CA2583268A1 - Self crosslinking waterborne coatings - Google Patents

Self crosslinking waterborne coatings Download PDF

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Publication number
CA2583268A1
CA2583268A1 CA002583268A CA2583268A CA2583268A1 CA 2583268 A1 CA2583268 A1 CA 2583268A1 CA 002583268 A CA002583268 A CA 002583268A CA 2583268 A CA2583268 A CA 2583268A CA 2583268 A1 CA2583268 A1 CA 2583268A1
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CA
Canada
Prior art keywords
coating
monomer
weight
poly
coating composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002583268A
Other languages
French (fr)
Other versions
CA2583268C (en
Inventor
Philip J. Ruhoff
Lynn O. Sabo
Janice K. Dreshar
Peter J. Mackulin
John M. Krajnik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sherwin Williams Co
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2583268A1 publication Critical patent/CA2583268A1/en
Application granted granted Critical
Publication of CA2583268C publication Critical patent/CA2583268C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/24—Homopolymers or copolymers of amides or imides
    • C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

An aqueous coating composition comprising (i) a binder resin having latent crosslinking functionality, (ii) a crosslink for the resin, and (iii) polymeric extender particles is disclosed.

Claims (21)

1. An aqueous coating composition comprising:

(i) a binder resin having latent crosslinking functionality;

(ii) an effective crosslinking amount of a crosslinker for the binder resin;
(iii) polymeric extender particles.
2. The coating of claim 1 wherein the latent crosslinking functionality comprises carbonyl groups.
3. The coating of claim 2 wherein the crosslinking agent is selected from the group consisting of di and poly amines, di and poly hydrazides, and di and poly hydrazines and mixtures thereof.
4. The coating of claim 1 wherein the binder resin is a latex resin.
5. The coating of claim 4 wherein the latex resin is the polymerized reaction product of a mixture of monomers comprising:

(i) about 1 to about 25% by weight of a monomer having latent crosslinking functionality;

(ii) about 0.5 to about 15% by weight of an acid functional monomer;

(iii) about 60 to about 98.5% of at least one other copolymerizable monomer.
6. The coating of claim 5 wherein the monomer having latent crosslinking functionality has pendent carbonyl groups as reactive crosslinking sites.
7. The coating of claim 2 wherein the crosslinker is selected from the group consisting of di and poly amines, di and poly hydrazides, and di and poly hydrazines.
8. The coating of claim 4 wherein the latex resin is the polymerized reaction product of a mixture of monomers comprising:

(i) about 1 to about 25% by weight of a monomer having latent crosslinking functionality;

(ii) about 0.5 to about 15% by weight of an acid functional monomer;
(iii) about 0.1 to about 10% of a wet adhesion promoting monomer; and (iv) about 50 to about 98.4% of at least one other copolymerizable monomer.
9. The coating of claim 8 wherein the monomer having latent crosslinking functionality has pendent carbonyl groups as reactive crosslinking sites.
10. The coating of claim 9 wherein the crosslinker is selected from the group consisting of di and poly amines, di and poly hydrazides, and di and poly hydrazines.
11. The coating of claim 4 wherein the latex resin is the polymerized reaction product of a mixture of monomers comprising:

(i) about 1 to about 25% by weight of a monomer having latent crosslinking functionality;

(ii) about 0.5 to about 15% by weight of an acid functional monomer;
(iii) about 0.1 to about 10% of a wet adhesion promoting monomer;
(iv) about 1 to about 55% by weight of styrene; and (v) zero to about 98.4% by weight of at least one other copolymerizable monomer.
12. The coating of claim 1 wherein the extender particles comprise polyvinyl chloride particles.
13. The coating of claim 12 wherein the polyvinyl chloride particles have an average particle size greater than 5 microns.
14. The coating of claim 13 wherein the polyvinyl chloride particles have an average particle size of 5 to about 150 microns.
15. The coating of claim 12 wherein the polyvinyl chloride extender particles are homopolymers of vinyl chloride.
16. The coating composition of claim 1 wherein the polymeric extender particles are present at about 5 to about 60 weight percent on a solids basis of the coating composition.
17. The coating composition of claim 16 wherein the polymeric extender particles are present at a level of about 25 to about 50 weight per cent on a solids basis of the coating composition.
18. The coating composition of claim 1 wherein the crosslinker is present at a level to provide at least 0.1 equivalent for each equivalent of latent crosslinking functionality.
19. The coating composition of claim 1 wherein the crosslinker is present at a level to provide about 0.2 to about 2.0 equivalents for each equivalent of latent crosslinking functionality.
20. The coating composition of claim 1 wherein the crosslinker is present at a level to provide about 0.4 to about 1.2 equivalents for each equivalent of latent crosslinking functionality.
21. A coating composition comprising:

(i) a binder resin obtained by polymerizing a monomer mixture comprising:
(a) about 1 to about 25% by weight of a monomer having carbonyl latent crosslinking functionality;

(b) about 0.5 to about 15% by weight of an acid functional monomer;
(c) about 0.1 to about 10% of a wet adhesion promoting monomer; and (d) about 50 to about 98.4% of at least one other copolymerizable monomer.

(ii) a crosslinker selected from the group consisting of di and poly amines, di and poly hydrazides, and di and poly hydrazines;

(iii) polyvinyl chloride extender particles.
CA2583268A 2004-10-08 2005-10-07 Self crosslinking waterborne coatings Expired - Fee Related CA2583268C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US61745004P 2004-10-08 2004-10-08
US60/617,450 2004-10-08
PCT/US2005/036404 WO2006042220A1 (en) 2004-10-08 2005-10-07 Self crosslinking waterborne coatings

Publications (2)

Publication Number Publication Date
CA2583268A1 true CA2583268A1 (en) 2006-04-20
CA2583268C CA2583268C (en) 2011-02-22

Family

ID=35696011

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2583268A Expired - Fee Related CA2583268C (en) 2004-10-08 2005-10-07 Self crosslinking waterborne coatings

Country Status (6)

Country Link
US (1) US20070135567A1 (en)
EP (1) EP1799782B1 (en)
BR (1) BRPI0518234A2 (en)
CA (1) CA2583268C (en)
MX (1) MX2007004011A (en)
WO (1) WO2006042220A1 (en)

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Also Published As

Publication number Publication date
EP1799782B1 (en) 2012-12-12
CA2583268C (en) 2011-02-22
MX2007004011A (en) 2007-05-23
US20070135567A1 (en) 2007-06-14
EP1799782A1 (en) 2007-06-27
WO2006042220A1 (en) 2006-04-20
BRPI0518234A2 (en) 2008-11-11

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