CA2667299A1 - Negative electrode for hybrid energy storage device - Google Patents

Negative electrode for hybrid energy storage device Download PDF

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Publication number
CA2667299A1
CA2667299A1 CA002667299A CA2667299A CA2667299A1 CA 2667299 A1 CA2667299 A1 CA 2667299A1 CA 002667299 A CA002667299 A CA 002667299A CA 2667299 A CA2667299 A CA 2667299A CA 2667299 A1 CA2667299 A1 CA 2667299A1
Authority
CA
Canada
Prior art keywords
negative electrode
current collector
corrosion
sheet
conductive coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002667299A
Other languages
French (fr)
Other versions
CA2667299C (en
Inventor
Edward Buiel
Leonid Rabinovich
Wei Sun
Vladimir Vichnyakov
Adam Swiecki
Joseph Cole
Victor Eshkenazi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Axion Power International Inc
Original Assignee
Axion Power International, Inc.
Edward Buiel
Leonid Rabinovich
Wei Sun
Vladimir Vichnyakov
Adam Swiecki
Joseph Cole
Victor Eshkenazi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Axion Power International, Inc., Edward Buiel, Leonid Rabinovich, Wei Sun, Vladimir Vichnyakov, Adam Swiecki, Joseph Cole, Victor Eshkenazi filed Critical Axion Power International, Inc.
Publication of CA2667299A1 publication Critical patent/CA2667299A1/en
Application granted granted Critical
Publication of CA2667299C publication Critical patent/CA2667299C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/26Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
    • H01G11/28Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/10Multiple hybrid or EDL capacitors, e.g. arrays or modules
    • H01G11/12Stacked hybrid or EDL capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/26Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • H01G11/34Carbon-based characterised by carbonisation or activation of carbon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • H01G11/38Carbon pastes or blends; Binders or additives therein
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66Current collectors
    • H01G11/68Current collectors characterised by their material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66Current collectors
    • H01G11/70Current collectors characterised by their structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/74Terminals, e.g. extensions of current collectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/74Terminals, e.g. extensions of current collectors
    • H01G11/76Terminals, e.g. extensions of current collectors specially adapted for integration in multiple or stacked hybrid or EDL capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/04Electrodes or formation of dielectric layers thereon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/04Hybrid capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/46Metal oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

Abstract

A negative electrode for a hybrid energy storage device includes a current collector; a corrosion-resistant conductive coating secured to at least one face of the current collector; a sheet comprising activated carbon adhered to the corrosion-resistant conductive coating; a tab portion extending from a side of the negative electrode; and a lug comprising a lead or lead alloy that encapsulates at least part of the tab portion.

Claims (18)

1. A negative electrode for a hybrid energy storage device, characterized by:
a current collector;
a corrosion-resistant conductive coating secured to at least one face of the current collector;
a sheet comprising activated carbon adhered to the corrosion-resistant conductive coating;
a tab portion extending from a side of said negative electrode; and a lug comprising a lead or lead alloy that encapsulates the tab portion.
2. The negative electrode of Claim 1, characterized in that the sheet comprises:
5-95 wt% activated carbon, 5-95 wt% lead, and 5-20 wt% conductive carbon.
3. The negative electrode of Claim 1-2, characterized in that a corrosion-resistant conductive coating is secured to both faces of said current collector, and a sheet comprising activated carbon is adhered to and in electrical contact with said corrosion-resistant conductive coatings on both faces of the current collector.
4. The negative electrode of Claim 1-2, characterized in that the current collector comprises a metallic material.
5. The negative electrode of Claim 1-2, characterized in that the current collector comprises a material having a conductivity of 1.0×10 5 siemens/m.
6. The negative electrode of Claim 1-4, characterized in that the current collector comprises copper or a copper alloy.
7. The negative electrode of Claim 1-2, characterized in that the corrosion-resistant conductive coating comprises an expanded graphite sheet or foil impregnated with paraffin and rosin.
8. The negative electrode of Claim 7, characterized in that the expanded graphite sheet or foil comprises low-density graphite having a density in the range of about 0.1 to about 2.0 g/cm3.
9. The negative electrode of Claim 1, characterized in that the current collector is in the form of a sheet, a foil, or a mesh.
10. The negative electrode of Claim 9, characterized in that the current collector is in the form of a mesh having the corrosion-resistant conductive coating pressed into the mesh.
11. The negative electrode of Claim 1-4, characterized in that the sheet of activated carbon further comprises at least one of polytetrafluoroethylene or ultra high molecular weight polyethylene.
12. The negative electrode of Claim 1-2, characterized in that the corrosion-resistant conductive coating comprises a titanium sub-oxide represented by the formula Ti x O2 x-1, wherein x is an integer.
13. The negative electrode of Claim 1-2, characterized in that the corrosion-resistant conductive coating comprises a conductive diamond material.
14. The negative electrode of Claim 1, characterized in that the lug has a thickness of about 0.05 mm to about 10 mm.
15. A negative electrode for a hybrid energy storage device, characterized by:

a current collector;

a corrosion-resistant conductive coating secured to at least one face of said current collector, and comprising a graphite sheet or foil impregnated with paraffin and rosin;
a sheet comprising activated carbon adhered to the corrosion-resistant conductive coating; and a tab portion extending from a side of said negative electrode.
16. The negative electrode of Claim 15, characterized in that the sheet of activated carbon further comprises at least one of polytetrafluoroethylene or ultra high molecular weight polyethylene.
17. The negative electrode of Claim 15, characterized in that the current collector comprises copper or a copper alloy.
18. A negative electrode being substantially as herein described with reference to the accompanying drawings.
CA2667299A 2006-10-23 2007-10-22 Negative electrode for hybrid energy storage device Expired - Fee Related CA2667299C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US85343906P 2006-10-23 2006-10-23
US60/853,439 2006-10-23
PCT/US2007/082047 WO2008051885A1 (en) 2006-10-23 2007-10-22 Negative electrode for hybrid energy storage device

Publications (2)

Publication Number Publication Date
CA2667299A1 true CA2667299A1 (en) 2008-05-02
CA2667299C CA2667299C (en) 2013-01-08

Family

ID=39324932

Family Applications (2)

Application Number Title Priority Date Filing Date
CA2667300A Expired - Fee Related CA2667300C (en) 2006-10-23 2007-10-22 Hybrid energy storage device and method of making same
CA2667299A Expired - Fee Related CA2667299C (en) 2006-10-23 2007-10-22 Negative electrode for hybrid energy storage device

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CA2667300A Expired - Fee Related CA2667300C (en) 2006-10-23 2007-10-22 Hybrid energy storage device and method of making same

Country Status (10)

Country Link
US (3) US8023251B2 (en)
EP (2) EP2076912B1 (en)
JP (2) JP5149300B2 (en)
KR (2) KR101050021B1 (en)
CN (2) CN101563741B (en)
BR (2) BRPI0717381A2 (en)
CA (2) CA2667300C (en)
ES (2) ES2500167T3 (en)
MX (2) MX2009004311A (en)
WO (2) WO2008051885A1 (en)

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