CA2499951A1 - Multiple catalyst system for olefin polymerization and polymers produced therefrom - Google Patents
Multiple catalyst system for olefin polymerization and polymers produced therefrom Download PDFInfo
- Publication number
- CA2499951A1 CA2499951A1 CA 2499951 CA2499951A CA2499951A1 CA 2499951 A1 CA2499951 A1 CA 2499951A1 CA 2499951 CA2499951 CA 2499951 CA 2499951 A CA2499951 A CA 2499951A CA 2499951 A1 CA2499951 A1 CA 2499951A1
- Authority
- CA
- Canada
- Prior art keywords
- indenyl
- butyl
- iso
- 2zirconium
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
- C09J123/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/416—Additional features of adhesives in the form of films or foils characterized by the presence of essential components use of irradiation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2401/00—Presence of cellulose
- C09J2401/006—Presence of cellulose in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2421/00—Presence of unspecified rubber
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/006—Presence of polyolefin in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
- C09J2423/046—Presence of homo or copolymers of ethene in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/10—Presence of homo or copolymers of propene
- C09J2423/106—Presence of homo or copolymers of propene in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2427/00—Presence of halogenated polymer
- C09J2427/006—Presence of halogenated polymer in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ehtylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g') of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less and to a continuous process to produce a branched olefin polymer comprising 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100~C; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.
Claims (82)
1. A polymer comprising at least 50 mol% of one or more C3 to C40 olefins where the polymers has:
a) a Dot T-Peel of 1 Newton or more on Kraft paper; and b) a branching index (g') of 0.98 or less measured at the Mz of the polymer;
c) an Mw of 100,000 or less.
d) A heat of fusion of 1 to 70 J/g.
a) a Dot T-Peel of 1 Newton or more on Kraft paper; and b) a branching index (g') of 0.98 or less measured at the Mz of the polymer;
c) an Mw of 100,000 or less.
d) A heat of fusion of 1 to 70 J/g.
2. The polymer of claim 1 wherein the branching index (g') is 0.95 or less measured at the Mz of the polymer.
3. The polymer of claim 1 wherein the Mw is 100 to 60,000.
4. The polymer of claim 1 which is a homopolypropylene or a copolymer of propylene and up to 5 mole% ethylene said polymer having:
a) an isotactic run length of 1 to 30, and b) a r dyad percentage of greater than 20%.
a) an isotactic run length of 1 to 30, and b) a r dyad percentage of greater than 20%.
5. The polymer of claim of claim 1 wherein the heat of fusion is from 1 to 50 J/g.
6. The polymer of claim 1 or 2 wherein the polymer comprises lass than 15 mole % of ethylene.
7. The polymer of any of the above claims wherein the polymer has a melt viscosity of 7000 mPa.cndot.sec or less at 190°C.
8. The polymer of any of the above claims wherein the polymer has a melt viscosity of 5000 mPa.cndot. or less at 190°C.
9. The polymer of any of the above claims wherein the polymer has a melt viscosity of 3000 mPa.cndot.sec or less at 190°C.
10. The polymer of any of the above claims wherein the polymer has a melt viscosity of between 500 and 3000 mPa.cndot.sec at 190°C.
11. The polymer of any of the above claims wherein the polymer has a Tg of 0°C or less.
12. The polymer of any of the above claims wherein the polymer has a Tg of 10°C or less.
13. The polymer of any of the above claims wherein the composition has a branching index (g) of 0.90 or less measured at the Mz of the polymer.
14. The polymer of any of the above claims wherein the polymer has an Mw of 50,000 or less and a branching index of 0.7 or less.
15. The polymer of any of the above claims wherein the molecular weight distribution of the polymer is bi- or multi-modal.
16. The polymer of any of the above claims wherein the polymer has an amorphous content of at least 50%.
17. The polymer of any of the above claims wherein the polymer has a peak melting point between 60 and 190°C.
18. The polymer of any of the above claims wherein the polymer has a molecular weight distribution (Mw/Mn) of at least 5.
19. The polymer of any of the above claims wherein the polymer has a crystallinity of at least 30%.
20. The polymer of any of the above claims wherein the polymer has 20 wt.%
or more of hexane room temperature soluble fraction and 50 wt % or less of Soxhlet heptane insolubles.
or more of hexane room temperature soluble fraction and 50 wt % or less of Soxhlet heptane insolubles.
21. The polymer of any of the above claims wherein the polymer comprises less than 3.0 mole % ethylene.
22. The polymer of any of the above claims where the polymer comprises diolefin.
23. The polymer of any of the above claims where the polymer comprises diolefin selected from the group consisting of 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene,cyclopentadiene, vinylnorbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, or combinations thereof.
24. The polymer of any of the above claims where the polymer has an Mz/Mn of 2 to 200.
25. The polymer of any of the above claims wherein the polymer has an Mz of 15,000 to 500,000.
26. The polymer of any of the above claims wherein the polymer has a SAFT
of 50 to 150°C.
of 50 to 150°C.
27. The polymer of any of the above claims wherein the polymer has a Shore A hardness of 95 or less.
28. The polymer of any of the above claims wherein the polymer has a set time of 5 seconds or less.
29. The polymer of any of the claims 1-17 and 19-28 wherein the polymer has an Mw/Mn of 2 to 75.
30. The polymer of any of the above claims wherein the polymer has a tensile strength at break of 0.5 MPa or more.
31. The polymer of any of the above claims wherein the polymer has a melt index of 900 dg/min or more.
32. The polymer of any of the above claims wherein the polymer is a homopolymer of propylene and or a copolymer of propylene and one or more of butene, pentene, hexene, octene, nonene, and decene, wherein the copolymer comprises less than 10 mole% ethylene, and wherein the homopolymer or copolymer has a Dot T-Peel of 3 or more Newtons; a viscosity of 7,000 mPasec/sec or less at 190 ° C; a branching index (g') of 0.85 or less measured at the Mz of the polymer; and an Mw of 100,000 or less.
33. The polymer of any of the above claims wherein the polymer comprises propylene, from 0 to 5 mol% ethylene, from 0 to 40 mol% of a C5 to C12 olefin, and 0 to 10 mol% of a diene.
34. The polymer of any of the above claims where the polymer comprises less than 1 mole% of ethylene and where the polymer has at least 2 mol%
(CH2)2 units.
(CH2)2 units.
35. The polymer of claim 34 wherein the polymer has at least 4 mol% (CH2)2 units.
36. The polymer of claim 34 wherein the polymer has at least 8 mol%!(CH2)2 units.
37. The polymer of claim 34 wherein the polymer has at least 15 mol%(CH2)2 units.
38. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 2 + X
mol% (CH2)2 units, where X is the mole % ethylene.
mol% (CH2)2 units, where X is the mole % ethylene.
39. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 4 + X
mol% (CH2)2 units.
mol% (CH2)2 units.
40. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 10 + X
mol% (CH2)2 units.
mol% (CH2)2 units.
41. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 15 + X
mol% (CH2)2 units.
mol% (CH2)2 units.
42. The polymer any of claims 1 to 41 where the polymer has a Dot T-Peel of 5 Newton or more.
43. The polymer any of claims 1 to 42 where the polymer has a Dot T-Peel of between 10 and 2000 Newtons.
44. The polymer any of claims 1 to 43 wherein the polymer has a Dot T-Peel of between 15 and 1000 Newtons.
45. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 3 mol% (CH2)2 units.
46. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 6 mol % (CH2)2 units.
47. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 10 mol % (CH2)2 units.
48. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 15 mol % (CH2)2 units.
49. The polymer of claim 109 where the amorphous component contains at least 20 mol % (CH2)2 units.
50. A composition comprising the polymer of any of claims 1 to 49 and one or hydrocarbon resins selected from the group consisting of aliphatic hydrocarbon resins, aromatic modified aliphatic hydrocarbon resins, hydrogenated polycyclopentadiene resins, polycyclopentadiene resins, gum rosins, gum rosin esters, wood rosins, wood rosin esters, tall oil rosins, tall oil rosins esters, polyterpenes, aromatic modified polyterpenes, terpene phenolics, aromatic modified hydrogenated polycyclopentadiene resins, hydrogenated aliphatic resin, hydrogenated aliphatic aromatic resins, hydrogenated terpenes and modified terpenes, and hydrogenated rosin esters.
51. The composition of claim 50 further wherein the hydrocarbon resin is present at 1 weight % to about 80 weight %.
52. The composition of claim 50 further wherein the hydrocarbon resin is present at less than 5% hydrocarbon resin.
53. A pallet comprising the polymer of any of claims 1 to 49.
54. A pellet comprising the composition of any of claims 50 to 52.
55. A continuous process to produce polymer of any of claims 1 to 49 comprising:
1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 15% or less under selected polymerization conditions;
2) selecting a second catalyst component capable of producing Polymer having an Mw of 100,000 or less and a crystallinity of 50% or more at the selected polymerization conditions;
3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins; and, 4) at a temperature of greater than 105°C;
5) at a residence time of 120 minutes or less;
5) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1;
7) wherein the activity of the catalyst components is at least 50 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer.
1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 15% or less under selected polymerization conditions;
2) selecting a second catalyst component capable of producing Polymer having an Mw of 100,000 or less and a crystallinity of 50% or more at the selected polymerization conditions;
3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins; and, 4) at a temperature of greater than 105°C;
5) at a residence time of 120 minutes or less;
5) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1;
7) wherein the activity of the catalyst components is at least 50 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer.
56. The process of claim 55 wherein the first catalyst component comprises a stereospecific metallocene catalyst compound.
57. The process of claim 55 wherein the first catalyst component comprises a non-stereospecific metallocene catalyst compound.
58. The process of claim 55, 56 or 57 wherein the second catalyst component comprises a stereospecific metallocene catalyst compound,
59. The process of claim 55 wherein the first catalyst component comprises one or more of dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(tetrametltylcyclopentadienyl)(t-butylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(s-butylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(n-butylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dichloride, diethylsilyl(tetramethylcyclogentadienyl)(1-adamantylamido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(tetramethylcyalopentadienyl}(oyclododecylarxzxdo) titaniwn dimetltyl, ditnethylsilyl(tetramethylcyclopentadienyl)(exo-2-norborr~ylamida}
titanium dimethyl, dimetlxylsiiyl(tetrarnethyleyelcpentadienyl)(cycloltexyl-atnido) titaaiuxn dimethyl, dirr~ethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dime'thylsilyi(2,5-dimetlaylcyclapentadienyl)(Gyclododeeylamido} titanium dichloride, dimethylsilyl(2,S-dimethylcycloperatadienyl)(exo-2-norhozxiylaznido) titanium dichlozide, dimethyl~iayl(2,5-dimethylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2,5-diraetltylcyclopentadiex~yl)(1-adamarltylamido) titaniu~rn dichloride, dimethylsilyl(3,4-dimethyleyclopentadienyl)(cyclododeaylamxdo) titanium dichloride, dirnethylsilyl(3,4-dixnethylcyclopentadienyl}(exo-2-noxbornylamido) titanium dichl4zide, dimEthylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamida) titanium dichloride, dimethylsilyl(3,4-dimethylcyclopentadiez~yl)(1-adamazatylamido) titanitun dichloride, disnethylsilyl(2-ethyl-S-methyleyclopentadiertyl}(cyclododacylamido)titanivrn dichloride, dimethylsilyl(2-ethyl-5-rnethyloyclopentadienyl)(exo-2-narbornyi~nido) titanium dichloride, dimethylsilyl(2-ethyl-5-methylcyclapentadienyl~(cyclohexylamido) titanium diehlpride, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(t-butylamido) titanium dimethyl, dimethylsilyl(tatramethylcyclopentadienyl)(s-butylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(n-butylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(exo-Z-norbomylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(exo-Z-norbomylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2,5S-dimethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2,S-dimethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl){cyclododecylamido)titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido) titanium dimethyl, and dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbomylamido) titanium dimethyl.
titanium dimethyl, dimetlxylsiiyl(tetrarnethyleyelcpentadienyl)(cycloltexyl-atnido) titaaiuxn dimethyl, dirr~ethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dime'thylsilyi(2,5-dimetlaylcyclapentadienyl)(Gyclododeeylamido} titanium dichloride, dimethylsilyl(2,S-dimethylcycloperatadienyl)(exo-2-norhozxiylaznido) titanium dichlozide, dimethyl~iayl(2,5-dimethylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2,5-diraetltylcyclopentadiex~yl)(1-adamarltylamido) titaniu~rn dichloride, dimethylsilyl(3,4-dimethyleyclopentadienyl)(cyclododeaylamxdo) titanium dichloride, dirnethylsilyl(3,4-dixnethylcyclopentadienyl}(exo-2-noxbornylamido) titanium dichl4zide, dimEthylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamida) titanium dichloride, dimethylsilyl(3,4-dimethylcyclopentadiez~yl)(1-adamazatylamido) titanitun dichloride, disnethylsilyl(2-ethyl-S-methyleyclopentadiertyl}(cyclododacylamido)titanivrn dichloride, dimethylsilyl(2-ethyl-5-rnethyloyclopentadienyl)(exo-2-narbornyi~nido) titanium dichloride, dimethylsilyl(2-ethyl-5-methylcyclapentadienyl~(cyclohexylamido) titanium diehlpride, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(t-butylamido) titanium dimethyl, dimethylsilyl(tatramethylcyclopentadienyl)(s-butylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(n-butylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(exo-Z-norbomylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(exo-Z-norbomylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2,5S-dimethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2,S-dimethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl){cyclododecylamido)titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido) titanium dimethyl, and dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbomylamido) titanium dimethyl.
60. The process of claim 55 wherein the second catalyst component comprises one or more of the racemic versions of:
dimethylsilyl (2-methyl-4-phenylindenyl) zirconium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl) zirconium dimethyl, dimethylsilyl (2-methyl-4-phenylindenyl) hafnium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl) hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dichloride, dimethylsilyl bis(indenyl)ziconium dimethyl, dimethylsilyl bis(indenyl)zirconium dichloride, the racemic isomers of:
dimethylsilanediylbis(2-methyl)metal dichloride;
dimethylsilanediylbis(indenyl)metal dichloride;
dimethylsilanediylbis(indenyl)metal dimethyl;
dimethylsilanediylbis(tetrahydroindenyl)metal dichloride;
dimethylsilanediylbis(tetrahydroindenyl)metal dimethyl;
dimethylsilanediylbis(indenyl)metal diethyl; and dibenzylsilanediylbis(indenyl)metal dimethyl;
wherein the metal can be chosen from Zr, Hf, or Ti.
dimethylsilyl (2-methyl-4-phenylindenyl) zirconium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl) zirconium dimethyl, dimethylsilyl (2-methyl-4-phenylindenyl) hafnium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl) hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dichloride, dimethylsilyl bis(indenyl)ziconium dimethyl, dimethylsilyl bis(indenyl)zirconium dichloride, the racemic isomers of:
dimethylsilanediylbis(2-methyl)metal dichloride;
dimethylsilanediylbis(indenyl)metal dichloride;
dimethylsilanediylbis(indenyl)metal dimethyl;
dimethylsilanediylbis(tetrahydroindenyl)metal dichloride;
dimethylsilanediylbis(tetrahydroindenyl)metal dimethyl;
dimethylsilanediylbis(indenyl)metal diethyl; and dibenzylsilanediylbis(indenyl)metal dimethyl;
wherein the metal can be chosen from Zr, Hf, or Ti.
61. The process of any of claims 55 to 60 wherein the activator comprises an alumoxane.
62. The process of any of claims 55 to 61 wherein the activator comprises an ionizing compound.
63. The process of any of claims 55 to 62 wherein the activator comprises a non-coordinating anion.
64. The process of any of claims 55 to 60 wherein the activator comprises one or more of methylalumoxane, trimethylammonium tetraphenylborate, triethylammonium tetraphenylborate, tripropylammonium tetraphenylborate, tri(n-butyl)ammonium tetraphenylborate, tri(t-butyl)ammonium tetraphenylborate, N,N-dimethylanilinium tetraphenylborate, N,N-diethylaniliniurn tetraphenylborate, N,N-dimethyl-(2,4,6-trimethylanilinium) tetraphenylborate, trimethylammonium tetrakis(pentafluorophenyl)borate, triethylammonium tetrakis(pentafluorophenyl)borate, tripropylammonium tetrakis(pentafluorophenyl)borate, tri(n-butyl)ammonium tetrakis(pentafluorophenyl)borate, tri(sec-butyl)ammonium tetrakis(pentafluorophenyl) borate, N,N-dimethylanilinium tetrakis(pentafluorophenyl) borate, N,N-diethylanilinium tetrakis(pentafluorophenyl) borate, N,N-dimethyl-(2,4,6-trimethylanilinium) tetrakis(pentafluorophenyl) borate, trimethylammonium tetrakis-(2,3,4,6-tetrafluorophenylborate, triethylammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, tripropylammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, tri(n-butyl)ammonium tetrakis-(2,3,4,6-tetrafluoro phenyl) borate, dimethyl(t-butyl)ammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, N,N-dimethylanilinium tetrakis.(2,3,4,6-tetrafluorophenyl) borate, N,N-diethylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, and N,N-dimethyl-(2,4,6-trimethylanilinium)tetrakis-(2,3,4,6-tetrafluorophenyl) borate;
di-(i-propyl)ammonium tetrakis(pentafluorophenyl) borate;
dicyclohexylammonium tetrakis(pentafluorophenyl) borate;
triphenylphosphonium tetrakis(pentafluorophenyl) borate;
tri(o-tolyl)phosphonium tetrakis(pentafluorophenyl) borate; and tri(2,6-dimethylphenyl)phosphonium tetrakis(pentafluorophenyl) borate.
di-(i-propyl)ammonium tetrakis(pentafluorophenyl) borate;
dicyclohexylammonium tetrakis(pentafluorophenyl) borate;
triphenylphosphonium tetrakis(pentafluorophenyl) borate;
tri(o-tolyl)phosphonium tetrakis(pentafluorophenyl) borate; and tri(2,6-dimethylphenyl)phosphonium tetrakis(pentafluorophenyl) borate.
65. The process of any of claims 55 to 64 wherein the first catalyst component as capable of polymerizing macromonomers having reactive termini; and the second component is capable of producing macromonomers having reactive termini.
66. The process of any of claims 55 to 65 further comprising diolefin.
67. The process of any of claims 55 to 65 further comprising one or more C4 to C40 dienes.
68. The process of any of claims 55 to 65 further comprising diene selected from the group consisting of 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, cyclopentadiene, vinylnorbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, or combinations thereof.
69. The process of any of claims 55 to 65 further comprising one or more dienes selected from the group consisting of 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, cyclopentadiene, vinylnorbornene, norbornadiene, etnylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, or combinations thereof.
70. The process of any of claims 55 to 69 wherein the reaction zone is a gas phase reactor.
71. The process of any of claims 55 to 69 wherein the reaction zone is a solution phase reactor.
72. The process of any of claims 55 to 69 wherein the reaction zone is a slurry phase reactor.
73. The process of any of claims 55 to 69 wherein the reaction zone is a solution phase reactor.
74. The process of any of claims 55 to 73 where the catalysts comprise one or more of the following combinations (where Me equals methyl, Ph equals phenyl, Et equals ethyl, Cp equals cyclopentadienyl, 3,8-di-t-BuFlu equals 3,8-di-tert-butylfluorenyl, 2-Me-4-PhInd equals 2-methyl-4-phenylindenyl, 2-MeInd equals 2-methylindenyl, c-C12H23 equals cyclododecyl, Me4C5 equals tetramethylcyclopentadienyl, H4Ind equals tetrahydroindenyl, and Ind equals indenyl):
(1) Me2Si(Me4C5)(N-c-C12H23)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(2) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator, (2a) Me2Si(Me4C5)(N-c-C12H13)TiMe2 and rac-Me2Si(2-Me-4 PhInd)2ZrMe2 activated with N,N-dimethylanillinium tetrakis(pentafluorophenyl)boron and or triphenylcarbonium tetrakis(pentafluorophenyl)boron;
(3) Me2Si(Me4C5)(N-c-C12H23)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(4) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(4a) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(5) Me2Si(Me4C5)(N-1-adamantyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(6) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(6a) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(7) Me2Si(Me4C5)(N-1-adamantyl)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(8) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(8a) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(9) Me2Si(Me4C5)(N-t-butyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(10) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-Me-4-Phind)2ZrMe2 activated with a non-coordinating anion activator;
(10a) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(11) Me2Si(Me4C5)(N-t-butyl)TiCl2 and rac-Me2Si(2-MeInd) activated with an alumoxane;
(12) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated With a nan-coordinating anion activator;
(12a) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and ar triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(13) Me2Si(Me4C5)(N-exo-norbornyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(14) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(14a) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(15) Me2Si(Me4C5)(N-exo-norbornyl)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(16) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(16a) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(17) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(18) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(18a) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(19) (p-Et3Siph)2C(Cp)(3,8-di-t-BuFlu)HfCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(20) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
Page 25a (20a) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(21) meso-CH2CH2(Ind)2ZrCl2 and rac-Me2Si(H4Ind)2ZrCl2 activated with an alumoxane;
(22) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with a non-coordinating anion activator;
(22a) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(23) meso-CH2CH2(Ind)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(24) meso-CH2CH2(Ind2)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(24a) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(25) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(He4Ind)2ZrCl2 activated with an alumoxane;
(26) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with a non-coordinating anion activator;
(26a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(27) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(28) meso-Me2Si(Ind)2ZrMe1 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(28a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(29) meso-Me2Si(2-MeInd)2ZrCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(30) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(30a) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(31) meso-Me2Si(2-MeInd)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(32) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(32a) meso-Me2Si(2-MeInd)2ZrMe2 sand rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(33) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(34) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(34a) mesa-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(35) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(36) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(36a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium;
tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(37) meso-Me2Si(2-Me-4-PhInd)2ZrCl2 and rac-Me2Si(2-ME-4-PhInd)2ZrCl2 activated with an alumoxane;
(38) meso-Me2Si(2-Me-4-PhInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(38a) meso-Me2Si(2-Me-4-PhInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(39) meso-CH2CH2(2-Me-4-PhInd)2ZrCl2 and rac-CH2CH2(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(40) meso-CH2CH2(2-Me-4-PhInd)2ZrMe2 and rac-CH2CH2(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(40a) meso-CH2CH2(2-Me-4-PhInd)2ZrMe2 and rac-CH2CH2(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(41) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-CH2CH2(2-MePhInd)2ZrCl2 activated with an alumoxane;
(42) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(42a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(43) meso-CH2CH2(Ind)2ZrCl2 and rac-CH3CH2(Ind)2ZrGl2 activated with an alumoxane;
(44) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(Ind)2ZrMe2 activated with a non-coordinating anion activator;
(44a) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2H2(Ind)2ZrMe2 activated with N,N'-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(45) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(Ind)2ZrCl2 activated with an alumoxane;
(46) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(Ind)2ZrMe2 activated with a non-coordinating anion activator;
(46a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(47) meso-CH2CH2(Ind)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 (4,7-Me2Ind = 4,7-dimethylindenyl) activated with an alumoxane;
(48) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(48a) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(49) meso-Me2Si(Ind)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 activated with an alumoxane;
(50) meso-Me2Si(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(50a) meso-Me2Si(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(51) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 (4,7-Me2Ind = 4,7-dimethylindenyl) activated with an alumoxane;
(52) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(52a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(53) meso-Me2-Si(2-MeInd)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 activated with an alumoxane;
(54) meso-Me2Si(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(54a) meso-Me2Si(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with such as N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(1) Me2Si(Me4C5)(N-c-C12H23)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(2) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator, (2a) Me2Si(Me4C5)(N-c-C12H13)TiMe2 and rac-Me2Si(2-Me-4 PhInd)2ZrMe2 activated with N,N-dimethylanillinium tetrakis(pentafluorophenyl)boron and or triphenylcarbonium tetrakis(pentafluorophenyl)boron;
(3) Me2Si(Me4C5)(N-c-C12H23)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(4) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(4a) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(5) Me2Si(Me4C5)(N-1-adamantyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(6) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(6a) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(7) Me2Si(Me4C5)(N-1-adamantyl)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(8) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(8a) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(9) Me2Si(Me4C5)(N-t-butyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(10) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-Me-4-Phind)2ZrMe2 activated with a non-coordinating anion activator;
(10a) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(11) Me2Si(Me4C5)(N-t-butyl)TiCl2 and rac-Me2Si(2-MeInd) activated with an alumoxane;
(12) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated With a nan-coordinating anion activator;
(12a) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and ar triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(13) Me2Si(Me4C5)(N-exo-norbornyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(14) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(14a) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(15) Me2Si(Me4C5)(N-exo-norbornyl)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(16) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(16a) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(17) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(18) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(18a) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(19) (p-Et3Siph)2C(Cp)(3,8-di-t-BuFlu)HfCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(20) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
Page 25a (20a) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(21) meso-CH2CH2(Ind)2ZrCl2 and rac-Me2Si(H4Ind)2ZrCl2 activated with an alumoxane;
(22) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with a non-coordinating anion activator;
(22a) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(23) meso-CH2CH2(Ind)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(24) meso-CH2CH2(Ind2)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(24a) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(25) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(He4Ind)2ZrCl2 activated with an alumoxane;
(26) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with a non-coordinating anion activator;
(26a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(27) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(28) meso-Me2Si(Ind)2ZrMe1 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(28a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(29) meso-Me2Si(2-MeInd)2ZrCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(30) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(30a) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(31) meso-Me2Si(2-MeInd)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(32) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(32a) meso-Me2Si(2-MeInd)2ZrMe2 sand rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(33) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(34) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(34a) mesa-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(35) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(36) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(36a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium;
tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(37) meso-Me2Si(2-Me-4-PhInd)2ZrCl2 and rac-Me2Si(2-ME-4-PhInd)2ZrCl2 activated with an alumoxane;
(38) meso-Me2Si(2-Me-4-PhInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(38a) meso-Me2Si(2-Me-4-PhInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(39) meso-CH2CH2(2-Me-4-PhInd)2ZrCl2 and rac-CH2CH2(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(40) meso-CH2CH2(2-Me-4-PhInd)2ZrMe2 and rac-CH2CH2(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(40a) meso-CH2CH2(2-Me-4-PhInd)2ZrMe2 and rac-CH2CH2(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(41) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-CH2CH2(2-MePhInd)2ZrCl2 activated with an alumoxane;
(42) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(42a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(43) meso-CH2CH2(Ind)2ZrCl2 and rac-CH3CH2(Ind)2ZrGl2 activated with an alumoxane;
(44) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(Ind)2ZrMe2 activated with a non-coordinating anion activator;
(44a) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2H2(Ind)2ZrMe2 activated with N,N'-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(45) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(Ind)2ZrCl2 activated with an alumoxane;
(46) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(Ind)2ZrMe2 activated with a non-coordinating anion activator;
(46a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(47) meso-CH2CH2(Ind)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 (4,7-Me2Ind = 4,7-dimethylindenyl) activated with an alumoxane;
(48) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(48a) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(49) meso-Me2Si(Ind)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 activated with an alumoxane;
(50) meso-Me2Si(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(50a) meso-Me2Si(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(51) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 (4,7-Me2Ind = 4,7-dimethylindenyl) activated with an alumoxane;
(52) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(52a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(53) meso-Me2-Si(2-MeInd)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 activated with an alumoxane;
(54) meso-Me2Si(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(54a) meso-Me2Si(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with such as N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
75. The process of any of claims 55 to 74 wherein the second catalyst component comprises one or more of:
dimethylsiladiyl(2-methyl, 4-(3',5',di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl{2-iso-propyl, 4-[3',5'-di-tbutylphenyl]2indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladlyl(2-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3'5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium, dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl)indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso butyl, 4-[3',5'-di..tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
4-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',3'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-(3',5'-bis- trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluorendiyl{2-iso-propyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluotendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-his-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis- trifluoromethylphenyl]indenyl)2 hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride dimethylsiladiyl(2-iso-propyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-isobutyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso propylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di- iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3';5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-(3',3'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-(3',5'_di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylpbenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyi]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl}2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4.-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-his-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di- iso propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3 butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9.silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl))2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl))2 .eta.4-1,4-biphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylanaidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride, dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride:
dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4 1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4 1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane{2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4.
diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-(3',5'-di-tbutylphenyl]indenyl)2 zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenylindenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2.eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1, 4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2-zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborarane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)zirconium dimethyl;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3,5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl(2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)}2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis{trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl}2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5' bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl(2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4- 1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5' -di-phenylphenyl]indenyl)2 .eta.4-1,4.diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3,5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl; or bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl.
dimethylsiladiyl(2-methyl, 4-(3',5',di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl{2-iso-propyl, 4-[3',5'-di-tbutylphenyl]2indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladlyl(2-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3'5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium, dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl)indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso butyl, 4-[3',5'-di..tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
4-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',3'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-(3',5'-bis- trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluorendiyl{2-iso-propyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluotendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-his-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis- trifluoromethylphenyl]indenyl)2 hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride dimethylsiladiyl(2-iso-propyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-isobutyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso propylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di- iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3';5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-(3',3'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-(3',5'_di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylpbenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyi]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl}2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4.-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-his-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di- iso propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3 butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9.silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl))2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl))2 .eta.4-1,4-biphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylanaidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride, dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride:
dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4 1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4 1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane{2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4.
diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-(3',5'-di-tbutylphenyl]indenyl)2 zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenylindenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2.eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1, 4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2-zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborarane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)zirconium dimethyl;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3,5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl(2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)}2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis{trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl}2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5' bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl(2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4- 1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5' -di-phenylphenyl]indenyl)2 .eta.4-1,4.diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3,5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl; or bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl.
76. The process of any of claims 55 to 75 wherein the second catalyst component comprises one or more of bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl.
77. A continuous process to prepare an adhesive comprising:
1) ~combining monomer, solvent, catalyst and activator in a reactor system, 2) ~withdrawing polymer solution from the reactor system, 3) ~removing at least 10% solvent from the polymer solution, 4) ~quenching the reaction, 5)~devolatilizing the polymer solution to form molten polymer, 6) ~combining the molten polymer and one or more additives in a static mixer, 7) ~removing the polymer combination from the static mixer, and 8) ~pelletizing or drumming the polymer combination.
1) ~combining monomer, solvent, catalyst and activator in a reactor system, 2) ~withdrawing polymer solution from the reactor system, 3) ~removing at least 10% solvent from the polymer solution, 4) ~quenching the reaction, 5)~devolatilizing the polymer solution to form molten polymer, 6) ~combining the molten polymer and one or more additives in a static mixer, 7) ~removing the polymer combination from the static mixer, and 8) ~pelletizing or drumming the polymer combination.
78. A continuous process in accordance with claim 55 to produce a branched olefin polymer comprising wherein:
1) ~the first catalyst component is capable of producing a polymer having an Mw of 80,000 or less and a crystallinity of 5% or less under selected polymerization conditions;
2) ~the second catalyst component capable of producing polymer having an Mw of 80,000 or less and a crystallinity of 20% or more at the selected polymerization conditions;
3) ~contacting the catalyst components in the presence of one or more activators with propylene and one or more C4 to C20 olefins, and, optionally one or more C4 to C20 diolefins;
4) ~at a temperature of greater than 100°C;
5) ~wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 20:1;
6) ~wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer.
1) ~the first catalyst component is capable of producing a polymer having an Mw of 80,000 or less and a crystallinity of 5% or less under selected polymerization conditions;
2) ~the second catalyst component capable of producing polymer having an Mw of 80,000 or less and a crystallinity of 20% or more at the selected polymerization conditions;
3) ~contacting the catalyst components in the presence of one or more activators with propylene and one or more C4 to C20 olefins, and, optionally one or more C4 to C20 diolefins;
4) ~at a temperature of greater than 100°C;
5) ~wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 20:1;
6) ~wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer.
79. The process of claim 78 wherein:
a) ~the olefins comprise propylene and one or more of butane, pentane, hexene, heptene, octane; nonene, decene, dodecene; and b) ~the temperature is greater than 110°C; and c) ~the residence time is 60 to 120 minutes; and d) ~the ratio of the first catalyst to the second catalyst is from 1:1 to 1:10.
a) ~the olefins comprise propylene and one or more of butane, pentane, hexene, heptene, octane; nonene, decene, dodecene; and b) ~the temperature is greater than 110°C; and c) ~the residence time is 60 to 120 minutes; and d) ~the ratio of the first catalyst to the second catalyst is from 1:1 to 1:10.
80. ~The process of claim 78 or 79 wherein the diolefin is present and is selected from the group consisting of 1,6-heptadiene, 1,7-octadiene,1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene,1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, cyclopentadiene, vinylnorbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, butadiene, pentadiene, hexadiene, pentadecadiene, hexadecadiene, heptadecadiene, octadecadiene, nonadecadiene, icosadiene, heneicosadiene, docosadiene, tricosadiene, tetracosadiene, pentacosadiene, hexacosadiene, heptacosadiene, octacosadiene, nonacosadiene, triacontadiene, cyclopentadiene, vinylnorbornene, norbornediene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, or combinations thereof.
81. ~The process of claim 78, 79 or 80 wherein the olefin comprises propylene and one or more of butane, pentene, hexene, heptene, octene, nonene, decene, dodecene, 4-methyl-pentene-1, 3-methyl pentene-1, and 3,5,5-trimethyl-hexane-1.
82, ~A continuous process to make an adhesive comprising 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions;
2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 ar less and a crystallinity of 20% or more at the selected polymerization conditions;
3) ~contacting, in a solvent and in a reaction zone under the selected polymerization conditions, the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins;
4) ~at a temperature of greater than 100°C;
5)~at a residence time of 120 minutes or less;
6) ~wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1;
7) ~wherein the activity of the catalyst components is at least 50 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer;
8) ~withdrawing polymer solution from the reaction zone;
9) ~removing at least 10% solvent from the polymer solution;
10) ~quenching the reaction;
11) ~devolatilizing the polymer solution to form molten polymer;
12) ~combining the molten polymer and one or more additives in a static mixer;
13) ~removing the polymer combination from the static mixer; and 14) ~pelletizing or drumming the polymer combination.
2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 ar less and a crystallinity of 20% or more at the selected polymerization conditions;
3) ~contacting, in a solvent and in a reaction zone under the selected polymerization conditions, the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins;
4) ~at a temperature of greater than 100°C;
5)~at a residence time of 120 minutes or less;
6) ~wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1;
7) ~wherein the activity of the catalyst components is at least 50 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer;
8) ~withdrawing polymer solution from the reaction zone;
9) ~removing at least 10% solvent from the polymer solution;
10) ~quenching the reaction;
11) ~devolatilizing the polymer solution to form molten polymer;
12) ~combining the molten polymer and one or more additives in a static mixer;
13) ~removing the polymer combination from the static mixer; and 14) ~pelletizing or drumming the polymer combination.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41848202P | 2002-10-15 | 2002-10-15 | |
US60/418,482 | 2002-10-15 | ||
US46071403P | 2003-04-04 | 2003-04-04 | |
US60/460,714 | 2003-04-04 | ||
PCT/US2003/032910 WO2004046214A2 (en) | 2002-10-15 | 2003-10-15 | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2499951A1 true CA2499951A1 (en) | 2004-06-03 |
CA2499951C CA2499951C (en) | 2013-05-28 |
Family
ID=32329058
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2499951 Expired - Fee Related CA2499951C (en) | 2002-10-15 | 2003-10-15 | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
Country Status (10)
Country | Link |
---|---|
US (6) | US7294681B2 (en) |
EP (3) | EP2261292B1 (en) |
JP (1) | JP4972284B2 (en) |
KR (1) | KR101113341B1 (en) |
CN (2) | CN101838362B (en) |
AU (2) | AU2003304716A1 (en) |
BR (1) | BR0315341B1 (en) |
CA (1) | CA2499951C (en) |
ES (1) | ES2394304T3 (en) |
WO (2) | WO2005108442A1 (en) |
Families Citing this family (486)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7919561B2 (en) * | 1996-09-04 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Process of producing thermoplastic polymer blends |
US20060263531A1 (en) * | 2003-12-18 | 2006-11-23 | Lichtenhan Joseph D | Polyhedral oligomeric silsesquioxanes as glass forming coatings |
US20080075872A1 (en) * | 1999-08-04 | 2008-03-27 | Lichtenhan Joseph D | Nanoscopic Assurance Coating for Lead-Free Solders |
JP4748908B2 (en) * | 1999-09-10 | 2011-08-17 | ザ・ユニバーシティ・オブ・シドニー | Dipeptidyl peptidase |
US6891960B2 (en) | 2000-08-12 | 2005-05-10 | Facet Technology | System for road sign sheeting classification |
US6674878B2 (en) * | 2001-06-07 | 2004-01-06 | Facet Technology Corp. | System for automated determination of retroreflectivity of road signs and other reflective objects |
US7776446B2 (en) * | 2001-06-04 | 2010-08-17 | Saint-Gobain Performance Plastics Corporation | Multi-layer release films |
ATE396472T1 (en) | 2002-06-26 | 2008-06-15 | Avery Dennison Corp | LENGTH-ORIENTED POLYMERIC FILMS |
US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
US7662885B2 (en) | 2002-08-12 | 2010-02-16 | Exxonmobil Chemical Patents Inc. | Method to make an article comprising polymer concentrate |
WO2004014997A2 (en) | 2002-08-12 | 2004-02-19 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
CA2500956C (en) | 2002-10-01 | 2011-09-13 | Paul C. Downey | Noise and vibration mitigating mat |
US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
KR101113341B1 (en) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US8653169B2 (en) * | 2002-10-15 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7700707B2 (en) * | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US8618219B2 (en) * | 2002-10-15 | 2013-12-31 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US20040175466A1 (en) | 2003-03-07 | 2004-09-09 | Douglas Michael J. | Multilayer barrier structures, methods of making the same and packages made therefrom |
US20040175464A1 (en) | 2003-03-07 | 2004-09-09 | Blemberg Robert J. | Multilayer structures, packages, and methods of making multilayer structures |
US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
JP4397895B2 (en) * | 2003-10-03 | 2010-01-13 | 株式会社クレハ | Stretch-molded multilayer container and method for producing the same |
US7872168B2 (en) * | 2003-10-31 | 2011-01-18 | Kimberely-Clark Worldwide, Inc. | Stretchable absorbent article |
US7144933B2 (en) | 2003-11-12 | 2006-12-05 | Eastman Chemical Company | Modified asphalt compositions |
US7202290B2 (en) * | 2003-11-12 | 2007-04-10 | Eastman Chemical Company | Modified asphalt compositions |
US7235280B2 (en) * | 2003-11-12 | 2007-06-26 | Srs Technologies, Inc. | Non-intrusive photogrammetric targets |
US20110236699A1 (en) * | 2003-11-14 | 2011-09-29 | Tundra Composites, LLC | Work piece comprising metal polymer composite with metal insert |
US9105382B2 (en) | 2003-11-14 | 2015-08-11 | Tundra Composites, LLC | Magnetic composite |
US20100280164A1 (en) | 2009-04-29 | 2010-11-04 | Tundra Composites, LLC. | Inorganic Composite |
JP2005146212A (en) * | 2003-11-19 | 2005-06-09 | Three M Innovative Properties Co | Single-sided adhesive tape |
DK1711558T3 (en) * | 2004-01-30 | 2008-09-22 | Renolit Ag | Syndiotactic polypropylene composition comprising a thermoplastic elastomer |
WO2005090427A2 (en) | 2004-03-17 | 2005-09-29 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
US7524911B2 (en) | 2004-03-17 | 2009-04-28 | Dow Global Technologies Inc. | Adhesive and marking compositions made from interpolymers of ethylene/α-olefins |
RU2375381C2 (en) * | 2004-03-17 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. | Catalyst composition, containing shuttle agent, for formation of multi-block-copolymer of higher olefin |
EP1727840B1 (en) | 2004-03-17 | 2012-10-24 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
US7589145B2 (en) * | 2004-04-15 | 2009-09-15 | Exxonmobil Chemical Patents Inc. | Syndiotactic rich polyolefins |
US7645829B2 (en) * | 2004-04-15 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Plasticized functionalized propylene copolymer adhesive composition |
US7258930B2 (en) | 2004-04-28 | 2007-08-21 | Cryovac, Inc. | Oxygen scavenging film with cyclic olefin copolymer |
US7590310B2 (en) | 2004-05-05 | 2009-09-15 | Facet Technology Corp. | Methods and apparatus for automated true object-based image analysis and retrieval |
US20050284338A1 (en) * | 2004-06-01 | 2005-12-29 | Dwyer Patrick A | Hot melt adhesive |
WO2006025949A2 (en) * | 2004-07-08 | 2006-03-09 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US7537840B2 (en) | 2004-08-05 | 2009-05-26 | H.B. Licensing & Financing, Inc. | Polyamide adhesive and articles including the same |
ES2416314T3 (en) | 2004-08-27 | 2013-07-31 | Chevron Phillips Chemical Company Lp | Polyolefin production processes |
KR100478631B1 (en) * | 2004-08-31 | 2005-03-23 | 주식회사 유닉스라바 | Coloring binder for pavement of a road and method for producing the same |
US20060062951A1 (en) * | 2004-09-23 | 2006-03-23 | Fina Technology, Inc. | Opaque films for use in packaging |
US20060083928A1 (en) * | 2004-10-15 | 2006-04-20 | Ajinomoto Co. Inc | Resin composition |
WO2006045086A2 (en) | 2004-10-20 | 2006-04-27 | E.I. Dupont De Nemours And Company | Additive package for thermoplastic condensation polymers |
GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
CA2486829A1 (en) * | 2004-11-04 | 2006-05-04 | Christopher John Nichols | Tile coating |
US20070287779A1 (en) * | 2004-11-10 | 2007-12-13 | Kaneka Corporation | Composition for Cap Liner, and Cap Liner Using the Same |
ATE552301T1 (en) | 2004-11-25 | 2012-04-15 | Mitsui Chemicals Inc | PROPYLENE RESIN COMPOSITION AND USE THEREOF |
US20060165929A1 (en) * | 2004-12-07 | 2006-07-27 | Lenges Geraldine M | Multilayer composite films and articles prepared therefrom |
US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
US20060155082A1 (en) * | 2005-01-10 | 2006-07-13 | Mcdaniel Max P | Process for producing polymers |
DE602006010027D1 (en) | 2005-02-03 | 2009-12-10 | Basell Poliolefine Srl | PROPYLENE POLYMER COMPOSITION FOR INJECTION MOLDING |
WO2006102106A1 (en) * | 2005-03-17 | 2006-09-28 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
JP5231987B2 (en) * | 2005-03-17 | 2013-07-10 | ダウ グローバル テクノロジーズ エルエルシー | Adhesive and marking composition produced from ethylene / α-olefin copolymer |
JP2008539290A (en) * | 2005-04-28 | 2008-11-13 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | Propylene polymer composition for thermoforming |
US20060244187A1 (en) * | 2005-05-02 | 2006-11-02 | Downey Paul C | Vibration damper |
US7451041B2 (en) | 2005-05-06 | 2008-11-11 | Facet Technology Corporation | Network-based navigation system having virtual drive-thru advertisements integrated with actual imagery from along a physical route |
US20060266472A1 (en) * | 2005-05-06 | 2006-11-30 | Kipp Michael D | Vacuum bagging methods and systems |
BRPI0612441A2 (en) * | 2005-05-12 | 2010-11-23 | Basell Poliolefine Srl | propylene ethylene copolymers and process for their preparation |
DE102005023280A1 (en) * | 2005-05-20 | 2006-11-23 | Pütz GmbH + Co. Folien KG | cling film |
TW200708544A (en) * | 2005-05-24 | 2007-03-01 | Hybrid Plastics Inc | Polyhedral oligomeric silsesquioxanes as glass forming coatings |
US7928164B2 (en) | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
US7951872B2 (en) * | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
EP1896537B1 (en) * | 2005-06-24 | 2017-10-11 | ExxonMobil Chemical Patents Inc. | Functionalized propylene copolymer adheside composition |
JP4991710B2 (en) * | 2005-06-24 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | Plasticized functional propylene copolymer adhesive composition |
CN101213249B (en) * | 2005-07-01 | 2012-02-01 | 巴塞尔聚烯烃意大利有限责任公司 | Propylene polymers having broad molecular weight distribution |
WO2007011541A1 (en) | 2005-07-15 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
US7989670B2 (en) | 2005-07-19 | 2011-08-02 | Exxonmobil Chemical Patents Inc. | Process to produce high viscosity fluids |
US8748361B2 (en) | 2005-07-19 | 2014-06-10 | Exxonmobil Chemical Patents Inc. | Polyalpha-olefin compositions and processes to produce the same |
WO2007011462A1 (en) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Lubricants from mixed alpha-olefin feeds |
US20070110951A1 (en) * | 2005-07-20 | 2007-05-17 | Frank Hoefflin | Thermally expansible material substantially free of tackifier |
KR101240656B1 (en) | 2005-08-01 | 2013-03-08 | 삼성디스플레이 주식회사 | Flat panel display and manufacturing method of flat panel display |
US20070055210A1 (en) * | 2005-09-06 | 2007-03-08 | Mama Happily Dress Fasch Ltd. | Sanitary napkin |
BRPI0617042B1 (en) * | 2005-09-15 | 2018-05-15 | Dow Global Technologies Inc. | PROCESS FOR PREPARING A RAMIFIED POLYMER, PROCESS FOR PREPARING A MULTI-RAMIFIED BLOCK PSEUDO AND RAMIFIED BLOCK POLYMER |
AU2006311913A1 (en) * | 2005-11-04 | 2007-05-18 | Dow Global Technologies Inc. | Coagent-mediated, grafted copolymers |
US8048947B2 (en) * | 2005-11-08 | 2011-11-01 | Exxonmobil Chemical Patents Inc. | Nanocomposites and methods for making the same |
US7750078B2 (en) * | 2005-12-07 | 2010-07-06 | Exxonmobil Chemical Patents Inc. | Systems and methods used for functionalization of polymeric material and polymeric materials prepared therefrom |
US20070141366A1 (en) * | 2005-12-21 | 2007-06-21 | Janet Rivett | Multilayer film with hot tack property |
US7758803B2 (en) * | 2006-01-11 | 2010-07-20 | Jiang Chang | Resorbable macroporous bioactive glass scaffold and method of manufacture |
US20090038701A1 (en) | 2006-01-17 | 2009-02-12 | Baxter International Inc. | Device, system and method for mixing |
US7776428B2 (en) * | 2006-02-13 | 2010-08-17 | Saint-Gobain Performance Plastics Corporation | Multi-layer release films |
US20070202311A1 (en) * | 2006-02-28 | 2007-08-30 | Saint-Gobain Performance Plastics Corporation | Multi-layer release films |
CN100345932C (en) * | 2006-03-01 | 2007-10-31 | 西南石油学院 | Cement permeation promoter for oil and gas well |
EP1840164A1 (en) * | 2006-03-30 | 2007-10-03 | SOLVAY INDUSTRIAL FOILS MANAGEMENT AND RESEARCH (Société Anonyme) | Retortable composition |
KR100880519B1 (en) * | 2006-04-07 | 2009-01-28 | 주식회사 엘지화학 | Olefin-Acrylate-Maleic Acid Anhydride-Norbornene Four-Composite Copolymer and Method for Preparing the Same |
US8557359B2 (en) * | 2006-04-12 | 2013-10-15 | Abbott Laboratories | Closure for container |
US20070244204A1 (en) * | 2006-04-13 | 2007-10-18 | Evelyne Prat | Rheology enhancers in non-oilfield applications |
US8003739B2 (en) * | 2007-10-17 | 2011-08-23 | Fina Technology, Inc. | Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins |
US8501675B2 (en) | 2006-06-06 | 2013-08-06 | Exxonmobil Research And Engineering Company | High viscosity novel base stock lubricant viscosity blends |
US8834705B2 (en) | 2006-06-06 | 2014-09-16 | Exxonmobil Research And Engineering Company | Gear oil compositions |
US8535514B2 (en) | 2006-06-06 | 2013-09-17 | Exxonmobil Research And Engineering Company | High viscosity metallocene catalyst PAO novel base stock lubricant blends |
US8299007B2 (en) | 2006-06-06 | 2012-10-30 | Exxonmobil Research And Engineering Company | Base stock lubricant blends |
US8921290B2 (en) | 2006-06-06 | 2014-12-30 | Exxonmobil Research And Engineering Company | Gear oil compositions |
ES2398725T3 (en) | 2006-06-14 | 2013-03-21 | Avery Dennison Corporation | Label material oriented in the longitudinal direction that can be shaped and cut with die and labels and process for its preparation |
US7744722B1 (en) | 2006-06-15 | 2010-06-29 | Clearwater Specialties, LLC | Methods for creping paper |
US20070292655A1 (en) * | 2006-06-19 | 2007-12-20 | Lear Corporation | Tuft coating |
EP2035226A2 (en) * | 2006-06-20 | 2009-03-18 | Avery Dennison Corporation | Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof |
US8785531B2 (en) * | 2006-07-06 | 2014-07-22 | Dow Global Technologies Llc | Dispersions of olefin block copolymers |
US8916640B2 (en) * | 2006-07-06 | 2014-12-23 | Dow Global Technologies Llc | Blended polyolefin dispersions |
US20080009573A1 (en) * | 2006-07-10 | 2008-01-10 | Ching Wah Chong | Labeled tackifiers |
JP5555490B2 (en) | 2006-07-19 | 2014-07-23 | エクソンモービル・ケミカル・パテンツ・インク | Method for producing polyolefin using metallocene catalyst |
EP2046559B1 (en) | 2006-07-28 | 2019-01-09 | LORD Corporation | Method for bonding metal surfaces with dual cure adhesive formulations |
US7641964B2 (en) * | 2006-08-03 | 2010-01-05 | Saint-Gobain Performance Pastics Corporation | Roofing membrane |
WO2008130425A1 (en) * | 2006-08-10 | 2008-10-30 | Adco Products, Inc. | Curable sealing method and foamed composition |
US20080045102A1 (en) * | 2006-08-15 | 2008-02-21 | Gerald Timothy Keep | Controlled flow polymer blends and products including the same |
US20080073366A1 (en) * | 2006-08-22 | 2008-03-27 | Backaert Dimitri M C J | Fast freeze container and seal |
US7799840B2 (en) * | 2006-09-12 | 2010-09-21 | Intellectual Property Holdings, Llc | Thermoplastic vibrational damper with constraining layer |
JP4999413B2 (en) * | 2006-09-22 | 2012-08-15 | 日東電工株式会社 | Pressure sensitive adhesive sheet with release liner |
CN101517028B (en) * | 2006-09-27 | 2013-07-17 | H.B.富勒公司 | Hot melt pressure sensitive adhesive composition that includes vegetable wax and articles including the same |
DE102006049089A1 (en) | 2006-10-18 | 2008-04-30 | Clariant International Limited | Hotmelt |
CN101631911B (en) * | 2006-11-13 | 2013-08-21 | 肖氏工业集团公司 | Methods and systems for recycling carpet and carpets manufactured from recycled material |
US7745544B2 (en) | 2006-11-30 | 2010-06-29 | Exxonmobil Chemical Patents Inc. | Catalytic epoxidation and hydroxylation of olefin/diene copolymers |
US7713636B2 (en) * | 2006-12-15 | 2010-05-11 | Exxonmobil Chemical Patents Inc. | Multi-layer films comprising propylene-based polymers |
DE102007041734A1 (en) * | 2006-12-20 | 2008-06-26 | Tesa Ag | Repulpable adhesives |
CN101563422B (en) * | 2006-12-21 | 2012-06-27 | 巴斯夫欧洲公司 | Article, especially cable sheathing, comprising thermoplastic polyurethane and crosslinked polyethylene in adhesive-bonded form |
CN101679911B (en) * | 2007-02-12 | 2012-02-08 | 陶氏环球技术有限责任公司 | Composite |
US7744306B2 (en) * | 2007-04-02 | 2010-06-29 | Greer Robert F | Preformed thermoplastic indicia for airport runways and taxiways |
US8993672B2 (en) * | 2007-04-09 | 2015-03-31 | The Regents Of The University Of California | Soft and strong elastomeric compositions from semicrystalline-amorphous polyolefin block copolymers |
US8603628B2 (en) * | 2007-04-30 | 2013-12-10 | Saint-Gobain Performance Plastics Corporation | Turbine blade protective barrier |
US10174499B1 (en) * | 2007-05-01 | 2019-01-08 | Pacific Coast Building Products, Inc. | Acoustical sound proofing material for architectural retrofit applications and methods for manufacturing same |
WO2008137285A1 (en) * | 2007-05-02 | 2008-11-13 | Dow Global Technologies Inc. | Batch inclusion packages |
US7943711B2 (en) * | 2007-05-14 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Ethylene elastomer compositions |
US20080286547A1 (en) * | 2007-05-18 | 2008-11-20 | Hubbard Michael A | Polypropylene films with enhanced moisture barrier properties, process for making and composition thereof |
CA2693581C (en) * | 2007-07-06 | 2015-11-24 | Henkel Corporation | Acrylic adhesives |
DE102007031967A1 (en) * | 2007-07-10 | 2009-01-15 | Clariant International Limited | Polyolefin-based building materials |
US20110293834A1 (en) * | 2007-08-15 | 2011-12-01 | Allen David P | Thermal Activated Pressure Sensitive Adhesive and Method for Producing the Same and Product therewith |
US20090047514A1 (en) * | 2007-08-15 | 2009-02-19 | Allen David P | Thermal Activated Pressure Sensitive Adhesive and Method for Producing the Same and Product therewith |
US20090053959A1 (en) * | 2007-08-21 | 2009-02-26 | Sudhin Datta | Soft and Elastic Nonwoven Polypropylene Compositions |
WO2011047194A1 (en) * | 2009-10-14 | 2011-04-21 | Adco Products, Inc. | Edge sealants having balanced properties |
US9115272B2 (en) | 2007-09-20 | 2015-08-25 | Adco Products Llc | Edge sealants having balanced properties |
TW200932770A (en) | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Metallocene catalysts and their use in polymerization processes |
WO2009059007A2 (en) * | 2007-10-31 | 2009-05-07 | Lord Corporation | Additives for improved adhesion to oily substrates |
US20090119175A1 (en) * | 2007-11-07 | 2009-05-07 | John Richardson | Tape sealant |
DE102007052965A1 (en) * | 2007-11-07 | 2009-05-14 | Clariant International Limited | Casting compositions containing waxes especially based on metallocene-catalyzed polyolefins, in particular for the encapsulation of electronic devices and components |
DE102007054614A1 (en) * | 2007-11-15 | 2009-05-20 | Clariant International Ltd. | Wax and polymer formulations containing metallocene-catalyzed polyolefins with and without filler, which are particularly suitable for cutting model production processes and their use for precision casting processes, hollow core production especially in the dental, jewelry and precision engineering sector |
US7910679B2 (en) * | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
AU2008346209B2 (en) | 2007-12-31 | 2013-06-20 | Pacey Innovations Limited | Flexible marking systems |
MX2010007764A (en) | 2008-01-18 | 2010-11-10 | Wild River Consulting Group Llc | Melt molding polymer composite and method of making and using the same. |
US8143353B2 (en) | 2008-01-18 | 2012-03-27 | Exxonmobil Chemical Patents Inc. | Polymerization process and adhesives therefrom |
WO2009097069A1 (en) | 2008-01-31 | 2009-08-06 | Exxonmobil Chemical Patents Inc. | Improved utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins |
US8076407B2 (en) * | 2008-02-08 | 2011-12-13 | Henkel Ag & Co. Kgaa | Hot melt adhesive |
ES2306616B1 (en) | 2008-02-12 | 2009-07-24 | Fundacion Cidaut | PROCEDURE FOR DETERMINATION OF THE LUMINANCE OF TRAFFIC SIGNS AND DEVICE FOR THEIR REALIZATION. |
WO2009103849A1 (en) * | 2008-02-18 | 2009-08-27 | Upm-Kymmene Wood Oy | Coated wood board |
US20090208685A1 (en) * | 2008-02-20 | 2009-08-20 | Sealed Air Corporation (Us) | Packaging film and method of decreasing scalping of polar cyclic compounds |
US8865959B2 (en) | 2008-03-18 | 2014-10-21 | Exxonmobil Chemical Patents Inc. | Process for synthetic lubricant production |
CN101981140B (en) * | 2008-03-28 | 2014-05-07 | 日清食品控股株式会社 | Ink composition for printing, paper container material using the ink composition, and heat insulating foamed paper container |
CN101977944A (en) | 2008-03-31 | 2011-02-16 | 埃克森美孚化学专利公司 | Production of shear-stable high viscosity pao |
EP2113541A1 (en) | 2008-04-28 | 2009-11-04 | Borealis AG | Adhesive propylene polymer composition suitable for extrusion coating of paper substrates |
US8642144B2 (en) * | 2008-05-28 | 2014-02-04 | Bemis Company, Inc. | Innerliner with nylon skin layer |
US8283400B2 (en) * | 2008-06-09 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
US8242198B2 (en) * | 2008-06-09 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
US8431642B2 (en) * | 2008-06-09 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
EP2300388A2 (en) * | 2008-06-16 | 2011-03-30 | The Texas A&M University System | Glass hardening methods and compositions |
US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
US8283428B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
US8283419B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
US8372930B2 (en) * | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
US8399725B2 (en) * | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
US7901780B2 (en) * | 2008-06-25 | 2011-03-08 | Solutia Inc. | Polymer interlayers comprising blends of plasticized poly(vinyl butyral) and poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester |
US20090324879A1 (en) * | 2008-06-27 | 2009-12-31 | 3M Innovative Properties Company | Sheet material having folded construction for inhibiting its separation from adhesive tape during dispensing of the same and methods of using and making the same |
JP5519659B2 (en) * | 2008-07-04 | 2014-06-11 | エルジー・ケム・リミテッド | Emissive liquid crystal compound, optical film including the same, and liquid crystal display device |
US8580902B2 (en) * | 2008-08-01 | 2013-11-12 | Exxonmobil Chemical Patents Inc. | Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom |
DE102008041278A1 (en) * | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Use of polyolefins as adhesion promoters for the production of laminates |
WO2010019802A1 (en) | 2008-08-15 | 2010-02-18 | Gesturetek, Inc. | Enhanced multi-touch detection |
US8394746B2 (en) | 2008-08-22 | 2013-03-12 | Exxonmobil Research And Engineering Company | Low sulfur and low metal additive formulations for high performance industrial oils |
US8476205B2 (en) | 2008-10-03 | 2013-07-02 | Exxonmobil Research And Engineering Company | Chromium HVI-PAO bi-modal lubricant compositions |
JP5481489B2 (en) * | 2008-11-19 | 2014-04-23 | エクソンモービル・ケミカル・パテンツ・インク | Adhesive composition and method for producing an adhesive composition |
US8093335B2 (en) * | 2008-12-15 | 2012-01-10 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin in-reactor blends and molded articles therefrom |
ES2432965T3 (en) | 2008-12-15 | 2013-12-05 | Exxonmobil Chemical Patents Inc. | Compositions of thermoplastic olefins |
US8106127B2 (en) * | 2008-12-15 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-reactor polymer blends |
JP5415559B2 (en) | 2008-12-30 | 2014-02-12 | サン−ゴバン パフォーマンス プラスティックス コーポレイション | Roof membrane installation method |
JP4816750B2 (en) * | 2009-03-13 | 2011-11-16 | 住友電気工業株式会社 | Connection method of printed wiring board |
US9144796B1 (en) | 2009-04-01 | 2015-09-29 | Johnson Matthey Public Limited Company | Method of applying washcoat to monolithic substrate |
WO2010130996A1 (en) | 2009-05-13 | 2010-11-18 | Sun Chemical B.V. | Modified polyamide acrylate oligomers |
US20120070601A1 (en) * | 2009-05-19 | 2012-03-22 | Polyone Corporation | Thermoplastic elastomers exhibiting superior food contact compliance |
DE102009026988A1 (en) * | 2009-05-27 | 2010-12-02 | Evonik Degussa Gmbh | Hybrid components with reactive hot melt adhesives |
EP2435526A4 (en) * | 2009-05-29 | 2012-10-31 | Exxonmobil Chem Patents Inc | Polyolefin adhesive compositions and method of making thereof |
US20110059277A1 (en) * | 2009-09-04 | 2011-03-10 | Rainer Kolb | Elastomeric Surface Coatings for Plastic Articles |
US20100316820A1 (en) * | 2009-06-16 | 2010-12-16 | Rainer Kolb | Composite Materials Comprising Propylene-Based Polymer Blend Coatings |
US9017593B2 (en) | 2009-06-16 | 2015-04-28 | Exxonmobil Chemical Patents Inc. | Composite materials comprising propylene-based polymer blend coatings |
WO2010147706A2 (en) * | 2009-06-16 | 2010-12-23 | Exxonmobil Chemical Patents Inc. | Polyolefin compositions for coating applications |
GB0912842D0 (en) * | 2009-07-23 | 2009-08-26 | Gmc Marketing Ltd | A mount for artwork |
US9266792B2 (en) | 2009-07-29 | 2016-02-23 | The United States Of America As Represented By The Secretary Of The Navy | Process and apparatus for the selective dimerization of terpenes and alpha-olefin oligomers with a single-stage reactor and a single-stage fractionation system |
US8785702B2 (en) | 2009-07-29 | 2014-07-22 | The United States Of America As Represented By The Secretary Of The Navy | Turbine and diesel fuels and methods for making the same |
US9242226B2 (en) | 2009-07-29 | 2016-01-26 | The Government Of The United States Of America As Represented By The Secretary Of The Navy | Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes |
US20120209047A1 (en) | 2009-07-29 | 2012-08-16 | Wright Michael E | Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents |
US8912373B2 (en) | 2009-07-29 | 2014-12-16 | The United States Of America As Represented By The Secretary Of The Navy | Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes |
US9649626B2 (en) | 2009-07-29 | 2017-05-16 | The United States Of America As Represented By The Secretary Of The Navy | Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes |
CN102471655B (en) | 2009-07-31 | 2015-02-11 | 汉高美国知识产权有限责任公司 | Low application temperature hot melt adhesive |
WO2011025587A1 (en) * | 2009-08-27 | 2011-03-03 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and method of making thereof |
US8158245B2 (en) * | 2009-09-24 | 2012-04-17 | Cytec Technology Corp. | Thermoplastic composites and methods of making and using same |
JP2011099091A (en) | 2009-09-30 | 2011-05-19 | Sumitomo Chemical Co Ltd | Manufacturing method for ethylenic polymer |
US8716201B2 (en) | 2009-10-02 | 2014-05-06 | Exxonmobil Research And Engineering Company | Alkylated naphtylene base stock lubricant formulations |
EP2492723B1 (en) * | 2009-10-21 | 2019-09-25 | Mitsubishi Gas Chemical Company, Inc. | Functional sheet and lens using same |
US20110112677A1 (en) * | 2009-11-11 | 2011-05-12 | Albert John Franklin | Method for controlling a physical property of a tubular blown film |
WO2011059431A1 (en) * | 2009-11-11 | 2011-05-19 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
JP2011113061A (en) * | 2009-11-30 | 2011-06-09 | Brother Industries Ltd | Antiglare film and display device |
CA2782873C (en) | 2009-12-24 | 2016-06-28 | Exxonmobil Chemical Patents Inc. | Process for producing novel synthetic basestocks |
US8226872B2 (en) * | 2010-01-18 | 2012-07-24 | Grote Industries, Inc. | Method for polyurethane bonding during and after overmolding |
JP5663189B2 (en) * | 2010-01-21 | 2015-02-04 | 出光興産株式会社 | Polypropylene nonwoven fabric |
CN102725319B (en) * | 2010-01-27 | 2014-10-15 | 埃克森美孚化学专利公司 | Copolymers, compositions thereof, and methods for making them |
US8642523B2 (en) | 2010-02-01 | 2014-02-04 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
US8748362B2 (en) | 2010-02-01 | 2014-06-10 | Exxonmobile Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed gas engines by reducing the traction coefficient |
US8728999B2 (en) | 2010-02-01 | 2014-05-20 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
US8759267B2 (en) | 2010-02-01 | 2014-06-24 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
US8598103B2 (en) | 2010-02-01 | 2013-12-03 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient |
ES2627915T5 (en) * | 2010-02-19 | 2021-09-29 | Exxonmobil Chemical Patents Inc | Elastomeric polymer blends and procedures for their production |
JP5471629B2 (en) * | 2010-03-10 | 2014-04-16 | 株式会社島津製作所 | Analysis system for liquid chromatograph and control program for the analysis system |
US8777828B2 (en) | 2010-05-17 | 2014-07-15 | Highcon Systems Ltd. | Method and system for creating co-layer surface adhesive rule |
US9102818B2 (en) * | 2010-05-17 | 2015-08-11 | Highcon Systems Ltd. | Method and system for surface adhesive rule technology |
CN102959144A (en) * | 2010-07-06 | 2013-03-06 | 提克纳有限公司 | High molecular weight polyethylene fibers and membranes, production and use thereof |
WO2012027450A2 (en) | 2010-08-26 | 2012-03-01 | Henkel Corporation | LOW APPLICATION TEMPERATURE AMORPHOUS POLY-α-OLEFIN ADHESIVE |
US9815915B2 (en) | 2010-09-03 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Production of liquid polyolefins |
CN103124777B (en) * | 2010-09-27 | 2016-08-03 | 汉高股份有限及两合公司 | Utilize the bonding of hotmelt |
US9109143B2 (en) * | 2010-10-15 | 2015-08-18 | Exxonmobil Chemical Patents Inc. | Polypropylene-based adhesive compositions |
AU2010246330A1 (en) | 2010-11-01 | 2012-05-17 | Finish Systems International, Llc | Stone-wood composite base engineered flooring |
US20120123374A1 (en) * | 2010-11-09 | 2012-05-17 | Richeson Galen C | Meltblown Nonwoven Compositions and Methods for Making Them |
JP5724150B2 (en) * | 2010-11-10 | 2015-05-27 | エルジー・ケム・リミテッド | Optical element and stereoscopic image display apparatus including optical element |
PL2640792T3 (en) * | 2010-11-19 | 2019-07-31 | Henkel Ag & Co. Kgaa | Adhesive compositions and use thereof |
US8959812B2 (en) | 2010-11-23 | 2015-02-24 | Circle Graphics, Inc. | Image display |
US9861215B2 (en) | 2010-11-23 | 2018-01-09 | Circle Graphics, Inc. | Image display with leather image substrate |
CN102194915B (en) * | 2011-03-23 | 2013-03-20 | 吉林大学 | Self-assembly nano TiO2 film ultraviolet detector and preparation method thereof |
US8669326B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Amine functionalized polyolefin and methods for preparation thereof |
US8785562B2 (en) | 2011-03-25 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Amphiphilic block polymers prepared by alkene metathesis |
US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
US8669330B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Olefin triblock polymers via ring-opening metathesis polymerization |
US8501894B2 (en) | 2011-03-25 | 2013-08-06 | Exxonmobil Chemical Patents Inc. | Hydrosilyation of vinyl macromers with metallocenes |
US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
US8835563B2 (en) | 2011-03-25 | 2014-09-16 | Exxonmobil Chemical Patents Inc. | Block copolymers from silylated vinyl terminated macromers |
US8940839B2 (en) | 2011-03-25 | 2015-01-27 | Exxonmobil Chemical Patents Inc. | Diblock copolymers prepared by cross metathesis |
US8455597B2 (en) | 2011-03-25 | 2013-06-04 | Exxonmobil Chemical Patents Inc. | Catalysts and methods of use thereof to produce vinyl terminated polymers |
WO2012134715A2 (en) * | 2011-03-25 | 2012-10-04 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
CN103443144B (en) * | 2011-03-25 | 2016-07-06 | 埃克森美孚化学专利公司 | The higher alkene copolymer of ethenyl blocking and manufacture method thereof |
US8426659B2 (en) | 2011-03-25 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
US8318998B2 (en) | 2011-03-25 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers |
JP2012214457A (en) | 2011-03-29 | 2012-11-08 | Sumitomo Chemical Co Ltd | Transition metal complex, method for producing the same, catalyst for trimerization, method for producing 1-hexene, substituted cyclopentadiene compound, and method for producing the same |
JP5900089B2 (en) | 2011-03-29 | 2016-04-06 | 住友化学株式会社 | Transition metal complex, method for producing the transition metal complex, catalyst for trimerization, method for producing 1-hexene, substituted cyclopentadiene compound, and method for producing the substituted cyclopentadiene compound |
FR2974497A1 (en) * | 2011-04-27 | 2012-11-02 | Centre Nat Rech Scient | INTERVERTEBRAL DISC PROSTHESIS IN THERMOPLASTIC MATERIAL WITH A GRADIENT OF MECHANICAL PROPERTIES |
WO2012149391A1 (en) | 2011-04-28 | 2012-11-01 | Adherent Laboratories, Inc. | Polyolefin based hot melt adhesive composition |
WO2012176946A1 (en) * | 2011-06-24 | 2012-12-27 | Sk 이노베이션 주식회사 | Transition metal catalyst system with excellent copolymerization and preparation method of ethylene homopolymer or copolymer of ethylene and α-olefin using same |
BR112013033143A2 (en) | 2011-06-27 | 2017-01-24 | Fuller H B Co | free radical initiator modified hot melt adhesive composition including functionalized polyethylene and propylene alpha olefin polymer |
CN103619976B (en) | 2011-06-27 | 2016-05-04 | H.B.富勒公司 | Propylene-alpha-olefin polymer, the hot-melt adhesive composition that comprises propylene-alpha-olefin polymer and the goods that comprise it |
WO2013036312A1 (en) | 2011-08-19 | 2013-03-14 | Avery Dennison Corporation | Blends of ethylene copolymers and propylene based plastomers in multilayer films for low noise and rf welding |
CN102444055B (en) * | 2011-09-03 | 2013-04-03 | 衡水宝秋数码科技有限公司 | Decorative wallpaper material for environmentally-friendly wall and preparation method thereof |
US20130059954A1 (en) * | 2011-09-06 | 2013-03-07 | Elmer's Products, Inc. | Glue sticks formulated with acrylic dispersions |
US9234150B2 (en) | 2011-10-10 | 2016-01-12 | Exxonmobil Research And Engineering Company | Low viscosity engine oil compositions |
US9005728B2 (en) * | 2011-11-08 | 2015-04-14 | Kimberly-Clark Worldwide, Inc. | Disposable absorbent pad |
US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
WO2013086217A1 (en) | 2011-12-06 | 2013-06-13 | Masco Corporation Of Indiana | Ozone distribution in a faucet |
US9050760B2 (en) | 2011-12-15 | 2015-06-09 | Ndc Technologies, Inc. | Blown film scanning method |
US10335308B2 (en) * | 2011-12-22 | 2019-07-02 | Avery Dennison Corporation | Flexible barrier films containing cyclic olefins |
US20150282978A1 (en) * | 2012-01-09 | 2015-10-08 | Avery Dennison Corporation | Low-Modulus, Halogen-Free, Odor Containment Barrier |
WO2013106065A1 (en) * | 2012-01-12 | 2013-07-18 | The Government Of The United States Of America As Represented By The Secretary Of The Navy | Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents |
JP6003976B2 (en) * | 2012-02-22 | 2016-10-05 | コニカミノルタ株式会社 | Optical film, circularly polarizing plate, and image display device |
KR101491053B1 (en) * | 2012-03-06 | 2015-02-10 | 주식회사 아모그린텍 | pressure-sensitive adhesive tape and preparation method thereof |
US9790132B2 (en) | 2012-03-09 | 2017-10-17 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
SG11201404422WA (en) | 2012-03-09 | 2014-08-28 | Exxonmobil Chem Patents Inc | Polyolefin adhesive compositions and methods of preparing the same |
US8851173B2 (en) | 2012-03-09 | 2014-10-07 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
US8796376B2 (en) | 2012-03-26 | 2014-08-05 | Exxonmobil Chemical Patents Inc. | Functionalized polymers and oligomers |
US20130289196A1 (en) | 2012-04-30 | 2013-10-31 | Shurtape Technologies, Llc | Film forming formulation for textured surfaces |
US20140017439A1 (en) * | 2012-07-10 | 2014-01-16 | Exxonmobil Chemical Patents Inc. | Carpet Comprising A Propylene-Based Elastomer and Methods of Making the Same |
US9238763B2 (en) | 2013-10-18 | 2016-01-19 | Exxonmobil Chemical Patents Inc. | Tackified polyolefin adhesive compositions |
US8852332B2 (en) * | 2012-07-26 | 2014-10-07 | Js3D Technology Company Limited | Synthetic modifier for hot asphaltic mixes for road paving and method of making same |
US9637252B2 (en) * | 2012-08-01 | 2017-05-02 | Right/Pointe, Llc | Sealant packaging and method |
US9676532B2 (en) | 2012-08-15 | 2017-06-13 | Avery Dennison Corporation | Packaging reclosure label for high alcohol content products |
PL2885362T3 (en) * | 2012-08-16 | 2017-04-28 | Clariant International Ltd | Flame-resistant coating for the rear side of a carpet |
CN103665567B (en) * | 2012-09-04 | 2015-09-16 | 中国石油化工股份有限公司 | Co-polymer foamed bead of propylene butene and preparation method thereof |
CN102827564A (en) * | 2012-09-18 | 2012-12-19 | 惠东伟康橡塑制品有限公司 | Glue, use of glue on polyvinyl chloride (PVC) floor and using method |
US8865824B2 (en) | 2012-09-19 | 2014-10-21 | IFS Industries Inc. | Hot melt adhesive |
US9241843B2 (en) | 2012-09-19 | 2016-01-26 | The Procter & Gamble Company | Article with tackifier-free adhesive |
US8940842B2 (en) | 2012-09-24 | 2015-01-27 | Chevron Phillips Chemical Company Lp | Methods for controlling dual catalyst olefin polymerizations |
CN104640889A (en) * | 2012-09-24 | 2015-05-20 | 埃克森美孚化学专利公司 | Production of vinyl terminated polyethylene using supported catalyst system |
CN102861389A (en) * | 2012-09-29 | 2013-01-09 | 黑龙江省森林保护研究所 | Forest fire control fire-resistant shield manufacturing method |
KR102126363B1 (en) | 2012-10-29 | 2020-06-24 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | Pavement marking compositions |
EP2913372A4 (en) * | 2012-10-29 | 2016-06-01 | Lintec Corp | Adhesive agent composition and adhesive sheet |
CN102964679B (en) * | 2012-10-31 | 2015-06-17 | 安徽省易达电子有限公司 | Capacitor film containing modified talc and preparation method thereof |
US9573348B2 (en) * | 2012-11-05 | 2017-02-21 | Toray Plastics (America), Inc. | Lidding structure based on aromatic polyester film, coextruded with a sealable/peelable epdxy-containing thermoplastic polymer |
EP2730626A1 (en) | 2012-11-12 | 2014-05-14 | Sika Technology AG | Reactive polyolefin hot melt adhesive with low adhesion to non-coated aluminium tools and its use as laminate hotmelt |
WO2014084349A1 (en) * | 2012-11-30 | 2014-06-05 | リンテック株式会社 | Adhesive agent composition, adhesive sheet, and electronic device |
EP2928691B1 (en) * | 2012-12-05 | 2021-07-28 | ExxonMobil Chemical Patents Inc. | Ethylene-based polymers and articles made therefrom |
CN103013336B (en) * | 2013-01-17 | 2015-01-28 | 山东浩珂矿业工程有限公司 | Emulsified asphalt paint special for warp-knitted polyester geogrid and preparation method |
WO2014120482A1 (en) * | 2013-01-30 | 2014-08-07 | Exxonmobil Chemical Patents Inc. | Branched propylene oligomers |
US9422385B2 (en) | 2013-01-30 | 2016-08-23 | Exxonmobil Chemical Patents Inc. | Polyethylene copolymers with vinyl terminated macromonomers as comonomers |
US20140220336A1 (en) * | 2013-02-05 | 2014-08-07 | Honeywell International Inc. | Pressure-sensitive adhesives that minimize plasticizer migration, pressure-sensitive adhesive articles with such pressure-sensitive adhesives, and methods for fabricating such pressure-sensitive adhesives |
US9593235B2 (en) | 2013-02-15 | 2017-03-14 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
US9267060B2 (en) | 2013-02-15 | 2016-02-23 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
JP6118131B2 (en) * | 2013-02-25 | 2017-04-19 | 日東電工株式会社 | Waterproof sound-permeable membrane, sound-permeable member, and electrical equipment |
US9738108B2 (en) | 2013-03-14 | 2017-08-22 | Circle Graphics, Inc. | Image display and kit |
WO2014153073A1 (en) * | 2013-03-14 | 2014-09-25 | Smart Planet Technologies, Inc. | Composite structures for packaging articles and related methods |
EP3747650B1 (en) | 2013-03-14 | 2022-07-27 | Smart Planet Technologies, Inc. | Repulpable and recyclable composite packaging articles and related methods |
US10458756B2 (en) | 2013-03-15 | 2019-10-29 | Scott R. Whitaker | Flexible adhesive ballistic shield |
US10302401B2 (en) | 2013-03-15 | 2019-05-28 | Scott R. Whitaker | Ballistic shield |
US8756085B1 (en) * | 2013-03-15 | 2014-06-17 | State Farm Mutual Automobile Insurance Company | Systems and methods for assessing property damage |
CN105209147B (en) | 2013-03-15 | 2020-07-03 | 唐纳森公司 | Filter media and elements |
EP3936164A1 (en) | 2013-05-29 | 2022-01-12 | H.B. Fuller Company | Elastic attachment adhesive composition |
US9474994B2 (en) | 2013-06-17 | 2016-10-25 | Donaldson Company, Inc. | Filter media and elements |
US9522213B2 (en) | 2013-06-18 | 2016-12-20 | H.B. Fuller Company | Pressure-sensitive hot melt adhesive composition including propylene thermoplastic elastomer and articles including the same |
WO2015002747A1 (en) * | 2013-07-02 | 2015-01-08 | Exxonmobile Chemical Patents Inc. | Carpet backing compositions and carpet backing comprising the same |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
WO2015009472A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemcal Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
US9834628B2 (en) | 2013-07-17 | 2017-12-05 | Exxonmobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
WO2015009479A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
US20160122452A1 (en) | 2013-07-17 | 2016-05-05 | Exxonmobil Chemical Patents Inc. | Ethylene-Propylene Copolymeric Compositions With Long Methylene Sequence Lengths |
EP3848401A1 (en) | 2013-07-17 | 2021-07-14 | ExxonMobil Chemical Patents Inc. | Isotactic propylene polymers |
WO2015009474A1 (en) * | 2013-07-17 | 2015-01-22 | Exxonmobil Chemical Patents Inc. | Ethylene-propylene copolymeric compositions with long methylene sequence lengths |
CN105377904B (en) | 2013-07-17 | 2018-07-10 | 埃克森美孚化学专利公司 | Metallocene and by its derivative carbon monoxide-olefin polymeric |
WO2015047030A1 (en) * | 2013-09-30 | 2015-04-02 | 주식회사 엘지화학 | Method for preparing propylene-1-butene copolymer and propylene-1-butene copolymer obtained thereby |
WO2015047031A1 (en) * | 2013-09-30 | 2015-04-02 | 주식회사 엘지화학 | Polypropylene preparation method and polypropylene obtained therefrom |
KR101593175B1 (en) * | 2013-09-30 | 2016-02-12 | 주식회사 엘지화학 | Method for preparing polypropylene and polypropylene prepared therefrom |
JP6161716B2 (en) * | 2013-10-18 | 2017-07-12 | 三井化学株式会社 | Adhesive containing ethylene / α-olefin copolymer |
WO2015057416A1 (en) | 2013-10-18 | 2015-04-23 | Exxonmobil Chemical Patents Inc. | High polymer load polyolefin adhesive compositions |
TWI611741B (en) * | 2013-11-01 | 2018-01-11 | 片片堅俄亥俄州工業公司 | Methods of transferring electrically conductive materials |
US10350848B2 (en) | 2013-11-26 | 2019-07-16 | Ansell Limited | Nitrile/polyurethane polymer blends |
US10639210B2 (en) | 2013-12-19 | 2020-05-05 | The Procter & Gamble Company | Article with tackifier-free adhesive |
DE102013022086A1 (en) * | 2013-12-23 | 2015-06-25 | MKT Moderne Kunststoff-Technik Gebrüder Eschbach GmbH | lipping |
CN103756259B (en) * | 2014-01-03 | 2016-05-25 | 交通运输部公路科学研究所 | The agent of a kind of asphalt dry method modification, its preparation method and asphalt |
US20150203654A1 (en) * | 2014-01-21 | 2015-07-23 | Js3D Technology Company Limited | Inorganic modifier for hot mix asphalt for road building and method of making same |
DE102014201992A1 (en) * | 2014-02-04 | 2015-08-06 | Leoni Bordnetz-Systeme Gmbh | Electric cable and method for producing an electrical cable bundle |
US9399686B2 (en) | 2014-02-07 | 2016-07-26 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
US10914073B2 (en) | 2014-02-25 | 2021-02-09 | Tamko Building Products Llc | Curtain die for applying a liquid release agent to a shingle substrate |
US10113314B2 (en) | 2014-02-25 | 2018-10-30 | Tamko Building Products, Inc. | Liquid release agent and associated methods of application |
GB201403551D0 (en) * | 2014-02-28 | 2014-04-16 | Fujifilm Mfg Europe Bv | Membrane stacks |
WO2015138215A1 (en) | 2014-03-14 | 2015-09-17 | H.B. Fuller Company | Hot melt adhesive compositions that include propylene polymer and ethylene copolymer |
US20170073556A1 (en) | 2014-04-22 | 2017-03-16 | Exxonmobil Chemical Patents Inc. | Hydrocarbon Tackifiers for Adhesive Compositions |
WO2015164016A1 (en) | 2014-04-22 | 2015-10-29 | Exxonmobil Chemical Patents Inc. | Adhesive compositions for nonwoven applications |
US8899318B1 (en) | 2014-04-24 | 2014-12-02 | Ronald C. Parsons | Applying an aggregate to expandable tubular |
WO2015167692A1 (en) | 2014-04-29 | 2015-11-05 | Exxonmobil Chemical Patents Inc. | Adhesive compositions with syndiotactic-rich polyolefins |
WO2015167870A1 (en) | 2014-04-29 | 2015-11-05 | 3M Innovative Properties Company | Copolymers of poly(ethylene-co-acrylic acid) and polydiorganosiloxanes |
CA2951030C (en) | 2014-06-02 | 2023-03-28 | Christopher J. Blackwell | Films with enhanced scuff resistance, clarity, and conformability |
ES2728532T3 (en) | 2014-06-12 | 2019-10-25 | Dow Global Technologies Llc | An improved process to produce pelletized polymer compositions |
ES2796870T3 (en) | 2014-06-30 | 2020-11-30 | Dow Global Technologies Llc | Catalytic systems for olefin polymerization |
JP6797694B6 (en) | 2014-06-30 | 2021-01-20 | ダウ グローバル テクノロジーズ エルエルシー | Process for olefin polymerization |
RU2562492C1 (en) * | 2014-07-15 | 2015-09-10 | Акционерное общество "Швабе-Оборона и Защита" (АО "Швабе-Оборона и Защита") | Glue composition |
US20160324241A2 (en) * | 2014-08-08 | 2016-11-10 | Yo Han Lee | An adhesive device for attaching a false eyelash and a false eyelash kit |
WO2016028961A1 (en) | 2014-08-21 | 2016-02-25 | Dow Global Technologies Llc | Hot melt adhesive composition including a crystalline block composite |
JP6548719B2 (en) | 2014-08-21 | 2019-07-24 | ダウ グローバル テクノロジーズ エルエルシー | Hot melt adhesive composition |
US10792194B2 (en) | 2014-08-26 | 2020-10-06 | Curt G. Joa, Inc. | Apparatus and methods for securing elastic to a carrier web |
US10428210B2 (en) | 2014-10-29 | 2019-10-01 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions for elastic applications |
US10844253B2 (en) | 2014-11-07 | 2020-11-24 | H.B. Fuller Company | Hot melt adhesive compositions that include semi-crystalline propylene polymer and wax and articles including the same |
CN104448572A (en) * | 2014-11-12 | 2015-03-25 | 合肥市瑞宏重型机械有限公司 | Plastic packaging material for low-temperature dairy product |
EP3029101B1 (en) | 2014-12-04 | 2017-02-15 | ExxonMobil Chemical Patents Inc. | Multi-modal polymer blend, hot melt adhesive comprising same and use thereof |
EP3240808B1 (en) | 2014-12-29 | 2020-05-13 | Dow Global Technologies LLC | Process to form ethylene/alpha-olefin interpolymers |
TWI525103B (en) | 2014-12-29 | 2016-03-11 | 財團法人工業技術研究院 | Modified cellulose and composite material using the same |
US9796795B2 (en) | 2015-01-14 | 2017-10-24 | Exxonmobil Chemical Patents Inc. | Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof |
US9816015B2 (en) | 2015-01-14 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Adhesive compositions made from propylene-based polymers and crystalline C2/C3 homopolymer |
US10385198B2 (en) * | 2015-01-14 | 2019-08-20 | Exxonmobil Chemical Patents Inc. | Polymer compositions with improved rheological properties |
WO2016171807A1 (en) | 2015-04-20 | 2016-10-27 | Exxonmobil Chemical Patents Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
US10688754B1 (en) * | 2015-02-10 | 2020-06-23 | Polymeric Converting Llc | Multifunctional contact clear filled pressure sensitive adhesive coated substrates |
CN104693359B (en) * | 2015-02-15 | 2017-08-29 | 广西大学 | Trans-critical cycle reaction system hydrogenation modification rosin and C9/C5 Petropols method and devices |
WO2016154012A1 (en) * | 2015-03-21 | 2016-09-29 | Invista North America S.A.R.L. | Fiberfill having cooling effect and articles made thereof |
EP3274405B1 (en) | 2015-03-27 | 2020-12-30 | ExxonMobil Chemical Patents Inc. | Propylene-based polymer compositions for injection molding |
CN107429015B (en) | 2015-03-27 | 2021-03-23 | 埃克森美孚化学专利公司 | Propylene-based polymer compositions for handle applications |
EP3286231B1 (en) | 2015-04-20 | 2019-10-09 | ExxonMobil Chemical Patents Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
EP3274381B1 (en) | 2015-04-20 | 2019-05-15 | ExxonMobil Chemical Patents Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
US9932501B2 (en) | 2015-04-23 | 2018-04-03 | Exxonmobil Chemical Patents Inc. | Hydrocarbon tackifiers for low temperature application adhesive compositions |
WO2016179010A1 (en) | 2015-05-01 | 2016-11-10 | Lord Corporation | Adhesive for rubber bonding |
US10633565B2 (en) | 2015-06-24 | 2020-04-28 | Exxonmobil Chemical Patents Inc. | Propylene-based polymers and plasticizers for use in adhesive compositions |
CA3005384C (en) | 2015-06-25 | 2020-09-22 | Pliteq Inc. | Impact damping mat, equipment accessory and flooring system |
US20180202150A1 (en) | 2015-06-25 | 2018-07-19 | Pliteq Inc. | Impact damping mat, equipment accessory and flooring system |
US10059898B2 (en) | 2015-08-21 | 2018-08-28 | Exxonmobil Chemical Patents Inc. | High-viscosity metallocene polyalpha-olefins with high electrohydrodynamic performance |
WO2017034659A1 (en) | 2015-08-21 | 2017-03-02 | Exxonmobil Chemical Patents Inc. | Lubricant base stock blends |
WO2017034680A1 (en) * | 2015-08-25 | 2017-03-02 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer with in-situ oil production |
US10611980B2 (en) | 2015-10-15 | 2020-04-07 | Exxonmobil Chemical Patents Inc. | Lubricant containing high-viscosity metallocene polyalpha-olefins |
CN105400354B (en) * | 2015-11-14 | 2018-10-12 | 合肥市易远新材料有限公司 | Water-based paint for surface of pop can body |
US11458214B2 (en) | 2015-12-21 | 2022-10-04 | Delta Faucet Company | Fluid delivery system including a disinfectant device |
PL3402857T3 (en) | 2016-01-14 | 2020-11-30 | Bostik, Inc. | Hot melt adhesive composition based on a blend of propylene copolymers prepared using single-site catalysts and methods |
CN108699412B (en) * | 2016-02-12 | 2021-04-27 | 东洋纺株式会社 | Adhesive composition for low energy surface substrates |
FR3048236B1 (en) * | 2016-02-29 | 2019-07-12 | Albea Le Treport | PRODUCT DELIVERY SYSTEM FOR BOTTLE |
KR101711788B1 (en) * | 2016-03-09 | 2017-03-14 | 한화케미칼 주식회사 | Hybride catalyst compositon, preparation method thereof, and manufactured polyolefin using the same |
WO2017190027A1 (en) * | 2016-04-28 | 2017-11-02 | Rocksolid Granit (Usa), Inc. | Surface overlay attached with double sided tape |
US9803037B1 (en) | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
CN109312015B (en) | 2016-05-03 | 2021-10-26 | 埃克森美孚化学专利公司 | Tetrahydroindacenyl catalyst compositions, catalyst systems, and methods of use thereof |
TWI701862B (en) * | 2016-05-12 | 2020-08-11 | 日商迪愛生股份有限公司 | Adhesive for the laminating, the laminate using it and production method thereof, and rechargeable battery and production method thereof |
WO2017210423A2 (en) | 2016-06-03 | 2017-12-07 | Msi Technology Llc | Adhesive compositions, articles including the adhesive compositions, and methods thereof |
ES2865028T3 (en) | 2016-06-20 | 2021-10-14 | Henkel Ag & Co Kgaa | Polybutene-1 based extrudable pressure sensitive adhesive suitable for resealable packaging |
CA3024733C (en) | 2016-07-01 | 2023-07-04 | H.B. Fuller Company | Propylene polymer-based hot melt adhesive composition exhibiting fast set time and articles including the same |
US10351488B2 (en) | 2016-08-02 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Unsaturated polyalpha-olefin materials |
US10882932B2 (en) | 2016-10-05 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Sterically hindered metallocenes, synthesis and use |
DE102016220263A1 (en) | 2016-10-17 | 2018-04-19 | Clariant Plastics & Coatings Ltd | PSAs |
CN106497489A (en) * | 2016-10-26 | 2017-03-15 | 沈阳万合胶业股份有限公司 | A kind of porous type pressure sensitive adhesive and preparation method thereof |
WO2018090182A1 (en) * | 2016-11-15 | 2018-05-24 | 惠州航程世纪科技有限公司 | Degradable adhesive composition and preparation method therefor |
JP6804944B2 (en) * | 2016-11-18 | 2020-12-23 | 出光興産株式会社 | Method for producing α-olefin low polymer |
EP3323866B1 (en) | 2016-11-22 | 2019-07-24 | Henkel AG & Co. KGaA | Extrudable pressure sensitive adhesive based on polybutene-1 polymer and a styrene copolymer suitable for reclosable packagings |
US10563055B2 (en) | 2016-12-20 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Carpet compositions and methods of making the same |
MX2019008294A (en) * | 2017-01-20 | 2019-09-06 | Henkel IP & Holding GmbH | Anaerobic lubricant sealant. |
WO2018151903A1 (en) | 2017-02-20 | 2018-08-23 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and processes for use thereof |
US10723819B2 (en) | 2017-02-20 | 2020-07-28 | Exxonmobil Chemical Patents, Inc. | Supported catalyst systems and processes for use thereof |
WO2018191010A1 (en) | 2017-04-10 | 2018-10-18 | Exxonmobil Chemical Patents Inc. | Linear ethylene cyclic olenfin polymers |
US20180327614A1 (en) * | 2017-05-09 | 2018-11-15 | Imam Abdulrahman Bin Faisal University | Method of repairing an acrylic denture base and zirconia autopolymerizable resins therof |
CN107168493A (en) * | 2017-06-01 | 2017-09-15 | 曙光节能技术(北京)股份有限公司 | A kind of CPU heat dissipating methods and device |
WO2019005760A1 (en) * | 2017-06-26 | 2019-01-03 | Ennis Paint, Inc. | Thermoplastic composition for sealing roadway joints |
US11708669B2 (en) * | 2017-07-18 | 2023-07-25 | Kao Corporation | Road paving method |
US10844150B2 (en) | 2017-08-04 | 2020-11-24 | Exxonmobil Chemical Patents Inc. | Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes |
CN111108130B (en) | 2017-08-04 | 2022-06-28 | 埃克森美孚化学专利公司 | Has the advantages ofcontaining-CH2-SiMe3Hybrid catalysts of partially unbridged hafnocenes |
CN110997818A (en) * | 2017-08-16 | 2020-04-10 | 科腾聚合物有限责任公司 | Granular pavement marking binders and related methods |
JP2019038965A (en) * | 2017-08-28 | 2019-03-14 | 住友化学株式会社 | adhesive |
KR102590973B1 (en) | 2017-09-29 | 2023-10-19 | 다우 글로벌 테크놀로지스 엘엘씨 | Bis-phenyl-phenoxy polyolefin catalysts with alkoxy or amido ligands on metal for improved solubility |
WO2019067274A1 (en) | 2017-09-29 | 2019-04-04 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility |
US11066428B2 (en) | 2017-09-29 | 2021-07-20 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having a methylenetrialkylsilicon ligand on the metal for improved solubility |
DK3473674T3 (en) | 2017-10-19 | 2022-06-20 | Abu Dhabi Polymers Co Ltd Borouge Llc | POLYPROPYLENE COMPOSITION |
US20190117534A1 (en) * | 2017-10-24 | 2019-04-25 | Collidion, Inc. | Grip Enhancing Compositions, and Methods and Uses Thereof |
CN107877403B (en) * | 2017-10-30 | 2019-03-19 | 郑州磨料磨具磨削研究所有限公司 | A kind of resin/metal bonded wheel wetting agent and preparation method thereof |
US10703838B2 (en) | 2017-10-31 | 2020-07-07 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems with four metallocenes on a single support |
KR102018535B1 (en) * | 2017-11-22 | 2019-09-06 | 한화케미칼 주식회사 | Catalyst for polymerizing olefin and polyolefin polymerized by using the same |
US10926250B2 (en) | 2017-12-01 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Catalyst systems and polymerization processes for using the same |
EP3717522A1 (en) | 2017-12-01 | 2020-10-07 | ExxonMobil Chemical Patents Inc. | Catalyst systems and polymerization processes for using the same |
IL275980B2 (en) | 2018-01-14 | 2023-10-01 | Collidion Inc | Compositions, Kits, Methods and Uses for Cleaning, Disinfecting, Sterilizing and/or Treating |
MX2020007614A (en) | 2018-01-29 | 2020-09-14 | Joa Curt G Inc | Apparatus and method of manufacturing an elastic composite structure for an absorbent sanitary product. |
US10865258B2 (en) | 2018-01-31 | 2020-12-15 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same |
US10851187B2 (en) | 2018-01-31 | 2020-12-01 | Exxonmobil Chemical Patents Inc. | Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same |
CN108385848A (en) * | 2018-01-31 | 2018-08-10 | 安徽金丰新型建材有限公司 | A kind of sandwich board surface processing method of polyurethane core material |
CN108383951A (en) * | 2018-03-06 | 2018-08-10 | 鲁东大学 | A method of improving polyurethane foam oil absorbency |
US10894841B2 (en) | 2018-03-19 | 2021-01-19 | Exxonmobil Chemical Patents Inc. | Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems |
WO2019194958A1 (en) | 2018-04-06 | 2019-10-10 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and compositions therefrom |
DE102018109269A1 (en) | 2018-04-18 | 2019-10-24 | Clariant Plastics & Coatings Ltd | Permanently tacky pressure-sensitive adhesives with improved environmental compatibility |
DE102018215927B4 (en) * | 2018-09-19 | 2022-02-17 | Profol GmbH | Foil for application to a target object |
CN110922517B (en) * | 2018-09-20 | 2023-01-03 | 中国石油化工股份有限公司 | Ethylene copolymer and preparation method thereof |
CN110922516B (en) * | 2018-09-20 | 2022-12-30 | 中国石油化工股份有限公司 | Ethylene copolymer and preparation method thereof |
US11925538B2 (en) | 2019-01-07 | 2024-03-12 | Curt G. Joa, Inc. | Apparatus and method of manufacturing an elastic composite structure for an absorbent sanitary product |
MX2021013460A (en) | 2019-05-03 | 2021-12-10 | Ennis Flint Inc | Systems and methods for making thermoplastic products and compositions. |
EP3999563A1 (en) | 2019-07-17 | 2022-05-25 | ExxonMobil Chemical Patents Inc. | High propylene content ep having low glass transition temperatures |
WO2021040384A1 (en) * | 2019-08-26 | 2021-03-04 | 주식회사 엘지화학 | Catalyst composition and method for preparing hydrocarbon resin by using same |
US11173072B2 (en) | 2019-09-05 | 2021-11-16 | Curt G. Joa, Inc. | Curved elastic with entrapment |
US11767673B2 (en) | 2019-09-30 | 2023-09-26 | Bmic Llc | Composite membrane for building applications |
US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
WO2021080813A1 (en) | 2019-10-22 | 2021-04-29 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions and processes for the production thereof |
WO2021080803A1 (en) | 2019-10-22 | 2021-04-29 | Exxonmobil Chemical Patents Inc. | Impact copolymer compositions |
WO2021113026A1 (en) | 2019-12-04 | 2021-06-10 | Exxonmobil Research And Engineering Company | Adhesive compositions |
KR102506502B1 (en) * | 2019-12-06 | 2023-03-06 | 주식회사 엘지화학 | Catalyst composition and preparation method of polyisobutene using the same |
US11492805B2 (en) | 2020-01-24 | 2022-11-08 | Building Materials Investment Corporation | Membrane installation methods |
KR102154464B1 (en) * | 2020-01-31 | 2020-09-10 | 동원시스템즈 주식회사 | Lid packing material for food container |
WO2021188361A1 (en) | 2020-03-20 | 2021-09-23 | Exxonmobil Chemical Patents Inc. | Linear alpha-olefin copolymers and impact copolymers thereof |
WO2021194831A1 (en) | 2020-03-25 | 2021-09-30 | Exxonmobil Chemical Patents Inc. | Alkylation of transition metal coordination catalyst complexes |
EP4127061A1 (en) | 2020-03-30 | 2023-02-08 | ExxonMobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
US20230167289A1 (en) | 2020-04-29 | 2023-06-01 | Dow Global Technologies Llc | High flow propylene-based interpolymer compositions |
US20230167254A1 (en) | 2020-05-01 | 2023-06-01 | Exxonmobil Chemical Patents Inc. | Linear Low Density Polyethylene for Film Applications |
US20230174757A1 (en) | 2020-05-01 | 2023-06-08 | Exxonmobil Chemical Patents Inc. | Linear Low Density Polyethylene for Film Applications |
WO2021257264A1 (en) | 2020-06-16 | 2021-12-23 | Exxonmobil Chemical Patents Inc. | Metallocene catalysts for producing vinyl-terminated polyalphaolefins and methods associated therewith |
WO2022029212A1 (en) * | 2020-08-06 | 2022-02-10 | Total Research & Technology Feluy | Process for preparing propylene polymers having long chain branches |
US11738334B2 (en) | 2020-08-11 | 2023-08-29 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and processes for use thereof |
US20240018279A1 (en) | 2020-08-13 | 2024-01-18 | Exxonmobil Chemical Patents Inc. | Cyclic Containing Polymer Compositions Obtained Using Transition Metal Bis(Phenolate) Catalyst Complexes and Process for Production Thereof |
CA3128681A1 (en) * | 2020-08-21 | 2022-02-21 | Building Materials Investment Corporation | Roofing materials with improved low temperature sealant performance and methods of making thereof |
CN112194749B (en) * | 2020-09-22 | 2023-06-09 | 上海葛蓝化工科技有限公司 | Metallocene catalyst for synthesizing polyolefin elastomer, preparation method and application |
US11651120B2 (en) * | 2020-09-30 | 2023-05-16 | GM Global Technology Operations LLC | Method and system of reporting stretching failure in stamping die development |
CN116323707A (en) | 2020-10-08 | 2023-06-23 | 埃克森美孚化学专利公司 | Supported catalyst systems and methods of use thereof |
JP7024842B2 (en) * | 2020-10-16 | 2022-02-24 | 日本ポリプロ株式会社 | Propene homopolymer |
CN116391246A (en) * | 2020-10-19 | 2023-07-04 | 3M创新有限公司 | Protective tape, articles made therefrom, and methods of making and using the same |
WO2022087121A1 (en) | 2020-10-22 | 2022-04-28 | Exxonmobil Chemical Patents Inc. | Multidentate lewis base catalysts and methods for use thereof |
US20230406967A1 (en) | 2020-10-28 | 2023-12-21 | Exxonmobil Chemical Patents Inc. | Non-Aromatic Hydrocarbon Soluble Olefin Polymerization Catalysts and Use Thereof |
CN112663346B (en) * | 2020-12-29 | 2021-08-31 | 南通市交通建设工程有限公司 | High-strength stress absorption film material and preparation method thereof |
WO2022155026A1 (en) | 2021-01-12 | 2022-07-21 | Exxonmobil Chemical Patents Inc. | Asymmetric constrained geometry catalysts |
CN112876831B (en) * | 2021-01-21 | 2023-04-14 | 上海中镭新材料科技有限公司 | Mineral reinforced PC/PET alloy resin and preparation method thereof |
CN114854332A (en) * | 2021-02-04 | 2022-08-05 | 厦门内加湖新材料科技有限公司 | Adhesive composition, lithium battery packaging material, and lithium battery |
US20220361603A1 (en) * | 2021-05-17 | 2022-11-17 | Autoliv Asp, Inc. | One piece woven medical gown with coating |
EP4347670A1 (en) | 2021-05-24 | 2024-04-10 | ExxonMobil Chemical Patents Inc. | Biphasic polymerization processes |
WO2023044215A1 (en) | 2021-09-14 | 2023-03-23 | Exxonmobil Chemical Patents Inc. | Catalyst feeder and processes thereof |
WO2023081010A1 (en) | 2021-11-05 | 2023-05-11 | Exxonmobil Chemical Patents Inc. | Polypropylene viscosity modifiers and lubricating oils thereof |
PT117611B (en) | 2021-11-29 | 2024-01-12 | Colquimica Industria Nac De Colas S A | HOT-FUSE GLUE DETECTABLE IN X-RAYS |
WO2023099529A1 (en) * | 2021-12-01 | 2023-06-08 | Totalenergies Onetech Belgium | Polymerization process using dual catalyst compositions |
CN114292606A (en) * | 2021-12-28 | 2022-04-08 | 苏州云裳电子有限公司 | Environment-friendly adhesive tape and preparation method thereof |
US20230235207A1 (en) * | 2022-01-27 | 2023-07-27 | Leaf Shave Company | Adhesive for Attaching Objects to a Surface |
BE1030411B1 (en) * | 2022-03-30 | 2023-11-08 | Balta Ind | RECYCLABLE TEXTILE PRODUCT FROM POLYPROPYLENE |
FR3134108A1 (en) * | 2022-03-31 | 2023-10-06 | Bostik Sa | Hot melt adhesive composition comprising a wax of natural origin |
US11730215B1 (en) | 2022-06-30 | 2023-08-22 | CreateMe Technologies LLC | Thioester adhesives for apparel products |
US11713405B1 (en) * | 2022-06-30 | 2023-08-01 | CreateMe Technologies LLC | Methods of disassembling apparel products having thioester adhesives |
US20240043669A1 (en) | 2022-08-04 | 2024-02-08 | Fina Technology, Inc. | Polypropylene compositions with improved clarity |
WO2024040097A1 (en) | 2022-08-16 | 2024-02-22 | Fina Technology, Inc. | Metallocene polypropylene compositions |
US20240110048A1 (en) | 2022-09-30 | 2024-04-04 | Fina Technology, Inc. | Polypropylene peroxide masterbatch |
CN117534894B (en) * | 2024-01-10 | 2024-03-12 | 山东金顺达管业有限公司 | Antistatic flame-retardant polyethylene composite material and preparation method and application thereof |
Family Cites Families (1196)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1953104A (en) | 1930-01-27 | 1934-04-03 | Du Pont Cellophane Co Inc | Adhesive |
US5066737A (en) | 1990-10-22 | 1991-11-19 | Shell Oil Company | Olefin polymerization catalyst |
US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
GB1003632A (en) | 1963-05-02 | 1965-09-08 | Oxford Paper Co | Improvements in planograpic printing plates |
US3221002A (en) | 1963-09-26 | 1965-11-30 | Cabot Corp | Process for polymerization utilizing a surface treated inorganic solid catalyst |
US3242099A (en) | 1964-03-27 | 1966-03-22 | Union Carbide Corp | Olefin polymerization catalysts |
US3231550A (en) | 1964-06-04 | 1966-01-25 | Union Carbide Corp | Olefin polymerization |
US3483276A (en) | 1964-12-04 | 1969-12-09 | Hercules Inc | Blends of modified and unmodified polypropylene |
FR1582841A (en) | 1967-03-29 | 1969-10-10 | ||
US3487112A (en) | 1967-04-27 | 1969-12-30 | Monsanto Co | Vapor phase hydroformylation process |
JPS5033513B1 (en) | 1969-04-11 | 1975-10-31 | ||
BE755430A (en) | 1969-08-30 | 1971-02-01 | Fahr Ag Maschf | RAKING WHEEL FOR HAYING MACHINES |
US3709954A (en) | 1970-03-16 | 1973-01-09 | Union Carbide Corp | Preparation of liquid polymers of olefins |
US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
US4115639A (en) | 1971-06-24 | 1978-09-19 | Union Carbide Corporation | Ethylene polymerization with ether modified catalyst |
US3868433A (en) | 1972-04-03 | 1975-02-25 | Exxon Research Engineering Co | Thermoplastic adhesive compositions |
US3821143A (en) | 1973-03-22 | 1974-06-28 | Du Pont | Hot melt adhesive composition containing a branched elastomeric copolymer |
IT1037112B (en) | 1975-03-28 | 1979-11-10 | Montedison Spa | CATALYSTS FOR THE POLYMERIZATION OF OLFINES |
US4217428A (en) | 1975-03-31 | 1980-08-12 | Eastman Kodak Company | Blends of substantially amorphous higher 1-olefin copolymers and tackifying resins useful as pressure-sensitive adhesives |
US3954697A (en) * | 1975-03-31 | 1976-05-04 | Eastman Kodak Company | Poly(higher-1-olefin-co-propylene) copolymers as hot-melt, pressure-sensitive adhesives |
GB1538057A (en) | 1975-08-13 | 1979-01-10 | Exxon Research Engineering Co | Petroleum resins |
US4077904A (en) | 1976-06-29 | 1978-03-07 | Union Carbide Corporation | Olefin polymerization process and catalyst therefor |
DE2742585A1 (en) | 1976-09-28 | 1978-03-30 | Asahi Chemical Ind | NEW POLYMERIZATION CATALYSTS AND THEIR USE (I) |
JPS5952643B2 (en) | 1977-01-27 | 1984-12-20 | 三井化学株式会社 | ethylene copolymer |
US4120916A (en) | 1977-03-02 | 1978-10-17 | Eastman Kodak Company | Amorphous and crystalline polyolefin based hot-melt adhesive |
US4178272A (en) | 1977-03-02 | 1979-12-11 | Eastman Kodak Company | Hot-melt adhesvies for bonding polyethylene |
DE2731067C3 (en) | 1977-07-09 | 1981-11-26 | Bunawerke Hüls GmbH, 4370 Marl | Process for the preparation of polybutadiene with a high content of monomer units in a cis-1,4 structure |
US4210570A (en) | 1978-01-06 | 1980-07-01 | Eastman Kodak Company | Blends of substantially amorphous olefin copolymers, compatible tackifying resins and plasticizing oils useful as hot melt, pressure-sensitive adhesives |
US4302565A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
US4482687A (en) | 1979-10-26 | 1984-11-13 | Union Carbide Corporation | Preparation of low-density ethylene copolymers in fluid bed reactor |
US4376062A (en) | 1979-11-28 | 1983-03-08 | Union Carbide Corporation | Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization |
ZA81322B (en) | 1980-01-23 | 1982-03-31 | Rohm & Haas | The preparation of graft copolymers, poly (vinyl chloride) compositions containing them and reactors useful in preparing them |
US4325837A (en) | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
DE3171017D1 (en) | 1980-08-19 | 1985-07-25 | Ici Plc | Fermentation process |
US4379758A (en) | 1980-12-24 | 1983-04-12 | Union Carbide Corporation | Catalyst composition for polymerizing ethylene |
US4361628A (en) | 1981-02-20 | 1982-11-30 | American Can Company | Coextruded film of polypropylene, polypropylene blend, and nylon |
DE3127133A1 (en) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | METHOD FOR PRODUCING POLYOLEFINS AND THEIR COPOLYMERISATS |
CA1174800A (en) | 1981-08-24 | 1984-09-18 | Charles Cozewith | Gas phase method for producing copolymers of ethylene and higher alpha-olefins |
JPS5883016A (en) | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | Production of propylene block copolymer |
US4409364A (en) * | 1981-12-04 | 1983-10-11 | Chemplex Company | Adhesive blends and composite structures comprising acid or anhydride modified PE + hope + polypropylene |
ES518372A0 (en) | 1981-12-21 | 1984-06-01 | Exxon Research Engineering Co | A PROCEDURE FOR THE HYDROGENATION OF OIL RESINS. |
CA1219994A (en) | 1981-12-24 | 1987-03-31 | Nobunori Maehara | Process for producing polybutadiene rubber with enhanced mechanical strength |
US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
EP0099774B2 (en) | 1982-06-24 | 1995-03-22 | BP Chimie Société Anonyme | Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed |
US4496698A (en) * | 1982-07-26 | 1985-01-29 | The Dow Chemical Company | Process for producing polyethylene having constant physical and chemical properties |
US4510286A (en) | 1982-09-03 | 1985-04-09 | Hercules Incorporated | Bonding resin composition |
JPS5975910A (en) | 1982-10-25 | 1984-04-28 | Mitsui Petrochem Ind Ltd | Ethylene copolymer |
DE3240383A1 (en) | 1982-11-02 | 1984-05-03 | Hoechst Ag, 6230 Frankfurt | METHOD FOR PRODUCING OLIGOMER ALUMINOXANES |
US4476283A (en) | 1982-11-12 | 1984-10-09 | Uniroyal, Inc. | Graft copolymerization process |
JPS59117508A (en) * | 1982-12-24 | 1984-07-06 | Mitsui Petrochem Ind Ltd | Olefin polymerization |
EP0115940B2 (en) | 1983-01-25 | 1997-03-19 | Mitsui Petrochemical Industries, Ltd. | Film-forming propylene copolymer, film thereof and process for production of the film |
EP0115434A3 (en) | 1983-01-27 | 1984-08-29 | Exxon Research And Engineering Company | Semicrystalline ethylene alpha-olefin copolymers for hot melt adhesives |
JPS59149944A (en) | 1983-02-15 | 1984-08-28 | Toyo Seikan Kaisha Ltd | Hot-melt adhesive |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
US4935474A (en) * | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4882406A (en) | 1983-06-15 | 1989-11-21 | Exxon Research & Engineering Company | Nodular copolymers formed of alpha-olefin copolymers coupled by non-conjugated dienes |
GB8317510D0 (en) | 1983-06-28 | 1983-08-03 | Exxon Research Engineering Co | Petroleum resins |
JPS6088016A (en) | 1983-10-21 | 1985-05-17 | Mitsui Petrochem Ind Ltd | Ethylene copolymer |
FR2555182B1 (en) | 1983-11-23 | 1986-11-07 | Bp Chimie Sa | PROCESS FOR THE PREPARATION OF A SUPPORTED CATALYST FOR THE COPOLYMERIZATION OF ETHYLENE WITH SUPERIOR ALPHA-OLEFINS |
JPS60166455A (en) * | 1983-12-29 | 1985-08-29 | 住友化学工業株式会社 | Polypropylene laminated film |
US4737548A (en) | 1984-07-16 | 1988-04-12 | Nippon Petrochemicals | Adhesive resins and laminate articles |
FR2572417B1 (en) | 1984-10-30 | 1987-05-29 | Atochem | ADHESIVE COMPOSITIONS BASED ON POLYPROPYLENE MODIFIED BY Grafting of an Unsaturated Monomer |
US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
JPH0641484B2 (en) | 1985-01-17 | 1994-06-01 | 三井石油化学工業株式会社 | Adhesive for chlorinated propylene-based polymer and chlorine-containing polymer or aromatic polymer |
ATE88196T1 (en) | 1985-01-31 | 1993-04-15 | Himont Inc | FREE LONG CHAIN BRANCHING POLYPROPYLENE, PROCESS FOR PRODUCTION AND USE THEREOF. |
JPS61192240A (en) | 1985-02-20 | 1986-08-26 | 株式会社 オシキリ | Method and apparatus for controlling temperature of bread dough |
US5100963A (en) | 1985-03-14 | 1992-03-31 | Avery Dennison Corporation | Pressure-sensitive adhesives based on similar polymers |
US5231126A (en) | 1985-04-01 | 1993-07-27 | Shi Guan Yi | Beta-crystalline form of isotactic polypropylene and method for forming the same |
DE3519064A1 (en) | 1985-05-28 | 1986-12-04 | Avery International Corp., Wilmington, Del. | MULTILAYER, SELF-ADHESIVE AND DRAWN PROTECTIVE FILM, IN PARTICULAR FOR MOTOR VEHICLES |
US4897455A (en) | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
CA1268753A (en) | 1985-06-21 | 1990-05-08 | Exxon Chemical Patents, Inc. | Supported polymerization catalyst |
US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
US4668834B1 (en) * | 1985-10-16 | 1996-05-07 | Uniroyal Chem Co Inc | Low molecular weight ethylene-alphaolefin copolymer intermediates |
US4668853A (en) | 1985-10-31 | 1987-05-26 | Westinghouse Electric Corp. | Arc-heated plasma lance |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US5124418A (en) | 1985-11-15 | 1992-06-23 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
FR2599826B1 (en) | 1986-06-04 | 1989-08-25 | Fives Cail Babcock | PROCESS FOR REGULATING A CEMENT-MANUFACTURING PLANT IN A DRY WAY WITH PRE-CALCINATION |
US4689437A (en) | 1986-07-21 | 1987-08-25 | Union Carbide Corporation | Oligomerization to alpha-olefins |
US4774144A (en) | 1986-07-28 | 1988-09-27 | Enron Chemical Company | Adhesive blends and composite structures |
US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
ATE177759T1 (en) | 1986-09-24 | 1999-04-15 | Mitsui Chemicals Inc | METHOD FOR OLEFIN POLYMERIZATION |
KR920000173B1 (en) | 1986-10-09 | 1992-01-09 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | Low crystal propyrene random copolymer composition and its making method and polypropylene composite lamination |
JPH0780933B2 (en) | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | Olefin Polymerization Method |
DE3640924A1 (en) | 1986-11-29 | 1988-06-01 | Hoechst Ag | 1-OLEFIN STEREOBLOCK POLYMER AND METHOD FOR THE PRODUCTION THEREOF |
FR2609036B1 (en) | 1986-12-29 | 1989-04-14 | Bp Chimie Sa | POLYMERIZATION OR COPOLYMERIZATION OF ETHYLENE IN THE GASEOUS PHASE IN THE PRESENCE OF A PREPOLYMER COMPRISING A CHROMIUM OXIDE CATALYST |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5096867A (en) | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
US5264405A (en) | 1989-09-13 | 1993-11-23 | Exxon Chemical Patents Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts |
IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US4719260A (en) | 1987-02-09 | 1988-01-12 | Eastman Kodak Company | Hot-melt adhesive compositions |
JPH0742301B2 (en) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | Particulate aluminoxane, its manufacturing method and its use |
US6121393A (en) | 1987-02-17 | 2000-09-19 | Mitsui Chemicals | Process for polymerizing alpha-olefins |
US5003019A (en) * | 1987-03-02 | 1991-03-26 | Mitsui Petrochemical Industries, Ltd. | Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers |
ATE133690T1 (en) | 1987-04-03 | 1996-02-15 | Fina Technology | METALLOCENE CATALYST SYSTEMS FOR THE POLYMERSATION OF OLEFINS, WITH A SILICON-HYDROCARBYL BRIDGE. |
JP2538588B2 (en) | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | Method for producing solid catalyst for olefin polymerization |
US4794096A (en) | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
US4939217A (en) | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
FR2613722B1 (en) | 1987-04-07 | 1990-11-23 | Bp Chimie Sa | PROCESS FOR THE MANUFACTURE OF PROPYLENE HOMOPOLYMER OR COPOLYMER GRANULES |
US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
FR2614897B1 (en) | 1987-05-07 | 1991-12-20 | Charbonnages Ste Chimique | THERMOPLASTIC COMPOSITIONS CONTAINING A MODIFIED ETHYLENE POLYMER AND A C3-C12 OLEFIN POLYMER, THEIR PREPARATION PROCESS AND THEIR APPLICATION FOR OBTAINING INDUSTRIAL ARTICLES |
DE3716286A1 (en) | 1987-05-15 | 1988-11-24 | Henkel Kgaa | METHOD FOR SHAPING AGGLOMERATION OF SOLID PARTICLES |
US5093415A (en) | 1987-05-19 | 1992-03-03 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing stereoregular polymers having a narrow molecular weight distribution |
DE3720984A1 (en) | 1987-06-25 | 1989-01-05 | Hoechst Ag | Curable mixtures and their use |
DE3726067A1 (en) | 1987-08-06 | 1989-02-16 | Hoechst Ag | METHOD FOR PRODUCING 1-OLEFIN POLYMERS |
US4826939A (en) | 1987-08-31 | 1989-05-02 | Eastman Kodak Company | Highly amorphous olefin terpolymer |
US5015749A (en) | 1987-08-31 | 1991-05-14 | The Dow Chemical Company | Preparation of polyhydrocarbyl-aluminoxanes |
DE3750776T2 (en) | 1987-09-11 | 1995-04-27 | Fina Technology | Catalyst system for polyolefin production with a broad molecular weight distribution. |
US4975403A (en) | 1987-09-11 | 1990-12-04 | Fina Technology, Inc. | Catalyst systems for producing polyolefins having a broad molecular weight distribution |
US4886853A (en) | 1987-11-30 | 1989-12-12 | Eastman Kodak Company | Hot-melt adhesive composition |
US5021257A (en) * | 1987-11-30 | 1991-06-04 | Eastman Kodak Company | Hot-melt adhesive composition |
EP0319043A3 (en) | 1987-12-04 | 1991-03-20 | Union Carbide Corporation | Hot melt adhesives |
FR2625506B1 (en) | 1987-12-31 | 1992-02-21 | Bp Chimie Sa | METHOD AND APPARATUS FOR THE MANUFACTURE OF CONTROLLED POLYMERS USING A REGULATION SYSTEM INCLUDING AN INFRARED SPECTROPHOTOMETER |
FR2628110B1 (en) | 1988-03-03 | 1994-03-25 | Bp Chimie | CATALYST FOR POLYMERIZATION OF ZIEGLER-NATTA-TYPE OLEFINS, SUPPORTED ON SPHERICAL MAGNESIUM CHLORIDE PARTICLES, AND PROCESS FOR PREPARING THE SAME |
US4939202A (en) | 1988-03-09 | 1990-07-03 | The International Group, Inc. | Barrier guard moisture-proof adhesive |
US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
US5149819A (en) | 1988-04-28 | 1992-09-22 | Ricoh Company, Ltd. | Squarylium compounds and optical information recording medium using the same |
US4950720A (en) | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
US5155160A (en) | 1988-05-02 | 1992-10-13 | James River Ii, Inc. | Polyolefin films having improved barrier properties |
US4960820A (en) | 1988-05-24 | 1990-10-02 | Shell Oil Company | Compositions and articles using high melt flow poly-1-butene and polypropylene blends |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
CA1319539C (en) | 1988-06-16 | 1993-06-29 | Armenag H. Dekmezian | Method and apparatus for collecting samples for analysis of chemical composition |
US5039614A (en) | 1988-06-16 | 1991-08-13 | Armenag Dekmezian | Method and apparatus for collecting samples for analysis of chemical composition |
US4929509A (en) | 1988-07-06 | 1990-05-29 | Eastman Kodak Company | Adhesives based on amorphous propylene/hexene copolymers |
FI893348A (en) | 1988-07-11 | 1990-01-12 | Sumitomo Chemical Co | ETYLEN-A-OLEFINKOPOLYMER OCH FILMER FRAMSTAELLDA AV DENNA. |
FR2634212B1 (en) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | APPARATUS AND METHOD FOR POLYMERIZATION OF GASEOUS OLEFINS IN A FLUIDIZED BED REACTOR |
US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
US5225500A (en) | 1988-07-15 | 1993-07-06 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
DE3826075A1 (en) | 1988-07-30 | 1990-02-01 | Hoechst Ag | 1-OLEFIN ISO BLOCK POLYMER AND METHOD FOR THE PRODUCTION THEREOF |
JP2600829B2 (en) * | 1988-08-04 | 1997-04-16 | 三井石油化学工業株式会社 | Polypropylene resin composition |
US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
KR920006464B1 (en) | 1988-09-14 | 1992-08-07 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | Olefin polymerization catalyst component olefin polymerization catalyst and process for the polymerization of olefins |
US5219903A (en) | 1988-10-15 | 1993-06-15 | Sumitomo Chemical Company, Ltd. | Pigment master batch for filler-containing polypropylene compositions |
EP0366411A3 (en) | 1988-10-28 | 1991-04-24 | Exxon Chemical Patents Inc. | Graft polymers of ethylene-propylene-diene monomer polymers with propylene, means of preparation, and use of polypropylene compositions |
JP2672354B2 (en) | 1988-11-22 | 1997-11-05 | 三井東圧化学株式会社 | Polypropylene resin composition |
US5041584A (en) | 1988-12-02 | 1991-08-20 | Texas Alkyls, Inc. | Modified methylaluminoxane |
US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
US5108680A (en) | 1988-12-17 | 1992-04-28 | Continental Aktiengesellschaft | Method of producing adhesive resin particles |
US5236649A (en) | 1988-12-23 | 1993-08-17 | The Dow Chemical | Extrudable thermoplastic particulates |
US5218071A (en) | 1988-12-26 | 1993-06-08 | Mitsui Petrochemical Industries, Ltd. | Ethylene random copolymers |
EP0685498B1 (en) | 1988-12-26 | 1999-05-26 | Mitsui Chemicals, Inc. | Olefin copolymers and processes for preparing same |
US5639842A (en) * | 1988-12-26 | 1997-06-17 | Mitsui Petrochemical Industries, Ltd. | Ethylene random copolymers |
FR2641540B1 (en) | 1989-01-12 | 1992-08-14 | Solvay | |
DE3901969A1 (en) | 1989-01-24 | 1990-07-26 | Hoechst Ag | BIAXIAL ORIENTED PLASTIC FILM |
US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
DE3907964A1 (en) | 1989-03-11 | 1990-09-13 | Hoechst Ag | METHOD FOR PRODUCING A SYNDIOTACTIC POLYOLEFIN |
CA2030807C (en) | 1989-04-11 | 1995-09-12 | Tadashi Asanuma | Molded articles of syndiotactic polypropylene and method for preparing same |
US5278216A (en) | 1989-04-18 | 1994-01-11 | Mitsui Toatsu Chemicals, Incorporated | Syndiotactic polypropylene resin composition |
AU5433090A (en) | 1989-04-18 | 1990-11-16 | Mitsui Toatsu Chemicals Inc. | Syndiotactic polypropylene molding and method of producing the same |
DE3912949A1 (en) | 1989-04-20 | 1990-10-25 | Huels Chemische Werke Ag | MELT ADHESIVE AND COATING |
US5236962A (en) | 1989-04-28 | 1993-08-17 | Himont Incorporated | Crystalline propylene polymers and copolymers in the form of spherical particles at high porosity |
US6255425B1 (en) | 1989-04-28 | 2001-07-03 | Mitsui Chemicals, Inc. | Syndiotactic polypropylene copolymer and extruded polypropylene articles |
DE3916555A1 (en) | 1989-05-20 | 1990-11-22 | Hoechst Ag | PROCESS FOR THE PRODUCTION OF ETHYLENE POLYMERS |
JP2896160B2 (en) | 1989-05-23 | 1999-05-31 | 三井化学株式会社 | Stretched polypropylene film |
US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
JP2818199B2 (en) * | 1989-06-12 | 1998-10-30 | 三井化学株式会社 | Syndiotactic polypropylene resin composition and method for producing the same |
US5594172A (en) * | 1989-06-21 | 1997-01-14 | Nissan Motor Co., Ltd. | Semiconductor accelerometer having a cantilevered beam with a triangular or pentagonal cross section |
US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
DE3921358A1 (en) | 1989-06-29 | 1991-01-10 | Hoechst Ag | BIAXIAL-ORIENTED POLYPROPYLENE FILM WITH HIGH MECHANICAL STRENGTH |
US5041251A (en) | 1989-07-27 | 1991-08-20 | Eastman Kodak Company | Pourable particles of normally tacky plastic materials and process for their preparation |
US5376612A (en) | 1989-08-10 | 1994-12-27 | Phillips Petroleum Company | Chromium catalysts and process for making chromium catalysts |
IL95097A0 (en) | 1989-08-23 | 1991-06-10 | Himont Inc | Thermoplastic olefin polymer and its preparation |
EP0414047B1 (en) | 1989-08-25 | 1997-01-08 | MITSUI TOATSU CHEMICALS, Inc. | A novel polypropylene fiber and a preparation process thereof |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5209971A (en) | 1989-09-06 | 1993-05-11 | Minnesota Mining And Manufacturing Company | Radiation curable polyolefin pressure sensitive adhesive |
DE3930205A1 (en) | 1989-09-09 | 1991-03-14 | Borsig Babcock Ag | TUBE BUNCH HEAT EXCHANGER |
US5548014A (en) | 1989-09-13 | 1996-08-20 | Exxon Chemical Patents Inc. | Blends of ethylene copolymers for hot melt adhesives |
US5504169A (en) | 1989-09-13 | 1996-04-02 | Exxon Chemical Patents Inc. | Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
DD300443A5 (en) * | 1989-09-13 | 1992-06-11 | Exxon Chemical Patents Inc | HOT MELT GLUE |
US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5066741A (en) | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
CA2027145C (en) | 1989-10-10 | 2002-12-10 | Michael J. Elder | Metallocene catalysts with lewis acids and aluminum alkyls |
US5763549A (en) | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
DE69018376T3 (en) | 1989-10-30 | 2002-05-16 | Fina Technology | Manufacture of metallocene catalysts for olefin polymerization. |
US5387568A (en) | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
GB8925685D0 (en) * | 1989-11-14 | 1990-01-04 | Exxon Chemical Patents Inc | Resin use for tackification |
JP2977595B2 (en) | 1989-11-20 | 1999-11-15 | 三井化学株式会社 | Syndiotactic polypropylene molded article and method for producing the same |
US6156846A (en) | 1989-11-28 | 2000-12-05 | Idemitsu Petrochemical Co., Ltd. | Flexible polypropylene resins, propylene bases elastomer compositions and process for production of olefin polymers |
EP0430472A3 (en) | 1989-11-30 | 1992-02-26 | Imperial Chemical Industries Plc | Multiple-layer polyolefin films |
DE3940197A1 (en) | 1989-12-05 | 1991-06-06 | Hoechst Ag | DOUBLE-SIDED SEALABLE, BIAXIAL-ORIENTED POLYOLEFIN MULTILAYER FILM, THEIR PRODUCTION AND THEIR USE |
JP2894823B2 (en) | 1989-12-06 | 1999-05-24 | 三井化学株式会社 | Method for producing radiation-resistant polypropylene resin composition and radiation-resistant molded article |
ATE186918T1 (en) | 1990-01-02 | 1999-12-15 | Exxon Chemical Patents Inc | SUPPORTED IONIC METALLOCE CATALYSTS FOR OLEFIN POLYMERIZATION |
EP0442245A1 (en) | 1990-02-12 | 1991-08-21 | KELLER S.p.A. | Device for locking the wheels of vehicles on a vehicle wagon |
US5519091A (en) * | 1990-02-13 | 1996-05-21 | Mitsui Petrochemical Industries, Ltd. | Method for the preparation of ethylene polymer compositions |
TW206240B (en) * | 1990-02-13 | 1993-05-21 | Mitsui Petroleum Chemicals Ind | |
US5151474A (en) | 1990-02-16 | 1992-09-29 | The Dow Chemical Company | Process control method for manufacturing polyolefin |
GB2241244B (en) | 1990-02-22 | 1994-07-06 | James C W Chien | Thermoplastic elastomers |
US5171793A (en) | 1990-02-22 | 1992-12-15 | Exxon Chemical Patents Inc. | Hydrogenated resins, adhesive formulations and process for production of resins |
DE4006402A1 (en) | 1990-03-01 | 1991-09-05 | Wolff Walsrode Ag | High-slip, drawn polypropylene film, for transparent packaging - contains mixts. of poly-iso-butyl-methacrylate! and poly-methyl-methacrylate as antiblocking agent, with antistatics and lubricants |
US5116881A (en) | 1990-03-14 | 1992-05-26 | James River Corporation Of Virginia | Polypropylene foam sheets |
WO1991015523A1 (en) | 1990-04-09 | 1991-10-17 | Mitsui Toatsu Chemicals, Incorporated | Propylene copolymer |
US5075386A (en) | 1990-04-12 | 1991-12-24 | Eastman Kodak Company | Cross-linkable hot-melt adhesive and method of producing same |
DE69130403T2 (en) | 1990-04-18 | 1999-04-15 | Mitsui Chemicals Inc | Syndiotactic propylene copolymer, preparation thereof and composition containing this copolymer |
MY107639A (en) | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
DE69111354T2 (en) | 1990-04-18 | 1995-12-21 | Mitsui Petrochemical Ind | HOT MELT ADHESIVE. |
US5114897A (en) | 1990-04-18 | 1992-05-19 | The Dow Chemical Company | Catalyst and process for polymerizing olefins |
US5252659A (en) | 1990-04-26 | 1993-10-12 | Toyoda Gosei Co., Ltd. | Molded polypropylene-α-olefin product having low coefficient of linear expansion |
JP2828485B2 (en) | 1990-04-27 | 1998-11-25 | 大倉工業株式会社 | Method for producing polypropylene-based multilayer stretched film |
AU7875791A (en) | 1990-05-07 | 1991-11-27 | Exxon Chemical Patents Inc. | Unsaturated alpha-olefin copolymers and method for preparation thereof |
DE4015254A1 (en) * | 1990-05-12 | 1991-11-14 | Hoechst Ag | METHOD FOR PRODUCING A POLYOLEFIN |
DE4015739A1 (en) | 1990-05-16 | 1991-11-21 | Hoechst Ag | METHOD FOR PRODUCING A COMPOSITE BODY FROM POLYPROPYLENE |
US5326824A (en) | 1990-05-18 | 1994-07-05 | Mitsui Toatsu Chemicals, Incorporated | Syndiotactic propylene copolymer, method for preparing same, and its use |
JP2927885B2 (en) | 1990-05-24 | 1999-07-28 | 三井化学株式会社 | Method for producing syndiotactic poly-α-olefin |
US5041585A (en) | 1990-06-08 | 1991-08-20 | Texas Alkyls, Inc. | Preparation of aluminoxanes |
BR9106589A (en) | 1990-06-22 | 1993-06-01 | Exxon Chemical Patents Inc | ALUMINUM-FREE MONOCYCLOPENTADYLENE METAL CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
JP2545006B2 (en) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | Addition polymerization catalyst |
WO1992001723A1 (en) | 1990-07-24 | 1992-02-06 | Mitsui Toatsu Chemicals, Incorporated | CATALYST FOR α-OLEFIN POLYMERIZATION AND PRODUCTION OF POLY-α-OLEFIN THEREWITH |
IT1243188B (en) | 1990-08-01 | 1994-05-24 | Himont Inc | POLYOLEFINIC ELASTOPLASTIC COMPOSITIONS |
US5219913A (en) | 1990-09-12 | 1993-06-15 | Idemitsu Petrochemical Company, Ltd. | Polypropylene-based resin composition |
DE4030385A1 (en) | 1990-09-26 | 1992-04-02 | Hoechst Ag | TRANSPARENT SHRINK FILM MADE OF BIAXIAL-ORIENTED POLYPROPYLENE FOR ALL-ROUND LABELING |
US5145689A (en) | 1990-10-17 | 1992-09-08 | Exxon Chemical Patents Inc. | Meltblowing die |
US5096743A (en) * | 1990-11-09 | 1992-03-17 | E. I. Du Pont De Nemours And Company | Process for making roofing membrane of epdm elastomer and ethylene-containing polymer |
US5317070A (en) * | 1990-11-09 | 1994-05-31 | Exxon Chemical Patents, Inc. | Syndiotactic hot melt adhesive |
DE59104869D1 (en) | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituted bisindenyl metallocenes, process for their preparation and their use as catalysts in olefin polymerization. |
EP0485821B1 (en) | 1990-11-12 | 1996-06-12 | Hoechst Aktiengesellschaft | Metallocenes with 2-substituted indenyl-derivates as ligands, process for their preparation and their use as catalysts |
US5243001A (en) | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
US5239022A (en) | 1990-11-12 | 1993-08-24 | Hoechst Aktiengesellschaft | Process for the preparation of a syndiotactic polyolefin |
US5294668A (en) | 1990-11-15 | 1994-03-15 | Minnesota Mining And Manufacturing Company | Polyolefin pressure-sensitive adhesive compositions containing macromonomers |
JPH051185A (en) | 1990-11-16 | 1993-01-08 | Mitsubishi Petrochem Co Ltd | Thermoplastic resin composition excellent in strength and its production |
WO1992009640A1 (en) | 1990-11-30 | 1992-06-11 | Idemitsu Kosan Co., Ltd. | Process for producing olefinic polymer |
DE4038935A1 (en) | 1990-12-06 | 1992-06-11 | Hoechst Ag | BIDDEN SEALABLE BIAXIALLY ORIENTED POLYOLE FINE MULTILAYER FOIL WITH INCREASED SCRAP AND IMPROVED BARRIER PROPERTIES |
ATE135358T1 (en) | 1990-12-27 | 1996-03-15 | Exxon Chemical Patents Inc | TRANSITION METAL AMIDE COMPOUND AND CATALYST SYSTEM FOR PRODUCING ISOTACTIC PROPYLENE |
DE69117534T3 (en) | 1990-12-27 | 2002-10-10 | Exxon Mobil Chem Patents Inc | HOT MELT ADHESIVE COMPOSITION |
US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
US5204037A (en) | 1991-01-25 | 1993-04-20 | Idemitsu Petrochemical Co., Ltd. | Process for production of polypropylene sheets or films |
US5152946A (en) | 1991-01-30 | 1992-10-06 | Hercules Incorporated | Producing low shrink packaging film |
US5851610A (en) | 1991-02-07 | 1998-12-22 | Applied Extrusion Technologies, Inc. | Shrink films and articles including the same |
CA2060019A1 (en) | 1991-03-04 | 1992-09-05 | Phil Marvin Stricklen | Process for producing polyolefins having a bimodal molecular weight distribution |
US5206197A (en) | 1991-03-04 | 1993-04-27 | The Dow Chemical Company | Catalyst composition for preparation of syndiotactic vinyl aromatic polymers |
JP3117231B2 (en) | 1991-03-11 | 2000-12-11 | 三井化学株式会社 | Method for producing syndiotactic poly-α-olefin having a broad molecular weight distribution |
TW218884B (en) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
US5436305A (en) | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
US5401817A (en) | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
US5571880A (en) | 1991-05-09 | 1996-11-05 | Phillips Petroleum Company | Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process |
CA2058383A1 (en) | 1991-05-17 | 1992-11-18 | Ted M. Pettijohn | Olefin polymerization |
DE69226564T3 (en) | 1991-05-20 | 2004-04-08 | Mitsui Chemicals, Inc. | Catalyst and process for olefin polymerization |
GB9111192D0 (en) | 1991-05-23 | 1991-07-17 | British Bio Technology | Synthetic process |
EP0702030B1 (en) | 1991-05-27 | 2001-03-21 | TARGOR GmbH | Process for preparing olefin polymers with large molecular weight distribution |
EP0516019B1 (en) | 1991-05-27 | 1995-12-27 | Hoechst Aktiengesellschaft | Process for preparing syndiotactic polyolefins with large molecular weight distribution |
US5341124A (en) | 1991-05-29 | 1994-08-23 | Se-Kure Controls, Inc. | Mountable product sensor and display stand |
DE4120009A1 (en) | 1991-06-18 | 1992-12-24 | Basf Ag | SOLUBLE CATALYST SYSTEMS FOR THE PRODUCTION OF POLYALK-1-ENEN WITH HIGH MOLES |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5594078A (en) * | 1991-07-23 | 1997-01-14 | Phillips Petroleum Company | Process for producing broad molecular weight polyolefin |
US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
EP0527589B1 (en) | 1991-08-08 | 1998-06-03 | Ube Rexene Corporation | Resin composition comprising amorphous polyolefin and crystalline polypropylene |
NL9101502A (en) | 1991-09-06 | 1993-04-01 | Dsm Nv | A METHOD FOR PREPARING A BRIDGED METALLOCENE COMPOUND, A CATALYST COMPONENT AND A METHOD FOR THE POLYMERIZATION OF OLEFINS. |
CA2077744C (en) | 1991-09-30 | 2003-04-15 | Edwar Shoukri Shamshoum | Homogeneous-heterogeneous catalyst system for polyolefins |
US5416228A (en) * | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
JP3341117B2 (en) | 1991-10-15 | 2002-11-05 | ザ ダウ ケミカル カンパニー | Production of metal coordination complex |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US5582923A (en) * | 1991-10-15 | 1996-12-10 | The Dow Chemical Company | Extrusion compositions having high drawdown and substantially reduced neck-in |
JP3394997B2 (en) | 1991-10-15 | 2003-04-07 | バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | Process for producing olefin polymers using metallocenes having specifically substituted indenyl ligands |
US5233049A (en) | 1991-10-29 | 1993-08-03 | Occidental Chemical Corporation | Highly fluorinated bis-imides |
BE1006840A5 (en) | 1992-05-04 | 1995-01-03 | Solvay | Catalyst system for olefin polymerisation; method for the polymerization and polymers therefrom. |
TW209877B (en) | 1991-11-04 | 1993-07-21 | Shell Internat Res Schappej B V | |
US5281679A (en) | 1991-11-07 | 1994-01-25 | Exxon Chemical Patents Inc. | Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof |
US5359015A (en) | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
IT1252388B (en) | 1991-11-12 | 1995-06-12 | Sviluppo Settori Impiego Srl | PROPYLENE POLYMERS AND COPOLYMERS SEAMED WITH VINYL POLYBUTADIENE AND PREPARATION PROCEDURE |
DE69224600T2 (en) | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Catalyst components for olefin polymerization |
US5367022A (en) | 1991-11-27 | 1994-11-22 | Quantum Chemical Corporation | Grafted polymeric products, and adhesive blends |
DE69224463T2 (en) | 1991-11-28 | 1998-07-09 | Showa Denko Kk | Novel metallocene and process for making polyolefins using the same |
JPH07501845A (en) | 1991-12-13 | 1995-02-23 | エクソン・ケミカル・パテンツ・インク | Copolymers of ethylene and longer alpha olefins |
US5496295A (en) | 1991-12-18 | 1996-03-05 | Minnesota Mining And Manufacturing Company | Multilayered barrier structures |
US5202361A (en) | 1991-12-23 | 1993-04-13 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive |
US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
DE69232297T2 (en) | 1992-01-06 | 2002-08-14 | Dow Chemical Co | catalyst composition |
US5391660A (en) | 1992-01-14 | 1995-02-21 | Nippon Oil Company, Limited | Process for preparing polyolefines |
EP0552945B1 (en) * | 1992-01-23 | 1997-05-07 | Mitsui Petrochemical Industries, Ltd. | Process for the preparation of polyolefin |
TW337527B (en) | 1992-01-24 | 1998-08-01 | Hoechst Ag | Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof |
TW304963B (en) | 1992-01-27 | 1997-05-11 | Hoechst Ag | |
US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
GB9205841D0 (en) | 1992-03-18 | 1992-04-29 | Exxon Chemical Patents Inc | Hydrocarbon resins,processes for their manufacture and adhesive compositions containing such resins |
US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
FI112233B (en) | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Catalyst for olefin polymerization, process for its preparation and its use |
US5310584B1 (en) | 1992-04-14 | 1999-02-16 | Amoco Corp | Thermoformable polypropylene-based sheet |
US5459217A (en) | 1993-04-09 | 1995-10-17 | Mitsui Petrochemical Industries, Ltd. | Ethylene/alpha-olefin copolymer |
FI96220C (en) | 1992-04-16 | 1996-05-27 | Borealis As | Plastic material for packaging |
EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
US5308817A (en) * | 1992-05-18 | 1994-05-03 | Fina Technology, Inc. | Metallocene catalyst component with good catalyst efficiency after aging |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
US5434115A (en) * | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
BE1005957A5 (en) | 1992-06-05 | 1994-04-05 | Solvay | Preparation method of catalyst system, process (co) polymerization of olefins and (co) polymer at least one olefine. |
JPH08501325A (en) | 1992-06-18 | 1996-02-13 | スペリレーネ エッセ.アール.エッレ. | Ethylene polymer manufacturing method |
US5710222A (en) | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
DE69332811T2 (en) | 1992-07-01 | 2004-01-29 | Exxonmobil Chem Patents Inc | Catalyst precursors based on Group 5 and 6 transition metals |
US5332707A (en) | 1992-07-31 | 1994-07-26 | Amoco Corporation | Olefin polymerization and copolymerization catalyst |
CA2141814A1 (en) | 1992-08-05 | 1994-02-17 | David Jonathan Upton | Supported ionic transition metal catalysts for olefin polymerization |
US5246779A (en) | 1992-08-10 | 1993-09-21 | Quantum Chemical Corporation | Microfine propylene polymer powders and process for their preparation |
ES2128371T3 (en) | 1992-08-15 | 1999-05-16 | Targor Gmbh | PROCEDURE FOR OBTAINING POLYOLEFINS. |
US6867253B1 (en) | 1994-04-19 | 2005-03-15 | Applied Elastomerics, Inc. | Tear resistant, crystalline midblock copolymer gels and articles |
US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
DE4228812A1 (en) | 1992-08-29 | 1994-03-03 | Hoechst Ag | Sealable polypropylene multilayer film, process for its production and its use |
EP0586168B1 (en) | 1992-09-04 | 2000-07-05 | BP Chemicals Limited | Catalyst compositions and process for preparing polyolefins |
JP3355534B2 (en) * | 1992-09-10 | 2002-12-09 | 住友化学工業株式会社 | Ethylene-α-olefin copolymer and molded article molded using the copolymer |
ES2126002T3 (en) * | 1992-09-15 | 1999-03-16 | Dow Chemical Co | MODIFICATION OF THE RESISTANCE TO THE SHOCK OF THERMOPLASTICS. |
TW254955B (en) | 1992-09-25 | 1995-08-21 | Ciba Geigy | |
WO1994007930A1 (en) | 1992-09-29 | 1994-04-14 | Exxon Chemical Patents Inc. | Long chain branched polymers and a process to make long chain branched polymers |
WO1994007928A1 (en) | 1992-10-02 | 1994-04-14 | The Dow Chemical Company | Supported homogeneous catalyst complexes for olefin polymerization |
CA2104046C (en) | 1992-10-05 | 1998-09-15 | Yen-Lane Chen | Adhesive compositions, wound dressings and methods |
US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
US5391793A (en) | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
CA2103401C (en) | 1992-11-19 | 2002-12-17 | Mamoru Takahashi | Ethylene copolymer composition |
US5464905A (en) | 1992-11-19 | 1995-11-07 | Mitsui Petrochemical Industries, Ltd. | Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process |
CA2103379C (en) | 1992-11-19 | 2000-05-23 | Toshiyuki Tsutsui | Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition |
WO1994012193A1 (en) | 1992-11-24 | 1994-06-09 | Debiopharm S.A. | Cisplatinum/oxaliplatinum combination |
IT1256663B (en) | 1992-12-15 | 1995-12-12 | Himont Inc | POLYPROPYLENE COMPOSITIONS WITH GOOD TRANSPARENCY AND IMPROVED IMPACT RESISTANCE. |
IT1256662B (en) | 1992-12-15 | 1995-12-12 | Himont Inc | HYDRAULIC THERMOPLASTIC ELASTOMERS AND PROCESS FOR THEIR PREPARATION |
BE1006438A3 (en) | 1992-12-17 | 1994-08-30 | Solvay | Catalyst system, use of this system catalyst for the (co) polymerization of olefins, method of preparation of this system and method for catalyst (co) polymerization of olefins. |
CA2110654C (en) | 1992-12-17 | 2006-03-21 | Albert Rossi | Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems |
IT1256664B (en) | 1992-12-28 | 1995-12-12 | Spherilene Srl | BITUMINOUS COMPOSITIONS MODIFIED WITH POLYOLEFINIC MATERIALS. |
IT1256260B (en) * | 1992-12-30 | 1995-11-29 | Montecatini Tecnologie Srl | ATACTIC POLYPROPYLENE |
EP0646624B1 (en) | 1993-01-11 | 1998-09-02 | Mitsui Chemicals, Inc. | Propylene polymer composition |
GB9300934D0 (en) | 1993-01-19 | 1993-03-10 | Bp Chem Int Ltd | Metallocene complexes |
US5914376A (en) | 1993-01-21 | 1999-06-22 | Targor Gmbh | Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof |
DE59408824D1 (en) | 1993-01-25 | 1999-11-25 | Hoechst Trespaphan Gmbh | Biaxially oriented polypropylene multilayer film, process for its production and its use |
US5391529A (en) | 1993-02-01 | 1995-02-21 | Albemarle Corporation | Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene |
DE69430795T2 (en) | 1993-02-05 | 2002-11-28 | Idemitsu Kosan Co | POLYETHYLENE, THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME AND METHOD FOR PRODUCING POLYETHYLENE |
TW298593B (en) | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
DE4304377A1 (en) | 1993-02-13 | 1994-08-18 | Hoechst Ag | Low-boiling, biaxially oriented polyolefin multilayer film, process for its preparation and its use |
US5747620A (en) * | 1993-02-22 | 1998-05-05 | Idemitsu Kosan Co., Ltd. | Ethylene copolymer, thermoplastic resin composition containing same, and process for preparing ethylene copolymer |
US6313240B1 (en) | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
BE1006880A3 (en) * | 1993-03-01 | 1995-01-17 | Solvay | Precurseur solid system of a catalyst for olefin polymerization, method of preparation, catalytic system including the solid precursor and method for polymerization of olefins in the presence of this system catalyst. |
DE4307440A1 (en) | 1993-03-10 | 1994-09-15 | Wolff Walsrode Ag | Multilayer, stretched, heat-sealable polypropylene film |
JP3352494B2 (en) | 1993-03-25 | 2002-12-03 | 三井鉱山株式会社 | Nitrogen oxide decomposition catalyst and denitration method using the same |
EP0619325B1 (en) | 1993-04-07 | 2001-08-29 | ATOFINA Research | Process for preparing polyolefin catalysts |
US5859088A (en) | 1993-04-13 | 1999-01-12 | Minnesota Mining And Manufacturing Company | Radiation-curable poly(α-olefin) adhesives |
CA2118777A1 (en) | 1993-04-13 | 1994-10-14 | Gaddam N. Babu | Radiation-curable poly(alpha-olefin) adhesives |
DE4312543A1 (en) | 1993-04-17 | 1994-10-20 | Hoechst Ag | Matte transfer metallization film, process for its production and its use |
US5290886A (en) | 1993-04-20 | 1994-03-01 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved low temperature properties |
US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
KR100190268B1 (en) | 1993-04-26 | 1999-06-01 | 에인혼 해롤드 | Process for polymerizing monomers in fludized beds |
GB9308669D0 (en) | 1993-04-27 | 1993-06-09 | Du Pont Canada | Grafting of monomers onto polyolefins in presence of organic peroxides |
US5643846A (en) * | 1993-04-28 | 1997-07-01 | Fina Technology, Inc. | Process for a isotactic/syndiotactic polymer blend in a single reactor |
US5804524A (en) | 1993-04-28 | 1998-09-08 | Fina Technology, Inc. | Process for a isotactic/syndiotactic polymer blend in a single reactor |
US5346963A (en) * | 1993-04-28 | 1994-09-13 | The Dow Chemical Company | Graft-modified, substantially linear ethylene polymers and methods for their use |
CA2121721C (en) | 1993-04-29 | 2004-11-23 | Giampiero Morini | Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution |
US5683818A (en) | 1993-05-04 | 1997-11-04 | Kawasaki Chemical Holding Co., Inc. | Method for improving the friction and wear properties of a polyamide and polyproyplene blend |
IT1264437B1 (en) | 1993-05-13 | 1996-09-23 | Spherilene Srl | POLYMERS OF PROPYLENE GRAFTED WITH POLYALKENYLENES AND PROCESS FOR THEIR PREPARATION |
KR960702485A (en) | 1993-05-13 | 1996-04-27 | 벤 씨. 카덴헤드 | POLYMERIZATION CATALYST SYSTEMS, THEIR PRODUCTION AND USE |
BE1007148A3 (en) | 1993-05-17 | 1995-04-11 | Solvay | Support for catalyst, method for producing gel precursor media for catalyst, method for preparing a catalyst support, catalyst for olefin polymerization and method for olefin polymerization using the catalyst . |
US5368919A (en) | 1993-05-20 | 1994-11-29 | Himont Incorporated | Propylene polymer compositions containing high melt strength propylene polymer material |
ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
BE1007040A3 (en) | 1993-05-25 | 1995-02-28 | Solvay | CATALYST SUPPORT AND ALPHA-OLEFIN POLYMERIZATION CATALYST; PROCESSES FOR THEIR PRODUCTION AND POLYMERIZATION OF ALPHA-OLEFINS IN THE PRESENCE OF THE CATALYST. |
DE69409029T2 (en) * | 1993-05-28 | 1998-08-13 | Sekisui Plastics | Separable web-shaped laminate made of thermoplastic foam, process for its production and molded articles made therefrom |
DE4318031A1 (en) | 1993-05-29 | 1994-12-01 | Hoechst Ag | Resin-containing, biaxially oriented polypropylene multilayer film, process for its production and its use |
DE69427999T3 (en) | 1993-06-07 | 2012-09-27 | Mitsui Chemicals, Inc. | Transition metal compound, olefin polymerization catalyst containing the same, processes for olefin polymerization therewith, and homo- and copolymers of propylene |
EP1209165B1 (en) * | 1993-06-07 | 2006-04-19 | Mitsui Chemicals, Inc. | Propylene elastomer |
AT403581B (en) | 1993-06-07 | 1998-03-25 | Danubia Petrochem Polymere | METHOD FOR PRODUCING NEW POLYPROPYLENE BY CHEMICAL DEGRADING |
US6586536B1 (en) | 1993-06-18 | 2003-07-01 | Joseph M. Kelley | High temperature process for the production of atactic, amorphous, tacky propylene homopolymers or copolymers |
US5354721A (en) * | 1993-06-22 | 1994-10-11 | Phillips Petroleum Company | Organo-aluminoxy product and use |
WO1995000526A1 (en) | 1993-06-24 | 1995-01-05 | The Dow Chemical Company | Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom |
DE4322140C1 (en) | 1993-07-02 | 1994-08-25 | Benecke Ag J H | Film or sheet based on polymers of ethylene and propylene, and the use thereof |
GB2279904A (en) | 1993-07-12 | 1995-01-18 | Courtaulds Films | Voided polypropylene laminate |
US5455305A (en) | 1993-07-12 | 1995-10-03 | Montell North America Inc. | Propylene polymer yarn and articles made therefrom |
US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
US5536773A (en) | 1993-07-16 | 1996-07-16 | Mitsui Petrochemical Industries, Ltd. | Polypropylene resin composition and the use of the same |
US6005049A (en) | 1993-07-19 | 1999-12-21 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
US6284857B1 (en) | 1993-07-22 | 2001-09-04 | Mitsui Chemical, Inc. | Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition |
CA2128920C (en) | 1993-07-28 | 1999-06-01 | Akihiko Yamamoto | Propylene polymer compositions |
CN1131953A (en) | 1993-08-06 | 1996-09-25 | 埃克森化学专利公司 | Polymerization catalysts, their production and use |
US5539069A (en) | 1993-08-10 | 1996-07-23 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalysts and methods of olefin polymerization |
IT1271418B (en) | 1993-08-11 | 1997-05-28 | Himont Inc | CAST FILM MANUFACTURES CONSTITUTED BY PROPYLENE POLYMERS |
US5700895A (en) | 1993-08-23 | 1997-12-23 | Sumitomo Chemical Company, Limited | Ethylene-α-olefin copolymer and molded article thereof |
DE4328571C1 (en) | 1993-08-25 | 1994-10-27 | Daimler Benz Ag | Stand for holding a wing in various opening positions relative to its frame |
JPH09502212A (en) | 1993-09-01 | 1997-03-04 | モービル・オイル・コーポレイション | New ring-closure polymer from non-conjugated dienes |
WO1995006556A1 (en) | 1993-09-02 | 1995-03-09 | Quantum Chemical Corporation | Biaxially-oriented polypropylene film with improved gas barrier |
US5455214A (en) | 1993-09-09 | 1995-10-03 | Mobil Oil Corporation | Metallocenes supported on ion exchange resins |
DE4330661A1 (en) | 1993-09-10 | 1995-03-16 | Basf Ag | Cold impact propylene polymers |
IT1271406B (en) | 1993-09-13 | 1997-05-28 | Spherilene Srl | PROCEDURE FOR THE PREPARATION OF ETHYLENE POLYMERS AND OBTAINED PRODUCTS |
US5631202A (en) * | 1993-09-24 | 1997-05-20 | Montell Technology Company B.V. | Stereospecific metallocene catalysts with stereolocking α-CP substituents |
DE4333128A1 (en) | 1993-09-29 | 1995-03-30 | Hoechst Ag | Process for the preparation of polyolefins |
DE4333569A1 (en) | 1993-10-01 | 1995-04-06 | Hoechst Ag | Process for olefin polymerization |
DE4334045A1 (en) | 1993-10-06 | 1995-04-13 | Bayer Ag | Catalyst, its production and use for gas phase polymerization of conjugated dienes |
WO1995010575A1 (en) * | 1993-10-13 | 1995-04-20 | Exxon Chemical Patents Inc. | Adhesives from low molecular weight polypropylene |
US5576259A (en) | 1993-10-14 | 1996-11-19 | Tosoh Corporation | Process for producing α-olefin polymer |
GB9321251D0 (en) | 1993-10-14 | 1993-12-01 | Du Pont Canada | Bounding polyvinyl chloride to cellulosic material |
US5817590A (en) | 1993-10-14 | 1998-10-06 | Tosoh Corporation | Catalyst for αE --olefin polymerization containing a Lewis base |
DE69417983T2 (en) | 1993-10-20 | 1999-09-16 | Sumitomo Chemical Co | Statistical propylene copolymer composition |
DE4335960A1 (en) | 1993-10-21 | 1995-04-27 | Hoechst Ag | Resin-containing, biaxially oriented polypropylene film, process for its production and its use |
DE4336560A1 (en) | 1993-10-27 | 1995-05-04 | Hoechst Ag | Biaxially oriented polyolefin film, process for its production and its use |
US5670438A (en) | 1993-10-27 | 1997-09-23 | Phillips Petroleum Company | Catalyst compositions and catalytic processes |
US5388640A (en) | 1993-11-03 | 1995-02-14 | Amoco Corporation | Method for producing methane-containing gaseous mixtures |
JP3423378B2 (en) | 1993-11-12 | 2003-07-07 | 三井化学株式会社 | Novel transition metal compound, olefin polymerization catalyst component comprising the transition metal compound, olefin polymerization catalyst containing the olefin polymerization catalyst component, and olefin polymerization method |
CA2176950C (en) | 1993-11-19 | 2006-01-31 | Moses Olukayode Jejelowo | Polymerization catalyst systems, their production and use |
US5397843A (en) * | 1993-11-22 | 1995-03-14 | Igi Baychem, Inc. | Polymer compositions comprising amorphous propylene polymer |
EP0654476B1 (en) | 1993-11-24 | 2001-01-24 | TARGOR GmbH | Metallocenes, their preparation and use as catalysts |
JPH07144455A (en) | 1993-11-25 | 1995-06-06 | Canon Inc | Ink jet recording apparatus |
FI95276C (en) | 1993-12-03 | 1996-01-10 | Borealis As | Catalyst for polymerization of olefins and process for their preparation |
KR960705858A (en) | 1993-12-08 | 1996-11-08 | 유미꾸라 레이이찌 | Novel Olefin Polymerization Catalyst and Process for Polymerizing Olefin by Using the Same |
IT1265296B1 (en) | 1993-12-20 | 1996-10-31 | Himont Inc | POLYPROPYLENE FILM FOR PACKAGING |
US5882774A (en) * | 1993-12-21 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Optical film |
FI945958A (en) | 1993-12-21 | 1995-06-22 | Hoechst Ag | Process for the preparation of polyolefins |
EP0659552B1 (en) | 1993-12-22 | 1997-11-05 | Sumitomo Chemical Company Limited | Polypropylene laminated film |
IT1265452B1 (en) | 1993-12-27 | 1996-11-22 | Himont Inc | POLYOLEFINIC COMPOSITE FILMS SUITABLE FOR PACKAGING |
DE69419893T2 (en) | 1993-12-27 | 1999-12-02 | Mitsui Chemicals Inc | Catalyst and process for olefin polymerization |
DE4344688A1 (en) | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocene compound |
DE69419241T2 (en) | 1993-12-27 | 2000-01-27 | Solvay | Zeolite-containing propylene polymer composition and article made from this composition |
DE4344689A1 (en) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocene compound |
US5739225A (en) | 1993-12-28 | 1998-04-14 | Idemitsu Kosan Co., Ltd. | Process for preparing olefin polymer, and ethylenic polymer |
US6214949B1 (en) | 1993-12-29 | 2001-04-10 | Fina Technology, Inc. | Polymerization of polyolefins having low melt flow and high molecular weight |
EP0664301A1 (en) | 1994-01-24 | 1995-07-26 | Dainichiseika Color & Chemicals Mfg. Co. Ltd. | Chitosan derivatives, preparation process thereof and cosmetic compositions containing same |
US6686433B1 (en) * | 1994-02-04 | 2004-02-03 | Exxonmobil Chemical Patents Inc. | Dual donor catalyst system for the polymerization of olefins |
EP0668296B1 (en) | 1994-02-18 | 1998-05-06 | Mitsui Petrochemical Industries, Ltd. | Ethylene polymer and process for preparing the same |
DE69502851T2 (en) | 1994-02-25 | 1998-11-12 | Sumitomo Chemical Co | Statistical propylene copolymer and film laminate thereof |
US5447895A (en) | 1994-03-10 | 1995-09-05 | Northwestern University | Sterically shielded diboron-containing metallocene olefin polymerization catalysts |
GB9404708D0 (en) | 1994-03-11 | 1994-04-27 | Du Pont Canada | Polypropylene-based hot-melt adhesive |
US5594080A (en) * | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
US5843577A (en) | 1994-03-29 | 1998-12-01 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved surface properties |
US5410003A (en) * | 1994-03-31 | 1995-04-25 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of homogeneous polyethylenes |
US5512612A (en) | 1994-04-04 | 1996-04-30 | Minnesota Mining And Manufacturing Company | Pressure sensitive adhesive employing a water-dispersible polymer and articles made there from |
EP0816395B1 (en) * | 1994-04-11 | 2000-07-19 | Mitsui Chemicals, Inc. | Process for preparing propylene polymer composition and propylene polymer composition |
CA2157400C (en) | 1994-04-11 | 2003-07-29 | Takashi Ueda | Process for preparing propylene polymer composition, and propylene polymer composition |
US5455111A (en) | 1994-04-12 | 1995-10-03 | Minnesota Mining And Manufacturing Company | Construction adhesive for porous film |
US5468560A (en) | 1994-04-19 | 1995-11-21 | The Boc Group, Inc. | Product and process for polymeric article with improved surface |
US5468440B1 (en) | 1994-05-06 | 1997-04-08 | Exxon Chemical Patents Inc | Process of making oriented film or structure |
EP0679686B1 (en) | 1994-04-28 | 1998-07-22 | Sumitomo Chemical Company Limited | Polypropylene composition for laminated and oriented film and laminated and oriented film thereof |
AU690907B2 (en) | 1994-05-12 | 1998-05-07 | Showa Denko Kabushiki Kaisha | Propylene polymer, process for producing the same, composition thereof, polymerization catalyst component, and process for producing the same |
EP0683180B1 (en) | 1994-05-18 | 2002-03-06 | Mitsubishi Chemical Corporation | Catalyst for polymerizing an olefin and method for polymerizing the olefin |
JPH10503789A (en) | 1994-05-24 | 1998-04-07 | エクソン・ケミカル・パテンツ・インク | Articles made from polypropylene, higher alpha-olefin copolymers |
FR2721039B1 (en) | 1994-06-13 | 1997-04-04 | Atochem Elf Sa | Hot melt adhesives based on ethylene - (meth) acrylate copolymers. |
US5955625A (en) | 1995-01-31 | 1999-09-21 | Exxon Chemical Patents Inc | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
US5486632A (en) | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
US5529850A (en) | 1994-07-05 | 1996-06-25 | Montell North America Inc. | Fibers produced from crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution |
EP0691366B1 (en) | 1994-07-08 | 1999-03-10 | Tokuyama Corporation | Stretched polypropylene film |
IT1270070B (en) | 1994-07-08 | 1997-04-28 | Spherilene Srl | COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINE |
AU689895B2 (en) | 1994-07-11 | 1998-04-09 | Tonen Chemical Corporation | Polypropylene resin composition |
ES2141868T3 (en) | 1994-07-13 | 2000-04-01 | Hoechst Trespaphan Gmbh | VARIETY LAYER DISCORTEZABLE AND SEALABLE POLYOLEFINIC, MANUFACTURING AND USE PROCEDURE. |
US5552489A (en) | 1994-07-22 | 1996-09-03 | Exxon Chemical Patents Inc. | Tackifiers and a process to obtain tackifiers |
US5455300A (en) | 1994-07-29 | 1995-10-03 | Montell North America Inc. | Graft copolymer of propylene polymer material impact modified with a heterophasic olefin polymer material |
DE4431644A1 (en) | 1994-08-01 | 1996-03-07 | Danubia Petrochem Deutschland | Olefin polymerisation catalyst esp. for direct isotactic/elastomer polypropylene@ prodn. |
US5616664A (en) | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
IT1274606B (en) | 1994-08-09 | 1997-07-18 | Spherilene Srl | MIXTURES OF ATACTIC POLYPROPYLENE AND SYNDIOTACTIC POLYPROPYLENE |
US5516583A (en) * | 1994-08-29 | 1996-05-14 | E. I. Du Pont De Nemours And Company | Adhesive for tamper evident seals |
DE4431838A1 (en) | 1994-09-07 | 1996-03-14 | Basf Ag | Supported metallocene catalyst systems |
AU693917B2 (en) | 1994-09-08 | 1998-07-09 | Showa Denko Kabushiki Kaisha | Propylene block copolymer, process for producing the same and resin composition comprising the same |
US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
TW369547B (en) | 1994-09-21 | 1999-09-11 | Mitsui Chemicals Inc | Olefin polymerization catalyst and process for olefin polymerization |
US5529943A (en) * | 1994-09-30 | 1996-06-25 | United Microelectronics Corporation | Method of making buried bit line ROM with low bit line resistance |
DE4436113A1 (en) | 1994-10-10 | 1996-04-11 | Hoechst Ag | Metallocene compound |
CA2160618A1 (en) | 1994-10-19 | 1996-04-20 | Yasuhiro Nohara | Propylene resin composition, molded articles thereof and propylene resin laminate |
US6300451B1 (en) | 1994-10-24 | 2001-10-09 | Exxon Chemical Patents Inc. | Long-chain branched polymers and their production |
WO1996013531A1 (en) | 1994-10-31 | 1996-05-09 | W.R. Grace & Co.-Conn. | Preparation of modified polyolefin catalysts and in situ preparation of supported metallocene and ziegler-natta/metallocene polyolefin catalysts |
US6291063B1 (en) | 1994-11-07 | 2001-09-18 | Cryovac, Inc. | Film containing silicon oil and antiblocking agent |
CA2162946C (en) | 1994-11-21 | 2004-01-06 | Kazuyuki Watanabe | Propylene block copolymer and process for producing the same |
CA2164461C (en) | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
DE4443458A1 (en) | 1994-12-07 | 1996-06-13 | Wolff Walsrode Ag | Multilayer, stretched, heat-sealable polypropylene film |
US5430070A (en) * | 1994-12-16 | 1995-07-04 | Ryusuke Kono | Functional insulation resin composition |
US5539124A (en) | 1994-12-19 | 1996-07-23 | Occidental Chemical Corporation | Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring |
JP3824325B2 (en) * | 1994-12-20 | 2006-09-20 | モンテル テクノロジー カンパニー ビーブイ | Reactant blend polypropylene, process for its production and process for the production of metallocene ligands |
TW383314B (en) * | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer |
DE69525228T2 (en) | 1994-12-20 | 2002-07-11 | Sumitomo Rubber Ind | Rubber compound for tire treads |
TW383313B (en) | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers |
SG38896A1 (en) | 1994-12-22 | 1997-04-17 | Sumitomo Chemical Co | Polypropylene composition and laminated and oriented film therefrom |
KR100252074B1 (en) | 1994-12-26 | 2000-04-15 | 나까니시 히로유끼 | Unsaturated ethylenic copolymer and its production |
DE4446923A1 (en) * | 1994-12-28 | 1996-07-04 | Hoechst Ag | Polyolefin wax |
ES2116188B1 (en) | 1994-12-30 | 1999-04-01 | Repsol Quimica Sa | PROCESS OF OBTAINING POLYOLEFINES WITH WIDE, BIMODAL OR MULTIMODAL MOLECULAR WEIGHT DISTRIBUTIONS. |
US5709937A (en) | 1995-01-13 | 1998-01-20 | Avery Dennison Corporation | Clear conformable oriented films and labels |
US5554775A (en) | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
US5888636A (en) * | 1995-01-19 | 1999-03-30 | Mitsui Chemicals, Inc. | Multi-layer blow molded article of polypropylene |
US5633018A (en) | 1995-01-20 | 1997-05-27 | E. I. Du Pont De Nemours And Company | Apparatus for forming crystalline polymer pellets |
IT1272923B (en) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | METALLOCENIC COMPOUNDS, PROCEDURE FOR THEIR PREPARATION, AND THEIR USE IN CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
EP0805826B1 (en) | 1995-01-24 | 2003-04-23 | E.I. Du Pont De Nemours And Company | Olefin polymers |
US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
US6495646B1 (en) | 1995-01-24 | 2002-12-17 | E. I. Du Pont De Nemours And Company | Polyolefins with new structures |
US6482907B1 (en) | 1995-01-24 | 2002-11-19 | E.I. Du Pont De Nemours And Company | Polymerization of olefins |
US5714256A (en) | 1995-01-27 | 1998-02-03 | Kimberly-Clark Worldwide, Inc. | Method of providing a nonwoven fabric with a wide bonding window |
US5516848A (en) * | 1995-01-31 | 1996-05-14 | Exxon Chemical Patents Inc. | Process to produce thermoplastic elastomers |
ES2144725T3 (en) | 1995-01-31 | 2000-06-16 | Exxon Chemical Patents Inc | THERMOPLASTIC PROPYLENE ELASTOMERS AND A PROCEDURE FOR PRODUCING THEM WITH A CHAMBER AND TWO CATALYSTS. |
US5539056A (en) * | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
US6455614B1 (en) | 1995-02-01 | 2002-09-24 | Rohm And Haas Company | Chlorine-free, zero voc, waterborne adhesion promoter for polyolefinic substrates |
EP0807096A1 (en) | 1995-02-01 | 1997-11-19 | Basf Aktiengesellschaft | Process for preparing olefin oligomers |
EP0809679B1 (en) * | 1995-02-16 | 2000-05-17 | Minnesota Mining And Manufacturing Company | Articles incorporating pressure-sensitive adhesives having improved adhesion to plasticized polyvinyl chloride |
US6063838A (en) | 1995-02-16 | 2000-05-16 | 3M Innovative Properties Company | Blended pressure-sensitive adhesives |
EP0728773B1 (en) | 1995-02-21 | 1998-11-04 | Mitsubishi Chemical Corporation | Catalysts for olefin polymerization and a process for preparing olefin polymers therewith |
US5594074A (en) * | 1995-02-21 | 1997-01-14 | Shell Oil Company | Process for improving processability of ultra low melt viscosity polymer |
DE69637372T2 (en) | 1995-02-23 | 2008-04-10 | H.B. Fuller Licensing & Financing, Inc., St. Paul | Process for the preparation of a continuous coating of thermoplastic material, and articles made therefrom |
DE19506287A1 (en) * | 1995-02-23 | 1996-08-29 | Basf Ag | Agglomerated polymer particles from water-swellable polymers, process for their preparation and their use |
AU4702796A (en) | 1995-03-01 | 1996-09-18 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borate complexes and catalysts derived therefrom |
US5599881A (en) * | 1995-03-07 | 1997-02-04 | Dupont Canada Inc. | Nucleophilic amine functionalized polyolefin |
AU688674B2 (en) | 1995-03-08 | 1998-03-12 | Shell Internationale Research Maatschappij B.V. | Bridged bis-amido group 4 metal compounds in a catalyst composition |
BR9604776A (en) | 1995-03-10 | 1998-06-23 | Dow Chemical Co | Sustained catalyst component Sustained catalyst process for preparing a sustained catalyst component and a sustained catalyst adduct of an organometallic compound polymerization process by adding the complex compound and method for preparing a complex compound |
DE19508668A1 (en) | 1995-03-14 | 1996-09-19 | Hoechst Ag | Process for treating a sealable film surface |
DE69617666T2 (en) | 1995-03-17 | 2002-08-08 | Bp Corp North America Inc N D | CARPET AND BACKPACK FOR IT |
EP0817805B1 (en) | 1995-03-27 | 2010-09-08 | E.I. Du Pont De Nemours And Company | Polychloroprene composition |
US5527846A (en) * | 1995-03-27 | 1996-06-18 | E. I. Du Pont De Nemours And Company | Polychloroprene adhesive latex composition |
NO315857B1 (en) | 1995-03-28 | 2003-11-03 | Japan Polyolefines Co Ltd | Ethylene <alpha> olefin copolymer, blend, film, laminated material, electrically insulating material and power cable containing this |
US5527752A (en) | 1995-03-29 | 1996-06-18 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for the production of polyolefins |
US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
US5637660A (en) | 1995-04-17 | 1997-06-10 | Lyondell Petrochemical Company | Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety |
US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
AU704598B2 (en) | 1995-04-24 | 1999-04-29 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesives for polyolefin surfaces |
KR19990008050A (en) | 1995-04-25 | 1999-01-25 | 폰티노트제이.릭 | Azaborolinyl Metal Complexes as Olefin Polymerization Catalyst |
AU696168B2 (en) | 1995-04-28 | 1998-09-03 | Sumitomo Chemical Company, Limited | Thermoplastic resin composition |
US5972490A (en) | 1995-04-29 | 1999-10-26 | Hoechst Trespaphan Gmbh | Polymeric films |
DE19515599A1 (en) | 1995-05-02 | 1996-11-07 | Hoechst Ag | Process for the production of polypropylene films and their use |
WO1996034894A1 (en) | 1995-05-02 | 1996-11-07 | Idemitsu Kosan Co., Ltd. | Process for producing styrenic polymer |
IT1274469B (en) | 1995-05-11 | 1997-07-17 | Spherilene Spa | DYNAMICALLY VULCANIZABLE POLYOLEFINIC COMPOSITIONS |
IT1274503B (en) | 1995-05-15 | 1997-07-17 | Montell North America Inc | HIGH TENACITY POLYOLEFINIC FIBERS |
BR9602268A (en) | 1995-05-16 | 1998-04-07 | Union Carbide Chem Plastic | Process for the production of polyethylene and polyethylene |
DE69603539T2 (en) | 1995-05-18 | 2000-01-13 | Fort James Corp | New creping adhesive compositions, creping method and creped fibrous tissue |
BR9609104A (en) | 1995-05-22 | 1999-02-02 | Minnesota Mining & Mfg | Adhesive article and roll of a recyclable protective adhesive article |
US5574082A (en) | 1995-05-25 | 1996-11-12 | Quantum Chemical Company | Propylene polymer compositions having improved color and stabilizers therefor. |
EP0745638A1 (en) | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxially oriented film of polypropylene with improved tear-through resistance |
EP0745477A1 (en) | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxially oriented polypropylene film with improved migration resistence |
EP0755779B1 (en) | 1995-05-31 | 2000-08-09 | Hoechst Aktiengesellschaft | Biaxially oriented polypropylene film with improved dimensional stability |
EP0745637A1 (en) | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxially oriented film of polypropylene with high area modules |
US5846654A (en) | 1995-06-02 | 1998-12-08 | Hercules Incorporated | High tenacity, high elongation polypropylene fibers, their manufacture, and use |
JPH08325327A (en) | 1995-06-02 | 1996-12-10 | Chisso Corp | Highly stereoregular polypropylene |
US6352948B1 (en) * | 1995-06-07 | 2002-03-05 | Kimberly-Clark Worldwide, Inc. | Fine fiber composite web laminates |
US5767031A (en) * | 1995-06-07 | 1998-06-16 | Fina Technology, Inc. | Ziegler-Natta catalysts modified with metallocenes |
US6143682A (en) | 1995-06-07 | 2000-11-07 | Exxon Chemical Patents Inc. | Bimetallocyclic transition metal catalyst systems |
US5618883A (en) * | 1995-06-07 | 1997-04-08 | Avery Dennison Corporation | Styrene ethylene-butylene and ethylene-propylene block copolymer hot melt pressure sensitive adhesives |
US6407177B1 (en) | 1995-06-07 | 2002-06-18 | Fina Technology, Inc. | Polypropylene blend |
AU700952B2 (en) | 1995-06-07 | 1999-01-14 | Pioneer Hi-Bred International, Inc. | PCR-based cDNA subtractive cloning method |
WO1996041808A1 (en) | 1995-06-08 | 1996-12-27 | Showa Denko K.K. | Ionic compounds and catalyst for olefin polymerization using the compounds |
ATE172992T1 (en) | 1995-06-12 | 1998-11-15 | Targor Gmbh | TRANSITION METAL JOINT |
TW326450B (en) | 1995-06-28 | 1998-02-11 | Mitsui Petroleum Chemicals Ind | Ethylene copolymer rubber, vulcanizable rubber composition containing the copolymer rubber, and process for preparing the same |
IT1275777B1 (en) | 1995-07-06 | 1997-10-17 | Enichem Spa | METALLOCENIC CATALYST FOR THE (CO) POLYMERIZATION OF OLEFINS |
IT1275514B (en) | 1995-07-12 | 1997-08-07 | Montell North America Inc | RETICULATED ATACTIC PROPENE POLYMERS |
IT1275530B (en) | 1995-07-14 | 1997-08-07 | Enichem Elastomers | ADHESIVE THERMOPLASTIC COMPOSITION |
SG64939A1 (en) | 1995-07-17 | 2002-02-19 | Mitsui Chemicals Inc | Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer |
US5720543A (en) | 1995-07-19 | 1998-02-24 | Diamondlight Industries, Inc. | Portable flashlight |
US5641848A (en) | 1995-07-24 | 1997-06-24 | Montell North America Inc. | Polypropylene blown film |
US5731253A (en) | 1995-07-27 | 1998-03-24 | Albemarle Corporation | Hydrocarbylsilloxy - aluminoxane compositions |
US5547766A (en) | 1995-07-28 | 1996-08-20 | Minnesota Mining And Manufacturing Company | Non-yellowing tape article |
DE19527652A1 (en) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocene compound |
US5559165A (en) | 1995-08-08 | 1996-09-24 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesives for bonding to sensitive areas of the human body |
IT1277468B1 (en) | 1995-08-09 | 1997-11-10 | Enichem Spa | CATALYST FOR THE (CO) POLYMERIZATION OF OLEFINS AND PROCESS USING THE SAME |
US5900517A (en) | 1995-08-30 | 1999-05-04 | Enichem S.P.A. | Cyclopentadienyl derivatives and process for their preparation |
JP3264148B2 (en) | 1995-08-31 | 2002-03-11 | 住友化学工業株式会社 | Propylene-ethylene random copolymer, its production method and film |
US5985426A (en) | 1995-09-06 | 1999-11-16 | Applied Extrusion Technologies, Inc. | Biaxially oriented polypropylene film with cold seal release surface |
CA2157806A1 (en) | 1995-09-08 | 1997-03-09 | David John Mitchell | Polypropylene-based hot-melt adhesive |
EP0763550B1 (en) | 1995-09-14 | 1999-05-06 | Showa Denko Kabushiki Kaisha | Ethylenic polymerization catalyst |
WO1997010300A1 (en) | 1995-09-14 | 1997-03-20 | Exxon Chemical Patents Inc. | Propylene polymer blends and films and articles made therefrom |
ES2211976T3 (en) | 1995-09-18 | 2004-07-16 | Exxonmobil Chemical Patents Inc. | HIGHLY WATERPROOF POLYPROPYLENE COMPOSITIONS AND THEIR PACKAGING APPLICATIONS. |
US5741563A (en) | 1995-09-18 | 1998-04-21 | Exxon Chemical Patents Inc. | Shrink films from propylene polymers |
ES2203714T3 (en) | 1995-09-28 | 2004-04-16 | Basell Polyolefine Gmbh | SUPPORTED CATALYST SYSTEM, PROCEDURE FOR PRODUCTION AND USE FOR OLEFIN POLYMERIZATION. |
JP2865598B2 (en) | 1995-10-02 | 1999-03-08 | 横浜ゴム株式会社 | Thermoplastic elastomer composition |
US5795941A (en) | 1995-10-03 | 1998-08-18 | The Dow Chemical Company | Crosslinkable bimodal polyolefin compositions |
JP3582181B2 (en) | 1995-10-04 | 2004-10-27 | 住友化学工業株式会社 | Carrier for olefin polymerization catalyst, olefin polymerization catalyst and method for producing olefin polymer |
KR19990064042A (en) | 1995-10-06 | 1999-07-26 | 그레이스 스티븐 에스. | Branched block ethylene polymer, preparation method thereof and composition comprising same |
FI105820B (en) | 1995-10-10 | 2000-10-13 | Borealis Tech Oy | Process for the preparation of homopolymers or copolymers of propylene |
CA2234167C (en) | 1995-10-10 | 2004-09-14 | Henrik Andtsjo | Process for making propylene homo or copolymers |
AT405286B (en) | 1995-10-16 | 1999-06-25 | Danubia Petrochem Polymere | POLYPROPYLENE WITH REDUCED WHITE BREAKAGE |
EP0768322A1 (en) | 1995-10-16 | 1997-04-16 | Sumitomo Chemical Company, Limited | Method for preparing catalyst component for olefin polymerization, catalyst for olefin polymerization and process for producing olefin polymer with the catalyst |
GB9521494D0 (en) | 1995-10-20 | 1995-12-20 | Exxon Chemical Patents Inc | Sprayable ethylene based hot metal adhesives |
US5869585A (en) | 1995-10-30 | 1999-02-09 | Mobil Oil Corporation | Multi-component catalyst systems for olefin polymerization |
GB9522859D0 (en) | 1995-11-08 | 1996-01-10 | Borealis As | Compounds |
US5693838A (en) | 1995-11-13 | 1997-12-02 | Albemarle Corporation | Aluminoxane process and product |
CA2239983C (en) | 1995-11-16 | 2002-07-30 | H.B. Fuller Licensing & Financing, Inc. | A polymeric composition in pellet form |
US6066588A (en) | 1995-11-22 | 2000-05-23 | Fina Research, S.A. | Bridged metallocenes catalyst for polymerization of olefins |
US5773516A (en) | 1995-12-06 | 1998-06-30 | Basf Aktiengesellschaft | Propylene polymers |
WO1997020872A1 (en) | 1995-12-07 | 1997-06-12 | Exxon Chemical Patents Inc. | Tackifiers and a process to obtain tackifiers |
DE19546501A1 (en) * | 1995-12-13 | 1997-06-19 | Hoechst Ag | Metallocene compound |
GB9525606D0 (en) | 1995-12-14 | 1996-02-14 | Iaf Biochem Int | Method and compositions for the synthesis of dioxolane nucleosides with - configuration |
JP3260268B2 (en) * | 1995-12-18 | 2002-02-25 | 宇部興産株式会社 | Polypropylene resin composition |
WO1997022639A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
JP3756192B2 (en) | 1995-12-21 | 2006-03-15 | 出光興産株式会社 | Organoaluminoxy compound and catalyst for polymer production using the same |
US5760028A (en) * | 1995-12-22 | 1998-06-02 | The Dupont Merck Pharmaceutical Company | Integrin receptor antagonists |
US5876855A (en) | 1995-12-22 | 1999-03-02 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive suitable for skin and method of preparing |
NZ316689A (en) | 1995-12-22 | 1999-04-29 | Minnesota Mining & Mfg | Blended pressure-sensitive adhesives comprising two components, one being pressure sensitive and the other being a thermoplastic material |
ID16442A (en) | 1996-01-22 | 1997-10-02 | Dow Chemical Co | WEIGHT POLYMER ETHYLENE ULTRA LOW MOLECULES |
IT1282373B1 (en) | 1996-01-31 | 1998-03-20 | Montell Nort America Inc | POLYOLEFIN COMPOSITION FOR COATING METALS WITH FLAME SPRAYING |
US6114477A (en) | 1996-02-09 | 2000-09-05 | Exxon Chemical Patents Inc. | Polymerization process |
DE19606167A1 (en) * | 1996-02-20 | 1997-08-21 | Basf Ag | Supported catalyst systems |
US5856256A (en) | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
DE19606165A1 (en) | 1996-02-20 | 1997-08-21 | Basf Ag | Process for the preparation of polymers of alkenes by gas phase polymerization |
DE19606166A1 (en) | 1996-02-20 | 1997-08-21 | Basf Ag | Process for the preparation of polymers of alkenes by suspension polymerization |
IT1282666B1 (en) | 1996-02-22 | 1998-03-31 | Enichem Spa | METALLOCENIC CATALYST REPLACED FOR THE (CO) POLYMERIZATION OF OLEFINS |
US5867316A (en) * | 1996-02-29 | 1999-02-02 | Minnesota Mining And Manufacturing Company | Multilayer film having a continuous and disperse phase |
NL1002586C2 (en) | 1996-03-12 | 1997-09-15 | Skf Ind Trading & Dev | Polymer-thickened lubricants for high operating temperatures. |
DE19609715C2 (en) | 1996-03-13 | 1998-10-08 | Roehm Gmbh | Multi-stage process for the production of highly heat-resistant polymethacrylate molding compounds |
ID17196A (en) | 1996-03-14 | 1997-12-11 | Dow Chemical Co | ADHESIVE INGREDIENTS THAT CONTAIN OLEFIN POLYMER |
WO1998041574A1 (en) | 1997-03-14 | 1998-09-24 | H.B. Fuller Licensing & Financing, Inc. | FOAMABLE COMPOSITIONS COMPRISING LOW VISCOSITY THERMOPLASTIC MATERIAL COMPRISING AN ETHYLENEα-OLEFIN |
AR006240A1 (en) | 1996-03-14 | 1999-08-11 | Fuller H B Licensing Financ | HOT MELTING ADHESIVE INCLUDING INTERPOLYMERS, NON-WOVEN ARTICLE THAT UNDERSTANDS IT, POLYMERIZATION PROCEDURE FOR PREPARATION AND BOX, CONTAINER, TRAY AND BOOK UNITED WITH SUCH ADHESIVE |
US6107430A (en) | 1996-03-14 | 2000-08-22 | The Dow Chemical Company | Low application temperature hot melt adhesive comprising ethylene α-olefin |
US5846558A (en) | 1996-03-19 | 1998-12-08 | Minnesota Mining And Manufacturing Company | Ionically conductive adhesives prepared from zwitterionic materials and medical devices using such adhesives |
US5756141A (en) * | 1996-03-20 | 1998-05-26 | Chen; Chin Shu | Method for producing ready to pour frozen concentrated clarified fruit juice, fruit juice produced therefrom, and high solids fruit product |
WO1997035892A1 (en) | 1996-03-27 | 1997-10-02 | The Dow Chemical Company | Solution polymerization process with dispersed catalyst activator |
RU2178422C2 (en) | 1996-03-27 | 2002-01-20 | Дзе Дау Кемикал Компани | Olefin polymerization catalyst activator, catalytic system, and polymerization process |
KR20000005128A (en) | 1996-03-29 | 2000-01-25 | 그레이스 스티븐 에스. | Metallocene cocatalyst |
US5985193A (en) | 1996-03-29 | 1999-11-16 | Fiberco., Inc. | Process of making polypropylene fibers |
HUP9901742A3 (en) | 1996-04-01 | 2000-04-28 | Dow Global Technologies Inc Mi | Process for solution polymerization of olefin |
US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
US5820981A (en) | 1996-04-02 | 1998-10-13 | Montell North America Inc. | Radiation visbroken polypropylene and fibers made therefrom |
TW440567B (en) | 1996-04-04 | 2001-06-16 | Toho Titanium Co Ltd | Propylene homopolymer |
US6114261A (en) | 1996-04-15 | 2000-09-05 | Ato Findley, Inc. | Nonwoven absorbent article containing an emollient resistant polybutylene-based hot melt adhesive |
US5763516A (en) * | 1996-04-24 | 1998-06-09 | H.B. Fuller Licensing & Financing, Inc. | Polyethylene based hot-melt adhesive |
EP0846793B1 (en) | 1996-04-25 | 2001-12-12 | Chisso Corporation | Polyolefin fibers and nonwoven fabric produced using the same |
US5667902A (en) | 1996-04-30 | 1997-09-16 | Mobil Oil Corporation | High moisture barrier polypropylene-based film |
US5744417A (en) | 1996-05-02 | 1998-04-28 | Lyondell Petrochemical Company | Supported catalyst |
US5942451A (en) | 1996-05-03 | 1999-08-24 | Bp Amoco Corporation | Antiskid fabric |
US6403708B2 (en) | 1996-05-27 | 2002-06-11 | Mitsui Chemicals Inc | Crystalline polypropylenes, process for preparing thereof, polypropylene compositions, and thermoformed products |
US5792549A (en) | 1996-05-30 | 1998-08-11 | Aep Industries, Inc. | Biaxially oriented polypropylene cold seal release films |
DE19622481A1 (en) * | 1996-06-05 | 1997-12-11 | Hoechst Ag | Supported catalyst system, process for its preparation and its use for the polymerization of olefins |
GB9611869D0 (en) | 1996-06-07 | 1996-08-07 | Bnfl Fluorchem Ltd | Preparation of fluoroketones |
EP0906343B1 (en) | 1996-06-17 | 2001-04-18 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
US5834538A (en) | 1996-06-18 | 1998-11-10 | Hercules Incorporated | Pressure sensitive adhesives |
DE19624581C2 (en) | 1996-06-20 | 1999-02-04 | Targor Gmbh | Transition metal compound and a process for their preparation, and their use |
US6368708B1 (en) | 1996-06-20 | 2002-04-09 | 3M Innovative Properties Company | Polyolefin microspheres |
WO1997049738A1 (en) | 1996-06-24 | 1997-12-31 | The Dow Chemical Company | Incorporation of functionalized comonomers in polyolefins |
JPH107851A (en) | 1996-06-24 | 1998-01-13 | Idemitsu Petrochem Co Ltd | Propylene resin composition and interior material for automobile |
US5852146A (en) | 1996-06-27 | 1998-12-22 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
GB9613814D0 (en) | 1996-07-02 | 1996-09-04 | Bp Chem Int Ltd | Supported polymerisation catalysts |
US6174974B1 (en) | 1996-07-05 | 2001-01-16 | Bayer Aktiengesellschaft | Method for producing thermoplastic elastomers |
US6150498A (en) | 1996-07-12 | 2000-11-21 | The Dow Chemical Company | Polymer recovery |
US5731451A (en) | 1996-07-12 | 1998-03-24 | Akzo Nobel Nv | Modified polyalkylauminoxane composition formed using reagent containing aluminum trialkyl siloxide |
US5705579A (en) | 1996-07-17 | 1998-01-06 | Phillips Petroleum Company | Olefin polymerization |
AR007940A1 (en) | 1996-07-22 | 1999-11-24 | Dow Chemical Co | HOT MELT ADHESIVES FOR GLUING CARDBOARD OR CARDBOARD SURFACES, PROCESS FOR OBTAINING ETHYLENE INTERPOLYMERS USEFUL IN THE PREPARATION OF SUCH ADHESIVES AND PACKAGING THAT INCLUDES THEM |
BR9710511A (en) | 1996-07-23 | 1999-08-17 | Dow Chemical Co | Catalyst composition and process for the polymerization of polymerizable monomers via addition |
US5861474A (en) * | 1996-07-23 | 1999-01-19 | The Dow Chemical Company | Polymer devolatilization |
US5844037A (en) | 1996-07-24 | 1998-12-01 | The Dow Chemical Company | Thermoplastic polymer compositions with modified electrical conductivity |
JPH1036587A (en) | 1996-07-24 | 1998-02-10 | Chisso Corp | Biaxially oriented polypropylene film |
US6297301B1 (en) | 1996-08-06 | 2001-10-02 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions having improved processing properties |
US5939503A (en) | 1996-08-09 | 1999-08-17 | California Institute Of Technology | Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization |
ES2160289T3 (en) | 1996-08-13 | 2001-11-01 | Basell Polyolefine Gmbh | SUPPORTED CATALYSTING SYSTEM, A PROCEDURE FOR OBTAINING AND USE FOR OLEFIN POLYMERIZATION. |
DE59712644D1 (en) | 1996-08-13 | 2006-06-14 | Basell Polyolefine Gmbh | Supported chemical compound |
US5854166A (en) | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
DE19654921A1 (en) | 1996-08-29 | 1998-03-05 | Hoechst Ag | Polyolfine molding compound for the production of nonwovens |
US6210764B1 (en) | 1996-08-29 | 2001-04-03 | Cryovac, Inc. | Film with substrate layer containing antiblocking agent |
DE19635503A1 (en) | 1996-09-02 | 1998-03-05 | Basf Ag | Low-whitening, tough modified propylene polymers |
KR20000068428A (en) | 1996-09-04 | 2000-11-25 | 엑손 케미칼 패턴츠 인코포레이티드 | Improved propylene polymers for oriented films |
US6583227B2 (en) * | 1996-09-04 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
US6576306B2 (en) | 1996-09-04 | 2003-06-10 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
AU4137597A (en) | 1996-09-06 | 1998-03-26 | Hyundai Petrochemical Co., Ltd. | Catalyst system for (co)polymerization of olefins and process for the preparation of olefin (co)polymers using the catalyst system |
WO1998011144A1 (en) | 1996-09-12 | 1998-03-19 | Bp Chemicals Limited | Polymerisation catalyst |
TW426203U (en) | 1996-09-18 | 2001-03-11 | Koninkl Philips Electronics Nv | Backlight luminaire |
US5986651A (en) | 1996-09-23 | 1999-11-16 | Motorola, Inc. | Method, system, and article of manufacture for producing a network navigation device |
US6048942A (en) | 1996-09-30 | 2000-04-11 | Montell North America Inc. | Thermoplastic olefin articles having high surface gloss and mar resistance |
US5847177A (en) | 1996-10-10 | 1998-12-08 | Albemarle Corporation | Production of hydrocarbon-soluble hydrocarbylaluminoxanes |
WO1998016311A1 (en) | 1996-10-15 | 1998-04-23 | Northwestern University | Phenolate constrained geometry metallocene olefin polymerization catalyst, method of making, and method of using |
US5744656A (en) | 1996-10-25 | 1998-04-28 | Boulder Scientific Company | Conversion of hexafluorobenzene to bromopentafluorobenzene |
DE69705186T2 (en) | 1996-10-30 | 2002-03-14 | Repsol Quimica Sa | Catalyst systems for the (co) polymerization of alpha olefins |
DE19644039A1 (en) | 1996-10-31 | 1998-05-07 | Hoechst Ag | Metallocenes |
DE19644041A1 (en) | 1996-10-31 | 1998-05-07 | Hoechst Ag | Metallocenes with partially hydrogenated pi ligands |
SG60151A1 (en) | 1996-11-15 | 1999-02-22 | Sumitomo Chemical Co | Propylene-1-butene copolymer |
FI104089B1 (en) * | 1996-11-15 | 1999-11-15 | Borealis As | Process for preparing homo- or copolymers of propylene |
HUP9904527A2 (en) | 1996-11-15 | 2000-05-28 | Montell Technology Company B.V. | Heterocyclic metallocenes and polymerization catalysts cont. thereof |
DE19648895A1 (en) | 1996-11-26 | 1998-05-28 | Clariant Gmbh | Polar modified polypropylene waxes |
EP0948570A1 (en) | 1996-11-27 | 1999-10-13 | Eastman Chemical Company | Method for preparing light-absorbing polymeric compositions |
TW442528B (en) * | 1996-12-02 | 2001-06-23 | Chisso Corp | Polypropylene composition |
US6245856B1 (en) | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
US6177377B1 (en) * | 1996-12-18 | 2001-01-23 | Amherst Polymer Technology, Inc. | Polymer blends and process for preparation |
US5847059A (en) | 1996-12-20 | 1998-12-08 | Fina Technology, Inc. | Catalyst yield from supported metallocene catalysts |
US5849655A (en) | 1996-12-20 | 1998-12-15 | Fina Technology, Inc. | Polyolefin catalyst for polymerization of propylene and a method of making and using thereof |
ATE203202T1 (en) | 1996-12-26 | 2001-08-15 | Du Pont Canada | FILMS WITH IMPROVED SEALING PROPERTIES |
US5947944A (en) | 1996-12-30 | 1999-09-07 | Kimberly-Clark Worldwide, Inc. | Stretched-thinned films comprising low crystallinity polymers and laminates thereof |
US5910136A (en) | 1996-12-30 | 1999-06-08 | Kimberly-Clark Worldwide, Inc. | Oriented polymeric microporous films with flexible polyolefins |
US6100351A (en) | 1997-01-07 | 2000-08-08 | Huntsman Polymers Corporation | Olefin polymerization process and products thereof |
US5854363A (en) | 1997-01-08 | 1998-12-29 | Phillips Petroleum Company | (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds |
US5856547A (en) | 1997-01-08 | 1999-01-05 | Phillips Petroleum Company | Organo omega-alkenyl cyclopentacarbyl silane compounds |
US5986008A (en) | 1997-01-09 | 1999-11-16 | Mitsui Chemicals, Inc. | Propylene polymer composition and thermoformed object |
US5747406A (en) | 1997-01-10 | 1998-05-05 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for the production of olefin polymers |
NL1004992C2 (en) | 1997-01-14 | 1998-07-15 | Dsm Nv | Use of compounds containing Si, Ge, Sn or Pb as a cocatalyst in the polymerization of olefins. |
ATE272078T1 (en) | 1997-01-14 | 2004-08-15 | Sabic Polypropylenes Bv | METHOD FOR OLEFIN POLYMERIZATION |
FI970349A (en) | 1997-01-28 | 1998-07-29 | Borealis As | New activator systems for metallocene compounds |
NZ336421A (en) | 1997-01-29 | 2001-06-29 | Dow Chemical Co | Heteromorphic polymer compositions comprising backbone polymer of ethylene/alpha olefin interpolymer and branch from backbone |
US5798175A (en) | 1997-01-31 | 1998-08-25 | American Tape Company | Pressure sensitive adhesives and tape product prepared therefrom |
US5827913A (en) * | 1997-02-05 | 1998-10-27 | H.B. Fuller Licensing & Financing, Inc. | Hot melt adhesive comprising an encapsulated ingredient |
US5739220A (en) * | 1997-02-06 | 1998-04-14 | Fina Technology, Inc. | Method of olefin polymerization utilizing hydrogen pulsing, products made therefrom, and method of hydrogenation |
US6114457A (en) | 1997-02-07 | 2000-09-05 | Exxon Chemical Patents Inc. | High melt strength polyethylene compositions |
US5851945A (en) | 1997-02-07 | 1998-12-22 | Exxon Chemical Patents Inc. | Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state |
JP2001511214A (en) | 1997-02-07 | 2001-08-07 | エクソン・ケミカル・パテンツ・インク | Preparation of vinyl-containing macromers |
ID20751A (en) | 1997-02-07 | 1999-02-25 | Mitsui Chemicals Inc | OLEFIN POLYMERIZATION AND OLEFIN POLYMER PROCESSES |
KR100564500B1 (en) | 1997-02-07 | 2006-03-29 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Propylene polymers incorporating polyethylene macromers |
BR9807468A (en) | 1997-02-07 | 2000-05-02 | Exxon Chemical Patents Inc | Compositions of high melting polyethylene |
AT408229B (en) | 1997-02-11 | 2001-09-25 | Borealis Ag | USE OF THERMOPLASTIC ELASTOMERS TO IMPROVE THE STABILITY OF POLYOLEFINS TO IONIZING RADIATION |
US6034164A (en) | 1997-02-21 | 2000-03-07 | Exxon Research And Engineering Co. | Nanocomposite materials formed from inorganic layered materials dispersed in a polymer matrix |
EP0878486B1 (en) | 1997-02-21 | 2006-01-25 | Council of Scientific and Industrial Research | A process for the preparation of supported metallocene catalyst |
US5756611A (en) | 1997-02-21 | 1998-05-26 | Lyondell Petrochemical Company | α-olefin polymerization catalysts |
US6451938B1 (en) | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
EP0963383A4 (en) | 1997-02-26 | 2002-10-24 | Advanced Elastomer Systems | Hydrosilylation cross-linking of thermoplastic elastomer |
PL335380A1 (en) | 1997-02-28 | 2000-04-25 | Dow Chemical Co | Carpet, carpet substrate and method of making them using a homogenously branched ethylene polymer |
DE19709667A1 (en) | 1997-03-11 | 1998-09-17 | Basf Ag | Comb polymers via metallocene catalysis |
AU6463898A (en) | 1997-03-17 | 1998-10-12 | Exxon Chemical Patents Inc. | Transition metal metallacyclopentadienyl compounds |
GB2323323A (en) | 1997-03-18 | 1998-09-23 | Hoechst Trespaphan Gmbh | Polymeric label |
CA2200373C (en) | 1997-03-19 | 2005-11-15 | Rupert Edward Von Haken Spence | Heteroligand |
US5723546A (en) | 1997-03-24 | 1998-03-03 | Rexene Corporation | Low- and high-molecular weight amorphous polyalphaolefin polymer blends having high melt viscosity, and products thereof |
US6080818A (en) | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
US6410664B1 (en) | 1997-03-24 | 2002-06-25 | Cryovac, Inc. | Catalyst compositions and processes for olefin polymers and copolymers |
DE19712380A1 (en) | 1997-03-25 | 1998-10-01 | Henkel Kgaa | Use of amphiphiles to permanently improve the adhesive and / or coating compatibility of polyolefin-based moldings, fibers and films |
AU702218B2 (en) | 1997-03-31 | 1999-02-18 | Kyushu-Taiyoukasei., Ltd. | Liner film for bulk container and container liner |
US6255426B1 (en) | 1997-04-01 | 2001-07-03 | Exxon Chemical Patents, Inc. | Easy processing linear low density polyethylene |
US6130357A (en) | 1997-04-03 | 2000-10-10 | Colorado State University Research Foundation | Polyhalogenated monoheteroborane anion compositions |
SG67489A1 (en) | 1997-04-07 | 1999-09-21 | Mitsui Chemicals Inc | Laminating propylene/1-butene random copolymer composition and composite film using the same |
US6143683A (en) | 1997-04-09 | 2000-11-07 | Fina Technology, Inc. | Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms |
US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
US5889128A (en) | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
DE19715155A1 (en) | 1997-04-11 | 1998-10-15 | Basf Ag | Catalyst preparations for the production of olefin (co) polymers |
AR012582A1 (en) | 1997-04-14 | 2000-11-08 | Dow Global Technologies Inc | POLYMERIC COMPOSITIONS OF IMPROVED ELONGATION AND ADHESIVE FORMULATIONS OF HOT MELTING INCLUDING SUCH COMPOSITION |
CN1106425C (en) | 1997-04-17 | 2003-04-23 | 智索股份有限公司 | Polypropylene composition and process for producing the same |
US6759475B2 (en) | 1997-04-24 | 2004-07-06 | Mitsui Chemicals, Inc. | Resin composition based on crystalline polypropylene |
TWI246520B (en) | 1997-04-25 | 2006-01-01 | Mitsui Chemicals Inc | Processes for olefin polymerization |
EP0977808B1 (en) | 1997-04-29 | 2002-10-16 | The Dow Chemical Company | Amorphous propylene-polyene copolymers and compositions thereof |
EP0977820B1 (en) | 1997-04-30 | 2004-07-14 | Ato Findley Inc | Hot melt adhesive with high peel and shear strengths for nonwoven applications |
EP0979074A4 (en) * | 1997-05-01 | 2003-07-09 | Novogen Inc | Treatment or prevention of menopausal symptoms and osteoporosis |
CA2288865A1 (en) | 1997-05-02 | 1998-11-12 | Dupont Canada Inc. | Ethylene/styrene polymer sealant layer for use in liquid packaging |
US6113996A (en) | 1997-05-19 | 2000-09-05 | Mobil Oil Corporation | Composition for uniaxially heat shrinkable biaxially oriented polypropylene film |
TW400341B (en) | 1997-05-22 | 2000-08-01 | Chisso Corp | Propyene polymer blends, processes of producing the same, and polypropylene resin compositions |
WO1998052686A1 (en) | 1997-05-22 | 1998-11-26 | Phillips Petroleum Company | Method for making and using a prepolymerized olefin polymerization catalyst |
JP3458656B2 (en) | 1997-05-27 | 2003-10-20 | 東ソー株式会社 | Olefin polymerization catalyst and method for producing olefin polymer |
US5972510A (en) | 1997-06-05 | 1999-10-26 | Isis Innovation Limited | Spherulite particles of isotactic polypropylene |
US6573352B1 (en) * | 1997-06-06 | 2003-06-03 | Idemitsu Petrochemical Co., Ltd. | Olefinic polymer |
GB9712663D0 (en) | 1997-06-16 | 1997-08-20 | Borealis As | Process |
FI111846B (en) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Process and apparatus for preparing mixtures of polypropylene |
FI111848B (en) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Process and equipment for the preparation of homopolymers and copolymers of propylene |
US6096676A (en) | 1997-07-02 | 2000-08-01 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
US5888607A (en) * | 1997-07-03 | 1999-03-30 | Minnesota Mining And Manufacturing Co. | Soft loop laminate and method of making |
DE69826476T2 (en) | 1997-07-04 | 2005-01-20 | Nippon Zeon Co., Ltd. | ADHESIVE FOR SEMICONDUCTOR COMPONENTS |
US6077907A (en) | 1997-07-09 | 2000-06-20 | Borealis Ag | Molded polyolefin parts of improved dimensional stability at elevated temperatures and improved stiffness |
US5911023A (en) | 1997-07-10 | 1999-06-08 | Alcatel Alsthom Compagnie Generale D'electricite | Polyolefin materials suitable for optical fiber cable components |
DE19729833A1 (en) | 1997-07-11 | 1999-01-14 | Clariant Gmbh | Polypropylene wax |
SG76545A1 (en) | 1997-07-11 | 2000-11-21 | Sumitomo Chemical Co | Propylene copolymer |
FI972946A (en) | 1997-07-11 | 1999-01-12 | Borealis As | Novel metallocene compounds for polymerization of ethylenically unsaturated monomers |
KR20000068602A (en) | 1997-07-22 | 2000-11-25 | 나까니시 히로유끼 | Ethylene/alpha-olefine copolymers, compositions, and processes for the preparation of the copolymers and the compositions |
GB9715317D0 (en) * | 1997-07-22 | 1997-09-24 | Bp Chem Int Ltd | Polymerisation catalysts |
BE1011301A6 (en) | 1997-07-24 | 1999-07-06 | Solvay | Composition polymer propylene for expanded granules, method for obtaining and use. |
DE59807129D1 (en) | 1997-07-28 | 2003-03-13 | Basell Polyolefine Gmbh | METHOD FOR PRODUCING METALLOCENES |
DE69812106T2 (en) | 1997-08-01 | 2003-12-18 | Dow Global Technologies Inc | catalyst activator |
WO1999007752A1 (en) * | 1997-08-05 | 1999-02-18 | Grand Polymer Co., Ltd. | Polypropylene resin composition and use thereof |
US6525157B2 (en) * | 1997-08-12 | 2003-02-25 | Exxonmobile Chemical Patents Inc. | Propylene ethylene polymers |
US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
WO1999009098A1 (en) | 1997-08-19 | 1999-02-25 | Idemitsu Petrochemical Co., Ltd. | Propylene polymer composition and films made therefrom |
US7454378B1 (en) | 1997-08-22 | 2008-11-18 | Grenex Corp. | Exchange method and apparatus |
US6325956B2 (en) | 1997-08-27 | 2001-12-04 | The Dow Chemical Company | Crosslinking of polymers and foams thereof |
KR100563338B1 (en) | 1997-08-27 | 2006-03-22 | 다우 글로벌 테크놀로지스 인크. | Crosslinking of polymers and foams thereof |
US6019735A (en) | 1997-08-28 | 2000-02-01 | Visco Technologies, Inc. | Viscosity measuring apparatus and method of use |
DE19738051A1 (en) * | 1997-09-01 | 1999-03-04 | Targor Gmbh | Injection molded article made of metallocene polypropylene |
US5997981A (en) | 1997-09-15 | 1999-12-07 | Kimberly-Clark Worldwide, Inc. | Breathable barrier composite useful as an ideal loop fastener component |
US6150297A (en) | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
US6045900A (en) | 1997-09-15 | 2000-04-04 | Kimberly-Clark Worldwide, Inc. | Breathable filled film laminate |
US6909028B1 (en) | 1997-09-15 | 2005-06-21 | Kimberly-Clark Worldwide, Inc. | Stable breathable elastic garments |
AU9094798A (en) | 1997-09-18 | 1999-04-05 | Chisso Corporation | Polypropylene composition |
CA2302173A1 (en) | 1997-09-19 | 1999-04-01 | The Dow Chemical Company | Modified alumoxane catalyst activator |
US6090325A (en) | 1997-09-24 | 2000-07-18 | Fina Technology, Inc. | Biaxially-oriented metallocene-based polypropylene films |
US5863994A (en) * | 1997-09-29 | 1999-01-26 | Montell North America Inc. | Using nitric oxide to reduce reactor fouling during polypropylene graft copolymerization |
US5858293A (en) * | 1997-09-30 | 1999-01-12 | Montell North America Inc. | Method for producing spunbonded materials with improved tensile strength |
DE19744102A1 (en) | 1997-10-06 | 1999-04-15 | Targor Gmbh | Metallocene catalyst system useful in (co)polyolefin production |
AU1188299A (en) | 1997-10-17 | 1999-05-10 | Huntsman Polymers Corporation | Novel polyolefins as blend component |
ATE285892T1 (en) | 1997-10-17 | 2005-01-15 | Total Petrochemicals Res Feluy | METALLIZABLE POLYPROPYLENE FILM |
JPH11115127A (en) | 1997-10-17 | 1999-04-27 | Asahi Du Pont Flash Span Products Kk | Composite nonwoven sheet |
US5986024A (en) | 1997-10-17 | 1999-11-16 | Sri International | Preparation of multimodal polymer compositions using multinuclear metallocene catalysts |
US5942462A (en) | 1997-10-20 | 1999-08-24 | Akzo Nobel N.V. | Process for preparing group 6 metal-based olefin polymerization catalyst component |
US5990035A (en) | 1997-10-21 | 1999-11-23 | Koeppl; Alexander | Polymerization catalyst systems, their preparation, and use |
US6552110B1 (en) | 1997-10-21 | 2003-04-22 | Dow Global Technologies Inc. | Thermoplastic marking compositions |
US6265512B1 (en) | 1997-10-23 | 2001-07-24 | 3M Innovative Company | Elastic polypropylenes and catalysts for their manufacture |
FI980342A0 (en) * | 1997-11-07 | 1998-02-13 | Borealis As | Polymerroer och -roerkopplingar |
US6521696B2 (en) | 1997-11-12 | 2003-02-18 | Dow Global Technologies Inc. | Aqueous pressure sensitive adhesive formulations |
WO1999028374A1 (en) | 1997-12-01 | 1999-06-10 | Jsp Corporation | Expandable polypropylene resin beads and products of in-mold expansion |
US5986009A (en) | 1997-12-03 | 1999-11-16 | The Dow Chemical Company | Blends of polypropylenes |
US6242545B1 (en) | 1997-12-08 | 2001-06-05 | Univation Technologies | Polymerization catalyst systems comprising substituted hafinocenes |
US6551955B1 (en) | 1997-12-08 | 2003-04-22 | Albemarle Corporation | Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use |
US6677265B1 (en) | 1997-12-08 | 2004-01-13 | Albemarle Corporation | Process of producing self-supported catalysts |
JP3403044B2 (en) | 1997-12-09 | 2003-05-06 | キヤノン株式会社 | Packaging container |
US6117962A (en) | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
SG71878A1 (en) | 1997-12-11 | 2000-04-18 | Sumitomo Chemical Co | Propylene-based polymer composition and foamed article thereof |
WO1999030822A1 (en) | 1997-12-16 | 1999-06-24 | Exxon Research And Engineering Company | Group 11 transition metal amine catalysts for olefin polymerization |
US6069213A (en) | 1997-12-16 | 2000-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst system |
US5916974A (en) | 1997-12-18 | 1999-06-29 | Montell North America Inc. | Morphology control in polypropylene graft copolymers |
US6277479B1 (en) | 1997-12-19 | 2001-08-21 | Kimberly-Clark Worldwide, Inc. | Microporous films having zoned breathability |
CN100488988C (en) | 1997-12-23 | 2009-05-20 | 陶氏环球技术公司 | Finishing design to increase the polymer content in olefin solution polymerization process |
US6042930A (en) * | 1997-12-24 | 2000-03-28 | The Dow Chemical Company | Plastic heat-activated adhesive labels |
TW431968B (en) | 1997-12-26 | 2001-05-01 | Toray Industries | A biaxially oriented polypropylene film to be metallized, a metallized biaxially oriented polypropylene film, and a laminate formed by using it |
DE19758124C1 (en) | 1997-12-30 | 1999-11-18 | Borealis Ag | Polypropylene tube with high strength |
US6531230B1 (en) | 1998-01-13 | 2003-03-11 | 3M Innovative Properties Company | Color shifting film |
US6228948B1 (en) | 1998-01-16 | 2001-05-08 | E. I. Du Pont De Nemours And Company | High melt flow, highly-grafted polypropylene |
DE19801687A1 (en) | 1998-01-19 | 1999-07-22 | Danubia Petrochem Polymere | Thermoplastic elastomers with good dyeability and high strength and elasticity as well as high impact polymer blends made from them |
EP0931814A1 (en) * | 1998-01-21 | 1999-07-28 | Fina Research S.A. | Polyolefins and uses thereof |
US6566467B1 (en) | 1998-01-22 | 2003-05-20 | Donald Frederick Lyons | Inhibitor composition for chloroprene polymerization |
US6486246B1 (en) | 1998-02-03 | 2002-11-26 | Montell Technology Company Bv | Polyolefin based hot melt adhesive composition |
DE59909402D1 (en) | 1998-02-12 | 2004-06-09 | Trespaphan Gmbh | SEALABLE BIAXIAL-ORIENTED POLYPROPYLENE FILM WITH IMPROVED PROPERTIES REGARDING BARRIER |
DE19806918A1 (en) * | 1998-02-19 | 1999-08-26 | Aventis Res & Tech Gmbh & Co | Catalyst system for the production of olefin polymers, especially polypropylene |
PL342450A1 (en) | 1998-02-20 | 2001-06-04 | Dow Chemical Co | Catalyst activators containing expanded anions |
US6046273A (en) | 1998-02-27 | 2000-04-04 | Montell North America Inc. | Thermal stability of alpha-substituted acrylate graft copolymers |
US6319998B1 (en) | 1998-03-04 | 2001-11-20 | Exxon Mobil Chemical Patents Inc. | Method for making polymer blends by using series reactors |
CN1133660C (en) | 1998-03-04 | 2004-01-07 | 埃克森美孚化学专利公司 | High temp olefin polymerization process |
IT1298616B1 (en) | 1998-03-10 | 2000-01-12 | Enichem Spa | BRIDGED METALLOCENIC COMPLEX FOR THE (CO) POLYMERIZATION OF OLEFINS |
CA2322960A1 (en) | 1998-03-11 | 1999-09-16 | The Dow Chemical Company | Deformable pressure sensitive adhesive tape |
US7022795B1 (en) | 1998-03-13 | 2006-04-04 | Novolen Technology Holdings, C.V. | Highly crystalline propylene homopolymers |
JPH11263812A (en) * | 1998-03-16 | 1999-09-28 | Nippon Polyolefin Kk | Random propylene copolymer and film and metallized film made therefrom |
HUP0102111A3 (en) | 1998-03-16 | 2002-06-28 | Dow Global Technologies Inc Mi | Polyolefin nanocomposites |
US6281300B1 (en) | 1998-03-20 | 2001-08-28 | Exxon Chemical Patents, Inc. | Continuous slurry polymerization volatile removal |
DE19812229A1 (en) | 1998-03-20 | 1999-09-23 | Basf Ag | Polymers of propene |
DE19813399A1 (en) | 1998-03-26 | 1999-09-30 | Basf Ag | Statistical propylene copolymers |
WO1999048605A1 (en) | 1998-03-26 | 1999-09-30 | The Dow Chemical Company | Ion exchanged aluminium-magnesium or fluorinated magnesium silicate aerogels and catalyst supports therefrom |
DE19813657A1 (en) | 1998-03-27 | 1999-09-30 | Aventis Res & Tech Gmbh & Co | Catalyst system, process for its preparation and its use for the polymerization of olefins |
JP2002509949A (en) | 1998-03-27 | 2002-04-02 | エクソンモービル・ケミカル・パテンツ・インク | Polymer supported catalyst for olefin polymerization |
US6268062B1 (en) | 1998-04-06 | 2001-07-31 | Applied Extrusion Technologies, Inc. | Polypropylene blends and films prepared therewith |
DE19816154A1 (en) | 1998-04-09 | 1999-10-21 | Bernhard Rieger | Linear isotactic polymers, processes for their production and their use and a catalyst combination |
KR100342541B1 (en) | 1998-04-16 | 2002-06-28 | 나까니시 히로유끼 | Olefin polymerization catalyst and polymerization process |
JPH11310762A (en) | 1998-04-17 | 1999-11-09 | Minnesota Mining & Mfg Co <3M> | Pressure-sensitive adhesive composition and pressure-sensitive adhesive article prepared by using the same |
DE69912276T2 (en) | 1998-04-27 | 2004-07-22 | Essex Specialty Products, Inc., Auburn Hills | METHOD FOR FIXING A WINDOW TO A SUBSTRATE USING A SILANE-FUNCTIONAL ADHESIVE COMPOSITION |
EP0953581B1 (en) | 1998-04-27 | 2004-01-07 | Repsol Quimica S.A. | Catalytic systems for the polymerization and copolymerization of alpha-olefins |
CA2321712C (en) | 1998-05-01 | 2008-03-18 | Exxon Chemical Patents, Inc. | Tridentate ligand-containing metal catalyst complexes for olefin polymerization |
JPH11315177A (en) | 1998-05-06 | 1999-11-16 | Idemitsu Petrochem Co Ltd | Polypropylene resin composition and film or sheet using the same |
CA2328303C (en) | 1998-05-06 | 2007-01-16 | Huntsman Polymers Corporation | Polymerizations using adjuvant catalyst |
US6800700B2 (en) * | 1998-05-06 | 2004-10-05 | Huntsman Polymers Corporation | Polymerizations using adjuvant catalysts |
US6534572B1 (en) | 1998-05-07 | 2003-03-18 | H. B. Fuller Licensing & Financing, Inc. | Compositions comprising a thermoplastic component and superabsorbent polymer |
US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
CN1130392C (en) | 1998-05-13 | 2003-12-10 | 埃克森美孚化学专利公司 | Propylene homopolymers and methods for making the same |
US6060584A (en) | 1998-05-13 | 2000-05-09 | Eastman Chemical Company | Process for the degradation of polyolefins |
US6087459A (en) | 1998-05-14 | 2000-07-11 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
US6207606B1 (en) | 1998-05-15 | 2001-03-27 | Univation Technologies, Llc | Mixed catalysts and their use in a polymerization process |
US6709742B2 (en) | 1998-05-18 | 2004-03-23 | Dow Global Technologies Inc. | Crosslinked elastic fibers |
WO1999060033A1 (en) | 1998-05-18 | 1999-11-25 | Phillips Petroleum Company | Catalyst composition for polymerizing monomers |
AR018359A1 (en) | 1998-05-18 | 2001-11-14 | Dow Global Technologies Inc | HEAT RESISTANT ARTICLE, CONFIGURED, IRRADIATED AND RETICULATED, FREE FROM A SILANAN RETICULATION AGENT |
JP2002516338A (en) | 1998-05-21 | 2002-06-04 | マクギル ユニバーシティー | Agents as inhibitors of cell migration and / or focal adhesion that interfere with the binding of protein tyrosine phosphatase PEST to signal proteins |
US6576723B1 (en) | 1998-05-23 | 2003-06-10 | Basell Polyolefine Gmbh | Catalyst system and its use for the polymerization of propylene |
US6177190B1 (en) * | 1998-05-29 | 2001-01-23 | 3M Innovative Properties Company | Radiation curable poly(1-alkene) based pressure-sensitive adhesives |
AU6988398A (en) | 1998-06-04 | 1999-12-16 | H.B. Fuller Licensing And Financing Inc. | Waterborne primer and oxygen barrier coating with improved adhesion |
EP1002814A4 (en) | 1998-06-05 | 2001-11-28 | Japan Polychem Corp | Propylene block copolymer and propylene resin composition |
EP1127079B1 (en) | 1998-06-16 | 2005-06-15 | Borealis Technology Oy | Olefin polymerization process |
US6180229B1 (en) * | 1998-06-17 | 2001-01-30 | H. B. Fuller Licensing & Financing, Inc. | Hot melt pressure sensitive adhesive composition useful for contact coating on heat sensitive substrates |
ID29383A (en) | 1998-06-19 | 2001-08-30 | Hengkel Kommanditgesellschaft | ADHESIVE ADHESIVES IN SOME LEVELS |
DE19827327A1 (en) | 1998-06-19 | 1999-12-30 | Targor Gmbh | Sealable multilayer film with a low sealing temperature and a low content of xylene-soluble material, useful in packaging applications |
US6350791B1 (en) * | 1998-06-22 | 2002-02-26 | 3M Innovative Properties Company | Thermosettable adhesive |
EP1865007B1 (en) | 1998-06-25 | 2009-03-25 | Idemitsu Kosan Co., Ltd. | Propylene polymer and composition containing the same, molded object and laminate comprising these, and processes for producing propylene polymer and composition containing the same |
AU757501B2 (en) | 1998-06-30 | 2003-02-20 | Dow Chemical Company, The | Hot melt adhesive composition comprising homogeneous ethylene interpolymer and block copolymer |
US6833404B2 (en) | 1998-06-30 | 2004-12-21 | H.B. Fuller Licensing & Financing Inc. | Hot melts utilizing a high glass transition temperature substantially aliphatic tackifying resin |
JP4438110B2 (en) | 1998-07-01 | 2010-03-24 | 東ソー株式会社 | Quantification method of target nucleic acid |
AU4965299A (en) | 1998-07-02 | 2000-01-24 | Exxon Chemical Patents Inc. | Propylene olefin copolymers |
SG72966A1 (en) | 1998-07-08 | 2000-05-23 | Sumitomo Chemical Co | Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer |
DE19830975A1 (en) | 1998-07-10 | 2000-01-13 | Wolff Walsrode Ag | Thermoformable, lubricious film based on polyolefins and polyamide |
BR9912124A (en) | 1998-07-16 | 2001-09-25 | Univation Tech Llc | Lewis acid co-catalysts based on aluminum for the polymerization of olefin |
US6376416B1 (en) | 1998-07-21 | 2002-04-23 | Japan Polychem Corporation | Olefin polymerization catalyst and process for producing olefin polymer |
US5969217A (en) | 1998-07-23 | 1999-10-19 | Monsanto Corporation | Soybean cultivar 9380479521366 |
WO2000006660A2 (en) | 1998-07-30 | 2000-02-10 | The Dow Chemical Company | High temperature polyolefin based adhesive film with improved polarity for adhering to polyurethane foams |
US6103152A (en) | 1998-07-31 | 2000-08-15 | 3M Innovative Properties Co. | Articles that include a polymer foam and method for preparing same |
US6008394A (en) | 1998-08-07 | 1999-12-28 | Arco Chemicals Technology, L.P. | Sulfonyl catalysts and method of using the same |
DE19836657A1 (en) | 1998-08-13 | 2000-02-17 | Hoechst Trespaphan Gmbh | Multilayer biaxially oriented polypropylene film for cigarette packaging consists of intermediate layer containing wax |
KR20010086206A (en) | 1998-08-18 | 2001-09-10 | 고토 기치 | Polypropylene composition |
JP4625182B2 (en) | 1998-08-20 | 2011-02-02 | バセルテック ユーエスエイ インコーポレイテッド | Crystalline propylene copolymer composition with improved sealing and optical properties and reduced solubility |
KR100404499B1 (en) * | 1998-08-21 | 2003-11-05 | 짓쏘 가부시끼가이샤 | Polypropylene film and multilayered polypropylene film |
EP1115761B1 (en) | 1998-08-26 | 2013-09-18 | ExxonMobil Chemical Patents Inc. | Branched polypropylene compositions |
US6417240B1 (en) | 1998-08-28 | 2002-07-09 | Dow Global Technologies Inc. | Foams prepared from blends of syndiotactic polypropylenes and thermoplastic polymers |
US6284814B1 (en) | 1998-08-31 | 2001-09-04 | Chakra V. Gupta | Method of making masterbatches of liquid additives and, in particular, antimicrobial masterbatches |
US6287705B1 (en) | 1998-09-01 | 2001-09-11 | Idemitsu Petrochemical Co., Ltd. | Propylene random copolymer, propylene resin composition, film of these, and multilayered propylene resin laminate |
US6255414B1 (en) | 1998-09-01 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
US6383425B1 (en) * | 1998-09-03 | 2002-05-07 | Bp Corporation North America Inc. | Method for extruding foamed polypropylene sheet having improved surface appearance |
EP0985677A1 (en) | 1998-09-07 | 2000-03-15 | Industrial Technology Research Institute | Dinuclear metallocene catalyst for olefin polymerization |
US6177527B1 (en) * | 1998-09-08 | 2001-01-23 | Union Carbide Chemical & Plastics Technology Corporation | Process for the preparation of polyethylene or polypropylene |
US6159888A (en) | 1998-09-09 | 2000-12-12 | Phillips Petroleum Company | Polymerization catalyst systems, their preparation, and use |
US6664208B1 (en) | 1999-09-07 | 2003-12-16 | Sumitomo Chemical Company, Limited | Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocarbon polymer |
US6124400A (en) | 1998-09-10 | 2000-09-26 | Academy Of Applied Science | Semicrystalline polymer alloy and process for preparation |
US6121377A (en) | 1998-09-10 | 2000-09-19 | Academy Of Applied Science | Process for the production of thermoplastic elastomeric polyolefin alloys, including syndiotactic-atactic polypropylene alloys and isotactic-atactic polypropylene alloys, and catalysts therefore |
US6221981B1 (en) | 1998-09-14 | 2001-04-24 | Phillips Petroleum Company | Method for making and using a supported metallcene catalyst system |
DE19903306A1 (en) | 1999-01-28 | 2000-08-03 | Targor Gmbh | Organometallic compound, catalyst system containing this organometallic compound and its use |
JP2000230089A (en) | 1998-10-16 | 2000-08-22 | Mitsubishi Chemicals Corp | Olefin thermoplastic elastomer composition and preparation thereof |
KR100430438B1 (en) | 1998-10-22 | 2004-07-19 | 대림산업 주식회사 | Supported metallocence catalyst, preparing method thereof and preparing method of polyolefin using the same |
RU2232766C2 (en) | 1998-10-23 | 2004-07-20 | Эксонмобил Кемикэл Пейтентс Инк. | Bridge-bound metallocenes, method for polymerization |
US6300433B1 (en) | 1998-10-23 | 2001-10-09 | Exxonmobil Chemical Patents Inc. | Olefin copolymerization process with bridged hafnocenes |
JP4623831B2 (en) | 1998-10-28 | 2011-02-02 | トレオファン・ジャーマニー・ゲーエムベーハー・ウント・コー・カーゲー | Biaxially oriented electrical insulating film with improved shrinkage at elevated temperatures |
US6589892B1 (en) | 1998-11-13 | 2003-07-08 | Kimberly-Clark Worldwide, Inc. | Bicomponent nonwoven webs containing adhesive and a third component |
EP1159351A1 (en) | 1998-12-08 | 2001-12-05 | The Dow Chemical Company | Melt-bondable polypropylene/ethylene polymer fiber and composition for making the same |
US6333389B2 (en) * | 1998-12-18 | 2001-12-25 | Univation Technologies, Llc | Olefin polymerization catalysts, their production and use |
US6430898B1 (en) | 1998-12-18 | 2002-08-13 | H.B. Fuller Licensing & Financing, Inc. | Method of packaging a thermoplastic composition with a film having a low complex viscosity and corresponding packaged article |
US6258903B1 (en) | 1998-12-18 | 2001-07-10 | Univation Technologies | Mixed catalyst system |
ATE384747T1 (en) | 1998-12-21 | 2008-02-15 | Exxonmobil Chem Patents Inc | METHOD FOR PRODUCING BRANCHED ETHYLENE-PROPYLENE COPOLYMERS |
US6855424B1 (en) * | 1998-12-28 | 2005-02-15 | Kinberly-Clark Worldwide, Inc. | Breathable composite elastic material having a cellular elastomeric film layer and method of making same |
ES2226498T3 (en) | 1998-12-30 | 2005-03-16 | UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION | COMPOSITIONS OF PRE-ACTIVATED NON-SUPPORTED CATALYSTS THAT HAVE A GIVEN CONCENTRATION AND METHODS OF USE. |
US6583076B1 (en) | 1999-01-08 | 2003-06-24 | Kimberly-Clark Worldwide, Inc. | Nonwoven fabrics prepared using visbroken single-site catalyzed polypropylene |
CA2359054C (en) | 1999-01-22 | 2011-07-05 | Lord Corporation | Autodepositable adhesive |
US6878756B2 (en) | 1999-02-02 | 2005-04-12 | The Procter & Gamble Company | Disposable human waste management devices with improved adhesive flange attachment means to facilitate water adhesion stability with low pain level removal |
JP3832129B2 (en) | 1999-02-05 | 2006-10-11 | 株式会社プライムポリマー | Polypropylene resin composition and injection molded product |
GB9902697D0 (en) | 1999-02-09 | 1999-03-31 | Bp Chem Int Ltd | Novel compounds |
DE19905415A1 (en) | 1999-02-10 | 2000-08-17 | Hoechst Trespaphan Gmbh | Transparent biaxially oriented polyolefin film |
US6515086B1 (en) * | 1999-02-19 | 2003-02-04 | Fina Research, S.A. | Polyolefin production |
US6653254B1 (en) | 1999-02-22 | 2003-11-25 | Fina Technology, Inc | Ziegler-Natta catalyst with metallocene for olefin polymerization |
US6610799B1 (en) | 1999-02-22 | 2003-08-26 | Borealis Technology Oy | Olefin polymerization process |
US6545108B1 (en) | 1999-02-22 | 2003-04-08 | Eastman Chemical Company | Catalysts containing N-pyrrolyl substituted nitrogen donors |
US6620896B1 (en) | 1999-02-23 | 2003-09-16 | Eastman Chemical Company | Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom |
EP1031582A1 (en) | 1999-02-26 | 2000-08-30 | Fina Research S.A. | Use and production of polypropylene |
JP2000256520A (en) | 1999-03-10 | 2000-09-19 | Idemitsu Petrochem Co Ltd | Propylene-based resin composition and interior automotive trim using the same |
US6255395B1 (en) | 1999-03-22 | 2001-07-03 | Hercules Incorporated | Masterbatches having high levels of resin |
EP1086986B1 (en) | 1999-03-26 | 2005-06-01 | Idemitsu Kosan Co., Ltd. | Propylene resin composition and process for producing the same |
GB9907154D0 (en) | 1999-03-29 | 1999-05-19 | Bp Chem Int Ltd | Polymerisation catalysts |
EP1041180A1 (en) | 1999-03-30 | 2000-10-04 | Fina Research S.A. | Polypropylene fibres |
US6207746B1 (en) | 1999-04-05 | 2001-03-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for production of thermoplastic polymer composition |
WO2000059721A1 (en) | 1999-04-06 | 2000-10-12 | International Paper Company | Outdoor banner stock |
US6632885B2 (en) | 1999-04-13 | 2003-10-14 | Mitsui Chemicals, Inc. | Soft syndiotactic polypropylene composition and molded product |
US6174930B1 (en) * | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
FR2792321B1 (en) | 1999-04-19 | 2003-12-12 | Atochem Elf Sa | PROCESS FOR PRODUCING POLYPROPYLENE RESIN WITH CONTROLLED RHEOLOGY |
US6225411B1 (en) | 1999-04-19 | 2001-05-01 | Montell Technology Company Bv | Soft propylene polymer blend with high melt strength |
US6127484A (en) | 1999-04-29 | 2000-10-03 | Equistar Chemicals, Lp | Olefin polymerization process |
BE1012637A3 (en) | 1999-04-29 | 2001-01-09 | Solvay | Polyolefins and method of making. |
FI991057A0 (en) | 1999-05-07 | 1999-05-07 | Borealis As | High stiffness propylene polymers and process for their preparation |
US6500563B1 (en) | 1999-05-13 | 2002-12-31 | Exxonmobil Chemical Patents Inc. | Elastic films including crystalline polymer and crystallizable polymers of propylene |
US6143825A (en) | 1999-05-14 | 2000-11-07 | Montell Technology Company Bv | Adhesive propylene polymer compositions suitable for coating substrates |
GB9911245D0 (en) | 1999-05-15 | 1999-07-14 | Bp Chem Int Ltd | Polymerisation catalysts |
US6423800B1 (en) | 1999-05-26 | 2002-07-23 | Fina Technology, Inc. | Pelletized polyolefin having ultra-high melt flow and its articles of manufacture |
US20010047065A1 (en) | 1999-06-03 | 2001-11-29 | Sun-Chueh Kao | Method for preparing a supported catalyst system and its use in a polymerization process |
US6416699B1 (en) | 1999-06-09 | 2002-07-09 | Fina Technology, Inc. | Reduced shrinkage in metallocene isotactic polypropylene fibers |
JP2001064322A (en) * | 1999-06-24 | 2001-03-13 | Idemitsu Petrochem Co Ltd | Propylene polymer and its molded article, and production of propylene polymer |
AU5884000A (en) * | 1999-06-24 | 2001-01-09 | Dow Chemical Company, The | Polyolefin composition with improved impact properties |
US6657000B1 (en) | 1999-06-25 | 2003-12-02 | Kraton Polymers U.S. Llc | Hot melt pressure sensitive positioning adhesive (III) |
CA2377259A1 (en) | 1999-06-25 | 2001-01-04 | Randal Ray Ford | Process for the polymerization of olefins; polyolefins, and films and articles produced therefrom |
GB9915039D0 (en) | 1999-06-28 | 1999-08-25 | Eastman Chem Co | Aqueous application of additives to polymeric particles |
US6858676B1 (en) * | 1999-07-21 | 2005-02-22 | Sumitomo Chemical Company, Ltd. | Olefin derived copolymer |
KR100699623B1 (en) | 1999-07-26 | 2007-03-23 | 이데미쓰 고산 가부시키가이샤 | Branched olefinic macromonomer, olefin graft copolymer, and olefin resin composition |
US6207773B1 (en) * | 1999-07-28 | 2001-03-27 | Industrial Technology Research Institute | Metallocene catalyst for preparing olefin polymer |
GB9917851D0 (en) | 1999-07-29 | 1999-09-29 | Borealis As | Process |
US6339109B1 (en) * | 1999-08-10 | 2002-01-15 | General Electric Company | Method of pelletization of polymer |
US6852787B1 (en) | 1999-08-17 | 2005-02-08 | Mcmichael James W. | Free-flowing polymer composition |
US6355747B1 (en) * | 1999-08-17 | 2002-03-12 | Solvay Polyolefins Europe-Belgium | Asymmetric silicon-bridged metallocenes useful as catalysts in the polymerization of α-olefins, process for their preparation and use of said metallocenes for the polymerization of α-olefins |
DE19939074A1 (en) | 1999-08-18 | 2001-02-22 | Beiersdorf Ag | Use of reactive phenolic resins in the production of high-viscosity self-adhesive compositions |
DE19939071A1 (en) | 1999-08-18 | 2001-02-22 | Beiersdorf Ag | Use of sulfur and sulfur donors for the crosslinking of high-viscosity self-adhesive hot melt pressure-sensitive adhesives based on non-thermoplastic elastomers |
DE19939078A1 (en) | 1999-08-18 | 2001-02-22 | Beiersdorf Ag | Use of isocyanates in the production of highly viscous self-adhesive compositions |
US6369176B1 (en) | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
DE19940151A1 (en) | 1999-08-24 | 2001-03-01 | Targor Gmbh | Supported catalyst systems, process for their preparation and process for the preparation of poly-1-alkenes with bimodal or multimodal molecular mass distribution |
BR9917469B1 (en) | 1999-08-31 | 2008-11-18 | process for polymerizing an olefin and / or an olefin and at least one or more other olefins, film, and article. | |
US6639020B1 (en) * | 1999-09-03 | 2003-10-28 | Exxon Mobil Chemical Patents Inc. | Plasticized polypropylene thermoplastics |
US6287658B1 (en) | 1999-09-10 | 2001-09-11 | E. I. Du Pont De Nemours And Company | Flexible composite suitable as packaging material |
US6489426B1 (en) | 1999-09-10 | 2002-12-03 | Chisso Corporation | Propylene base polymer and a polypropylene film using the same |
SG82087A1 (en) | 1999-09-10 | 2001-07-24 | Sumitomo Chemical Co | Pressure sensitive adhesive |
RU2232783C2 (en) | 1999-09-14 | 2004-07-20 | Бэйселлтек Ю Эс Эй Инк. | Shock-resistant polyolefin compositions |
JP4438138B2 (en) * | 1999-09-17 | 2010-03-24 | 住友化学株式会社 | Thermoplastic resin composition |
US6183849B1 (en) | 1999-09-17 | 2001-02-06 | Exxon Research And Engineering Company | Method for manufacturing composite board using high oil content wax and the composite board made using high oil content wax |
GB9923072D0 (en) | 1999-09-29 | 1999-12-01 | Bp Chem Int Ltd | Polymerisation catalyst |
WO2001025296A1 (en) | 1999-10-02 | 2001-04-12 | Borealis Technology Oy | Modified supported catalysts for the polymerization of olefins |
WO2001025300A1 (en) | 1999-10-05 | 2001-04-12 | Idemitsu Petrochemical Co., Ltd. | Propylene polymers and resin composition and molding containing the polymers |
WO2001025299A1 (en) | 1999-10-06 | 2001-04-12 | Idemitsu Petrochemical Co., Ltd. | Rolled polypropylene and injection-molded polypropylene |
US6863989B1 (en) | 1999-10-08 | 2005-03-08 | The Procter & Gamble Company | Adhesives comprising linear isotactic polymers |
EP1238035A1 (en) | 1999-10-08 | 2002-09-11 | The Procter & Gamble Company | Adhesives comprising linear, isotactic polymers |
SK5492002A3 (en) | 1999-10-22 | 2002-12-03 | Univation Tech Llc | Start up methods for multiple catalyst systems |
US6271323B1 (en) | 1999-10-28 | 2001-08-07 | Univation Technologies, Llc | Mixed catalyst compounds, catalyst systems and their use in a polymerization process |
US6399722B1 (en) | 1999-12-01 | 2002-06-04 | Univation Technologies, Llc | Solution feed of multiple catalysts |
EP1231236B1 (en) | 1999-10-26 | 2012-12-05 | Idemitsu Kosan Co., Ltd. | Polypropylene film and multilayered laminate |
CN1320037C (en) | 1999-10-26 | 2007-06-06 | 出光兴产株式会社 | Polypropylene film and multilayer laminate |
DE69915626T2 (en) | 1999-10-26 | 2005-02-03 | Repsol Quimica S.A. | Biscyclopentadienyl compounds linked by a carbon atom and metallocenes prepared therewith |
US6559090B1 (en) | 1999-11-01 | 2003-05-06 | W. R. Grace & Co.-Conn. | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
DE60006146T2 (en) * | 1999-11-04 | 2004-09-30 | Exxonmobil Chemical Patents Inc., Baytown | PROPYLENE COPOLYMER FOAMS AND THEIR USE |
US6380327B1 (en) | 1999-11-12 | 2002-04-30 | E. I. Du Pont De Nemours And Company | Chain transfer agents for olefin polymerization |
US6395847B2 (en) | 1999-11-19 | 2002-05-28 | Exxonmobil Chemical Patents Inc. | Supported organometallic catalysts and their use in olefin polymerization |
GB9927432D0 (en) | 1999-11-20 | 2000-01-19 | Avecia Bv | Aqueous polymer emulsions |
DE19956422A1 (en) * | 1999-11-24 | 2001-06-13 | Hella Kg Hueck & Co | Detachable adhesives for joining substrates |
DE19957384A1 (en) | 1999-11-29 | 2001-05-31 | Targor Gmbh | Propylene polymer, useful for the production of water pipes, has a Mw of 350,000-1,000,000 g/mol, Mw/Mn of 4-10, contains polymer fractions having a viscosity number of 500-1400 ml/g and 200-400 ml/g |
US6340730B1 (en) * | 1999-12-06 | 2002-01-22 | Univation Technologies, Llc | Multiple catalyst system |
DE60009012T2 (en) | 1999-12-07 | 2005-01-20 | Mitsubishi Chemical Corp. | Copolymer composition based on propene |
US6602598B1 (en) | 1999-12-07 | 2003-08-05 | Sls Patent Corporation | Quiet unwind stretch wrap film |
US6329454B1 (en) | 1999-12-08 | 2001-12-11 | The Dow Chemical Company | Filled propylene polymer composition |
US6300419B1 (en) | 1999-12-08 | 2001-10-09 | The Dow Chemical Company | Propylene polymer composition |
US20020013440A1 (en) | 1999-12-10 | 2002-01-31 | Agarwal Pawan Kumar | Propylene diene copolymers |
US20010053837A1 (en) | 1999-12-10 | 2001-12-20 | Agarwal Pawan Kumar | Articles formed from propylene diene copolymers |
US20010007896A1 (en) | 1999-12-10 | 2001-07-12 | Agarwal Pawan Kumar | Propylene diene copolymers |
KR20020064334A (en) | 1999-12-10 | 2002-08-07 | 엑손 케미칼 패턴츠 인코포레이티드 | Articles formed from propylene diene copolymers |
US6323284B1 (en) * | 1999-12-10 | 2001-11-27 | Exxonmobil Chemical Patents, Inc. | Method of preparation of crosslinked blends of amorphous and crystalline polymers |
US20010016639A1 (en) | 1999-12-10 | 2001-08-23 | Agarwal Pawan Kumar | Article formed from propylene diene copolymers |
US6248832B1 (en) * | 1999-12-10 | 2001-06-19 | Exxon Mobile Chemical Patents Inc. | Crosslinked blends of amorphous and crystalline polymers and their applications |
ATE293643T1 (en) | 1999-12-10 | 2005-05-15 | Exxonmobil Chem Patents Inc | PROPENE DIENE COPOLYMERS |
JP2001172453A (en) * | 1999-12-14 | 2001-06-26 | Basell Technology Co Bv | Propylene resin composition |
DE19960411B4 (en) | 1999-12-15 | 2005-09-15 | E.I. Du Pont De Nemours And Co., Wilmington | Use of a dispersion adhesive as a laminating adhesive |
US6750302B1 (en) | 1999-12-16 | 2004-06-15 | Phillips Petroleum Company | Organometal catalyst compositions |
DE19961340A1 (en) | 1999-12-17 | 2001-07-19 | Basf Ag | Process for the emulsion polymerization of olefins |
US6407171B1 (en) | 1999-12-20 | 2002-06-18 | Exxon Chemical Patents Inc. | Blends of polyethylene and polypropylene |
WO2001046278A2 (en) * | 1999-12-21 | 2001-06-28 | Exxon Chemical Patents Inc. | Adhesive alpha-olefin inter-polymers |
DE19962130A1 (en) | 1999-12-21 | 2001-07-05 | Basell Polypropylen Gmbh | Semi-crystalline propylene polymer compositions with good suitability for the production of biaxially oriented films |
AU1863201A (en) | 1999-12-21 | 2001-07-03 | Basell Polyolefine Gmbh | Partly crystalline propylene polymerisate composition for production of biaxial-stretched polypropylene films |
JP4901043B2 (en) | 1999-12-23 | 2012-03-21 | バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | Transition metal compounds, ligand compositions, catalyst compositions and methods of using them for olefin polymerization and copolymerization |
US6444605B1 (en) | 1999-12-28 | 2002-09-03 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed metal alkoxide and cycloalkadienyl catalysts for the production of polyolefins |
US6399531B1 (en) | 1999-12-28 | 2002-06-04 | Union Carbide Chemicals & Plastics Technology Corporation | Hybrid ziegler-natta and cycloalkadienyl catalysts for the production of polyolefins |
US20020037979A1 (en) | 1999-12-28 | 2002-03-28 | Robert Charles Job | Mixed ziegler/metallocene catalysts for the production of bimodal polyolefins |
US6426026B1 (en) | 1999-12-28 | 2002-07-30 | Union Carbide Chemicals & Plastics Technology Corporation | Process for pelletizing ultra-high melt flow polymers |
US6403855B1 (en) | 1999-12-28 | 2002-06-11 | Exxon Mobil Chemical Patents Inc. | Synthesis of crystalline silicoaluminophosphates and use in olefin production |
US20020128401A1 (en) | 1999-12-28 | 2002-09-12 | Robert Charles Job | Self-supported hybrd catalysts for the production of polyolefins |
DE19963585A1 (en) | 1999-12-29 | 2001-07-12 | Dupont Performance Coatings | Hot-melt adhesive useful for precoating materials, comprises a diamine-cured prepolymer prepared by reacting a crystalline linear polyester and a linear polyether with a diisocyanate |
US6448302B1 (en) | 2000-01-19 | 2002-09-10 | The Sherwin-Williams Company | Radiation curable coatings having low gloss and coated articles made therefrom |
US7160949B2 (en) | 2000-01-21 | 2007-01-09 | Mitsui Chemicals, Inc. | Olefin block copolymers, processes for producing the same and uses thereof |
US6329468B1 (en) | 2000-01-21 | 2001-12-11 | Bostik Findley, Inc. | Hot melt adhesive based on semicrystalline flexible polyolefins |
EP2267042B1 (en) | 2000-01-26 | 2015-06-10 | Mitsui Chemicals, Inc. | Olefin diblock copolymer of very low polydispersity and process for preparing the same |
US6465558B2 (en) | 2000-02-03 | 2002-10-15 | Ferro Corporation | Solvent based adhesive composition |
US6492465B1 (en) | 2000-02-08 | 2002-12-10 | Exxonmobil Chemical Patents, Inc. | Propylene impact copolymers |
FR2804964B1 (en) | 2000-02-14 | 2006-09-29 | Omya Sa | USE OF VERY HIGH FLUIDITY ISOTACTIC POLYPROPYLENES FOR THE PREPARATION OF CONCENTRATES OF LOADS USED IN OLEFIN-TYPE THERMOPLASTICS, LOAD CONCENTRATES AND THERMOPLASTICS THUS OBTAINED |
US6579823B2 (en) | 2000-02-18 | 2003-06-17 | Eastman Chemical Company | Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors |
US20020065192A1 (en) | 2000-02-18 | 2002-05-30 | Mackenzie Peter Borden | Productivity catalysts and microstructure control |
EP1126053A1 (en) | 2000-02-18 | 2001-08-22 | Atofina Research S.A. | Polypropylene fibres |
EP1126054A1 (en) | 2000-02-18 | 2001-08-22 | Atofina Research S.A. | Polypropylene fibres |
DE60108796T2 (en) | 2000-02-21 | 2006-01-12 | Cables Pirelli | Fire-resistant and waterproof, halogen-free low-voltage cables |
JP2001316534A (en) * | 2000-03-01 | 2001-11-16 | Chisso Corp | Long-fiber reinforced polypropylene resin composition and molded product |
AU3823201A (en) | 2000-03-17 | 2001-10-03 | Dow Chemical Co | Macrocellular polyolefin foam having a high service temperature for acoustical applications |
EP1187877B1 (en) | 2000-03-22 | 2004-07-14 | Basell Polyolefine GmbH | Process for the preparation of thermoplastic compositions of isotactic polypropylene and flexible polypropylene of lower isotacticity |
US6359077B1 (en) * | 2000-03-29 | 2002-03-19 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing high melt flow polymers |
ES2252202T3 (en) | 2000-03-30 | 2006-05-16 | H.B. FULLER LICENSING & FINANCING, INC. | ADHESIVE COMPOSITIONS INCLUDING PARTICULATED THERMOPLASTIC. |
IT1318436B1 (en) | 2000-03-31 | 2003-08-25 | Enichem Spa | POLYCYCLIC SUBSTITUTED CYCLOPENTADIENES AND METHOD FOR THEIR PREPARATION. |
GB0008690D0 (en) | 2000-04-07 | 2000-05-31 | Borealis Polymers Oy | Process |
GB0008770D0 (en) | 2000-04-10 | 2000-05-31 | Bp Chem Int Ltd | Polymerisation process |
WO2001077193A1 (en) | 2000-04-10 | 2001-10-18 | Bp Chemicals Limited | Polymerisation process |
DE60121585T2 (en) | 2000-04-21 | 2007-07-19 | Exxonmobil Chemical Patents Inc., Baytown | METHOD FOR THE SPRAYING OF A MELT ADHESIVE |
US6596198B1 (en) | 2000-04-28 | 2003-07-22 | Albemarle Corporation | Additive system for polymers in pellet form which provides proportioned stabilization and internal mold release characteristics |
US6528448B1 (en) | 2000-04-28 | 2003-03-04 | Phillips Petroleum Company | Polymerization catalyst compositions and processes to produce polymers and bimodal polymers |
ATE318860T1 (en) | 2000-05-04 | 2006-03-15 | Dow Global Technologies Inc | MOLECULAR MELTS AND METHOD FOR THEIR PRODUCTION AND USE |
US6509107B2 (en) * | 2000-05-05 | 2003-01-21 | Solvay Engineered Polymers | Platable engineered polyolefin alloys |
US6635733B2 (en) | 2000-05-23 | 2003-10-21 | Chisso Corporation | Elastomeric polypropylene |
DE60108062T2 (en) | 2000-05-24 | 2005-06-02 | Basell Polyolefine Gmbh | PROPYLENE POLYMERS AND METHOD FOR THE PRODUCTION THEREOF |
WO2001092407A1 (en) | 2000-05-30 | 2001-12-06 | Idemitsu Petrochemical Co., Ltd. | Resin composition for calendering and polyolefin material for leather-like article |
US6476135B1 (en) | 2000-06-07 | 2002-11-05 | Basell Poliolefine Italia S.P.A. | Polyolefin composition containing low viscosity propylene homopolymer, fiber and extensible non-woven fabric prepared therefrom |
AU2001268419A1 (en) | 2000-06-14 | 2001-12-24 | Luzenac America, Inc. | High flexural modulus and/or high heat deflection temperature thermoplastic elastomers and methods for producing the same |
JP4938199B2 (en) * | 2000-06-14 | 2012-05-23 | 出光興産株式会社 | Polyolefin hot melt adhesive resin |
WO2001098381A2 (en) | 2000-06-16 | 2001-12-27 | Albemarle Corporation | Polymerization process using self-supported catalysts |
DE10029694A1 (en) | 2000-06-16 | 2001-12-20 | Basf Ag | Use of radically-produced polymers, including block copolymers, in a very wide range of applications, eg coatings, toners, cosmetics, detergents, ink-jets, adhesives, moldings, films and fibers |
CN1447824A (en) | 2000-06-20 | 2003-10-08 | 阿托菲纳公司 | Grafted syndiotactic polypropylene and coextruding binders based on syndiotactic polypropylene |
US6573344B1 (en) | 2000-06-22 | 2003-06-03 | Phillips Petroleum Company | Propylene polymerization process |
US6468451B1 (en) | 2000-06-23 | 2002-10-22 | 3M Innovative Properties Company | Method of making a fibrillated article |
JP3772648B2 (en) | 2000-06-30 | 2006-05-10 | 住友化学株式会社 | Polypropylene resin composition |
US6380122B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
US6376410B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
SG106615A1 (en) * | 2000-06-30 | 2004-10-29 | Sumitomo Chemical Co | Polypropylene resin composition, t die film made of the same and method of producing t die film |
EP1170306A1 (en) | 2000-07-05 | 2002-01-09 | ATOFINA Research | Production of polypropylene having improved properties |
JP4323797B2 (en) | 2000-07-07 | 2009-09-02 | エイ.ブイ.トップチーブ インスティテュート オブ ペトロケミカル シンセシス | Preparation of hydrophilic pressure sensitive adhesives with optimized adhesive properties |
EP1739126A1 (en) | 2000-07-12 | 2007-01-03 | Japan Polychem Corporation | Propylene type resin composition, film made thereof, and laminated resin film |
DE10129151A1 (en) | 2000-08-09 | 2002-02-21 | Henkel Kgaa | Two-component adhesive system, e.g. for laying laminate flooring, comprises an aqueous polymer dispersion and a dispersion of drying agent in an oil phase containing compounds with covalent carbon-heteroatom bonds |
NO20013880L (en) | 2000-08-22 | 2002-02-25 | Rohm & Haas | Matrix and process for the production of polyolefins |
DE60137341D1 (en) | 2000-08-22 | 2009-02-26 | Exxonmobil Chem Patents Inc | POLYPROPYLENE FILMS |
US6555238B2 (en) | 2000-08-24 | 2003-04-29 | Dupont-Toray Co. Ltd. | Polyimide film, method of manufacture, and metal interconnect board with polyimide film substrate |
US6448301B1 (en) | 2000-09-08 | 2002-09-10 | 3M Innovative Properties Company | Crosslinkable polymeric compositions and use thereof |
US6852799B2 (en) | 2000-09-11 | 2005-02-08 | Universite De Liege | Universal compatibilizing agent for polyolefines and polar plastics |
US6586531B2 (en) | 2000-10-04 | 2003-07-01 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch and composition suitable for injection molding |
AU1153502A (en) | 2000-10-11 | 2002-04-22 | Aristech Chemical Corp | Polypropylene materials with high melt flow rate and good molding characteristics and methods of making |
JP2002121329A (en) * | 2000-10-13 | 2002-04-23 | Asahi Kasei Corp | Elastomer composition |
EP1272533B1 (en) | 2000-10-13 | 2008-09-03 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
CA2323307A1 (en) | 2000-10-16 | 2002-04-16 | Peter Jackson | Crosslinked, heat shrinkable polypropylene compositions |
US6613381B1 (en) | 2000-10-20 | 2003-09-02 | 3M Innovative Properties Company | Thermoplastic additives for hot melt adhesives based on non-thermoplastic hydrocarbon elastomers |
US6417242B1 (en) | 2000-10-23 | 2002-07-09 | Dow Global Technologies Inc. | Propylene polymer foams |
JP4064048B2 (en) | 2000-10-25 | 2008-03-19 | 住友化学株式会社 | Propylene polymer and film comprising the same |
EP1330479B2 (en) | 2000-10-30 | 2015-01-21 | ExxonMobil Chemical Patents Inc. | Graft-modified polymers based on novel propylene ethylene copolymers |
US6518327B1 (en) * | 2000-11-02 | 2003-02-11 | Basell Poliolefine Italia S.P.A. | Irradiation process for making olefin graft copolymers with low weight side chains |
US6489004B1 (en) | 2000-11-03 | 2002-12-03 | Kimberly-Clark Worldwide, Inc. | Hook and loop fastener having an increased coefficient of friction |
US6357610B1 (en) | 2000-11-03 | 2002-03-19 | Francisco D. Irace | Interlocking cabinet assembly |
US7064160B2 (en) | 2000-11-10 | 2006-06-20 | Japan Polychem Corporation | Moldability modifier for polypropylene resin and polypropylene resin composition containing the same |
JP4742211B2 (en) | 2000-11-29 | 2011-08-10 | Jnc株式会社 | Long fiber reinforced polypropylene resin composition and molded product |
US6713573B2 (en) | 2000-11-30 | 2004-03-30 | Univation Technologies, Llc | Catalyst modifiers and their use in the polymerization of olefin(s) |
WO2002045956A1 (en) | 2000-12-06 | 2002-06-13 | Trespaphan Gmbh | Label film with improved adhesion |
WO2002046300A2 (en) | 2000-12-06 | 2002-06-13 | Ciba Speciality Chemicals Holding Inc. | Polypropylene resin compositions |
US6534608B2 (en) * | 2000-12-07 | 2003-03-18 | Univation Technologies, Llc | Support materials for use with polymerization catalysts |
US6596814B2 (en) | 2000-12-07 | 2003-07-22 | Sunoco Inc. (R&M) | Polypropylene film having good drawability in a wide temperature range and film properties |
US6664309B2 (en) | 2000-12-07 | 2003-12-16 | Bostik Findley, Inc. | Antimicrobial hot melt adhesive |
US6489400B2 (en) * | 2000-12-21 | 2002-12-03 | 3M Innovative Properties Company | Pressure-sensitive adhesive blends comprising ethylene/propylene-derived polymers and propylene-derived polymers and articles therefrom |
TWI238169B (en) | 2000-12-22 | 2005-08-21 | Basell Technology Co Bv | Bioriented polypropylene films |
DE60108173T2 (en) | 2000-12-22 | 2005-06-02 | Dow Global Technologies, Inc., Midland | propylene copolymer |
JP2004516373A (en) | 2000-12-22 | 2004-06-03 | バセル ポリオレフィン イタリア エス.ピー.エー. | Polyolefin sheet for thermoforming |
WO2002051928A2 (en) * | 2000-12-22 | 2002-07-04 | Exxonmobil Chemical Patents Inc. | Composites comprising semicrystalline random ethylene / propylenecopolymers |
SG129994A1 (en) | 2000-12-27 | 2007-03-20 | Sumitomo Chemical Co | Copolymer, adhesive containing the same and laminate |
US6861472B2 (en) | 2000-12-28 | 2005-03-01 | General Electric Company | Poly(arylene ether)-polyolefin compositions and articles derived therefrom |
US20020123538A1 (en) * | 2000-12-29 | 2002-09-05 | Peiguang Zhou | Hot-melt adhesive based on blend of amorphous and crystalline polymers for multilayer bonding |
US6774069B2 (en) * | 2000-12-29 | 2004-08-10 | Kimberly-Clark Worldwide, Inc. | Hot-melt adhesive for non-woven elastic composite bonding |
US6657009B2 (en) * | 2000-12-29 | 2003-12-02 | Kimberly-Clark Worldwide, Inc. | Hot-melt adhesive having improved bonding strength |
US6455634B1 (en) | 2000-12-29 | 2002-09-24 | 3M Innovative Properties Company | Pressure sensitive adhesive blends comprising (meth)acrylate polymers and articles therefrom |
US6872784B2 (en) * | 2000-12-29 | 2005-03-29 | Kimberly-Clark Worldwide, Inc. | Modified rubber-based adhesives |
US6657025B2 (en) | 2001-01-12 | 2003-12-02 | Fina Technology, Inc. | Production of ultra high melt flow polypropylene resins |
US7192902B2 (en) | 2001-01-16 | 2007-03-20 | Exxonmobil Chemical Patents Inc. | Polymerization process with mixed catalyst compositions |
US20020164446A1 (en) | 2001-01-17 | 2002-11-07 | Zhiming Zhou | Pressure sensitive adhesives with a fibrous reinforcing material |
US6858700B2 (en) * | 2001-01-19 | 2005-02-22 | Chervon U.S.A. Inc. | Polymerizable higher diamondoid derivatives |
US6593407B2 (en) | 2001-02-06 | 2003-07-15 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesive composition |
US7193013B2 (en) | 2001-02-07 | 2007-03-20 | Idemitsu Kosan Co. Ltd. | Polyolefin resin composition |
JP2002241439A (en) * | 2001-02-16 | 2002-08-28 | Chisso Corp | Propylene-olefin copolymer and its production method |
JP3921951B2 (en) | 2001-02-27 | 2007-05-30 | 住友化学株式会社 | Polypropylene resin composition and method for producing the same |
US6777497B2 (en) | 2001-03-07 | 2004-08-17 | Sumitomo Chemical Company, Limited | Polypropylene-based resin composition, process for producing the same and injection molded article |
DE60211444T2 (en) | 2001-03-15 | 2006-11-30 | Mitsui Chemicals, Inc. | AUTOMOTIVE PARTS FROM A POLYPROPYLENE RESIN COMPOSITION |
MY137183A (en) | 2001-03-16 | 2009-01-30 | Dow Global Technologies Inc | Method of making interpolymers and products made therefrom |
US6599971B2 (en) | 2001-03-29 | 2003-07-29 | Milliken & Company | Metals salts of hexahydrophthalic acid as nucleating additives for crystalline thermoplastics |
DE10296585B4 (en) | 2001-03-29 | 2013-01-10 | Idemitsu Kosan Co., Ltd. | Polyolefin-based resin composition and film |
US6855656B2 (en) * | 2001-03-30 | 2005-02-15 | Toho Catalyst Co., Ltd. | Polymerization and propylene block copolymer |
US6825276B2 (en) | 2001-04-17 | 2004-11-30 | Pliant Corporation | Nonoriented stiff packaging film with superior tear properties |
DE60135786D1 (en) | 2001-04-19 | 2008-10-23 | Mitsui Chemicals Inc | FLEXIBLE RESIN PELLET AND METHOD FOR THE PRODUCTION THEREOF |
US6858695B2 (en) * | 2001-04-27 | 2005-02-22 | National Starch And Chemical Investment Holding Corporation | Curable hot melt adhesive for casemaking |
GB0111020D0 (en) | 2001-05-04 | 2001-06-27 | Borealis Tech Oy | Process |
US6559211B2 (en) | 2001-05-23 | 2003-05-06 | Milliken & Company | Highly versatile thermoplastic nucleators |
US7217455B2 (en) | 2001-05-30 | 2007-05-15 | 3M Innovative Properties Company | Weatherstrip tape and method for producing the same |
GB0113892D0 (en) | 2001-06-07 | 2001-08-01 | Rewires Devon Ltd | Shaver socket |
WO2003000752A1 (en) | 2001-06-20 | 2003-01-03 | Polypropylene Belgium (Naamloze Vennootschap) | Composition based on propylene polymer, process for its obtention, use for the manufacture of expanded granules and cellular articles |
US20030211310A1 (en) | 2001-06-21 | 2003-11-13 | Haas Christopher K. | Foam and method of making |
US7141300B2 (en) | 2001-06-27 | 2006-11-28 | Nitto Denko Corporation | Adhesive sheet for dicing |
JP4234005B2 (en) | 2001-07-12 | 2009-03-04 | 出光興産株式会社 | Polyolefin resin composition |
CA2449938A1 (en) | 2001-07-25 | 2003-02-06 | Avery Dennison Corporation | Synthetic paper skins and methods of their manufacture |
FR2828198B1 (en) | 2001-07-31 | 2007-02-23 | Atofina | ISOTACTIC POLYPROPYLENE OBTAINED BY METALLOCENE GRAFT CATALYSIS |
EP1428840A4 (en) | 2001-08-07 | 2005-04-06 | Denki Kagaku Kogyo Kk | Process for producing polymer |
US6506847B1 (en) * | 2001-08-08 | 2003-01-14 | Basell Poliolefine Italia S.P.A. | Controlling the molecular weight of graft copolymers using polymerizable chain transfer agents |
WO2003014174A1 (en) | 2001-08-08 | 2003-02-20 | Sumitomo Chemical Company, Limited | Modified olefin copolymer |
EP1424348B1 (en) | 2001-08-24 | 2005-11-02 | Mitsubishi Chemical Corporation | Propylene polymer |
US6709734B2 (en) | 2001-08-27 | 2004-03-23 | Sumitomo Chemical Company, Limited | Resin sheet, thermoformed article, and multilayer structure |
JP2003073524A (en) | 2001-09-03 | 2003-03-12 | Sumitomo Chem Co Ltd | Basic magnesium sulfate-fiber reinforced polypropylene resin composition and injection molded product obtained by using the same resin composition |
US6583209B2 (en) | 2001-09-06 | 2003-06-24 | Equistar Chemicals, Lp | Propylene polymer composites having improved melt strength |
US6562930B2 (en) | 2001-09-18 | 2003-05-13 | Cornell Research Foundation, Inc. | Bis(salicylaldiminato)titanium complex catalysts, highly syndiotactic polypropylene by a chain-end control mechanism, block copolymers containing this |
EP1295926A1 (en) | 2001-09-19 | 2003-03-26 | ExxonMobil Chemical Patents Inc. | Components for adhesive compositions and process for manufacture |
US6855411B2 (en) * | 2001-09-26 | 2005-02-15 | Toray Plastics (America), Inc. | Polyolefin oil resistant film using void initiating solid particles |
CA2460009A1 (en) | 2001-10-01 | 2003-04-10 | Dow Global Technologies Inc. | Blow moldable propylene polymer compositions |
FR2830868B1 (en) | 2001-10-11 | 2004-12-03 | Atofina | COMPOSITION BASED ON ISOTACTIC POLYPROPYLENE OBTAINED BY METALLOCENE CATALYSIS AND ISOTACTIC POLYPROPYLENE OBTAINED BY CATALYSIS ZIEGLER NATTA, GRAFT |
WO2003031176A1 (en) | 2001-10-12 | 2003-04-17 | Toray Plastics (America), Inc. | Polyolefin film for use in cold seal cohesive applications |
US6653385B2 (en) | 2001-10-18 | 2003-11-25 | Bostik Findley, Inc. | Hot melt adhesive composition based on a blend of amorphous poly-α-olefin and syndiotactic polypropylene |
JP3448581B2 (en) | 2001-10-19 | 2003-09-22 | リケンテクノス株式会社 | Thermoplastic elastomer composition, molded article and composite molded article using the same |
EP1308470B8 (en) | 2001-11-01 | 2006-08-02 | Mitsubishi Chemical Corporation | Modified propylene polymer, adhesive composition obtainable therefrom and adhesive comprising the same |
US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
US6943215B2 (en) | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
US6916892B2 (en) | 2001-12-03 | 2005-07-12 | Fina Technology, Inc. | Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene |
US7208552B2 (en) | 2001-12-28 | 2007-04-24 | Nippon Paper Industries, Co., Ltd. | Binder resin compositions, production process and use thereof |
CN100424107C (en) | 2002-01-31 | 2008-10-08 | 三菱化学株式会社 | Non-rigid propylene resin composition |
US6844078B2 (en) * | 2002-02-06 | 2005-01-18 | Toray Plastics (America) Inc. | Polyolefin oil resistant film using high isotactic content polypropylene |
JP4068978B2 (en) * | 2002-02-14 | 2008-03-26 | 三井化学株式会社 | Polyolefin resin composition and shrink film using the same |
EP1482010B1 (en) | 2002-03-05 | 2021-01-13 | Nippon Paper Industries Co., Ltd. | Aqueous dispersion, process for producing the same, and use |
BR0308290A (en) | 2002-03-08 | 2005-01-11 | Monsanto Technology Llc | Treatment and prevention of inflammatory disorders |
US6777476B2 (en) | 2002-03-09 | 2004-08-17 | Hyundai Motor Company | Polypropylene resin composition |
US6998431B2 (en) | 2002-03-28 | 2006-02-14 | Fina Technology, Inc. | Polymerization process |
DE60335089D1 (en) | 2002-03-28 | 2011-01-05 | Zeon Corp | HYDROCARBON POLYMER COMPOSITIONS AND FORM BODY |
US6723769B2 (en) | 2002-03-28 | 2004-04-20 | Fina Technology, Inc. | Polymerization process |
US6758994B2 (en) | 2002-03-28 | 2004-07-06 | Fina Technology, Inc. | Method of producing polypropylene tapes |
US6824721B2 (en) | 2002-03-29 | 2004-11-30 | Fina Technology, Inc. | Polypropylene fibers |
SE0201129L (en) | 2002-04-16 | 2003-10-17 | Borealis Tech Oy | Syntactic polyolefin composition for pipe coating g |
US6878327B2 (en) | 2002-04-19 | 2005-04-12 | Fina Technology, Inc. | Process of making polypropylene fibers |
US7241844B2 (en) | 2002-04-22 | 2007-07-10 | Said Bouhelal | Method for cross-linking isotactic polymers in the presence of peroxide |
US20050159566A1 (en) | 2002-04-23 | 2005-07-21 | Idemitsu Kosan Co., Ltd | Process for producing highly flowable propylene polymer and highly flowable propylene polymer |
DE10218087B4 (en) | 2002-04-23 | 2008-04-17 | Asahi Kasei Kabushiki Kaisha | Resin composition for a battery case for a secondary battery and a battery case for a secondary battery |
US7199204B2 (en) | 2002-05-07 | 2007-04-03 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesive composition |
US20030211349A1 (en) | 2002-05-08 | 2003-11-13 | Longmoore Kenneth J. | Cold seal release film with improved scuff resistance |
US7144925B2 (en) | 2002-05-09 | 2006-12-05 | Dow Global Technologies Inc. | Fire resistance acoustic foam |
US6673870B2 (en) * | 2002-05-13 | 2004-01-06 | The Procter & Gamble Company | Compositions of polyolefins and hyperbranched polymers with improved tensile properties |
DE10221310A1 (en) | 2002-05-14 | 2003-12-11 | Trespaphan Gmbh | Highly active beta nucleation additive for polypropylene |
US6660805B1 (en) | 2002-05-16 | 2003-12-09 | Lord Corporation | Two-part adhesive: part A-monomer, toughener(s), optional adhesion promotor and reducing agent; part B-epoxy resin |
EP1362870A1 (en) * | 2002-05-16 | 2003-11-19 | Atofina | Layered structure with a binder based on a polyolefine grafted with an acrylate monomer |
US6756463B2 (en) | 2002-05-16 | 2004-06-29 | Japan Polychem Corporation | Propylene polymer |
DE10221707A1 (en) | 2002-05-16 | 2003-12-04 | Clariant Gmbh | Polyolefin films with improved processability |
ATE365752T1 (en) | 2002-06-13 | 2007-07-15 | Basell Poliolefine Srl | ZIEGLER NATTA CATALYST FOR THE POLYMERIZATION OF OLEFINS |
US6881793B2 (en) | 2002-07-16 | 2005-04-19 | Fina Technology, Inc. | Polyproplylene materials and method of preparing polypropylene materials |
US6734253B2 (en) | 2002-07-19 | 2004-05-11 | Dow Global Technologies, Inc. | Scratch and mar resistant propylene polymer composition |
EP1527106A2 (en) | 2002-08-01 | 2005-05-04 | Basell Poliolefine Italia S.P.A. | Highly stereoregular polypropylene with improved properties |
US7238846B2 (en) | 2002-08-14 | 2007-07-03 | Exxonmobil Chemical Patents Inc. | Conversion process |
US6992146B2 (en) | 2002-08-22 | 2006-01-31 | Sunoco Inc. (R&M) | Very low melt viscosity resin |
US6855777B2 (en) * | 2002-08-22 | 2005-02-15 | Sunoco, Inc. (R&M) | Very low melt viscosity resin |
US6905760B1 (en) | 2002-08-29 | 2005-06-14 | Asahi Kasei Life And Living Corporation | Polypropylene-based wrap film |
US7064163B2 (en) | 2002-09-04 | 2006-06-20 | Msi Technology Llc | Polyolefin-based adhesive resins and method of making adhesive resins |
JP2004103851A (en) | 2002-09-10 | 2004-04-02 | Renesas Technology Corp | Static semiconductor memory device |
US7125924B2 (en) | 2002-09-17 | 2006-10-24 | Basell Poliolefine Italia S.P.A. | Highly filled soft polyolefin compositions |
DE10244213A1 (en) | 2002-09-23 | 2004-04-01 | Bayer Ag | Process for the preparation of homo-, copolymers and / or block copolymers with metallocenes with a donor-acceptor interaction after living polymerization |
US6818698B1 (en) | 2002-10-07 | 2004-11-16 | Owens Corning Composites Sprl | Aqueous emulsification of high molecular weight functionlized polyolefins |
JP4208543B2 (en) | 2002-10-11 | 2009-01-14 | 三井化学株式会社 | Branched polar group-containing olefin copolymer |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
KR101113341B1 (en) * | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7247679B2 (en) | 2002-10-17 | 2007-07-24 | Exxonmobil Chemical Patents Inc. | Hetero phase polymer compositions |
US6994763B2 (en) | 2002-10-24 | 2006-02-07 | Advanced Design Concept Gmbh | Elastomeric multicomponent fibers, nonwoven webs and nonwoven fabrics |
US7439312B2 (en) | 2002-10-24 | 2008-10-21 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
US7067585B2 (en) | 2002-10-28 | 2006-06-27 | Bostik, Inc. | Hot melt adhesive composition based on a random copolymer of isotactic polypropylene |
JP4426527B2 (en) | 2002-12-20 | 2010-03-03 | エクソンモービル・ケミカル・パテンツ・インク | Polymerization process |
US7183364B2 (en) | 2002-12-20 | 2007-02-27 | University Of Maryland, College Park | Process for preparation of polyolefins via degenerative transfer polymerization |
CN100447532C (en) | 2002-12-24 | 2008-12-31 | 株式会社日本耐美得 | Road information providing server, road information providing system, road information providing method, route search server, route search system, and route search method |
US6919405B2 (en) | 2002-12-31 | 2005-07-19 | 3M Innovative Properties Company | Release compositions and articles made therefrom |
US7226880B2 (en) | 2002-12-31 | 2007-06-05 | Kimberly-Clark Worldwide, Inc. | Breathable, extensible films made with two-component single resins |
US6780936B1 (en) | 2003-02-11 | 2004-08-24 | Exxonmobil Chemical Patents Inc. | Diene-modified propylene polymer nucleating agents |
KR100712631B1 (en) | 2003-02-14 | 2007-05-02 | 미쓰이 가가쿠 가부시키가이샤 | Syndiotactic propylene polymer composition |
WO2004074338A1 (en) | 2003-02-21 | 2004-09-02 | Mitsubishi Chemical Corporation | Propylene copolymer, composition comprising the same and method for producing the same |
US7226974B2 (en) | 2003-03-07 | 2007-06-05 | Asahi Kasei Kabushiki Kaisha | Olefinic rubber composition |
US6984680B2 (en) | 2003-04-15 | 2006-01-10 | Adherent Laboratories, Inc. | Low odor, light color hot pick-up adhesive |
US6767857B1 (en) | 2003-05-29 | 2004-07-27 | Fina Technology, Inc. | Process for forming a Ziegler-Natta catalyst system having a controlled morphology |
US7078468B2 (en) | 2003-06-27 | 2006-07-18 | Fina Technology, Inc. | Polymerization catalyst system using di-sec-butyldimethoxysilane for preparation of polypropylene |
US7201815B2 (en) | 2003-09-02 | 2007-04-10 | H.B. Fuller Licensing & Financing Inc. | Paper laminates manufactured using foamed adhesive systems |
JP2007505173A (en) | 2003-09-11 | 2007-03-08 | バセル ポリオレフィン ジーエムビーエイチ | Multi-stage process for producing heterophasic propylene copolymers |
US7268185B2 (en) | 2003-09-24 | 2007-09-11 | Sumitomo Chemical Company, Limited | Thermoplastic resin composition and its injection molded article |
DE602004008095T2 (en) | 2003-10-07 | 2008-04-30 | Dow Global Technologies, Inc., Midland | POLYPROPYLENE COMPOSITION FOR AIR COOLED BUBBLE FOILS |
US6800703B1 (en) | 2003-10-15 | 2004-10-05 | Equistar Chemicals, Lp | Method for preparing propylene polymers having broad molecular weight distribution |
US7202296B2 (en) | 2003-12-19 | 2007-04-10 | Albemarle Corporation | Flame retardant compositions and their use |
US7247675B2 (en) | 2003-12-30 | 2007-07-24 | Kimberly-Clark Worldwide, Inc. | Elastomer compositions and method of making them |
US20070197712A1 (en) | 2004-03-11 | 2007-08-23 | Idemitsu Unitech Co., Ltd. | Resin composition containing inorganic nucleating agent, molding thereof and process for producing the same |
ATE482983T1 (en) | 2004-03-12 | 2010-10-15 | Basell Polyolefine Gmbh | METHOD FOR POLYMERIZING 1-HEXENE OR HIGHER ALPHA-OLEFINS |
EP1723184A1 (en) | 2004-03-12 | 2006-11-22 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
EP1727836A2 (en) | 2004-03-12 | 2006-12-06 | Basell Polyolefine GmbH | Catalyst system for the polymerization of olefin |
US7101622B2 (en) | 2004-03-19 | 2006-09-05 | Dow Global Technologies Inc. | Propylene-based copolymers, a method of making the fibers and articles made from the fibers |
ATE547442T1 (en) | 2004-04-02 | 2012-03-15 | Nexttec Gmbh | METHOD FOR PRODUCING A COMPOSITE SORPTION MATERIAL FOR THE CHROMATOGRAPHIC SEPARATION OF BIOPOLYMERS |
DE102004016431A1 (en) | 2004-04-02 | 2005-10-20 | Siemens Ag | Method for producing a rotationally symmetrical component |
US7714057B2 (en) | 2005-06-24 | 2010-05-11 | Dow Global Technologies Inc. | Automotive articles prepared from filled TPO compositions, and methods of making the same |
US10362098B2 (en) | 2016-06-21 | 2019-07-23 | Facebook, Inc. | Load balancing back-end application services utilizing derivative-based cluster metrics |
-
2003
- 2003-10-15 KR KR20057006479A patent/KR101113341B1/en active IP Right Grant
- 2003-10-15 US US10/687,508 patent/US7294681B2/en not_active Expired - Lifetime
- 2003-10-15 EP EP20100181853 patent/EP2261292B1/en not_active Expired - Lifetime
- 2003-10-15 CA CA 2499951 patent/CA2499951C/en not_active Expired - Fee Related
- 2003-10-15 JP JP2004570359A patent/JP4972284B2/en not_active Expired - Fee Related
- 2003-10-15 CN CN2010101434298A patent/CN101838362B/en not_active Expired - Fee Related
- 2003-10-15 WO PCT/US2003/033163 patent/WO2005108442A1/en not_active Application Discontinuation
- 2003-10-15 US US10/686,951 patent/US7524910B2/en active Active
- 2003-10-15 ES ES03811599T patent/ES2394304T3/en not_active Expired - Lifetime
- 2003-10-15 CN CN2009102534483A patent/CN101724110B/en not_active Expired - Fee Related
- 2003-10-15 EP EP20030811599 patent/EP1558655B1/en not_active Expired - Lifetime
- 2003-10-15 EP EP20030818982 patent/EP1620479B1/en not_active Expired - Lifetime
- 2003-10-15 AU AU2003304716A patent/AU2003304716A1/en not_active Abandoned
- 2003-10-15 WO PCT/US2003/032910 patent/WO2004046214A2/en active Application Filing
- 2003-10-15 BR BRPI0315341-0B1A patent/BR0315341B1/en not_active IP Right Cessation
- 2003-10-15 AU AU2003302033A patent/AU2003302033A1/en not_active Abandoned
-
2007
- 2007-08-02 US US11/888,870 patent/US8071687B2/en active Active
- 2007-08-02 US US11/888,876 patent/US8088867B2/en active Active
-
2011
- 2011-10-25 US US13/280,381 patent/US8563647B2/en active Active
-
2013
- 2013-09-10 US US14/022,663 patent/US8957159B2/en not_active Expired - Lifetime
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2499951A1 (en) | Multiple catalyst system for olefin polymerization and polymers produced therefrom | |
JP5348732B2 (en) | Multi-catalyst and reactor system for olefin polymerization and polymers produced thereby | |
US8455589B2 (en) | Polymerization process and adhesives therefrom | |
WO2019027585A1 (en) | Mixed catalysts with unbridged hafnocenes with -ch2-sime3 moieties | |
EP3341437B1 (en) | Ethylene copolymer with in-situ oil production | |
RU2013137866A (en) | METHOD FOR PRODUCING MODIFIED METALLOCENES CATALYST, PRODUCED CATALYST AND ITS APPLICATION | |
US20200048382A1 (en) | Mixed Catalyst Systems and Methods of Using the Same | |
SG178201A1 (en) | Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom | |
WO2007061525A1 (en) | Syndiotactic propylene elastomers | |
EP3661981A1 (en) | Polyethylene compositions and films prepared therefrom | |
WO2019089145A1 (en) | Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents | |
WO2018067289A1 (en) | Sterically hindered metallocenes, synthesis and use | |
US20210179743A1 (en) | Low aromatic polyolefins | |
CN111868117B (en) | Method for preparing PEDM with high propylene content by using tetrahydroindacene base catalyst system | |
EP3583137A1 (en) | Hafnocene catalyst compounds and process for use thereof | |
EP3523337A1 (en) | Sterically hindered metallocenes, synthesis and use |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20201015 |