CA2536292A1 - Improved resin compositions for extrusion coating - Google Patents
Improved resin compositions for extrusion coating Download PDFInfo
- Publication number
- CA2536292A1 CA2536292A1 CA002536292A CA2536292A CA2536292A1 CA 2536292 A1 CA2536292 A1 CA 2536292A1 CA 002536292 A CA002536292 A CA 002536292A CA 2536292 A CA2536292 A CA 2536292A CA 2536292 A1 CA2536292 A1 CA 2536292A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- polymeric material
- melt index
- less
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
Abstract
A composition is disclosed which is particularly suited for use in extrusion coating. The composition comprises a polymeric material having a rheology such that the slope S of a natural log-natural log plot of loss modulus (or G") versus storage modulus (or G') is greater than [0.635*(melt index)+13.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF RI
fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater. The compositions exhibit reduced neck-in when used in extrusion coating and the neck-in is independent of melt strength, thereby facilitating improved extrusion processes.
fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater. The compositions exhibit reduced neck-in when used in extrusion coating and the neck-in is independent of melt strength, thereby facilitating improved extrusion processes.
Claims (31)
1. A composition comprising a polymeric material having a rheology such that the slope (or S) determined by linear least squares regression, of a plot of the natural log of loss modulus (or G") versus natural log of storage modulus (or G') is greater than [0.635*(melt index)+13.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF RI fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC
molecular weight of 1,750,000 g/mol or greater.
molecular weight of 1,750,000 g/mol or greater.
2. The composition of Claim 1 wherein the polymeric material has a melt strength less than about 5 cN.
3. The composition of Claim 1 wherein the polymeric material comprises LDPE.
4. The composition of Claim 1 wherein the polymeric material comprises a blend of at least two polymeric materials.
5. The composition of Claim 1 wherein the polymeric material comprises Linear PE.
6. The composition of Claim 3 wherein the LDPE comprises a high molecular weight highly branched component with an MWD greater than 10 and a Mw(absolute)/Mw(GPC) ratio greater than 3Ø
7. The composition of Claim 6 wherein the LDPE is made in an autoclave reactor with chilled ethylene feed below 35°C operating in single phase mode.
8. The composition of Claim 1 wherein the polymeric material has a melt index greater than 10 g/10min.
9. The composition of Claim 8 wherein the polymeric material has a melt index greater than about 13 g/10min.
10. The composition of Claim 8 wherein the polymeric material has a melt index less than about 100 g/10min.
11. The composition of Claim 1 wherein the polymeric material has a Mark-Houwink plot where the slope is less than 0.25 in the absolute molecular weight range between 300,000 and 3,000,000 g/mol.
12. The composition of Claim 1 wherein the value for S is at least 1%
greater than [0.635*(melt index)+13.2]/[(melt index)+16.6].
greater than [0.635*(melt index)+13.2]/[(melt index)+16.6].
13. The composition of Claim 12 wherein the value for S is at least 2%
greater than [0.635*(melt index)+13.2]/[(melt index)+16.6].
greater than [0.635*(melt index)+13.2]/[(melt index)+16.6].
14. The composition of Claim 1 wherein the polymeric material has a CDF RI fraction less than 0.21 of a GPC chromatogram which has a molecular weight above 85,000 g/mol.
15. The composition of Claim 1 wherein the polymeric material has a CDF RI fraction less than 0.20 of a GPC chromatogram which has a molecular weight above 85,000 g/mol.
16. The composition of Claim 1 wherein the polymer material has a CDF
LS fraction greater than 0.09 of a GPC chromatogram which has a molecular weight above 1,750,000 g/mol.
LS fraction greater than 0.09 of a GPC chromatogram which has a molecular weight above 1,750,000 g/mol.
17. The use of a composition according to Claim 1 to make a cast film, profile extrusion, coated substrate, extrusion lamination or extrusion coated substrate.
18. In a process for extruding a polymeric material onto a substrate, the improvement comprising: using a polymeric material having a rheology such that the slope (or S) determined by linear least squares regression, of a natural log-natural log plot of loss modulus (or G") versus storage modulus (or G') is greater than [0.635*(melt index)+13.2]/[(melt index)+16.6].
19. The process of Claim 18 wherein the neck-in observed is less than 3 inches when running at a line speed of 440 ft/min.
20. The process of Claim 18 wherein the neck-in observed is less than 2.5 inches when running at a line speed of 440 ft/min.
21. The process of Claim 18 wherein the neck-in observed is less than 2 inches when running at a line speed of 440 ft/min.
22. The process of Claim 18 wherein the draw down is at least 1500 ft/min.
23. The process of Claim 18 wherein the polymeric material has a melt strength of less than 5 cN.
24. A polymeric film layer having a rheology such that the slope (or S) determined by linear least squares regression, of a natural log-natural log plot of loss modulus (or G") versus storage modulus (or G') is greater than [0.665*(melt index)+14.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF
RI
fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater.
RI
fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater.
25. The film layer of claim 24 wherein the layer has a CDF LS fraction of more than 0.09 at a conventional GPC molecular weight of 1,750,000 g/mol or greater.
26. The film layer of Claim 24 in which the film layer was produced using an extrusion coating, extrusion lamination, or cast film process.
27. A composition of matter comprising:
a. from about 10 to about 25 percent by weight of the composition of a high pressure low density type polyethylene resin having a melt index (I2) less than about 2, a molecular weight distribution greater than about 10, a Mw(absolute)/Mw(GPC) ratio greater than about 3.0, and a melt strength greater than about 24.1 -18.0*log10(MI); and b. from about 90 to about 75 percent by weight of the composition, of a Linear PE
having a density in the range of 0.97-0.857 g/cc and a melt index (I2) in the range of 20-100 ;
wherein the MI of the composition of matter is greater than about 10 g/10 minutes.
a. from about 10 to about 25 percent by weight of the composition of a high pressure low density type polyethylene resin having a melt index (I2) less than about 2, a molecular weight distribution greater than about 10, a Mw(absolute)/Mw(GPC) ratio greater than about 3.0, and a melt strength greater than about 24.1 -18.0*log10(MI); and b. from about 90 to about 75 percent by weight of the composition, of a Linear PE
having a density in the range of 0.97-0.857 g/cc and a melt index (I2) in the range of 20-100 ;
wherein the MI of the composition of matter is greater than about 10 g/10 minutes.
28. The composition of Claim 27 in which component a) has a melt index (I2) less than about 1 g/10 minutes.
29. The composition of Claim 27 wherein the composition has a melt strength less than about 5 cN.
30. The composition of Claim 27 wherein the Mw(absolute)/Mw(GPC) ratio of component (a) is greater than 3.2.
31. The composition of Claim 27 wherein the Mw(absolute)/Mw(GPC) ratio of component (a) is greater than 3.5.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50058503P | 2003-09-05 | 2003-09-05 | |
US60/500,585 | 2003-09-05 | ||
PCT/US2004/029124 WO2005023912A2 (en) | 2003-09-05 | 2004-09-03 | Improved resin compositions for extrusion coating |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2536292A1 true CA2536292A1 (en) | 2005-03-17 |
CA2536292C CA2536292C (en) | 2012-05-08 |
Family
ID=34272972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2536292A Active CA2536292C (en) | 2003-09-05 | 2004-09-03 | Improved resin compositions for extrusion coating |
Country Status (14)
Country | Link |
---|---|
US (1) | US7776987B2 (en) |
EP (1) | EP1664165B1 (en) |
JP (2) | JP5144932B2 (en) |
KR (1) | KR101136590B1 (en) |
CN (1) | CN1845952B (en) |
AR (1) | AR045592A1 (en) |
AU (1) | AU2004270723B2 (en) |
BR (1) | BRPI0413766B1 (en) |
CA (1) | CA2536292C (en) |
MX (1) | MXPA06002483A (en) |
MY (1) | MY145537A (en) |
PL (1) | PL1664165T3 (en) |
TW (1) | TWI356081B (en) |
WO (1) | WO2005023912A2 (en) |
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-
2004
- 2004-09-03 CN CN2004800252011A patent/CN1845952B/en not_active Expired - Fee Related
- 2004-09-03 JP JP2006525522A patent/JP5144932B2/en not_active Expired - Fee Related
- 2004-09-03 EP EP04783395.9A patent/EP1664165B1/en active Active
- 2004-09-03 KR KR1020067004405A patent/KR101136590B1/en not_active IP Right Cessation
- 2004-09-03 BR BRPI0413766-3A patent/BRPI0413766B1/en active IP Right Grant
- 2004-09-03 AU AU2004270723A patent/AU2004270723B2/en not_active Ceased
- 2004-09-03 US US10/566,937 patent/US7776987B2/en active Active
- 2004-09-03 MX MXPA06002483A patent/MXPA06002483A/en active IP Right Grant
- 2004-09-03 WO PCT/US2004/029124 patent/WO2005023912A2/en active Search and Examination
- 2004-09-03 PL PL04783395T patent/PL1664165T3/en unknown
- 2004-09-03 CA CA2536292A patent/CA2536292C/en active Active
- 2004-09-06 TW TW093126861A patent/TWI356081B/en not_active IP Right Cessation
- 2004-09-06 MY MYPI20043599A patent/MY145537A/en unknown
- 2004-09-06 AR ARP040103186A patent/AR045592A1/en active IP Right Grant
-
2012
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JP5144932B2 (en) | 2013-02-13 |
JP2012233197A (en) | 2012-11-29 |
EP1664165B1 (en) | 2013-11-13 |
KR20060098363A (en) | 2006-09-18 |
EP1664165A2 (en) | 2006-06-07 |
AU2004270723B2 (en) | 2010-08-05 |
BRPI0413766B1 (en) | 2014-01-28 |
MY145537A (en) | 2012-02-29 |
AU2004270723A1 (en) | 2005-03-17 |
BRPI0413766A (en) | 2006-10-31 |
AR045592A1 (en) | 2005-11-02 |
KR101136590B1 (en) | 2012-04-24 |
US20060281866A1 (en) | 2006-12-14 |
WO2005023912A3 (en) | 2005-08-11 |
US7776987B2 (en) | 2010-08-17 |
WO2005023912A2 (en) | 2005-03-17 |
TW200521188A (en) | 2005-07-01 |
CA2536292C (en) | 2012-05-08 |
JP2007504329A (en) | 2007-03-01 |
TWI356081B (en) | 2012-01-11 |
MXPA06002483A (en) | 2006-06-20 |
PL1664165T3 (en) | 2014-04-30 |
CN1845952B (en) | 2010-10-13 |
CN1845952A (en) | 2006-10-11 |
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