CA2438265A1 - Dual-ovenable heat-sealable packaging film - Google Patents

Dual-ovenable heat-sealable packaging film Download PDF

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Publication number
CA2438265A1
CA2438265A1 CA 2438265 CA2438265A CA2438265A1 CA 2438265 A1 CA2438265 A1 CA 2438265A1 CA 2438265 CA2438265 CA 2438265 CA 2438265 A CA2438265 A CA 2438265A CA 2438265 A1 CA2438265 A1 CA 2438265A1
Authority
CA
Canada
Prior art keywords
film
layer
heat
polyamides
nylon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA 2438265
Other languages
French (fr)
Other versions
CA2438265C (en
Inventor
Arthur Leroy Berrier
Cynthia Louise Ebner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cryovac LLC
Original Assignee
Cryovac LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cryovac LLC filed Critical Cryovac LLC
Publication of CA2438265A1 publication Critical patent/CA2438265A1/en
Application granted granted Critical
Publication of CA2438265C publication Critical patent/CA2438265C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/34Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package
    • B65D81/3446Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package specially adapted to be heated by microwaves
    • B65D81/3461Flexible containers, e.g. bags, pouches, envelopes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1379Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1379Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • Y10T428/1383Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31725Of polyamide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31725Of polyamide
    • Y10T428/31728Next to second layer of polyamide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31725Of polyamide
    • Y10T428/31728Next to second layer of polyamide
    • Y10T428/31732At least one layer is nylon type

Abstract

A dual ovenable film having a first layer comprising one or more polyamides and a second layer comprising one or more polyamides. The first layer forms the first outer surface of the film. The second layer has a melting point of at least about 210°C. The film is capable of forming a water-containing package by providing two 4 inch by 6 inch sheets of the film each having four perimeter sides, placing the sheets in superimposed, coextensive arrangement having the first layers of the films in contact with each other, and heat sealing three perimeter sides of the sheets together using a 1/8-inch wide sealing bar at a temperature o~ 290°F, a dwell time of 0.5 seconds, and a sealing pressure of 40 psig to form an open pouch having heat seals along three of the four perimeter sides, The open pouch can be filled with 100 milliliters of distilled water at a temperature of 73°F and the fourth perimeter side of the sheet can be heat sealed together under the same conditions as used to seal the three perimeter sides to form a closed package having a heat seal along the fourth perimeter side and containing the water. The seal strength of the resulting heat seals is at least 1 pound/inch after the closed, water-containing package has been exposed to three hours in a conventional oven at 400°F (air temperature). The film may be used to form heat sealed pouches at "polyolefin-type" of heat seat conditions, yet the integrity of the heat seals may be maintained even when the heat seal is exposed to conventional oven conditions.

Claims (30)

1. ~A film comprising:
a first layer comprising one or more polyamides; and a second layer comprising one or more polyamides, wherein the second layer has a melting point of at least about 210°C;
wherein;
the film has first and second opposite outer surfaces and the first layer forms the first outer surface of the film; and the film is capable of forming a water-containing package by providing two 4 inch by 6 inch sheets of the film each having four perimeter sides, placing the sheets in superimposed, coextensive arrangement having the first layers of the films in contact with each other, heat sealing three perimeter sides of the sheets together using a 1/8-inch wide sealing bar at a temperature of 290°F, a dwell tune of 0.5 seconds, and a sealing pressure of 40 psig to form an open pouch having heat seals along three of the four perimeter sides, filling the open pouch with 100 milliliters of distilled water at a temperature of 73°F, heat sealing the fourth perimeter sides of the sheets together under the same conditions as used to seal the three perimeter sides to form a closed package having a heat seal along the fourth perimeter side and containing the water, where the seal strength of the heat seals is at least 1 pound/inch after the closed, water-containing package has been exposed to three hours in a conventional oven at 400°F (air temperature).
2. ~The film of claim 1 wherein the sealing bar has a temperature of 300°F.
3. ~The film of claim 1 wherein the first lager has a melting point and the melting point of the second layer is at least about 20°F greater than the melting point of the first layer.
4. ~The film of claim 1 wherein the first layer comprises at least two polyamides.
5. ~The film of claim 1 wherein the first layer has a glass transition temperature of less than about 120°C measured at a 50% relative humidity.
6. ~The film of claim 1 wherein the first layer comprises at least 70% by weight of the first layer of a blend comprising one or more polyamides having a melting point of at least about 210°C and one or more polyamides having a melting point of less than about 210°C.
7. ~The film of claim 6 wherein the blend comprises at least about 50% by weight of the blend of the one or more polyamides having a melting point of less than about 210°C.
8. ~The film of claim 1 wherein the first layer comprises at least 20%
amorphous polyamide by weight of the first layer.
9. ~The film of claim 1 wherein the first layer comprises at least about 80%
of one or more polyamides by weight of the first layer.
10. ~The film of claim 1 wherein the first layer comprises less than about 50%
of the total thickness of the film.
11. ~The film of claim 1 wherein the first layer comprises two or more polyamides selected from nylon-6, nylon-6,6, nylon-6,6,6,10, nylon-6,12, and nylon-6,1/6,T.
12. ~The film of claim 1 wherein the first layer comprises nylon-6, nylon-6,6/6,10, and nylon-6,1/6,T.
13, ~The film of claim 1 wherein the second layer comprises at least about 50%
of the total thickness of the film.
14. ~The film of claim 1 wherein the second layer comprises at least about 80%
of one or more polyamides by weight of the second layer.
15. ~The film of claim 1 wherein the second layer comprises one or more polyamides selected from nylon-6, nylon-6,6, and nylon 6/6,6.
16. The film of claim 1 wherein the second layer forms the second outer surface of the film.
17. The film of claim 1 wherein the film is capable of forming a heat seal having a seal strength of at least about 4 lbf-in where the heat seal is formed by heat sealing the first layers of two sheets of the film together using a 1/8-inch wide sealing bar at a temperature of 300°F, a dwell time of 0.5 seconds, and a sealing pressure of 40 psig.
18. ~The film of claim 1 wherein the haze of the film after two hours of exposure to air temperature of 400°F in a conventional oven is less than about 20%.
19. ~The film of claim 1 wherein the first layer comprises one or more heat stabilizers.
20. ~The film of claim 1 wherein the film comprises less than about 20% of polyolefin by weight of the film.
21. ~The film of claim 1 wherein the film is substantially free of polyolefin.
22, ~The film of claim 1 wherein the film comprises less than about 20%
polyester by weight of the film.
23. ~The film of claim 1 wherein the film, is substantially free of polyester,
24. ~A packaged food comprising:
a food; and a package enclosing the food, wherein the package comprises the film of claim 1.
25. ~The film of claim 1 wherein the film comprises a third layer comprising ethylene/vinyl alcohol.
26, ~The film of claim 1 wherein the first layer consists essentially of one or more polyamides.
27. ~The film of claim 1 wherein the melting point of the first layer is less than about 220°C.
28. ~The film of claim 1 wherein the film has an oxygen transmission rate of no more than about 150 cubic centimeters (at standard temperature and pressure) per square meter per day per 1 atmosphere of oxygen pressure differential measured at 0% relative humidity and 23°C.
29. The film of claim 1 wherein the film comprises at least about 70 weight %
polyamide by weight of the film.
30. ~A method of heating a food comprising:
providing a food enclosed an a package comprising the film of claim 1;
placing the food enclosed in the package in an oven; and activating the oven to heat the food enclosed in the package to a desired level.
CA 2438265 2002-08-27 2003-08-26 Dual-ovenable heat-sealable packaging film Expired - Lifetime CA2438265C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/228,515 2002-08-27
US10/228,515 US6979494B2 (en) 2002-08-27 2002-08-27 Dual-ovenable, heat-sealable packaging film

Publications (2)

Publication Number Publication Date
CA2438265A1 true CA2438265A1 (en) 2004-02-27
CA2438265C CA2438265C (en) 2012-08-07

Family

ID=31495344

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2438265 Expired - Lifetime CA2438265C (en) 2002-08-27 2003-08-26 Dual-ovenable heat-sealable packaging film

Country Status (6)

Country Link
US (2) US6979494B2 (en)
EP (1) EP1393897B1 (en)
AU (1) AU2003236479B2 (en)
CA (1) CA2438265C (en)
ES (1) ES2424479T3 (en)
NZ (1) NZ527620A (en)

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US6979494B2 (en) 2005-12-27
US20060088678A1 (en) 2006-04-27
NZ527620A (en) 2005-03-24
ES2424479T3 (en) 2013-10-02
EP1393897A3 (en) 2004-06-02
AU2003236479B2 (en) 2008-04-17
EP1393897A2 (en) 2004-03-03
CA2438265C (en) 2012-08-07
US20040043233A1 (en) 2004-03-04
AU2003236479A1 (en) 2004-03-18
US7504158B2 (en) 2009-03-17
EP1393897B1 (en) 2013-07-10

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