CA2510866A1 - Process for manufacturing a packaging material - Google Patents

Process for manufacturing a packaging material Download PDF

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Publication number
CA2510866A1
CA2510866A1 CA002510866A CA2510866A CA2510866A1 CA 2510866 A1 CA2510866 A1 CA 2510866A1 CA 002510866 A CA002510866 A CA 002510866A CA 2510866 A CA2510866 A CA 2510866A CA 2510866 A1 CA2510866 A1 CA 2510866A1
Authority
CA
Canada
Prior art keywords
laminate
lacquer
adhesive
electron
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002510866A
Other languages
French (fr)
Inventor
Hans Rudolf Naegeli
Franz Peter Homback
Patrick Benz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3A Composites International AG
Original Assignee
Alcan Technology and Management Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alcan Technology and Management Ltd filed Critical Alcan Technology and Management Ltd
Publication of CA2510866A1 publication Critical patent/CA2510866A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/16Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/06Coating on the layer surface on metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/28Multiple coating on one surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/738Thermoformability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/75Printability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00Treatment by energy or chemical effects
    • B32B2310/08Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0875Treatment by energy or chemical effects by wave energy or particle radiation using particle radiation
    • B32B2310/0887Treatment by energy or chemical effects by wave energy or particle radiation using particle radiation using electron radiation, e.g. beta-rays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00Metals, their alloys or their compounds
    • B32B2311/24Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2553/00Packaging equipment or accessories not otherwise provided for
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1334Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]

Abstract

A process for manufacturing a packaging material having at least two films (14) or foils (12) bonded together to a multi-layer laminate (10) via at least one adhesive layer (13) is such that the adhesive layers are of an electron-beam-curable adhesive and the laminate is radiated with electrons to cure the adhesive. The laminate is particularly suitable for manufacturing containers, in particular such for packaging foodstuffs for humans and animals. The laminate production using electron-beam-curable adhesive results in a significant reduction in throughput time and to a reduction in solvent emissions when substituting an electron-beam-curable adhesive for a solvent-based adhesive.

Description

~

Process for Manufacturing a Packaging Material The invention relates to a process for manufacturing a packaging material having at least two films or foils bonded together to a multi-layer laminate via at least one adhesive layer, whereby the adhesive layer/layers is/are are cured.
Also within the scope of the invention is a deep drawn container made from the laminate.
Today, aluminium-based sterilisable containers for animal foodstuffs are manufactured by laminating an aluminium foil that may be lacquer-coated and a cast polypropylene (cPP)-film to a high grade sterilisable polyurethane (PUR)-adhesive. The laminate is stored under defined conditions until the adhesive has completely cure-hardened. The final structure is: cPP-film / adhesive layer /
aluminium foil. After subsequent curing over a period of several days, the finished laminate can be cut to size and dispatched to the customers. The throughput time from receiving the order up to dispatching the finished laminate depends essentially on the time required for the PUR-adhesive to cure-harden.
The object of the invention is to provide a process of the kind mentioned at the start, by means of which the time for curing the adhesive required for lamination purposes, and with that the throughput time can be reduced in comparison with conventional laminate manufacture.
That objective is achieved by way of the invention in that at least one adhesive is of an electron-beam-curable adhesive and the laminate is radiated with electrons to cure the adhesive.
The radiation curing of electron-beam-curable adhesives takes place within a fraction of a second on passing through a radiation unit, whereby the final bond strength is essentially reached when the laminate emerges from the radiation unit and coiled i.e. without any additional time for curing.

~
The advantage of laminate manufacture using electron-beam-curing adhesives is not only the significantly reduced throughput time but also in a reduction of solvent emissions, if solvent-based adhesives can be replaced by electron-beam-curing adhesives.
A preferred laminate exhibits two films or foils and an adhesive layer of an electron-beam-curable adhesive.
A preferred laminate exhibits the following structure: polyolefin-film /
adhesive layer of an electron-beam-curable adhesive / aluminium foil.
The laminate may, in addition, exhibit lacquer layers and/or printing on the aluminium foil. Preferred laminates with additional lacquer layers and/or printing are:
- Polyolefin-film / adhesive layer of an electron-beam-curable adhesive /
aluminium foil / lacquer layer, in particular gold coloured lacquer layer, whereby the lacquer layer is preferably of an electron-beam-curable lacquer, and the laminate is radiated with electrons for the purpose of curing the lacquer.
- Polyolefin-film / adhesive layer of an electron-beam-curable adhesive /
aluminium foil / lacquer layer, in particular gold coloured lacquer layer /
printing, whereby the lacquer layer and/or the printing is preferably of an electron-beam-curable lacquer or printing substance, and the laminate is radiated with electrons in order to cure the lacquer or printing substance.
- Polyolefin-film / adhesive layer of an electron-beam-curable adhesive /
aluminium foil / lacquer layer / printing / top-layer of lacquer, whereby the lacquer layers and/or the printing are preferably of electron-beam-curable lacquer or printing substances and the laminate is radiated with electrons to cure the lacquer or printing substance.
Preferred polyolefin-films are sealable films of polyethylene (PE) or polypropylene (PP). For sterilisable or high temperature cooking applications PP-films, in particular a cast PP-film, are to be preferred because of the good resistance to conditions involving high temperatures.
The acrylate-based adhesive may contain monomers, oligomers or mixtures of monomers and oligomers. Examples of monomers are mono-, di- and multi-functional acrylates such as phosphoric-acid-ester-acrylates, hydroxy-acrylates, carboxy-acrylates, amino-acrylates, acrylic acid and acryl-amide. Examples of oligomers are epoxy-acrylates, urethane-acrylates, polyester-acrylates, silicon-acrylates and silane-acrylates. The above mentioned monomers and oligomers are either available commercially or can be manufactured using routine methods. The term "acrylate" used here (or "acryl") includes also "methacrylate"
(or "methacryl"), whereby the acrylates are preferred.
The laminate manufactured according to the invention is particularly suitable for manufacturing deep-drawn and sterilisable containers for packaging foodstuffs for humans and animals. Packaging containers manufactured from the laminate by deep drawing are also particularly suitable for portion packaging for meals, packaging for electronic components and battery packs.
Further advantages, features and details are revealed in the following description of preferred examples and with the aid of the drawing which shows schematically in - Fig. 1 cross-section through a laminated packaging film, - Fig. 2 manufacture of the packaging film shown in Fig. 1 A packaging film 10 shown in Fig. 1 for manufacturing deep drawn containers for animal food exhibits - as outer side - an aluminium foil 12 with a gold coloured lacquer coating 11 and a sealable cPP-film 14 as inner side. The alu-minium foil 12 on the outside is bonded permanently to the sealing film 14 by way of an adhesive layer 13 of electron-beam-curable adhesive. In a typical packaging film 10 the thickness of the aluminium foil is e.g. about 60 Nm, the thickness of the cPP-film about 30 Nm.
Figure 2 shows the manufacture of a packaging film 10. The gold lacquered aluminium foil 12 is uncoiled in strip form from a first spool 16 and continuously coated with adhesive 13 on the side not coated with the gold lacquer 11. The sealing film 14 in strip form is led from a second spool 18 onto the aluminium foil 12 coated with adhesive 13 and laminated to this in a continuous manner to form the packaging film 10. The packaging film 10 passes through a radiation unit 20 in which the adhesive layer 13 cures in a fraction of a section due to the electron beam radiation. Thereby, the process parameters i.e. the high voltage and the dosage of radiation are set such that an adequate level of radiation is applied to the adhesive layer 13 to harden it, but only a small level having a negative effect on the cPP-film 14 provided for sealing purposes. On emerging from the radiation unit 20, the packaging film 10 is coiled onto a third spool 22.
Immediately after coiling onto the spool 22, the packaging film 10 with completely cured adhesive layer 13 can be divided into units of commercial required widths using a cutting device.
It is to be understood as self-evident that the bonding of the films or foils in the above lamination process can be such that the adhesive may also be deposited on the other film or foil than that mentioned in the examples.

Claims (11)

1. Process for manufacturing a packaging material having at least two films (14) or foils (12) by means of at least one adhesive layer (13) to form a multi-layer laminate (10), whereby the adhesive layer/layers is/are cured, characterised in that, at least one adhesive layer (13) is of an electron-beam-curable adhesive and the laminate (10) is radiated with electrons to cure the adhesive.
2. Process according to claim 1, characterised in that the laminate (10) exhibits two films (14) or foils (12) and an adhesive layer (13) of an electron-beam-curable adhesive.
3. Process according to claim 2, characterised in that the laminate (10) exhibits the following structure: PP-film (14) / adhesive (13) of an electron-beam-curable adhesive / aluminium foil (12).
4. Process according to claim 3, characterised in that the laminate (10) exhibits additional lacquer layers (11) and/or printing on the aluminium foil (12).
5. Process according to claim 3, characterised in that the laminate (10) exhibits the following structure: PP-film (14) / adhesive layer (13) of an electron-beam curable adhesive / aluminium foil (12) / lacquer layer (11), in particular gold coloured lacquer layer, whereby the lacquer layer is preferably an electron-beam-curable lacquer and the laminate is radiated with electrons to cure the lacquer.
6. Process according to claim 3, characterised in that the laminate (10) exhibits the following structure: PP-film (14) / adhesive layer (13) of an electron-beam-curable adhesive / aluminium foil (12) / lacquer layer (11), in particular gold coloured lacquer layer / printing, whereby the lacquer layer and/or the printing is preferably of an electron-beam-curable lacquer or printing substance, and the laminate is radiated with electrons to cure the lacquer or printing substance.
7. Process according to claim 3, characterised in that the laminate (10) exhibits the following structure: PP-film (14) / adhesive layer (13) of an electron-beam-curable adhesive / aluminium foil (12) / lacquer layer (11) /
printing, outer coat of lacquer, whereby the lacquer layers and/or the printing are preferably of an electron-beam-curable lacquer or printing substance, and the laminate is radiated with electrons to cure the lacquer or printing substance.
8. Process according to one of the claims 3 to 7, characterised in that the PP-layer (14) is a cast PP-film.
9. Process according to one of the claims 1 to 8, characterised in that the adhesive layer (13) is an acrylate-based electron-beam-curable adhesive.
10. Deep drawn and sterilisable packaging container for packaging foodstuffs for humans and animals, made from a laminate (10) manufactured using the process according to one of the claims 1 to 9.
11. Deep drawn packaging container as portion size packaging for meals, packaging for electronic components and battery packs, made from a laminate (10) manufactured using the process according to one of the claims 1 to 9.
CA002510866A 2004-07-01 2005-06-27 Process for manufacturing a packaging material Abandoned CA2510866A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04405405A EP1621333A1 (en) 2004-07-01 2004-07-01 Method for production of a packaging material
EP04405405.4 2004-07-01

Publications (1)

Publication Number Publication Date
CA2510866A1 true CA2510866A1 (en) 2006-01-01

Family

ID=34932173

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002510866A Abandoned CA2510866A1 (en) 2004-07-01 2005-06-27 Process for manufacturing a packaging material

Country Status (3)

Country Link
US (1) US20060003120A1 (en)
EP (1) EP1621333A1 (en)
CA (1) CA2510866A1 (en)

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Also Published As

Publication number Publication date
US20060003120A1 (en) 2006-01-05
EP1621333A1 (en) 2006-02-01

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