CA2460156A1 - Surfactant-free cleaning compositions and processes for the use thereof - Google Patents
Surfactant-free cleaning compositions and processes for the use thereof Download PDFInfo
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- CA2460156A1 CA2460156A1 CA002460156A CA2460156A CA2460156A1 CA 2460156 A1 CA2460156 A1 CA 2460156A1 CA 002460156 A CA002460156 A CA 002460156A CA 2460156 A CA2460156 A CA 2460156A CA 2460156 A1 CA2460156 A1 CA 2460156A1
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- 239000000203 mixture Substances 0.000 title claims abstract 57
- 238000004140 cleaning Methods 0.000 title claims abstract 33
- 238000000034 method Methods 0.000 title claims abstract 13
- 239000000835 fiber Substances 0.000 claims abstract 4
- 239000003205 fragrance Substances 0.000 claims 16
- 239000002253 acid Substances 0.000 claims 13
- 229920001577 copolymer Polymers 0.000 claims 12
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 12
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 12
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 12
- 239000003513 alkali Substances 0.000 claims 11
- -1 ammonium ions Chemical class 0.000 claims 11
- 150000002500 ions Chemical class 0.000 claims 11
- 239000002738 chelating agent Substances 0.000 claims 8
- 239000003795 chemical substances by application Substances 0.000 claims 8
- 239000002270 dispersing agent Substances 0.000 claims 8
- 239000000463 material Substances 0.000 claims 8
- 239000002904 solvent Substances 0.000 claims 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 7
- 239000003755 preservative agent Substances 0.000 claims 7
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims 6
- 229920002125 Sokalan® Polymers 0.000 claims 6
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims 6
- 239000004584 polyacrylic acid Substances 0.000 claims 6
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims 6
- 235000007586 terpenes Nutrition 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 5
- 150000003505 terpenes Chemical class 0.000 claims 4
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 claims 3
- WBTIFBJEYFLFFW-UHFFFAOYSA-N 2-(hydroxymethylazaniumyl)acetate Chemical compound OCNCC(O)=O WBTIFBJEYFLFFW-UHFFFAOYSA-N 0.000 claims 3
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims 3
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims 3
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims 3
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims 3
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 claims 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims 3
- XPJVKCRENWUEJH-UHFFFAOYSA-N Isobutylparaben Chemical compound CC(C)COC(=O)C1=CC=C(O)C=C1 XPJVKCRENWUEJH-UHFFFAOYSA-N 0.000 claims 3
- CMHMMKSPYOOVGI-UHFFFAOYSA-N Isopropylparaben Chemical compound CC(C)OC(=O)C1=CC=C(O)C=C1 CMHMMKSPYOOVGI-UHFFFAOYSA-N 0.000 claims 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims 3
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims 3
- 229920000805 Polyaspartic acid Polymers 0.000 claims 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 3
- 150000001298 alcohols Chemical class 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims 3
- 229940067596 butylparaben Drugs 0.000 claims 3
- 229910001424 calcium ion Inorganic materials 0.000 claims 3
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims 3
- SOROIESOUPGGFO-UHFFFAOYSA-N diazolidinylurea Chemical compound OCNC(=O)N(CO)C1N(CO)C(=O)N(CO)C1=O SOROIESOUPGGFO-UHFFFAOYSA-N 0.000 claims 3
- 229960001083 diazolidinylurea Drugs 0.000 claims 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 3
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 claims 3
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 claims 3
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims 3
- 229940071206 hydroxymethylglycinate Drugs 0.000 claims 3
- 229940080260 iminodisuccinate Drugs 0.000 claims 3
- 229940113094 isopropylparaben Drugs 0.000 claims 3
- 229910001425 magnesium ion Inorganic materials 0.000 claims 3
- 239000011976 maleic acid Substances 0.000 claims 3
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims 3
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims 3
- 229960002216 methylparaben Drugs 0.000 claims 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims 3
- 229960005323 phenoxyethanol Drugs 0.000 claims 3
- 108010064470 polyaspartate Proteins 0.000 claims 3
- 229910001414 potassium ion Inorganic materials 0.000 claims 3
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims 3
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 claims 3
- 229960003415 propylparaben Drugs 0.000 claims 3
- 229910001415 sodium ion Inorganic materials 0.000 claims 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 3
- 229940117958 vinyl acetate Drugs 0.000 claims 3
- KIDJHPQACZGFTI-UHFFFAOYSA-N [6-[bis(phosphonomethyl)amino]hexyl-(phosphonomethyl)amino]methylphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCCCCCN(CP(O)(O)=O)CP(O)(O)=O KIDJHPQACZGFTI-UHFFFAOYSA-N 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 2
- 239000011550 stock solution Substances 0.000 claims 2
- 239000002689 soil Substances 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- C11D2111/12—
Abstract
Surfactant-free cleaning compositions are provided for use in removing soil and stains from fiber surfaces such as carpets, upholstery and the like as well as for preventing redeposition of soil and stains on such surfaces.
Additionally, processes are provided for cleaning such soiled and/or stained fiber surfaces utilizing aqueous forms of such surfactant-free cleaning compositions having a surface tension of greater than about 38 dynes per centimeter.
Additionally, processes are provided for cleaning such soiled and/or stained fiber surfaces utilizing aqueous forms of such surfactant-free cleaning compositions having a surface tension of greater than about 38 dynes per centimeter.
Claims (33)
1. A surfactant-free cleaning composition comprising:
a) a water soluble dispersing agent;
b) a water soluble anti-redeposition agent;
c) at least one alkali counter ion;
d) a water soluble chelating agent;
e) a fragrance material; and f) a fragrance solubilizing agent; and g) a preservative agent.
a) a water soluble dispersing agent;
b) a water soluble anti-redeposition agent;
c) at least one alkali counter ion;
d) a water soluble chelating agent;
e) a fragrance material; and f) a fragrance solubilizing agent; and g) a preservative agent.
2. The surfactant-free cleaning composition of claim 1 comprising a concentrated aqueous stock solution.
3. The surfactant-free cleaning composition of claim 1 in aqueous form having a surface tension greater than about 38 dynes per centimeter.
4. The surfactant-free cleaning composition of claim 3 wherein the water-soluble dispersing agent is selected from the group consisting of polyacrylic acid; polyacrylic acid/maleic acid copolymers; polymethacrylic acid, polyaspartic acid and mixtures thereof.
5. The surfactant-free cleaning composition of claim 3 wherein the water-soluble anti-redeposition agent is selected from the group consisting of polyvinylpyrrolidone; polyvinylbetaine; polyvinyl pyrrolidone/vinylacetate copolymers; polyvinylpyrrolidone/dimethylaminoethylmethacrylate copolymers;
polyvinylpyrrolidone/acrylic acid copolymers; polymethylvinylether/maleic anhydride copolymers; polyvinylpyridine-n-oxide and mixtures thereof.
polyvinylpyrrolidone/acrylic acid copolymers; polymethylvinylether/maleic anhydride copolymers; polyvinylpyridine-n-oxide and mixtures thereof.
6. The surfactant-free cleaning composition of claim 3 wherein the alkali counter ion is selected from the group consisting of sodium ions, potassium ions, calcium ions, magnesium ions, ammonium ions and amine ions and mixtures thereof.
7. The surfactant-free cleaning composition of claim 3 wherein the water soluble chelating agent is selected from the group consisting of ethylenediaminetetraacetic acid; diethylenediaminepentaacetic acid;
nitrilotriacetic acid; hydroxyethylenediaminetriacetic acid; iminodisuccinate acid;
aminotrismethylenephosphonic acid;
hexamethylenediaminetetramethylenephosphonic acid;
diethylenetriaminepentamethylene-phosphonic acid and mixtures thereof.
nitrilotriacetic acid; hydroxyethylenediaminetriacetic acid; iminodisuccinate acid;
aminotrismethylenephosphonic acid;
hexamethylenediaminetetramethylenephosphonic acid;
diethylenetriaminepentamethylene-phosphonic acid and mixtures thereof.
8. The surfactant-free cleaning composition of claim 3 wherein the fragrance material is selected from the group consisting of terpene compounds, oxygenated terpene derivatives, oxygenated aromatic derivatives and mixtures thereof.
9. The surfactant-free cleaning composition of claim 3 wherein the fragrance solubilizing agent is selected from the group consisting of alcohols, glycol ethers and glycol ether esters of glycol and mixtures thereof.
10. The surfactant-free cleaning composition of claim 3 wherein the amount of alkali counter ion present in the cleaning composition is sufficient to maintain a pH range of about 5.0 to about 12.0 in the aqueous composition.
11. The surfactant-free cleaning composition of claim 3 wherein the preservative agent is selected from the group consisting of 1,3-dihydroxymethyl-5-5-dimethylhydantoin (DMDM Hydantoin); 1,2-benzisothiazolin-3-one; 5-chloro-2-methyl-4-isothiazolin-3-one; 2-methyl-4-isothiazolin-3-one; 3-iodo-2-propynyl butyl carbamate; phenoxyethanol; 2-bromo-2-nitropropane-1,3-diol;
methyl paraben; propyl paraben; isopropyl paraben; butyl paraben; isobutyl paraben; diazolidinyl urea and hydroxymethylglycinate and mixtures thereof.
methyl paraben; propyl paraben; isopropyl paraben; butyl paraben; isobutyl paraben; diazolidinyl urea and hydroxymethylglycinate and mixtures thereof.
12. An aqueous, surfactant-free cleaning composition having a surface tension of greater than about 38 dynes per centimeter comprising:
a) a water-soluble polymeric dispersing agent; and b) a water-soluble polymeric anti-redeposition agent; and c) an alkali counter ion; and d) optionally, a chelating agent; and e) optionally, a fragrance material; and f) optionally, a fragrance solubilizing agent; and g) optionally a preservative agent.
a) a water-soluble polymeric dispersing agent; and b) a water-soluble polymeric anti-redeposition agent; and c) an alkali counter ion; and d) optionally, a chelating agent; and e) optionally, a fragrance material; and f) optionally, a fragrance solubilizing agent; and g) optionally a preservative agent.
13. The surfactant-free cleaning composition of claim 12 wherein the water-soluble dispersing agent is selected from the group consisting of polyacrylic acid; polyacrylic acid/maleic acid copolymers; polymethacrylic acid, polyaspartic acid and mixtures thereof.
14. The surfactant-free cleaning composition of claim 12 wherein the water-soluble anti-redeposition agent is selected from the group consisting of polyvinylpyrrolidone; polyvinylbetaine; polyvinyl pyrrolidone/vinylacetate copolymers; polyvinylpyrrolidone/dimethylaminoethylmethacrylate copolymers;
polyvinylpyrrolidone/acrylic acid copolymers; polymethylvinylether/maleic anhydride copolymers; polyvinylpyridine-n-oxide and mixtures thereof.
polyvinylpyrrolidone/acrylic acid copolymers; polymethylvinylether/maleic anhydride copolymers; polyvinylpyridine-n-oxide and mixtures thereof.
15. The surfactant-free cleaning composition of claim 12 wherein the alkali counter ion is selected from the group consisting of sodium ions, potassium ions, calcium ions, magnesium ions, ammonium ions and amine ions and mixtures thereof.
16. The surfactant-free cleaning composition of claim 12 wherein the water soluble chelating agent is selected from the group consisting of ethylenediaminetetraacetic acid; diethylenediaminepentaacetic acid;
nitrilotriacetic acid; hydroxyethylenediaminetriacetic acid; iminodisuccinate acid;
aminotrismethylenephosphonic acid;
hexamethylenediaminetetramethylenephosphonic acid;
diethylenetriaminepentamethylene-phosphonic acid and mixtures thereof.
nitrilotriacetic acid; hydroxyethylenediaminetriacetic acid; iminodisuccinate acid;
aminotrismethylenephosphonic acid;
hexamethylenediaminetetramethylenephosphonic acid;
diethylenetriaminepentamethylene-phosphonic acid and mixtures thereof.
17. The surfactant-free cleaning composition of claim 12 wherein the fragrance material is selected from the group consisting of terpene compounds, oxygenated terpene derivatives, oxygenated aromatic derivatives and the like and mixtures thereof.
18. The surfactant-free cleaning composition of claim 12 wherein the fragrance solubilizing agent is selected from the group consisting of alcohols, glycol ethers, glycol ether esters of glycol and mixtures thereof.
19. The surfactant-free cleaning composition of claim 12 wherein the amount of alkali counter ion present in the cleaning composition is sufficient to maintain a pH range of about 5.0 to about 12.0 in the aqueous composition.
20. The surfactant-free cleaning composition of claim 12 wherein the preservative agent is selected from the group consisting of 1,3-dihydroxymethyl-5-5-dimethylhydantoin (DMDM Hydantoin); 1,2-benzisothiazolin-3-one; 5-chloro-2-methyl-4-isothiazolin-3-one; 2-methyl-4-isothiazolin-3-one; 3-iodo-2-propynyl butyl carbamate; phenoxyethanol; 2-bromo-2-nitropropane-1,3-diol;
methyl paraben; propyl paraben; isopropyl paraben; butyl paraben; isobutyl paraben; diazolidinyl urea and hydroxymethylglycinate and mixtures thereof.
methyl paraben; propyl paraben; isopropyl paraben; butyl paraben; isobutyl paraben; diazolidinyl urea and hydroxymethylglycinate and mixtures thereof.
21 An aqueous, surfactant-free cleaning composition having a surface tension of greater than about 38 dynes per centimeter comprising the following ingredients (in weight percentages per total weight of the aqueous composition):
a) 0.01 - 10.0% dispersing agent b) 0.001 - 5.0% anti-redeposition agent c) sufficient alkali counter ion to adjust the pH of the aqueous composition to about 5.0 - 12.0 d) 0.01 - 10.0% chelating agent e) 0.0001 - 2.0% fragrance material f) 0.05 - 25.0% fragrance solubilizing agent g) sufficient water to adjust the weight percent of the aqueous composition to 100%.
a) 0.01 - 10.0% dispersing agent b) 0.001 - 5.0% anti-redeposition agent c) sufficient alkali counter ion to adjust the pH of the aqueous composition to about 5.0 - 12.0 d) 0.01 - 10.0% chelating agent e) 0.0001 - 2.0% fragrance material f) 0.05 - 25.0% fragrance solubilizing agent g) sufficient water to adjust the weight percent of the aqueous composition to 100%.
22. A process for cleaning a fiber surface comprising applying an effective amount of an aqueous, surfactant-free cleaning composition having a surface tension of at least greater than 38 dynes per centimeter to a stained or soiled area on the fiber surface.
23. The process of claim 22 wherein the aqueous cleaning composition comprises:
a polymeric dispersing agent;
an anti-redeposition agent and an alkali counter ion.
a polymeric dispersing agent;
an anti-redeposition agent and an alkali counter ion.
24. The process of claim 23 wherein the aqueous cleaning composition further comprises one or more of the following ingredients:
a chelating agent;
a fragrance material;
a fragrance solubilizing agent; and a preservative agent.
a chelating agent;
a fragrance material;
a fragrance solubilizing agent; and a preservative agent.
25. The process of claim 23 wherein the dispersing agent is selected from the group consisting of polyacrylic acid; polyacrylic acid/maleic acid copolymers; polymethacrylic acid, polyaspartic acid and mixtures thereof.
26. The process of claim 23 wherein the anti-redeposition agent is selected from the group consisting of polyvinylpyrrolidone; polyvinylbetaine;
polyvinyl pyrrolidone/vinylacetate copolymers;
polyvinylpyrrolidone/dimethylaminoethylmethacrylate copolymers;
polyvinylpyrrolidone/acrylic acid copolymers; polymethylvinylether/maleic anhydride copolymers; polyvinylpyridine-n-oxide and mixtures thereof.
polyvinyl pyrrolidone/vinylacetate copolymers;
polyvinylpyrrolidone/dimethylaminoethylmethacrylate copolymers;
polyvinylpyrrolidone/acrylic acid copolymers; polymethylvinylether/maleic anhydride copolymers; polyvinylpyridine-n-oxide and mixtures thereof.
27. The process of claim 23 wherein the alkali counter ion is selected from the group consisting of sodium ions, potassium ions, calcium ions, magnesium ions, ammonium ions and amine ions and mixtures thereof.
28. The process of claim 24 wherein the chelating agent is selected from the group consisting of ethylenediaminetetraacetic acid;
diethylenediaminepentaacetic acid; nitrilotriacetic acid;
hydroxyethylenediaminetriacetic acid; iminodisuccinate acid;
aminotrismethylenephosphonic acid;
hexamethylenediaminatetramethylenephosphonic acid;
diethylenetriaminepentamethylene-phosphonic acid and mixtures thereof.
diethylenediaminepentaacetic acid; nitrilotriacetic acid;
hydroxyethylenediaminetriacetic acid; iminodisuccinate acid;
aminotrismethylenephosphonic acid;
hexamethylenediaminatetramethylenephosphonic acid;
diethylenetriaminepentamethylene-phosphonic acid and mixtures thereof.
29. The process of claim 24 wherein the fragrance material is selected from the group consisting of terpenes, oxygenated terpene derivatives, oxygenated aromatic derivatives and the like and mixtures thereof.
30. The process of claim 24 wherein the fragrance solubilizing agent is selected from the group consisting of alcohols, glycol ethers and glycol ether esters and the like
31. The process of claim 24 wherein the amount of alkali counter ion present in the cleaning composition is sufficient to maintain a pH range of about 5.0 to about 12.0 in the aqueous composition.
32. The process of claim 24 wherein the preservative agent is selected from the group consisting of 1,3-dihydroxymethyl-5-5-dimethylhydantoin (DMDM Hydantoin); 1,2-benzisothiazolin-3-one; 5-chloro-2-methyl-4-isothiazolin-3-one; 2-methyl-4-isothiazolin-3-one; 3-iodo-2-propynyl butyl carbamate; phenoxyethanol; 2-bromo-2-nitropropane-1,3-diol; methyl paraben;
propyl paraben; isopropyl paraben; butyl paraben; isobutyl paraben;
diazolidinyl urea and hydroxymethylglycinate and mixtures thereof.
propyl paraben; isopropyl paraben; butyl paraben; isobutyl paraben;
diazolidinyl urea and hydroxymethylglycinate and mixtures thereof.
33. A concentrated aqueous stock solution for forming an aqueous, surfactant-free cleaning composition comprising:
a) a water-soluble polymeric dispersing agent; and b) a water-soluble polymeric anti-redeposition agent; and c) an alkali counter ion; and d) optionally, a chelating agent; and e) optionally, a fragrance material; and f) optionally, a fragrance solubilizing agent; and g) optionally a preservative agent.
a) a water-soluble polymeric dispersing agent; and b) a water-soluble polymeric anti-redeposition agent; and c) an alkali counter ion; and d) optionally, a chelating agent; and e) optionally, a fragrance material; and f) optionally, a fragrance solubilizing agent; and g) optionally a preservative agent.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32230801P | 2001-09-14 | 2001-09-14 | |
| US60/322,308 | 2001-09-14 | ||
| US10/078,010 US6835704B2 (en) | 2001-09-14 | 2002-02-19 | Surfactant-free cleaning compositions and processes for the use thereof |
| US10/078,010 | 2002-02-19 | ||
| PCT/US2002/019458 WO2003025107A1 (en) | 2001-09-14 | 2002-06-19 | Surfactant-free cleaning compositions and processes for the use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2460156A1 true CA2460156A1 (en) | 2003-03-27 |
| CA2460156C CA2460156C (en) | 2010-08-24 |
Family
ID=26760019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2460156A Expired - Fee Related CA2460156C (en) | 2001-09-14 | 2002-06-19 | Surfactant-free cleaning compositions and processes for the use thereof |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US6835704B2 (en) |
| CA (1) | CA2460156C (en) |
| WO (1) | WO2003025107A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10993437B2 (en) | 2013-06-18 | 2021-05-04 | Chemgreen Innovation Inc. | Anti-microbial polymer incorporating a quaternary ammonium group |
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| US8375494B2 (en) * | 2001-09-14 | 2013-02-19 | Clean Control Corporation | Cleaning compositions containing a corrosion inhibitor |
| US20050101512A1 (en) * | 2003-11-11 | 2005-05-12 | Isp Investments Inc. | Soil settling composition |
| EP1908817A4 (en) * | 2005-07-01 | 2008-08-13 | Miz Co Ltd | Method for washing clothes and detergent composition therefor |
| US7645333B2 (en) * | 2005-12-02 | 2010-01-12 | The Clorox Company | Aqueous composition and method for imparting resistance to stain absorption |
| WO2008055362A1 (en) * | 2006-11-08 | 2008-05-15 | Innovations Solutions Now Inc. | Fuel or fuel additive composition and method for its manufacture and use |
| US20080271259A1 (en) * | 2007-05-04 | 2008-11-06 | Daike Wang | Solid cleaning composition for imparting bleach resistance to textiles cleaned therewith |
| CN100450596C (en) * | 2007-06-08 | 2009-01-14 | 江南大学 | Micro-filtering or super-filtering film regenerating agent and preparing method |
| EP2031050A1 (en) * | 2007-08-29 | 2009-03-04 | Unilever N.V. | A process for cleaning fabrics |
| CN101953756B (en) * | 2010-09-10 | 2011-12-28 | 雀氏（福建）实业发展有限公司 | Wet tissue compound solution |
| WO2013060679A1 (en) * | 2011-10-27 | 2013-05-02 | Basf Se | Use of a composition containing vinyl-lactam-containing polymer, solvent and at least one halogen-free biocide as a metal-quenching medium |
| US8765001B2 (en) * | 2012-08-28 | 2014-07-01 | Rohm And Haas Electronic Materials Llc | Texturing of monocrystalline semiconductor substrates to reduce incident light reflectance |
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-
2002
- 2002-02-19 US US10/078,010 patent/US6835704B2/en not_active Expired - Lifetime
- 2002-06-19 CA CA2460156A patent/CA2460156C/en not_active Expired - Fee Related
- 2002-06-19 WO PCT/US2002/019458 patent/WO2003025107A1/en not_active Application Discontinuation
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10993437B2 (en) | 2013-06-18 | 2021-05-04 | Chemgreen Innovation Inc. | Anti-microbial polymer incorporating a quaternary ammonium group |
Also Published As
| Publication number | Publication date |
|---|---|
| US20030060384A1 (en) | 2003-03-27 |
| US20050096241A1 (en) | 2005-05-05 |
| US6835704B2 (en) | 2004-12-28 |
| CA2460156C (en) | 2010-08-24 |
| US7005013B2 (en) | 2006-02-28 |
| WO2003025107A1 (en) | 2003-03-27 |
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| Date | Code | Title | Description |
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| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20190619 |