CA2470157A1 - Antimicrobial pre-moistened wipers - Google Patents

Antimicrobial pre-moistened wipers Download PDF

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Publication number
CA2470157A1
CA2470157A1 CA002470157A CA2470157A CA2470157A1 CA 2470157 A1 CA2470157 A1 CA 2470157A1 CA 002470157 A CA002470157 A CA 002470157A CA 2470157 A CA2470157 A CA 2470157A CA 2470157 A1 CA2470157 A1 CA 2470157A1
Authority
CA
Canada
Prior art keywords
wiper
weight
sanitizing formulation
solution
exhibits
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002470157A
Other languages
French (fr)
Other versions
CA2470157C (en
Inventor
James W. Clark
Shawn E. Jenkins
Julie W. Trusock
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Kimberly Clark Worldwide Inc
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Individual
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Application filed by Individual filed Critical Individual
Publication of CA2470157A1 publication Critical patent/CA2470157A1/en
Application granted granted Critical
Publication of CA2470157C publication Critical patent/CA2470157C/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2525—Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
    • Y10T442/277—Coated or impregnated cellulosic fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Abstract

A pre-moistened wiper that exhibits good antimicrobial kill at relatively small levels of antimicrobial agent is provided. In one embodiment, for example, the wiper contains a sanitizing formulation that includes between about 0.01% by weight to about 1% by weight of an antimicrobial agent, including a quaternary ammonium compound, and water. The sanitizing formulation is capable of being released from the wiper as a solution such that the quaternary ammonium compound is present within the solution in an amount less than about 2000 parts per millionof the solution. The wiper can exhibit a log reduction for E. Coli of at least about 2.

Claims (48)

1. A wiper comprising a substrate and a sanitizing formulation applied to said substrate in an amount from about 150% to about 600% of the dry weight of the wiper, wherein said sanitizing formulation comprises water and between about 0.01 % by weight to about 1 % by weight of an antimicrobial agent that includes a quaternary ammonium compound, wherein said sanitizing formulation is capable of being released from said substrate as a solution such that said quaternary ammonium compound is present within said solution in an amount less than about 2000 parts per million of said solution, and wherein the wiper exhibits a log reduction for E. Coli of at least about 2.
2. A wiper as defined in claim 1, wherein said quaternary ammonium compound has the following formula:
wherein, R1, R2, R3, and R4 are independently selected from the group consisting of H, C1-C30 alkyl, C1-C30 alkenyl, C1-30 alkylethoxy, C1-30 alkylphenolethoxy, and combinations thereof; and A is selected from the group consisting of halogens; methosulfates, phosphates, and combinations thereof.
3. A wiper as defined in claim 1, wherein said quaternary ammonium compound has the following formula:
wherein, R is a C8-C18 alkyl group; and A is a halogen atom.
4. A wiper as defined in claim 1, wherein said antimicrobial agent comprises between about 0.01 % to about 0.4% by weight of said sanitizing formulation.
5. A wiper as defined in claim 1, wherein said antimicrobial agent comprises between about 0.1 % to about 0.4% by weight of said sanitizing formulation.
6. A wiper as defined in claim 1, wherein said sanitizing formulation further comprises a sequestrant in an amount between about 0.01 % to about 5% by weight of said sanitizing formulation.
7. A wiper as defined in claim 1, wherein said sanitizing formulation further comprises a nonionic surfactant.
8. A wiper as defined in claim 7, wherein said nonionic surfactant comprises between about 0.01 % to about 1 % by weight of said sanitizing formulation.
9. A wiper as defined in claim 1, wherein said sanitizing formulation further comprises between about 0.001 % to about 30% by weight of non-aqueous solvent.
10. A wiper as defined in claim 1, further comprising between about 0.001 % to about 5% by weight of preservative.
11. A wiper as defined in claim 1, wherein the pH of said sanitizing formulation is greater than about 8.
12. A wiper as defined in claim 1, wherein the pH of said sanitizing formulation is between about 9 to about 12.
13. A wiper as defined in claim 1, wherein the wiper exhibits a log reduction for E. Coli of at least about 3.
14. A wiper as defined in claim 1, wherein the wiper exhibits a log reduction for E. Coli of at least about 4.
15. A wiper as defined in claim 1, wherein the wiper exhibits a log reduction for E. Coli of at least about 5.
16. A wiper as defined in claim 1, wherein the wiper exhibits a log reduction for S. Aureus of at least about 2.
17. A wiper as defined in claim 1, wherein the wiper exhibits a log reduction for S. Aureus of at least about 3.
18. A wiper as defined in claim 1, wherein the wiper exhibits a log reduction for S. Aureus of at least about 4.
19. A wiper as defined in claim 1, wherein the wiper exhibits a log reduction for S. Aureus of at least about 5.
20. A wiper as defined in claim 1, wherein the wiper exhibits a Kill Efficiency Ratio of at least about 10.
21. A wiper as defined in claim 1, wherein the wiper exhibits a Kill Efficiency Ratio of at least about 100.
22. A wiper as defined in claim 1, wherein the wiper exhibits a Kill Efficiency Ratio of at least about 400.
23. A wiper as defined in claim 1, wherein the wiper exhibits an Antimicrobial Reduction of less than about 95%.
24. A wiper as defined in claim 1, wherein the wiper exhibits an Antimicrobial Reduction between about 60% to about 80%.
25. A wiper as defined in claim 1, wherein said quaternary compound is capable of being released into said solution in an amount of between about 150 to about 400 parts per million of solution.
26. A wiper as defined in claim 1, wherein said substrate is a nonwoven fabric.
27. A wiper comprising a nonwoven fabric and a sanitizing formulation applied to said nonwoven fabric in an amount from about 150% to about 600% of the dry weight of the wiper, said sanitizing formulation comprising between about 0.01 % by weight to about 0.4% by weight of at least one benzalkonium halide, wherein said sanitizing formulation is capable of being released from said nonwoven fabric into a solution such that said benzalkonium halide is present within said solution in an amount less than about 2000 parts per million of said solution, and wherein the wiper exhibits a log reduction for E. Coli and S.
Aureus of at least about 3.
28. A wiper as defined in claim 27, wherein said benzalkonium halide comprises between about 0.1 % to about 0.4% by weight of said sanitizing formulation.
29. A wiper as defined in claim 27, wherein said sanitizing formulation further comprises sequestrant in an amount between about 0.01 % to about 1.5%
by weight of said sanitizing formulation.
30. A wiper as defined in claim 27, wherein said sanitizing formulation further comprises nonionic surfactant in an amount between about 0.01 % to about 1% by weight of said sanitizing formulation.
31. A wiper as defined in claim 27, wherein said sanitizing formulation further comprises non-aqueous solvent in an amount between about 1% to about 15% by weight of said sanitizing formulation.
32. A wiper as defined in claim 27, wherein the wiper exhibits a log reduction for E. Coli of at least about 4.
33. A wiper as defined in claim 27, wherein the wiper exhibits a log reduction for S. Aureus of at least about 4.
34. A wiper as defined in claim 27, wherein said benzalkonium chloride is capable of being released into said solution in an amount of between about 150 to about 400 parts per million of solution.
35. A wiper comprising a nonwoven fabric and a sanitizing formulation applied to said nonwoven fabric in an amount from about 150% to about 600% of the dry weight of the wiper, said sanitizing formulation comprising between about 0.01 % by weight to about 0.4% by weight of at least one benzalkonium halide, wherein said sanitizing formulation is capable of being released from said nonwoven fabric as a solution such that said benzalkonium halide is present within said solution in an amount less than about 2000 parts per million of said solution, and wherein the wiper exhibits a Kill Efficiency Ratio of at least about 100.
36. A wiper as defined in claim 35, further comprising a preservative, a sequestrant, a non-aqueous solvent, a nonionic surfactant, or combinations thereof.
37. A wiper as defined in claim 35, wherein the wiper exhibits a Kil1 Efficiency Ratio of at least about 200.
38. A wiper as defined in claim 35, wherein said benzalkonium chloride is capable of being released into said solution in an amount of between about 150 to about 400 parts per million of solution.
39. A method for sanitizing a surface, said method comprising:

providing a wiper that contains a substrate applied with a sanitizing formulation in an amount from about 150% to about 600% of the dry weight of the wiper, said sanitizing formulation comprising between about 0.01 % by weight to about 0.4% by weight of at least one quaternary ammonium compound; and moving said wiper across the surface such that at least a portion of said sanitizing formulation is released from said wiper to form a released solution, said released solution containing less than about 2000 parts per million of said quaternary ammonium compound, said released solution exhibiting a log reduction for E. Coli of at least about 2.
40. A method as defined in claim 39, wherein said quaternary ammonium compound has the following formula:
wherein, R is a C8-C18 alkyl group; and A is a halogen atom.
41. A method as defined in claim 39, wherein said antimicrobial agent comprises between about 0.1% to about 0.4% by weight of said sanitizing formulation.
42. A method as defined in claim 39, wherein said sanitizing formulation further comprises sequestrant in an amount between about 0.01 % to about 5% by weight of said sanitizing formulation.
43. A method as defined in claim 39, wherein said sanitizing formulation further comprises nonionic surfactant in an amount between about 0.01 % to about 1 % by weight of said sanitizing formulation.
44. A method as defined in claim 39, wherein said sanitizing formulation further comprises between about 0.001 % to about 30% by weight of non-aqueous solvent.
45. A method as defined in claim 39, wherein said sanitizing formulation further comprises between about 0.001 % to about 5% by weight of preservative.
46. A method as defined in claim 39, wherein the released solution exhibits a log reduction for E. Coli and S. Aureus of at least about 3.
47. A method as defined in claim 39, wherein the released solution contains between about 150 to about 400 parts per million of said quaternary ammonium compound.
48. A method as defined in claim 39, further comprising removing said wiper from a resealable container prior to wiping the surface.
CA2470157A 2001-12-20 2002-10-31 Antimicrobial pre-moistened wipers Expired - Lifetime CA2470157C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/027,791 2001-12-20
US10/027,791 US7838447B2 (en) 2001-12-20 2001-12-20 Antimicrobial pre-moistened wipers
PCT/US2002/035243 WO2003053144A1 (en) 2001-12-20 2002-10-31 Antimicrobial pre-moistened wipers

Publications (2)

Publication Number Publication Date
CA2470157A1 true CA2470157A1 (en) 2003-07-03
CA2470157C CA2470157C (en) 2012-03-20

Family

ID=21839802

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2470157A Expired - Lifetime CA2470157C (en) 2001-12-20 2002-10-31 Antimicrobial pre-moistened wipers

Country Status (14)

Country Link
US (1) US7838447B2 (en)
EP (1) EP1455576B1 (en)
JP (1) JP2005513074A (en)
KR (1) KR100976006B1 (en)
AR (1) AR037643A1 (en)
AU (1) AU2002357689B2 (en)
CA (1) CA2470157C (en)
DE (1) DE60231831D1 (en)
EG (1) EG23190A (en)
MX (1) MXPA04005852A (en)
PE (1) PE20030590A1 (en)
TW (1) TW200305366A (en)
WO (1) WO2003053144A1 (en)
ZA (1) ZA200402895B (en)

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