CA2502102A1 - Coating compositions comprising alkyl ketene dimers and alkyl succinic anhydrides for use in paper making - Google Patents

Coating compositions comprising alkyl ketene dimers and alkyl succinic anhydrides for use in paper making Download PDF

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Publication number
CA2502102A1
CA2502102A1 CA002502102A CA2502102A CA2502102A1 CA 2502102 A1 CA2502102 A1 CA 2502102A1 CA 002502102 A CA002502102 A CA 002502102A CA 2502102 A CA2502102 A CA 2502102A CA 2502102 A1 CA2502102 A1 CA 2502102A1
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CA
Canada
Prior art keywords
composition
paper
acrylic acid
acid containing
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002502102A
Other languages
French (fr)
Other versions
CA2502102C (en
Inventor
Charles W. Propst, Jr
James C. Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Spectra Kote Corp
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CA 2773070 priority Critical patent/CA2773070C/en
Publication of CA2502102A1 publication Critical patent/CA2502102A1/en
Application granted granted Critical
Publication of CA2502102C publication Critical patent/CA2502102C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14Carboxylic acids; Derivatives thereof
    • D21H17/15Polycarboxylic acids, e.g. maleic acid
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14Carboxylic acids; Derivatives thereof
    • D21H17/15Polycarboxylic acids, e.g. maleic acid
    • D21H17/16Addition products thereof with hydrocarbons
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/17Ketenes, e.g. ketene dimers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/12Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)

Abstract

Additives for paper making are disclosed herein. Specifically, the additives are wax-free alternatives to conventional coatings, including ASA, AKD and optionally an acrylic containing composition. Other additives may be include d in the coating, such as cationic particles or compositions. The coatings may be used at a variety of points during the paper making process, including on the calender stack and in the wet end.

Claims (40)

  1. I claim:

    In a process for making paper wherein a furnish is deposited on a wire and dewatered, the improvement comprising:
    adding to the furnish a mixture comprising an effective amount of a composition comprising at least one member selected from the group consisting of alkyl ketene dimer (AKD) and alkyl succinic anhydride (ASA) and optionally an acrylic acid containing composition.
  2. 2. The process of claim 1, wherein the mixture comprises an acrylic acid containing composition.
  3. 3. The process of claim 2, wherein the mixture further comprises a crosslinking agent in an amount sufficient to crosslink the acrylic acid containing composition.
  4. 4. The process of claim 3, wherein the crosslinking agent comprises an organic compound.
  5. 5. The process of claim 3, wherein the crosslinking agent is at least one selected from the group consisting of zinc oxide, ammonium oxide, calcium oxide, calcium stearate, magnesium stearate, aluminum oxide, isostearate, magnesium oxide, stannous oxide, tungsten oxide, sodium tungstate, sodium tungstate dehydrate, titanium oxide, aluminum stearate, zinc octoate, zinc salts of fatty acids, zirconium oxide, calcium isosterate, calcium salts of fatty acids, magnesium salts of fatty acids, and aluminum salts of fatty acids.
  6. 6. The process of claim 2, wherein the paper made is selected from the group consisting of Kraft, linerboard and medium.
  7. 7. The process of claim 6, further adding a starch containing component to the furnish.
  8. 8. The process of claim 1, wherein the furnish comprises a stock, the stock comprising recycled fibers and said recycled fibers contain an acrylic acid containing composition.
  9. 9. The process of claim 1, wherein the mixture comprises a polymerizable cationic composition.
  10. 10. In a process for making paper, wherein a furnish is deposited on a wire and dewatered to form a paper, and the dewatered paper is subsequently pressed a number of times to further reduce the water content of the paper, the improvement comprising adding a mixture comprising an effective amount of a composition, the composition comprising at least one member selected from the group consisting of alkyl ketene dimer (AKD) and alkyl succinic anhydride (ASA) and optionally an acrylic acid containing composition, to at least one side of the dewatered paper subsequent to a first pressing step.
  11. 11. The process of claim 10, wherein the composition comprises an acrylic acid containing composition.
  12. 12. The process of claim 11, wherein the mixture further comprises a crosslinking agent in an amount effective to crosslink the acrylic acid containing composition.
  13. 13. The process of claim 10, wherein the mixture is applied to both sides of the dewatered paper subsequent to a first pressing step.
  14. 14. The process of claim 10, wherein the mixture comprises a polymerizable cationic composition.
  15. 15. In a process for making paper wherein a furnish is deposited on a wire and dewatered to form a paper, the dewatered paper is subsequently pressed to further reduce the water content of the paper and is subsequently calendered, the improvement comprising introducing to at least one side of the paper a mixture, the mixture comprising an effective amount of a composition, said composition comprising at least one member selected from the group consisting of alkyl ketene dimer (AKD) and alkyl succinic anhydride (ASA) and optionally an acrylic acid containing composition, between the pressing and calendering steps.
  16. 16. The process of claim 15, wherein the mixture further comprises an acrylic acid containing composition.
  17. 17. The process of claim 15, wherein the mixture further comprises a crosslinking agent, in an amount effective to crosslink the acrylic acid containing composition.
  18. 18. The process of claim 15, wherein the mixture is introduced to both sides of the paper.
  19. 19. The process of claim 15, wherein the mixture comprises a polymerizable cationic composition.
  20. 20. A process for making paper comprising the following steps:
    (A) applying a furnish to a wire;
    (B) dewatering the furnish and obtaining a water containing paper;
    (C) pressing the water containing paper to reduce the water content;
    (D) calendering the pressed paper;
    (E) recovering a finished paper; and (F) adding a coating, comprising an effective amount of at least one member selected from the group consisting of alkyl ketene dimer (AKD) and alkyl succinic anhydride (ASA) and optionally an acrylic acid containing composition.
  21. 21. The process of claim 20, wherein the coating comprises an acrylic acid containing composition.
  22. 22. The process of claim 21, wherein the coating further comprises a crosslinking agent in an amount effective to crosslink the acrylic acid containing composition.
  23. 23. The process of claim 21, wherein the coating adding in step (G) further comprises a starch containing composition.
  24. 24. The process of claim 20, wherein said coating is added more than once during said paper making process.
  25. 25. The process of claim 20, wherein the mixture comprises a polymerizable cationic composition.
  26. 26. A composition comprising:
    at least one member selected from the group consisting of alkyl ketene dimer and akylene succinic anhydride;
    an acrylic acid containing composition; and optionally wood fibers.
  27. 27. The composition of claim 26, further comprising wood fibers.
  28. 28. The composition of claim 26, further comprising a crosslinking agent in an amount sufficient to crosslink the acrylic acid containing composition.
  29. 29. The composition of claim 28, wherein the crosslinking agent is at least one selected from the group consisting of zinc oxide, ammonium oxide, calcium oxide, magnesium stearate, isostearate, calcium stearate, stannous oxide, tungsten oxide, titanium oxide, zinc octoate, aluminum stearate, aluminum oxide, zinc salts of fatty acids, zirconium oxide, calcium isosterate, calcium salts of fatty acids, magnesium salts of fatty acids, and aluminum salts of fatty acids.
  30. 30. The composition of claim 26, further comprising a starch containing composition.
  31. 31. The process of claim 26, wherein the mixture comprises a polymerizable cationic composition.
  32. 32. A process of making a coated paper or kraft stock comprising the steps of:
    providing a paper or kraft stock;
    applying an aqueous resin coating composition as a coating to said paper or stock in an amount in excess of the desired amount of coating;
    said aqueous coating composition comprising at least one member selected from the group consisting of alkyl ketene dimer (AKD) and alkyl succinic anhydride (ASA) and optionally an acrylic acid containing composition;
    metering and removing unwanted coating material from said paper or stock coated with said excess amount of coating material by directing a flow of fluid against said coating;
    solidfying the coating on Said paper or stock; and obtaining a coated paper or kraft stock.
  33. 33. The process of claim 31, where the aqueous coating composition further comprises a starch containing composition.
  34. 34. The process of claim 31, wherein said aqueous composition comprises an acrylic acid containing composition.
  35. 35. The process of claim 33, wherein said aqueous composition further comprises a crosslinking agent in an amount sufficient to crosslink the acrylic acid containing-composition.
  36. 36. The process of claim 32, wherein the fluid is a directed stream of air.
  37. 37. The process of claim 32, wherein the unwanted coating material is recovered and at least some of the recovered material is remixed and applied to said paper or stock.
  38. 38. The process of claim 32, wherein the coating comprises a polymerizable cationic composition.
  39. 39. In a process for making paper wherein a furnish is deposited on a wire and dewatered, the improvement comprising:
    adding to the furnish a mixture comprising an effective amount of a composition comprising at least one member selected from the group consisting of alkyl ketene dimer (AKD) and alkyl succinic anhydride (ASA) and optionally a polymerizable cationic composition.
  40. 40. The process of claim 39, wherein the mixture comprises a polymerizable cationic composition.
CA2502102A 2002-10-24 2003-10-24 Coating compositions comprising alkyl ketene dimers and alkyl succinic anhydrides for use in paper making Expired - Lifetime CA2502102C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA 2773070 CA2773070C (en) 2002-10-24 2003-10-24 Process for preparing a coated paper

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US42072802P 2002-10-24 2002-10-24
US60/420,728 2002-10-24
US10/691,700 US7429309B2 (en) 2002-10-24 2003-10-24 Coating compositions comprising alkyl ketene dimers and alkyl succinic anhydrides for use in paper making
US10/691,700 2003-10-24
PCT/US2003/033743 WO2004037930A2 (en) 2002-10-24 2003-10-24 Coating compositions comprising alkyl ketene dimers and alkyl succinic anhydrides for use in paper making

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA 2773070 Division CA2773070C (en) 2002-10-24 2003-10-24 Process for preparing a coated paper

Publications (2)

Publication Number Publication Date
CA2502102A1 true CA2502102A1 (en) 2004-05-06
CA2502102C CA2502102C (en) 2012-05-29

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CA2502102A Expired - Lifetime CA2502102C (en) 2002-10-24 2003-10-24 Coating compositions comprising alkyl ketene dimers and alkyl succinic anhydrides for use in paper making

Country Status (15)

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US (5) US7429309B2 (en)
EP (1) EP1601726B1 (en)
JP (1) JP4907086B2 (en)
KR (1) KR101073642B1 (en)
CN (2) CN101864690B (en)
AU (2) AU2003286658B8 (en)
BR (1) BR0315421B1 (en)
CA (1) CA2502102C (en)
ES (1) ES2406370T3 (en)
FI (1) FI123562B (en)
NO (1) NO335295B1 (en)
NZ (1) NZ539452A (en)
PT (1) PT1601726E (en)
SE (1) SE529892C2 (en)
WO (1) WO2004037930A2 (en)

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WO2004037930A2 (en) 2004-05-06
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