CA2609860A1 - Water-in-oil bitumen dispersions and methods for producing paving compositions from the same - Google Patents

Water-in-oil bitumen dispersions and methods for producing paving compositions from the same Download PDF

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CA2609860A1
CA2609860A1 CA 2609860 CA2609860A CA2609860A1 CA 2609860 A1 CA2609860 A1 CA 2609860A1 CA 2609860 CA2609860 CA 2609860 CA 2609860 A CA2609860 A CA 2609860A CA 2609860 A1 CA2609860 A1 CA 2609860A1
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alkyl
composition
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CA2609860C (en
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Everett Crews
Tom Girardeau
Iain Jack
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Ingevity South Carolina LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/26—Bituminous materials, e.g. tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C08L95/005—Aqueous compositions, e.g. emulsions
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00—Pavings made of prefabricated single units
    • E01C5/12—Pavings made of prefabricated single units made of units with bituminous binders or from bituminous material, e.g. asphalt mats
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00—Coherent pavings made in situ
    • E01C7/08—Coherent pavings made in situ made of road-metal and binders
    • E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00—Adapting or protecting infrastructure or their operation
    • Y02A30/30—Adapting or protecting infrastructure or their operation in transportation, e.g. on roads, waterways or railways
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Abstract

The present invention relates to bituminous compositions suitable for use in paving applications containing water-in-oil bitumen dispersion of paving grade bitumen such as penetration-graded, viscosity-graded and/or penetration-graded varieties that is substantially free of volatile solvents and made by controlling temperature-dependent interfacial rheology through the use of selected surfactants. The invention paving compositions are suitable for use in the construction of load-bearing, high-traffic pavements at a temperature range lower than that required for conventional hot-mix bituminous paving compositions, yet with similar or superior compaction to densities property and at least equal cure rate.

Claims (147)

1. Bituminous composition comprising:
(a) water-in-oil bitumen dispersion in an amount from about 2% to about 10% by total weight of the bituminous composition, wherein the dispersion comprises:
(i) bitumen in an amount from about 75% to about 95% by total weight of the bitumen dispersion, (ii) surfactant package having an interfacial tension between the bitumen and water of less than 40 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1% weight, in an amount from about 0.05% to about 2% by total weight of the bitumen dispersion, (ii) water in an amount to complete the dispersion; and (b) aggregate and/or reclaimed asphalt pavement in an amount from about 90% to about 98% by total weight of the bituminous composition.
2. The composition of claim 1, wherein the amount of the bitumen is from about 85% to about 95% by total weight of the bitumen dispersion.
3. The composition of claim 1, wherein the amount of the surfactant package is from about 0.08% to about 0.5% by total weight of the bitumen dispersion.
4. The composition of claim 1, wherein the amount of the surfactant package is from about 0.1% to about 0.75% by total weight of the bitumen dispersion.
5. The composition of claim 1, wherein the bitumen comprises at least one member selected from the group consisting of naturally occurring bitumen, bitumen derived from crude oil, petroleum pitch obtained from a cracking process, coal tar, polymer-modified bitumen, rubberized bitumen, rubberized bitumen containing recycled tire material, acid-modified bitumen, wax-modified bitumen, and combinations thereof.
6. The composition of claim 1, wherein the naturally occurring bitumen comprises at least one member selected from the group consisting of lake asphalt, lake asphalt derivative, gilsonite, gilsonite derivative, and combinations thereof.
7. The composition of claim 1, wherein the bitumen comprises at least one member selected from the group consisting of unmodified bitumen, modified bitumen, and combinations thereof.
8. The composition of claim 7, wherein the modified bitumen comprises at least one additive selected from the group consisting of natural rubber, synthetic rubber, plastomer, thermoplastic resin, thermosetting resin, elastomer, and combinations thereof.
9. The composition of claim 7, wherein the modified bitumen comprises at least one additive selected from the group consisting of styrene-butadiene-styrene, styrene-butadiene-rubber, polyisoprene, polybutylene, butadiene-styrene rubber, vinyl polymer, ethylene vinyl acetate, ethylene vinyl acetate derivative, sulfur-containing crosslinker, salt, acid modifier, wax modifier, and combinations thereof.
10. The composition of claim 7, wherein the acid modifier comprises at least one member selected from the group consisting of tall oil acid, distilled tall oil, crude tall oil, tall oil pitch, phosphoric acid derivative of tall oil acids, phosphoric acid derivative of tall oil pitch, polyphosphoric acid, and combinations thereof.
11. The composition of claim 1, wherein the surfactant package comprises one member selected from the group consisting of anionic surfactant, cationic surfactant, amphoteric surfactant, nonionic surfactant, and combinations thereof.
12. The composition of claim 11, wherein the anionic surfactant comprises at least one member selected from the group consisting of saturated C-12 to C-24 fatty acids;
unsaturated C-12 to C-24 fatty acids; unsaturated C-12 to C-24 fatty acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; rosin acids; rosin acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; natural resinous polymers; Vinsol resins;
quebracho resins; tannins; lignous polymers; polyacrylic acid; polyacrylate derivatives;
alkyl sulfonates; alkyl benzyl sulfonates; alkyl sulfates; alkyl phosphonates;
alkyl phosphates; phenolic resins; and combinations thereof.
13. The composition of claim 11, wherein the anionic surfactant comprises at least one member selected from the group consisting of complexes, addition products, and condensation products formed by a reaction of (i) at least one member selected from the group consisting of natural resinous polymer, Vinsol resin, quebracho resin, tannins and lignin; and (ii) at least one member selected from the group consisting of saturated C10-C24 fatty acids, unsaturated C10-C24 fatty acids, and unsaturated C10-C24 fatty acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, dienes and dienophiles.
14. The composition of claim 11, wherein the anionic surfactant comprises at least one member selected from the group consisting of sulfate, sulfonate, phosphate, and phosphonate derivative of at least one compound selected from the group consisting of lignin, natural resinous polymers, Vinsol resins, quebracho resins, and tannins.
15. The composition of claim 11, wherein the anionic surfactant comprises at least one member selected from the group consisting of sulfate, sulfonate, phosphate, and phosphonate derivative of a member selected from the group consisting of complexes, addition products, and condensation products formed by a reaction of (i) at least one member selected from the group consisting of natural resinous polymer, Vinsol resin, quebracho resin, tannins and lignin; and (ii) at least one member selected from the group consisting of saturated C10-C24 fatty acids, unsaturated C10-C24 fatty acids, and unsaturated C10-C24 fatty acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dienophile.
16. The composition of claim 11, wherein the amphoteric surfactant comprises at least one product obtained by (i) modifying C-12 to C-24 fatty acid with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; and then (ii) reacting the resulting modified product with at least one member selected from the group consisting of polyethylene polyamines, lithium C-12 to C-24 alkyl amidopropyl halide methyl carboxylate betaine, sodium C-12 to C-24 alkyl amidopropyl halide methyl carboxylate betaines, potassium C-12 to C-24 alkyl amidopropyl halide methyl carboxylate betaines, lithium C-12 to C-24 alkyl amidopropyl halide phosphate betaines, sodium C-12 to C-24 alkyl amidopropyl halide phosphate betaines, potassium C-12 to C-24 alkyl amidopropyl halide phosphate betaines, lithium C-12 to C-24 alkyl amidopropyl halide sulphate betaines, sodium C-12 to C-24 alkyl amidopropyl halide sulphate betaines, and potassium C-12 to C-24 alkyl amidopropyl halide sulphate betaines.
17. The composition of claim 11, wherein the cationic surfactant comprises at least one member selected from the group consisting of fatty imidoamines derived from (i) modifying C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile, and then (ii) reacting the resulting modified products with polyalkylenepolyamines; fatty amidoamines derived from (i) modifying C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; and then (ii) reacting the resulting modified products with at least one member selected from the group consisting of polyalkylenepolyamines, saturated C-12 to C-24 alkyl monoamines, unsaturated C-12 to C-24 alkyl monoamines, saturated C-12 to C-24 alkyl polypropylenepolyamines, unsaturated C-12 to C-24 alkyl polypropylenepolyamines; polyoxyethylene derivatives made by modifying saturated C-12 to C-24 alkyl monoamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide; polyoxyethylene derivatives made by modifying unsaturated C-12 to C-24 alkyl monoamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide;
polyoxyethylene derivatives made by modifying saturated C-12 to C-24 alkyl polypropylenepolyamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide; polyoxyethylene derivatives made by modifying unsaturated C-12 to C-24 alkyl polypropylenepolyamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide;
saturated C-12 to C-24 alkyl aryl monoamines; unsaturated C-12 to C-24 alkyl aryl monoamines;
saturated C-12 to C-24 alkyl aryl polypropylenepolyamines; unsaturated C-12 to alkyl aryl polypropylenepolyamines; saturated C-12 to C-24 quaternary amines;
unsaturated C-12 to C-24 quaternary amines; amine derivatives of tannins;
amine derivatives of phenolic resins; amine derivatives of lignins; amine-modified polyacrylates; and combinations thereof.
18. The composition of claim 11, wherein the cationic surfactant comprises at least one member selected from the group consisting of saturated C-12 to C-24 alkyl monoamines, unsaturated C-12 to C-24 alkyl monoamines, saturated C-12 to C-24 alkyl polypropylenepolyamines, unsaturated C-12 to C-24 alkyl polypropylenepolyamines, and combinations thereof.
19. The composition of claim 11, wherein the cationic surfactant is a blend of at least one member selected from the group consisting of saturated and unsaturated C-12 to alkyl monoamines, and at least one member selected from the group consisting of saturated and unsaturated C-12 to C-24 alkyl polypropylenepolyamines.
20. The composition of claim 11, wherein the nonionic surfactant comprises at least one member selected from the group consisting of alkylaryl polyethylene oxide derivative of alkanol; polypropylene oxide derivative of alkanol; polyethylene oxide derivative of alkanol; polypropylene oxide derivative of alkanol, wherein the alkanol has branched, linear, or cyclic structure; polyethoxylated surfactant; polypropoxylated surfactant;
sorbitan esters; monosaccharide derivative; polysaccharide derivative; protein stabilizer;
mechanical stabilizers; and combinations thereof.
21. The composition of claim 20, wherein the protein stabilizer comprises at least one member selected from the group consisting of casein, albumin, and combinations thereof.
22. The composition of claim 20, wherein the mechanical stabilizers comprises at least one member selected from the group consisting of phyllosilicate bentonite, montmorillonite clay, and combinations thereof.
23. The composition of claim 11, wherein the nonionic surfactant comprises at least one member selected from the group consisting of alkyl polysaccharide; alkylphenol alkoxylate; fatty alcohol ethoxylate; saturated fatty acid propoxylate;
unsaturated fatty acid propoxylate; ethoxylate of escinoleic acid; ethoxylate of castor oil;
propoxylate of escinoleic acid; propoxylate of castor oil, wherein the ethoxylate has linear, branched, or cyclic structure, and the propoxylate linear, branched, or cyclic structure.
24. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of polyethylene-polypropylene block copolymer; hydroxypoly(oxyethylene) poly(oxypropylene) poly(oxyethylene) block copolymers; 1,2-propyleneglycol ethoxylated; 1,2-propyleneglycol propoxylated;
and synthetic block copolymer of ethylene oxide and propylene oxide having molecular weights exceeding 300 g/mole.
25. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of decyl alcohol ethoxylates; castor oil ethoxylate; ceto-oleyl alcohol ethoxylate; ethoxylated alkanolamide; fatty alcohol alkoxylates; dinonyl phenol ethoxylate, nonyl phenol ethoxylate; sorbitan ester ethoxylate; alkyl ether sulphate; monoalkyl sulphosuccinamate; alkyl phenol ether sulphate; fatty alcohol sulphate; di-alkyl sulphosuccinate; alkyl ether phosphate; alkyl phenol ether phosphate; alkyl naphthalene sulphonate; .alpha.-olefin sulphonate; alkyl benzene sulphonic acids and salt, alkyl ampho(di)acetate; alkyl betaine; alkyl polysaccharide; alkylamine ethoxylate; amine oxide; and combinations thereof.
26. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of oligomer, co-oligomer, ter-oligomer, tetra-oligomer, homopolymer, copolymer, terpolymer, and tetrapolymer of at least one monomer selected from the group consisting of acrylic acid, alkylacrylic acid, alkyl ester of acrylic acid, alkyl ester of alkylacrylic acid, hydroxyalkyl ester of acrylic acid, hydroxyalkyl ester of alkylacrylic acid, acrylamide, alkylacrylamide, N-alkyl acrylamide, N,N-dialkyl acrylamdide, N-hydroxyalkylacrylamide, N,N-dihydroxyalkylacrylamide, styrene, alkylstyrene, ethene, propene, higher order alkene, diene, hydroxylated propene, polyhyrdoxylated polyalkene, halogenated ethylene, halogenated propylene, and halogenated alkylidene.
27. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of lithium, sodium, potassium, magnesium, calcium, ammonium, and alkylammonium salts of at least one member selected from the group consisting of oligomers, co-oligomers, ter-oligomers, tetra-oligomers, homopolymers, copolymers, terpolymers, and tetrapolymers of at least one monomer selected from the group consisting of acrylic acid, alkylacrylic acid, alkyl ester of acrylic acid, alkyl ester of alkylacrylic acid, hydroxyalkyl ester of acrylic acid, hydroxyalkyl ester of alkylacrylic acid, acrylamide, alkylacrylamide, N-alkyl acrylamide, N,N-dialkyl acrylamdide, N-hydroxyalkylacrylamide, N,N-dihydroxyalkylacrylamide, styrene, alkylstyrene, ethene, propene, higher order alkene, diene, hydroxylated propene, polyhyrdoxylated polyalkene, halogenated ethylene, halogenated propylene, and halogenated alkylidene.
28. The composition of claim 1, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of oligomers, co-oligomers, ter-oligomers, tetra-oligomers, homopolymers, copolymers, terpolymers, and tetrapolymers of at least one monomer selected from the group consisting of acrylic acid, alkylacrylic acid, alkyl ester of acrylic acid, alkyl ester of alkylacrylic acid, hydroxyalkyl ester of acrylic acid, hydroxyalkyl ester of alkylacrylic acid, acrylamide, alkylacrylamide, N-alkyl acrylamide, N,N-dialkyl acrylamdide, N-hydroxyalkylacrylamide, N,N-dihydroxyalkylacrylamide, styrene, alkylstyrene, ethene, propene, higher order alkene, diene, hydroxylated propene, polyhyrdoxylated polyalkene, halogenated ethylene, halogenated propylene, and halogenated alkylidene.
29. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
30. The composition of claim 1, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
31. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of monoethoxylated, polyethoxylated, monopropylated, and polypropylated condensate of at least one member selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, oligomeric aziridine, polyaziridine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
32. The composition of claim 1, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of monoethoxylated , polyethoxylated, monopropylated, and polypropylated condensates of at least one compound selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, oligomeric aziridine, polyaziridine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
33. The composition of claim 1, wherein the surfactant package comprises homolog of hydroxylalkyl amine.
34. The composition of claim 1, wherein the surfactant package comprises salt obtained by a reaction of (i) homolog of hydroxyalkyl amine and (ii) at least one member selected from the group consisting of hydrogen halide, carboxylic acid and phosphoric acid.
35. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of C-36 dimeric fatty acid and C-54 trimeric fatty acid.
36. The composition of claim 1, wherein the surfactant package comprises polymeric condensation product of C-36 dimeric fatty acid and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
37. The composition of claim 1, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of polymeric condensation product of C-36 dimeric fatty acid and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
38. The composition of claim 1, wherein the surfactant package comprises polymeric condensation product of C-54 trimeric fatty acids and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
39. The composition of claim 1, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of polymeric condensation product of C-54 trimeric fatty acid and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
40. The composition of claim 1, wherein the surfactant package comprises at least one member selected from the group consisting of hydroxystearic acid, oligomer of hydroxystearic acid, and polymeric hydroxystearic acid.
41. The composition of claim 1, wherein the surfactant package comprises polymeric condensation product formed by a reaction of (i) at least one member selected from the group consisting of ethylene amine, propylene amine, ethylene/propylene amine, oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylene amine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine; and (ii) at least one member selected from the group consisting of hydroxystearic acid, oligomer of hydroxystearic acid, and polymeric hydroxystearic acid.
42. The composition of claim 1, the surfactant package comprises polymeric condensation product of (i) at least one member selected from the group consisting of hydroxystearic acid, oligomers of hydroxystearic acid, and polymeric hydroxystearic acid; and (ii) at least one member selected from the group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, and Lewis acid base.
43. The composition of claim 1, wherein the surfactant package comprises ethoxytrimethyleneamine derivatives of C-12 to C-24 fatty amines of structure (I) wherein R = saturated or unsaturated aliphatic C-12 to C-24 having linear, branched, or cyclic structure;
x + y >= 2; and a , b >= 0.
44. The composition of claim 1, wherein the surfactant package comprises polymeric condensation product of (i) at least one member selected from the group consisting of hydroxystearic acid, oligomers of hydroxystearic acid, and polymeric hydroxystearic acid; and (ii) at least one member selected from the group consisting of ethoxytrimethyleneamine derivatives of C-12 to C-24 fatty amines of structure (I).
45. The composition of claim 1, wherein the surfactant package comprises propoxytrimethyleneamine derivatives of C-12 to C-24 fatty amines of structure (II) wherein R = saturated or unsaturated aliphatic C-12 to C-24 having linear, branched, or cyclic structure;
x + y >= 2;and a,b >= 0.
46. The composition of claim 1, wherein the surfactant package comprises polymeric condensation product of (i) at least one member selected from the group consisting of hydroxystearic acid, oligomers of hydroxystearic acid, and polymeric hydroxystearic acid; and (ii) at least one member selected from the group consisting of propoxytrimethyleneamine derivative of C-12 to C-24 fatty amine of structure (II).
47. The composition of claim 1, wherein the surfactant package comprises aliphatic diakylamine of structure (III) wherein R1, R2= saturated or unsaturated C-12 to C-24 moieties having linear, branched, or cyclic structure.
48. The composition of claim 1, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of saturated and unsaturated aliphatic C-12 to C-24 dialkyl amine of structure (III).
49. The composition of claim 1, wherein the surfactant package comprises quaternary amine of structure (IV) wherein R1, R2= saturated or unsaturated aliphatic C-12 to C-24 moieties having linear, branched, or cyclic structure; and R3, R4 = methyl or higher order homolog of saturated or unsaturated aliphatic C-12 to C-24 moieties having linear, branched, or cyclic structure.
50. The composition of claim 1, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of saturated and unsaturated aliphatic C-12 to C-24 alkyl quaternary amine of structure (IV).
51. The composition of claim 1, wherein the surfactant package comprises quaternary amine of structure (V) wherein:

R1, R2= saturated or unsaturated aliphatic C-12 to C-24 moieties having linear, branched, or cyclic structure; and R3, R4 = ethoxy moieties, propoxy moieties, or combinations thereof.
52. The composition of claim 1, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of saturated and unsaturated aliphatic C-12 to C-24 alkyl quaternary amine of structure (V).
53. The composition of claim 1, wherein the surfactant package comprises bisamide formed by a reaction of polyalkylenepolyamine and adduct obtained by modifying at least one member selected from the group consisting of saturated aliphatic C-12 to C-24 fatty acid and unsaturated aliphatic C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophiles, wherein the C-12 to C-24 fatty acid has linear, branched, or cyclic structure.
54. The composition of claim 1, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of bisamide formed by a reaction of polyalkylenepolyamine and adduct obtained by modifying at least one member selected from the group consisting of saturated aliphatic C-12 to C-24 fatty acid and unsaturated aliphatic C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophiles, wherein the C-12 to C-24 fatty acid has linear, branched, or cyclic structure.
55. The composition of claim 1, wherein the surfactant package comprises dialkylarylamine.
56. The composition of claim 1, wherein the surfactant package comprises salt obtained by the reaction of at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and dilakylarylamine.
57. The composition of claim 1, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 40 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
58. The composition of claim 1, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 30 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
59. The composition of claim 1, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 20 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
60. The composition of claim 1, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 10 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
61. The composition of claim 1, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 5 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
62. The composition of claim 1, wherein the water-in-oil bitumen dispersion comprises organic solvent in an amount of less than or equal to 4% by weight by total weight of the dispersion.
63. The composition of claim 1, wherein the water-in-oil bitumen dispersion comprises organic solvent in an amount of less than or equal to 1% by weight by total weight of the dispersion.
64. The composition of claim 1, wherein the aggregate comprises at least one member selected from the group consisting of dense-graded aggregate, gap-graded aggregate, open-graded, stone-matrix aggregate, reclaimed asphalt paving material, reclaimed roofing shingles, and combinations thereof.
65. The composition of claim 1, further comprising additive for enhancing processability or improving performance.
66. The composition of claim 1, wherein the water-in-oil bitumen dispersion is produced using high-shear mixing process comprising at least one member selected from the group consisting of high-shear colloid mill dispersion, high-shear static mixer dispersion, high-shear roto-mixer dispersion, high-shear dispersion via injection of the water into a bitumen process stream through phase inversion process, and combinations thereof.
67. The composition of claim 1, characterized by its application to a surface being paved at a temperature in a range of about 0° C to about 120° C.
68. The composition of claim 1, characterized by its application to a surface being paved at a temperature in a range of about 85° C to about 100° C.
69. The composition of claim 1, characterized by its application to a surface being paved at a temperature in a range of about 85.degree C to about 95° C.
70. A thin lift overlay for paving applications comprising the bituminous composition of claim 1.
71. A bituminous paving block comprising the bituminous composition of claim 1.
72. A method for producing a bituminous composition comprising steps of:
(A) preparing water-in-oil bituminous dispersion comprising:
(i) bitumen, in an amount from about 75% to about 95% by total weight of the bitumen dispersion, (ii) surfactant package having an interfacial tension between the bitumen and water of less than 40 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1% weight, in an amount from about 0.05% to about 2% by total weight of the bitumen dispersion, and (iii) water in an amount to complete the dispersion; and (B) producing the bituminous composition having a temperature from about 50° C
to about 120° C by mixing:
(i) the water-in-oil bitumen dispersion of step (A), having a temperature from about 75° C to a bout 95° C, in an amount from about 2% to about 10% by total weight of the bituminous composition, and (ii) aggregate and/or reclaimed asphalt pavement, having a temperature from about 60° C to about 140° C, in an amount from about 90% to about 98%
by total weight of the bituminous composition.
73. The method of claim 72, wherein the produced bituminous composition has a temperature in the range of about 55° C to about 120° C.
74. The method of claim 72, wherein the produced bituminous composition has a temperature in the range of about 60° C to about 95° C.
75. The method of claim 72, wherein the water-in-oil bitumen dispersion of step (B) (i) has a temperature in the range of about 85°C to about 95°C.
76. The method of claim 72, wherein the aggregate and/or reclaimed asphalt pavement of step (B) (ii) has a temperature in the range of about 60°C to about 120°C.
77. The method of claim 72, wherein the water-in-oil bituminous dispersion is delivered after production directly into at least one stationary or mobile asphalt mixing unit, wherein the mixing unit comprises at least one member selected from the group consisting of drum mixers, pug-mill batch mixers, dual mixers, and combinations thereof, and wherein the mobile mixing unit comprises equipment used in in-situ or in-place operations.
78. A paved road comprising at least one layer of a bituminous composition, wherein the bituminous composition comprises:
(a) ~water-in-oil bitumen dispersion in an amount from about 2% to about 10%
by total weight of the bituminous composition, wherein the dispersion comprises:
(i) ~bitumen, in an amount from about 75% to about 95% by total weight of the bitumen dispersion, (ii) ~surfactant package having an interfacial tension between the bitumen and water of less than 40 dynes/cm at a temperature of 26 C and at an aqueous concentration of less than 0.1 % weight, in an amount from about 0.05% to about 2% by total weight of the bitumen dispersion, (iii) ~water in an amount to complete the dispersion; and (b) ~aggregate and/or reclaimed asphalt pavement in an amount from about 90%
to about 98% by total weight of the bituminous composition.
79. The paved road of claim 78, wherein an amount of the bitumen in the dispersion is from about 85% to about 95% by total weight of the bitumen dispersion.
80. The paved road of claim 78, wherein an amount of the surfactant package in the dispersion is from about 0.08% to about 0.5% by total weight of the bitumen dispersion.
81. The paved road of claim 78, wherein an amount of the surfactant package in the dispersion is from about 0.1% to about 0.75% by total weight of the bitumen dispersion.
82. The paved road of claim 78, wherein the bitumen comprises at least one member selected from the group consisting of naturally occurring bitumen, bitumen derived from crude oil, petroleum pitches obtained from a cracking process, coal tar, polymer-modified bitumen, rubberized bitumen, rubberized bitumen containing recycled tire material, acid-modified bitumen, wax-modified bitumen, and combinations thereof.
83. The paved road of claim 82, wherein the naturally occurring bitumen comprises at least one member selected from the group consisting of lake asphalt, lake asphalt derivative, gilsonite, gilsonite derivative, and combinations thereof.
84. The paved road of claim 78, wherein the bitumen comprises at least one member selected from the group consisting of unmodified bitumen, modified bitumen, and combinations thereof.
85. The paved road of claim 84, wherein the modified bitumen comprises at least one additive selected from the group consisting of natural rubber, synthetic rubber, plastomer, thermoplastic resin, thermosetting resin, elastomer, and combinations thereof.
86. The paved road of claim 84, wherein the modified bitumen comprises at least one additive selected from the group consisting of styrene-butadiene-styrene, styrene-butadiene-rubber, polyisoprene, polybutylenes, butadiene-styrene rubbers, vinyl polymers, ethylene vinyl acetate, ethylene vinyl acetate derivatives, sulfur-containing crosslinker, salts acid modifier, wax modifier, and combinations thereof.
87. The paved road of claim 86, wherein the acid modifier comprises at least one member selected from the group consisting of tall oil acid, crude tall oil, tall oil pitch, phosphoric acid derivative of tall oil acids, phosphoric acid derivative of tall oil pitch, polyphosphoric acid, and combinations thereof.
88. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of anionic surfactant, cationic surfactant, amphoteric surfactant, nonionic surfactant, and combinations thereof.
89. The paved road of claim 88, wherein the anionic surfactant comprises at least one member selected from the group consisting of saturated C-12 to C-24 fatty acids;
unsaturated C-12 to C-24 fatty acids; unsaturated C-12 to C-24 fatty acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; rosin acids; rosin acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; natural resinous polymers; Vinsol resins;

quebracho resins; tannins; lignous polymers; polyacrylic acid; polyacrylate derivatives;
alkyl sulfonates; alkyl benzyl sulfonates; alkyl sulfates; alkyl phosphonates;
alkyl phosphates; phenolic resins; and combinations thereof.
90. The paved road of claim 88, wherein the anionic surfactant comprises at least one member selected from the group consisting of complexes, addition products, and condensation products formed by a reaction of (i) at least one member selected from the group consisting of natural resinous polymer, Vinsol resin, quebracho resin, tannins and lignin; and (ii) at least one member selected from the group consisting of saturated C l 0-C24 fatty acids, unsaturated C10-C24 fatty acids, and unsaturated C10-C24 fatty acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, dienes and dienophiles.
91. The paved road of claim 88, wherein the anionic surfactant comprises at least one member selected from the group consisting of sulfate, sulfonate, phosphate, and phosphonate derivative of at least one compound selected from the group consisting of lignin, natural resinous polymers, Vinsol resins, quebracho resins, and tannins.
92. The paved road of claim 88, wherein the anionic surfactant comprises at least one member selected from the group consisting of sulfate, sulfonate, phosphate, and phosphonate derivative of a member selected from the group consisting of complexes, addition products, and condensation products formed by a reaction of (i) at least one member selected from the group consisting of natural resinous polymer, Vinsol resin, quebracho resin, tannins and lignin; and (ii) at least one member selected from the group consisting of saturated C10-C24 fatty acids, unsaturated C10-C24 fatty acids, and unsaturated C10-C24 fatty acids modified with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dienophile.
93. The paved road of claim 88, wherein the amphoteric surfactant comprises at least one product obtained by (i) modifying C-12 to C-24 fatty acid with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; and then (ii) reacting the resulting modified product with at least one member selected from the group consisting of polyethylene polyamines, lithium C-12 to C-24 alkyl amidopropyl halide methyl carboxylate betaine, sodium C-12 to C-24 alkyl amidopropyl halide methyl carboxylate betaines, potassium C-12 to C-24 alkyl amidopropyl halide methyl carboxylate betaines, lithium C-12 to C-24 alkyl amidopropyl halide phosphate betaines, sodium C-12 to C-24 alkyl amidopropyl halide phosphate betaines, potassium C-12 to C-24 alkyl amidopropyl halide phosphate betaines, lithium C-12 to C-24 alkyl amidopropyl halide sulphate betaines, sodium C-12 to C-24 alkyl amidopropyl halide sulphate betaines, and potassium C-12 to C-24 alkyl amidopropyl halide sulphate betaines.
94. The paved road of claim 88, wherein the cationic surfactant comprises at least one member selected from the group consisting of fatty imidoamines derived from (i) modifying C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile, and then (ii) reacting the resulting modified products with polyalkylenepolyamines; fatty amidoamines derived from (i) modifying C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophile; and then (ii) reacting the resulting modified products with at least one member selected from the group consisting of polyalkylenepolyamines, saturated C-12 to C-24 alkyl monoamines, unsaturated C-12 to C-24 alkyl monoamines, saturated C-12 to C-24 alkyl polypropylenepolyamines, unsaturated C-12 to C-24 alkyl polypropylenepolyamines; polyoxyethylene derivatives made by modifying saturated C-12 to C-24 alkyl monoamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide; polyoxyethylene derivatives made by modifying unsaturated C-12 to C-24 alkyl monoamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide;
polyoxyethylene derivatives made by modifying saturated C-12 to C-24 alkyl polypropylenepolyamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide; polyoxyethylene derivatives made by modifying unsaturated C-12 to C-24 alkyl polypropylenepolyamines with at least one member selected from the group consisting of ethylene oxide and propylene oxide;
saturated C-12 to C-24 alkyl aryl monoamines; unsaturated C-12 to C-24 alkyl aryl monoamines;

saturated C-12 to C-24 alkyl aryl polypropylenepolyamines; unsaturated C-12 to alkyl aryl polypropylenepolyamines; saturated C-12 to C-24 quaternary amines;
unsaturated C-12 to C-24 quaternary amines; amine derivatives of tannins;
amine derivatives of phenolic resins; amine derivatives of lignins; amine-modified polyacrylates; and combinations thereof.
95. The paved road of claim 88, wherein the cationic surfactant comprises at least one member selected from the group consisting of saturated C-12 to C-24 alkyl monoamines, unsaturated C-12 to C-24 alkyl monoamines, saturated C-12 to C-24 alkyl polypropylenepolyamines, unsaturated C-12 to C-24 alkyl polypropylenepolyamines, and combinations thereof.
96. The paved road of claim 88, wherein the cationic surfactant is a blend of at least one member selected from the group consisting of saturated and unsaturated C-12 to alkyl monoamines, and at least one member selected from the group consisting of saturated and unsaturated C-12 to C-24 alkyl polypropylenepolyamines.
97. The paved road of claim 88, wherein the nonionic surfactant comprises at least one member selected from the group consisting of alkylaryl polyethylene oxide derivative of alkanol; polypropylene oxide derivative of alkanol; polyethylene oxide derivative of alkanol; polypropylene oxide derivative of alkanol, wherein the alkanol has branched, linear, or cyclic structure; polyethoxylated surfactant; polypropoxylated surfactant;
sorbitan esters; monosaccharide derivative; polysaccharide derivative; protein stabilizer;
mechanical stabilizers; and combinations thereof.
98. The paved road of claim 97, wherein the protein stabilizer comprises at least one member selected from the group consisting of casein, albumin, and combinations thereof.
99. The paved road of claim 97, wherein the mechanical stabilizers comprises at least one member selected from the group consisting of phyllosilicate bentonite, montmorillonite clay, and combination thereof.
100. The paved road of claim 88, wherein the nonionic surfactant comprises at least one member selected from the group consisting of alkyl polysaccharide; alkylphenol alkoxylate; fatty alcohol ethoxylate; saturated fatty acid propoxylate;
unsaturated fatty acid propoxylate; ethoxylate of escinoleic acid; ethoxylate of castor oil;
propoxylate of escinoleic acid; propoxylate of castor oil, wherein the ethoxylate has linear, branched, or cyclic structure, and the propoxylate linear, branched, or cyclic structure.
101. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of polyethylene-polypropylene block copolymer, hydroxypoly(oxyethylene) poly(oxypropylene) poly(oxyethylene) block copolymers, 1,2-propyleneglycol ethoxylated, 1,2-propyleneglycol propoxylated;
and synthetic block copolymer of ethylene oxide and propylene oxide having molecular weights exceeding 300 g/mole.
102. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of decyl alcohol ethoxylates; castor oil ethoxylate; ceto-oleyl alcohol ethoxylate; ethoxylated alkanolamide; fatty alcohol alkoxylates; dinonyl phenol ethoxylate, nonyl phenol ethoxylate; sorbitan ester ethoxylate; alkyl ether sulphate; monoalkyl sulphosuccinamate; alkyl phenol ether sulphate; fatty alcohol sulphate; di-alkyl sulphosuccinate; alkyl ether phosphate; alkyl phenol ether phosphate; alkyl naphthalene sulphonate; .alpha.-olefin sulphonate; alkyl benzene sulphonic acids and salt, alkyl ampho(di)acetate; alkyl betaine; alkyl polysaccharide; alkylamine ethoxylate; amine oxide; and combinations thereof.
103. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of oligomer, co-oligomer, ter-oligomer, tetra-oligomer, homopolymer, copolymer, terpolymer, and tetrapolymer of at least one monomer selected from the group consisting of acrylic acid, alkylacrylic acid, alkyl ester of acrylic acid, alkyl ester of alkylacrylic acid, hydroxyalkyl ester of acrylic acid, hydroxyalkyl ester of alkylacrylic acid, acrylamide, alkylacrylamide, N-alkyl acrylamide, N,N-dialkyl acrylamdide, N-hydroxyalkylacrylamide, N,N-dihydroxyalkylacrylamide, styrene, alkylstyrene, ethene, propene, higher order alkene, diene, hydroxylated propene, polyhyrdoxylated polyalkene, halogenated ethylene, halogenated propylene, and halogenated alkylidene.
104. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of lithium, sodium, potassium, magnesium, calcium, ammonium, and alkylammonium salts of at least one member selected from the group consisting of oligomers, co-oligomers, ter-oligomers, tetra-oligomers, homopolymers, copolymers, terpolymers, and tetrapolymers of at least one monomer selected from the group consisting of acrylic acid, alkylacrylic acid, alkyl ester of acrylic acid, alkyl ester of alkylacrylic acid, hydroxyalkyl ester of acrylic acid, hydroxyalkyl ester of alkylacrylic acid, acrylamide, alkylacrylamide, N-alkyl acrylamide, N,N-dialkyl acrylamdide, N-hydroxyalkylacrylamide, N,N-dihydroxyalkylacrylamide, styrene, alkylstyrene, ethene, propene, higher order alkene, diene, hydroxylated propene, polyhyrdoxylated polyalkene, halogenated ethylene, halogenated propylene, and halogenated alkylidene.
105. The paved road of claim 78, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of oligomers, co-oligomers, ter-oligomers, tetra-oligomers, homopolymers, copolymers, terpolymers, and tetrapolymers of at least one monomer selected from the group consisting of acrylic acid, alkylacrylic acid, alkyl ester of acrylic acid, alkyl ester of alkylacrylic acid, hydroxyalkyl ester of acrylic acid, hydroxyalkyl ester of alkylacrylic acid, acrylamide, alkylacrylamide, N-alkyl acrylamide, N,N-dialkyl acrylamdide, N-hydroxyalkylacrylamide, N,N-dihydroxyalkylacrylamide, styrene, alkylstyrene, ethene, propene, higher order alkene, diene, hydroxylated propene, polyhyrdoxylated polyalkene, halogenated ethylene, halogenated propylene, and halogenated alkylidene.
106. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
107. The paved road of claim 78, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
108. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of monoethoxylated, polyethoxylated, monopropylated, and polypropylated condensate of at least one member selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, oligomeric aziridine, polyaziridine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
109. The paved road of claim 78, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of monoethoxylated , polyethoxylated, monopropylated, and polypropylated condensates of at least one compound selected from the group consisting of oligomeric ethyleneamine, oligomeric polypropyleneamine, hexamethylene diamine, bis-hexamethylene diamine, oligomeric aziridine, polyaziridine, polyethylene polyamine, polypropylene polyamine, polyethylene/polypropylene polyamine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
110. The paved road of claim 78, wherein the surfactant package comprises homolog of hydroxylalkyl amine.
111. The paved road of claim 78, wherein the surfactant package comprises salt obtained by a reaction of (i) homolog of hydroxyalkyl amine and (ii) at least one member selected from the group consisting of hydrogen halide, carboxylic acid and phosphoric acid.
112. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of C-36 dimeric fatty acid and C-54 trimeric fatty acid.
113. The paved road of claim 78, wherein the surfactant package comprises polymeric condensation product of C-36 dimeric fatty acid and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
114. The paved road of claim 78, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of polymeric condensation product of C-36 dimeric fatty acid and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
115. The paved road of claim 78, wherein the surfactant package comprises polymeric condensation product of C-54 trimeric fatty acids and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
116. The paved road of claim 78, wherein the surfactant package comprises salt obtained by a reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of polymeric condensation product of C-54 trimeric fatty acid and at least one member selected from the group consisting of oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylamine, polypropylene polyamine, the distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine.
117. The paved road of claim 78, wherein the surfactant package comprises at least one member selected from the group consisting of hydroxystearic acid, oligomer of hydroxystearic acid, and polymeric hydroxystearic acid.
118. The paved road of claim 78, wherein the surfactant package comprises polymeric condensation product formed by a reaction of (i) at least one member selected from the group consisting of ethylene amine, propylene amine, ethylene/propylene amine, oligomeric ethyleneamine, polyethylene polyamine, oligomeric propylene amine, distillation residue from polyalkylene polyamine manufacture, and higher order polyalkylene polyamine; and (ii) at least one member selected from the group consisting of hydroxystearic acid, oligomer of hydroxystearic acid, and polymeric hydroxystearic acid.
119. The paved road of claim 78, the surfactant package comprises polymeric condensation product of (i) at least one member selected from the group consisting of hydroxystearic acid, oligomers of hydroxystearic acid, and polymeric hydroxystearic acid; and (ii) at least one member selected from the group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, and Lewis acid base.
120. The paved road of claim 78, wherein the surfactant package comprises ethoxytrimethyleneamine derivatives of C-12 to C-24 fatty amines of structure (I) wherein R = saturated or unsaturated aliphatic C-12 to C-24 having linear, branched, or cyclic structure;
x + y >= 2; and a, b >= 0.
121. The paved road of claim 78, wherein the surfactant package comprises polymeric condensation product of (i) at least one member selected from the group consisting of hydroxystearic acid, oligomers of hydroxystearic acid, and polymeric hydroxystearic acid; and (ii) at least one member selected from the group consisting of ethoxytrimethyleneamine derivatives of C-12 to C-24 fatty amines of structure (I).
122. The paved road of claim 78, wherein the surfactant package comprises propoxytrimethyleneamine derivatives of C-12 to C-24 fatty amines of structure (II) wherein R = saturated or unsaturated aliphatic C-12 to C-24 having linear, branched, or cyclic structure;
x + y >= 2; and a, b >= 0.
123. The paved road of claim 78, wherein the surfactant package comprises polymeric condensation product of (i) at least one member selected from the group consisting of hydroxystearic acid, oligomers of hydroxystearic acid, and polymeric hydroxystearic acid; and (ii) at least one member selected from the group consisting of propoxytrimethyleneamine derivative of C-12 to C-24 fatty amine of structure (II).
124. The paved road of claim 78, wherein the surfactant package comprises aliphatic diakylamine of structure (III) wherein R1, R2 = saturated or unsaturated C-12 to C-24 moieties having linear, branched, or cyclic structure.
125. The paved road of claim 78, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of saturated and unsaturated aliphatic C-12 to C-24 dialkyl amine of structure (III).
126. The paved road of claim 78, wherein the surfactant package comprises quaternary amine of structure (IV) wherein R1, R2 = saturated or unsaturated aliphatic C-12 to C-24 moieties having linear, branched, or cyclic structure; and R3, R4 = methyl or higher order homolog of saturated or unsaturated aliphatic C-12 to C-24 moieties having linear, branched, or cyclic structure.
127. The paved road of claim 78, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of saturated an unsaturated aliphatic C-12 to C-24 alkyl quaternary amine of structure (IV).
128. The paved road of claim 78, wherein the surfactant package comprises quaternary amine of structure (V) wherein:

R1, R2 = saturated or unsaturated aliphatic C-12 to C-24 moieties having linear, branched, or cyclic structure; and R3, R4 = ethoxy moieties, propoxy moieties, or combinations thereof.
129. The paved road of claim 78, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of saturated an unsaturated aliphatic C-12 to C-24 alkyl quaternary amine of structure (V).
130. The paved road of claim 78, wherein the surfactant package comprises bisamide formed by a reaction of polyalkylenepolyamine and adduct obtained by modifying at least one member selected from the group consisting of saturated aliphatic C-12 to C-24 fatty acid unsaturated aliphatic C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophiles, and wherein the C-12 to C-24 fatty acid has linear, branched, or cyclic structure.
131. The paved road of claim 78, wherein the surfactant package comprises salt obtained by the reaction of (i) at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and (ii) at least one member selected from the group consisting of bisamide formed by a reaction of polyalkylenepolyamine and adduct obtained by modifying at least one member selected from the group consisting of saturated aliphatic C-12 to C-24 fatty acid unsaturated aliphatic C-12 to C-24 fatty acids with at least one member selected from the group consisting of acrylic acid, maleic anhydride, fumaric acid, diene and dieneophiles, and wherein the C-12 to C-24 fatty acid has linear, branched, or cyclic structure.
132. The paved road of claim 78, wherein the surfactant package comprises dialkylarylamine.
133. The paved road of claim 78, wherein the surfactant package comprises salt obtained by the reaction of at least one member selected from the group consisting of hydrogen halide, carboxylic acid, and phosphoric acid; and dilakylarylamine.
134. The paved road of claim 78, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 40 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
135. The paved road of claim 78, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 30 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
136. The paved road of claim 78, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 20 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
137. The paved road of claim 78, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 10 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
138. The paved road of claim 78, wherein the surfactant package has an interfacial tension between the bitumen and water of less than 5 dynes/cm at a temperature of 26° C and at an aqueous concentration of less than 0.1 % weight.
139. The paved road of claim 78, wherein the water-in-oil bitumen dispersion comprises organic solvent in an amount of less than or equal to 4% by weight by total weight of the dispersion.
140. The paved road of claim 78, wherein the water-in-oil bitumen dispersion comprises organic solvent in an amount of less than 1% by weight by total weight of the dispersion.
141. The paved road of claim 78, wherein the aggregate comprises at least one member selected from the group consisting of dense-graded aggregate, gap-graded aggregate, open-graded, stone-matrix aggregate, reclaimed asphalt paving material, reclaimed roofing shingles, and combinations thereof.
142. The paved road of claim 78, wherein the bituminous composition further comprises additive for enhancing processability or improving performance of the composition.
143. The paved road of claim 78, wherein the water-in-oil bitumen dispersion is using high-shear mixing process comprising at least one member selected from the group consisting of high-shear colloid mill dispersion, high-shear static mixer dispersion, high-shear roto-mixer dispersion, high-shear dispersion via injection of the water into a bitumen process stream through phase inversion process, and combinations thereof.
144. The paved road of claim 78, wherein the bituminous composition is applied to its surface at a temperature in a range of about 0° C to about 120°
C.
145. The paved road of claim 78, wherein the bituminous composition is applied to its surface at a temperature in a range of about 85° C to about 100°
C.
146. The paved road of claim 78, wherein the bituminous composition is applied to its surface at a temperature in a range of about 85° C to about 95°
C.
147. The paved road of claim 78, wherein during preparation of the bituminous composition, the water-in-oil bitumen dispersion has a temperature in a range of about 75°C to about 95°C, and the aggregate and/or reclaimed asphalt pavement has a temperature in a range of about 60°C to about 140°C.
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