CA2693306A1 - Improved thin-film coatings, electro-optic elements and assemblies incorporating these elements - Google Patents
Improved thin-film coatings, electro-optic elements and assemblies incorporating these elements Download PDFInfo
- Publication number
- CA2693306A1 CA2693306A1 CA2693306A CA2693306A CA2693306A1 CA 2693306 A1 CA2693306 A1 CA 2693306A1 CA 2693306 A CA2693306 A CA 2693306A CA 2693306 A CA2693306 A CA 2693306A CA 2693306 A1 CA2693306 A1 CA 2693306A1
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- layer
- optical element
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- substrate
- present
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Links
- 230000000712 assembly Effects 0.000 title abstract 2
- 238000000429 assembly Methods 0.000 title abstract 2
- 238000009501 film coating Methods 0.000 title abstract 2
- 239000010409 thin film Substances 0.000 title abstract 2
- 230000003287 optical effect Effects 0.000 claims 12
- 238000000034 method Methods 0.000 claims 10
- 239000000758 substrate Substances 0.000 claims 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 4
- -1 AZO Chemical compound 0.000 claims 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 229910052787 antimony Inorganic materials 0.000 claims 2
- 229910052785 arsenic Inorganic materials 0.000 claims 2
- 229910052797 bismuth Inorganic materials 0.000 claims 2
- 229910052793 cadmium Inorganic materials 0.000 claims 2
- 150000004770 chalcogenides Chemical group 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 229910052732 germanium Inorganic materials 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- 229910052738 indium Inorganic materials 0.000 claims 2
- 229910052741 iridium Inorganic materials 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052745 lead Inorganic materials 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 229910052755 nonmetal Inorganic materials 0.000 claims 2
- 230000006911 nucleation Effects 0.000 claims 2
- 238000010899 nucleation Methods 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 claims 2
- 229910052711 selenium Inorganic materials 0.000 claims 2
- 239000011669 selenium Substances 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 229910052716 thallium Inorganic materials 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 239000011787 zinc oxide Substances 0.000 claims 2
- 238000005468 ion implantation Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000005240 physical vapour deposition Methods 0.000 claims 1
- 238000009832 plasma treatment Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000002834 transmittance Methods 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/157—Structural association of cells with optical devices, e.g. reflectors or illuminating devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/02—Rear-view mirror arrangements
- B60R1/04—Rear-view mirror arrangements mounted inside vehicle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/02—Rear-view mirror arrangements
- B60R1/06—Rear-view mirror arrangements mounted on vehicle exterior
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/02—Rear-view mirror arrangements
- B60R1/08—Rear-view mirror arrangements involving special optical features, e.g. avoiding blind spots, e.g. convex mirrors; Side-by-side associations of rear-view and other mirrors
- B60R1/083—Anti-glare mirrors, e.g. "day-night" mirrors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/02—Rear-view mirror arrangements
- B60R1/08—Rear-view mirror arrangements involving special optical features, e.g. avoiding blind spots, e.g. convex mirrors; Side-by-side associations of rear-view and other mirrors
- B60R1/083—Anti-glare mirrors, e.g. "day-night" mirrors
- B60R1/085—Anti-glare mirrors, e.g. "day-night" mirrors using a combination of interchangeable reflecting surfaces, e.g. reversible mirrors
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3647—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer in combination with other metals, silver being more than 50%
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/3663—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties specially adapted for use as mirrors
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/67—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light
- E06B3/6715—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light
- E06B3/6722—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light with adjustable passage of light
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/155—Electrodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/12—Mirror assemblies combined with other articles, e.g. clocks
- B60R2001/1215—Mirror assemblies combined with other articles, e.g. clocks with information displays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/12—Mirror assemblies combined with other articles, e.g. clocks
- B60R2001/1223—Mirror assemblies combined with other articles, e.g. clocks with sensors or transducers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/12—Mirror assemblies combined with other articles, e.g. clocks
- B60R2001/1253—Mirror assemblies combined with other articles, e.g. clocks with cameras, video cameras or video screens
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R2300/00—Details of viewing arrangements using cameras and displays, specially adapted for use in a vehicle
- B60R2300/10—Details of viewing arrangements using cameras and displays, specially adapted for use in a vehicle characterised by the type of camera system used
- B60R2300/108—Details of viewing arrangements using cameras and displays, specially adapted for use in a vehicle characterised by the type of camera system used using 'non-standard' camera systems, e.g. camera sensor used for additional purposes i.a. rain sensor, camera sensor split in multiple image areas
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
- G02F1/13439—Electrodes characterised by their electrical, optical, physical properties; materials therefor; method of making
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2201/00—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
- G02F2201/34—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00 reflector
Abstract
Electro-optic elements are becoming commonplace in a number of vehicular and architectural applications.
Various electro-op-tic element configurations provide variable transmittance and or variable reflectance for windows and mirrors. The present invention relates to var-ious thin-film coatings, electro-optic elements and assemblies incorporat-ing these elements.
Various electro-op-tic element configurations provide variable transmittance and or variable reflectance for windows and mirrors. The present invention relates to var-ious thin-film coatings, electro-optic elements and assemblies incorporat-ing these elements.
Claims (20)
1. An optical element, comprising:
a first substrate comprising a first and second surface, the first substrate comprising at least one first layer of material on at least one of the first and second surfaces, wherein the at least one first layer comprises an outer surface that has been modified such that the outer surface comprises an atom type not present in a bulk of the at least one first layer and an atom type present in the bulk of the at least one first layer, and that advances at least a select one of adhesion, stability, nucleation and conductivity of a second layer that is adjacent to the outer surface of the at least one first layer.
a first substrate comprising a first and second surface, the first substrate comprising at least one first layer of material on at least one of the first and second surfaces, wherein the at least one first layer comprises an outer surface that has been modified such that the outer surface comprises an atom type not present in a bulk of the at least one first layer and an atom type present in the bulk of the at least one first layer, and that advances at least a select one of adhesion, stability, nucleation and conductivity of a second layer that is adjacent to the outer surface of the at least one first layer.
2. The optical element of claim 1, wherein the optical element comprises an electro-optic element.
3. The optical element of claim 2, further comprising:
a second substrate comprising a third and fourth surface, wherein the first and second substrate cooperate to form a cavity therebetween; and an electrochromic medium located within the cavity.
a second substrate comprising a third and fourth surface, wherein the first and second substrate cooperate to form a cavity therebetween; and an electrochromic medium located within the cavity.
4. The optical element of claim 1, wherein the outer surface of the at least one first layer is modified with a member of the chalcogenide group of elements.
5. The optical element of claim 4, wherein the outer surface of the at least one first layer is modified with at least one of sulfur and selenium.
6. The optical element of claim 1, wherein a majority of the atom type not present in the bulk of the at least one first layer is located at a depth of between 1 and 10 atomic layers of the outer surface.
7. The optical element of claim 6, wherein a majority of the atom type not present in the bulk of the at least one first layer is located at a depth of between 1 and 5 atomic layers of the outer surface.
8. The optical element of claim 7, wherein a majority of the atom type not present in the bulk of the at least one first layer is located at a depth of between 1 and 2 atomic layers of the outer surface.
9. The optical element of claim 1, wherein the at least one first layer comprises at least one of a non-metal, a metal, and a metal oxide.
10. The optical element of claim 9, wherein the at least one first layer comprises at least a select one of ITO, IZO, zinc oxide, AZO, TiO2, w, Mo, Fe, Tu, Ox, Co, Rh, Ir, Cu, Ag, Au, Zn, Cd, Hg, Ga, In, Tl, Ge, Sn, Pb, As, Sb, and Bi.
11. A method for manufacturing an optical element, comprising:
providing a first substrate comprising a first and second surface, the first substrate comprising at least one first layer of material on at least one of the first and second surfaces; and modifying an outer surface of the at least one layer such that the outer surface includes an atom type not present in a bulk of the at least one first layer and an atom type present in the bulk of the at least one first layer, and that advances at least a select one of a of adhesion, stability, nucleation and conductivity of a second layer that is adjacent to the surface of the at least one first layer.
providing a first substrate comprising a first and second surface, the first substrate comprising at least one first layer of material on at least one of the first and second surfaces; and modifying an outer surface of the at least one layer such that the outer surface includes an atom type not present in a bulk of the at least one first layer and an atom type present in the bulk of the at least one first layer, and that advances at least a select one of a of adhesion, stability, nucleation and conductivity of a second layer that is adjacent to the surface of the at least one first layer.
12. The method of claim 11, wherein the modifying step comprises at least one of ion implantation, plasma treatment, chemical treatment, and physical vapor deposition.
13. The method of claim 11, further comprising:
providing a second substrate comprising a third and fourth surface, wherein the first and second substrate cooperate to form a cavity therebetween; and providing an electrochromic medium located within the cavity.
providing a second substrate comprising a third and fourth surface, wherein the first and second substrate cooperate to form a cavity therebetween; and providing an electrochromic medium located within the cavity.
14. The method of claim 11, wherein the modifying step includes modifying the outer surface of the at least one layer with a member of the chalcogenide group of elements.
15. The method of claim 14, wherein the modifying step includes modifying the outer surface of the at least one first layer with at least one of sulfur and selenium.
16. The method of claim 11, wherein the modifying step results in a majority of the atom type not present in the bulk of the at least one layer being located at a depth of between 1 and 10 atomic layers of the outer surface.
17. The method of claim 16, wherein the modifying step results in a majority of the atom type not present in the bulk of the at least one layer being located at a depth of between 1 and 5 atomic layers of the outer surface.
18. The method of claim 17, wherein the modifying step results in a majority of the atom type not present in the bulk of the at least one layer being located at a depth of between 1 and 2 atomic layers of the outer surface.
19. The method of claim 11, wherein the step of providing the first substrate comprises providing the at least one first layer as comprising at least one of a non-metal, a metal, and a metal oxide.
20. The method of claim 19, wherein the step of providing the first substrate comprises providing the at least one first layer as comprising at least a select one of ITO, IZO, zinc oxide, AZO, TiO2, w, Mo, Fe, Tu, Ox, Co, Rh, Ir, Cu, Ag, Au, Zn, Cd, Hg, Ga, In, Tl, Ge, Sn, Pb, As, Sb, and Bi.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/833,701 | 2007-08-03 | ||
US11/833,701 US7746534B2 (en) | 2006-12-07 | 2007-08-03 | Thin-film coatings, electro-optic elements and assemblies incorporating these elements |
PCT/US2008/071875 WO2009020846A1 (en) | 2007-08-03 | 2008-08-01 | Improved thin-film coatings, electro-optic elements and assemblies incorporating these elements |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2693306A1 true CA2693306A1 (en) | 2009-02-12 |
CA2693306C CA2693306C (en) | 2011-04-19 |
Family
ID=40341658
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2693306A Active CA2693306C (en) | 2007-08-03 | 2008-08-01 | Improved thin-film coatings, electro-optic elements and assemblies incorporating these elements |
Country Status (7)
Country | Link |
---|---|
US (1) | US7746534B2 (en) |
EP (1) | EP2183642B1 (en) |
JP (1) | JP4751961B2 (en) |
KR (1) | KR100997280B1 (en) |
CN (1) | CN101784951B (en) |
CA (1) | CA2693306C (en) |
WO (1) | WO2009020846A1 (en) |
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US5910854A (en) | 1993-02-26 | 1999-06-08 | Donnelly Corporation | Electrochromic polymeric solid films, manufacturing electrochromic devices using such solid films, and processes for making such solid films and devices |
US5668663A (en) | 1994-05-05 | 1997-09-16 | Donnelly Corporation | Electrochromic mirrors and devices |
US6891563B2 (en) * | 1996-05-22 | 2005-05-10 | Donnelly Corporation | Vehicular vision system |
US6326613B1 (en) | 1998-01-07 | 2001-12-04 | Donnelly Corporation | Vehicle interior mirror assembly adapted for containing a rain sensor |
US6172613B1 (en) | 1998-02-18 | 2001-01-09 | Donnelly Corporation | Rearview mirror assembly incorporating vehicle information display |
US6124886A (en) | 1997-08-25 | 2000-09-26 | Donnelly Corporation | Modular rearview mirror assembly |
US8294975B2 (en) | 1997-08-25 | 2012-10-23 | Donnelly Corporation | Automotive rearview mirror assembly |
US8288711B2 (en) | 1998-01-07 | 2012-10-16 | Donnelly Corporation | Interior rearview mirror system with forwardly-viewing camera and a control |
US6445287B1 (en) | 2000-02-28 | 2002-09-03 | Donnelly Corporation | Tire inflation assistance monitoring system |
US6477464B2 (en) | 2000-03-09 | 2002-11-05 | Donnelly Corporation | Complete mirror-based global-positioning system (GPS) navigation solution |
US6329925B1 (en) | 1999-11-24 | 2001-12-11 | Donnelly Corporation | Rearview mirror assembly with added feature modular display |
US6693517B2 (en) | 2000-04-21 | 2004-02-17 | Donnelly Corporation | Vehicle mirror assembly communicating wirelessly with vehicle accessories and occupants |
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WO2001064481A2 (en) | 2000-03-02 | 2001-09-07 | Donnelly Corporation | Video mirror systems incorporating an accessory module |
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2007
- 2007-08-03 US US11/833,701 patent/US7746534B2/en active Active
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2008
- 2008-08-01 JP JP2010520214A patent/JP4751961B2/en active Active
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- 2008-08-01 EP EP08827166.3A patent/EP2183642B1/en active Active
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JP4751961B2 (en) | 2011-08-17 |
KR20100044196A (en) | 2010-04-29 |
EP2183642B1 (en) | 2019-02-20 |
US20080310005A1 (en) | 2008-12-18 |
CA2693306C (en) | 2011-04-19 |
KR100997280B1 (en) | 2010-11-29 |
CN101784951A (en) | 2010-07-21 |
EP2183642A4 (en) | 2011-06-15 |
WO2009020846A1 (en) | 2009-02-12 |
EP2183642A1 (en) | 2010-05-12 |
JP2010536068A (en) | 2010-11-25 |
CN101784951B (en) | 2011-07-27 |
US7746534B2 (en) | 2010-06-29 |
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