CA2473611A1 - Thermoplastic foam containing particulate additive - Google Patents
Thermoplastic foam containing particulate additive Download PDFInfo
- Publication number
- CA2473611A1 CA2473611A1 CA002473611A CA2473611A CA2473611A1 CA 2473611 A1 CA2473611 A1 CA 2473611A1 CA 002473611 A CA002473611 A CA 002473611A CA 2473611 A CA2473611 A CA 2473611A CA 2473611 A1 CA2473611 A1 CA 2473611A1
- Authority
- CA
- Canada
- Prior art keywords
- foam
- polymer
- acid
- particulate additive
- polymer resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006260 foam Substances 0.000 title claims abstract 28
- 239000000654 additive Substances 0.000 title claims abstract 13
- 230000000996 additive effect Effects 0.000 title claims abstract 11
- 229920001169 thermoplastic Polymers 0.000 title 1
- 239000004416 thermosoftening plastic Substances 0.000 title 1
- 239000002952 polymeric resin Substances 0.000 claims abstract 15
- 229920003002 synthetic resin Polymers 0.000 claims abstract 15
- 229920000642 polymer Polymers 0.000 claims abstract 12
- 239000002253 acid Substances 0.000 claims abstract 11
- 239000011159 matrix material Substances 0.000 claims abstract 11
- 150000008065 acid anhydrides Chemical class 0.000 claims abstract 5
- 150000002148 esters Chemical class 0.000 claims abstract 4
- 150000003839 salts Chemical class 0.000 claims abstract 4
- 238000010521 absorption reaction Methods 0.000 claims abstract 3
- 229920000098 polyolefin Polymers 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 5
- 229920000573 polyethylene Polymers 0.000 claims 5
- 229920001155 polypropylene Polymers 0.000 claims 5
- 239000003063 flame retardant Substances 0.000 claims 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 239000002671 adjuvant Substances 0.000 claims 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- -1 poly(acrylic acid) Polymers 0.000 claims 2
- 229920005672 polyolefin resin Polymers 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000004604 Blowing Agent Substances 0.000 claims 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims 1
- 229910000410 antimony oxide Inorganic materials 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- WXUAQHNMJWJLTG-UHFFFAOYSA-N monomethylpersuccinic acid Natural products OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 claims 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims 1
- 238000005192 partition Methods 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229920001384 propylene homopolymer Polymers 0.000 claims 1
- 239000002516 radical scavenger Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 239000000779 smoke Substances 0.000 claims 1
- 229940071182 stannate Drugs 0.000 claims 1
- 125000005402 stannate group Chemical group 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
- 239000001384 succinic acid Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 230000001413 cellular effect Effects 0.000 abstract 1
- 229920002397 thermoplastic olefin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Abstract
A cellular thermoplastic polyolefin foam comprising at least one particulate additive in admixture with a polymer matrix is disclosed, along with a process and foamable gel for manufacturing the same, wherein the polyolefin matrix comprises at least one polymer resin graft-modified with at least one polar group selected from the group consisting of acid, acid ester, and acid anhydride, and salts thereof. The invention facilitates the manufacture of macrocellular foams useful for acoustic absorption having increased amounts of particulate additives that provide certain desired properties difficult to achieve without the particulate additives, such as improved flame retardancy.
Claims (25)
1. A macrocellular polymer foam having an average cell size, measured according to ASTM D3575, of at least 1.5 mm and a density less than 100 kilograms per cubic meter comprising:
A) at least one particulate additive in admixture with B) a polymer matrix, wherein. the polymer matrix comprises at least one polymer resin graft-modified with at least one polar group selected from the group consisting of acid, acid ester, or acid anhydride, pr a salt thereof.
A) at least one particulate additive in admixture with B) a polymer matrix, wherein. the polymer matrix comprises at least one polymer resin graft-modified with at least one polar group selected from the group consisting of acid, acid ester, or acid anhydride, pr a salt thereof.
2. The foam of claim 1, wherein the acid of the acid, acid ester, or acid anhydride, or salt thereof, is a mono-unsaturated carboxylic acid.
3. The foam of claim l, wherein the acid is acrylic acid and the acid anhydride is maleic anhydride.
4. The foam of claim 3; wherein the polymer resin graft-modified with at least one polar group has at least one pendant polar group selected from the group consisting of poly(acrylic acid), methyl acetate, succinic acid and maleic anhydride.
5. The foam of any one of the preceding claims; wherein the polymer matrix B) comprises at least one polyolefin resin.
6. The foam of claim 5, wherein the at least one polyolefin resin is at least one ethylene polymer or at least one propylene polymer, or a mixture of at least one ethylene polymer and at least one propylene polymer.
7. The foam of Claim 6, wherein the ethylene polymer is an ethylene homopolymer or an interpolymer of ethylene and at least one monomer selected from the group consisting of one or more C3-C10 .alpha.-olefin polymers.
8. The foam of claim 6 or 7, wherein the propylene polymer is a propylene homopolymer or an interpolymer of propylene with ethylene or one or more C4-.alpha.-olefin polymers.
9, The foam of any one of the preceding claims, wherein the particulate additive comprises a metal oxide, halides, borate, silicate, or stannate.
10. The foam of any one of the preceding claims, wherein the particulate additive is a flame retardant adjuvant, flame retardant, antioxidant, antiblock additive, colorant, pigment, filler, or acid scavenger.
11. The foam of Claim 10, wherein the dame retardant adjuvant is a flame retardant synergist, a smoke suppressant or a char forming agent.
12. The foam of claim 11, wherein the particulate additive comprises an antimony oxide flame retardant synergist.
13. The foam of any one of the preceding claims, wherein the at least one polymer resin of the polymer matrix B) comprises at least one first-category polymer resin that has, on the average, at least one polar group per resin molecule and at least one second-category polymer resin that has, on the average, less than 0.1 polar group per polymer resin molecule.
14. The foam of claim 13, wherein the at least one second-category polymer resin is an ethylene polymer or a propylene polymer, or a mixture of an ethylene polymer and a propylene polymer.
15. The foam of claim 13 or 14, wherein the ratio of the average melt flow rate of the first-category polymer resins(s) to the average melt flow rate of the second-category polymer resin(s), each melt flow rate measured according to ASTM D1238 (2.16 kg,.), is in the range from l:2 to 15:1.
16. The foam of any one of the preceding claims further comprising a halogenated flame retardant C).
17. The foam of any one of claims 13 to 16, wherein the first category polymer resin of the polymer matrix B) is graft modified with at least 0.1 weight-percent polar groups.
18. The foam of any one of claims 13 to 16, wherein the first category polymer resin of the polymer matrix B) is graft-modified with up to 10 weight-percent polar groups.
19. The foam of any one of claims 13 to 18, wherein the weight ratio of the first category polymer resin of the polymer matrix B) to the particulate additive A) is in the range from 0.1:1 to 3:1.
20. The foam of any one of the preceding claims having an average cell size, measured according to ASTM D3575. of at least 4.5 mm.
21. The foam of any one of the preceding claims having an average sound absorption coefficient (measured via ASTM E1050 at 250, 500, 1000 and 2000 hertz (Hz) sound frequencies) o~ at least 0.15.
22. The foam of any one of the preceding claims in the form of an office partition, automotive decoupler, domestic appliance sound insulation, industrial noise absorber, sound proofing panel, hanging baffle, or machine enclosure.
23. Use of the foam of any one of the preceding claims as an acoustic absorption material.
24. A foamable gel suitable for making the foam according to claim 1 comprising:
1) at least one particulate additive in admixture with at least one polymer matrix and 2) at least one blowing agent, wherein the polymer matrix comprises at least one polymer resin graft-modified with at least one polar group selected from the group consisting of acid, acid ester, or acid anhydride, or salt thereof and the weight ratio of the polymer resin graft-modifed with at least one polar group to the particulate additive is not greater than 5:1.
1) at least one particulate additive in admixture with at least one polymer matrix and 2) at least one blowing agent, wherein the polymer matrix comprises at least one polymer resin graft-modified with at least one polar group selected from the group consisting of acid, acid ester, or acid anhydride, or salt thereof and the weight ratio of the polymer resin graft-modifed with at least one polar group to the particulate additive is not greater than 5:1.
25. A method for making macrocellular polymer foams containing at least one particulate additive comprising expanding a foamable gel according to claim 24.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35883202P | 2002-02-22 | 2002-02-22 | |
| US60/358,832 | 2002-02-22 | ||
| PCT/US2003/002053 WO2003072644A2 (en) | 2002-02-22 | 2003-01-15 | Thermoplastic foam containing particulate additive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2473611A1 true CA2473611A1 (en) | 2003-09-04 |
| CA2473611C CA2473611C (en) | 2010-03-16 |
Family
ID=27766003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2473611A Expired - Fee Related CA2473611C (en) | 2002-02-22 | 2003-01-15 | Thermoplastic foam containing particulate additive |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7226955B2 (en) |
| EP (1) | EP1476499B1 (en) |
| JP (1) | JP4276082B2 (en) |
| KR (1) | KR20040094713A (en) |
| CN (1) | CN1266202C (en) |
| AT (1) | ATE415444T1 (en) |
| AU (1) | AU2003214883B2 (en) |
| CA (1) | CA2473611C (en) |
| DE (1) | DE60324896D1 (en) |
| ES (1) | ES2314186T3 (en) |
| TW (1) | TW200303885A (en) |
| WO (1) | WO2003072644A2 (en) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3875974B2 (en) * | 2003-04-11 | 2007-01-31 | 西川ゴム工業株式会社 | Sound insulation sheet |
| DE102004024501A1 (en) * | 2004-05-18 | 2005-12-15 | Hilti Ag | Fireproof material |
| US8541496B2 (en) * | 2005-12-29 | 2013-09-24 | Joel Sereboff | Energy absorbing composition and impact and sound absorbing applications thereof |
| US7754791B2 (en) | 2005-12-29 | 2010-07-13 | Sereflex Group LLC | Energy absorbing composition and impact and sound absorbing applications thereof |
| US8987367B2 (en) | 2005-12-29 | 2015-03-24 | Joel L. Sereboff | Energy absorbing composition and impact and sound absorbing applications thereof |
| WO2007134080A2 (en) * | 2006-05-08 | 2007-11-22 | Polymer Products Company, Inc. | Flame-retardant polymeric compositions |
| CA2686755A1 (en) * | 2007-05-16 | 2008-11-27 | Nova Chemicals, Inc. | Plastic-cellulosic composite articles |
| AR070957A1 (en) * | 2008-01-11 | 2010-05-19 | Nova Chem Inc | METHOD FOR PRODUCING THERMOPLASTIC COMPOUND MATERIALS OF A COPOLYMER CONTAINING LOADED ANHYDRID WITH CELLULOSICAL MATERIALS |
| US20100014282A1 (en) * | 2008-07-15 | 2010-01-21 | Michael Danesh | Fire-resistant and noise attenuating recessed lighting assembly |
| ES2443070T3 (en) * | 2008-08-15 | 2014-02-17 | Invista Technologies S.À.R.L. | Polymeric composite materials, flame retardant fibers and carpets and manufacturing procedures for each of them |
| US7714611B1 (en) * | 2008-12-03 | 2010-05-11 | Advantage Logic, Inc. | Permutable switching network with enhanced multicasting signals routing for interconnection fabric |
| WO2010111106A1 (en) * | 2009-03-27 | 2010-09-30 | Dow Global Technologies Inc. | Polymeric foam containing alumina boehmite |
| US9260577B2 (en) * | 2009-07-14 | 2016-02-16 | Toray Plastics (America), Inc. | Crosslinked polyolefin foam sheet with exceptional softness, haptics, moldability, thermal stability and shear strength |
| CA2714732A1 (en) * | 2009-09-08 | 2011-03-08 | Polymer Products Company, Inc. | Halogen-free fire retardant compositions |
| EP2638540A4 (en) | 2010-11-09 | 2017-11-08 | California Institute of Technology | Acoustic suppression systems and related methods |
| JP6013597B2 (en) | 2012-05-31 | 2016-10-25 | コーニング インコーポレイテッド | Rigid interlayer for laminated glass structures |
| KR102210037B1 (en) | 2012-12-21 | 2021-02-01 | 다우 글로벌 테크놀로지스 엘엘씨 | Polyolefin-based cable compound formulation for improved foamability and enhanced processability |
| ES2688532T3 (en) | 2013-01-18 | 2018-11-05 | Basf Se | Acrylic dispersion based coating compositions |
| JP6119277B2 (en) * | 2013-02-07 | 2017-04-26 | 東レ株式会社 | Foam |
| WO2015031590A2 (en) | 2013-08-30 | 2015-03-05 | Corning Incorporated | Light-weight, high stiffness glass laminate structure |
| WO2016051371A1 (en) * | 2014-10-03 | 2016-04-07 | Pirelli Tyre S.P.A. | Soundproof tyre for vehicle wheels |
| US10350861B2 (en) | 2015-07-31 | 2019-07-16 | Corning Incorporated | Laminate structures with enhanced damping properties |
| BR112018068858B1 (en) * | 2016-03-25 | 2022-05-03 | Pirelli Tyre S.P.A | Sound-insulating self-sealing tire, and process for manufacturing a sound-insulating self-sealing tire |
| CN110753572B (en) * | 2017-06-14 | 2022-06-28 | 3M创新有限公司 | Acoustically active material |
| CN108608686A (en) * | 2018-04-28 | 2018-10-02 | 中山市益孚生物科技有限公司 | A kind of composite material and its manufacturing method for absorbing ultrasonic wave |
| US20190338099A1 (en) * | 2018-05-07 | 2019-11-07 | Trexel, Inc. | Three-dimensional suction molding method for polymeric foams |
Family Cites Families (90)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3177269A (en) | 1960-10-10 | 1965-04-06 | Dow Chemical Co | Graft copolymers of polyolefins and acrylic and methacrylic acid and method of making the same |
| US3267173A (en) | 1962-05-18 | 1966-08-16 | Allied Chem | Product and process for making a polyethylene-maleate diester graft copolymer |
| US3250730A (en) | 1962-10-15 | 1966-05-10 | Hercules Powder Co Ltd | Preparation of molded plastic articles |
| US3270090A (en) | 1963-04-22 | 1966-08-30 | Dow Chemical Co | Method for making graft copolymers of polyolefins and acrylic and methacrylic acid |
| US3414551A (en) | 1965-06-24 | 1968-12-03 | Hercules Inc | Modification of crystalline propylene polymers |
| US3437550A (en) | 1966-01-07 | 1969-04-08 | Hercules Inc | Glass fiber reinforced crystalline polypropylene composition and laminate |
| GB1217231A (en) | 1967-01-13 | 1970-12-31 | Asahi Chemical Ind | Modified polymer composition and a process for producing the same |
| CA849081A (en) | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
| US3499819A (en) | 1967-04-20 | 1970-03-10 | Hercules Inc | Laminates of aluminum and polypropylene foam and method therefor |
| US3644230A (en) | 1968-02-19 | 1972-02-22 | Haskon Inc | Extrusion process for polyolefin foam |
| US3573152A (en) | 1969-07-29 | 1971-03-30 | Foster Grant Co Inc | Thermoplastic elongated cellular products |
| US3708555A (en) | 1970-02-24 | 1973-01-02 | Gaylord Ass | Grafting of a mixture of styrene and maleic anhydride onto backbone polymers containing active or labile hydrogen atoms |
| US3862265A (en) | 1971-04-09 | 1975-01-21 | Exxon Research Engineering Co | Polymers with improved properties and process therefor |
| DE2242324C3 (en) | 1971-08-30 | 1986-10-02 | Mitsubishi Rayon Co., Ltd., Tokio/Tokyo | Process for the production of glass-reinforced polyolefin compositions |
| US3868433A (en) | 1972-04-03 | 1975-02-25 | Exxon Research Engineering Co | Thermoplastic adhesive compositions |
| US3953655A (en) | 1972-04-03 | 1976-04-27 | Exxon Research And Engineering Company | Polymers with improved properties and process therefor |
| US3873643A (en) | 1972-12-18 | 1975-03-25 | Chemplex Co | Graft copolymers of polyolefins and cyclic acid and acid anhydride monomers |
| US3884451A (en) | 1973-01-17 | 1975-05-20 | Exxon Research Engineering Co | Mixing apparatus and method |
| US3882194A (en) | 1973-01-26 | 1975-05-06 | Chemplex Co | Cografted copolymers of a polyolefin, an acid or acid anhydride and an ester monomer |
| US4100076A (en) | 1977-06-23 | 1978-07-11 | The Harshaw Chemical Company | Titanate treated antimony compounds |
| US4214054A (en) | 1977-10-21 | 1980-07-22 | Asahi-Dow Limited | Expanded olefin polymer |
| DE2902468A1 (en) | 1979-01-23 | 1980-07-31 | Bayer Ag | THERMOPLASTIC POLYESTER MOLDINGS WITH HIGH TOUGHNESS |
| ZA81322B (en) | 1980-01-23 | 1982-03-31 | Rohm & Haas | The preparation of graft copolymers, poly (vinyl chloride) compositions containing them and reactors useful in preparing them |
| GB2070021B (en) | 1980-02-21 | 1984-03-21 | Furukawa Electric Co Ltd | Crosslinked ethylene-vinyl acetate copolymer foam containing an inorganic material and its production |
| US4277569A (en) | 1980-03-10 | 1981-07-07 | Sentinel Foam Products Incorporated | Fire-retardant foam |
| US4323528A (en) | 1980-08-07 | 1982-04-06 | Valcour Imprinted Papers, Inc. | Method and apparatus for making large size, low density, elongated thermoplastic cellular bodies |
| US4362486A (en) | 1980-10-07 | 1982-12-07 | International Business Machines Corporation | Automatic multilayer ceramic (MLC) screening machine |
| FR2517682A1 (en) | 1981-12-03 | 1983-06-10 | Centre Nat Rech Scient | NOVEL GRAFTED POLYOLEFIN AND PROCESS FOR ITS PREPARATION |
| US4639495A (en) | 1981-12-21 | 1987-01-27 | E. I. Du Pont De Nemours And Company | Extruding process for preparing functionalized polyolefin polymers |
| US4506056A (en) | 1982-06-07 | 1985-03-19 | Gaylord Research Institute Inc. | Maleic anhydride-modified polymers and process for preparation thereof |
| JPS59164346A (en) * | 1983-03-08 | 1984-09-17 | Dainippon Ink & Chem Inc | Thermoplastic molding material |
| JPS6011329A (en) | 1983-07-01 | 1985-01-21 | Mitsubishi Petrochem Co Ltd | Continuous manufacture of crosslinked and foamed body |
| US4578431A (en) | 1983-08-31 | 1986-03-25 | Mobil Oil Corporation | Process for improving melt strength of ethylene polymers by treatment with organic peroxide |
| US4578428A (en) | 1983-12-16 | 1986-03-25 | Montedison S.P.A. | Modified olefine polymers and process for their manufacture |
| US4741865A (en) | 1984-05-29 | 1988-05-03 | Nyacol Products, Inc. | Flameproofing composition |
| US4927888A (en) | 1986-09-05 | 1990-05-22 | The Dow Chemical Company | Maleic anhydride graft copolymers having low yellowness index and films containing the same |
| US4950541A (en) | 1984-08-15 | 1990-08-21 | The Dow Chemical Company | Maleic anhydride grafts of olefin polymers |
| US4762890A (en) | 1986-09-05 | 1988-08-09 | The Dow Chemical Company | Method of grafting maleic anhydride to polymers |
| FR2572417B1 (en) | 1984-10-30 | 1987-05-29 | Atochem | ADHESIVE COMPOSITIONS BASED ON POLYPROPYLENE MODIFIED BY Grafting of an Unsaturated Monomer |
| US4714716A (en) | 1984-11-16 | 1987-12-22 | The Dow Chemical Company | Lightly crosslinked linear olefinic polymer foams and process for making |
| ZA86528B (en) | 1985-01-31 | 1986-09-24 | Himont Inc | Polypropylene with free-end long chain branching,process for making it,and use thereof |
| JPH0689201B2 (en) | 1985-02-19 | 1994-11-09 | 宇部興産株式会社 | Glass fiber reinforced polypropylene composition |
| JPS61276808A (en) | 1985-05-31 | 1986-12-06 | Ube Ind Ltd | Maleic acid-modified polyolefin and production thereof |
| CA1236613A (en) | 1985-06-27 | 1988-05-10 | Chun S. Wong | Process for the grafting of monomers onto polyolefins |
| JPH0721478B2 (en) | 1986-03-31 | 1995-03-08 | 財団法人化学及血清療法研究所 | Working film for immunosensor |
| US4739017A (en) | 1986-06-06 | 1988-04-19 | The Dow Chemical Company | Retro Diels Alder assisted polymer grafting process |
| JPS63117008A (en) | 1986-11-05 | 1988-05-21 | Idemitsu Petrochem Co Ltd | Production of modified polyethylene |
| JPH0819318B2 (en) | 1986-11-19 | 1996-02-28 | 三菱瓦斯化学株式会社 | Solvent resistant polyphenylene ether resin composition |
| DE3642239A1 (en) | 1986-12-10 | 1988-06-23 | Ver Schuhmasch Gmbh | METHOD AND DEVICE FOR CHANGING A SHOE SHOE |
| US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US4824720A (en) | 1988-02-11 | 1989-04-25 | The Dow Chemical Company | Coalesced polyolefin foam having exceptional cushioning properties |
| IN171050B (en) | 1987-04-11 | 1992-07-04 | Stamicarbon | |
| US4824736A (en) | 1987-09-23 | 1989-04-25 | Aristech Chemical Corporation | Gasoline tank of tin-free (electroplate chrome-chrome oxide coated) steel coated with a maleic anhydride modified polypropylene |
| US4857254A (en) | 1988-02-22 | 1989-08-15 | Du Pont Canada Inc. | Method for grafting monomers onto molten hydrocarbon polymer |
| US4862890A (en) | 1988-02-29 | 1989-09-05 | Everest Medical Corporation | Electrosurgical spatula blade with ceramic substrate |
| US4857600A (en) | 1988-05-23 | 1989-08-15 | Union Carbide Corporation | Process for grafting diacid anhydrides |
| GB8827335D0 (en) | 1988-11-23 | 1988-12-29 | Du Pont Canada | Method for manufacture of modified polypropylene compositions |
| US5059376A (en) | 1989-04-20 | 1991-10-22 | Astro-Valcour, Incorporated | Methods for rapid purging of blowing agents from foamed polymer products |
| US5001197A (en) | 1989-05-10 | 1991-03-19 | Exxon Chemical Patents Inc. | Polypropylene composition and method for functionalization of polypropylene |
| US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5079302A (en) | 1990-01-19 | 1992-01-07 | University Of Akron | Polymerization process and the polymers thereof |
| DK0533742T3 (en) | 1990-06-14 | 1997-08-18 | Dow Chemical Co | Fire resistant alkenyl aromatic foam |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| US5585058A (en) | 1991-04-30 | 1996-12-17 | The Dow Chemical Company | Method for providing accelerated release of a blowing agent from a plastic foam |
| US5527573A (en) | 1991-06-17 | 1996-06-18 | The Dow Chemical Company | Extruded closed-cell polypropylene foam |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5367022A (en) | 1991-11-27 | 1994-11-22 | Quantum Chemical Corporation | Grafted polymeric products, and adhesive blends |
| US5552096A (en) | 1991-12-13 | 1996-09-03 | Exxon Chemical Patents Inc. | Multiple reaction process in melt processing equipment |
| US5242016A (en) | 1992-04-02 | 1993-09-07 | Nartron Corporation | Laminated plate header for a refrigeration system and method for making the same |
| US5346963A (en) | 1993-04-28 | 1994-09-13 | The Dow Chemical Company | Graft-modified, substantially linear ethylene polymers and methods for their use |
| US5344888A (en) | 1993-05-14 | 1994-09-06 | Quantum Chemical Corporation | Process for making graft propylene polymers |
| US5344886A (en) | 1993-05-14 | 1994-09-06 | Quantum Chemical Corporation | Process for making graft propylene polymers |
| US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| KR970705587A (en) | 1994-08-25 | 1997-10-09 | 그윈넬 해리 제이 | High-molecular-weight low-molecular-weight polypropylene (MALEATED HIGH ACID NUMBER HIGH MOLECULAR WEIGHT POLYPROPYLENE OF LOW COLOR) |
| US5736618A (en) | 1995-05-05 | 1998-04-07 | Poloso; Anthony | High density polyethylene with improved thermoforming characteristics |
| DE19607480A1 (en) | 1996-02-28 | 1997-09-04 | Danubia Petrochem Polymere | Continuous process for the production of polypropylene mixtures with increased stress crack resistance and melt resistance |
| JPH1027421A (en) | 1996-07-10 | 1998-01-27 | Sony Corp | Device for reproducing disk and method therefor |
| FR2754535A1 (en) | 1996-10-16 | 1998-04-17 | Atochem Elf Sa | GRAFTED POLYMERS WITH CONTROLLED VISCOSITY |
| JP3492131B2 (en) | 1997-01-20 | 2004-02-03 | 積水化学工業株式会社 | Olefin resin foam |
| DE19720975A1 (en) | 1997-05-20 | 1998-11-26 | Danubia Petrochem Polymere | Polyolefin foams with high heat resistance |
| BR9814450A (en) | 1997-08-27 | 2000-10-03 | Dow Chemical Co | Process for a modified rheology polyolefin, composition and use |
| IT1298584B1 (en) * | 1998-02-10 | 2000-01-12 | Montell North America Inc | EXPANDED IONOMERIC CRYSTALLINE POLYOLEFINS |
| CN1147524C (en) | 1998-09-17 | 2004-04-28 | 陶氏环球技术公司 | Acoustical open-cell polyolefins and process for making |
| TR200100743T2 (en) | 1998-09-17 | 2001-06-21 | The Dow Chemical Company | Foams useful in sound control |
| US6048909A (en) | 1998-12-04 | 2000-04-11 | The Dow Chemical Company | Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
| US6218476B1 (en) | 1999-03-03 | 2001-04-17 | Eastman Chemical Company | Functionalized polypropylenes and process for production |
| US6239197B1 (en) | 1999-04-23 | 2001-05-29 | Great Lakes Chemical Corporation | Vacuum de-aerated powdered polymer additives |
| US7018700B2 (en) | 2000-03-17 | 2006-03-28 | Dow Global Technologies Inc. | Acoustic absorption polymer foam having improved thermal insulating performance |
| WO2001070861A2 (en) | 2000-03-17 | 2001-09-27 | Dow Global Technologies Inc. | Polyolefin foam for sound and thermal insulation |
| US6590006B2 (en) | 2000-03-17 | 2003-07-08 | Dow Global Technologies Inc. | Macrocellular polyolefin foam having a high service temperature for acoustical applications |
-
2003
- 2003-01-15 KR KR10-2004-7012991A patent/KR20040094713A/en active IP Right Grant
- 2003-01-15 AT AT03710726T patent/ATE415444T1/en not_active IP Right Cessation
- 2003-01-15 AU AU2003214883A patent/AU2003214883B2/en not_active Ceased
- 2003-01-15 DE DE60324896T patent/DE60324896D1/en not_active Expired - Lifetime
- 2003-01-15 US US10/499,802 patent/US7226955B2/en not_active Expired - Lifetime
- 2003-01-15 ES ES03710726T patent/ES2314186T3/en not_active Expired - Lifetime
- 2003-01-15 JP JP2003571343A patent/JP4276082B2/en not_active Expired - Fee Related
- 2003-01-15 CA CA2473611A patent/CA2473611C/en not_active Expired - Fee Related
- 2003-01-15 CN CNB03804398XA patent/CN1266202C/en not_active Expired - Fee Related
- 2003-01-15 EP EP03710726A patent/EP1476499B1/en not_active Expired - Lifetime
- 2003-01-15 WO PCT/US2003/002053 patent/WO2003072644A2/en active Application Filing
- 2003-02-21 TW TW092103682A patent/TW200303885A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE415444T1 (en) | 2008-12-15 |
| JP2005518471A (en) | 2005-06-23 |
| US7226955B2 (en) | 2007-06-05 |
| TW200303885A (en) | 2003-09-16 |
| WO2003072644A2 (en) | 2003-09-04 |
| JP4276082B2 (en) | 2009-06-10 |
| CN1639241A (en) | 2005-07-13 |
| EP1476499A2 (en) | 2004-11-17 |
| ES2314186T3 (en) | 2009-03-16 |
| DE60324896D1 (en) | 2009-01-08 |
| AU2003214883A1 (en) | 2003-09-09 |
| CA2473611C (en) | 2010-03-16 |
| KR20040094713A (en) | 2004-11-10 |
| WO2003072644A3 (en) | 2003-11-20 |
| AU2003214883B2 (en) | 2007-10-04 |
| EP1476499B1 (en) | 2008-11-26 |
| CN1266202C (en) | 2006-07-26 |
| US20050086823A1 (en) | 2005-04-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2473611A1 (en) | Thermoplastic foam containing particulate additive | |
| JP4987207B2 (en) | Polymeric polyolefin foam with high working temperature for acoustic applications | |
| US20050158536A1 (en) | Molded body of thermoplastic resin having sound absorption characteristics | |
| MXPA02008936A (en) | Preparation of a macrocellular acoustic foam. | |
| EP0726290B1 (en) | A polyolefin based crosslinked foam | |
| JP2016017144A (en) | Method for producing crosslinked polyethylene-based resin foamed particle and method for producing cross-linked polyethylene-based resin particle | |
| CN105153546A (en) | Preparation of environment-friendly water foamed polypropylene master batch, and extruded microfoamed sheet prepared from master batch | |
| JPH10329220A (en) | Sound absorbing thermoplastic resin particle molding | |
| US7144925B2 (en) | Fire resistance acoustic foam | |
| JP3557766B2 (en) | Polyolefin-based electron beam crosslinked foam | |
| CN105801990A (en) | Halogen-free red phosphorus-free high-flame retardation heat-shrinkable bush and preparation method thereof | |
| JP3064777B2 (en) | Polypropylene-based electron beam crosslinked foam with excellent moldability | |
| AU2002316094B2 (en) | Fire resistance acoustic foam | |
| JP4756957B2 (en) | Extruded foam | |
| EP1016511B1 (en) | Molded body of thermoplastic resin having sound absorption characteristics | |
| JP2007039601A (en) | Extruded foam | |
| JPH0570620A (en) | Composition for flame-retardant resin foamed body, flame-retardant resin foamed body and its production | |
| JP2755109B2 (en) | Continuous sheet flame-retardant polypropylene-based crosslinked foam | |
| JP2016037551A (en) | Water-crosslinkable foam resin composition as well as foamed body and production method thereof | |
| JP2581354B2 (en) | Composition for flame-retardant resin foam, flame-retardant resin foam, and method for producing flame-retardant resin foam | |
| KR100570187B1 (en) | Thermal resistant resin compound for noise-blocking pad of architecture | |
| JPS619444A (en) | Preparation of flame-retardant crosslinked polyethlene foam | |
| JPS58168632A (en) | Production of synthetic resin foam highly filled with inorganic matter | |
| CN109836700A (en) | A kind of preparation method and expanded polypropylene of fire-retardant low thermally conductive expanded polypropylene | |
| JPH0570619A (en) | Composition for flame-retardant resin foamed body, flame-retradant resin foamed body and its production |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20180115 |