CA2676108A1 - Foamed thermoplastic polyurethanes - Google Patents

Foamed thermoplastic polyurethanes Download PDF

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Publication number
CA2676108A1
CA2676108A1 CA002676108A CA2676108A CA2676108A1 CA 2676108 A1 CA2676108 A1 CA 2676108A1 CA 002676108 A CA002676108 A CA 002676108A CA 2676108 A CA2676108 A CA 2676108A CA 2676108 A1 CA2676108 A1 CA 2676108A1
Authority
CA
Canada
Prior art keywords
process according
blowing agent
parts
thermoplastic polyurethane
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002676108A
Other languages
French (fr)
Other versions
CA2676108C (en
Inventor
Dominicus Limerkens
Johan Van Dijck
Bart Van Edom
Rhona Watson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman International LLC
Original Assignee
Huntsman International Llc
Dominicus Limerkens
Johan Van Dijck
Bart Van Edom
Rhona Watson
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8237406&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2676108(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Huntsman International Llc, Dominicus Limerkens, Johan Van Dijck, Bart Van Edom, Rhona Watson filed Critical Huntsman International Llc
Publication of CA2676108A1 publication Critical patent/CA2676108A1/en
Application granted granted Critical
Publication of CA2676108C publication Critical patent/CA2676108C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/22—Expandable microspheres, e.g. Expancel®
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Abstract

Process for the preparation of foamed thermoplastic polyurethanes characterized in that the foaming of the thermoplastic polyurethane is carried out in the presence of thermally expandable microspheres.

Claims (15)

1. Process for the preparation of foamed thermoplastic polyurethanes wherein foaming of the thermoplastic polyurethane is carried out in the presence of thermally expandable microspheres containing a hydrocarbon and in the presence of an additional blowing agent, the amount of microspheres being between 0.5 and 4.0 parts by weight per 100 parts by weight of thermoplastic polyurethane, and the amount of additional blowing agent being between 0.5 and 4.0 parts by weight per 100 parts by weight of thermoplastic polyurethane.
2. Process according to claim 1, wherein the hydrocarbon is an aliphatic or cycloaliphatic hydrocarbon.
3. Process according to claim 1 or 2, wherein an endothermic blowing agent is present as the additional blowing agent.
4. Process according to claim 1 or 2, wherein an exothermic blowing agent is present as the additional blowing agent.
5. Process according to claim 3, wherein the endothermic blowing agent comprises bicarbonates or citrates.
6. Process according to claim 4, wherein the exothermic blowing agent comprises azodicarbonamide type compounds.
7. Process according to any one of claims 1 to 6, wherein the process is carried out by injection moulding.
8. Process according to any one of claims 1 to 6, wherein the process is carried out in a pressurized mould.
9. Process according to any one of claims 1 to 8, wherein the thermoplastic polyurethane is made by using a difunctional isocyanate composition comprising an aromatic difunctional isocyanate and a difunctional polyhydroxy compound.
10. Process according to claim 9, wherein the aromatic difunctional isocyanate comprises diphenylmethane diisocyanate.
11. Process according to claim 9, wherein the difunctional polyhydroxy compound comprises a polyoxyalkylene diol or polyester diol.
12. Process according to claim 11, wherein the polyoxyalkylene diol comprises oxyethylene groups.
13. Process according to claim 12, wherein the polyoxyalkylene diol is a poly(oxyethylene-oxypropylene) diol.
14. Process according to any one of claims 1 to 13, wherein the amount of microspheres is between 1.0 and 3.0 parts by weight per 100 parts by weight of thermoplastic polyurethane.
15. Process according to any one of claims 1 to 14, wherein the amount of additional blowing agent is between 1.0 and 3.0 parts by weight per 100 parts by weight of thermoplastic polyurethane.
CA2676108A 1999-01-26 2000-01-05 Foamed thermoplastic polyurethanes Expired - Lifetime CA2676108C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP99101359.0 1999-01-26
EP99101359 1999-01-26
CA002360114A CA2360114C (en) 1999-01-26 2000-01-05 Foamed thermoplastic polyurethanes

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CA002360114A Division CA2360114C (en) 1999-01-26 2000-01-05 Foamed thermoplastic polyurethanes

Publications (2)

Publication Number Publication Date
CA2676108A1 true CA2676108A1 (en) 2000-08-03
CA2676108C CA2676108C (en) 2011-11-22

Family

ID=8237406

Family Applications (2)

Application Number Title Priority Date Filing Date
CA002360114A Expired - Lifetime CA2360114C (en) 1999-01-26 2000-01-05 Foamed thermoplastic polyurethanes
CA2676108A Expired - Lifetime CA2676108C (en) 1999-01-26 2000-01-05 Foamed thermoplastic polyurethanes

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CA002360114A Expired - Lifetime CA2360114C (en) 1999-01-26 2000-01-05 Foamed thermoplastic polyurethanes

Country Status (24)

Country Link
US (2) US7202284B1 (en)
EP (2) EP1165674B1 (en)
JP (1) JP3357871B2 (en)
KR (1) KR100611686B1 (en)
CN (2) CN100586978C (en)
AR (2) AR035007A1 (en)
AT (2) ATE221906T1 (en)
AU (1) AU768105B2 (en)
BR (1) BR0007689A (en)
CA (2) CA2360114C (en)
CO (1) CO5200795A1 (en)
CZ (1) CZ20012684A3 (en)
DE (2) DE60000314T2 (en)
DK (2) DK1165674T3 (en)
EG (1) EG22463A (en)
ES (2) ES2269548T3 (en)
HK (1) HK1044346B (en)
MY (1) MY121404A (en)
PL (1) PL201662B1 (en)
PT (2) PT1165674E (en)
RU (1) RU2229486C2 (en)
TW (1) TWI224605B (en)
UA (1) UA72494C2 (en)
WO (1) WO2000044821A1 (en)

Families Citing this family (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USD953709S1 (en) 1985-08-29 2022-06-07 Puma SE Shoe
USD855953S1 (en) 2017-09-14 2019-08-13 Puma SE Shoe sole element
KR100611686B1 (en) * 1999-01-26 2006-08-14 헌트스만 인터내셔날,엘엘씨 Foamed Thermoplastic Polyurethanes
ATE499953T1 (en) * 1999-03-02 2011-03-15 Convatec Technologies Inc HYDROCOLLOID GLUE
EP1240006B1 (en) * 1999-12-24 2006-02-08 Huntsman International Llc Gas assisted injection moulding
US6866906B2 (en) 2000-01-26 2005-03-15 International Paper Company Cut resistant paper and paper articles and method for making same
EP1174458A1 (en) * 2000-07-20 2002-01-23 Huntsman International Llc Foamed thermoplastic polyurethanes
WO2002096635A1 (en) 2001-05-25 2002-12-05 Apache Products Company Expandable microspheres for foam insulation and methods
DE10162348A1 (en) † 2001-12-18 2003-07-10 Basf Ag Process for applying functional materials to thermoplastic polyurethane
RU2330911C2 (en) 2002-09-13 2008-08-10 Интернэшнл Пейпер Компани Paper of improved rigidity and bulk and method to produce thereof
DE10326138A1 (en) * 2003-06-06 2004-12-23 Basf Ag Process for the production of expandable thermoplastic elastomers
DE10340539A1 (en) * 2003-09-01 2005-03-24 Basf Ag Process for the preparation of expanded thermoplastic elastomers
DE10342857A1 (en) * 2003-09-15 2005-04-21 Basf Ag Expandable thermoplastic polyurethane blends
JP2007529600A (en) * 2004-03-15 2007-10-25 ダウ グローバル テクノロジーズ インコーポレイティド Method for adhering foamable flexible polyurethane to a substrate
WO2006027805A1 (en) 2004-09-08 2006-03-16 Elachem S.R.L. Composition and process for the realization of low density expanded products
ITRN20050006A1 (en) * 2005-02-22 2006-08-23 Goldenplast Spa GRANULAR MIXTURE OF POLYURETHANE-BASED THERMOPLASTIC MATERIALS FOR THE FORMATION OF LIGHT, EXPANDED AND SPECIAL SHOES, FOOTWEAR
WO2006099364A1 (en) 2005-03-11 2006-09-21 International Paper Company Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same
DE102005050411A1 (en) 2005-10-19 2007-04-26 Basf Ag Shoe soles based on foamed thermoplastic polyurethane (TPU)
US9387642B2 (en) 2006-01-13 2016-07-12 Rich Cup Bio-Chemical Technology Co., Ltd. Process for manufacturing a heat insulation container
US20120251719A1 (en) * 2006-01-13 2012-10-04 Sheng-Shu Chang Process for manufacturing a heat insulation container
ATE482991T1 (en) * 2006-01-18 2010-10-15 Basf Se FOAM BASED ON THERMOPLASTIC POLYURETHANES
JP5235875B2 (en) * 2006-06-30 2013-07-10 ハンツマン・インターナショナル・エルエルシー New tennis ball
WO2008014227A2 (en) 2006-07-24 2008-01-31 Huntsman Petrochemical Corporation Light colored foam for use in marine applications
PL2109637T3 (en) 2007-01-16 2019-02-28 Basf Se Hybrid systems consisting of foamed thermoplastic elastomers and polyurethanes
EP2129844A4 (en) * 2007-03-13 2011-11-30 Acma Ind Ltd Impact absorbing product
BRPI0809606A2 (en) * 2007-04-05 2014-09-30 Teijin Aramid Bv METHOD FOR PRODUCING A POLYMER FOAM, FOAM, AND MOLDED ARTICLE
EP2072549A1 (en) * 2007-12-19 2009-06-24 Huntsman International Llc Novel composition from a polyisocyanate and a polyether monoamine
EP2328947A1 (en) 2008-08-28 2011-06-08 International Paper Company Expandable microspheres and methods of making and using the same
US8372770B2 (en) * 2008-12-11 2013-02-12 Chevron U.S.A. Inc. Reformer regeneration process
ES2522821T3 (en) * 2009-05-11 2014-11-18 Basf Se Hybrid foam
BRPI1011009B1 (en) * 2009-06-09 2020-01-28 Huntsman Int Llc material and process for preparing a material
DE102009044532A1 (en) * 2009-11-15 2011-05-19 Allgaier Gmbh & Co. Besitz Kg Method for producing objects
KR101231023B1 (en) 2009-11-26 2013-02-07 제일모직주식회사 Rigid polyurethane foam having an excellent insulating ability and method for preparing the same
TWI486368B (en) 2010-01-11 2015-06-01 Lubrizol Advanced Mat Inc Thermoplastic polyurethane for printing blankets
KR101332433B1 (en) * 2010-08-24 2013-11-22 제일모직주식회사 Rigid polyurethane foam having good insulation property and method for preparing the same
KR101020089B1 (en) 2010-09-03 2011-03-09 한국신발피혁연구소 Method for manufacture of ultra super light-weight shape memory foam composition with excellent shape-stability
DE102011108744B4 (en) * 2011-07-28 2014-03-13 Puma SE Method for producing a sole or a sole part of a shoe
DE102012206094B4 (en) 2012-04-13 2019-12-05 Adidas Ag Soles for sports footwear, shoes and method of making a shoe sole
US8815201B2 (en) 2012-05-22 2014-08-26 Chevron U.S.A. Inc. Process for regenerating a reforming catalyst
DE102012105351A1 (en) * 2012-06-20 2013-12-24 Dipl.-Ing. Dr. Ernst Vogelsang Gmbh & Co Kg Method for producing a pipe
US9737439B2 (en) * 2012-07-12 2017-08-22 3M Innovative Properties Company Push-in earplug
US8968613B2 (en) * 2012-07-12 2015-03-03 3M Innovative Properties Company Method of making an earplug
PL410884A1 (en) * 2012-07-13 2015-07-20 Arya Polimer Sanayi Ve Ticaret Limited Şirketi Rubber from low density thermoplastic polyurethane (TPU)
DE102013202291B4 (en) 2013-02-13 2020-06-18 Adidas Ag Damping element for sportswear and shoes with such a damping element
US9610746B2 (en) 2013-02-13 2017-04-04 Adidas Ag Methods for manufacturing cushioning elements for sports apparel
DE102013202306B4 (en) 2013-02-13 2014-12-18 Adidas Ag Sole for a shoe
DE102013002519B4 (en) 2013-02-13 2016-08-18 Adidas Ag Production method for damping elements for sportswear
DE102013108053A1 (en) 2013-07-26 2015-01-29 Kurtz Gmbh Method and device for producing a particle foam part
EP2958727B1 (en) 2013-02-20 2018-09-05 Kurtz GmbH Method and device for producing a foam particle part
USD758056S1 (en) 2013-04-12 2016-06-07 Adidas Ag Shoe
USD776410S1 (en) 2013-04-12 2017-01-17 Adidas Ag Shoe
DE102013207467A1 (en) * 2013-04-24 2014-10-30 Tesa Se Dual foamed polymer mass
EP2829495A1 (en) 2013-07-23 2015-01-28 Habasit AG Abrasion-resistant belt
WO2015061127A1 (en) * 2013-10-21 2015-04-30 Basf Se Viscoelastic foam system
KR20160135816A (en) 2014-03-21 2016-11-28 헨켈 아게 운트 코. 카게아아 Thermally expandable compositions
DE102014215897B4 (en) 2014-08-11 2016-12-22 Adidas Ag adistar boost
DE102014216115B4 (en) 2014-08-13 2022-03-31 Adidas Ag 3D elements cast together
US9884949B1 (en) * 2015-04-10 2018-02-06 Georgia Tech Research Corporation Syntactic foam with residual internal pressurization
DE102015206486B4 (en) 2015-04-10 2023-06-01 Adidas Ag Shoe, in particular sports shoe, and method for manufacturing the same
DE102015206900B4 (en) 2015-04-16 2023-07-27 Adidas Ag sports shoe
DE102015209795B4 (en) 2015-05-28 2024-03-21 Adidas Ag Ball and process for its production
DE202015005873U1 (en) 2015-08-25 2016-11-28 Rti Sports Gmbh bicycle saddle
USD783264S1 (en) 2015-09-15 2017-04-11 Adidas Ag Shoe
KR101726700B1 (en) 2016-05-11 2017-04-13 주식회사 동성코퍼레이션 Thermoplastic polyurethane with cross-linking sites and Cross-linking foam method using the same
USD840136S1 (en) 2016-08-03 2019-02-12 Adidas Ag Shoe midsole
USD840137S1 (en) 2016-08-03 2019-02-12 Adidas Ag Shoe midsole
USD852475S1 (en) 2016-08-17 2019-07-02 Adidas Ag Shoe
DE202016005103U1 (en) 2016-08-24 2017-11-29 Rti Sports Gmbh bicycle saddle
DE202017000579U1 (en) 2017-02-03 2018-05-04 Ergon International Gmbh bicycle saddle
EP3504113A1 (en) 2016-08-24 2019-07-03 Ergon International GmbH Bicycle saddle
DE102017201775A1 (en) 2017-02-03 2018-08-09 Ergon International Gmbh Bicycle saddle, saddle pad and method of making a bicycle saddle or saddle pad
US20190202513A1 (en) 2016-08-30 2019-07-04 Ergon International Gmbh Bicycle Saddle, Saddle Pad, and Method for Producing a Bicycle Saddle or Saddle Pad
DE102016216309A1 (en) 2016-08-30 2018-03-01 Ergon International Gmbh Bicycle saddle, saddle pad and method of making a bicycle saddle or saddle pad
JP1582717S (en) 2016-09-02 2017-07-31
KR102205059B1 (en) 2016-11-17 2021-01-19 미쓰이 가가쿠 가부시키가이샤 Manufacturing method of polyurethane resin, polyurethane resin and molded product
WO2018092744A1 (en) 2016-11-17 2018-05-24 三井化学株式会社 Thermoplastic polyurethane resin for foaming and production method thereof, and molded article
CN106626202A (en) 2017-01-16 2017-05-10 美瑞新材料股份有限公司 Preparation method of expansive type thermoplastic polyurethane elastomer product
USD850766S1 (en) 2017-01-17 2019-06-11 Puma SE Shoe sole element
US11597462B2 (en) 2017-01-28 2023-03-07 Ergon International Gmbh Bicycle saddle
DE202017004495U1 (en) 2017-08-28 2018-11-30 Ergon International Gmbh bicycle saddle
DE202017000484U1 (en) 2017-01-28 2018-05-03 Ergon International Gmbh bicycle saddle
DE102017202026A1 (en) 2017-02-09 2018-08-09 Ergon International Gmbh Bicycle saddle and method of making a bicycle saddle
DE202017002940U1 (en) 2017-05-29 2018-08-30 Ergon International Gmbh bicycle saddle
US10864676B2 (en) 2017-06-01 2020-12-15 Nike, Inc. Methods of manufacturing articles utilizing foam particles
US11339264B2 (en) 2017-07-20 2022-05-24 Solvay Sa Functionalized particulate bicarbonate as blowing agent, foamable polymer composition containing it, and its use in manufacturing a thermoplastic foamed polymer
EP3441291A1 (en) 2017-08-10 2019-02-13 SQlab GmbH Ergonomic bicycle saddle for relieving the pressure on seat bones
WO2019029781A1 (en) 2017-08-11 2019-02-14 Puma SE Method for producing a shoe
DE202017004489U1 (en) 2017-08-29 2018-12-02 Ergon International Gmbh bicycle saddle
USD975417S1 (en) 2017-09-14 2023-01-17 Puma SE Shoe
USD899061S1 (en) 2017-10-05 2020-10-20 Adidas Ag Shoe
DE202018000895U1 (en) 2018-02-21 2019-05-23 Ergon International Gmbh bicycle saddle
DE202018000943U1 (en) 2018-02-22 2019-05-23 Ergon International Gmbh bicycle saddle
US11832684B2 (en) 2018-04-27 2023-12-05 Puma SE Shoe, in particular a sports shoe
DE102018211090A1 (en) 2018-07-05 2020-01-09 Ergon International Gmbh Bicycle saddle and method for producing a cushion element for a bicycle saddle
CN108948724B (en) * 2018-08-22 2020-11-06 清华大学 Preparation method of thermoplastic polyurethane foam with high mechanical loss factor
CN109251353A (en) * 2018-10-24 2019-01-22 东莞市富兴鞋材有限公司 Expancel DU: the high-efficiency broad spectrum auxiliary agent of polyurathamc physical property is improved
EP3984401B1 (en) 2018-12-06 2023-06-07 Nike Innovate C.V. Methods of manufacturing articles utilizing foam particles
JP7227682B2 (en) * 2019-04-26 2023-02-22 株式会社イノアックコーポレーション sound absorbing material
CN110330631A (en) * 2019-07-16 2019-10-15 华北电力大学（保定） A kind of preparation method of the inner core packing material for composite insulation cross arm
DE202019104601U1 (en) 2019-08-22 2020-11-24 Ergon International Gmbh Bicycle saddle
WO2021101967A1 (en) 2019-11-19 2021-05-27 Nike, Inc. Methods of manufacturing articles having foam particles
EP3825081B8 (en) * 2019-11-22 2023-01-11 BIC Violex Single Member S.A. Razor blades
USD944504S1 (en) 2020-04-27 2022-03-01 Puma SE Shoe
KR102422811B1 (en) * 2020-11-25 2022-07-19 (주)아트프린텍 Upper member of shoes with design and manufacturing method of thereof
WO2022194985A1 (en) * 2021-03-19 2022-09-22 Huntsman International Llc Method for making a low density thermally recyclable polymer foam

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0022617B2 (en) 1979-07-11 1991-09-25 Imperial Chemical Industries Plc Polyisocyanate compositions and their use in the preparation of polyurethane foams
AT366565B (en) 1979-11-08 1982-04-26 Schaefer Philipp MOLDED PART FROM POLYURETHANE AND METHOD FOR PRODUCING THE SAME
JPS59108041A (en) 1982-12-14 1984-06-22 Asahi Oorin Kk Preparation of polyurethane foam
US5096992A (en) * 1989-03-20 1992-03-17 Reeves Brothers, Inc. Use of modified diisocyanates for preparing linear thermoplastic polyurethane elastomers having improved properties
DE3930838A1 (en) * 1989-09-15 1991-03-28 Bayer Ag METHOD FOR PRODUCING TPU-CONTAINING CHEMICAL MATERIALS
DE4015714A1 (en) 1990-05-16 1991-11-21 Bayer Ag Glass fibre-reinforced thermoplastic polyurethane foam - by injection moulding mixt. of GFR thermoplastic polyurethane and a blowing agent
DE4117649C1 (en) 1991-05-29 1993-01-07 Era Beschichtung Gmbh & Co. Kg, 3078 Stolzenau, De
US5583196A (en) * 1992-01-31 1996-12-10 Karl Fischer Industrieanlagen Gmbh Melt formed from polyurethane and/or polyurethane urea elastomer and method for producing the same
US5260343A (en) * 1993-01-04 1993-11-09 Basf Corporation Low density flexible integral skin polyurethane systems using thermoplastic hydrocarbon microspheres and water as co-blowing agents
DE4307648A1 (en) * 1993-03-11 1994-09-15 Basf Ag Foams based on thermoplastic polyurethanes as well as expandable, particulate, thermoplastic polyurethanes, particularly suitable for the production of foam molded articles
US5418257A (en) * 1993-04-08 1995-05-23 Weisman; Morey Modified low-density polyurethane foam body
US5272001A (en) * 1993-04-08 1993-12-21 Morey Weisman Modified low-density polyurethane foam body
WO1995008590A1 (en) * 1993-09-24 1995-03-30 Urethane Technologies, Inc. Process for forming integral skin microcellular structures
CA2117741A1 (en) * 1993-10-28 1995-04-29 Michael F. Hurley Rim process utilizing isocyanates based upon 2,4'-and 4,4'- diphenylmethane diisocyanate
DE4406219A1 (en) * 1994-02-25 1995-08-31 Basf Schwarzheide Gmbh Solid or foam/solid polyurethane(s) for shoe soles
EP0692516A1 (en) 1994-07-15 1996-01-17 Hans-Joachim Burger Thermoplastic syntactic foam with accurate dimensions
BE1008800A7 (en) 1994-10-07 1996-08-06 Orfit Ind Foamed thermoplastic material.
JP3485382B2 (en) 1995-06-01 2004-01-13 富士通テン株式会社 FM-CW radar device
US5987783A (en) * 1995-06-05 1999-11-23 Acushnet Company Golf shoe having spike socket spine system
US5874133A (en) * 1995-06-07 1999-02-23 Randemo, Inc. Process for making a polyurethane composite
JPH09157427A (en) * 1995-12-05 1997-06-17 Matsumoto Yushi Seiyaku Co Ltd Paste-like composition and laminate having synthetic resin layer prepared by using the same
CA2239950C (en) * 1997-08-11 2007-09-18 Bayer Corporation Syntactic rigid pur/pir foam boardstock
JPH11310619A (en) 1998-04-30 1999-11-09 Mitsubishi Electric Corp Polyurethane foam, its production, insulating material and insulating box
US6103152A (en) * 1998-07-31 2000-08-15 3M Innovative Properties Co. Articles that include a polymer foam and method for preparing same
KR100611686B1 (en) * 1999-01-26 2006-08-14 헌트스만 인터내셔날,엘엘씨 Foamed Thermoplastic Polyurethanes

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HK1044346A1 (en) 2002-10-18
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KR100611686B1 (en) 2006-08-14
PL350180A1 (en) 2002-11-18
EG22463A (en) 2003-02-26
HK1044346B (en) 2005-05-06
CZ20012684A3 (en) 2001-11-14
DE60000314D1 (en) 2002-09-12
US8067476B2 (en) 2011-11-29
JP3357871B2 (en) 2002-12-16
ES2269548T3 (en) 2007-04-01
AR059855A2 (en) 2008-05-07
WO2000044821A1 (en) 2000-08-03
EP1165674A1 (en) 2002-01-02
EP1233037A2 (en) 2002-08-21
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CO5200795A1 (en) 2002-09-27
AU768105B2 (en) 2003-12-04
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US7202284B1 (en) 2007-04-10
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RU2229486C2 (en) 2004-05-27
DE60031290T2 (en) 2007-06-06
PL201662B1 (en) 2009-04-30
UA72494C2 (en) 2005-03-15
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