CA2656514A1 - Coated glass articles - Google Patents
Coated glass articles Download PDFInfo
- Publication number
- CA2656514A1 CA2656514A1 CA 2656514 CA2656514A CA2656514A1 CA 2656514 A1 CA2656514 A1 CA 2656514A1 CA 2656514 CA2656514 CA 2656514 CA 2656514 A CA2656514 A CA 2656514A CA 2656514 A1 CA2656514 A1 CA 2656514A1
- Authority
- CA
- Canada
- Prior art keywords
- coating
- article according
- composition
- film forming
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract 16
- 239000000203 mixture Substances 0.000 claims abstract 27
- 239000011347 resin Substances 0.000 claims abstract 22
- 229920005989 resin Polymers 0.000 claims abstract 22
- 238000000576 coating method Methods 0.000 claims abstract 19
- 229910052751 metal Inorganic materials 0.000 claims abstract 17
- 239000002184 metal Substances 0.000 claims abstract 17
- 150000001875 compounds Chemical class 0.000 claims abstract 8
- 238000006116 polymerization reaction Methods 0.000 claims abstract 8
- 239000003085 diluting agent Substances 0.000 claims abstract 6
- 125000000524 functional group Chemical group 0.000 claims abstract 6
- 239000000758 substrate Substances 0.000 claims abstract 6
- 238000000034 method Methods 0.000 claims abstract 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract 4
- 230000002378 acidificating effect Effects 0.000 claims abstract 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 4
- 230000001737 promoting effect Effects 0.000 claims abstract 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract 4
- 239000010703 silicon Substances 0.000 claims abstract 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract 3
- 238000005299 abrasion Methods 0.000 claims abstract 3
- 239000000945 filler Substances 0.000 claims abstract 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract 3
- 239000010936 titanium Substances 0.000 claims abstract 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 3
- 239000011248 coating agent Substances 0.000 claims 17
- 239000000049 pigment Substances 0.000 claims 7
- 150000002739 metals Chemical class 0.000 claims 6
- 239000000853 adhesive Substances 0.000 claims 5
- 230000001070 adhesive effect Effects 0.000 claims 5
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 4
- 239000000975 dye Substances 0.000 claims 4
- 229910052733 gallium Inorganic materials 0.000 claims 4
- 239000003999 initiator Substances 0.000 claims 4
- 150000002736 metal compounds Chemical class 0.000 claims 3
- 229910044991 metal oxide Inorganic materials 0.000 claims 3
- 150000004706 metal oxides Chemical class 0.000 claims 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 238000006845 Michael addition reaction Methods 0.000 claims 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 2
- 239000002318 adhesion promoter Substances 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 239000002270 dispersing agent Substances 0.000 claims 2
- 238000010894 electron beam technology Methods 0.000 claims 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- 239000010931 gold Substances 0.000 claims 2
- 239000003112 inhibitor Substances 0.000 claims 2
- 230000000977 initiatory effect Effects 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 239000012948 isocyanate Substances 0.000 claims 2
- 150000002513 isocyanates Chemical class 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 239000004332 silver Substances 0.000 claims 2
- 239000004094 surface-active agent Substances 0.000 claims 2
- 239000011135 tin Substances 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 claims 1
- 230000000903 blocking effect Effects 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 238000007607 die coating method Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/48—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
- C03C2217/485—Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/118—Deposition methods from solutions or suspensions by roller-coating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/31—Pre-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/925—Polymer from at least one nonethylenic monomer having terminal ethylenic unsaturation other than polyurethanes, polyesters, polyepoxides, aminoplasts, and phenoplasts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31645—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Abstract
The invention is a composition comprising: a) one or more film forming resins having at least one functional group capable of polymerization; b) one or more reactive diluents capable of reacting with the film forming resin; c) one or more silicon, titanium, zirconium, aluminum or metal containing compounds capable of promoting adhesion of the composition to glass; d) one or more fillers capable of imparting abrasion resistance to the composition when cured; and e) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety. The composition of the invention is useful as a frit on the window of a vehicle. Furthermore, the invention relates to a method for applying the coatings to glass and a method for bonding the coated glass to a structure or substrate, for instance, a building.
Claims (32)
1. An article comprising a glass substrate having one or more coatings disposed thereon comprising the reaction product of a) one or more film forming resins having at least one functional group capable of polymerization;
b) one or more reactive diluents capable of reacting with the film forming resin;
c) one or more silicon, titanium, zirconium, aluminum, or metal containing compounds capable of promoting adhesion of the composition to glass;
d) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety; and c) one or more of i) one or more pigments or dyes which render the coating partially opaque or opaque or ii) one or more metals or metal compounds which render the coating reflective.
b) one or more reactive diluents capable of reacting with the film forming resin;
c) one or more silicon, titanium, zirconium, aluminum, or metal containing compounds capable of promoting adhesion of the composition to glass;
d) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety; and c) one or more of i) one or more pigments or dyes which render the coating partially opaque or opaque or ii) one or more metals or metal compounds which render the coating reflective.
2. An article according to Claim 1 wherein the coating comprises one or more pigments or dyes which render the coating partially opaque or opaque
3. An article according to Claim 4 wherein at least one of the one or more pigments are capable of blocking the transmission of ultraviolet light.
4. An article according to Claim 1 which comprises one or more metals or metal compounds which render the coating reflective.
5. An article according to Claim 4 wherein the metal or metal oxide is a transition or group III, IV, & VI, metals.
6. An article according to Claim 5 wherein the metal is gallium, copper, chromium, nickel, tin, iron, cobalt, silver and gold, or the oxides thereof, or various mixtures of such metals and oxides.
7. An article according to Claim 6 wherein the metal is gallium.
8. An article according to Claim 3 wherein the functional groups capable of polymerization of the film-forming resin polymerize when exposed to irradiation and the composition further comprises f) one or more catalysts or initiators capable of initiating polymerization of the film-forming resin.
9. An article according to Claim 8 wherein the one or more film-forming resins contain unsaturated moieties which polymerize when exposed to ultraviolet light and the initiator is a photoinitiator.
10. An article according to Claim 9 wherein the one or more film forming resins contain unsaturated moieties which polymerize when exposed to electron beams.
11. An article according to Claim 3 wherein the coating further comprises one or more surfactants, dispersants, inhibitors, or mixtures thereof.
12. An article according to Claim 3 which further comprises one or more fillers capable of imparting abrasion resistance to the composition when polymerized.
13. An article according to Claim 9 wherein the film forming resins, and reactive diluents have acrylate functional moieties.
14. An article according to Claim 3 wherein adhesion promoter comprises a mixture of a Michael addition adduct a high molecular weight adduct having multiple alkoxysilanes.
15. An article according to Claim 3 wherein the pigment is carbon black.
16. An article according to Claim 4 wherein the coating comprising one or more metal or metal oxides is disposed on the glass and disposed on the metal or metal oxide coating is a coating comprising the reaction product of a) one or more film forming resins having at least one functional group capable of polymerization;
b) one or more reactive diluents capable of reacting with the film forming resin;
c) one or more silicon, titanium, zirconium, aluminium, or metal containing compounds capable of promoting adhesion of the composition to glass;
d) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety; and c) one or more pigments or dyes which render die coating partially opaque or opaque.
b) one or more reactive diluents capable of reacting with the film forming resin;
c) one or more silicon, titanium, zirconium, aluminium, or metal containing compounds capable of promoting adhesion of the composition to glass;
d) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety; and c) one or more pigments or dyes which render die coating partially opaque or opaque.
17. A window structure comprising a window frame and a window which comprises an article according to Claim 1.
18. A window structure according to Claim 17 wherein the cured coating is bonded to an adhesive and the adhesive is further bonded to a window frame of the structure.
19. A spandrel structure comprising an Article according to Claim 4.
20. A spandrel structure according to Claim 19 which further comprises an insulating panel material bonded to the opaque coating.
21. A method for coating a glass substrate comprising applying a coating according to Claim 1 to the surface of the glass substrate and (b) exposing the coated glass substrate to conditions such that the coating cures.
22. A method for bonding a glass into a structure which comprises applying an adhesive having isocyanate, siloxy or both isocyanate and siloxy functionality to the surface of the cured coating of an article according to Claim 1;
contacting the glass with a window frame of a structure wherein the adhesive is located between the glass and the window frame and allowing the adhesive to cure.
contacting the glass with a window frame of a structure wherein the adhesive is located between the glass and the window frame and allowing the adhesive to cure.
23. A composition comprising a) one or more film forming resins having at least one functional group capable of polymerization;
h) one or more reactive diluents capable of reacting with the film forming resin;
C) one or more silicon, titanium zirconium, aluminum, or metal containing compounds capable of promoting adhesion of the composition to glass;
d) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety; and e) one or more of one or more metals or metal compounds which render the composition reflective once cured wherein the metal is gallium, copper, chromium, nickel, tin, iron, cobalt, silver and gold, or the oxides thereof, or various mixtures of such metals and oxides.
h) one or more reactive diluents capable of reacting with the film forming resin;
C) one or more silicon, titanium zirconium, aluminum, or metal containing compounds capable of promoting adhesion of the composition to glass;
d) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety; and e) one or more of one or more metals or metal compounds which render the composition reflective once cured wherein the metal is gallium, copper, chromium, nickel, tin, iron, cobalt, silver and gold, or the oxides thereof, or various mixtures of such metals and oxides.
24. A composition according to Claim 24 wherein the metal is gallium.
25. A composition according to Claim 23 wherein the functional groups capable of polymerization of the film-forming resin polymerize when exposed to irradiation and the composition further comprises f) one or more catalysts or initiators capable of initiating polymerization of the film-forming resin.
26. A composition according to Claim 23 wherein the one or more film-forming resins contain unsaturated moieties which polymerize when exposed to ultraviolet light and the initiator is a photoinitiator.
27. A compositions according to Claim 26 wherein the one or more film forming resins contain unsaturated moieties which polymerize when exposed to electron beams.
28. A composition according to Claim 23 which further comprises one or more surfactants, dispersants, inhibitors, or mixtures thereof.
29. A composition according to Claim 23 which further comprises one or more fillers capable of imparting abrasion resistance to the composition when polymerized.
30. A composition according to Claim 27 wherein the film forming resins, and reactive diluents have acrylate functional moieties.
31. A composition according to Claim 23 wherein adhesion promoter comprises a mixture of a Michael addition adduct and a high molecular weight adduct having multiple alkoxysilanes.
32. A method according to Claim 20 wherein more than one coating comprising pigments of dyes are applied to the glass substrate wherein each coating contains a different color pigment.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/472,119 US7781493B2 (en) | 2005-06-20 | 2006-06-20 | Protective coating for window glass |
US11/472,119 | 2006-06-20 | ||
PCT/US2006/049094 WO2007149125A1 (en) | 2006-06-20 | 2006-12-20 | Coated glass articles |
Publications (2)
Publication Number | Publication Date |
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EP (1) | EP2035341B1 (en) |
JP (1) | JP5264718B2 (en) |
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CN (1) | CN101472852B (en) |
BR (1) | BRPI0621688A2 (en) |
CA (1) | CA2656514C (en) |
MX (1) | MX2008015077A (en) |
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2006
- 2006-06-20 US US11/472,119 patent/US7781493B2/en not_active Expired - Fee Related
- 2006-12-20 RU RU2009101472A patent/RU2417172C2/en not_active IP Right Cessation
- 2006-12-20 EP EP06848064.9A patent/EP2035341B1/en not_active Not-in-force
- 2006-12-20 WO PCT/US2006/049094 patent/WO2007149125A1/en active Application Filing
- 2006-12-20 BR BRPI0621688-9A patent/BRPI0621688A2/en not_active IP Right Cessation
- 2006-12-20 KR KR1020087030920A patent/KR101035428B1/en not_active IP Right Cessation
- 2006-12-20 CA CA 2656514 patent/CA2656514C/en not_active Expired - Fee Related
- 2006-12-20 CN CN2006800550325A patent/CN101472852B/en not_active Expired - Fee Related
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EP2035341A1 (en) | 2009-03-18 |
US20100316828A1 (en) | 2010-12-16 |
US20120046375A1 (en) | 2012-02-23 |
US7781493B2 (en) | 2010-08-24 |
BRPI0621688A2 (en) | 2011-12-20 |
CA2656514C (en) | 2012-03-13 |
JP5264718B2 (en) | 2013-08-14 |
US8080299B2 (en) | 2011-12-20 |
RU2417172C2 (en) | 2011-04-27 |
RU2009101472A (en) | 2010-07-27 |
US8273801B2 (en) | 2012-09-25 |
KR101035428B1 (en) | 2011-05-18 |
JP2009541196A (en) | 2009-11-26 |
CN101472852B (en) | 2012-02-08 |
CN101472852A (en) | 2009-07-01 |
US20060287408A1 (en) | 2006-12-21 |
KR20090018145A (en) | 2009-02-19 |
EP2035341B1 (en) | 2016-04-06 |
WO2007149125A1 (en) | 2007-12-27 |
MX2008015077A (en) | 2008-12-05 |
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