CA2545203A1 - Transparent and translucent crosslinked propylene-based elastomers, and their production and use - Google Patents
Transparent and translucent crosslinked propylene-based elastomers, and their production and use Download PDFInfo
- Publication number
- CA2545203A1 CA2545203A1 CA 2545203 CA2545203A CA2545203A1 CA 2545203 A1 CA2545203 A1 CA 2545203A1 CA 2545203 CA2545203 CA 2545203 CA 2545203 A CA2545203 A CA 2545203A CA 2545203 A1 CA2545203 A1 CA 2545203A1
- Authority
- CA
- Canada
- Prior art keywords
- less
- crosslinked elastomer
- elastomer
- propylene
- crosslinked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
- D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet
- Y10T442/678—Olefin polymer or copolymer sheet or film [e.g., polypropylene, polyethylene, ethylene-butylene copolymer, etc.]
Abstract
The present invention provides a crosslinked propylene-based elastomer having an isotactic propylene triad tacticity of from 65 to 95%, a melting point by DSC equal to or less than 110~C, a heat of fusion of from 5 J/g to 50 J/g, and a haze% per 100 mil thickness of 95 or less, and comprising at least 75 wt%
propylene-derived units, at least 5 wt% ethylene-derived units, and optionally 10 wt% or less of dime-derived units. In an embodiment, the present invention is a blend of a continuous phase of the crosslinked propylene-based elastomer and a dispersed phase of a crystalline polymeric compound. The present invention also provides elastomeric compositions comprising a crosslinked propylene-based elastomer as described herein and 100 parts by weight or less of a pigment per 100 parts of polymer. The present invention also provides films, fibers, nonwovens, molded objects, and extruded forms which include any of the inventive compositions described herein.
propylene-derived units, at least 5 wt% ethylene-derived units, and optionally 10 wt% or less of dime-derived units. In an embodiment, the present invention is a blend of a continuous phase of the crosslinked propylene-based elastomer and a dispersed phase of a crystalline polymeric compound. The present invention also provides elastomeric compositions comprising a crosslinked propylene-based elastomer as described herein and 100 parts by weight or less of a pigment per 100 parts of polymer. The present invention also provides films, fibers, nonwovens, molded objects, and extruded forms which include any of the inventive compositions described herein.
Claims (14)
1. A crosslinked elastomer comprising:
(a) propylene-derived units in an amount of at least 75 wt%, based on the combined weight of components (a), (b), and (c);
(b) ethylene-derived units in an amount of at least 5 wt%, based on the combined weight of components (a), (b), and (c); and (c) optionally 10 wt% or less of diene-derived units, based on the combined weight of components (a), (b), and (c);
wherein the elastomer has an isotactic propylene triad tacticity of from 65 to 95%, a melting point by DSC equal to or less than 110°C, a heat of fusion of from 5 J/g to 50 J/g, and a haze% per 100 mil thickness of 95 or less, preferably 60 or less, more preferably 40 or less, and especially 20 or less.
(a) propylene-derived units in an amount of at least 75 wt%, based on the combined weight of components (a), (b), and (c);
(b) ethylene-derived units in an amount of at least 5 wt%, based on the combined weight of components (a), (b), and (c); and (c) optionally 10 wt% or less of diene-derived units, based on the combined weight of components (a), (b), and (c);
wherein the elastomer has an isotactic propylene triad tacticity of from 65 to 95%, a melting point by DSC equal to or less than 110°C, a heat of fusion of from 5 J/g to 50 J/g, and a haze% per 100 mil thickness of 95 or less, preferably 60 or less, more preferably 40 or less, and especially 20 or less.
2. The crosslinked elastomer according to claim 1, wherein the crosslinked elastomer of claim 1, wherein the elastomer, prior to crosslinking, has an MFR
@230°C of from 0.1 to 400, and preferably from 5 to 150.
@230°C of from 0.1 to 400, and preferably from 5 to 150.
3. The crosslinked elastomer according to claim 1 or 2, wherein the crosslinked elastomer has an ultimate tensile strength of 0.5 MPa or greater.
4. The crosslinked elastomer according to any of the preceding claims, wherein the crosslinked elastomer has an ultimate tensile strength (TS), measured in MPa, of 0.5 or greater.
5. The crosslinked elastomer according to any of the preceding claims, wherein the elastomer comprises diene-derived units in an amount of from 0.3 to wt%, based on the combined weight of components (a), (b), and (c).
6. The crosslinked elastomer according to any of the preceding claims, wherein the ratio of the Shore A hardness to MFR@230°C of the elastomer, prior to crosslinking, and the ultimate tensile strength (TS), measured in MPa, of the crosslinked elastomer, satisfy the following equation:
(Shore A hardness/MFR@230°C)<=1.66*TS - B1, where B1 is 0, preferably 3.33, more preferably 6.66, and especially 10.
(Shore A hardness/MFR@230°C)<=1.66*TS - B1, where B1 is 0, preferably 3.33, more preferably 6.66, and especially 10.
7. The crosslinked elastomer according to any of the preceding claims, wherein the crosslinked elastomer has a Die C tear strength (Die C), measured in lb force/inch, of 50 or greater.
8. The crosslinked elastomer according to any of the preceding claims, wherein the ratio of the Shore A hardness to MFR@230°C of the elastomer, prior to crosslinking, and the Die C tear strength (Die C), measured in lb force/inch, of the crosslinked elastomer, satisfy the following equation:
(Shore A hardness/MFR@230°C)<=0.2*Die C - B2, where B2 is 0, preferably 10, more preferably 20, and especially 30.
(Shore A hardness/MFR@230°C)<=0.2*Die C - B2, where B2 is 0, preferably 10, more preferably 20, and especially 30.
9. A blend composition comprising a continuous phase formed by the crosslinked elastomer of any of the preceding claims and a dispersed phase of a crystalline polymer component having a melting point by DSC of 115°C or higher, and a heat of fusion of 50 J/g or higher, and is selected from the group consisting of propylene homopolymers, propylene graft copolymers, propylene block copolymers, propylene random copolymers, and mixtures thereof, and is preferably isotactic polypropylene.
10. An elastomeric composition comprising the composition according to any of the preceding claims and 100 parts by weight or less of a pigment, preferably a colored pigment, per 100 parts of polymer.
11. An article comprising the composition according to any of the preceding claims, wherein the article has a haze% per 100 mil thickness of 95 or less, preferably 80 or less, more preferably 50 or less, and especially 30 or less.
12. The article according to claim 11, wherein the article is an extruded article or a molded object.
13. The blend composition as set forth in Claim 9 wherein said blend composition has been heated to a level sufficient to melt substantially the entirety of the crystalline polymer component.
14. The blend composition as set forth in Claim 9 wherein said crystalline polymer component is isotactic polypropylene and wherein said blend has been heated to at least 150°C.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51997503P | 2003-11-14 | 2003-11-14 | |
| US60/519,975 | 2003-11-14 | ||
| PCT/US2004/037875 WO2005049672A1 (en) | 2003-11-14 | 2004-11-12 | Transparent and translucent crosslinked propylenebased elastomers, and their production and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2545203A1 true CA2545203A1 (en) | 2005-06-02 |
| CA2545203C CA2545203C (en) | 2010-02-02 |
Family
ID=34619409
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2545203 Expired - Fee Related CA2545203C (en) | 2003-11-14 | 2004-11-12 | Transparent and translucent crosslinked propylene-based elastomers, and their production and use |
| CA 2546075 Expired - Fee Related CA2546075C (en) | 2003-11-14 | 2004-11-12 | Propylene-based elastomers and uses thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2546075 Expired - Fee Related CA2546075C (en) | 2003-11-14 | 2004-11-12 | Propylene-based elastomers and uses thereof |
Country Status (6)
| Country | Link |
|---|---|
| US (4) | US7928165B2 (en) |
| EP (2) | EP1687346B1 (en) |
| JP (2) | JP5244316B2 (en) |
| CN (2) | CN1890276B (en) |
| CA (2) | CA2545203C (en) |
| WO (3) | WO2005049671A1 (en) |
Families Citing this family (115)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002519497A (en) * | 1998-07-01 | 2002-07-02 | エクソンモービル・ケミカル・パテンツ・インク | Elastic blend comprising a crystalline propylene polymer and a crystallizable propylene polymer |
| US7282541B2 (en) | 2000-10-30 | 2007-10-16 | Exxonmobil Chemical Patents Inc. | Functionalized polypropylene-based polymers |
| EP1330479B2 (en) | 2000-10-30 | 2015-01-21 | ExxonMobil Chemical Patents Inc. | Graft-modified polymers based on novel propylene ethylene copolymers |
| WO2002051928A2 (en) * | 2000-12-22 | 2002-07-04 | Exxonmobil Chemical Patents Inc. | Composites comprising semicrystalline random ethylene / propylenecopolymers |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| WO2004014997A2 (en) | 2002-08-12 | 2004-02-19 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| US7928165B2 (en) * | 2003-11-14 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Transparent and translucent crosslinked propylene-based elastomers, and their production and use |
| JP4499440B2 (en) * | 2004-02-05 | 2010-07-07 | 日本発條株式会社 | Foamable olefinic thermoplastic elastomer composition for injection molding and its foamed molded article |
| ATE552301T1 (en) | 2004-11-25 | 2012-04-15 | Mitsui Chemicals Inc | PROPYLENE RESIN COMPOSITION AND USE THEREOF |
| CA2588770C (en) * | 2004-12-17 | 2010-03-23 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and articles therefrom |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| WO2006083505A1 (en) * | 2005-01-31 | 2006-08-10 | Exxonmobil Chemical Patents Inc. | Polymeric compositions including their uses and methods of production |
| RU2008101445A (en) * | 2005-06-13 | 2009-07-20 | Базелль Полиолефине Гмбх (De) | METHOD FOR COPOLIMERIZATION OF PROPYLENE |
| US7585917B2 (en) | 2005-06-13 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic blend compositions |
| US20070021564A1 (en) * | 2005-07-13 | 2007-01-25 | Ellul Maria D | Peroxide-cured thermoplastic vulcanizates |
| WO2007011541A1 (en) | 2005-07-15 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
| US7872075B2 (en) * | 2005-10-07 | 2011-01-18 | Exxonmobil Chemical Patents Inc. | Peroxide-cured thermoplastic vulcanizates and process for making the same |
| JP4753838B2 (en) * | 2005-11-08 | 2011-08-24 | 花王株式会社 | Elastic nonwoven fabric |
| US20070129493A1 (en) * | 2005-12-06 | 2007-06-07 | Abdelhadi Sahnoune | Random propylene diene copolymer thermoplastic vulcanizate compositions |
| JP5552232B2 (en) * | 2005-12-06 | 2014-07-16 | エクソンモービル・ケミカル・パテンツ・インク | Ethylene elastomer composition |
| JP4753852B2 (en) * | 2006-01-11 | 2011-08-24 | 花王株式会社 | Elastic nonwoven fabric |
| US7863364B2 (en) * | 2006-01-17 | 2011-01-04 | Exxonmobil Chemical Patents Inc. | Process for making dynamically-loaded articles comprising propylene-based elastomers, composition for use in such processes, and article made using such processes |
| GB0601166D0 (en) * | 2006-01-20 | 2006-03-01 | Exxonmobil Chem Patents Inc | Thermoplastic polyolefins and methods for their production |
| WO2008016518A2 (en) | 2006-08-02 | 2008-02-07 | Exxonmobil Chemical Patents Inc. | Propylene-based polymer article |
| US7951871B2 (en) * | 2006-11-10 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Curing rubber by hydrosilation |
| US7943701B2 (en) * | 2007-01-26 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Fibers and non-wovens prepared with propylene-based elastomers |
| US7666491B2 (en) * | 2007-01-26 | 2010-02-23 | Building Materials Investment Corporation | Method and use of a stretchable nonreinforced TPO building materials |
| US7951732B2 (en) | 2007-01-26 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Elastomeric laminates for consumer products |
| US7943219B2 (en) * | 2007-03-23 | 2011-05-17 | Kimberly-Clark Worldwide, Inc. | Films and articles with reversible opacity change upon stretching, and methods of making and using same |
| JP5161481B2 (en) * | 2007-05-02 | 2013-03-13 | 株式会社ジェイエスピー | Polypropylene resin foam molding with skin |
| US7943711B2 (en) | 2007-05-14 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Ethylene elastomer compositions |
| US20080286547A1 (en) * | 2007-05-18 | 2008-11-20 | Hubbard Michael A | Polypropylene films with enhanced moisture barrier properties, process for making and composition thereof |
| US9187631B2 (en) * | 2007-10-22 | 2015-11-17 | Trinseo Europe Gmbh | Polymeric compositions and processes for molding articles |
| US8609772B2 (en) | 2007-10-23 | 2013-12-17 | Exxonmobil Chemical Patents Inc. | Elastic films having improved mechanical and elastic properties and methods for making the same |
| US20090111945A1 (en) * | 2007-10-26 | 2009-04-30 | Sudhin Datta | Soft Homogeneous Isotactic Polypropylene Compositions |
| US8841383B2 (en) | 2007-11-02 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Ethylene-propylene terpolymers in tire sidewalls |
| US7863206B2 (en) * | 2007-11-09 | 2011-01-04 | Exxonmobil Chemical Patents Inc. | Fibers and non-wovens prepared with propylene-based elastomers |
| US8101534B2 (en) * | 2007-11-09 | 2012-01-24 | Exxonmobil Chemical Patents Inc. | Fibers and non-wovens prepared with propylene-based elastomers |
| US7994253B2 (en) | 2008-04-15 | 2011-08-09 | Exxonmobil Chemical Patents Inc. | Translucent propylene-based elastomeric compositions |
| US7867433B2 (en) | 2008-05-30 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Polyolefin-based crosslinked articles |
| US8765832B2 (en) | 2011-10-14 | 2014-07-01 | Exxonmobil Chemical Patents Inc. | Polyolefin-based crosslinked compositions and methods of making them |
| US8202941B2 (en) | 2008-06-27 | 2012-06-19 | Exxonmobil Chemical Patents Inc. | High shrinkage propylene-based films |
| US20120015854A1 (en) | 2008-08-08 | 2012-01-19 | Ravishankar Periagaram S | Olefinic Copolymer Compositions for Viscosity Modification of Motor Oil |
| US9498932B2 (en) | 2008-09-30 | 2016-11-22 | Exxonmobil Chemical Patents Inc. | Multi-layered meltblown composite and methods for making same |
| US9168718B2 (en) * | 2009-04-21 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Method for producing temperature resistant nonwovens |
| US10161063B2 (en) | 2008-09-30 | 2018-12-25 | Exxonmobil Chemical Patents Inc. | Polyolefin-based elastic meltblown fabrics |
| EP2376559B1 (en) | 2008-12-29 | 2016-05-04 | ExxonMobil Chemical Patents Inc. | Process for forming polymer blends |
| US8664336B2 (en) | 2008-12-29 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Process for forming polymer blends |
| JP2012517363A (en) * | 2009-02-10 | 2012-08-02 | プロプライアテクト・エル．ピー． | Foam laminated product and method for producing the same |
| CN102333644B (en) * | 2009-02-27 | 2015-07-22 | 埃克森美孚化学专利公司 | Multi-layer nonwoven in situ laminates and method of producing the same |
| US20110059277A1 (en) * | 2009-09-04 | 2011-03-10 | Rainer Kolb | Elastomeric Surface Coatings for Plastic Articles |
| US9017593B2 (en) * | 2009-06-16 | 2015-04-28 | Exxonmobil Chemical Patents Inc. | Composite materials comprising propylene-based polymer blend coatings |
| EP2454318B1 (en) | 2009-07-15 | 2014-06-25 | Dow Global Technologies LLC | Polymer compositions, methods of making the same, and articles prepared from the same |
| US8975334B2 (en) * | 2009-07-23 | 2015-03-10 | Exxonmobil Chemical Patents Inc. | Crosslinkable propylene-based copolymers, methods for preparing the same, and articles made therefrom |
| US8742019B2 (en) | 2009-10-02 | 2014-06-03 | Exxonmobil Chemical Patents Inc. | Crosslinked polyolefin polymer blends |
| US8247494B2 (en) * | 2009-11-23 | 2012-08-21 | Exxonmobil Chemical Patents Inc. | Thermoset compositions with dispersed thermoplastic resin therein and process for making them |
| US8425924B2 (en) * | 2009-11-24 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Propylene compositions containing a pyrethroid and products made therefrom |
| EP2390279A1 (en) * | 2009-12-17 | 2011-11-30 | ExxonMobil Chemical Patents Inc. | Polypropylene composition with plasticiser for sterilisable films |
| EP2516708B1 (en) * | 2009-12-23 | 2016-02-17 | Invista Technologies S.à.r.l. | Polyolefin elastic fiber |
| BR112012015365A2 (en) | 2009-12-23 | 2020-09-15 | Invista Technologies S.A.R.L. | article and method for preparing a cloth |
| EP2515814B1 (en) | 2009-12-23 | 2018-03-14 | Invista Technologies S.à.r.l. | Stretch articles including polyolefin elastic fiber |
| JP2013515871A (en) | 2009-12-23 | 2013-05-09 | インビスタ テクノロジーズ エス エイ アール エル | Elastic fiber containing anti-adhesive additive |
| EP2545215B1 (en) | 2010-03-12 | 2014-08-27 | ExxonMobil Chemical Patents Inc. | Method for producing temperature resistant nonwovens |
| CN102939326A (en) | 2010-06-09 | 2013-02-20 | 埃克森美孚石油公司 | Film composition and method of making the same |
| CA2801537C (en) | 2010-07-12 | 2014-10-21 | Exxonmobil Oil Corporation | Laminate film and method of making the same |
| US8557906B2 (en) | 2010-09-03 | 2013-10-15 | Exxonmobil Chemical Patents Inc. | Flame resistant polyolefin compositions and methods for making the same |
| JP5706668B2 (en) * | 2010-11-09 | 2015-04-22 | ポリプラスチックス株式会社 | Cross-linked olefin elastomer |
| CN103298876B (en) * | 2010-11-24 | 2016-12-07 | 埃克森美孚化学专利公司 | The polymer composition that high filler loads |
| EP2723927B1 (en) * | 2011-06-21 | 2016-11-23 | ExxonMobil Chemical Patents Inc. | Elastic nonwoven materials comprising propylene-based and ethylene-based polymers |
| CA2841268A1 (en) | 2011-07-08 | 2013-01-17 | Exxonmobil Oil Corporation | Multi-layer films having improved sealing properties |
| WO2013036312A1 (en) | 2011-08-19 | 2013-03-14 | Avery Dennison Corporation | Blends of ethylene copolymers and propylene based plastomers in multilayer films for low noise and rf welding |
| FI125678B (en) * | 2011-08-26 | 2016-01-15 | Bioretec Oy | BIOABSORABLE, ORIENTED, DEFORMABLE FIXATION MATERIAL AND DISC |
| CN103946022B (en) * | 2011-12-02 | 2016-10-12 | 埃克森美孚化学专利公司 | Plural layers and manufacture method thereof |
| US10335308B2 (en) | 2011-12-22 | 2019-07-02 | Avery Dennison Corporation | Flexible barrier films containing cyclic olefins |
| US20130165354A1 (en) | 2011-12-22 | 2013-06-27 | Exxonmobil Research And Engineering Company | Method for improving engine fuel efficiency |
| EP2669086A1 (en) * | 2012-05-28 | 2013-12-04 | Dow Global Technologies LLC | Cast silage film with enhanced cling properties |
| US10548367B2 (en) * | 2013-01-29 | 2020-02-04 | Exxonmobil Chemical Patents Inc. | Footwear sole comprising a propylene-based elastomer, footwear comprising said sole, and methods of making them |
| EP3662996A3 (en) | 2013-03-14 | 2020-12-16 | Verbio Vereinigte BioEnergie AG | Molybdenum and tungsten complexes as olefin metathesis catalysts and reactions using the catalysts |
| US11492477B2 (en) * | 2013-06-04 | 2022-11-08 | Exxonmobil Chemicals Patent Inc. | Polymer compositions and nonwoven compositions prepared therefrom |
| US10071950B2 (en) | 2013-07-12 | 2018-09-11 | Ximo Ag | Use of immobilized molybdenum- and tungsten-containing catalysts in olefin cross metathesis |
| US10427146B2 (en) | 2013-10-01 | 2019-10-01 | Ximo Ag | Immobilized metathesis tungsten oxo alkylidene catalysts and use thereof in olefin metathesis |
| WO2016014230A1 (en) | 2014-07-25 | 2016-01-28 | Exxonmobil Chemical Patents Inc. | Footwear compositions comprising propylene-based elastomers |
| CN107075209B (en) | 2014-09-30 | 2020-05-19 | 埃克森美孚化学专利公司 | Low ethylene amorphous propylene-ethylene-diene terpolymer compositions |
| EP3201009B1 (en) * | 2014-09-30 | 2018-05-16 | ExxonMobil Chemical Patents Inc. | Propylene-ethylene-diene terpolymer additives for improved tire tread performance |
| CA2964346C (en) | 2014-10-24 | 2020-07-21 | Exxonmobil Chemical Patents Inc. | Chain end functionalized polyolefins for improving wet traction and rolling resistance of tire treads |
| US10428210B2 (en) | 2014-10-29 | 2019-10-01 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions for elastic applications |
| BR112017022413A2 (en) | 2015-06-05 | 2018-07-10 | Exxonmobil Chemical Patents Inc | heat-sealed continuous filament fabrics comprising propylene-based elastomer compositions and methods for making them |
| BR112018008584B1 (en) | 2015-11-03 | 2021-08-31 | National Oilwell Varco Denmark I/S | FLEXIBLE TUBE NOT ATTACHED FOR SUBSEA FLUID TRANSPORTATION |
| CN106637681A (en) * | 2015-11-04 | 2017-05-10 | 张家港骏马无纺布有限公司 | Elastic nonwoven and preparing method thereof |
| US9487653B2 (en) | 2015-12-08 | 2016-11-08 | Exxonmobil Chemical Patents Inc. | Process of making crosslinked polyolefin polymer blends and compositions prepared thereof |
| US10744494B2 (en) | 2015-12-23 | 2020-08-18 | Ximo Ag | Immobilized metal alkylidene catalysts and use thereof in olefin metathesis |
| US10790404B2 (en) | 2016-03-30 | 2020-09-29 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions for photovoltaic cell applications |
| US10844529B2 (en) | 2016-05-02 | 2020-11-24 | Exxonmobil Chemicals Patents Inc. | Spunbond fabrics comprising propylene-based elastomer compositions and methods for making the same |
| CN109563326A (en) * | 2016-06-30 | 2019-04-02 | 陶氏环球技术有限责任公司 | Based on ethylene/alpha-olefin/polyenoid composition |
| EP3488039A4 (en) * | 2016-07-22 | 2019-07-03 | ExxonMobil Chemical Patents Inc. | Polypropylene nonwoven fibers, fabrics and methods for making same |
| WO2018190940A1 (en) | 2017-04-14 | 2018-10-18 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising epdm and epr |
| US11566122B2 (en) | 2017-11-01 | 2023-01-31 | Avient Corporation | Damping thermoplastic olefin elastomers |
| US11512191B2 (en) | 2017-11-10 | 2022-11-29 | Avient Corporation | Polyolefin elastomer blends for elastomeric films |
| US11220092B2 (en) * | 2018-01-04 | 2022-01-11 | Exxonmobil Chemical Patents Inc. | Films and methods of making the same |
| US11925226B2 (en) | 2018-02-05 | 2024-03-12 | The Board Of Trustees Of The Leland Stanford Junior University | Spectrally selective textile for passive radiative outdoor personal cooling |
| EP3768734A1 (en) * | 2018-03-19 | 2021-01-27 | ExxonMobil Chemical Patents Inc. | Elastomeric propylene-alpha-olefin-diene terpolymer compositions |
| US20200208315A1 (en) | 2018-12-27 | 2020-07-02 | Exxonmobil Chemical Patents Inc. | Propylene-Based Spunbond Fabrics With Faster Crystallization Time |
| WO2020190507A1 (en) | 2019-03-19 | 2020-09-24 | Exxonmobil Chemical Patents Inc. | Multilayer oriented films |
| EP3999563A1 (en) | 2019-07-17 | 2022-05-25 | ExxonMobil Chemical Patents Inc. | High propylene content ep having low glass transition temperatures |
| US20230097049A1 (en) | 2019-12-13 | 2023-03-30 | Exxonmobil Chemical Patents Inc, | Propylene-Based Elastomer Compositions, Articles Thereof, and Methods Thereof |
| WO2021167739A1 (en) | 2020-02-18 | 2021-08-26 | Exxonmobil Chemical Patents Inc. | High tenacity handwrap stretch film for improved pallet stability |
| US20220072743A1 (en) * | 2020-06-26 | 2022-03-10 | The Research Foundation For The State University Of New York | Thermoplastic components, systems, and methods for forming same |
| US20230138702A1 (en) * | 2021-10-29 | 2023-05-04 | Lion Copolymer Geismar, Llc | Ethylene propylene diene monomer (epdm) and vinyl norbornene diene (vnb) copolymers and methods of making same |
| WO2023076070A1 (en) | 2021-10-29 | 2023-05-04 | Exxonmobil Chemical Patents Inc. | Extrusion processes for functionalized polymer compositions |
| WO2023076071A1 (en) | 2021-10-29 | 2023-05-04 | Exxonmobil Chemical Patents Inc. | Method of forming a composition comprising a functionalized polymer |
| US20240043589A1 (en) * | 2022-07-26 | 2024-02-08 | Synthomer Adhesive Technologies Llc | Propylene-ethylene copolymers and adhesives containing propylene-ethylene copolymers |
Family Cites Families (93)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US519975A (en) | 1894-05-15 | Hamilton e | ||
| US2972600A (en) | 1957-09-27 | 1961-02-21 | Schenectady Varnish Company In | Substituted phenols |
| NL291470A (en) | 1961-11-24 | 1900-01-01 | ||
| US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
| NL6910985A (en) | 1968-07-18 | 1970-01-20 | ||
| US3806558A (en) * | 1971-08-12 | 1974-04-23 | Uniroyal Inc | Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic |
| GB1489580A (en) * | 1973-10-15 | 1977-10-19 | Nordiske Kabel Traad | Manufacturing cross-linked moulded articles from cross-linkable polymeric materials |
| JPS5234150A (en) * | 1975-09-11 | 1977-03-15 | Nippon Cable Syst Inc | Control cable |
| JPS5237953A (en) | 1975-09-19 | 1977-03-24 | Nippon Ii P Rubber Kk | Preparation of thermoplastic elastomer |
| SU660982A1 (en) | 1976-07-02 | 1979-05-05 | Предприятие П/Я В-8952 | Method of obtaining copolymers |
| US4311628A (en) * | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4368565A (en) | 1978-03-28 | 1983-01-18 | Biax-Fiberfilm Corporation | Grooved roller assembly for laterally stretching film |
| JPS6011604B2 (en) * | 1978-04-21 | 1985-03-27 | 住友電気工業株式会社 | Manufacturing method for long rubber products |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4540753A (en) | 1983-06-15 | 1985-09-10 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
| US4603158A (en) | 1984-09-28 | 1986-07-29 | Battelle Development Corporation | Optically transparent elastomers |
| US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
| JPS61247747A (en) * | 1985-04-26 | 1986-11-05 | Mitsui Petrochem Ind Ltd | Thepoplastic elastomeric composition |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5391629A (en) | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
| DE3713862A1 (en) | 1987-04-25 | 1988-11-10 | Reifenhaeuser Masch | METHOD AND SPINNED FLEECE SYSTEM FOR PRODUCING A SPINNED FLEECE FROM SYNTHETIC CONTINUOUS FILAMENT |
| JPH01247441A (en) * | 1988-03-30 | 1989-10-03 | Mitsui Petrochem Ind Ltd | Thermoplastic elastomer composition |
| US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| FR2634212B1 (en) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | APPARATUS AND METHOD FOR POLYMERIZATION OF GASEOUS OLEFINS IN A FLUIDIZED BED REACTOR |
| KR900009719A (en) | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | New Ethylene-Propylene Copolymer |
| JP2655899B2 (en) * | 1988-12-23 | 1997-09-24 | 昭和電工株式会社 | Thermoplastic elastomer composition |
| JP2682130B2 (en) | 1989-04-25 | 1997-11-26 | 三井石油化学工業株式会社 | Flexible long-fiber non-woven fabric |
| JP2738562B2 (en) * | 1989-05-25 | 1998-04-08 | 三菱化学株式会社 | Method for producing unsaturated copolymer |
| US5100947A (en) * | 1989-05-26 | 1992-03-31 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having improved stiffness/impact balance |
| US4987493A (en) * | 1989-08-01 | 1991-01-22 | Rca Licensing Corporation | Memory efficient interlace apparatus and method as for a picture in a picture display |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5382400A (en) | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
| US5336552A (en) | 1992-08-26 | 1994-08-09 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| JP3328360B2 (en) | 1993-03-31 | 2002-09-24 | 三井化学株式会社 | Thermoplastic elastomer |
| JP2918412B2 (en) * | 1993-04-01 | 1999-07-12 | 積水化学工業株式会社 | Polyolefin resin foam |
| US5290886A (en) | 1993-04-20 | 1994-03-01 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved low temperature properties |
| KR100190268B1 (en) | 1993-04-26 | 1999-06-01 | 에인혼 해롤드 | Process for polymerizing monomers in fludized beds |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| EP1209165B1 (en) | 1993-06-07 | 2006-04-19 | Mitsui Chemicals, Inc. | Propylene elastomer |
| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| US5324576A (en) * | 1993-08-25 | 1994-06-28 | Minnesota Mining And Manufacturing Company | Polyolefin meltblown elastic webs |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| JP3388644B2 (en) * | 1994-09-27 | 2003-03-24 | 三菱化学株式会社 | Production method of block copolymer |
| JPH08113657A (en) | 1994-10-17 | 1996-05-07 | Bando Chem Ind Ltd | Bonding of fiber material to rubber composition |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| US6327477B1 (en) * | 1995-03-31 | 2001-12-04 | Canon Kabushiki Kaisha | Wireless communication apparatus and system |
| US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| US5656693A (en) * | 1995-06-14 | 1997-08-12 | Exxon Chemical Patents Inc. | Thermoplastic elastomers having improved cure |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| US5672660A (en) | 1995-12-01 | 1997-09-30 | Advanced Elastomer Systems, L.P. | Hydrosilylation crosslinking |
| WO1997022639A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
| JP2000504868A (en) * | 1996-02-15 | 2000-04-18 | テレフォンアクチボラゲット・エルエム・エリクソン | Management interworking unit and method of forming such a unit |
| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
| US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| US6069849A (en) | 1996-09-17 | 2000-05-30 | Xilinx, Inc. | Method and system for measuring signal propagation delays using the duty cycle of a ring oscillator |
| EP0844278B1 (en) * | 1996-11-26 | 2003-05-28 | Basell North America Inc. | Polyolefin composition used for making embossed sheets with improved grain retention |
| US6245856B1 (en) * | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
| US6268438B1 (en) | 1996-12-17 | 2001-07-31 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomeric compositions |
| WO1998031283A1 (en) | 1997-01-17 | 1998-07-23 | Assurance Medical,Inc. | Tissue examination |
| CA2249275A1 (en) | 1997-01-21 | 1998-07-23 | Masaaki Kawasaki | Vulcanized molding having surface decorative layer, painted thermoplastic resin composition, and painted elastomer composition |
| US6525157B2 (en) * | 1997-08-12 | 2003-02-25 | Exxonmobile Chemical Patents Inc. | Propylene ethylene polymers |
| US6635715B1 (en) * | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| JP4275857B2 (en) * | 1998-03-04 | 2009-06-10 | エクソンモービル・ケミカル・パテンツ・インク | Method for enhancing diene conversion in EPDM type polymerization |
| US6319998B1 (en) | 1998-03-04 | 2001-11-20 | Exxon Mobil Chemical Patents Inc. | Method for making polymer blends by using series reactors |
| WO1999045062A1 (en) * | 1998-03-04 | 1999-09-10 | Exxon Chemical Patents Inc. | Product and method for making polyolefin polymer dispersions |
| JP2002519497A (en) * | 1998-07-01 | 2002-07-02 | エクソンモービル・ケミカル・パテンツ・インク | Elastic blend comprising a crystalline propylene polymer and a crystallizable propylene polymer |
| US20010008695A1 (en) * | 1998-10-23 | 2001-07-19 | Nelson Bolton | Polymer films and laminates thereof |
| AU2480900A (en) * | 1998-12-24 | 2000-07-31 | Kimberly-Clark Worldwide, Inc. | Absorbent structure and method for production |
| US6500563B1 (en) * | 1999-05-13 | 2002-12-31 | Exxonmobil Chemical Patents Inc. | Elastic films including crystalline polymer and crystallizable polymers of propylene |
| ES2234609T3 (en) * | 1999-05-13 | 2005-07-01 | Exxonmobil Chemical Patents Inc. | ELASTIC FIBERS AND ARTICLES MADE OF THE SAME, WHICH INCLUDE CRYSTALLINE AND CRYSTALLIZABLE PROPYLENE POLYMERS. |
| US6265493B1 (en) | 1999-07-21 | 2001-07-24 | The Penn State Research Foundation | Polyolefin graft copolymers derived from linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same |
| KR100769774B1 (en) | 2000-10-25 | 2007-10-23 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Processes and apparatus for continuous solution polymerization |
| WO2002051928A2 (en) | 2000-12-22 | 2002-07-04 | Exxonmobil Chemical Patents Inc. | Composites comprising semicrystalline random ethylene / propylenecopolymers |
| JP5156167B2 (en) * | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | Propylene-ethylene polymer and production method |
| US7193024B2 (en) * | 2001-06-15 | 2007-03-20 | Dow Global Technology Inc. | Alpha-Olefin based branched polymer |
| US6968337B2 (en) * | 2001-07-10 | 2005-11-22 | Audible Magic Corporation | Method and apparatus for identifying an unknown work |
| EP1295926A1 (en) | 2001-09-19 | 2003-03-26 | ExxonMobil Chemical Patents Inc. | Components for adhesive compositions and process for manufacture |
| US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| US6794553B2 (en) | 2001-11-09 | 2004-09-21 | Shell Oil Company | Process for the telomerization of a conjugated diene, catalyst and bidentate ligand useful therein |
| JP2003313434A (en) * | 2002-02-25 | 2003-11-06 | Sumitomo Chem Co Ltd | Thermoplastic elastomer composition |
| US6753373B2 (en) | 2002-06-20 | 2004-06-22 | Kris W. Winowiecki | Polyolefin compositions and method of use thereof in molded products |
| US20030236852A1 (en) | 2002-06-20 | 2003-12-25 | International Business Machines Corporation | Sharing network adapter among multiple logical partitions in a data processing system |
| US6960375B2 (en) * | 2003-05-27 | 2005-11-01 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Bottle containing recycled polymers |
| US7928165B2 (en) | 2003-11-14 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Transparent and translucent crosslinked propylene-based elastomers, and their production and use |
| US20050234172A1 (en) | 2004-04-19 | 2005-10-20 | Fina Technology, Inc. | Random copolymer-impact copolymer blend |
| US8389615B2 (en) * | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
-
2004
- 2004-11-12 US US10/987,794 patent/US7928165B2/en not_active Expired - Fee Related
- 2004-11-12 CA CA 2545203 patent/CA2545203C/en not_active Expired - Fee Related
- 2004-11-12 WO PCT/US2004/037834 patent/WO2005049671A1/en active Application Filing
- 2004-11-12 CA CA 2546075 patent/CA2546075C/en not_active Expired - Fee Related
- 2004-11-12 US US10/988,162 patent/US7605217B2/en not_active Expired - Fee Related
- 2004-11-12 WO PCT/US2004/037833 patent/WO2005049670A1/en active Application Filing
- 2004-11-12 JP JP2006539915A patent/JP5244316B2/en active Active
- 2004-11-12 WO PCT/US2004/037875 patent/WO2005049672A1/en active Application Filing
- 2004-11-12 JP JP2006539908A patent/JP5525680B2/en active Active
- 2004-11-12 EP EP20040810851 patent/EP1687346B1/en active Active
- 2004-11-12 CN CN200480035710.2A patent/CN1890276B/en not_active Expired - Fee Related
- 2004-11-12 US US10/988,161 patent/US7390866B2/en active Active
- 2004-11-12 CN CN2004800334416A patent/CN1878799B/en not_active Expired - Fee Related
- 2004-11-12 EP EP20040801029 patent/EP1687345B1/en not_active Not-in-force
- 2004-11-12 US US10/987,670 patent/US8013093B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007511642A (en) | 2007-05-10 |
| CA2546075A1 (en) | 2005-06-02 |
| US20050107529A1 (en) | 2005-05-19 |
| CA2546075C (en) | 2010-12-14 |
| US8013093B2 (en) | 2011-09-06 |
| US7390866B2 (en) | 2008-06-24 |
| WO2005049672A1 (en) | 2005-06-02 |
| WO2005049671A1 (en) | 2005-06-02 |
| WO2005049670A1 (en) | 2005-06-02 |
| US20050107530A1 (en) | 2005-05-19 |
| EP1687345A1 (en) | 2006-08-09 |
| CA2545203C (en) | 2010-02-02 |
| EP1687346B1 (en) | 2012-06-06 |
| JP5525680B2 (en) | 2014-06-18 |
| US20050107534A1 (en) | 2005-05-19 |
| CN1878799A (en) | 2006-12-13 |
| EP1687345B1 (en) | 2013-12-25 |
| CN1878799B (en) | 2011-02-09 |
| JP2007511643A (en) | 2007-05-10 |
| JP5244316B2 (en) | 2013-07-24 |
| EP1687346A1 (en) | 2006-08-09 |
| US7605217B2 (en) | 2009-10-20 |
| CN1890276A (en) | 2007-01-03 |
| CN1890276B (en) | 2014-02-26 |
| US7928165B2 (en) | 2011-04-19 |
| US20050131142A1 (en) | 2005-06-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2545203A1 (en) | Transparent and translucent crosslinked propylene-based elastomers, and their production and use | |
| CA2577290A1 (en) | Polymeric compositions including their uses and methods of production | |
| EP1702956A3 (en) | Polyolefin compositions with improved properties | |
| EP0831125A4 (en) | Thermoplastic resin composition and products of injection molding thereof | |
| WO2006065799A3 (en) | Articles having improved clarity, prepared from propylene-ethylene copolymers | |
| WO2009064583A3 (en) | Fibers and non-wovens prepared with propylene-based elastomers | |
| CA2373271A1 (en) | Elastic fibers and articles made therefrom, including crystalline and crystallizable polymers of propylene | |
| WO2010077881A3 (en) | Thermoplastic polyolefin in-reactor blends and molded articles therefrom | |
| US20170253012A1 (en) | Polyolefin-based elastic film structures, laminates and methods thereof | |
| EP1731538A4 (en) | Multi-stage propylene polymer, process for producing the same, and propylene resin composition | |
| EP1837351A4 (en) | Polypropylene block copolymer, its use, and polypropylene resin composition comprising said polypropylene block copolymer | |
| WO2008121464A8 (en) | A polypropylene composition, a method of producing the same, and articles made therefrom | |
| EP1978070A4 (en) | Adhesive and layered product made with the same | |
| CA2093295C (en) | Film or molded article of a thermolastic with a terpolymer component | |
| EP0927743A4 (en) | Flexible polypropylene resin compositions, films or sheets made therefrom, and surface-protective films or sheets made therefrom | |
| PL1788022T3 (en) | Polypropylene resin with low shrinkage, high impact strength, stiffness and scratch resistance | |
| WO2008124040A8 (en) | Soft heterogeneous isotactic polyroplene compositions | |
| EP1106647A3 (en) | Propylene-based copolymer composition | |
| KR20140123268A (en) | Thermoplastic Elastomer Composition and Molded Article Using Same | |
| EP1195406A4 (en) | Polypropylene resin composition excellent in moldability and physical properties | |
| JP2010106200A (en) | Resin composition and sheet-like molded article made therefrom | |
| US5599865A (en) | Molded product of a polypropylene resin | |
| KR101981956B1 (en) | Composite composition for automobile parts and automobile parts formed therefrom | |
| US6906144B2 (en) | Polypropylene-based resin composition for powder slush molding | |
| WO2016048866A1 (en) | Polyolefin-based elastic film structures, laminates and methods thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20201112 |