hydrocarbon feeds with the catalyst according to the invention in fixed bed or ebullating bed operation.
Claims (9)
1. A hydroprocessing catalyst suitable for the conversion of heavy hydrocarbon oils comprising 7-20 wt.% of Group VI metal, calculated as trioxide, and 0.5-6 wt.% of Group VIII metal, calculated as oxide, on a carrier comprising alumina, the catalyst having the following physical properties: a surface area of 100-180 m2/g, a total pore volume of 0.55 ml/g or more, a %PV(>200 .ANG. d) of at least 50%, a %PV(>1,000 .ANG. d) of at least 5%, a %PV(100-1,200 .ANG. d) of at least 85%, a %PV(> 4,000 .ANG. d) of
2%, and a %PV(> 10,000 .ANG. d) .of 0-1 %.
2. The catalyst of claim 1 wherein the %PV(>200 .ANG. d) is 6.0-80%.
2. The catalyst of claim 1 wherein the %PV(>200 .ANG. d) is 6.0-80%.
3. The catalyst of claim 1 or 2 wherein the %PV(>1,000 .ANG. d) is 8-30%, preferably 8-25%.
4. The catalyst of any one of the preceding claims wherein the carrier consists essentially of alumina with less than 2.5 wt.% of silica, preferably less than 1.5% of silica, more preferably less than 0.5% of silica.
5. The catalyst of any one of the preceding claims wherein the Group VI
metal is molybdenum and the Group VIII metal is nickel.
metal is molybdenum and the Group VIII metal is nickel.
6. A process for the hydroprocessing of heavy hydrocarbon feeds comprising the step of bringing a heavy hydrocarbon feed into contact with a hydroprocessing catalyst according to any one of the preceding claims in the presence of hydrogen at a temperature of 350-450°C and a pressure of 5-25 MPa.
7. The process of claim 6 wherein the temperature is 400-450°C and the pressure is 14-19 MPa.
8. The process of claim 6 or 7 wherein the catalyst is in the form of an ebullating bed.
9. The process of claim 6 or 7 wherein the catalyst is in the form of a fixed bed.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001/485 | 2001-01-05 | ||
| JP2001000485A JP4638610B2 (en) | 2001-01-05 | 2001-01-05 | Hydrotreating catalyst and hydrotreating method |
| PCT/EP2001/015383 WO2002053286A2 (en) | 2001-01-05 | 2001-12-20 | Hydroprocessing catalyst and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2433324A1 true CA2433324A1 (en) | 2002-07-11 |
| CA2433324C CA2433324C (en) | 2010-02-23 |
Family
ID=18869261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2433324A Expired - Lifetime CA2433324C (en) | 2001-01-05 | 2001-12-20 | Hydroprocessing catalyst and use thereof |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7169294B2 (en) |
| EP (1) | EP1347832B1 (en) |
| JP (1) | JP4638610B2 (en) |
| KR (1) | KR100747359B1 (en) |
| CA (1) | CA2433324C (en) |
| DE (1) | DE60104901T2 (en) |
| PL (1) | PL202786B1 (en) |
| SK (1) | SK286585B6 (en) |
| TW (1) | TW587958B (en) |
| WO (1) | WO2002053286A2 (en) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8012343B2 (en) | 2002-12-06 | 2011-09-06 | Frans Lodewijk Plantenga | Heavy feed HPC process using a mixture of catalysts |
| US7648625B2 (en) | 2003-12-19 | 2010-01-19 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| CN1997724B (en) * | 2004-06-17 | 2012-07-04 | 埃克森美孚研究工程公司 | Catalyst combination and two-step hydroprocessing method for heavy hydrocarbon oil |
| CA2601124C (en) * | 2005-03-24 | 2013-12-17 | Idemitsu Kosan Co., Ltd. | Desulfurizing agent and method of desulfurization with the same |
| MXPA05012893A (en) | 2005-11-29 | 2007-11-23 | Mexicano Inst Petrol | Catalyst for the hydrodesulfurization of residues and heavy crudes. |
| JP2008093493A (en) * | 2006-10-05 | 2008-04-24 | Idemitsu Kosan Co Ltd | Demetallization catalyst and method for hydrotreating heavy oil by using the same |
| JP4805211B2 (en) * | 2007-05-28 | 2011-11-02 | コスモ石油株式会社 | Heavy hydrocarbon oil hydrotreating catalyst, method for producing the same, and hydrotreating method |
| MX2007009504A (en) | 2007-08-07 | 2009-02-06 | Mexicano Inst Petrol | Catalyst for the first stage of hydro demetallization in a hydro processing system with multiple reactors for the improvement of heavy and extra-heavy crudes. |
| EP2203250B1 (en) * | 2007-10-19 | 2015-04-08 | Shell Internationale Research Maatschappij B.V. | Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation |
| CA2806585C (en) * | 2010-08-13 | 2020-03-24 | Alexei Grigorievich Gabrielov | A hydroprocessing catalyst prepared with waste catalyst fines and its use |
| US9376637B2 (en) * | 2010-08-13 | 2016-06-28 | Shell Oil Company | Method of making a hydroprocessing catalyst with a single step metal and chelant incorporation, the catalyst, and the use of the catalyst |
| EP2603318B1 (en) * | 2010-08-13 | 2020-05-13 | Shell Oil Company | A chelant and polar additive containing composition for hydroprocessing of hydrocarbon feedstocks |
| US20120264953A1 (en) * | 2011-04-14 | 2012-10-18 | Basf Se | Zinc-comprising catalyst for preparing ethylene oxide |
| CN103608106B (en) * | 2011-04-14 | 2016-03-09 | 巴斯夫欧洲公司 | For the preparation of ethylene oxide containing zinc catalyst |
| RU2624024C2 (en) * | 2011-09-01 | 2017-06-30 | Адванст Рифайнинг Текнолоджиз Ллк | Catalyst carrier and catalysts, obtained on its basis |
| TWI666310B (en) * | 2013-03-15 | 2019-07-21 | Advanced Refining Technologies Llc | Catalyst compositions, process for hydrotreating heavy hydrocarbon fractions, and process of preparing precipitated alumina compositions |
| US10137436B2 (en) * | 2013-09-27 | 2018-11-27 | Cosmo Oil Co., Ltd. | Hydrogenation catalyst for heavy hydrocarbon oil and hydrogenation method for heavy hydrocarbon oil |
| EP3050623B1 (en) | 2013-09-27 | 2021-01-27 | Cosmo Oil Co., Ltd. | Hydrogenation catalyst for heavy hydrocarbon oil, production method for hydrogenation catalyst for heavy hydrocarbon oil, and hydrogenation method for heavy hydrocarbon oil |
| CN105579135B (en) * | 2013-10-11 | 2018-12-21 | 克斯莫石油株式会社 | Hydrotreating catalyst, the manufacturing method of the hydrotreating catalyst of heavy hydrocarbon oil and the hydrotreating method of heavy hydrocarbon oil of heavy hydrocarbon oil |
| FR3022157B1 (en) | 2014-06-13 | 2017-09-01 | Ifp Energies Now | BIMODAL CATALYST WITH COMALATED ACTIVE PHASE, PROCESS FOR PREPARING THE SAME, AND USE THEREOF IN HYDROTREATMENT OF RESIDUES |
| FR3022158B1 (en) | 2014-06-13 | 2018-02-23 | IFP Energies Nouvelles | MESOPOROUS CATALYST OF RESIDUAL HYDROCONVERSION AND METHOD OF PREPARATION |
| FR3022159B1 (en) | 2014-06-13 | 2018-04-27 | IFP Energies Nouvelles | MESOPOROUS AND MACROPOROUS CATALYST OF RESIDUAL HYDROCONVERSION AND METHOD OF PREPARATION |
| FR3022156B1 (en) | 2014-06-13 | 2018-02-23 | Ifp Energies Now | CATALYST AND MACROPOROUS CATALYST WITH COMALATED ACTIVE PHASE, PROCESS FOR THE PREPARATION THEREOF AND USE THEREOF IN HYDROTREATMENT OF RESIDUES |
| US10054140B2 (en) | 2016-02-12 | 2018-08-21 | Crystaphase Products, Inc. | Use of treating elements to facilitate flow in vessels |
| TWI736612B (en) * | 2016-04-25 | 2021-08-21 | 荷蘭商蜆殼國際研究所 | An ebullated bed process for high conversion of heavy hydrocarbons with a low sediment yield |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| US20180230389A1 (en) | 2017-02-12 | 2018-08-16 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US11420193B2 (en) | 2017-07-21 | 2022-08-23 | Albemarle Europe Srl | Hydrotreating catalyst with a titanium containing carrier and organic additive |
| US11524278B2 (en) | 2017-07-21 | 2022-12-13 | Albemarle Europe Srl | Hydrotreating catalyst with a titanium containing carrier and sulfur containing organic additive |
| CN111744483B (en) * | 2019-03-28 | 2021-09-07 | 中国石油化工股份有限公司 | Aluminum oxide, preparation method and application thereof |
| EP4076719A1 (en) | 2019-12-20 | 2022-10-26 | Crystaphase Products Inc. | Resaturation of gas into a liquid feedstream |
| RU2724048C1 (en) * | 2019-12-24 | 2020-06-19 | Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" | Catalyst carrier for dehydrogenation of paraffin hydrocarbons in a stationary layer based on active aluminum oxide |
| TW202224768A (en) * | 2020-08-26 | 2022-07-01 | 美商先進精鍊科技有限公司 | Incorporation of boron in hydroprocessing catalysts, catalysts obtained and use thereof |
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-
2001
- 2001-01-05 JP JP2001000485A patent/JP4638610B2/en not_active Expired - Lifetime
- 2001-12-20 WO PCT/EP2001/015383 patent/WO2002053286A2/en active IP Right Grant
- 2001-12-20 EP EP01986437A patent/EP1347832B1/en not_active Expired - Lifetime
- 2001-12-20 SK SK990-2003A patent/SK286585B6/en not_active IP Right Cessation
- 2001-12-20 CA CA2433324A patent/CA2433324C/en not_active Expired - Lifetime
- 2001-12-20 PL PL366142A patent/PL202786B1/en unknown
- 2001-12-20 KR KR1020037008966A patent/KR100747359B1/en active IP Right Grant
- 2001-12-20 US US10/250,604 patent/US7169294B2/en not_active Expired - Lifetime
- 2001-12-20 DE DE60104901T patent/DE60104901T2/en not_active Expired - Lifetime
- 2001-12-31 TW TW090133471A patent/TW587958B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002053286A2 (en) | 2002-07-11 |
| EP1347832B1 (en) | 2004-08-11 |
| SK9902003A3 (en) | 2004-01-08 |
| US7169294B2 (en) | 2007-01-30 |
| WO2002053286A3 (en) | 2003-07-31 |
| KR20030080214A (en) | 2003-10-11 |
| SK286585B6 (en) | 2009-01-07 |
| DE60104901D1 (en) | 2004-09-16 |
| JP2002204959A (en) | 2002-07-23 |
| DE60104901T2 (en) | 2005-08-11 |
| US20040050754A1 (en) | 2004-03-18 |
| JP4638610B2 (en) | 2011-02-23 |
| KR100747359B1 (en) | 2007-08-07 |
| PL202786B1 (en) | 2009-07-31 |
| TW587958B (en) | 2004-05-21 |
| EP1347832A2 (en) | 2003-10-01 |
| CA2433324C (en) | 2010-02-23 |
| PL366142A1 (en) | 2005-01-24 |
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