CA2470642A1 - Saline soluble inorganic fibres - Google Patents

Saline soluble inorganic fibres Download PDF

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Publication number
CA2470642A1
CA2470642A1 CA002470642A CA2470642A CA2470642A1 CA 2470642 A1 CA2470642 A1 CA 2470642A1 CA 002470642 A CA002470642 A CA 002470642A CA 2470642 A CA2470642 A CA 2470642A CA 2470642 A1 CA2470642 A1 CA 2470642A1
Authority
CA
Canada
Prior art keywords
sio2
cao
zro2
mgo
thermal insulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002470642A
Other languages
French (fr)
Other versions
CA2470642C (en
Inventor
Gary Anthony Jubb
Craig John Freeman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MORGAN ADVANCED MATERIALS PLC
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9928638&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2470642(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2470642A1 publication Critical patent/CA2470642A1/en
Application granted granted Critical
Publication of CA2470642C publication Critical patent/CA2470642C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C03C13/06—Mineral fibres, e.g. slag wool, mineral wool, rock wool
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00—Casings; Linings; Walls; Roofs
    • F27D1/0003—Linings or walls
    • F27D1/0006—Linings or walls formed from bricks or layers with a particular composition or specific characteristics
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2213/00—Glass fibres or filaments
    • C03C2213/02—Biodegradable glass fibres
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only

Abstract

Thermal insulation is provided for use in applications requiring continuous resistance to temperatures of 1260 ~C without reaction with alumino-silicate firebricks, the insulation comprises fibres having a composition in wt% 65 %<SiO2 <86 %, MgO <10 %, 14 % < CaO < 28 %, A1203 <2 %, Zr02 <3 %, B203<5 %, P205 <5 %, 72 % <Si02+ZrO2+B203+5*P205, 95 % < Si02 + CaO + MgO + A1203 +Zr02 + B203 + P205. Addition of elements selected from the group Sc, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y or mixtures thereof improves fibre quality and the strength of blankets made from the fibres.

Claims (19)

1. Thermal insulation for use in applications requiring continuous resistance to temperatures of 126O°C without reaction with alumino-silicate firebricks, the. insulation comprising fibres having a composition in wt%
72%<=SiO2 <86%
MgO <=2.5%
14% < CaO < 28%
A12O3 <2%
ZrO2 <3%
B2O3 <5%
P2O3; <5%
72% <SiO2+ZrO2+B2O3+5*P2O5 95% < SiO2 + CaO + MgO + A12O3 +ZrO2 + B2O3 + P2O5
2. Thermal insulation as claimed in Claim 1, in which the amount of MgO
present in the fibre is less than 1.75%.
3. Thermal insulation as claimed in any of Claims 1 to 2, in which the amount of CaO is in the range 18% < CaO < 26%.
4. Thermal insulation as claimed in Claim 1, in which 98% < SiO2 + CaO + MgO + A.12O3 +ZrO2 + B2Q3 + P2O5.
5. Thermal insulation as claimed in Claim 4, in which 98.5% < SiO2 + CaO + MgO + A12O3 +ZrO2 + B2O3 + P2O5.
6. Thermal insulation as claimed Claim 5, in which 99% .< SiO2 + CaO + MgO + A12O3 +ZrO2 + B2O3 + P2O5.
7. Thermal insulation as claimed in any of Claims 1 to 6, having the -composition:- .
72%<SiO2<8O%
18%< CaO<26%
0%< MgO<2.5%
0%<Al2O3<1%
0%<ZrO2 <1.5%
98.5% < SiO2 + CaO + MgO + Al2O3 +Zr42 + B2O3 + P2O5.
8. Thermal insulation as claimed in any one of Claims 1 to 7, having the composition:-72% < SiO2 < 74%
24% < CaO <26%
9. A silicate fibre comprising:-65%<SiO2 <86%
MgO <10%
14% < CaO < 28%
Al2O3 <2%
ZrO2 <3%
B2O3 <5%
P2O5 <5%
72% <SiO2+ZrO2+B2O3+5*P2O5 95% < SiO2 + CaO + MgO + Al2O3 +ZrO2 + B2O3 + P2O5.
0.1 % < R2O3 <4%
where R is selected from the group Sc, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y or mixtures thereof.
10. A silicate fibre as claimed in Claim 9, in which R is La or Y or mixtures thereof.
11. A silicate fibre as claimed in Claim 10, in which R is La.
12. A silicate fibre as claimed in anyone of Claims 9 to 11, in which the amount of R2O3 is greater than 0.25%, more preferably > 0.5%, and still more preferably >1.0%.
13. A silicate fibre as claimed in any one of Claims 9 to 12, in which the amount of R2O3 is <2.5%, preferably <1.5% by weight.
14. A silicate fibre as claimed in any one of Claims 9 to 13, having the composition in wt%:-72%<SiO2<80%
18%< CaO<26%
0%< MgO<3%
0%<Al2O3<1%
0%<ZrO2 <1.5%
1% < R2O3 <2.5%
15. A silicate fibre as claimed in Claim 14, in which R comprises La.

Agent's Ref FP-09-0575 - 2nd amendment
16. A silicate fibre as claimed in Claim 15, having the composition in wt%:-SiO2:- 73 ~ 0.5%
CaO:- 24 ~ 0.5%
La2O3:- 1.3 - 1.5%
Remaining components:- <2%, preferably <1.5%
17. Thermal insulation comprising silicate fibres as claimed in any one of Claims 9 to 14.
X 8. Thermal insulation comprising wholly fibres as specified in any one of claims 1 to 16.
19. Thermal insulation as claimed in any of Claims 1 to 7, in which the thermal insulation is in the form of a blanket.
20. Thermal insulation as claimed in any of Claims 1 to 19, for use in applications requiring continuous resistance to temperatures of 1300°C
without reaction with alumino-silicate firebricks, 21. Use as thermal insulation, of a body comprising fibres as specified in any of Claims 1 to 6, in an application requiring continuous resistance to temperatures of 1260°C without reaction with alumino-silicate firebrick.
22. Use as claimed in Claim 21, in an application requiring continuous resistance to temperatures of 1300°C without reaction with alumino-silicate firebrick:
23. A method of improving the fiberisation of alkaline earth silicate fibres having a composition in wt%
65%<SiO2 <86%
MgO <10%
14% < CaO < 28%
Al2O3 <2%
ZrO2 <3%
B2O3 <5%
P2O5 <5%
72% <SiO2+ZrO2+B2O3+5*P2O5 95% < SiO2 + CaO + MgO + A12O3 +ZrO2 + B2O3 + P2O5 by inclusion in the components of the fibre of R2O3 in amounts ranging from 1% to 4% by weight, where R is selected from the group Sc, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y or mixtures thereof.
18 24. A method as claimed in Claim 23, in which R is La or Y or mixtures thereof.
25. A method as claimed in Claim 24, in which R is La.
19
CA2470642A 2002-01-04 2003-01-02 Saline soluble inorganic fibres Expired - Lifetime CA2470642C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0200162A GB2383793B (en) 2002-01-04 2002-01-04 Saline soluble inorganic fibres
GB0200162.6 2002-01-04
PCT/GB2003/000003 WO2003059835A1 (en) 2002-01-04 2003-01-02 Saline soluble inorganic fibres

Publications (2)

Publication Number Publication Date
CA2470642A1 true CA2470642A1 (en) 2003-07-24
CA2470642C CA2470642C (en) 2010-09-21

Family

ID=9928638

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2470642A Expired - Lifetime CA2470642C (en) 2002-01-04 2003-01-02 Saline soluble inorganic fibres

Country Status (17)

Country Link
US (3) US7470641B2 (en)
EP (2) EP1544177B1 (en)
JP (2) JP4744084B2 (en)
KR (1) KR100710686B1 (en)
CN (2) CN1868947A (en)
AT (2) ATE384690T1 (en)
AU (1) AU2003201632B2 (en)
BR (2) BR0318801B1 (en)
CA (1) CA2470642C (en)
DE (2) DE60301263T2 (en)
ES (2) ES2297540T3 (en)
GB (1) GB2383793B (en)
MX (1) MXPA04006500A (en)
PL (1) PL210855B1 (en)
RU (1) RU2303574C2 (en)
WO (1) WO2003059835A1 (en)
ZA (1) ZA200404146B (en)

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