CA2588770A1 - Homogeneous polymer blend and articles therefrom - Google Patents
Homogeneous polymer blend and articles therefrom Download PDFInfo
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- CA2588770A1 CA2588770A1 CA002588770A CA2588770A CA2588770A1 CA 2588770 A1 CA2588770 A1 CA 2588770A1 CA 002588770 A CA002588770 A CA 002588770A CA 2588770 A CA2588770 A CA 2588770A CA 2588770 A1 CA2588770 A1 CA 2588770A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Abstract
This invention relates to homogeneous blends of: 1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight % alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170° C. and a melt flow rate of 200 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having: a) 10 to 50 percent crystallinity or less; b) a melt flow rate of 200 dg/min or less; c) a DSC melting point (second melt Tm) of 130° C. or less; d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt % comonomer content with a difference of no greater than 20 wt % relative to the average wt % comonomer content of the copolymer; e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, for use in films, fibers, non-wovens, molded articles and the like.
Claims (100)
1. A film comprising a homogeneous blend of:
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170°C
and a melt flow rate of 200 dg/min or less preferably the semi-crystalline polymer is a homopolymer, preferably of propylene); and
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170°C
and a melt flow rate of 200 dg/min or less preferably the semi-crystalline polymer is a homopolymer, preferably of propylene); and
2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 10 to 50 percent crystallinity;
b) a melt flow rate of 200 dg/min or less;
c) a DSC melting point (second melt Tm) of 130°C or less;
d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer;
e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend has:
i) a melt flow rate of 0.5 to 100 dg/min; and ii) less than 5 weight % filler, based upon the weight of the polymers and the filler; and iii) a permanent set of greater than 65%; and where the film has:
1) a thickness of 2.5 to 635 microns;
2) a haze of 10% or less, prior to addition of clarifying or nucleating agents;
a) 10 to 50 percent crystallinity;
b) a melt flow rate of 200 dg/min or less;
c) a DSC melting point (second melt Tm) of 130°C or less;
d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer;
e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend has:
i) a melt flow rate of 0.5 to 100 dg/min; and ii) less than 5 weight % filler, based upon the weight of the polymers and the filler; and iii) a permanent set of greater than 65%; and where the film has:
1) a thickness of 2.5 to 635 microns;
2) a haze of 10% or less, prior to addition of clarifying or nucleating agents;
3) a 45 degree gloss of 85 or more;
4) a 1° Secant tensile modulus of 860 to 205 MPa;
5) an Elmendorf tear in the machine direction of 1.57 g/micron or more;
6) an Elmendorf tear in the transverse direction of 1.57 g/micron or more;
and
and
7) a total energy impact at 23 °C of 2.7 J or more.
2. The film of claim 1 wherein the difference in comonomer content is no greater than 10 weight%.
3. The film of claim 1 or 2 wherein the composition distribution of the semi-amorphous copolymer is 90 or more.
4. The film of any of claims 1 to 3 wherein the film has a machine direction Elmendorf Tear or 2.16 g/micron or greater.
5. The film of any of claims 1 to 4 wherein the film has a Total energy impact of 4 J or greater.
6. The film of any of claims 1 to 5 wherein the film has a Puncture Energy of 0.12 J/micron or greater.
7. The film of any of claims 1 to 6 wherein the film has a 1% Secant tensile modulus of 518 MPa or lower.
2. The film of claim 1 wherein the difference in comonomer content is no greater than 10 weight%.
3. The film of claim 1 or 2 wherein the composition distribution of the semi-amorphous copolymer is 90 or more.
4. The film of any of claims 1 to 3 wherein the film has a machine direction Elmendorf Tear or 2.16 g/micron or greater.
5. The film of any of claims 1 to 4 wherein the film has a Total energy impact of 4 J or greater.
6. The film of any of claims 1 to 5 wherein the film has a Puncture Energy of 0.12 J/micron or greater.
7. The film of any of claims 1 to 6 wherein the film has a 1% Secant tensile modulus of 518 MPa or lower.
8. The film of any of claims 1 to 7 wherein the film has a haze of 5% or less.
9. The film of any of paragraphs 1 to 8 wherein the film has a 45 degree gloss of 88 units or greater.
10. The film of any of claims 1 to 9 wherein the film has a 1% secant tensile modulus of 690 MPa or less, an MD Elmendorf Tear of 1.77 g/micron or more, a haze of 2% or lower, a 45 degree gloss of 88 units or higher, and a Total energy impact at 23°C of 4 J or greater.
11. The film of any of paragraphs 1 to 10 wherein the film has a 1% secant tensile modulus of 518 MPa or lower, an MD Elmendorf tear of 2.16 g/microns or greater, a haze of 2% or lower, a 45 degree gloss of 88 units or higher, and a Total energy impact at 23 °C of 4.75J or greater.
12. The film of any of paragraphs 1 to 11 wherein the blend has a permanent set of 85% or greater.
13. A molded article comprising a homogeneous blend of 1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170°C
and a melt flow rate of 200 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight %
of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 10 to 50 percent crystallinity or less;
b) a melt flow rate of 200 dg/min or less;
c) a DSC melting point (second melt Tm) of 130°C or less;
d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer;
e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend has:
i) a melt flow rate of 0.5 to 200 dg/min; and ii) less than 5 weight % filler, based upon the weight of the polymers and the filler; and iii) a permanent set of greater than 65%; and iv) a haze of 12% or less measured on a 1 mm thick injection molded chip, where the molded article has:
1) a thickness of 250 µm to 10 mm;
2) a 1% Secant Flexural Modulus at 23 °C of 1035 MPa or less;
3) a Gardner Impact Strength at 23°C of 11.3 J or more; and 4) a Gardner Impact Strength at 0°C of 50 5.6 J or more.
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170°C
and a melt flow rate of 200 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight %
of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 10 to 50 percent crystallinity or less;
b) a melt flow rate of 200 dg/min or less;
c) a DSC melting point (second melt Tm) of 130°C or less;
d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer;
e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend has:
i) a melt flow rate of 0.5 to 200 dg/min; and ii) less than 5 weight % filler, based upon the weight of the polymers and the filler; and iii) a permanent set of greater than 65%; and iv) a haze of 12% or less measured on a 1 mm thick injection molded chip, where the molded article has:
1) a thickness of 250 µm to 10 mm;
2) a 1% Secant Flexural Modulus at 23 °C of 1035 MPa or less;
3) a Gardner Impact Strength at 23°C of 11.3 J or more; and 4) a Gardner Impact Strength at 0°C of 50 5.6 J or more.
14. The molded article of claim 13 wherein the molded article has a Notched Izod Impact Strength at 23°C of 53J/m or more.
15. The molded article of claim 13 or 14 wherein the molded article has a Gardner Impact Strength at 23°C of 22.6 J or more.
16. The molded article of any of claims 13 to 15 wherein the molded article has a Notched Izod Impact Strength at 23°C of 80 J/m or more.
17. The molded article of any of claims 13 to 16 wherein the molded article has a Gardner Impact Strength at 23°C of 22.6 J or more with failure being in ductile mode.
18. The molded article of any of claims 13 to 17 wherein the molded article has an Ultimate Elongation at 23 °C of 1000% or more.
19. The molded article of any of claims 13 to 18 where the difference in comonomer content is no greater than 10 weight%.
20. The molded article of any of claims 13 to 19 wherein the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more.
21. The molded article of any of claims 13 to 20 wherein the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more and the difference in comonomer content is no greater than 10 weight%.
22. The molded article of any of claims 13 to 21 wherein the molded article has a 1% secant flexural modulus at 23 °C of less than 690 MPa.
23. The molded article of any of claims 13 to 22 wherein the blend has a haze of less than 10%.
24. The molded article of any of claims 13 to 23 wherein the molded article has a 1% secant flexural modulus at 23 °C of less than 690 MPa, an ultimate elongation at 23 °C of greater than 1000%, a Gardner at both 23°C and 0°C of greater than 22.6 J, an Instrumented impact at both 23°C and 0°C
of greater than 27.1 J.
of greater than 27.1 J.
25. The molded article of any of claims 13 to 24 wherein the molded article has a 1% secant flexural modulus less than 690 MPa, a notched Izod impact strength at 23°C of greater than 80 J/m, an Instrumented impact at both 23°C and 0°C of greater than 27.1J where failures are all in ductile mode.
26. The molded article of any of claims 13 to 25 wherein the blend has permanent set of 85% or greater.
27. The molded article of any of claims 13 to 26 wherein the blend has permanent set of 150% or greater.
28. The molded article of any of claims 13 to 27 where in the semi-crystalline polymer is a propylene homopolymer.
29. The molded article of any of claims 13 to 28 wherein the semi-amorphous polymer has a heat of fusion of from 10 to 40 J/g.
30. The molded article of any of claims 13 to 29 wherein the semi-crystalline polymer has a melting point of from 125 to 160°C.
31. The molded article of any of claims 13 to 30 wherein the semi-amorphous polymer has a melting point of from 35 to 100°C.
32. A non-woven comprising a homogeneous blend of:
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight % alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170°C and a melt flow rate of 2000 dg/min or less (preferably the semi-crystalline polymer is a homopolymer, preferably of propylene); and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) less than 50 percent crystallinity;
b) a melt flow rate of 2000 dg/min or less;
c) a DSC melting point (second melt Tm) of 130°C or less;
d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend has:
i) a melt flow rate of 1 to 2000 dg/min; and ii) less than 5 weight % filler, based upon the weight of the polymers and the filler, iii) a permanent set of greater than 65%; and iv) a haze of 12 % or less measured on a 1 mm thick injection molded chip where the non-woven has:
1) a Hand of 40 g or less for 35 g/sm fabrics;
2) an optimum bonding temperature at least 5°C lower than the optimum bonding temperature for the same nonwoven article made from the same composition except that the semi-amorphous copolymer is absent.
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight % alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170°C and a melt flow rate of 2000 dg/min or less (preferably the semi-crystalline polymer is a homopolymer, preferably of propylene); and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) less than 50 percent crystallinity;
b) a melt flow rate of 2000 dg/min or less;
c) a DSC melting point (second melt Tm) of 130°C or less;
d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend has:
i) a melt flow rate of 1 to 2000 dg/min; and ii) less than 5 weight % filler, based upon the weight of the polymers and the filler, iii) a permanent set of greater than 65%; and iv) a haze of 12 % or less measured on a 1 mm thick injection molded chip where the non-woven has:
1) a Hand of 40 g or less for 35 g/sm fabrics;
2) an optimum bonding temperature at least 5°C lower than the optimum bonding temperature for the same nonwoven article made from the same composition except that the semi-amorphous copolymer is absent.
33. The non-woven of claim 32 wherein the nonwoven has a hand on 35 g/sm fabric of 30 g or less, preferably 20 g or less, preferably 15 g or less.
34. The non-woven of claim 32 or 33 wherein the nonwoven has an optimum bonding temperature at least 7.5°C lower than the optimum bonding temperature for the same nonwoven made from the same composition except that the semi-amorphous copolymer is absent.
35. The non-woven of any of paragraphs 32 to 34 wherein the nonwoven has an optimum bonding temperature at least 10°C lower than the optimum bonding temperature for the same nonwoven made from the same composition except that the semi-amorphous copolymer is absent.
36. The non-woven of any of paragraphs 32 to 35 wherein at 35 g/sm the non-woven has a hand of 30 g or lower and a TD peak tensile load under optimum bonding of 3180 g force or greater.
37. The non-woven of. any of claims 32 to 36 wherein the difference in comonomer content is no greater than 10 weight%.
38. The non-woven of any of claims 32 to 37 wherein the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more.
39. The non-woven of any of claims 32 to 38 wherein the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more and the difference in comonomer content is no greater than 10 weight%.
40. The non-woven of any of claims 32 to 39 wherein the blend has a haze of less than 10%.
41. The non-woven of any of claims 32 to 40 wherein the blend comprises from 1 to 5000 ppm of a slip agent.
42. The non-woven of any of claims 32 to 41 wherein the blend comprises a nucleating agent.
43. The non-woven of any of claims 32 to 42 wherein the blend further comprises nucleating agent selected from the group consisting of adipic acid, benzoic acid, or metal salts of these acids, sorbitols, and 3,4-dimethylbenzylidene sorbitol.
44. A homogeneous polymer blend comprising:
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C 10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity or less;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler,, where the blend has:
a) a permanent set of greater than 65%;
b) a haze of 20% or less;
c) a melt flow rate of 1 to 50 dg/min; and d) optionally, a heat deflection temperature of 45°C or more.
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C 10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity or less;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler,, where the blend has:
a) a permanent set of greater than 65%;
b) a haze of 20% or less;
c) a melt flow rate of 1 to 50 dg/min; and d) optionally, a heat deflection temperature of 45°C or more.
45. The composition of claim 44 the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more and/or the difference in comonomer content is no greater than 10 weight%.
46. The composition of claim 44 or 45 wherein the blend has a permanent set of 85% or greater, preferably 100% or greater, preferably 150% or greater.
47. The composition of any of claims 44 to 46 wherein the blend comprises from 1 to 5000 ppm of a slip agent.
48. The composition of any of claims 44 to 47 wherein the blend comprises a nucleating agent.
49. The composition of any of claims 44 to 48 wherein the semi-crystalline polymer comprises propylene and from 1 to 3 weight % of one or more comonomers selected from the group consisting of ethylene, butene, pentene, hexene, heptene, octene, nonene, and decene.
50. The composition of any of claims 44 to 49 wherein the semi-crystalline polymer is a propylene homopolymer.
51. The composition of any of claims 44 to 50 wherein the semi-amorphous polymer has a heat of fusion of from 10 to 40 J/g.
52. The composition of any of claims 44 to 51 wherein the semi-amorphous polymer has a melting point of from 35 to 100°C.
53. A film comprising a homogeneous polymer blend comprising:
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity or less;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler, where the blend has:
a) a permanent set of greater than 65%;
b) a haze of 20% or less;
c) a melt flow rate of 0.5 to 100 dg/min, and where the film has:
1) a thickness of 0.1 to 25 mils (2.5 to 635 microns);
2) a haze of 20% or less, prior to addition of clarifying or nucleating agents;
3) a 1° Secant flexural modulus of 860 to 205 MPa;
4) an Elmendorf tear in the machine direction 1.57 g/micron or more;
5) an Elmendorf tear in the transverse direction of 1.57 g/micron or more;
and 6) a total energy impact at 23 °C of 2.7 J or more.
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity or less;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler, where the blend has:
a) a permanent set of greater than 65%;
b) a haze of 20% or less;
c) a melt flow rate of 0.5 to 100 dg/min, and where the film has:
1) a thickness of 0.1 to 25 mils (2.5 to 635 microns);
2) a haze of 20% or less, prior to addition of clarifying or nucleating agents;
3) a 1° Secant flexural modulus of 860 to 205 MPa;
4) an Elmendorf tear in the machine direction 1.57 g/micron or more;
5) an Elmendorf tear in the transverse direction of 1.57 g/micron or more;
and 6) a total energy impact at 23 °C of 2.7 J or more.
54. The film of claim 53 wherein the difference in comonomer content is no greater than 10 weight%
55. The film of claim 53 or 54 the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more.
56. The film of any of claims 53 to 55 wherein the film has a machine direction Elmendorf Tear or 2.16 g/micron or greater.
57. The film of any of claims 53 to 56 wherein the film has a Total energy impact of 4 J or greater.
58. The film of any of claims 53 to 57 wherein the film has a Puncture Energy of 0.12 J/micron or greater.
59. The film of any of claims 53 to 58 wherein the film has a 1% Secant tensile modulus of 518 MPa or lower.
60. The film of any of claims 53 to 59 wherein the film has a haze of 5% or less.
61. The film of any of claims 53 to 60 wherein the film has a 45 degree gloss of 88 units or greater.
62. The film of any of claims 53 to 61 wherein the film has a 1% secant tensile modulus of 690 MPa or less, an MD Elmendorf Tear of 1.77 g/micron or more, a haze or 2% or lower, a 45 degree gloss of 88 units or higher, and a Total energy impact at 23°C of 4 J or greater.
63. The film of any of claims 53 to 63 wherein the film has a 1% secant tensile modulus of 518 MPa or lower, an MD Elmendorf tear of 2.16 g/microns or greater, a haze of 2% or lower, a 45 degree gloss of 88 units or higher, and a Total energy impact at 23 °C of 4.75J or greater.
64. The film of any of claims 53 to 63 wherein the blend has a permanent set of 85% or greater.
65. The film of any of claims 53 to 64 wherein the blend comprises from 1 to 5000 ppm of a slip agent.
66. The film of any of claims 53 to 65 wherein the blend comprises a nucleating agent.
67. The film of any of claims 53 to 66 wherein the semi-crystalline polymer comprises propylene and from 1 to 3 weight % of one or more comonomers selected from the group consisting of ethylene, butene, pentene, hexene, heptene, octene, nonene, and decene.
68. The film of any of claims 53 to 67 wherein the semi-crystalline polymer is a propylene homopolymer.
69. The film of any of claims 53 to 68 wherein the semi-amorphous polymer has a heat of fusion of from 10 to 40 J/g.
70. The film of any of claims 53 to 69 wherein the semi-amorphous polymer has a melting point of from 35 to 100°C.
71. A fiber comprising a homogeneous polymer blend comprising:
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer;
e) an Mw/Mn of 1.5 to 4; and f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend:
1) comprises less than 5 weight % filler, based upon the weight of the polymers and the filler;
2) has a permanent set of greater than 65%;
3) has a haze of 20% or less; and 4) has a melt flow rateof from 1 to 50 dg/min, and where the fiber has:
1) a Hand of 40 g or less when converted into spunbond fabric of 35 g/sm fabrics basis weight.
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer;
e) an Mw/Mn of 1.5 to 4; and f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, where the blend:
1) comprises less than 5 weight % filler, based upon the weight of the polymers and the filler;
2) has a permanent set of greater than 65%;
3) has a haze of 20% or less; and 4) has a melt flow rateof from 1 to 50 dg/min, and where the fiber has:
1) a Hand of 40 g or less when converted into spunbond fabric of 35 g/sm fabrics basis weight.
72. A non-woven comprising a homogeneous polymer blend comprising:
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler, where the blend has:
a) a permanent set of greater than 65%;
b) a haze of 20% or less; and c) melt flow rate of 1 to 2000 dg/min, and and where the non-woven has:
1) a Hand of 40 g or less for 35 g/sm fabrics;
2) an optimum bonding temperature at least 5°C lower than the optimum bonding temperature for the same nonwoven article made from the same composition except that the semi-amorphous copolymer is absent.
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler, where the blend has:
a) a permanent set of greater than 65%;
b) a haze of 20% or less; and c) melt flow rate of 1 to 2000 dg/min, and and where the non-woven has:
1) a Hand of 40 g or less for 35 g/sm fabrics;
2) an optimum bonding temperature at least 5°C lower than the optimum bonding temperature for the same nonwoven article made from the same composition except that the semi-amorphous copolymer is absent.
73. The non-woven of claim 72 wherein the nonwoven has a hand on 35 g/sm fabric of 30 g or less.
74. The non-woven of claim 72 or 73 wherein the nonwoven has an optimum bonding temperature at least 7.5°C lower than the optimum bonding temperature for the same nonwoven made from the same composition except that the semi-amorphous copolymer is absent.
75. The non-woven of any of claims 72 to 74 wherein the nonwoven has an optimum bonding temperature at least 10°C lower than the optimum bonding temperature for the same nonwoven made from the same composition except that the semi-amorphous copolymer is absent.
76. The non-woven of any of claims 72 to 75 wherein at 35 g/sm the non-woven has a hand of 30 g or lower and a TD peak tensile load under optimum bonding of 3180 g force or greater.
77. The fiber of claim 71 or the non-woven of any of claims 72 to 76 the difference in comonomer'content is no greater than 10 weight%.
78. The fiber of claim 71 or the non-woven of any of claims 72 to 77 wherein the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more.
79. The fiber of claim 71 or the non-woven of any of claims 72 to 78 wherein the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more and the difference in comonomer content is no greater than 10 weight%.
80. The fiber of claim 71 or the non-woven of any of claims 72 to 79 wherein the blend has a haze of less than 10%.
81. The fiber of claim 71 or the non-woven of any of claims 72 to 80 wherein the blend comprises from 1 to 5000 ppm of a slip agent.
82. The fiber of claim 71 or the non-woven of any of claims 72 to 81 wherein the blend comprises a nucleating agent selected from the group consisting of adipic acid, benzoic acid, or metal salts of these acids, sorbitols, and 3,4-dimethylbenzylidene sorbitol.
83. A molded article comprising a homogeneous polymer blend comprising:
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler, where the blend has:
i) a melt flow rate of 0.5 to 200 dg/min; and ii) optionally, less than 5 weight % filler, based upon the weight of the polymers and the filler; and iii) a permanent set of greater than 65%; and iv) a haze of 12% or less measured on a 1 mm thick injection molded chip;
and v) optionally, a heat deflection temperature of 45°C or more, where the molded article has:
1) a thickness of 250 µm to 10 mm;
2) a 1% Secant Flexural Modulus at 23 °C of 1035 MPa or less;
3) a Gardner Impact Strength at 23°C of 11.3 J or more; and 4) a Gardner Impact Strength at 0°C of 5.6 J or more.
1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight %
alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 160°C
and a melt flow rate of 50 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having:
a) 8 to 35 percent crystallinity;
b) a melt flow rate of 1 to 50 dg/min;
c) a DSC melting point (second melt Tm) of 90°C or less;
d) an intermolecular composition distribution compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt% comonomer content with a difference of no greater than 20 wt% relative to the average wt% comonomer content of the copolymer; and e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, and g) the blend comprises less than 5 weight % filler, based upon the weight of the polymers and the filler, where the blend has:
i) a melt flow rate of 0.5 to 200 dg/min; and ii) optionally, less than 5 weight % filler, based upon the weight of the polymers and the filler; and iii) a permanent set of greater than 65%; and iv) a haze of 12% or less measured on a 1 mm thick injection molded chip;
and v) optionally, a heat deflection temperature of 45°C or more, where the molded article has:
1) a thickness of 250 µm to 10 mm;
2) a 1% Secant Flexural Modulus at 23 °C of 1035 MPa or less;
3) a Gardner Impact Strength at 23°C of 11.3 J or more; and 4) a Gardner Impact Strength at 0°C of 5.6 J or more.
84. The molded article of claim 83 wherein the molded article has a Notched Izod Impact Strength at 23°C of 53J/m or more.
85. The molded article of claim 83 or 84 wherein the molded article has a Gardner Impact Strength at 23°C of 22.6 J or more.
86. The molded article of any of claims 83 to 85 wherein the molded article has a Notched Izod Impact Strength at 23°C of 80 J/m or more.
87. The molded article of any of claims 83 to 86 wherein the molded article has a Gardner Impact Strength at 23°C of 22.6 J or more with failure being in ductile mode.
88. The molded article of any of claims 83 to 87 wherein the molded article has an Ultimate Elongation at 23 °C of 1000% or more.
89. The molded article of any of claims 83 to 88 wherein the difference in comonomer content is no greater than 10 weight%.
90. The molded article of any of claims 83 to 89 the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more.
91. The molded article of any of claims 83 to 90 wherein the intermolecular composition distribution of the semi-amorphous copolymer is 90% or more and the difference in comonomer content is no greater than 10 weight%.
92. The molded article of any of claims 83 to 91 wherein the molded article has a 1% secant flexural modulus at 23 °C of less than 690 MPa.
93. The molded article of any of claims 83 to 92 wherein the blend has a haze of less than 10%.
94. The molded article of any of claims 83 to 93 wherein the molded article has a 1% secant flexural modulus at 23 °C of less than 690 MPa, an ultimate elongation at 23 °C of greater than 1000%, a Gardner at both 23°C and 0°C of greater than 22.6 J, an Instrumented impact at both 23°C and 0°C
of greater than 27.1 J.
of greater than 27.1 J.
95. The molded article of any of claims 83 to 94 wherein the molded article has a 1% secant flexural modulus less than 690 MPa, a notched Izod impact strength at 23°C of greater than 80 J/m, an Instrumented impact at both 23°C and 0°C of greater than 27.1J where failures are all in ductile mode.
96. The molded article of any of claims 83 to 95 wherein the blend has permanent set of 85% or greater.
97. The molded article of any of claims 83 to 96 where in the semi-crystalline polymer is a propylene homopolymer.
98. The molded article of any of claims 83 to 97 wherein the semi-amorphous polymer has a heat of fusion of from 10 to 40 J/g.
99. The molded article of any of claims 83 to 98 wherein the semi-crystalline polymer has a melting point of from 125 to 160°C.
100. The molded article of any of claims 83 to 99 wherein the semi-amorphous polymer has a melting point of from 35 to 100°C.
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63742904P | 2004-12-17 | 2004-12-17 | |
| US60/637,429 | 2004-12-17 | ||
| US65531005P | 2005-02-22 | 2005-02-22 | |
| US65561205P | 2005-02-22 | 2005-02-22 | |
| US60/655,612 | 2005-02-22 | ||
| US60/655,310 | 2005-02-22 | ||
| PCT/US2005/044615 WO2006065648A1 (en) | 2004-12-17 | 2005-12-09 | Homogeneous polymer blend and articles therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2588770A1 true CA2588770A1 (en) | 2006-06-22 |
| CA2588770C CA2588770C (en) | 2010-03-23 |
Family
ID=36089234
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2588770A Expired - Fee Related CA2588770C (en) | 2004-12-17 | 2005-12-09 | Homogeneous polymer blend and articles therefrom |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7619038B2 (en) |
| EP (1) | EP1831304B1 (en) |
| JP (1) | JP4782800B2 (en) |
| AT (1) | ATE467658T1 (en) |
| CA (1) | CA2588770C (en) |
| DE (1) | DE602005021248D1 (en) |
| WO (1) | WO2006065648A1 (en) |
Families Citing this family (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| EP1530611B1 (en) | 2002-08-12 | 2013-12-04 | ExxonMobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7662885B2 (en) * | 2002-08-12 | 2010-02-16 | Exxonmobil Chemical Patents Inc. | Method to make an article comprising polymer concentrate |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US8466235B2 (en) * | 2002-08-27 | 2013-06-18 | Braskem America, Inc. | Polypropylene blends for non-woven production |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| EP1833910B1 (en) * | 2004-12-17 | 2009-08-26 | ExxonMobil Chemical Patents Inc. | Polymer blends and nonwoven articles therefrom |
| EP1828303B1 (en) * | 2004-12-17 | 2009-08-26 | ExxonMobil Chemical Patents, Inc., A Corporation of the State of Delaware | Heterogeneous polymer blends and molded articles therefrom |
| US20060240733A1 (en) * | 2005-04-25 | 2006-10-26 | Fina Technology, Inc. | Fibers and fabrics prepared from blends of homopolymers and copolymers |
| US7928164B2 (en) * | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
| US7951872B2 (en) * | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
| US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
| US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
| JP5438966B2 (en) | 2005-07-15 | 2014-03-12 | エクソンモービル・ケミカル・パテンツ・インク | Elastomer composition |
| KR101364329B1 (en) * | 2006-02-02 | 2014-02-18 | 바젤 폴리올레핀 게엠베하 | Propylene melt blown resins, propylene melt blown resin fibers and non-woven fabric made from the same, and methods of making the same |
| EP1840164A1 (en) * | 2006-03-30 | 2007-10-03 | SOLVAY INDUSTRIAL FOILS MANAGEMENT AND RESEARCH (Société Anonyme) | Retortable composition |
| US20080061468A1 (en) * | 2006-09-07 | 2008-03-13 | Frank Li | Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators |
| US7589138B2 (en) * | 2006-12-05 | 2009-09-15 | Fina Technology, Inc. | Injection molding process |
| EP2205674B1 (en) * | 2007-10-22 | 2019-04-17 | Trinseo Europe GmbH | Polymeric compositions and processes for molding articles |
| US7906588B2 (en) * | 2007-10-26 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Soft heterogeneous isotactic polypropylene compositions |
| US20090111945A1 (en) * | 2007-10-26 | 2009-04-30 | Sudhin Datta | Soft Homogeneous Isotactic Polypropylene Compositions |
| WO2009058313A1 (en) | 2007-10-30 | 2009-05-07 | Milliken & Company | Additive composition and thermoplastic compositions comprising the same |
| KR101195707B1 (en) * | 2007-12-20 | 2012-10-29 | 가부시키가이샤 호소카와 요코 | Multilayered body for medical containers and medical container |
| HUP0700828A2 (en) * | 2007-12-20 | 2010-01-28 | Richter Gedeon Nyrt | Transdermal pharmaceutical compositions containing tolperisone alone and in combination |
| US8710148B2 (en) | 2011-12-02 | 2014-04-29 | Exxonmobil Chemical Patents Inc. | Polymer compositions and nonwoven compositions prepared therefrom |
| US20100125114A1 (en) * | 2008-11-14 | 2010-05-20 | Williams Michael G | Propylene-Based Film Compositions |
| US8029633B2 (en) * | 2009-01-27 | 2011-10-04 | Milliken & Company | Method of forming a consolidated fibrous structure |
| US7960024B2 (en) * | 2009-01-27 | 2011-06-14 | Milliken & Company | Multi-layered fiber |
| US8119549B2 (en) * | 2009-01-27 | 2012-02-21 | Milliken & Company | Consolidated fibrous structure |
| US8114507B2 (en) * | 2009-01-27 | 2012-02-14 | Milliken & Company | Multi-layered fiber |
| US8147957B2 (en) * | 2009-01-27 | 2012-04-03 | Milliken & Company | Consolidated fibrous structure |
| US20110059277A1 (en) * | 2009-09-04 | 2011-03-10 | Rainer Kolb | Elastomeric Surface Coatings for Plastic Articles |
| US8217116B2 (en) * | 2009-07-15 | 2012-07-10 | Braskem America, Inc. | Polypropylene composition for buried structures |
| WO2011030893A1 (en) * | 2009-09-14 | 2011-03-17 | 出光興産株式会社 | Spun-bonded nonwoven fabric and fiber product |
| US9442220B2 (en) * | 2010-08-30 | 2016-09-13 | Samsung Electronics Co., Ltd. | Composition for polarizing film, polarizing film, method of manufacturing the same, and liquid crystal display provided with the polarizing film |
| GB2491575B (en) | 2011-06-02 | 2013-11-27 | Innovia Films Ltd | Package |
| FI125678B (en) * | 2011-08-26 | 2016-01-15 | Bioretec Oy | BIOABSORABLE, ORIENTED, DEFORMABLE FIXATION MATERIAL AND DISC |
| CN103917701B (en) * | 2011-08-30 | 2016-06-29 | 道达尔研究技术弗吕公司 | Comprise the fiber of random copolymer of propylene and the manufacture method of non-woven fleece and described fiber |
| ES2634514T3 (en) * | 2012-02-24 | 2017-09-28 | Borealis Ag | Fiber quality with improved spinning performance and mechanical properties |
| JP5931207B2 (en) | 2012-09-27 | 2016-06-08 | 三井化学株式会社 | Spunbond nonwoven fabric |
| JP6181662B2 (en) * | 2012-10-25 | 2017-08-16 | 出光興産株式会社 | Polyolefin molded body |
| EP2925795B1 (en) | 2012-12-03 | 2018-12-26 | ExxonMobil Chemical Patents Inc. | Propylene polymers |
| US9322114B2 (en) | 2012-12-03 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Polypropylene fibers and fabrics |
| US20150353718A1 (en) * | 2013-02-28 | 2015-12-10 | Dow Global Technologies Llc | A blend composition suitable for injection molding applications |
| CN105264134B (en) | 2013-03-12 | 2019-07-30 | 博爱无纺布公司 | Extendible adhesive-bonded fabric |
| EP3064547A4 (en) * | 2013-10-31 | 2017-06-14 | Idemitsu Kosan Co., Ltd | Polyolefin composition, oriented polyolefin film, and production method for same |
| CN105722485B (en) * | 2013-11-20 | 2020-02-11 | 金伯利-克拉克环球有限公司 | Absorbent article comprising a soft and durable backsheet |
| WO2015075631A1 (en) * | 2013-11-20 | 2015-05-28 | Kimberly-Clark Worldwide, Inc. | Soft and durable nonwoven composite |
| BR212016015230U2 (en) * | 2013-12-30 | 2016-09-27 | Corning Optical Comm Llc | composite film for a fiber optic cable |
| CN106104346A (en) * | 2013-12-30 | 2016-11-09 | 康宁光电通信有限责任公司 | There are the fiber optic cables of inflaming retarding membrane |
| WO2015102816A1 (en) * | 2013-12-30 | 2015-07-09 | Corning Optical Communications LLC | Fiber optic cable with sleeve |
| US10150858B2 (en) * | 2014-02-11 | 2018-12-11 | Flint Hills Resources, Lp | Blended compositions, methods for making same, and articles made therefrom |
| JP6340091B2 (en) * | 2014-07-15 | 2018-06-06 | ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓ Ａｇ | Phthalate-free nucleated PP homopolymer for meltblown fibers |
| CN107073162A (en) * | 2014-11-18 | 2017-08-18 | 金伯利-克拉克环球有限公司 | Soft and durable nonwoven web |
| US10654620B2 (en) | 2015-10-27 | 2020-05-19 | Berry Plastics Corporation | Multi-layer film |
| US10603884B2 (en) | 2016-07-07 | 2020-03-31 | Berry Plastics Corporation | Multi-layer film |
| GB2604452B (en) | 2018-01-24 | 2022-12-28 | Nike Innovate Cv | A resin composition |
| US20220002923A1 (en) * | 2018-11-23 | 2022-01-06 | Sabic Global Technologies B.V. | Composition for making spun bond nonwoven fabric |
| US11492474B2 (en) | 2018-12-27 | 2022-11-08 | Exxonmobil Chemicals Patents Inc. | Slit film tape compositions |
| EP3849369B1 (en) | 2019-07-19 | 2022-03-02 | Nike Innovate C.V. | Sole structures including polyolefin plates and articles of footwear formed therefrom |
| WO2021016039A1 (en) | 2019-07-19 | 2021-01-28 | Nike Innovate C.V. | Articles of footwear including sole structures and rand |
| WO2021262977A1 (en) * | 2020-06-26 | 2021-12-30 | Jabil Inc. | Improved melt blown articles and methods to form them |
Family Cites Families (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE599410A (en) | 1960-01-23 | |||
| NL270258A (en) | 1960-10-17 | |||
| NL296509A (en) | 1962-09-10 | |||
| US3888949A (en) | 1973-06-21 | 1975-06-10 | Du Pont | Blends of propylene-alpha-olefin copolymers and polypropylene |
| US3882197A (en) | 1973-06-21 | 1975-05-06 | Du Pont | Alpha-olefin copolymer blends |
| DE3039728A1 (en) | 1979-10-22 | 1981-04-30 | Kimberly-Clark Corp., 54956 Neenah, Wis. | SUCTIONABLE DEVICE |
| US4461872A (en) | 1983-02-22 | 1984-07-24 | E. I. Du Pont De Nemours And Company | Blends of a propylene/α-olefin copolymer with isotactic prolypropylene |
| US4665130A (en) | 1984-08-31 | 1987-05-12 | Shell Oil Company | Packaging film and sheet capable of forming peelable seals with good optics |
| GB8613161D0 (en) | 1986-05-30 | 1986-07-02 | Exxon Chemical Patents Inc | Sealable films |
| US5213744A (en) | 1987-04-21 | 1993-05-25 | Exxon Chemical Patents Inc. | Process for making polyolefin films |
| IT1227893B (en) | 1988-12-14 | 1991-05-14 | Himont Inc Centerville Road Ne | POLYPROPYLENE COMPOSITIONS WITH GOOD TRANSPARENCY AND IMPROVED IMPACT RESISTANCE |
| KR900009719A (en) | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | New Ethylene-Propylene Copolymer |
| CA2012729C (en) | 1989-04-07 | 1997-05-20 | Takashi Kuroda | Dulled stretched molding and process for producing the same |
| IT1230133B (en) | 1989-04-28 | 1991-10-14 | Himont Inc | PLASTIC-ELASTIC POLYPROPYLENE COMPOSITIONS |
| US5171628A (en) | 1989-05-25 | 1992-12-15 | Exxon Chemical Patents Inc. | Low creep polypropylene textiles |
| JP3015967B2 (en) | 1989-10-02 | 2000-03-06 | 旭化成工業株式会社 | Multilayer packaging film and method for producing the same |
| AU636487B2 (en) | 1990-06-18 | 1993-04-29 | Kimberly-Clark Worldwide, Inc. | A nonwoven web with improved barrier properties |
| WO1993003093A1 (en) | 1991-07-18 | 1993-02-18 | Exxon Chemical Patents Inc. | Heat sealed article |
| US6153703A (en) | 1991-12-20 | 2000-11-28 | Exxon Research And Engineering Company | Semicrystalline polymer blend compositions with enhanced interspherulitic and interlamellar strength |
| US5331047A (en) | 1993-02-17 | 1994-07-19 | Himont Incorporated | Olefin polymer films |
| WO1994028219A1 (en) | 1993-05-25 | 1994-12-08 | Exxon Chemical Patents Inc. | Novel polyolefin fibers and their fabrics |
| DE4317655A1 (en) | 1993-05-27 | 1994-12-01 | Basf Ag | Multi-phase block copolymers of propylene |
| GB2278363B (en) * | 1993-05-28 | 1996-10-30 | Chaloke Pungtrakul | A method for the prevention of blocking in linear low density polyethylene films |
| DE69426043T3 (en) | 1993-06-07 | 2015-06-18 | Mitsui Chemicals, Inc. | polypropylene |
| CA2125246C (en) | 1993-06-07 | 2001-07-03 | Junichi Imuta | Transition metal compound and olefin polymerization catalyst using the same |
| JPH10502975A (en) | 1994-05-24 | 1998-03-17 | エクソン・ケミカル・パテンツ・インク | Fibers and fabrics containing low melting point propylene polymer |
| JP3380043B2 (en) | 1994-06-30 | 2003-02-24 | 三菱樹脂株式会社 | Stretch film for food packaging |
| US5552489A (en) | 1994-07-22 | 1996-09-03 | Exxon Chemical Patents Inc. | Tackifiers and a process to obtain tackifiers |
| US5910362A (en) | 1996-04-25 | 1999-06-08 | Chisso Corporation | Polyolefin fiber and non-woven fabric produced by using the same |
| US5994482A (en) | 1997-03-04 | 1999-11-30 | Exxon Chemical Patents, Inc. | Polypropylene copolymer alloys and process for making |
| US6080818A (en) | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
| US6525157B2 (en) | 1997-08-12 | 2003-02-25 | Exxonmobile Chemical Patents Inc. | Propylene ethylene polymers |
| US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| WO2002083754A1 (en) | 2001-04-12 | 2002-10-24 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US6017615A (en) | 1997-08-25 | 2000-01-25 | Huntsman Polymers Corporation | Film product comprising novel polyolefins |
| US6165599A (en) | 1997-09-15 | 2000-12-26 | Applied Extrusion Technologies, Inc. | Biaxially oriented film prepared from metallocene catalyzed polypropylene |
| US6444774B1 (en) | 1997-10-10 | 2002-09-03 | Exxonmobil Chemical Patents, Inc. | Propylene polymers for fibers and fabrics |
| US6096420A (en) | 1998-01-30 | 2000-08-01 | Tredegar Corporation | Thin plastic film |
| EP1002814A4 (en) | 1998-06-05 | 2001-11-28 | Japan Polychem Corp | Propylene block copolymer and propylene resin composition |
| US6833404B2 (en) | 1998-06-30 | 2004-12-21 | H.B. Fuller Licensing & Financing Inc. | Hot melts utilizing a high glass transition temperature substantially aliphatic tackifying resin |
| EP1098934A1 (en) | 1998-07-01 | 2001-05-16 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| KR20010072663A (en) | 1998-07-02 | 2001-07-31 | 엑손 케미칼 패턴츠 인코포레이티드 | Propylene olefin copolymers |
| US6583076B1 (en) | 1999-01-08 | 2003-06-24 | Kimberly-Clark Worldwide, Inc. | Nonwoven fabrics prepared using visbroken single-site catalyzed polypropylene |
| US6750284B1 (en) | 1999-05-13 | 2004-06-15 | Exxonmobil Chemical Patents Inc. | Thermoplastic filled membranes of propylene copolymers |
| DE60017889T2 (en) | 1999-05-13 | 2006-04-06 | Exxonmobil Chemical Patents Inc., Baytown | ELASTIC FIBERS AND ARTICLES THEREOF CONTAINING CRYSTALLINE AND CRYSTALLIZABLE PROPYLENE POLYMERS |
| US6500563B1 (en) | 1999-05-13 | 2002-12-31 | Exxonmobil Chemical Patents Inc. | Elastic films including crystalline polymer and crystallizable polymers of propylene |
| CA2310925C (en) | 1999-06-11 | 2005-10-11 | Kuraray Co., Ltd. | Multilayered structure |
| US6143818A (en) | 1999-08-04 | 2000-11-07 | Ato Findley, Inc. | Hot melt adhesive based on ethylene-propylene rubber (EPR) and semicrystalline olefinic polymers |
| WO2001046277A2 (en) | 1999-12-22 | 2001-06-28 | Exxonmobil Chemical Patents, Inc. | Polypropylene-based adhesive compositions |
| CN1590422A (en) | 1999-12-23 | 2005-03-09 | 巴塞尔聚烯烃有限公司 | Transition metal compound, ligand system, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins |
| US6476135B1 (en) | 2000-06-07 | 2002-11-05 | Basell Poliolefine Italia S.P.A. | Polyolefin composition containing low viscosity propylene homopolymer, fiber and extensible non-woven fabric prepared therefrom |
| US6932592B2 (en) | 2000-06-22 | 2005-08-23 | Exxonmobil Chemical Patents Inc. | Metallocene-produced very low density polyethylenes |
| US6800692B2 (en) | 2000-06-22 | 2004-10-05 | Exxonmobil Chemical Patents Inc. | Metallocene-produced very low density polyethylenes |
| DE60103333T2 (en) | 2000-08-11 | 2005-06-02 | Japan Polychem Corp. | As the heat shrinkable shrink label, suitable resin composition and film containing the same |
| KR100769774B1 (en) | 2000-10-25 | 2007-10-23 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Processes and apparatus for continuous solution polymerization |
| US6657009B2 (en) | 2000-12-29 | 2003-12-02 | Kimberly-Clark Worldwide, Inc. | Hot-melt adhesive having improved bonding strength |
| US6388013B1 (en) | 2001-01-04 | 2002-05-14 | Equistar Chemicals, Lp | Polyolefin fiber compositions |
| US6531214B2 (en) | 2001-02-14 | 2003-03-11 | 3M Innovative Properties Company | Replacement for plasticized polyvinyl chloride |
| WO2002083753A1 (en) | 2001-04-12 | 2002-10-24 | Exxonmobil Chemical Patents Inc. | Propylene ethylene copolymers |
| US20040250108A1 (en) | 2001-08-29 | 2004-12-09 | Richard Parsons | Facility monitor |
| EP1444276A1 (en) | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| DK1453994T3 (en) | 2001-11-06 | 2007-09-10 | Dow Global Technologies Inc | Isotactic propylene copolymer fibers, their preparation and use |
| US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| WO2003040233A2 (en) | 2001-11-06 | 2003-05-15 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
| US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
| WO2003040095A2 (en) | 2001-11-06 | 2003-05-15 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
| US6900147B2 (en) | 2001-11-28 | 2005-05-31 | Kimberly-Clark Worldwide, Inc. | Nonwoven webs having improved necking uniformity |
| AU2003301438A1 (en) | 2002-10-17 | 2004-05-04 | Exxonmobil Chemical Patents Inc. | Hetero phase polymer compositions |
| AU2003297134A1 (en) | 2002-12-17 | 2004-07-29 | Exxonmobil Chemical Patents Inc. | Elastic blends comprising elastic crystalline polymer and crystallizable polymers for ethylene |
| US7312167B2 (en) | 2002-12-23 | 2007-12-25 | Kimberly-Clark Worldwide, Inc. | Breathable multilayer films for use in absorbent articles |
| US6984696B2 (en) | 2003-03-28 | 2006-01-10 | Exxonmobil Chemical Patents Inc. | Elastic blends of semicrystalline propylene polymers and high glass transition temperature materials |
| CN100582155C (en) * | 2003-05-08 | 2010-01-20 | 诺沃连科技控股公司 | Polypropylene resin composition |
| WO2005049670A1 (en) * | 2003-11-14 | 2005-06-02 | Exxonmobil Chemical Patents Inc. | Propylene-based elastomers and uses thereof |
| US20050106978A1 (en) * | 2003-11-18 | 2005-05-19 | Cheng Chia Y. | Elastic nonwoven fabrics made from blends of polyolefins and processes for making the same |
| US7482762B2 (en) | 2003-11-21 | 2009-01-27 | Matsushita Electric Works, Ltd. | Discharge lamp ballast with detection of abnormal discharge outside the arc tube |
| EP1828303B1 (en) * | 2004-12-17 | 2009-08-26 | ExxonMobil Chemical Patents, Inc., A Corporation of the State of Delaware | Heterogeneous polymer blends and molded articles therefrom |
| ES2328611T3 (en) * | 2004-12-17 | 2009-11-16 | Exxonmobil Chemical Patents Inc. | FILMS OF POLYMER BLENDS. |
| WO2006113132A1 (en) * | 2005-04-14 | 2006-10-26 | Exxonmobil Chemical Patents Inc. | Transparent polyolefin compositions |
-
2005
- 2005-12-09 DE DE602005021248T patent/DE602005021248D1/en active Active
- 2005-12-09 EP EP05853516A patent/EP1831304B1/en not_active Not-in-force
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- 2005-12-09 AT AT05853516T patent/ATE467658T1/en not_active IP Right Cessation
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| CA2588770C (en) | 2010-03-23 |
| JP4782800B2 (en) | 2011-09-28 |
| US7619038B2 (en) | 2009-11-17 |
| EP1831304A1 (en) | 2007-09-12 |
| WO2006065648A1 (en) | 2006-06-22 |
| EP1831304B1 (en) | 2010-05-12 |
| DE602005021248D1 (en) | 2010-06-24 |
| JP2008524387A (en) | 2008-07-10 |
| US20060183860A1 (en) | 2006-08-17 |
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