CA2522826C - Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase comprising a water in oil emulsion - Google Patents
Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase comprising a water in oil emulsion Download PDFInfo
- Publication number
- CA2522826C CA2522826C CA2522826A CA2522826A CA2522826C CA 2522826 C CA2522826 C CA 2522826C CA 2522826 A CA2522826 A CA 2522826A CA 2522826 A CA2522826 A CA 2522826A CA 2522826 C CA2522826 C CA 2522826C
- Authority
- CA
- Canada
- Prior art keywords
- phase
- cleansing
- personal cleansing
- article according
- saturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 168
- 230000008901 benefit Effects 0.000 title claims abstract description 65
- 239000007762 w/o emulsion Substances 0.000 title claims abstract description 13
- 239000007788 liquid Substances 0.000 title claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- -1 hydroxy fatty acids Chemical class 0.000 claims description 36
- 229920000642 polymer Polymers 0.000 claims description 34
- 125000002091 cationic group Chemical group 0.000 claims description 28
- 239000003921 oil Substances 0.000 claims description 24
- 229920006395 saturated elastomer Polymers 0.000 claims description 22
- 230000008021 deposition Effects 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000003995 emulsifying agent Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 14
- 239000004005 microsphere Substances 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 12
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- WCOXQTXVACYMLM-UHFFFAOYSA-N 2,3-bis(12-hydroxyoctadecanoyloxy)propyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC(O)CCCCCC)COC(=O)CCCCCCCCCCC(O)CCCCCC WCOXQTXVACYMLM-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 8
- 239000003792 electrolyte Substances 0.000 claims description 8
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 8
- 150000005690 diesters Chemical class 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 229960000541 cetyl alcohol Drugs 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000002280 amphoteric surfactant Substances 0.000 claims description 5
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 4
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical class COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 claims description 4
- 235000021314 Palmitic acid Nutrition 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 229960000735 docosanol Drugs 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 239000003607 modifier Substances 0.000 claims description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 229940057400 trihydroxystearin Drugs 0.000 claims description 4
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 3
- ILCOCZBHMDEIAI-UHFFFAOYSA-N 2-(2-octadecoxyethoxy)ethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCOCCO ILCOCZBHMDEIAI-UHFFFAOYSA-N 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 239000003205 fragrance Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 229940098760 steareth-2 Drugs 0.000 claims description 3
- 229940012831 stearyl alcohol Drugs 0.000 claims description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 230000003255 anti-acne Effects 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000002738 chelating agent Substances 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 239000003814 drug Substances 0.000 claims description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 2
- 239000013003 healing agent Substances 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 229940098695 palmitic acid Drugs 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920000223 polyglycerol Polymers 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 235000003441 saturated fatty acids Nutrition 0.000 claims description 2
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 2
- 239000003352 sequestering agent Substances 0.000 claims description 2
- 229960004274 stearic acid Drugs 0.000 claims description 2
- 150000003445 sucroses Chemical class 0.000 claims description 2
- 239000000516 sunscreening agent Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 229930003231 vitamin Natural products 0.000 claims description 2
- 239000011782 vitamin Substances 0.000 claims description 2
- 229940088594 vitamin Drugs 0.000 claims description 2
- 235000013343 vitamin Nutrition 0.000 claims description 2
- 239000000341 volatile oil Substances 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 2
- 150000002194 fatty esters Chemical class 0.000 claims 1
- 239000000344 soap Substances 0.000 claims 1
- 229920001059 synthetic polymer Polymers 0.000 claims 1
- 150000003722 vitamin derivatives Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 21
- 239000002537 cosmetic Substances 0.000 abstract description 11
- 239000012071 phase Substances 0.000 description 131
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 37
- 239000000047 product Substances 0.000 description 31
- 239000004615 ingredient Substances 0.000 description 30
- 238000002156 mixing Methods 0.000 description 29
- 235000019198 oils Nutrition 0.000 description 22
- 230000003750 conditioning effect Effects 0.000 description 19
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 16
- 229960003237 betaine Drugs 0.000 description 14
- 229920001223 polyethylene glycol Polymers 0.000 description 13
- 239000004166 Lanolin Substances 0.000 description 12
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid ester group Chemical group C(CCCCCCCCCCC)(=O)O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 12
- 235000019388 lanolin Nutrition 0.000 description 12
- 229940039717 lanolin Drugs 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 238000013019 agitation Methods 0.000 description 10
- 244000303965 Cyamopsis psoralioides Species 0.000 description 9
- 239000011780 sodium chloride Substances 0.000 description 9
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 8
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 8
- 239000004264 Petrolatum Substances 0.000 description 8
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 8
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 description 8
- 239000002304 perfume Substances 0.000 description 8
- 229940066842 petrolatum Drugs 0.000 description 8
- 235000019271 petrolatum Nutrition 0.000 description 8
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 7
- 229920006317 cationic polymer Polymers 0.000 description 7
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000005639 Lauric acid Substances 0.000 description 6
- NWGKJDSIEKMTRX-BFWOXRRGSA-N [(2r)-2-[(3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)C1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-BFWOXRRGSA-N 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 229920002379 silicone rubber Polymers 0.000 description 6
- 235000015424 sodium Nutrition 0.000 description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 6
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- 239000002202 Polyethylene glycol Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 5
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
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- 238000003860 storage Methods 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
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- HGXHGHZOBLDERL-UHFFFAOYSA-N [NH4+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O Chemical compound [NH4+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O HGXHGHZOBLDERL-UHFFFAOYSA-N 0.000 description 4
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- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 235000013871 bee wax Nutrition 0.000 description 3
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- 238000004140 cleaning Methods 0.000 description 3
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
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- 239000003906 humectant Substances 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
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- 210000004080 milk Anatomy 0.000 description 2
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- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229940069822 monoethanolamine lauryl sulfate Drugs 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KKXWPVVBVWBKBL-UHFFFAOYSA-N n,n-diethylethanamine;dodecyl hydrogen sulfate Chemical compound CC[NH+](CC)CC.CCCCCCCCCCCCOS([O-])(=O)=O KKXWPVVBVWBKBL-UHFFFAOYSA-N 0.000 description 1
- BOUCRWJEKAGKKG-UHFFFAOYSA-N n-[3-(diethylaminomethyl)-4-hydroxyphenyl]acetamide Chemical compound CCN(CC)CC1=CC(NC(C)=O)=CC=C1O BOUCRWJEKAGKKG-UHFFFAOYSA-N 0.000 description 1
- MCVUKOYZUCWLQQ-UHFFFAOYSA-N n-tridecylbenzene Natural products CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 229940116985 potassium lauryl sulfate Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229940045998 sodium isethionate Drugs 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- HVFAVOFILADWEZ-UHFFFAOYSA-M sodium;2-[2-(dodecanoylamino)ethyl-(2-hydroxyethyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCN(CCO)CC([O-])=O HVFAVOFILADWEZ-UHFFFAOYSA-M 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- HYHAWELIVMOSBT-UHFFFAOYSA-M sodium;2-aminopentadecanoate Chemical compound [Na+].CCCCCCCCCCCCCC(N)C([O-])=O HYHAWELIVMOSBT-UHFFFAOYSA-M 0.000 description 1
- LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 description 1
- IWMMSZLFZZPTJY-UHFFFAOYSA-M sodium;3-(dodecylamino)propane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCNCCCS([O-])(=O)=O IWMMSZLFZZPTJY-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 150000003408 sphingolipids Chemical class 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/03—Liquid compositions with two or more distinct layers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Personal cleansing compositions, comprise (A) a cleansing phase containing a surfactant and water; and (B) a separate benefit phase comprising at least one water in oil emulsion; wherein the cleansing and benefit phases are packaged together and are in physical contact. The two phases are packaged in physical contact and remain separate and stable at ambient conditions for at least 180 days. These compositions and corresponding methods provide improved cosmetics, skin feel, and/or skin benefit efficacy.
Description
STRIPED LIQUID PERSONAL CLEANSING COMPOSITIONS CONTAINING A
CLEANSING PHASE AND A SEPARATE BENEFIT PHASE COMPRISING A WATER
IN OIL EMULSION
FIELD OF THE INVENTION
The present invention relates to striped liquid personal cleansing compositions comprising a cleansing phase and a separate benefit phase comprising a water in oil emulsion wherein the two phases are packaged in physical contact while remaining stable for long periods of time.
BACKGROUND OF THE INVENTION
Personal cleansing compositions that purport to provide skin-conditioning benefits are known. Many of these compositions are aqueous systems comprising an emulsified conditioning oil or other similar materials in combination with a lathering surfactant.
Although many of these products can provide both conditioning and cleansing benefits, there are often trade-offs associated with their use. For instance, it is often difficult to formulate a product that deposits a sufficient amount of skin conditioning agents on skin during use. In order to combat emulsification of the skin conditioning agents by the cleansing surfactant, large amounts of the skin conditioning agent are often added to the compositions. Unfortunately, raising the level of skin conditioning agent in order to achieve increased deposition can negatively affect product lather performance and stability.
One attempt at providing conditioning and cleansing benefits from a personal cleansing product while maintaining stability has been the use of dual-chamber packaging. These packages comprise separate cleansing compositions and conditioning compositions, and allow for the co-dispensing of the two in a single or dual stream. The separate conditioning and cleansing compositions thus remain physically separate and stable during prolonged storage and just prior to application, but then mix during or after dispensing to provide conditioning and cleansing benefits from a physically stable system. Although such dual-chamber delivery systems provide improved conditioning benefits versus of conventional systems, it is often difficult to achieve consistent and uniform performance because of the uneven dispensing ratio between the cleansing phase and the conditioning phase from these dual-chamber packages. Additionally, these packaging systems add considerable cost to the finished product.
Striped personal cleansing compositions are also known in the art. However, these compositions do not contain a cleansing phase and a benefit phase and thus stability has not been an issue for these products.
Accordingly, the need still remains for stable personal cleansing compositions that provide both cleansing and improved skin conditioning benefits. It has now been found that striped personal cleansing compositions comprising two phases in physical contact that remain stable for long periods of time can be formulated.
These striped personal cleansing compositions of the present invention comprise cleansing and benefit phases that are packaged in physical contact yet remain stable. These compositions provide improved deposition of conditioning agents on skin.
The compositions of the present invention further provide superior cosmetics via the striped appearance and improved skin feel during and after application. It has been found that such compositions can be formulated with sufficiently high levels of benefit agents without compromising product lather performance and stability. The superior lather performance of these compositions can be demonstrated via the lather volume method described herein.
It has also been found that the striped personal cleansing compositions herein can be formulated with selected skin active agents that provide improved chronic skin benefits to the skin. These compositions comprise a cleansing phase containing a cleansing surfactant and at least one additional benefit phase containing a skin active agent, wherein the cleansing and active phases are packaged in physical contact while remaining stable for long periods of time.
SUMMARY OF THE INVENTION
The present invention is directed to a striped personal cleansing composition comprising first stripe comprising a cleansing phase comprising a surfactant and water, and at least one additional stripe comprising a separate benefit phase comprising a water in oil emulsion.
DETAILED DESCRIPTION
The striped personal cleansing compositions of the present invention comprise a first stripe comprising a cleansing phase, and at least one separate additional stripe comprising a benefit phase. The benefit phase comprises a water in oil emulsion. These and other essential limitations of the compositions and methods of the present invention, as well as many of the optional ingredients suitable for use herein, are described in detail hereinafter.
By the term "stripe" as used herein, is meant that the cleansing phase and the benefit phase herein occupy separate but distinct physical spaces inside the package in which they are stored, but are in direct contact with one another (i.e., they are not separated by a barrier and they are not emulsified or mixed to any significant degree). In one preferred embodiment of the present invention, the cleansing phase and the benefit phase are present within the container as distinct layers or "stripes". The stripes may be relatively uniform and even across the dimension of the package. Alternatively, the layers may be uneven, i.e. wavy, or may be nonuniform in dimension.
The stripes do not need to necessarily extend across the entire dimension of the package. The "stripe' can be various geometric shapes, various different colors or include glitter or pearlescence.
The term "ambient conditions" as used herein, refers to surrounding conditions at one (1) atmosphere of pressure, 50% relative humidity, and 25 C.
The term "stable" as used herein, unless otherwise specified, refers to compositions that maintain at least two "separate" phases when sitting in physical contact at ambient conditions for a period of at least about 180 days. By "separate" is meant that there is substantially no mixing of the phases, observable to the naked eye, prior to dispensing of the composition.
The term "personal cleansing composition" as used herein, refers to compositions intended for topical application to the skin or hair.
The phrase "substantially free of' as used herein, means that the composition comprises less than about 3%, preferably less than about 1%, more preferably less than about 0.5%, even more preferably less than about 0.25%, and most preferably less than about 0.1% of the stated ingredient.
All percentages, parts and ratios as used herein are by weight of the total composition, unless otherwise specified. All such weights as they pertain to listed ingredients are based on the active level and, therefore, do not include solvents or by-products that may be included in commercially available materials, unless otherwise specified.
The personal cleansing compositions and methods of the present invention can comprise, consist of, or consist essentially of, the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful in personal cleansing compositions intended for topical application to the hair or skin.
Product Form The personal cleansing compositions of the present invention are typically in the form of a liquid. The term "liquid" as used herein means that the composition is generally flowable to some degree. "Liquids", therefore, can include liquid, semi-liquid, cream, lotion or gel compositions intended for topical application to skin. These compositions typically exhibit a viscosity of equal to or greater than about 3,000 cps, but less than 1,000,000 cps. These compositions contain a cleansing phase and a benefit phase, both of which are described in greater detail hereinafter.
CLEANSING PHASE AND A SEPARATE BENEFIT PHASE COMPRISING A WATER
IN OIL EMULSION
FIELD OF THE INVENTION
The present invention relates to striped liquid personal cleansing compositions comprising a cleansing phase and a separate benefit phase comprising a water in oil emulsion wherein the two phases are packaged in physical contact while remaining stable for long periods of time.
BACKGROUND OF THE INVENTION
Personal cleansing compositions that purport to provide skin-conditioning benefits are known. Many of these compositions are aqueous systems comprising an emulsified conditioning oil or other similar materials in combination with a lathering surfactant.
Although many of these products can provide both conditioning and cleansing benefits, there are often trade-offs associated with their use. For instance, it is often difficult to formulate a product that deposits a sufficient amount of skin conditioning agents on skin during use. In order to combat emulsification of the skin conditioning agents by the cleansing surfactant, large amounts of the skin conditioning agent are often added to the compositions. Unfortunately, raising the level of skin conditioning agent in order to achieve increased deposition can negatively affect product lather performance and stability.
One attempt at providing conditioning and cleansing benefits from a personal cleansing product while maintaining stability has been the use of dual-chamber packaging. These packages comprise separate cleansing compositions and conditioning compositions, and allow for the co-dispensing of the two in a single or dual stream. The separate conditioning and cleansing compositions thus remain physically separate and stable during prolonged storage and just prior to application, but then mix during or after dispensing to provide conditioning and cleansing benefits from a physically stable system. Although such dual-chamber delivery systems provide improved conditioning benefits versus of conventional systems, it is often difficult to achieve consistent and uniform performance because of the uneven dispensing ratio between the cleansing phase and the conditioning phase from these dual-chamber packages. Additionally, these packaging systems add considerable cost to the finished product.
Striped personal cleansing compositions are also known in the art. However, these compositions do not contain a cleansing phase and a benefit phase and thus stability has not been an issue for these products.
Accordingly, the need still remains for stable personal cleansing compositions that provide both cleansing and improved skin conditioning benefits. It has now been found that striped personal cleansing compositions comprising two phases in physical contact that remain stable for long periods of time can be formulated.
These striped personal cleansing compositions of the present invention comprise cleansing and benefit phases that are packaged in physical contact yet remain stable. These compositions provide improved deposition of conditioning agents on skin.
The compositions of the present invention further provide superior cosmetics via the striped appearance and improved skin feel during and after application. It has been found that such compositions can be formulated with sufficiently high levels of benefit agents without compromising product lather performance and stability. The superior lather performance of these compositions can be demonstrated via the lather volume method described herein.
It has also been found that the striped personal cleansing compositions herein can be formulated with selected skin active agents that provide improved chronic skin benefits to the skin. These compositions comprise a cleansing phase containing a cleansing surfactant and at least one additional benefit phase containing a skin active agent, wherein the cleansing and active phases are packaged in physical contact while remaining stable for long periods of time.
SUMMARY OF THE INVENTION
The present invention is directed to a striped personal cleansing composition comprising first stripe comprising a cleansing phase comprising a surfactant and water, and at least one additional stripe comprising a separate benefit phase comprising a water in oil emulsion.
DETAILED DESCRIPTION
The striped personal cleansing compositions of the present invention comprise a first stripe comprising a cleansing phase, and at least one separate additional stripe comprising a benefit phase. The benefit phase comprises a water in oil emulsion. These and other essential limitations of the compositions and methods of the present invention, as well as many of the optional ingredients suitable for use herein, are described in detail hereinafter.
By the term "stripe" as used herein, is meant that the cleansing phase and the benefit phase herein occupy separate but distinct physical spaces inside the package in which they are stored, but are in direct contact with one another (i.e., they are not separated by a barrier and they are not emulsified or mixed to any significant degree). In one preferred embodiment of the present invention, the cleansing phase and the benefit phase are present within the container as distinct layers or "stripes". The stripes may be relatively uniform and even across the dimension of the package. Alternatively, the layers may be uneven, i.e. wavy, or may be nonuniform in dimension.
The stripes do not need to necessarily extend across the entire dimension of the package. The "stripe' can be various geometric shapes, various different colors or include glitter or pearlescence.
The term "ambient conditions" as used herein, refers to surrounding conditions at one (1) atmosphere of pressure, 50% relative humidity, and 25 C.
The term "stable" as used herein, unless otherwise specified, refers to compositions that maintain at least two "separate" phases when sitting in physical contact at ambient conditions for a period of at least about 180 days. By "separate" is meant that there is substantially no mixing of the phases, observable to the naked eye, prior to dispensing of the composition.
The term "personal cleansing composition" as used herein, refers to compositions intended for topical application to the skin or hair.
The phrase "substantially free of' as used herein, means that the composition comprises less than about 3%, preferably less than about 1%, more preferably less than about 0.5%, even more preferably less than about 0.25%, and most preferably less than about 0.1% of the stated ingredient.
All percentages, parts and ratios as used herein are by weight of the total composition, unless otherwise specified. All such weights as they pertain to listed ingredients are based on the active level and, therefore, do not include solvents or by-products that may be included in commercially available materials, unless otherwise specified.
The personal cleansing compositions and methods of the present invention can comprise, consist of, or consist essentially of, the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful in personal cleansing compositions intended for topical application to the hair or skin.
Product Form The personal cleansing compositions of the present invention are typically in the form of a liquid. The term "liquid" as used herein means that the composition is generally flowable to some degree. "Liquids", therefore, can include liquid, semi-liquid, cream, lotion or gel compositions intended for topical application to skin. These compositions typically exhibit a viscosity of equal to or greater than about 3,000 cps, but less than 1,000,000 cps. These compositions contain a cleansing phase and a benefit phase, both of which are described in greater detail hereinafter.
All of the product forms contemplated for purposes of defining the compositions and methods of the present invention are rinse-off formulations, by which is meant the product is applied topically to the skin or hair and then subsequently (i.e., within minutes) rinsed away with water, or otherwise wiped off using a substrate or other suitable removal means.
Cleansing Phase The personal cleansing compositions of the present invention comprise an aqueous cleansing phase that contains a surfactant suitable for application to the skin or hair. Suitable surfactants for use herein include any known or otherwise effective cleansing surfactant which are suitable for application to the skin, and which are otherwise compatible with the other essential ingredients in the aqueous cleansing phase of the compositions. These cleansing surfactants include anionic, nonionic, cationic, zwitterionic or amphoteric surfactants, or combinations thereof. Other suitable surfactants are described in McCutcheon's, Emulsifiers and Detergents, 1989 Annual, published by M. C. Publishing Co., and in U.S. Patent 3,929,678.
The aqueous cleansing phase of the personal care compositions preferably comprises a cleansing surfactant at concentrations ranging from about 3% to about 60%, more preferably from about 4% to about 30%, even more preferably from about 5% to about 25%, by weight of the aqueous cleansing phase. The preferred pH range of the cleansing phase is from about 5 to about 8.
The aqueous cleansing phase of the personal care compositions preferably produces a Total Lather Volume of at least 350 ml, preferably greater than 400ml, even more preferably greater than 600ml, as described in the Lathering Volume Test. The aqueous cleansing phase of the personal care compositions preferably produces a Flash Lather Volume of at least 150 ml, preferably greater than 200ml, most preferably greater than 300m1 as described in the Lathering Volume Test.
Anionic surfactants suitable for use in the cleansing phase include alkyl and alkyl ether sulfates. These materials have the respective formula ROSO3M and RO(C2H4O)xSO3M, wherein R is alkyl or alkenyl of from about 8 to about 24 carbon atoms, x is 1 to 10, and M is a water-soluble cation such as ammonium, sodium, potassium and triethanolamine.
The alkyl ether sulfates are typically made as condensation products of ethylene oxide and monohydric alcohols having from about 8 to about 24 carbon atoms. Preferably, R has from about 10 to about 18 carbon atoms in both the alkyl and alkyl ether sulfates. The alcohols can be derived from fats, e.g., coconut oil or tallow, or can be synthetic. Lauryl alcohol and straight chain alcohols derived from coconut oil are preferred herein. Such alcohols are reacted with about I
to about 10, preferably from about 3 to about 5, and more preferably with about 3, molar proportions of ethylene oxide and the resulting mixture of molecular species having, for example, an average of 3 moles of ethylene oxide per mole of alcohol, is sulfated and neutralized.
Other suitable anionic surfactants include water-soluble salts of the organic, sulfuric acid reaction products of the general formula [R1-SO3-M], wherein R1 is chosen from the group consisting of a straight or branched chain, saturated aliphatic hydrocarbon radical having from about 8 to about 24, preferably about 10 to about 18, carbon atoms; and M is a cation. Suitable examples are the salts of an organic sulfuric acid reaction product of a hydrocarbon of the methane series, including iso-, neo-, ineso-, and n-paraffins, having about 8 to about 24 carbon atoms, preferably about 10 to about 18 carbon atoms and a sulfonating agent, e.g., SO3, H2SO4, oleum, obtained according to known sulfonation methods, including bleaching and hydrolysis.
Preferred are alkali metal and ammonium sulfonated C10-18 n-paraffins.
Preferred anionic surfactants for use in the cleansing phase include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, monoethanolamine cocoyl sulfate, sodium tridecyl benzene sulfonate, sodium dodecyl benzene sulfonate, and combinations thereof.
Amphoteric surfactants suitable for use in the cleansing phase include those that are broadly described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic water solubilizing group, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate. Examples of compounds falling within this definition are sodium 3-dodecyl-aminopropionate, sodium 3-dodecylaminopropane sulfonate, sodium lauryl sarcosinate, N-alkyltaurines such as the one prepared by reacting dodecylamine with sodium isethionate according to the teaching of U.S. Patent 2,658,072, N-higher alkyl aspartic acids such as those produced according to the teaching of U.S. Patent 2,438,091, and the products described in U.S. Patent 2,528,378.
Zwitterionic surfactants suitable for use in the cleansing phase include those that are broadly described as derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate.
Such suitable zwitterionic surfactants can be represented by the formula:
(R3)x I
R2-Y+-CH2-R4-Z
wherein R2 contains an alkyl, alkenyl, or hydroxy alkyl radical of from about 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxide moieties and from 0 to about 1 glyceryl moiety;
Y is selected from the group consisting of nitrogen, phosphorus, and sulfur atoms; R3 is an alkyl or monohydroxyalkyl group containing about l to about 3 carbon atoms; X is 1 when Y is a sulfur atom, and 2 when Y is a nitrogen or phosphorus atom; R4 is an alkylene or hydroxyalkylene of from about 1 to about 4 carbon atoms and Z is a radical selected from the group consisting of carboxylate, sulfonate, sulfate, phosphonate, and phosphate groups.
Other zwitterionic surfactants suitable for use in the cleansing phase include betaines, including high alkyl betaines such as coco dimethyl carboxymethyl betaine, cocoamidopropyl betaine, cocobetaine, lauryl amidopropyl betaine, oleyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alphacarboxyethyl betaine, cetyl dimethyl carboxymethyl betaine, lauryl bis- (2-hydroxyethyl) carboxymethyl betaine, stearyl bis- (2-hydroxypropyl) carboxymethyl betaine, oleyl dimethyl gamma-carboxypropyl betaine, and lauryl bis-(2-hydroxypropyl)alpha-carboxyethyl betaine. The sulfobetaines may be represented by coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis-(2-hydroxyethyl) sulfopropyl betaine and the like; amidobetaines and amidosulfobetaines, wherein the RCONH(CH2)3 radical is attached to the nitrogen atom of the betaine are also useful in this invention.
Characteristics of Cleansing Phase Preferred For Stability Lamellar Structurant The compositions of the present invention preferably comprise about 0.1 % to 10% by wt.
of a structurant agent in the cleansing phase which functions in the compositions to form a lamellar phase. It is believed the lamellar phase enhances the interfacial stability between the cleansing phase and the benefit phase.
Suitable structurant include fatty acids or ester derivatives thereof, a fatty alcohol, or trihydroxystearin, polycare 133. More preferably the structurant is selected from lauric acid or trihydroxystearin.
In an additional embodiment of the present invention the surfactant compositions for use in the cleansing phase exhibit Non-Newtonian shear thinning behavior (herein referred to as free flowing compositions). These cleansing compositions comprising water, at least one anionic surfactant, an electrolyte and at least one alkanolamide. It has been found that by employing a cleansing phase exhibiting Non-Newtonian shear thinning behavior, the stability of the resulting personal cleansing composition may be increased.
The alkanolamide if present has the general structure of:
0 (R,-O)xH
II
R-C-N
(R2-O)yH
wherein R is C8 to C24 or preferably in some embodiments C8 to C22 or in other embodiments C8 to C18 saturated or unsaturated straight chain or branched aliphatic group, R, and R2 are the same or different C2-C4 straight chain or branched aliphatic group, x = 0 to 10; y = 1 - 10 and wherein the sum of x and y is less than or equal to 10.
The amount of alkanolamide when present in the composition is about 0.1% to about 10%
by weight, and in some embodiments is preferably about 2% to about 5% by weight. Some preferred alkanolamides include Cocamide MEA (Coco monethanolamide) and Cocamide MIPA
(Coco monoisopropranolamide). A co-surfactant from the classes of nonionic surfactant, amphoteric and/or zwitterionic surfactant or cationic surfactant may be optionally incorporated.
The electrolyte, if used, can be added per se to the composition or it can be formed in situ xia the counter-ions included in one of the raw materials. The electrolyte preferably includes an anion comprising phosphate, chloride, sulfate or citrate and a cation comprising sodium, ammonium, potassium, magnesium or mixtures thereof. Some preferred electrolytes are sodium or ammonium chloride or sodium or ammonium sulfate.
The electrolyte should be present in an amount, which facilitates formation of the free flowing composition. Generally, this amount is from about 0.1% by weight to about 15% by weight, preferably from about 1% to about 6% by weight of the cleansing phase, but may be varied if required.
Optional Ingredients for use in the Cleansing Phase Other suitable optional ingredients which may be employed in the cleansing phase include humectants and solutes. A variety of humectants and solutes can be employed and can be present at a level of from about 0.1 % to about 50 %, preferably from about 0.5 % to about 35 %, and more preferably from about 2 % to about 20 % of the personal care composition.
Nonionic polyethylene/polypropylene glycol polymers are preferably used as skin conditioning agents. Polymers useful herein that are especially preferred are PEG-2M wherein x equals 2 and n has an average value of about 2,000 (PEG 2-M is also known as Polyox WSRO N-from Union Carbide and as PEG-2,000); PEG-5M wherein x equals 2 and n has an average value of about 5,000 (PEG 5-M is also known as Polyox WSR 35 and Polyox WSRO
N-80, both from Union Carbide and as PEG-5,000 and Polyethylene Glycol 200,000); PEG-7M wherein x equals 2 and n has an average value of about 7,000 (PEG 7-M is also known as Polyox WSRO
(N-750 from Union Carbide); PEG-9M wherein x equals 2 and n has an average value of about 9,000 (PEG 9-M is also known as Polyox WSRO N-3333 from Union Carbide); PEG-14 M
wherein x equals 2 and n has an average value of about 14,000 (PEG 14-M is also known as Polyox WSR-205 and Polyox WSRO N-3000 both from Union Carbide); and PEG-90M
wherein x equals 2 and n has an average value of about 90,000 (PEG-90M is also known as Polyox WSRO-301 from Union Carbide.) The striped personal cleansing compositions of the present invention may additionally comprise an organic cationic deposition polymer in the cleansing phase as a deposition aid for the benefit agents described hereinafter. Concentrations of the cationic deposition polymer preferably range from about 0.025% to about 3%, more preferably from about 0.05% to about 2%, even more preferably from about 0.1 % to about I%, by weight of the cleansing phase composition.
Suitable cationic deposition polymers for use in the striped personal cleansing composition of the present invention contain cationic nitrogen-containing moieties such as quaternary ammonium or cationic protonated amino moieties. The cationic protonated amines can be primary, secondary, or tertiary amines (preferably secondary or tertiary), depending upon the particular species and the selected pH of the personal cleansing composition. The average molecular weight of the cationic deposition polymer is between about 5,000 to about 10 million, preferably at least about 100,000, more preferably at least about 200,000, but preferably not more than about 2 million, more preferably not more than about 1.5 million. The polymers also have a cationic charge density ranging from about 0.2 meq/gm to about 5 meq/gm, preferably at least about 0.4 meq/gm, more preferably at least about 0.6 meq/gm., at the pH of intended use of the personal cleansing composition, which pH will generally range from about pH 4 to about pH 9, preferably between about pH 5 and about pH 8.
The charge density can be controlled and adjusted in accordance with techniques well known in the art. As used herein the "charge density" of the cationic polymers is defined as the number of cationic sites per polymer gram atomic weight (molecular weight), and can be expressed in terms of meq/gram of cationic charge. In general, adjustment of the proportions of amine or quaternary ammonium moieties in the polymer, as well as pH of the personal cleansing composition in the case of the amines, will affect the charge density.
Any anionic counterions can be use in association with the cationic deposition polymers so long as the polymers remain soluble in water, in the personal cleansing composition, or in a coacervate phase of the personal cleansing composition, and so long as the counterions are physically and chemically compatible with the essential components of the personal cleansing composition or do not otherwise unduly impair product performance, stability or aesthetics.
Nonlimiting examples of such counterions include halides (e.g., chlorine, fluorine, bromine, iodine), sulfate and methlylsulfate.
Nonlimiting examples of cationic deposition polymers for use in the personal cleansing composition include polysaccharide polymers, such as cationic cellulose derivatives. Preferred cationic cellulose polymers are the salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 10 which are available from Amerchol Corp. (Edison, N.J., USA) in their Polymer KG, JR
and LR series of polymers with the most preferred being KG-30M.
Other suitable cationic deposition polymers include cationic guar gum derivatives, such as guar hydroxypropyltrimonium chloride, specific examples of which include the Jaguar series (preferably Jaguar C-17) commercially available from Rhodia Inc., and N-Hance polymer series commercially available from Aqualon.
Other suitable cationic deposition polymers include synthetic cationic polymers. The cationic polymers suitable for use in the cleansing composition herein is water soluble or dispersible, non crosslinked, cationic polymers having a cationic charge density of from about 4 meq/gm to about 7 meq/gm, preferably from about 4 meq/gm to about 6 meq/gm, more preferably from about 4.2 meq/gm to about 5.5 meq/gm. The select polymers also must have an average molecular weight of from about 1,000 to about I million, preferably from about 10,000 to about 500,000, more preferably from about 75,000 to about 250,000.
The concentration of the cationic polymer in the cleansing composition ranges about 0.025% to about 5%, preferably from about 0.1% to about 3%, more preferably from about 0.2%
to about I%, by weight of the composition.
A non-limiting example of a commercially available synthetic cationic polymer for use in the cleansing compositions is polymethyacrylamidopropyl' trimonium chloride, available under the trade name Polycare 133, from Rhodia, Cranberry, N.J., U.S.A.
The cationic polymers herein are either soluble in the cleansing phase, or preferably are soluble in a complex coacervate phase in the striped personal cleansing composition formed by the cationic deposition polymer and the anionic surfactant component described hereinbefore.
Complex coacervates of the cationic deposition polymer can also be formed with other charged materials in the personal cleansing composition.
Coacervate formation is dependent upon a variety of criteria such as molecular weight, component concentration, and ratio of interacting ionic components, ionic strength (including, modification of ionic strength, for example, by addition of salts), charge density of the cationic and anionic components, pH, and temperature. Coacervate systems and the effect of these parameters have been described, for example, by J. Caelles, et al., "Anionic and Cationic Compounds in Mixed Systems", Cosmetics & Toiletries, Vol. 106, April 1991, pp 49-54, C. J.
van Oss, "Coacervation, Complex-Coacervation and Flocculation", J. Dispersion Science and Technology, Vol. 9 (5,6), 1988-89, pp 561-573, and D. J. Burgess, "Practical Analysis of Complex Coacervate Systems", J. of Colloid anti Interface Science, Vol. 140, No. 1, November 1990, pp 227-238.
It is believed to be particularly advantageous for the cationic deposition polymer to be present in the personal cleansing composition in a coacervate phase, or to form a coacervate phase upon application or rinsing of the cleansing composition to or from the skin.
Complex coacervates are believed to more readily deposit on the skin, which results in improved deposition of the benefit materials. Thus, in general, it is preferred that the cationic deposition polymer exists in the personal cleansing composition as a coacervate phase or form a coacervate phase upon dilution. If not already a coacervate in the personal cleansing composition, the cationic deposition polymer will preferably exist in a complex coacervate form in the cleansing composition upon dilution with water.
Techniques for analysis of formation of complex coacervates are known in the art. For example, centrifugation analyses of the personal cleansing compositions, at any chosen stage of dilution, can be utilized to identify whether a coacervate phase has formed.
Benefit Phase (Water in Oil Emulsion) The benefit phase of the present invention comprises a water in oil emulsion comprising an oil, an emulsifier, water and preferably a density modifier. The oil phase is the continuous phase and the water phase is the discontinuous or "internal" phase.
Oils The benefit phase of the present invention typically comprises from about 10%
to about 99% of oil, more preferably 20 to about 95% oil, even more preferably from 50 to about 90% oil and most preferably from 60% to about 80%.
In general the higher the level of oil employed in the water in oil emulsion the more stable the personal cleansing composition employing the water in oil emulsion will be. Oils suitable for use herein include any natural and synthetic materials with an overall solubility parameter less than about 12.5 (cal/cm3)0.5, preferably less than about 11.5 (cal/cm3)0.5.
Solubility parameters for the oils described herein are determined by methods well known in the chemical arts for establishing the relative polar character of a material. A description of solubility parameters and means for determining them are described by C. D. Vaughn, "Solubility Effects in Product, Package, Penetration and Preservation" 103 Cosmetics and Toiletries 47-69, October 1988; and C. D. Vaughn, "Using Solubility Parameters in Cosmetics Formulation", 36 J.
Soc. Cosmetic Chemists 319-333, September/October, 1988.
The benefit agent for use in the benefit phase of the composition has a Vaughan Solubility Parameter (VSP) of from about 5 to about 10, preferably from about 6 to less than 10, more preferably from about 6 to about 9. Non-limiting examples of benefit agents having VSP values ranging from about 5 to about 10 include the following:
VAUGHAN SOLUBILITY PARAMETERS*
Cyclomethicone 5.92 Squalene 6.03 Petrolatum 7.33 Isopropyl Palmitate 7.78 Isopropyl Myristate 8.02 Castor Oil 8.90 Cholesterol 9.55 = As reported in Solubility, Effects in Product, Package, Penetration and Preservation, C. D.
Vaughan, Cosmetics and Toiletries, Vol. 103, October 1988.
By "overall solubility parameter" is meant that it is possible to use oils with higher solubility parameters than 12.5 (cal/cm3)0'5 if they are blended with other oils to reduce the overall solubility parameter of the oil mixture to less than about 12.5 (cal/cm3)0.s For example, a small portion of diethylene glycol (so] par = 13.61) could be blended with lanolin oil (sol par = 7.3) and a cosolublizing agent to create a mixture that has a solubility parameter of less than 12.5(cal/cm3)0.5 Suitable for use herein oils include but are not limited, to hydrocarbon oils and waxes, silicones, fatty acid derivatives, cholesterol, cholesterol derivatives, diglycerides, triglycerides, vegetable oils, vegetable oil derivatives, acetoglyceride esters, alkyl esters, alkenyl esters, lanolin and its derivatives, wax esters, beeswax derivatives, sterols and phospholipids, and combinations thereof.
Non-limiting examples of hydrocarbon oils and waxes suitable for use herein include petrolatum, mineral oil, micro-crystalline waxes, polyalkenes, paraffins, cerasin, ozokerite, polyethylene, perhydrosqualene, poly alpha olefins, hydrogenated polyisobutenes and combinations thereof.
Non-limiting examples of silicone oils suitable for use herein include dimethicone copolyol, dimethylpolysiloxane, diethylpolysiloxane, mixed C1-C30 alkyl polysiloxanes, phenyl dimethicone, dimethiconol, and combinations thereof. Preferred are non-volatile silicones selected from dimethicone, dimethiconol, mixed C1-C30 alkyl polysiloxane, and combinations thereof. Nonlimiting examples of silicone oils useful herein are described in U.S. Patent No.
Cleansing Phase The personal cleansing compositions of the present invention comprise an aqueous cleansing phase that contains a surfactant suitable for application to the skin or hair. Suitable surfactants for use herein include any known or otherwise effective cleansing surfactant which are suitable for application to the skin, and which are otherwise compatible with the other essential ingredients in the aqueous cleansing phase of the compositions. These cleansing surfactants include anionic, nonionic, cationic, zwitterionic or amphoteric surfactants, or combinations thereof. Other suitable surfactants are described in McCutcheon's, Emulsifiers and Detergents, 1989 Annual, published by M. C. Publishing Co., and in U.S. Patent 3,929,678.
The aqueous cleansing phase of the personal care compositions preferably comprises a cleansing surfactant at concentrations ranging from about 3% to about 60%, more preferably from about 4% to about 30%, even more preferably from about 5% to about 25%, by weight of the aqueous cleansing phase. The preferred pH range of the cleansing phase is from about 5 to about 8.
The aqueous cleansing phase of the personal care compositions preferably produces a Total Lather Volume of at least 350 ml, preferably greater than 400ml, even more preferably greater than 600ml, as described in the Lathering Volume Test. The aqueous cleansing phase of the personal care compositions preferably produces a Flash Lather Volume of at least 150 ml, preferably greater than 200ml, most preferably greater than 300m1 as described in the Lathering Volume Test.
Anionic surfactants suitable for use in the cleansing phase include alkyl and alkyl ether sulfates. These materials have the respective formula ROSO3M and RO(C2H4O)xSO3M, wherein R is alkyl or alkenyl of from about 8 to about 24 carbon atoms, x is 1 to 10, and M is a water-soluble cation such as ammonium, sodium, potassium and triethanolamine.
The alkyl ether sulfates are typically made as condensation products of ethylene oxide and monohydric alcohols having from about 8 to about 24 carbon atoms. Preferably, R has from about 10 to about 18 carbon atoms in both the alkyl and alkyl ether sulfates. The alcohols can be derived from fats, e.g., coconut oil or tallow, or can be synthetic. Lauryl alcohol and straight chain alcohols derived from coconut oil are preferred herein. Such alcohols are reacted with about I
to about 10, preferably from about 3 to about 5, and more preferably with about 3, molar proportions of ethylene oxide and the resulting mixture of molecular species having, for example, an average of 3 moles of ethylene oxide per mole of alcohol, is sulfated and neutralized.
Other suitable anionic surfactants include water-soluble salts of the organic, sulfuric acid reaction products of the general formula [R1-SO3-M], wherein R1 is chosen from the group consisting of a straight or branched chain, saturated aliphatic hydrocarbon radical having from about 8 to about 24, preferably about 10 to about 18, carbon atoms; and M is a cation. Suitable examples are the salts of an organic sulfuric acid reaction product of a hydrocarbon of the methane series, including iso-, neo-, ineso-, and n-paraffins, having about 8 to about 24 carbon atoms, preferably about 10 to about 18 carbon atoms and a sulfonating agent, e.g., SO3, H2SO4, oleum, obtained according to known sulfonation methods, including bleaching and hydrolysis.
Preferred are alkali metal and ammonium sulfonated C10-18 n-paraffins.
Preferred anionic surfactants for use in the cleansing phase include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, monoethanolamine cocoyl sulfate, sodium tridecyl benzene sulfonate, sodium dodecyl benzene sulfonate, and combinations thereof.
Amphoteric surfactants suitable for use in the cleansing phase include those that are broadly described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic water solubilizing group, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate. Examples of compounds falling within this definition are sodium 3-dodecyl-aminopropionate, sodium 3-dodecylaminopropane sulfonate, sodium lauryl sarcosinate, N-alkyltaurines such as the one prepared by reacting dodecylamine with sodium isethionate according to the teaching of U.S. Patent 2,658,072, N-higher alkyl aspartic acids such as those produced according to the teaching of U.S. Patent 2,438,091, and the products described in U.S. Patent 2,528,378.
Zwitterionic surfactants suitable for use in the cleansing phase include those that are broadly described as derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate.
Such suitable zwitterionic surfactants can be represented by the formula:
(R3)x I
R2-Y+-CH2-R4-Z
wherein R2 contains an alkyl, alkenyl, or hydroxy alkyl radical of from about 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxide moieties and from 0 to about 1 glyceryl moiety;
Y is selected from the group consisting of nitrogen, phosphorus, and sulfur atoms; R3 is an alkyl or monohydroxyalkyl group containing about l to about 3 carbon atoms; X is 1 when Y is a sulfur atom, and 2 when Y is a nitrogen or phosphorus atom; R4 is an alkylene or hydroxyalkylene of from about 1 to about 4 carbon atoms and Z is a radical selected from the group consisting of carboxylate, sulfonate, sulfate, phosphonate, and phosphate groups.
Other zwitterionic surfactants suitable for use in the cleansing phase include betaines, including high alkyl betaines such as coco dimethyl carboxymethyl betaine, cocoamidopropyl betaine, cocobetaine, lauryl amidopropyl betaine, oleyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alphacarboxyethyl betaine, cetyl dimethyl carboxymethyl betaine, lauryl bis- (2-hydroxyethyl) carboxymethyl betaine, stearyl bis- (2-hydroxypropyl) carboxymethyl betaine, oleyl dimethyl gamma-carboxypropyl betaine, and lauryl bis-(2-hydroxypropyl)alpha-carboxyethyl betaine. The sulfobetaines may be represented by coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis-(2-hydroxyethyl) sulfopropyl betaine and the like; amidobetaines and amidosulfobetaines, wherein the RCONH(CH2)3 radical is attached to the nitrogen atom of the betaine are also useful in this invention.
Characteristics of Cleansing Phase Preferred For Stability Lamellar Structurant The compositions of the present invention preferably comprise about 0.1 % to 10% by wt.
of a structurant agent in the cleansing phase which functions in the compositions to form a lamellar phase. It is believed the lamellar phase enhances the interfacial stability between the cleansing phase and the benefit phase.
Suitable structurant include fatty acids or ester derivatives thereof, a fatty alcohol, or trihydroxystearin, polycare 133. More preferably the structurant is selected from lauric acid or trihydroxystearin.
In an additional embodiment of the present invention the surfactant compositions for use in the cleansing phase exhibit Non-Newtonian shear thinning behavior (herein referred to as free flowing compositions). These cleansing compositions comprising water, at least one anionic surfactant, an electrolyte and at least one alkanolamide. It has been found that by employing a cleansing phase exhibiting Non-Newtonian shear thinning behavior, the stability of the resulting personal cleansing composition may be increased.
The alkanolamide if present has the general structure of:
0 (R,-O)xH
II
R-C-N
(R2-O)yH
wherein R is C8 to C24 or preferably in some embodiments C8 to C22 or in other embodiments C8 to C18 saturated or unsaturated straight chain or branched aliphatic group, R, and R2 are the same or different C2-C4 straight chain or branched aliphatic group, x = 0 to 10; y = 1 - 10 and wherein the sum of x and y is less than or equal to 10.
The amount of alkanolamide when present in the composition is about 0.1% to about 10%
by weight, and in some embodiments is preferably about 2% to about 5% by weight. Some preferred alkanolamides include Cocamide MEA (Coco monethanolamide) and Cocamide MIPA
(Coco monoisopropranolamide). A co-surfactant from the classes of nonionic surfactant, amphoteric and/or zwitterionic surfactant or cationic surfactant may be optionally incorporated.
The electrolyte, if used, can be added per se to the composition or it can be formed in situ xia the counter-ions included in one of the raw materials. The electrolyte preferably includes an anion comprising phosphate, chloride, sulfate or citrate and a cation comprising sodium, ammonium, potassium, magnesium or mixtures thereof. Some preferred electrolytes are sodium or ammonium chloride or sodium or ammonium sulfate.
The electrolyte should be present in an amount, which facilitates formation of the free flowing composition. Generally, this amount is from about 0.1% by weight to about 15% by weight, preferably from about 1% to about 6% by weight of the cleansing phase, but may be varied if required.
Optional Ingredients for use in the Cleansing Phase Other suitable optional ingredients which may be employed in the cleansing phase include humectants and solutes. A variety of humectants and solutes can be employed and can be present at a level of from about 0.1 % to about 50 %, preferably from about 0.5 % to about 35 %, and more preferably from about 2 % to about 20 % of the personal care composition.
Nonionic polyethylene/polypropylene glycol polymers are preferably used as skin conditioning agents. Polymers useful herein that are especially preferred are PEG-2M wherein x equals 2 and n has an average value of about 2,000 (PEG 2-M is also known as Polyox WSRO N-from Union Carbide and as PEG-2,000); PEG-5M wherein x equals 2 and n has an average value of about 5,000 (PEG 5-M is also known as Polyox WSR 35 and Polyox WSRO
N-80, both from Union Carbide and as PEG-5,000 and Polyethylene Glycol 200,000); PEG-7M wherein x equals 2 and n has an average value of about 7,000 (PEG 7-M is also known as Polyox WSRO
(N-750 from Union Carbide); PEG-9M wherein x equals 2 and n has an average value of about 9,000 (PEG 9-M is also known as Polyox WSRO N-3333 from Union Carbide); PEG-14 M
wherein x equals 2 and n has an average value of about 14,000 (PEG 14-M is also known as Polyox WSR-205 and Polyox WSRO N-3000 both from Union Carbide); and PEG-90M
wherein x equals 2 and n has an average value of about 90,000 (PEG-90M is also known as Polyox WSRO-301 from Union Carbide.) The striped personal cleansing compositions of the present invention may additionally comprise an organic cationic deposition polymer in the cleansing phase as a deposition aid for the benefit agents described hereinafter. Concentrations of the cationic deposition polymer preferably range from about 0.025% to about 3%, more preferably from about 0.05% to about 2%, even more preferably from about 0.1 % to about I%, by weight of the cleansing phase composition.
Suitable cationic deposition polymers for use in the striped personal cleansing composition of the present invention contain cationic nitrogen-containing moieties such as quaternary ammonium or cationic protonated amino moieties. The cationic protonated amines can be primary, secondary, or tertiary amines (preferably secondary or tertiary), depending upon the particular species and the selected pH of the personal cleansing composition. The average molecular weight of the cationic deposition polymer is between about 5,000 to about 10 million, preferably at least about 100,000, more preferably at least about 200,000, but preferably not more than about 2 million, more preferably not more than about 1.5 million. The polymers also have a cationic charge density ranging from about 0.2 meq/gm to about 5 meq/gm, preferably at least about 0.4 meq/gm, more preferably at least about 0.6 meq/gm., at the pH of intended use of the personal cleansing composition, which pH will generally range from about pH 4 to about pH 9, preferably between about pH 5 and about pH 8.
The charge density can be controlled and adjusted in accordance with techniques well known in the art. As used herein the "charge density" of the cationic polymers is defined as the number of cationic sites per polymer gram atomic weight (molecular weight), and can be expressed in terms of meq/gram of cationic charge. In general, adjustment of the proportions of amine or quaternary ammonium moieties in the polymer, as well as pH of the personal cleansing composition in the case of the amines, will affect the charge density.
Any anionic counterions can be use in association with the cationic deposition polymers so long as the polymers remain soluble in water, in the personal cleansing composition, or in a coacervate phase of the personal cleansing composition, and so long as the counterions are physically and chemically compatible with the essential components of the personal cleansing composition or do not otherwise unduly impair product performance, stability or aesthetics.
Nonlimiting examples of such counterions include halides (e.g., chlorine, fluorine, bromine, iodine), sulfate and methlylsulfate.
Nonlimiting examples of cationic deposition polymers for use in the personal cleansing composition include polysaccharide polymers, such as cationic cellulose derivatives. Preferred cationic cellulose polymers are the salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 10 which are available from Amerchol Corp. (Edison, N.J., USA) in their Polymer KG, JR
and LR series of polymers with the most preferred being KG-30M.
Other suitable cationic deposition polymers include cationic guar gum derivatives, such as guar hydroxypropyltrimonium chloride, specific examples of which include the Jaguar series (preferably Jaguar C-17) commercially available from Rhodia Inc., and N-Hance polymer series commercially available from Aqualon.
Other suitable cationic deposition polymers include synthetic cationic polymers. The cationic polymers suitable for use in the cleansing composition herein is water soluble or dispersible, non crosslinked, cationic polymers having a cationic charge density of from about 4 meq/gm to about 7 meq/gm, preferably from about 4 meq/gm to about 6 meq/gm, more preferably from about 4.2 meq/gm to about 5.5 meq/gm. The select polymers also must have an average molecular weight of from about 1,000 to about I million, preferably from about 10,000 to about 500,000, more preferably from about 75,000 to about 250,000.
The concentration of the cationic polymer in the cleansing composition ranges about 0.025% to about 5%, preferably from about 0.1% to about 3%, more preferably from about 0.2%
to about I%, by weight of the composition.
A non-limiting example of a commercially available synthetic cationic polymer for use in the cleansing compositions is polymethyacrylamidopropyl' trimonium chloride, available under the trade name Polycare 133, from Rhodia, Cranberry, N.J., U.S.A.
The cationic polymers herein are either soluble in the cleansing phase, or preferably are soluble in a complex coacervate phase in the striped personal cleansing composition formed by the cationic deposition polymer and the anionic surfactant component described hereinbefore.
Complex coacervates of the cationic deposition polymer can also be formed with other charged materials in the personal cleansing composition.
Coacervate formation is dependent upon a variety of criteria such as molecular weight, component concentration, and ratio of interacting ionic components, ionic strength (including, modification of ionic strength, for example, by addition of salts), charge density of the cationic and anionic components, pH, and temperature. Coacervate systems and the effect of these parameters have been described, for example, by J. Caelles, et al., "Anionic and Cationic Compounds in Mixed Systems", Cosmetics & Toiletries, Vol. 106, April 1991, pp 49-54, C. J.
van Oss, "Coacervation, Complex-Coacervation and Flocculation", J. Dispersion Science and Technology, Vol. 9 (5,6), 1988-89, pp 561-573, and D. J. Burgess, "Practical Analysis of Complex Coacervate Systems", J. of Colloid anti Interface Science, Vol. 140, No. 1, November 1990, pp 227-238.
It is believed to be particularly advantageous for the cationic deposition polymer to be present in the personal cleansing composition in a coacervate phase, or to form a coacervate phase upon application or rinsing of the cleansing composition to or from the skin.
Complex coacervates are believed to more readily deposit on the skin, which results in improved deposition of the benefit materials. Thus, in general, it is preferred that the cationic deposition polymer exists in the personal cleansing composition as a coacervate phase or form a coacervate phase upon dilution. If not already a coacervate in the personal cleansing composition, the cationic deposition polymer will preferably exist in a complex coacervate form in the cleansing composition upon dilution with water.
Techniques for analysis of formation of complex coacervates are known in the art. For example, centrifugation analyses of the personal cleansing compositions, at any chosen stage of dilution, can be utilized to identify whether a coacervate phase has formed.
Benefit Phase (Water in Oil Emulsion) The benefit phase of the present invention comprises a water in oil emulsion comprising an oil, an emulsifier, water and preferably a density modifier. The oil phase is the continuous phase and the water phase is the discontinuous or "internal" phase.
Oils The benefit phase of the present invention typically comprises from about 10%
to about 99% of oil, more preferably 20 to about 95% oil, even more preferably from 50 to about 90% oil and most preferably from 60% to about 80%.
In general the higher the level of oil employed in the water in oil emulsion the more stable the personal cleansing composition employing the water in oil emulsion will be. Oils suitable for use herein include any natural and synthetic materials with an overall solubility parameter less than about 12.5 (cal/cm3)0.5, preferably less than about 11.5 (cal/cm3)0.5.
Solubility parameters for the oils described herein are determined by methods well known in the chemical arts for establishing the relative polar character of a material. A description of solubility parameters and means for determining them are described by C. D. Vaughn, "Solubility Effects in Product, Package, Penetration and Preservation" 103 Cosmetics and Toiletries 47-69, October 1988; and C. D. Vaughn, "Using Solubility Parameters in Cosmetics Formulation", 36 J.
Soc. Cosmetic Chemists 319-333, September/October, 1988.
The benefit agent for use in the benefit phase of the composition has a Vaughan Solubility Parameter (VSP) of from about 5 to about 10, preferably from about 6 to less than 10, more preferably from about 6 to about 9. Non-limiting examples of benefit agents having VSP values ranging from about 5 to about 10 include the following:
VAUGHAN SOLUBILITY PARAMETERS*
Cyclomethicone 5.92 Squalene 6.03 Petrolatum 7.33 Isopropyl Palmitate 7.78 Isopropyl Myristate 8.02 Castor Oil 8.90 Cholesterol 9.55 = As reported in Solubility, Effects in Product, Package, Penetration and Preservation, C. D.
Vaughan, Cosmetics and Toiletries, Vol. 103, October 1988.
By "overall solubility parameter" is meant that it is possible to use oils with higher solubility parameters than 12.5 (cal/cm3)0'5 if they are blended with other oils to reduce the overall solubility parameter of the oil mixture to less than about 12.5 (cal/cm3)0.s For example, a small portion of diethylene glycol (so] par = 13.61) could be blended with lanolin oil (sol par = 7.3) and a cosolublizing agent to create a mixture that has a solubility parameter of less than 12.5(cal/cm3)0.5 Suitable for use herein oils include but are not limited, to hydrocarbon oils and waxes, silicones, fatty acid derivatives, cholesterol, cholesterol derivatives, diglycerides, triglycerides, vegetable oils, vegetable oil derivatives, acetoglyceride esters, alkyl esters, alkenyl esters, lanolin and its derivatives, wax esters, beeswax derivatives, sterols and phospholipids, and combinations thereof.
Non-limiting examples of hydrocarbon oils and waxes suitable for use herein include petrolatum, mineral oil, micro-crystalline waxes, polyalkenes, paraffins, cerasin, ozokerite, polyethylene, perhydrosqualene, poly alpha olefins, hydrogenated polyisobutenes and combinations thereof.
Non-limiting examples of silicone oils suitable for use herein include dimethicone copolyol, dimethylpolysiloxane, diethylpolysiloxane, mixed C1-C30 alkyl polysiloxanes, phenyl dimethicone, dimethiconol, and combinations thereof. Preferred are non-volatile silicones selected from dimethicone, dimethiconol, mixed C1-C30 alkyl polysiloxane, and combinations thereof. Nonlimiting examples of silicone oils useful herein are described in U.S. Patent No.
5,011,681 (Ciotti et al.).
Non-limiting examples of diglycerides and triglycerides suitable for use herein include castor oil, soy bean oil, derivatized soybean oils such as maleated soy bean oil, safflower oil, cotton seed oil, corn oil, walnut oil, peanut oil, olive oil, cod liver oil, almond oil, avocado oil, palm oil and sesame oil, vegetable oils, sunflower seed oil, and vegetable oil derivatives; coconut oil and derivatized coconut oil, cottonseed oil and derivatized cottonseed oil, jojoba oil, cocoa butter, and combinations thereof. In addition any of the above oils that have been partially or fully hydrogenated are also suitable.
Non-limiting examples of acetoglyceride esters suitable for use herein include acetylated monoglycerides.
Non-limiting examples of alkyl esters suitable for use herein include isopropyl esters of fatty acids and long chain esters of long chain fatty acids, e.g. SEFA
(sucrose esters of fatty acids). Lauryl pyrolidone carboxylic acid, pentaerthritol esters, aromatic mono, di or triesters, cetyl ricinoleate, non-limiting examples of which include isopropyl palmitate, isopropyl myristate, cetyl riconoleate and stearyl riconoleate. Other examples are:
hexyl laurate, isohexyl laurate, myristyl myristate, isohexyl palmitate, decyl oleate, isodecyl oleate, hexadecyl stearate, decyl stearate, isopropyl isostearate, diisopropyl adipate, diisohexyl adipate, dihexyldecyl adipate, diisopropyl sebacate, acyl isononanoate lauryl lactate, myristyl lactate, cetyl lactate, and combinations thereof.
Non-limiting examples of alkenyl esters suitable for use herein include oleyl myristate, oleyl stearate, oleyl oleate, and combinations thereof.
Non-limiting examples of lanolin and lanolin derivatives suitable for use herein include lanolin, lanolin oil, lanolin wax, lanolin alcohols, lanolin fatty acids, isopropyl lanolate, acetylated lanolin, acetylated lanolin alcohols, lanolin alcohol linoleate, lanolin alcohol riconoleate, hydroxylated lanolin, hydrogenated lanolin and combinations thereof.
Still other suitable oils include milk triglycerides (e.g., hydroxylated milk glyceride) and polyol fatty acid polyesters.
Still other suitable oils include wax esters, non-limiting examples of which include beeswax and beeswax derivatives, spermaceti, myristyl myristate, stearyl stearate, and combinations thereof. Also useful are vegetable waxes such as carnauba and candelilla waxes;
sterols such as cholesterol, cholesterol fatty acid esters; and phospholipids such as lecithin and derivatives, sphingo lipids, ceramides, glycosphingo lipids, and combinations thereof.
Low HLB Emulsifier The water-in-oil emulsion of the present invention also includes about 0.1% to about 20% of a low HLB emulsifier, more preferably from about 0.1% to about 10%, still more preferably from about 0.5% to about 9%, of one or more low HLB
emulsifier. The low HLB emulsifier may function as an emulsifier Preferred low HLB emulsifiers are those having an HLB of from about 1 to about 10, more preferably from 1 to about 8. Suitable low HLB emulsifiers are those selected from saturated C14 to C30 fatty alcohols, saturated C16 to C30 fatty alcohols containing from about 1 to about 5 moles of ethylene oxide, saturated C16 to C30 diols, saturated C16 to C30 monoglycerol ethers, saturated C16 to C30 hydroxy fatty acids, C14 to C30 hydroxylated and nonhydroxylated saturated fatty acids, C14 to C30 saturated ethoxylated fatty acids, amines and alcohols containing from about 1 to about 5 moles of ethylene oxide diols, C14 to C30 saturated glyceryl mono esters with a monoglyceride content of at least 40%, C14 to C30 saturated polyglycerol esters having from about 1 to about 3 alkyl group and from about 2 to about 3 saturated glycerol units, C14 to C30 glyceryl mono ethers, C14 to C30 sorbitan mono/diesters, C14 to C30 saturated ethoxylated sorbitan mono/diesters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated methyl glucoside esters, C14 to C30 saturated sucrose mono/diesters, C14 to C30 saturated ethoxylated methyl glucoside esters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated polyglucosides having an average of between 1 to 2 glucose units and mixtures thereof, having a melting point of at least about 45 C.
The low HLB emulsifiers of the present invention are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, stearic acid, palmitic acid, the polyethylene glycol ether of stearyl alcohol having an average of about 1 to about 5 ethylene oxide units, the polyethylene glycol ether of cetyl alcohol having an average of about 1 to about 5 ethylene oxide units, and mixtures thereof. More preferred low HLB emulsifiers of the present invention are selected from stearyl alcohol, cetyl alcohol, behenyl alcohol, the polyethylene glycol ether of stearyl alcohol having an average of about 2 ethylene oxide units (steareth-2), the polyethylene glycol ether of cetyl alcohol having an average of about 2 ethylene oxide units, and mixtures thereof. Even more preferred low HLB emulsifiers are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, steareth-2, and mixtures thereof.
Density Modifiers To further improve stability under stress conditions such as high temperature and vibration, it is preferable to adjust the densities of the separate phases such that they are substantially equal. To achieve this, low density microspheres are added to the cleansing phase of the striped composition. The low density microspheres employed to reduce the overall density of the cleansing phase are particles having a density lower than 0.7 g/cm3, preferably less than 0.2 g/cm3, more preferably less than 0.1 g/cm3, most preferably less than 0.05 g/cm3. The low density microspheres generally have a diameter less than 200 m, preferably less than 100 gm, most preferably less than 40 m. Preferably, the density difference between the cleansing phase and the benefit phase is less than 0.15 g/cm3, more preferably, the density difference is less than 0.10 g/cm3, even more preferably, the density difference is less than 0.05g/cm3, most preferably, the density difference is less than 0.01 g/cm3.
The microspheres are produced from any appropriate inorganic or organic material, compatible with a use on the skin, that is, nonirritating and nontoxic.
Expanded microspheres made of thermoplastic material are known, and may be obtained, for example, according to the processes described in Patents and Patent Applications EP-56219, EP-348372, EP-486080, EP-320473, EP-112807 and U.S. Pat. No. 3,615,972.
These microspheres may be produced from any nontoxic and non-irritant thermoplastic materials. Polymers or copolymers of acrylonitrile or of vinylidene chloride may be used, for example. It is possible to use, for example, a copolymer containing, by weight, from 0 to 60% of units derived from vinylidene chloride, from 20 to 90% of units derived from acrylonitrile and from 0 to 50% of units derived from an acrylic or styrene monomer, the sum of the percentages (by weight) being equal to 100. The acrylic monomer is, for example, a methyl or ethyl acrylate or methacrylate. The styrene monomer is, for example, alpha-methylstyrene or styrene. These microspheres can be in the dry or hydrated state.
The internal cavity of expanded hollow microspheres contains a gas, which can be a hydrocarbon such as isobutane or isopentane or alternatively air. Among hollow microspheres which can be used, special mention may be made of those marketed under the brand name EXPANCEL (thermoplastic expandable microspheres) by the Akzo Nobel Company, especially those of DE (dry state) or WE (hydrated state) grade. Examples include:
Expancel 091 DE 40 d30; Expancel 091 DE 80 d30; Expancel 051 DE 40 d60; Expancel 091 WE 40 d24;
Expancel 053 DE 40 d20.
Representative microspheres derived from an inorganic material, include, for instance, "Qcel Hollow Microspheres" and "EXTENDOSPHERESTM Ceramic Hollow Spheres", both available from the PQ Corporation. Examples are: Qcel 300; Qcel 6019; Qcel 6042S.
Just as low density microspheres can be added to the cleansing phase of the present invention to improve vibrational stability, high density materials can be added to the benefit phase to increase its density having the same impact on stability.
Aqueous Phase The benefit phase of the present invention typically comprises from about 1%
to about 90% of an aqueous phase. The aqueous phase comprises a fluid selected from the group consisting of water, mono- and polyhydric alcohols (glycerin, propylene glycol, ethanol, isopropanol, etc.).
Optional Ingredients The personal cleansing compositions of the present invention may further comprise other optional ingredients that may modify the physical, chemical, cosmetic or aesthetic characteristics of the compositions or serve as additional "active" components when deposited on the skin. The compositions may also further comprise optional inert ingredients. Many such optional ingredients are known for use in personal care compositions, and may also be used in the personal cleansing compositions herein, provided that such optional materials are compatible with the essential materials described herein, or do not otherwise unduly impair product performance.
Such optional ingredients are most typically those materials approved for use in cosmetics and that are described in reference books such as the CTFA Cosmetic Ingredient Handbook, Second Edition, The Cosmetic, Toiletries, and Fragrance Association, Inc.
1988, 1992. These optional materials can be used in any aspect of the compositions of the present invention, including either of the active or cleansing phases as described herein.
Optional ingredients for use in the cleansing phase of the compositions of the present invention can include any benefit phase material as described herein that is also compatible with the selected ingredients in the cleansing phase. Likewise, optional ingredients for use in the benefit phase of the compositions of the present invention can include any cleansing phase material described herein that is also compatible with the selected ingredients in the benefit phase.
Other optional ingredients for use in either phase of the composition, preferably the benefit phase, include silicone elastomer powders and fluids to provide any of a variety of product benefits, including improved product stability, application cosmetics, emolliency, conditioning, and so forth. The concentration of the silicone elastomers in the composition preferably ranges from about 0.1% to about 20%, more preferably from about 0.5% to about 10%, by weight of the composition. In this context, the weight percentages are based upon the weight of the silicone elastomers material itself, excluding any silicone-containing fluid that typically accompanies such silicone elastomers materials in the formulation process. The silicone elastomers suitable for optional use herein include emulsifying and non-emulsifying silicone elastomers, non-limiting examples of which are described in U.S. patent application serial number 09/613,266 (assigned to The Procter & Gamble Company).
The separate benefit phase of the striped liquid personal cleansing compositions may optionally comprise the following skin benefit ingredients for enhanced delivery of these water in oil emulsion materials on skin. Non limiting examples of these optional ingredients include vitamins and derivatives thereof (e.g., ascorbic acid, vitamin E, tocopheryl acetate, and the like);
sunscreens; thickening agents (e.g., polyol alkoxy ester, available as Crothixmfrom Croda);
preservatives for maintaining the anti microbial integrity of the cleansing compositions; anti-acne medicaments (resorcinol, salicylic acid, and the like); antioxidants; skin soothing and healing agents such as aloe vera extract, allantoin and the like; chelators and sequestrants; and agents suitable for aesthetic purposes such as fragrances, essential oils, skin sensates, pigments, pearlescent agents (e.g., mica and titanium dioxide), lakes, colorings, and the like (e.g., clove oil, menthol, camphor, eucalyptus oil, and eugenol).
Method of Use The striped personal cleansing compositions of the present invention are preferably applied topically to the desired area of the skin or hair in an amount sufficient to provide effective delivery of the skin conditioning agent to the applied surface, or to otherwise provide effective skin conditioning benefits. The compositions can be applied directly to the skin or indirectly via the use of a cleansing puff, washcloth, sponge or other implement. The compositions are preferably diluted with water prior to, during, or after topical application, and then subsequently rinsed or wiped off of the applied surface, preferably rinsed off of the applied surface using water or a water-insoluble substrate in combination with water.
Method of Manufacture The personal cleansing compositions of the present invention may be prepared by any known or otherwise effective technique, suitable for making and formulating the desired striped product form. It is effective to combine toothpaste-tube filling technology with a spinning stage design. Additionally, the present invention can be prepared by the method and apparatus as disclosed in U.S. patent 6,213,166, The method and apparatus allows two or more compositions to be filled with a spiral configuration into a single container.
The method requires that at least two nozzles be employed to fill the container. The container is placed on a static mixer and spun as the composition is introduced into the container.
Alternatively, it is especially effective to combine at least two phases by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product. Specific non-limiting examples of such methods as they are applied to specific embodiments of the present invention are described in the following examples.
If the personal cleansing compositions contain stripes of varying colors it may be desirable to package these compositions in a transparent package such that the consumer can view the pattern through the package. Because of the viscosity of the subject compositions it may also be desirable to include instructions to the consumer to store the package upside down, on its cap to facilitate dispensing.
Analytical Methods Lather Volume Lather volume of a striped liquid personal cleansing composition is measured using a graduated cylinder and a tumbling apparatus. A 1,000 ml graduated cylinder is chosen which is marked in 10 ml increments and has a height of 14.5 inches at the 1,000 ml mark from the inside of its base (for example, Pyrex No. 2982). Distilled water (100 grams at 23 C) is added to the graduated cylinder. The cylinder is clamped in a rotating device, which clamps the cylinder with an axis of rotation that transects the center of the graduated cylinder. One gram of the total personal cleansing composition (0.5g of the cleansing phase and 0.5g of the benefit phase when measuring the total product, or 1 g of the cleansing phase when the measuring the cleansing phase only) is added into the graduated cylinder and the cylinder is capped. The cylinder is rotated at a rate of 10 revolutions in about 20 seconds, and stopped in a vertical position to complete the first rotation sequence. A timer is set to allow 30 seconds for the lather thus generated to drain. After 30 seconds of such drainage, the first lather volume is measured to the nearest 10 ml mark by recording the lather height in ml up from the base (including any water that has drained to the bottom on top of which the lather is floating).
If the top surface of the lather is uneven, the lowest height at which it is possible to see halfway across the graduated cylinder is the first lather volume (ml). If the lather is so coarse that a single or only a few foam cells ("bubbles") reach across the entire cylinder, the height at which at least 10 foam cells are required to fill the space is the first lather volume, also in ml up from the base. Foam cells larger than one inch in any dimension, no matter where they occur, are designated as unfilled air instead of lather. Foam that collects on the top of the graduated cylinder but does not drain is also incorporated in the measurement if the foam on the top is in its own continuous layer, by adding the ml of foam collected there using a ruler to measure thickness of the layer, to the ml of foam measured up from the base. The maximum foam height is 1,000 ml (even if the total foam height exceeds the 1,000 ml mark on the graduated cylinder). One minute after the first rotation is completed, a second rotation sequence is commenced which is identical in speed and duration to the first rotation sequence. The second lather volume is recorded in the same manner as the first, after the same 30 seconds of drainage time. A third sequence is completed and the third lather volume is measured in the same manner, with the same pause between each for drainage and taking the measurement.
The lather result after each sequence is added together and the Total Lather Volume determined as the sum of the three measurements, in ml. The Flash Lather Volume is the result after the first rotation sequence only, in ml, i.e., the first lather volume.
Compositions according to the present invention perform significantly better in this test than similar compositions in conventional emulsion form.
Viscosity of the Liquid Personal Cleansing Composition TM
The Wells-Brookfield Cone/Plate Model DV-11+ Viscometer can be used to determine the viscosity of the liquid personal cleansing compositions herein. The determination is performed at 25 C with the 2.4cm cone measuring system with a gap of 0.013mm between the two small pins on the respective cone and plate. The measurement is performed by injecting 0.5m1 of the sample, to be analyzed, between the cone and plate and, then, rotating the cone at a set speed of I
rpm. The resistance to the rotation of the cone produces a torque that is proportional to the shear stress of the liquid sample. The amount of torque is read 2 minutes after loading the sample and computed by the viscometer into absolute centipoise units (mPa*s) based on the geometric constant of the cone, the rate of rotation, and the stress related torque.
Yield Point of Liquid Personal Cleansing Composition TM
The Carrimed CSL 100 Controlled Stress Rheometer can be used to determine the yield point of the liquid personal cleansing compositions. For purpose herein, the yield point is the amount of stress required to produce a strain of 1% on the liquid personal cleansing composition.
The determination is performed at 77F with the 4cm 2 cone measuring system set with a 51 micron gap. The determination is performed via the programmed application of a shear stress (typically from about 0.06 dynes/sq. centimeter to about 500 dynes/sq.
centimeter) over time interval of 5 minutes. It is this amount of stress that results in a deformation of the sample, a shear stress vs. strain curve can be created. From this curve, the yield point of the liquid personal cleansing composition can be calculated.
EXAMPLES
The following examples further describe and demonstrate embodiments within the scope of the present invention. The examples are given solely for the purpose of illustration and are not to be construed as limitations of the present invention, as many variations thereof are possible without departing from the spirit and scope of the invention. All exemplified amounts are concentrations by weight of the total composition, i.e., wt/wt percentages, unless otherwise specified.
Each of the exemplified compositions provides improved deposition or effectiveness of the skin conditioning agents or optional ingredients delivered from each prepared composition.
Examples 1-3.
The following examples described in Table 1 are non-limiting examples of the personal cleaning compositions herein.
Table 1: Cleansing Phase and Benefit phase Compositions Example 1 Example 2 Example 3 Ingredient wt% wt% Wt%
1. Cleansing Phase Composition Ammonium Laureth-3 Sulfate 3.0 3.0 3.0 Sodium Lauroamphoacetate 16.7 16.7 16.7 TV
(Miranol L-32 Ultra from Rhodia) Ammonium Lauryl Sulfate 1.0 1.0 1.0 Lauric Acid 0.9 0.9 0.9 Trihydroxystearin (Thixcin R) 2.0 2.0 2.0 Guar Hydroxypropyltrimonium Chloride 0.17 0.75 0.75 T
e 3196 from Aqualon) (N-Hanc Guar Hydroxypropyltrimonium Chloride 0.58 - -(Jaguar C-17 from Rhodia) Polyquaterium 10 0.45 - -TM
(UCARE polymer JR-30M from Amerchol) Polymethacrylamidopropyltrimonium Chloride - 0.24 -(Polycare 133 from Rhodia) Polyquaternium-39 - 0.81 -(Merqurt Plus 3300 from Calgon ) PEG 90M (PolyoxTM WSR 301 from Union 0.25 - -Carbide) PEG-14M (Polyox WSR N-3000 H from Union 0.45 2.45 2.45 Carbide) Linoleamidoprypyl PG-Dimonium Chloride - 1.0 4.0 Phosphate Dimethicone TM
(Monasil PLN from Uniqema) Glycerin 1.4 4.9 4.9 Sodium Chloride 0.3 0.3 0.3 Sodium Benzoate 0.25 0.25 0.25 Disodium EDTA 0.13 0.13 0.13 Glydant 0.37 0.37 0.37 Citric Acid 1.6 0.95 0.95 Titanium Dioxide 0.5 0.5 0.5 Perfume 0.5 0.5 0.5 Water Q.S. Q.S. Q.S.
II. Benefit Composition Petrolatum 80 80 80 PEG-30 Dipolyhydroxystearate (Arlacel TM P135) 1 1 I
Water 19 19 19 The cleansing phase and benefit phase compositions described above can be prepared by conventional formulation and mixing techniques. The cleansing composition 1 can be prepared by first creating the following premixes: citric acid in water premix at 1:3 ratio, Guar polymer premix with Jaguar C-17 and N-Hance 3196 in water at 1:10 ratio, UCARE premix with JR-30M
in water at about 1:30 ratio, and Polyox premix with PEG-90M and PEG-14M in Glycerin at about 1:2 ratio. Then, the following ingredients will be added into the main mixing vessel:
ammonium lauryl sulfate, ammonium laureth-3 sulfate, citric acid premix, Miranol L-32 ultra, TM
sodium chloride, sodium benzoate, disodium EDTA, lauric acid, Thixcin R, Guar premix, TM
UCARE premix, Polyox Premix, and the rest of water. Then one will heat the vessel with agitation until it reaches 190 F (88 C). Let it mix for about 10 min. Cool the batch with a cold water bath with slow agitation until it reaches 110 F (43 C). Add the following ingredients:
Glydant, perfume, Titanium Dioxide. Mix until a homogeneous solution forms.
The cleansing composition 2 can be prepared by first creating the following premixes:
citric acid in water premix at 1:3 ratio, Guar polymer premix with N-Hance 3196 in water at 1:10 ratio, and Polyox premix with PEG-14M in Glycerin at about 1:2 ratio. Then, the following ingredients will be added into the main mixing vessel: ammonium lauryl sulfate, ammonium laureth-3 sulfate, citric acid premix, Miranol L-32 ultra, sodium chloride, sodium benzoate, TM
disodium EDTA, lauric acid, Thixcin R, Guar premix, Polyox Premix, Polycare 133, Merquat Plus 3300, Monosil PLN, and the rest of water. Then, the vessel will be heated with agitation until it reaches 190 F (88 C). Let it mix for about 10 min. Next, the batch will be cooled with a cold water bath with slow agitation until it reaches I10 F (43 C). Finally, the following ingredients will be added: Glydant, perfume, Titanium Dioxide and mixed until a homogeneous solution forms.
The cleansing composition 3 can be prepared by first creating the following premixes:
citric acid in water premix at 1:3 ratio, Guar polymer premix with N-Hance 3196 in water at 1:10 ratio, and Polyox premix with PEG-14M in Glycerin at about 1:2 ratio. Then, the following ingredients will be added into the main mixing vessel: ammonium lauryl sulfate, ammonium laureth-3 sulfate, citric acid premix, Miranol L-32 ultra, sodium chloride, sodium benzoate, disodium EDTA, lauric acid, Thixcin R, Guar premix, Polyox Premix, Monasil PLN, and the rest of water. Then the vessel will be heated with agitation until it reaches 190 F
(88 C). The vessel will be mixed for about 10 min. Next, the batch will be cooled with a cold water bath with slow agitation until it reaches 110 F (43 C). Finally, the following ingredients will be added: Glydant, perfume, Titanium Dioxide and mixed until a homogeneous solution forms.
Benefit phase The benefit phase can be prepared by adding Petrolatum into the main mixing vessel.
Then, the vessel will be heated to 185 F and add Arlacel P135. Then, slowly add water with agitation. Keep agitating until homogeneous.
The cleansing and benefit phases are packaged into a single container by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product. The sample stage spins the bottle during the filling process to create a striped appearance.
Examples 4-6 The following examples described in Table 2 are non-limiting examples of the personal cleaning compositions herein. Table 2: Cleansing Phase and Benefit phase Compositions Example 4 Example 5 Example 6 Ingredient wt% wt% wt%
1. Cleansing Phase Composition MiracareTM SLB-365 (From Rhodia) 47.4 47.4 47.4 (Sodium Trideceth Sulfate, Sodium Lauramphoacetate, Cocamide MEA) Guar Hydroxypropyltrimonium Chloride - 0.7 (N-Hance 3196 from Aqualon) PEG 90M (PolyoxTM WSR 301 from Dow - - 0.2 Chemical) Cocamide MEA 3.0 - -Polycare 133 - - 0.4 Lauric Acid - 2.0 2.0 Sodium Chloride 3.5 3.5 3.5 Disodium EDTA 0.05 0.05 0.05 Glydant 0.67 0.67 0.67 Citric Acid 0.4 0.4 0.4 Perfume 2.0 2.0 2.0 Water Q.S. Q.S. Q.S.
(pH) (6.0) (6.0) (6.0) U. Benefit phase Composition Petrolatum 80 80 80 PEG-30 Dipolyhydroxystearate (Arlacel P135) 1 1 1 Water 19 19 19 The compositions described above can be prepared by conventional formulation and mixing techniques. The cleansing phase composition can be prepared by first adding citric acid into water at 1:3 ratios to form a citric acid premix. The following ingredients will then be added into the main mixing vessel in the following sequence: water, Miracare SLB-354, sodium chloride, sodium benzoate, Disodium EDTA, glydant. The main mixing vessel will start to be agitated. In a separate mixing vessel, disperse polymers (Polyquaterium 10, Jaguar C-17, or N-Hance 3196) in water at 1:10 ratio will form a polymer premix. The completely dispersed polymer premix will be added into the main mixing vessel with continuous agitation. Polyox WSR 301 will be dispersed in water and then added to the main mixing vessel.
Then, the rest of the water and perfume will be added into the batch. The batch will be kept agitating until a homogenous solution forms.
Benefit-phase The benefit phase can be prepared by adding Petrolatum into the main mixing vessel.
TM
Then, the vessel will be heated to 185F and add Arlacel P135. Then, slowly add water with agitation. Keep agitating until homogeneous.
The cleansing and benefit phases are packaged into a single container by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product.. The sample stage spins the bottle during filling process to create a striped appearance.
Examples 7-9 The following examples described in Table 3 are non-limiting examples of the personal cleaning compositions herein. Table 3: Cleansing Phase and Benefit phase Compositions Example 7 Example 8 Example 9 Ingredient wt% wt% wt%
1. Cleansing Phase Composition Miracare SLB-365 (from Rhodia) 47.4 47.4 47.4 (Sodium Trideceth Sulfate, Sodium Lauramphoacetate, Cocamide MEA) Sodium Chloride 3.5 3.5 3.5 Disodium EDTA 0.05 0.05 0.05 Glydant 0.67 0.67 0.67 - -Citric Acid 0.4 0.4 0.4 Perfume 2.0 2.0 2.0 Water Q.S. Q.S. Q.S.
(pH) (6.0) (6.0) (6.0) II. Benefit phase Composition Petrolatum 80 80 80 PEG-30 Dipolyhydroxystearate (Arlacel P135) 1 1 1 Water 19 19 19 The compositions described above can be prepared by conventional formulation and mixing techniques. The cleansing phase composition can be prepared by first adding citric acid into water at 1:3 ratio to form a citric acid premix. The following ingredients will be added into the main mixing vessel in the following sequence: water, Miracare SLB-354, sodium chloride, sodium benzoate, Disodium EDTA, glydant. The main mixing vessel will start to be agitated.
Then, perfume will be added into the batch. The batch will be kept agitating until a homogenous solution forms.
Benefit phase The benefit phase can be prepared by adding Petrolatum into the main mixing vessel.
Then, the vessel will be heated to 185F and add Arlacel P135. Then, slowly add water with agitation. Keep agitating until homogeneous.
The cleansing and benefit phases are packaged into a single container by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product. The sample stage spins the bottle during the filling process to create a striped appearance.
Non-limiting examples of diglycerides and triglycerides suitable for use herein include castor oil, soy bean oil, derivatized soybean oils such as maleated soy bean oil, safflower oil, cotton seed oil, corn oil, walnut oil, peanut oil, olive oil, cod liver oil, almond oil, avocado oil, palm oil and sesame oil, vegetable oils, sunflower seed oil, and vegetable oil derivatives; coconut oil and derivatized coconut oil, cottonseed oil and derivatized cottonseed oil, jojoba oil, cocoa butter, and combinations thereof. In addition any of the above oils that have been partially or fully hydrogenated are also suitable.
Non-limiting examples of acetoglyceride esters suitable for use herein include acetylated monoglycerides.
Non-limiting examples of alkyl esters suitable for use herein include isopropyl esters of fatty acids and long chain esters of long chain fatty acids, e.g. SEFA
(sucrose esters of fatty acids). Lauryl pyrolidone carboxylic acid, pentaerthritol esters, aromatic mono, di or triesters, cetyl ricinoleate, non-limiting examples of which include isopropyl palmitate, isopropyl myristate, cetyl riconoleate and stearyl riconoleate. Other examples are:
hexyl laurate, isohexyl laurate, myristyl myristate, isohexyl palmitate, decyl oleate, isodecyl oleate, hexadecyl stearate, decyl stearate, isopropyl isostearate, diisopropyl adipate, diisohexyl adipate, dihexyldecyl adipate, diisopropyl sebacate, acyl isononanoate lauryl lactate, myristyl lactate, cetyl lactate, and combinations thereof.
Non-limiting examples of alkenyl esters suitable for use herein include oleyl myristate, oleyl stearate, oleyl oleate, and combinations thereof.
Non-limiting examples of lanolin and lanolin derivatives suitable for use herein include lanolin, lanolin oil, lanolin wax, lanolin alcohols, lanolin fatty acids, isopropyl lanolate, acetylated lanolin, acetylated lanolin alcohols, lanolin alcohol linoleate, lanolin alcohol riconoleate, hydroxylated lanolin, hydrogenated lanolin and combinations thereof.
Still other suitable oils include milk triglycerides (e.g., hydroxylated milk glyceride) and polyol fatty acid polyesters.
Still other suitable oils include wax esters, non-limiting examples of which include beeswax and beeswax derivatives, spermaceti, myristyl myristate, stearyl stearate, and combinations thereof. Also useful are vegetable waxes such as carnauba and candelilla waxes;
sterols such as cholesterol, cholesterol fatty acid esters; and phospholipids such as lecithin and derivatives, sphingo lipids, ceramides, glycosphingo lipids, and combinations thereof.
Low HLB Emulsifier The water-in-oil emulsion of the present invention also includes about 0.1% to about 20% of a low HLB emulsifier, more preferably from about 0.1% to about 10%, still more preferably from about 0.5% to about 9%, of one or more low HLB
emulsifier. The low HLB emulsifier may function as an emulsifier Preferred low HLB emulsifiers are those having an HLB of from about 1 to about 10, more preferably from 1 to about 8. Suitable low HLB emulsifiers are those selected from saturated C14 to C30 fatty alcohols, saturated C16 to C30 fatty alcohols containing from about 1 to about 5 moles of ethylene oxide, saturated C16 to C30 diols, saturated C16 to C30 monoglycerol ethers, saturated C16 to C30 hydroxy fatty acids, C14 to C30 hydroxylated and nonhydroxylated saturated fatty acids, C14 to C30 saturated ethoxylated fatty acids, amines and alcohols containing from about 1 to about 5 moles of ethylene oxide diols, C14 to C30 saturated glyceryl mono esters with a monoglyceride content of at least 40%, C14 to C30 saturated polyglycerol esters having from about 1 to about 3 alkyl group and from about 2 to about 3 saturated glycerol units, C14 to C30 glyceryl mono ethers, C14 to C30 sorbitan mono/diesters, C14 to C30 saturated ethoxylated sorbitan mono/diesters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated methyl glucoside esters, C14 to C30 saturated sucrose mono/diesters, C14 to C30 saturated ethoxylated methyl glucoside esters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated polyglucosides having an average of between 1 to 2 glucose units and mixtures thereof, having a melting point of at least about 45 C.
The low HLB emulsifiers of the present invention are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, stearic acid, palmitic acid, the polyethylene glycol ether of stearyl alcohol having an average of about 1 to about 5 ethylene oxide units, the polyethylene glycol ether of cetyl alcohol having an average of about 1 to about 5 ethylene oxide units, and mixtures thereof. More preferred low HLB emulsifiers of the present invention are selected from stearyl alcohol, cetyl alcohol, behenyl alcohol, the polyethylene glycol ether of stearyl alcohol having an average of about 2 ethylene oxide units (steareth-2), the polyethylene glycol ether of cetyl alcohol having an average of about 2 ethylene oxide units, and mixtures thereof. Even more preferred low HLB emulsifiers are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, steareth-2, and mixtures thereof.
Density Modifiers To further improve stability under stress conditions such as high temperature and vibration, it is preferable to adjust the densities of the separate phases such that they are substantially equal. To achieve this, low density microspheres are added to the cleansing phase of the striped composition. The low density microspheres employed to reduce the overall density of the cleansing phase are particles having a density lower than 0.7 g/cm3, preferably less than 0.2 g/cm3, more preferably less than 0.1 g/cm3, most preferably less than 0.05 g/cm3. The low density microspheres generally have a diameter less than 200 m, preferably less than 100 gm, most preferably less than 40 m. Preferably, the density difference between the cleansing phase and the benefit phase is less than 0.15 g/cm3, more preferably, the density difference is less than 0.10 g/cm3, even more preferably, the density difference is less than 0.05g/cm3, most preferably, the density difference is less than 0.01 g/cm3.
The microspheres are produced from any appropriate inorganic or organic material, compatible with a use on the skin, that is, nonirritating and nontoxic.
Expanded microspheres made of thermoplastic material are known, and may be obtained, for example, according to the processes described in Patents and Patent Applications EP-56219, EP-348372, EP-486080, EP-320473, EP-112807 and U.S. Pat. No. 3,615,972.
These microspheres may be produced from any nontoxic and non-irritant thermoplastic materials. Polymers or copolymers of acrylonitrile or of vinylidene chloride may be used, for example. It is possible to use, for example, a copolymer containing, by weight, from 0 to 60% of units derived from vinylidene chloride, from 20 to 90% of units derived from acrylonitrile and from 0 to 50% of units derived from an acrylic or styrene monomer, the sum of the percentages (by weight) being equal to 100. The acrylic monomer is, for example, a methyl or ethyl acrylate or methacrylate. The styrene monomer is, for example, alpha-methylstyrene or styrene. These microspheres can be in the dry or hydrated state.
The internal cavity of expanded hollow microspheres contains a gas, which can be a hydrocarbon such as isobutane or isopentane or alternatively air. Among hollow microspheres which can be used, special mention may be made of those marketed under the brand name EXPANCEL (thermoplastic expandable microspheres) by the Akzo Nobel Company, especially those of DE (dry state) or WE (hydrated state) grade. Examples include:
Expancel 091 DE 40 d30; Expancel 091 DE 80 d30; Expancel 051 DE 40 d60; Expancel 091 WE 40 d24;
Expancel 053 DE 40 d20.
Representative microspheres derived from an inorganic material, include, for instance, "Qcel Hollow Microspheres" and "EXTENDOSPHERESTM Ceramic Hollow Spheres", both available from the PQ Corporation. Examples are: Qcel 300; Qcel 6019; Qcel 6042S.
Just as low density microspheres can be added to the cleansing phase of the present invention to improve vibrational stability, high density materials can be added to the benefit phase to increase its density having the same impact on stability.
Aqueous Phase The benefit phase of the present invention typically comprises from about 1%
to about 90% of an aqueous phase. The aqueous phase comprises a fluid selected from the group consisting of water, mono- and polyhydric alcohols (glycerin, propylene glycol, ethanol, isopropanol, etc.).
Optional Ingredients The personal cleansing compositions of the present invention may further comprise other optional ingredients that may modify the physical, chemical, cosmetic or aesthetic characteristics of the compositions or serve as additional "active" components when deposited on the skin. The compositions may also further comprise optional inert ingredients. Many such optional ingredients are known for use in personal care compositions, and may also be used in the personal cleansing compositions herein, provided that such optional materials are compatible with the essential materials described herein, or do not otherwise unduly impair product performance.
Such optional ingredients are most typically those materials approved for use in cosmetics and that are described in reference books such as the CTFA Cosmetic Ingredient Handbook, Second Edition, The Cosmetic, Toiletries, and Fragrance Association, Inc.
1988, 1992. These optional materials can be used in any aspect of the compositions of the present invention, including either of the active or cleansing phases as described herein.
Optional ingredients for use in the cleansing phase of the compositions of the present invention can include any benefit phase material as described herein that is also compatible with the selected ingredients in the cleansing phase. Likewise, optional ingredients for use in the benefit phase of the compositions of the present invention can include any cleansing phase material described herein that is also compatible with the selected ingredients in the benefit phase.
Other optional ingredients for use in either phase of the composition, preferably the benefit phase, include silicone elastomer powders and fluids to provide any of a variety of product benefits, including improved product stability, application cosmetics, emolliency, conditioning, and so forth. The concentration of the silicone elastomers in the composition preferably ranges from about 0.1% to about 20%, more preferably from about 0.5% to about 10%, by weight of the composition. In this context, the weight percentages are based upon the weight of the silicone elastomers material itself, excluding any silicone-containing fluid that typically accompanies such silicone elastomers materials in the formulation process. The silicone elastomers suitable for optional use herein include emulsifying and non-emulsifying silicone elastomers, non-limiting examples of which are described in U.S. patent application serial number 09/613,266 (assigned to The Procter & Gamble Company).
The separate benefit phase of the striped liquid personal cleansing compositions may optionally comprise the following skin benefit ingredients for enhanced delivery of these water in oil emulsion materials on skin. Non limiting examples of these optional ingredients include vitamins and derivatives thereof (e.g., ascorbic acid, vitamin E, tocopheryl acetate, and the like);
sunscreens; thickening agents (e.g., polyol alkoxy ester, available as Crothixmfrom Croda);
preservatives for maintaining the anti microbial integrity of the cleansing compositions; anti-acne medicaments (resorcinol, salicylic acid, and the like); antioxidants; skin soothing and healing agents such as aloe vera extract, allantoin and the like; chelators and sequestrants; and agents suitable for aesthetic purposes such as fragrances, essential oils, skin sensates, pigments, pearlescent agents (e.g., mica and titanium dioxide), lakes, colorings, and the like (e.g., clove oil, menthol, camphor, eucalyptus oil, and eugenol).
Method of Use The striped personal cleansing compositions of the present invention are preferably applied topically to the desired area of the skin or hair in an amount sufficient to provide effective delivery of the skin conditioning agent to the applied surface, or to otherwise provide effective skin conditioning benefits. The compositions can be applied directly to the skin or indirectly via the use of a cleansing puff, washcloth, sponge or other implement. The compositions are preferably diluted with water prior to, during, or after topical application, and then subsequently rinsed or wiped off of the applied surface, preferably rinsed off of the applied surface using water or a water-insoluble substrate in combination with water.
Method of Manufacture The personal cleansing compositions of the present invention may be prepared by any known or otherwise effective technique, suitable for making and formulating the desired striped product form. It is effective to combine toothpaste-tube filling technology with a spinning stage design. Additionally, the present invention can be prepared by the method and apparatus as disclosed in U.S. patent 6,213,166, The method and apparatus allows two or more compositions to be filled with a spiral configuration into a single container.
The method requires that at least two nozzles be employed to fill the container. The container is placed on a static mixer and spun as the composition is introduced into the container.
Alternatively, it is especially effective to combine at least two phases by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product. Specific non-limiting examples of such methods as they are applied to specific embodiments of the present invention are described in the following examples.
If the personal cleansing compositions contain stripes of varying colors it may be desirable to package these compositions in a transparent package such that the consumer can view the pattern through the package. Because of the viscosity of the subject compositions it may also be desirable to include instructions to the consumer to store the package upside down, on its cap to facilitate dispensing.
Analytical Methods Lather Volume Lather volume of a striped liquid personal cleansing composition is measured using a graduated cylinder and a tumbling apparatus. A 1,000 ml graduated cylinder is chosen which is marked in 10 ml increments and has a height of 14.5 inches at the 1,000 ml mark from the inside of its base (for example, Pyrex No. 2982). Distilled water (100 grams at 23 C) is added to the graduated cylinder. The cylinder is clamped in a rotating device, which clamps the cylinder with an axis of rotation that transects the center of the graduated cylinder. One gram of the total personal cleansing composition (0.5g of the cleansing phase and 0.5g of the benefit phase when measuring the total product, or 1 g of the cleansing phase when the measuring the cleansing phase only) is added into the graduated cylinder and the cylinder is capped. The cylinder is rotated at a rate of 10 revolutions in about 20 seconds, and stopped in a vertical position to complete the first rotation sequence. A timer is set to allow 30 seconds for the lather thus generated to drain. After 30 seconds of such drainage, the first lather volume is measured to the nearest 10 ml mark by recording the lather height in ml up from the base (including any water that has drained to the bottom on top of which the lather is floating).
If the top surface of the lather is uneven, the lowest height at which it is possible to see halfway across the graduated cylinder is the first lather volume (ml). If the lather is so coarse that a single or only a few foam cells ("bubbles") reach across the entire cylinder, the height at which at least 10 foam cells are required to fill the space is the first lather volume, also in ml up from the base. Foam cells larger than one inch in any dimension, no matter where they occur, are designated as unfilled air instead of lather. Foam that collects on the top of the graduated cylinder but does not drain is also incorporated in the measurement if the foam on the top is in its own continuous layer, by adding the ml of foam collected there using a ruler to measure thickness of the layer, to the ml of foam measured up from the base. The maximum foam height is 1,000 ml (even if the total foam height exceeds the 1,000 ml mark on the graduated cylinder). One minute after the first rotation is completed, a second rotation sequence is commenced which is identical in speed and duration to the first rotation sequence. The second lather volume is recorded in the same manner as the first, after the same 30 seconds of drainage time. A third sequence is completed and the third lather volume is measured in the same manner, with the same pause between each for drainage and taking the measurement.
The lather result after each sequence is added together and the Total Lather Volume determined as the sum of the three measurements, in ml. The Flash Lather Volume is the result after the first rotation sequence only, in ml, i.e., the first lather volume.
Compositions according to the present invention perform significantly better in this test than similar compositions in conventional emulsion form.
Viscosity of the Liquid Personal Cleansing Composition TM
The Wells-Brookfield Cone/Plate Model DV-11+ Viscometer can be used to determine the viscosity of the liquid personal cleansing compositions herein. The determination is performed at 25 C with the 2.4cm cone measuring system with a gap of 0.013mm between the two small pins on the respective cone and plate. The measurement is performed by injecting 0.5m1 of the sample, to be analyzed, between the cone and plate and, then, rotating the cone at a set speed of I
rpm. The resistance to the rotation of the cone produces a torque that is proportional to the shear stress of the liquid sample. The amount of torque is read 2 minutes after loading the sample and computed by the viscometer into absolute centipoise units (mPa*s) based on the geometric constant of the cone, the rate of rotation, and the stress related torque.
Yield Point of Liquid Personal Cleansing Composition TM
The Carrimed CSL 100 Controlled Stress Rheometer can be used to determine the yield point of the liquid personal cleansing compositions. For purpose herein, the yield point is the amount of stress required to produce a strain of 1% on the liquid personal cleansing composition.
The determination is performed at 77F with the 4cm 2 cone measuring system set with a 51 micron gap. The determination is performed via the programmed application of a shear stress (typically from about 0.06 dynes/sq. centimeter to about 500 dynes/sq.
centimeter) over time interval of 5 minutes. It is this amount of stress that results in a deformation of the sample, a shear stress vs. strain curve can be created. From this curve, the yield point of the liquid personal cleansing composition can be calculated.
EXAMPLES
The following examples further describe and demonstrate embodiments within the scope of the present invention. The examples are given solely for the purpose of illustration and are not to be construed as limitations of the present invention, as many variations thereof are possible without departing from the spirit and scope of the invention. All exemplified amounts are concentrations by weight of the total composition, i.e., wt/wt percentages, unless otherwise specified.
Each of the exemplified compositions provides improved deposition or effectiveness of the skin conditioning agents or optional ingredients delivered from each prepared composition.
Examples 1-3.
The following examples described in Table 1 are non-limiting examples of the personal cleaning compositions herein.
Table 1: Cleansing Phase and Benefit phase Compositions Example 1 Example 2 Example 3 Ingredient wt% wt% Wt%
1. Cleansing Phase Composition Ammonium Laureth-3 Sulfate 3.0 3.0 3.0 Sodium Lauroamphoacetate 16.7 16.7 16.7 TV
(Miranol L-32 Ultra from Rhodia) Ammonium Lauryl Sulfate 1.0 1.0 1.0 Lauric Acid 0.9 0.9 0.9 Trihydroxystearin (Thixcin R) 2.0 2.0 2.0 Guar Hydroxypropyltrimonium Chloride 0.17 0.75 0.75 T
e 3196 from Aqualon) (N-Hanc Guar Hydroxypropyltrimonium Chloride 0.58 - -(Jaguar C-17 from Rhodia) Polyquaterium 10 0.45 - -TM
(UCARE polymer JR-30M from Amerchol) Polymethacrylamidopropyltrimonium Chloride - 0.24 -(Polycare 133 from Rhodia) Polyquaternium-39 - 0.81 -(Merqurt Plus 3300 from Calgon ) PEG 90M (PolyoxTM WSR 301 from Union 0.25 - -Carbide) PEG-14M (Polyox WSR N-3000 H from Union 0.45 2.45 2.45 Carbide) Linoleamidoprypyl PG-Dimonium Chloride - 1.0 4.0 Phosphate Dimethicone TM
(Monasil PLN from Uniqema) Glycerin 1.4 4.9 4.9 Sodium Chloride 0.3 0.3 0.3 Sodium Benzoate 0.25 0.25 0.25 Disodium EDTA 0.13 0.13 0.13 Glydant 0.37 0.37 0.37 Citric Acid 1.6 0.95 0.95 Titanium Dioxide 0.5 0.5 0.5 Perfume 0.5 0.5 0.5 Water Q.S. Q.S. Q.S.
II. Benefit Composition Petrolatum 80 80 80 PEG-30 Dipolyhydroxystearate (Arlacel TM P135) 1 1 I
Water 19 19 19 The cleansing phase and benefit phase compositions described above can be prepared by conventional formulation and mixing techniques. The cleansing composition 1 can be prepared by first creating the following premixes: citric acid in water premix at 1:3 ratio, Guar polymer premix with Jaguar C-17 and N-Hance 3196 in water at 1:10 ratio, UCARE premix with JR-30M
in water at about 1:30 ratio, and Polyox premix with PEG-90M and PEG-14M in Glycerin at about 1:2 ratio. Then, the following ingredients will be added into the main mixing vessel:
ammonium lauryl sulfate, ammonium laureth-3 sulfate, citric acid premix, Miranol L-32 ultra, TM
sodium chloride, sodium benzoate, disodium EDTA, lauric acid, Thixcin R, Guar premix, TM
UCARE premix, Polyox Premix, and the rest of water. Then one will heat the vessel with agitation until it reaches 190 F (88 C). Let it mix for about 10 min. Cool the batch with a cold water bath with slow agitation until it reaches 110 F (43 C). Add the following ingredients:
Glydant, perfume, Titanium Dioxide. Mix until a homogeneous solution forms.
The cleansing composition 2 can be prepared by first creating the following premixes:
citric acid in water premix at 1:3 ratio, Guar polymer premix with N-Hance 3196 in water at 1:10 ratio, and Polyox premix with PEG-14M in Glycerin at about 1:2 ratio. Then, the following ingredients will be added into the main mixing vessel: ammonium lauryl sulfate, ammonium laureth-3 sulfate, citric acid premix, Miranol L-32 ultra, sodium chloride, sodium benzoate, TM
disodium EDTA, lauric acid, Thixcin R, Guar premix, Polyox Premix, Polycare 133, Merquat Plus 3300, Monosil PLN, and the rest of water. Then, the vessel will be heated with agitation until it reaches 190 F (88 C). Let it mix for about 10 min. Next, the batch will be cooled with a cold water bath with slow agitation until it reaches I10 F (43 C). Finally, the following ingredients will be added: Glydant, perfume, Titanium Dioxide and mixed until a homogeneous solution forms.
The cleansing composition 3 can be prepared by first creating the following premixes:
citric acid in water premix at 1:3 ratio, Guar polymer premix with N-Hance 3196 in water at 1:10 ratio, and Polyox premix with PEG-14M in Glycerin at about 1:2 ratio. Then, the following ingredients will be added into the main mixing vessel: ammonium lauryl sulfate, ammonium laureth-3 sulfate, citric acid premix, Miranol L-32 ultra, sodium chloride, sodium benzoate, disodium EDTA, lauric acid, Thixcin R, Guar premix, Polyox Premix, Monasil PLN, and the rest of water. Then the vessel will be heated with agitation until it reaches 190 F
(88 C). The vessel will be mixed for about 10 min. Next, the batch will be cooled with a cold water bath with slow agitation until it reaches 110 F (43 C). Finally, the following ingredients will be added: Glydant, perfume, Titanium Dioxide and mixed until a homogeneous solution forms.
Benefit phase The benefit phase can be prepared by adding Petrolatum into the main mixing vessel.
Then, the vessel will be heated to 185 F and add Arlacel P135. Then, slowly add water with agitation. Keep agitating until homogeneous.
The cleansing and benefit phases are packaged into a single container by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product. The sample stage spins the bottle during the filling process to create a striped appearance.
Examples 4-6 The following examples described in Table 2 are non-limiting examples of the personal cleaning compositions herein. Table 2: Cleansing Phase and Benefit phase Compositions Example 4 Example 5 Example 6 Ingredient wt% wt% wt%
1. Cleansing Phase Composition MiracareTM SLB-365 (From Rhodia) 47.4 47.4 47.4 (Sodium Trideceth Sulfate, Sodium Lauramphoacetate, Cocamide MEA) Guar Hydroxypropyltrimonium Chloride - 0.7 (N-Hance 3196 from Aqualon) PEG 90M (PolyoxTM WSR 301 from Dow - - 0.2 Chemical) Cocamide MEA 3.0 - -Polycare 133 - - 0.4 Lauric Acid - 2.0 2.0 Sodium Chloride 3.5 3.5 3.5 Disodium EDTA 0.05 0.05 0.05 Glydant 0.67 0.67 0.67 Citric Acid 0.4 0.4 0.4 Perfume 2.0 2.0 2.0 Water Q.S. Q.S. Q.S.
(pH) (6.0) (6.0) (6.0) U. Benefit phase Composition Petrolatum 80 80 80 PEG-30 Dipolyhydroxystearate (Arlacel P135) 1 1 1 Water 19 19 19 The compositions described above can be prepared by conventional formulation and mixing techniques. The cleansing phase composition can be prepared by first adding citric acid into water at 1:3 ratios to form a citric acid premix. The following ingredients will then be added into the main mixing vessel in the following sequence: water, Miracare SLB-354, sodium chloride, sodium benzoate, Disodium EDTA, glydant. The main mixing vessel will start to be agitated. In a separate mixing vessel, disperse polymers (Polyquaterium 10, Jaguar C-17, or N-Hance 3196) in water at 1:10 ratio will form a polymer premix. The completely dispersed polymer premix will be added into the main mixing vessel with continuous agitation. Polyox WSR 301 will be dispersed in water and then added to the main mixing vessel.
Then, the rest of the water and perfume will be added into the batch. The batch will be kept agitating until a homogenous solution forms.
Benefit-phase The benefit phase can be prepared by adding Petrolatum into the main mixing vessel.
TM
Then, the vessel will be heated to 185F and add Arlacel P135. Then, slowly add water with agitation. Keep agitating until homogeneous.
The cleansing and benefit phases are packaged into a single container by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product.. The sample stage spins the bottle during filling process to create a striped appearance.
Examples 7-9 The following examples described in Table 3 are non-limiting examples of the personal cleaning compositions herein. Table 3: Cleansing Phase and Benefit phase Compositions Example 7 Example 8 Example 9 Ingredient wt% wt% wt%
1. Cleansing Phase Composition Miracare SLB-365 (from Rhodia) 47.4 47.4 47.4 (Sodium Trideceth Sulfate, Sodium Lauramphoacetate, Cocamide MEA) Sodium Chloride 3.5 3.5 3.5 Disodium EDTA 0.05 0.05 0.05 Glydant 0.67 0.67 0.67 - -Citric Acid 0.4 0.4 0.4 Perfume 2.0 2.0 2.0 Water Q.S. Q.S. Q.S.
(pH) (6.0) (6.0) (6.0) II. Benefit phase Composition Petrolatum 80 80 80 PEG-30 Dipolyhydroxystearate (Arlacel P135) 1 1 1 Water 19 19 19 The compositions described above can be prepared by conventional formulation and mixing techniques. The cleansing phase composition can be prepared by first adding citric acid into water at 1:3 ratio to form a citric acid premix. The following ingredients will be added into the main mixing vessel in the following sequence: water, Miracare SLB-354, sodium chloride, sodium benzoate, Disodium EDTA, glydant. The main mixing vessel will start to be agitated.
Then, perfume will be added into the batch. The batch will be kept agitating until a homogenous solution forms.
Benefit phase The benefit phase can be prepared by adding Petrolatum into the main mixing vessel.
Then, the vessel will be heated to 185F and add Arlacel P135. Then, slowly add water with agitation. Keep agitating until homogeneous.
The cleansing and benefit phases are packaged into a single container by first placing the separate compositions in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section.
Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases.
The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product. The sample stage spins the bottle during the filling process to create a striped appearance.
Claims (20)
1. A personal care article comprising a package containing a liquid striped personal cleansing composition comprising:
a) a first stripe comprising a cleansing phase comprising from about 1% to about 50%, by weight of the cleansing phase, of a surfactant selected from the group consisting of anionic surfactant, non-ionic surfactant, zwitterionic surfactant, cationic surfactant, soap, and mixtures thereof and a cationic deposition polymer;
wherein the cleansing phase is non-Newtonian shear thinning, has a viscosity of equal to or greater than about 3,000 centipoise and a yield point of at least about 0.1 Pascal; and b) at least one additional stripe comprising a benefit phase comprising a water in oil emulsion comprising an oil, a low HLB emulsifier having an HLB
below 10, and water; and wherein the cleansing phase and the benefit phase are in physical contact with one another within said package.
a) a first stripe comprising a cleansing phase comprising from about 1% to about 50%, by weight of the cleansing phase, of a surfactant selected from the group consisting of anionic surfactant, non-ionic surfactant, zwitterionic surfactant, cationic surfactant, soap, and mixtures thereof and a cationic deposition polymer;
wherein the cleansing phase is non-Newtonian shear thinning, has a viscosity of equal to or greater than about 3,000 centipoise and a yield point of at least about 0.1 Pascal; and b) at least one additional stripe comprising a benefit phase comprising a water in oil emulsion comprising an oil, a low HLB emulsifier having an HLB
below 10, and water; and wherein the cleansing phase and the benefit phase are in physical contact with one another within said package.
2. A personal cleansing article according to claim 1, wherein the cleansing phase comprises:
(i) at least one anionic surfactant;
(ii) at least one electrolyte;
(iii) at least one amphoteric surfactant; and (iv) water.
(i) at least one anionic surfactant;
(ii) at least one electrolyte;
(iii) at least one amphoteric surfactant; and (iv) water.
3. A personal cleansing article according to claim 2, wherein said cleansing phase comprises from about 3% to about 50%, by weight of the cleansing phase, of the at least one anionic surfactant and the at least one amphoteric surfactant.
4. A personal cleansing article according to claim 2, wherein the electrolyte comprises:
i) an anion selected from the group consisting of phosphate, chloride, sulfate, citrate, and mixtures thereof, and ii) a cation selected from the group consisting of sodium, ammonium, potassium, magnesium, and mixtures thereof; and wherein the electrolyte is present at a level of from about 0.1% to about 15% by weight of the cleansing phase.
i) an anion selected from the group consisting of phosphate, chloride, sulfate, citrate, and mixtures thereof, and ii) a cation selected from the group consisting of sodium, ammonium, potassium, magnesium, and mixtures thereof; and wherein the electrolyte is present at a level of from about 0.1% to about 15% by weight of the cleansing phase.
5. A personal cleansing article according to claim 1, wherein said benefit phase comprises from about 0.5% to about 9%, by weight of said benefit phase, of the low HLB emulsifier.
6. A personal cleansing article according to claim 1, wherein the low HLB
emulsifier comprises an HLB of below 8.
emulsifier comprises an HLB of below 8.
7. A personal cleansing article according to claim 1, wherein said low HLB
emulsifier is selected from the group of materials having a melting point of at least about 45°C consisting of saturated C14 to C30 fatty alcohols, saturated C16 to C30 fatty alcohols containing from about 1 to about 5 moles of ethylene oxide, saturated C16 to C30 diols, saturated C16 to C30 monoglycerol ethers, saturated C16 to C30 hydroxy fatty acids, C14 to C30 hydroxylated and nonhydroxylated saturated fatty acids, C14 to C30 saturated ethoxylated fatty acids, amines and alcohols containing from about 1 to about 5 moles of ethylene oxide diols, C14 to C30 saturated glyceryl mono esters with a monoglyceride content of at least 40%
by weight, C14 to C30 saturated polyglycerol esters having from about 1 to about 3 alkyl group and from about 2 to about 3 saturated glycerol units, C14 to C30 glyceryl mono ethers, C14 to C30 sorbitan mono/diesters, C14 to C30 saturated ethoxylated sorbitan mono/diesters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated methyl glucoside esters, C14 to C30 saturated sucrose mono/diesters, C14 to C30 saturated ethoxylated methyl glucoside esters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated polyglucosides having an average of between 1 to 2 glucose units and mixtures thereof.
emulsifier is selected from the group of materials having a melting point of at least about 45°C consisting of saturated C14 to C30 fatty alcohols, saturated C16 to C30 fatty alcohols containing from about 1 to about 5 moles of ethylene oxide, saturated C16 to C30 diols, saturated C16 to C30 monoglycerol ethers, saturated C16 to C30 hydroxy fatty acids, C14 to C30 hydroxylated and nonhydroxylated saturated fatty acids, C14 to C30 saturated ethoxylated fatty acids, amines and alcohols containing from about 1 to about 5 moles of ethylene oxide diols, C14 to C30 saturated glyceryl mono esters with a monoglyceride content of at least 40%
by weight, C14 to C30 saturated polyglycerol esters having from about 1 to about 3 alkyl group and from about 2 to about 3 saturated glycerol units, C14 to C30 glyceryl mono ethers, C14 to C30 sorbitan mono/diesters, C14 to C30 saturated ethoxylated sorbitan mono/diesters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated methyl glucoside esters, C14 to C30 saturated sucrose mono/diesters, C14 to C30 saturated ethoxylated methyl glucoside esters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated polyglucosides having an average of between 1 to 2 glucose units and mixtures thereof.
8. A personal cleansing article according to claim 1, wherein said low HLB
emulsifier is selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, steareth-2, and mixtures thereof.
emulsifier is selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, steareth-2, and mixtures thereof.
9. A personal cleansing article according to claim 1, wherein said benefit phase comprises from about 10% to about 90%, by weight of said benefit phase, of the oil.
10. A personal cleansing article according to claim 1, wherein said liquid striped personal cleansing composition additionally comprises a density modifier.
11. A personal cleansing article according to claim 10, wherein the density modifier is a hollow microsphere.
12. A personal cleansing article according to claim 1, wherein said cationic deposition polymer is selected from cationic cellulosic derivatives, cationic guar derivatives, cationic synthetic polymers and mixtures thereof.
13. A personal cleansing article according to claim 1, wherein the cleansing phase additionally comprises a lamellar structurant.
14. A personal cleansing article according to claim 13, wherein the lamellar structurant is selected from fatty acids, fatty esters, trihydroxystearin, fatty alcohols, and mixture thereof.
15. A personal cleansing article according to claim 1, wherein at least one phase contains a colorant.
16. A personal cleansing article according to claim 15, wherein the cleansing and benefit phases visually form a pattern within the package.
17. A personal cleansing article according to claim 16, wherein the pattern is selected from the group consisting of striped, marbled, geometric, and mixtures thereof.
18. A personal cleansing article according to claim 1, wherein said package is transparent.
19. A personal cleansing article according to claim 1, wherein said package comprises a lid; and said package includes instructions to store said package on said lid.
20. A personal cleansing article according to claim 1, wherein the composition comprises additives, wherein the additives are selected from the group consisting of vitamins; vitamin derivatives; sunscreen agents; thickening agents;
preservatives; anti-acne medicaments; antioxidants; skin soothing and healing agents; chelators; sequestrants; fragrances; essential oils; skin sensates;
pigments;
pearlescent agents; lakes; coloring agent and mixtures thereof.
preservatives; anti-acne medicaments; antioxidants; skin soothing and healing agents; chelators; sequestrants; fragrances; essential oils; skin sensates;
pigments;
pearlescent agents; lakes; coloring agent and mixtures thereof.
Applications Claiming Priority (3)
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US46706503P | 2003-05-01 | 2003-05-01 | |
US60/467,065 | 2003-05-01 | ||
PCT/IB2004/051592 WO2004096162A2 (en) | 2003-05-01 | 2004-04-23 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase comprising a water in oil emulsion |
Publications (2)
Publication Number | Publication Date |
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CA2522826A1 CA2522826A1 (en) | 2004-11-11 |
CA2522826C true CA2522826C (en) | 2011-09-20 |
Family
ID=33418436
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CA2522826A Expired - Lifetime CA2522826C (en) | 2003-05-01 | 2004-04-23 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase comprising a water in oil emulsion |
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US (1) | US20040248748A1 (en) |
EP (1) | EP1617811B1 (en) |
JP (1) | JP2006515360A (en) |
KR (1) | KR100772945B1 (en) |
CN (1) | CN1780602B (en) |
AT (1) | ATE387178T1 (en) |
AU (1) | AU2004233757B2 (en) |
BR (1) | BRPI0409593A (en) |
CA (1) | CA2522826C (en) |
DE (1) | DE602004012084T2 (en) |
ES (1) | ES2300805T3 (en) |
HK (1) | HK1090831A1 (en) |
MX (1) | MXPA05011722A (en) |
WO (1) | WO2004096162A2 (en) |
Families Citing this family (66)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL162227A0 (en) | 2001-12-21 | 2005-11-20 | Rhodia | Stable surfactant compositions for suspending components |
EP1539094A1 (en) | 2002-09-20 | 2005-06-15 | The Procter & Gamble Company | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase |
US20070137042A1 (en) * | 2005-12-20 | 2007-06-21 | Focht Heather L | Shaving kit, article of commerce and a method of shaving comprising a personal care composition |
KR100828468B1 (en) | 2002-11-04 | 2008-05-13 | 더 프록터 앤드 갬블 캄파니 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase with improved stability |
EP1617809B1 (en) | 2003-05-01 | 2015-07-08 | The Procter & Gamble Company | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase comprising a high internal phase emulsion |
AU2004237615B2 (en) | 2003-05-01 | 2007-06-14 | The Procter & Gamble Company | Visually distinctive multiple liquid phase compositions |
KR20060130027A (en) | 2003-10-10 | 2006-12-18 | 버텍스 파마슈티칼스 인코포레이티드 | Inhibitors of serine proteases, particularly hcv ns3-ns4a protease |
US20050143269A1 (en) * | 2003-12-24 | 2005-06-30 | Wei Karl S. | Multi-phase personal cleansing compositions comprising a lathering cleansing phase and a non-lathering structured aqueous phase |
US8951947B2 (en) | 2003-12-24 | 2015-02-10 | The Procter & Gamble Company | Multi-phase personal cleansing compositions comprising a lathering cleansing phase and a non-lathering structured aqueous phase |
US7268104B2 (en) * | 2003-12-31 | 2007-09-11 | Kimberly-Clark Worldwide, Inc. | Color changing liquid cleansing products |
CN1921819B (en) | 2004-02-27 | 2011-11-30 | 宝洁公司 | Mild multi-phased personal care composition |
US20050192188A1 (en) * | 2004-02-27 | 2005-09-01 | Wagner Julie A. | Mild body wash |
KR20060113776A (en) * | 2004-02-27 | 2006-11-02 | 더 프록터 앤드 갬블 캄파니 | A mild body wash |
US7738980B2 (en) * | 2004-03-04 | 2010-06-15 | Yamaha Corporation | Apparatus for editing configuration data of digital mixer |
US20050276829A1 (en) * | 2004-04-21 | 2005-12-15 | Qing Stella | Personal care compositions that deposit solid hydrophilic benefit agents |
US20050238680A1 (en) * | 2004-04-21 | 2005-10-27 | Qing Stella | Personal care compositions that deposit hydrophilic benefit agents |
US20050239670A1 (en) * | 2004-04-21 | 2005-10-27 | Qing Stella | Personal care compositions that deposit hydrophilic benefit agents |
US20050238595A1 (en) * | 2004-04-21 | 2005-10-27 | Qing Stella | Personal care compositions that deposit sunless tanning benefit agents |
DE102004021312A1 (en) * | 2004-04-29 | 2005-11-24 | Cognis Ip Management Gmbh | Emulsifier concentrate for cosmetic composition |
US20050276768A1 (en) * | 2004-06-14 | 2005-12-15 | Karl Shiqing Wei | Multi-phased personal care composition |
BRPI0514487A (en) * | 2004-08-19 | 2008-06-17 | Colgate Palmolive Co | method of preparing a composition and composition |
US20060079421A1 (en) * | 2004-10-08 | 2006-04-13 | Wagner Julie A | Stable multi-phased personal care composition |
US20060079418A1 (en) * | 2004-10-08 | 2006-04-13 | Wagner Julie A | Stable multi-phased personal care composition |
US7666825B2 (en) * | 2004-10-08 | 2010-02-23 | The Procter & Gamble Company | Stable, patterned multi-phased personal care composition |
US20060079419A1 (en) * | 2004-10-08 | 2006-04-13 | Julie Ann Wagner | Depositable solids |
US20060079420A1 (en) * | 2004-10-08 | 2006-04-13 | Wagner Julie A | Multi-phase personal cleansing composition |
US8147853B2 (en) | 2005-02-15 | 2012-04-03 | The Procter & Gamble Company | Personal care compositions containing hydrophobically modified non-platelet particles |
JP4620489B2 (en) * | 2005-02-22 | 2011-01-26 | 株式会社日本色材工業研究所 | Composition |
US7527077B2 (en) * | 2005-02-25 | 2009-05-05 | The Procter & Gamble Company | Multi-phase personal care compositions, processes for making and providing, and articles of commerce |
EP1861066A2 (en) * | 2005-03-21 | 2007-12-05 | The Procter and Gamble Company | Multi-phase personal care composition comprising visually distinct phases |
US7820609B2 (en) * | 2005-04-13 | 2010-10-26 | The Procter & Gamble Company | Mild, structured, multi-phase personal cleansing compositions comprising density modifiers |
CN106726635A (en) * | 2005-04-13 | 2017-05-31 | 宝洁公司 | Gentle structured, multi-phase personal cleansing compositions |
CA2603299A1 (en) * | 2005-04-13 | 2006-10-26 | The Procter & Gamble Company | Structured multi-phased personal care composition comprising branched anionic surfactants |
ES2464272T3 (en) * | 2005-05-20 | 2014-06-02 | Solvay Usa Inc. | Structured Surfactant Compositions |
US20070141001A1 (en) | 2005-12-15 | 2007-06-21 | The Procter & Gamble Company | Non-migrating colorants in multi-phase personal cleansing compositions |
US8104616B2 (en) | 2006-02-11 | 2012-01-31 | The Procter & Gamble Company | Clamshell package for holding and displaying consumer products |
US8153144B2 (en) | 2006-02-28 | 2012-04-10 | The Proctor & Gamble Company | Stable multiphase composition comprising alkylamphoacetate |
ES2529291T3 (en) | 2007-03-21 | 2015-02-18 | Colgate-Palmolive Company | Structured compositions comprising a clay |
US8105996B2 (en) * | 2007-03-30 | 2012-01-31 | The Procter & Gamble Company | Multiphase personal care composition comprising a structuring |
US8158566B2 (en) * | 2007-03-30 | 2012-04-17 | The Procter & Gamble Company | Multiphase personal care composition comprising a structuring system that comprises an associative polymer, a low HLB emulsifier and an electrolyte |
US20080247968A1 (en) * | 2007-04-05 | 2008-10-09 | Ralph Albert Sagel | Multi-phase dentifrice with characters |
US20080247969A1 (en) * | 2007-04-05 | 2008-10-09 | William Michael Glandorf | Opaque multi-phase dentifrice with patterns |
US20080245678A1 (en) * | 2007-04-05 | 2008-10-09 | Nicholas Seymour Gantenberg | Transparent multi-phase dentifrice with alternating bands |
US20080247971A1 (en) * | 2007-04-05 | 2008-10-09 | Nicholas Seymour Gantenberg | Transparent multi-phase dentifrice with coils |
US20080247970A1 (en) * | 2007-04-05 | 2008-10-09 | Nicholas Seymour Gantenberg | Opaque multi-phase dentifrice with alternating bands |
US20080247967A1 (en) * | 2007-04-05 | 2008-10-09 | Ralph Albert Sagel | Dentifrice with packaging layers |
US20080248072A1 (en) * | 2007-04-05 | 2008-10-09 | William Michael Glandorf | Transparent multi-phase dentifrice with patterns |
US20090324521A1 (en) * | 2007-07-27 | 2009-12-31 | Jonathan Robert Cetti | Personal Care Article For Sequentially Dispensing Compositions With Variable Concentrations Of Hydrophobic Benefit Materials |
US20090063334A1 (en) * | 2007-08-28 | 2009-03-05 | Alistair Duncan | Business-to-business transaction processing utilizing electronic payment network |
US20090060957A1 (en) * | 2007-08-30 | 2009-03-05 | William Michael Glandorf | Oral compositions |
MX2010009239A (en) | 2008-02-25 | 2010-09-10 | Procter & Gamble | Hair care compositions comprising sucrose polyesters. |
US8840871B2 (en) * | 2008-07-28 | 2014-09-23 | The Procter & Gamble Company | Multiphase personal care composition with enhanced deposition |
WO2010013203A2 (en) * | 2008-07-28 | 2010-02-04 | The Procter & Gamble Company | In-vitro deposition evaluation method for identifying personal care compositions which provide improved deposition of benefit agents |
US20120276177A1 (en) | 2009-12-23 | 2012-11-01 | Colgate-Palmolive Company | Visually patterned and oriented compositions |
AU2012296606A1 (en) | 2011-08-16 | 2014-03-06 | The Gillette Company | Composition dispensing device comprising a moisturizing composition |
RU2602806C2 (en) | 2012-05-17 | 2016-11-20 | Колгейт-Палмолив Компани | Multiphase composition containing surfactant and fragrance substance |
JP6001385B2 (en) * | 2012-08-31 | 2016-10-05 | ポーラ化成工業株式会社 | Multilayer cream |
MX2017006148A (en) | 2014-11-10 | 2017-07-27 | Procter & Gamble | Personal care compositions with two benefit phases. |
WO2016077327A1 (en) | 2014-11-10 | 2016-05-19 | The Procter & Gamble Company | Personal care compositions with two benefit phases |
US10966916B2 (en) | 2014-11-10 | 2021-04-06 | The Procter And Gamble Company | Personal care compositions |
DE102015219021A1 (en) | 2015-10-01 | 2016-05-25 | Henkel Ag & Co. Kgaa | Process for the preparation of a cosmetic cleansing emulsion |
JP6254638B2 (en) * | 2016-04-18 | 2017-12-27 | 株式会社 資生堂 | Liquid skin cleansers and liquid skin cleansing products |
WO2019079409A1 (en) | 2017-10-20 | 2019-04-25 | The Procter & Gamble Company | Aerosol foam skin cleanser |
WO2019079405A1 (en) | 2017-10-20 | 2019-04-25 | The Procter & Gamble Company | Aerosol foam skin cleanser |
CN113015904A (en) | 2018-11-29 | 2021-06-22 | 宝洁公司 | Method for screening personal care products |
CN111904920A (en) * | 2020-09-18 | 2020-11-10 | 上海煦轼生物科技有限公司 | Cleansing milk with cutin removing effect and preparation method thereof |
Family Cites Families (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3228662A (en) * | 1965-01-26 | 1966-01-11 | Warner Lambert Pharmaceutical | Multi-colored cosmetic preparation |
CA783534A (en) * | 1965-06-15 | 1968-04-23 | Unilever Limited | Liquid detergent compositions |
US3980767A (en) * | 1968-07-23 | 1976-09-14 | Beecham Group Limited | Gel toothpastes |
LU67772A1 (en) * | 1973-06-08 | 1975-03-06 | ||
US4159028A (en) * | 1977-03-28 | 1979-06-26 | Almay, Inc. | Method of forming and containerizing a multiphase cosmetic composition |
US4335103A (en) * | 1977-03-28 | 1982-06-15 | Almay, Inc. | Multiphase cosmetic composition |
US4263363A (en) * | 1979-12-20 | 1981-04-21 | Colgate-Palmolive Company | Emulsion-containing absorbent article having improved water holding capacity |
GB2100126B (en) * | 1981-06-11 | 1984-08-01 | Colgate Palmolive Co | A dentifrice |
US4518578A (en) * | 1983-05-16 | 1985-05-21 | Colgate-Palmolive Company | Dentifrice composition containing visually clear pigment-colored stripe |
US4966205A (en) * | 1988-02-02 | 1990-10-30 | Pola Chemical Industries Ltd. | Method and apparatus for charging transparent material |
US5059414A (en) * | 1988-07-01 | 1991-10-22 | Shiseido Co. Ltd. | Multi-phase high viscosity cosmetic products |
US4980155A (en) * | 1989-09-11 | 1990-12-25 | Revlon, Inc. | Two phase cosmetic composition |
US5635171A (en) * | 1990-12-21 | 1997-06-03 | L'oreal | Cosmetic or pharmaceutical composition in the form of a rigid gel, particularly for containing inclusions therein |
US5304334A (en) * | 1992-04-28 | 1994-04-19 | Estee Lauder, Inc. | Method of preparing a multiphase composition |
FR2694494B1 (en) * | 1992-08-05 | 1994-09-30 | Rhone Poulenc Chimie | Cosmetic composition containing non-water-soluble particles in suspension. |
GB9223439D0 (en) * | 1992-11-09 | 1992-12-23 | Unilever Plc | Washing composition |
US5455035A (en) * | 1994-01-13 | 1995-10-03 | Elizabeth Arden Company, Division Of Conopco, Inc. | Clear two-phase cosmetic composition |
GB9414572D0 (en) * | 1994-07-19 | 1994-09-07 | Unilever Plc | Soap composition |
GB9414573D0 (en) * | 1994-07-19 | 1994-09-07 | Unilever Plc | Detergent composition |
AU719223B2 (en) * | 1995-08-07 | 2000-05-04 | Unilever Plc | Liquid cleansing composition comprising soluble, lamellar phase inducing structurant |
GB9523167D0 (en) * | 1995-11-13 | 1996-01-17 | Unilever Plc | Cosmetic composition |
US5947335A (en) * | 1996-10-15 | 1999-09-07 | Lever Brothers Company | Dual compartment package |
DE19650952A1 (en) * | 1996-12-07 | 1998-06-10 | Henkel Kgaa | Two-phase skin care products |
US5929019A (en) * | 1997-01-30 | 1999-07-27 | Lever Brothers Company, Division Of Conopco, Inc. | Cleansing composition with separately dispensed cleansing base and benefit base wherein benefit base also comprises surfactant |
US5965501A (en) * | 1997-03-28 | 1999-10-12 | Lever Brothers Company, Division Of Conopco, Inc. | Personal washing bar compositions comprising emollient rich phase/stripe |
US5965500A (en) * | 1997-07-24 | 1999-10-12 | Levers Brothers Company, Division Of Conopco, Inc. | Stable liquid composition comprising high levels of emollients |
FR2780644B1 (en) * | 1998-07-03 | 2001-07-20 | Oreal | COSMETIC OR DERMATOLOGICAL COMPOSITION IN THE FORM OF A DISPERSION OF AN OIL PHASE AND AN AQUEOUS PHASE, STABILIZED USING CUBIC GEL PARTICLES |
AU1479501A (en) * | 1999-11-12 | 2001-06-06 | Procter & Gamble Company, The | Improved dual phase stannous oral compositions |
US6534457B2 (en) * | 2000-03-20 | 2003-03-18 | Unilever Home And Personal Care Usa, Division Of Conopco, Inc. | Extrudable multiphase composition comprising lamellar phase inducing structurant in each phase |
US6534456B2 (en) * | 2000-03-20 | 2003-03-18 | Unilever Home And Personal Care Usa, Division Of Conopco, Inc. | Extrudable multiphase composition comprising a lamellar phase and an isotropic phase |
US6306806B1 (en) | 2000-03-22 | 2001-10-23 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc | Dual chamber cleansing system comprising water-in-oil emulsion as benefit stripe |
DE10033414B4 (en) * | 2000-07-08 | 2004-02-19 | Wella Aktiengesellschaft | Clear, two-phase, foam-forming aerosol hair care product |
US6429177B1 (en) * | 2000-08-22 | 2002-08-06 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Separating multi-phase personal wash composition in a transparent or translucent package |
WO2003013467A1 (en) * | 2001-08-10 | 2003-02-20 | Beiersdorf Ag | Cosmetic cleansing formulations, based on a combination of sodium laureth sulphate and alkyl polyamphopolycarboxy glycinates |
US6538909B2 (en) * | 2001-12-13 | 2003-03-25 | Enova Systems | Universal high efficiency power converter |
IL162227A0 (en) * | 2001-12-21 | 2005-11-20 | Rhodia | Stable surfactant compositions for suspending components |
US6673755B2 (en) * | 2002-01-16 | 2004-01-06 | The Procter & Gamble Company | Personal cleansing compositions containing cleansing and skin active phases separated by one or more packaging barriers |
AU2003209436A1 (en) * | 2002-02-08 | 2003-09-02 | The Procter & Gamble Company | Rinse-off skin conditioning compositions |
BRPI0201235B1 (en) * | 2002-04-12 | 2017-05-02 | Natura Cosmeticos Sa | multiphase cosmetic makeup |
KR100828468B1 (en) * | 2002-11-04 | 2008-05-13 | 더 프록터 앤드 갬블 캄파니 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase with improved stability |
US7229486B2 (en) * | 2003-04-17 | 2007-06-12 | Saralee/De N.V. | Shoe and leather care product |
US7838479B2 (en) * | 2003-06-09 | 2010-11-23 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Packaged product containing an extrudable multiphase composition of a free fatty acid phase and a soap phase |
JP2006528635A (en) * | 2003-07-22 | 2006-12-21 | ローディア インコーポレイティド | A novel branched sulfate used in personal care formulations |
-
2004
- 2004-04-23 JP JP2006500367A patent/JP2006515360A/en active Pending
- 2004-04-23 CN CN2004800114774A patent/CN1780602B/en not_active Expired - Lifetime
- 2004-04-23 EP EP04760188A patent/EP1617811B1/en not_active Expired - Lifetime
- 2004-04-23 DE DE602004012084T patent/DE602004012084T2/en not_active Expired - Lifetime
- 2004-04-23 MX MXPA05011722A patent/MXPA05011722A/en active IP Right Grant
- 2004-04-23 CA CA2522826A patent/CA2522826C/en not_active Expired - Lifetime
- 2004-04-23 AT AT04760188T patent/ATE387178T1/en not_active IP Right Cessation
- 2004-04-23 AU AU2004233757A patent/AU2004233757B2/en not_active Ceased
- 2004-04-23 WO PCT/IB2004/051592 patent/WO2004096162A2/en active IP Right Grant
- 2004-04-23 KR KR1020057020181A patent/KR100772945B1/en active IP Right Grant
- 2004-04-23 BR BRPI0409593-6A patent/BRPI0409593A/en not_active Application Discontinuation
- 2004-04-23 ES ES04760188T patent/ES2300805T3/en not_active Expired - Lifetime
- 2004-04-30 US US10/836,984 patent/US20040248748A1/en not_active Abandoned
-
2006
- 2006-07-03 HK HK06107486A patent/HK1090831A1/en not_active IP Right Cessation
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WO2004096162A2 (en) | 2004-11-11 |
AU2004233757A1 (en) | 2004-11-11 |
CA2522826A1 (en) | 2004-11-11 |
EP1617811B1 (en) | 2008-02-27 |
ATE387178T1 (en) | 2008-03-15 |
EP1617811A2 (en) | 2006-01-25 |
ES2300805T3 (en) | 2008-06-16 |
MXPA05011722A (en) | 2006-01-23 |
KR20050113285A (en) | 2005-12-01 |
KR100772945B1 (en) | 2007-11-02 |
US20040248748A1 (en) | 2004-12-09 |
CN1780602A (en) | 2006-05-31 |
HK1090831A1 (en) | 2007-01-05 |
WO2004096162A3 (en) | 2005-05-19 |
DE602004012084T2 (en) | 2009-02-19 |
BRPI0409593A (en) | 2006-05-02 |
AU2004233757B2 (en) | 2007-08-02 |
JP2006515360A (en) | 2006-05-25 |
CN1780602B (en) | 2010-05-26 |
DE602004012084D1 (en) | 2008-04-10 |
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