CA2809479A1 - Roofing composite including dessicant and method of thermal energy management of a roof by reversible sorption and desorption of moisture - Google Patents

Abstract

A roof system is secured to a roof deck on a building. The roof system has a thermal energy absorbing product including a desiccant located between the roof deck and a roof barrier. The desiccant reversibly absorbs moisture, and in response thereto, heat is released and absorbed by the desiccant to effect a thermal management of the roof system.

Description

Attorney Docket No R-9441 ROOFING COMPOSITE INCLUDING DESSICANT AND METHOD OF
THERMAL ENERGY MANAGEMENT OF A ROOF BY REVERSIBLE
SORPTION AND DESORPTION OF MOISTURE
BACKGROUND OF THE INVENTION
Field of the Disclosure 100011 The present invention relates in general to roofing and, in particular, to a system, method and apparatus for thermal energy management in a roof by reversible sorption and desorption of moisture.
Description of the Related Art

[0002] Typical residential roofs in the North America have bitumen-based roofing materials that provide satisfactory water shedding, long term durability and have aesthetic appeal. Most asphaltic roofing materials are colored in traditional dark earth tones.
These colors absorb significant amounts of solar heat during hot summer times, which penetrates through the roof deck, attic and ceiling into the house. The heat penetration increases the need for cooling energy for the indoor comfort of residence occupants.
100031 On the other hand, these types of roofing products usually have good thermal emittance and low thermal mass. These properties allow them to quickly re-radiate and lose solar heat during the night. This results in the so-called "super cooling" effect that may increase the heating energy need to maintain indoor temperatures during the night.
This issue is particularly problematic for cold to moderate climate regions, and for seasons where the day and night temperature differences are significant, such as in the spring or fall seasons.
[0004] Therefore, it would be advantageous to have a roofing system that can store or manage the solar heat during the day, and then release that heat into the house during the night to improve the energy efficiency of the house. It would be a further advantage to Attorney Docket No R-9441 have such a system that is compatible with current asphaltic shingle aesthetics, and can be readily applied with existing roofing techniques and construction practices.
[0005] Some asphaltic shingles have improved solar reflectance that reduces the absorption of solar heat. Although such products lower cooling energy costs, particularly in warmer climates, they are not designed for managing solar heat during the night or for significant seasonal changes. In colder climates, these products can have heating penalties due to the loss of solar heat. This is also true when radiant barriers are used to reduce solar heat flux into the attic. Radiant barriers do not capture or manage solar heat.
[0006] Other conventional solutions include ventilated decks and ventilation systems that reduce heat flux into the attic via air flows to expel heat. Again, these systems do not store or manage solar heat for the later cooler times of day. Therefore, it would be advantageous to have a roofing material/system that can store or manage the solar heat during the day time and then release back into the house during the night time to optimize whole building energy efficiency. It is further advantageous to have such a material/system that will not affect current asphaltic shingle aesthetic values or can be applied easily with current known roofing technique or construction practices.
SUMMARY
100071 Embodiments of a system, method and apparatus for thermal energy management of a roof by reversible sorption and desorption of moisture are disclosed. For example, a roof system may comprise a roof deck on a building, and a roof barrier secured to the roof deck. The roof system has a thermal energy absorbing product including a desiccant located between the roof deck and the roof barrier. The desiccant reversibly adsorbs and releases moisture, and in response thereto heat is reversibly released and absorbed by the desiccant to effect a thermal management of the roof system.
[0008] The foregoing and other objects and advantages of these embodiments will be apparent to those of ordinary skill in the art in view of the following detailed description, taken in conjunction with the appended claims and the accompanying drawings.

Attorney Docket No R-944I
BRIEF DESCRIPTION OF THE DRAWINGS
[0009] So that the manner in which the features and advantages of the embodiments are attained and can be understood in more detail, a more particular description may be had by reference to the embodiments thereof that are illustrated in the appended drawings.
However, the drawings illustrate only some embodiments and therefore are not to be considered limiting in scope as there may be other equally effective embodiments.
[0010] FIGS. 1 - 3 are isometric views of embodiments of a roof product.
[0011] FIG. 4 is a sectional view of an embodiment of a roof product installed in a roof of a building.
[0012] FIG. 5 is a partially sectioned, isometric view of another embodiment showing layers of a roof product.
[0013] FIG. 6 is an enlarged top view of an embodiment of a roof product.
[0014] FIG. 7 is a partially sectioned, isometric view of an embodiment showing layers of a roof product.
[0015] FIGS. 8A and 8B are schematic isometric views of buildings having embodiments of roof products installed thereon.
[0016] FIG. 9 is a schematic side view of an embodiment of a method of manufacturing a roof product.
[0017] FIGS. 10A-10D are various views of test huts.
[0018] FIG. 11 is an isometric view of the framing for the test huts of FIGS.
10A-10D.
[0019] FIGS. 12A and 12B are schematic sectional side views of control and experimental roof decks, respectively.

3 Attorney Docket No R-9441 [0020] FIGS. 13-15 are plots of performance data for the control and experimental roof decks of FIGS. 12A and 12B.
[0021] The use of the same reference symbols in different drawings indicates similar or identical items.
DETAILED DESCRIPTION
[0022] Embodiments of a system, method and apparatus for thermal energy management of a roof by reversible sorption and desorption of moisture are disclosed. For example, a roof product 11 or thermal energy absorbing product (TEAP) may comprise a sheet or a panel (which may be rigid; see, e.g., FIGS. 1 and 2) or a flexible roll of material (see, e.g., FIG. 3) having a plurality of layers and/or materials.
[0023] In some embodiments, the roof product 11 comprises only a desiccant 13 (FIG.
1), such as a desiccant-filled sheet, for use as a heat absorbing layer and as an underlayment. Examples of desiccants are described in U.S. Pat. App. Pub.
2010/0107550, which is incorporated herein by reference in its entirety. Some embodiments of the desiccant may comprise clay, nano-clay, montmorillonite clay, synthetic zeolite, surface modified carbon, carbon molecular sieve, activated carbon, calcium oxide, calcium sulfate, salt, inorganic salt, silica gel, activated alumina, polymeric desiccant material (e.g., sodium polyacrylate), cellulose material, metal silicate, or any combination thereof.
100241 The desiccant materials may comprise moisture adsorbents (i.e., a surface phenomenon), not necessarily those desiccants that dissolve into liquid (i.e., via chemical reaction) when absorbing enough moisture. Advantageously, heat is absorbed by the moisture inside the desiccant. When heat is absorbed by the moisture in the desiccant (such as during a weather heating cycle), the moisture changes from a liquid water phase to a water vapor phase, and the moisture evaporates from the desiccant. In addition, when water vapor in the air condenses onto the surfaces of the porous structures of the desiccant (such as during a weather cooling cycle), heat is released from the desiccant to

4 Attorney Docket No R-9441 the building on which the roof product is installed. This process repeats as the roof product experiences weather heating and cooling cycles.
[0025] In the summer during daylight, some embodiments of the desiccant absorb heat (e.g., heat flow from outside) and release moisture to reduce the flow of heat into a building. In winter during daylight, some embodiments of the desiccant absorb heat (e.g., heat from inside) and release moisture to reduce the flow of heat to outside of a building.
In summer and winter at night, the desiccant may absorb moisture and release heat to both outside and inside a building. During winter, there is less moisture in the air than during summer, so there may be less energy savings than during the summer.
[0026] The desiccant 13 may be mounted between a roof deck 35 and roof barrier (e.g., shingle). In other embodiments (FIGS. 2 and 3), a vent layer 15 having channels 17 that may be used to transfer excess moisture through an entire length L of the roof product 11. A fire retardant 19 may be included to suppress fire through the vent layer 15. The desiccant 13, vent layer 15 and fire retardant 19 may form a unitary structure as shown.
[0027] In other embodiments, the roof product 11 further comprises outer skin layers comprising an uppermost layer 21 and a lowermost layer 23, between which may be located the desiccant 13, the vent layer 15 and the fire retardant 19. As shown in FIGS. 2 and 3, the fire retardant 19 may be located between the desiccant 13 and the vent layer 15. The vent layer 15 also may be located between the desiccant 13 and the fire retardant 19.
[0028] Still other embodiments of the roof product 11 may include an upper radiant barrier 31 (FIG. 4) and a lower moisture barrier 33, such that the roof product 11 comprises the only material located between the roof deck 35 and the roof barrier 37.
The uppermost layer 31 may be UV resistant. Versions of the roof product 11 may have a thickness T of about 0.75 to 2.5 inches. For example, the desiccant 13 may have a thickness of about 0.25 inches to about 1 inch, the vent layer 15 may have a thickness of about 0.25 inches to about 1 inch, and the fire retardant 19 may have a thickness of about 0.25 inches to about 0.5 inches.

Attorney Docket No R-9441 [0029] In still other embodiments, the intumescent may expand in the presence of fire to about 20 times its original volume. Thus, fire retardant thickness may comprise a ratio of about 1/20th of the vent layer thickness. For example, for a vent layer thickness of about 0.25 inches, the fire retardant thickness is at least about 0.01 inches to effectively block air flow through the vent layer 15. In addition, the roof product 11 may be configured with an overall weight per unit area in a range of about 1 pound per square foot (lbs/ft2), to about 10 lbs/ft2, or less than about 10 lbs/ft2, or less than about 5 lbs/ft2, or less than about 3 lbs/ft2.
[0030] In some embodiments, the desiccant 13 may have a heat of absorption of greater than about 30 kJ/mol-H20 to store solar heat during a heating cycle, and has a thermal emittance of greater than about 0.70 that re-radiates stored heat during a cooling cycle.
For example, the heat of absorption may be greater than about 30 kJ/mol-H20, and a heat absorbing range thereof may be about 10 C to about 50 C, or about 20 C to about 40 C.
In other embodiments, the desiccant may have a heat of absorption of greater than about 20 kJ/mol-H20, greater than about 25 kJ/mol-H20, greater than about 35 kJ/mol-H20, or greater than about 40 kJ/mol-H20 to store solar heat during a heating cycle.
In still other versions, the desiccant may have a heat of absorption of less than about 70 kJ/mol-H20, less than about 65 kJ/mol-H20, or less than about 50 kJ/mol-H20 to store solar heat during a heating cycle. Other versions of the roof product include two or more desiccant materials having different heat capacities and/or heat absorbing ranges.
[0031] The desiccant 13 may comprise a powder or be in a granulated or encapsulated form with sizes that are less than about 0.5 mm in diameter. As shown in FIG.

5, the desiccant 13 may comprise media 41 located between skin layers 43, 45, with or without an adhesive 47. In the example of FIGS. 5 and 6, the media 41 may be located in a structure 49 having cavities (e.g., an array of honeycomb cavities with vertical axes).
FIG. 7 depicts an embodiment of the desiccant 13 having outer skin layers 50 that contain moisture storage media 41 in a binder matrix. Such media may be formed, for example, by extrusion, gel casting, lamination, solvent casting or extrusion coating.

6 Attorney Docket No R-9441 100321 Referring again to FIGS. 2 and 3, the channels 17 in the vent layer 15 may have openings along the edges thereof that extend completely through the roof product 11 along length L. Each opening may have an effective area of about 0.01 in2 to about 1 in2, or about 0.05 in2 to about 0.5 in2 in other embodiments.
[0033] As shown in FIGS. 8A and 8B, a plurality of the roof products 11 is assembled in an abutting configuration on the roof of a building 61. FIG. 8A depicts the roof products 11 in sheet or panel form, while FIG. 8B depicts the roof products 11 in roll form. The vent layer 15 of roof product 11 is adapted to vent excess heat from an eave 63 of the roof up to a ridge 65 of the roof and out to atmosphere. The vent layers 15 inside roof products 11 may be positioned to vent excess heat via natural air flow from the lower eave 63 of the roof up to the ridge 65 of the roof. Thus, the channels 17 of the vent layers 15 may form substantially contiguous, uninterrupted air flow paths between abutting products having inlets substantially only adjacent the eave 63 of the roof and outlets substantially only adjacent the ridge 65 of the roof The openings of channels 17 are large enough to eliminate the need for precise alignment of the inlets and outlets of adjacent, abutting products 11 such that a path for air flow is substantially unimpeded.
[0034] The roof product 11 may comprise rolls of material (FIG. 8B) that extend continuously from adjacent the eave 63 to adjacent the ridge 65 to form continuous, uninterrupted air flow paths having inlets only adjacent the eave and outlets only adjacent the ridge, such that there is no air flow communication in the channels 17 between laterally adjacent rolls of the roof product 11.
[0035] Alternatively, some embodiments may include the capacity of lateral flow of air between channels with lateral openings. A plurality of roofing products 11 may be laid up on a roof deck with adjacent roof products 11 being arranged side-by-side, in horizontal and vertical courses (horizontal only in FIG. 8B) from a lower end 63 of the roof deck to an upper end 65 thereof Their vent channels 17 may communicate laterally (side to side) with each other through one or more lateral openings, for providing airflow through successive horizontal courses of the roofing products 11 within in the same vertical course.

7 Attorney Docket No R-9441 100361 As depicted in FIGS. 2 and 4, the roof product 11 is directly fastenable to the roof deck 35 of a building, and is covered by outer roof barriers 37 (e.g., shingles, tiles, membranes, etc.). Roof barriers 37 may be located on top of the roof products without substantially affecting an overall thickness and functionality of the roof products 11. In the embodiment of FIG. 6, the roof product may be provided with a plurality of cells 53 that are adapted to be penetrated by roofing fasteners 55, such as nails. The cells 53 may be void of a material 41 used to form the desiccant 13.
[0037] In some embodiments, skin layers may be added to enhance the walkable surface for roofers, particularly in wet conditions. The skin layers may be configured for walkability and may include elements such as synthetic underlayment products.
In addition, they may provide some UV resistance for short term exposure (e.g., one year of UV stability) if left unprotected on the roof Furthermore, the skin layer may be combined with a radiant barrier, such as aluminum foils, metalized films, mirrorized surfaces, etc., to reflect solar heat.
100381 The desiccant may comprise a desirable heat of absorption that can store solar heat over an extended period of time. It may have a desirable thermal emittance that re-radiates stored heat during night time or during extended cold periods to leverage the stored solar heat for greater indoor comfort. In some embodiments, the desiccant absorbs heat in a given range of temperatures and releases the stored heat upon cooling in a selected range of temperatures. Moreover, the roof product remains flexible in lower temperatures down to about 0 C, and remains structurally sound for a roof walkable surface in higher temperatures where a roof surface temperature may exceed 70 C.
[0039] The desiccant may perform without leakage even after being penetrated by roofing nails. For example, when a nail penetrates the structure, it goes through only a small number of capsules, leaving the vast majority of them intact over the roof area.
[0040] For embodiments with venting channels, the channels may provide sufficient openings for air flow, but not for insect infiltration or infestation. For example, a screen structure may be employed to inhibit such. The openings also are not so small that they are susceptible to clogging from airborne dust or contamination. Suitable materials for

8 Attorney Docket No R-9441 this layer may comprise thermoplastics, thermoplastic elastomers, aluminum, thermoset resins, cellulose composite, wood composites, rubbers, or their mixtures. The layer may contain fillers or functional fillers, fire retardants, or intumescent agents to reduce or block the air passages in the event of a fire. The layer may further contain biocides or fungicides to prevent or inhibit microbial growth. The layer may be constructed, for example, by industrial processes such as extrusion, injection molding, compression molding, pultrusion, lamination, or thermal forming.
[0041] Embodiments of the fire retardant reduce the risk of a fire spreading and penetrating into the underlying roof deck. This material may reduce the size of or block the air passages of the venting layer during a fire. It also may provide a charring or fire suffocating effect to prevent further spreading of fire. For example, it may provide Class A fire protection for the underlying roof deck. Suitable fire retarding media may comprise expandable clay, expandable carbon black, intumescent silicates, hydrated metal silicates, bromated compounds, halocarbons, aluminum hydroxide, magnesium hydroxide, hydromagnesite, antimony trioxide, various hydrates, red phosphorus, boron compounds, phosphonium salts, or their mixtures.
[0042] In some embodiments, the fire retardant may be combined with the desiccant. For example, such a combination may comprise forming the fire retardant as part of the skin layer for the desiccant, or by intermingling the flame retarding media with the moisture storage media within the layer. Other versions may include a fire retardant applied as a separate accessory to the roofing product. For example, a strip of "fire stop"
tape may be applied near the bottom or top of the vent channels to close the channels in the event of fire.
[0043] In other embodiments, the fire retardant may be combined with the air venting layer by incorporating the fire retardant as a skin layer, or by incorporating the fire retardant media in the materials for construction the venting layer. In addition, the fire retardant media may be dispersed or incorporated into the materials for forming the roof deck composite. Other variations to the construction of the roof deck composite for managing solar heat will become apparent to those who are skilled in the art.

9 Attorney Docket No.: R-944!
100441 The roof composite for absorbing solar heat may comprise a carrier or carrier layer and a thermal heat absorbing layer comprised of desiccant materials.
Additional multi-layer configurations where other functional layers, such as a skin layers with proper moisture permeability, a layer providing air ventilation to reduce heat flux, and/or a structural layer for improving strength, or their combinations, also may be included in the composite. The roofing composite can be a sheet form, a roll form, a three dimensional structural shape. or as part of existing roofing shingle or tile configuration. The roof composite may be applied as stand-alone layer on roof deck prior to shingle installation, or can be as an underlayment layer, or as part of roofing article during manufacturing of the roofing article.
100451 The heat absorbing layer may comprise one or more materials that will absorb moisture wherein they can act as a heat sink at elevated temperatures.
particularly during daytime to absorb solar heat: and become a heat source during the nighttime where the temperatures dropped and the moisture released. Although the latent heat of the adsorption/ desorption of water is well documented. the embodiments disclosed herein work well as a heat management material as the moisture transport during daytime and nighttime.
100461 A carrier layer may provide the integrity and adequate strength such that the resultant roofing composite can be transported. handling by installer, and applied on a job site. Also, it may provide adequate weathering or durability for roof environments, unless it will be protected by additional UV protecting layer.
100471 In one aspect the carrier layer may contain the desiccant in a zone adjacent a venting channel so that air transport adjacent the desiccant can facilitate reversible sorption and desorption of moisture to manage heat transfer. The desiccant can be disposed within a relatively open structure with a high surface area to allow easy moisture transfer. A film or sheet with desired permeability may be used to contain the desiccant within the open structure. In one embodiment the film or sheet is a polymeric film having a moisture permeability that varies with temperature and/or humidity. such as the MemBrain" vapor retarder films available from CertainTeed.

Attorney Docket No.: R-9441 100481 Alternatively, a woven or nonwoven web or mat of polymer or glass having a porous and open structure to let moisture transfer in and out of the desiccant is provided on a tace of the desiccant zone adjacent to the venting channel. The porosity or openness of the structure is fine enough in texture so that the desiccant is contained.
For example, a particulate desiccant having a high surface area can be contained within cells of a honeycomb structured panel by means of a porous and/or permeable sheet or film.
100491 Alternatively, the desiccant may be contained within a porous open structured web sandwiched between containment sheets. at least one of which is porous and/or permeable and oriented adjacent a venting channel in a roofing product construction.
A film or paper layer of material may have a physical porosity further controlled or modified by microperforating or needle punching.
100501 FIG. 9 depicts an embodiment of a process for making the roof composite. The method may include preparing a carrier layer 91 in a web process (with or without an optional backing film 90), depositing a desiccant or TEAP material 93 on the carrier layer 91, performing an optional packing/calendaring process 95, fixing the desiccant materials to the carrier layer (e.g., such as with an optional adhesives 97a.
97b or optional top film 99), followed by cutting 101 into suitable dimensions or packaging 103 into suitable form for roofing applications. The process is schematically shown in FIG. 4 and various variations will become apparent to those who are skilled in the art.
If the carrier layer is part of a multi- layer composite or part of the roofing article, additional steps may follow after the fixing of the desiccant powders in the carrier layer, such as laminating onto another layer or adhering to the roofing article.
[0051] In still other embodiments, a roof system may comprise a roof deck on a building;
and a roof product secured to the roof deck; and an underlayment or TEAP
comprising a desiccant located between the roof deck and the roof product, whereby the desiccant reversibly absorbs and releases moisture, and thereby heat is reversibly released and absorbed by the desiccant to effect a thermal management of the roof system.

Attorney Docket No R-9441 [0052] The desiccant may have a heat of absorption that stores solar heat during a heating cycle, and has a thermal emittance that re-radiates stored heat during a cooling cycle.
The desiccant may comprise a powder, sheet form, or an encapsulated form with sizes that is in a range of about U.S. mesh #10 to about U.S. mesh #325, or about U.S. mesh #60 to about U.S. mesh #325, or about U.S. mesh #100 to about U.S. mesh #325.
[0053] The TEAP may comprise a rigid sheet, a rigid panel or a flexible roll.
The TEAP
may comprise a non-woven mat, glass mat, woven mat, scrim, felt, Kraft paper, honeycomb board. channeled panel, industrial fabric, recycled mat, porous ceramic board, cementitious board, \ ood composite, plastic wood, inorganic bonded composite, gypsum board. or any combination thereof The TEAP may have an effective heat of absorption to regulate at least 5% of solar energy incident thereon, at least 10% of solar energy incident thereon, or greater than 20% of solar energy incident thereon, or greater than 30% of solar energy incident thereon.
[0054] The roof product may be attached through the TEAP to the roof deck with fasteners or adhesives. The TEAP may be directly nailable for roofing shingles on top thereof without affecting an overall thickness and functionality of the TEAP.
The TEAP
may be flexible in lower temperatures about 0 C, and remains structurally sound for a roof walkable surface in higher temperatures where a roof surface temperature exceeds about 70 C.
[0055] In addition, the TEAP may have a plurality of cells configured to be penetrated by roofing fasteners, and the cells are void of the desiccant. The TEAP may include an upper radiant barrier and a lower moisture barrier, such that the TEAP
comprises the only material located between a roof deck and a roof product. The TEAP may have a thickness of about 0.75 inches to about 2.5 inches, or about 0.25 inches to about 1 inch.
The TEAP may have a weight in a range of about 1 pound per square foot to about 10 pounds per square foot.
[0056] The roof system may further comprise an additive, a lire retardant, an anti-microbial addition, a UV stabilizer, a UV protection layer. or any combination thereof.
The desiccant and fire retardant may form a unitary structure. The fire retardant and the Attorney Docket No R-9441 TEAP each may comprise media, and the media are mixed and combined in a single layer. The single layer may comprise less than about 25% of the fire retardant, less than about 10% of the fire retardant, or less than about 5% of the fire retardant.
[0057] The roof system may further comprise a skin layer (e.g., polymeric, porous, etc.) adjacent the desiccant. The skin layer may have permeability that will not vary with temperature or humidity, since the moisture is capable of coming in or going out at various temperatures for absorbing or desorbing to occur with the desiccant.
The moisture permeability of the skin layer may be greater than 2 perm, greater than 5 perm, or greater than 10 perm. The skin layer may comprise an uppermost layer and a lowermost layer, between which are located the desiccant.
[0058] The desiccant may have a moisture permeability that varies with at least one of temperature and relative humidity, and may include membrane properties for permeability. The desiccant may be provided with selected water absorption/desorption properties.
[0059] The roof system may further comprise a ventilation channel adjacent the desiccant, whereby air having a humidity flowing through the ventilation channel transports moisture to and from the desiccant, and the heat thus absorbed and released by the desiccant effects thermal management of the roof system.
100601 An embodiment of an underlayment may be configured to be located on a roof between a roof product and a roof deck. The underlayment may comprise a desiccant;
and a ventilation channel adjacent the desiccant, whereby air having a humidity flowing through the ventilation channel is configured to reversibly transport moisture to and from the desiccant, such that heat is reversibly released and absorbed, respectively, by the desiccant to effect a thermal management of the roof.
[0061] The ventilation channel may be adapted to ventilate an entire length of the roof The desiccant, ventilation channel and a fire retardant may form a unitary structure. The ventilation channel may comprise a carrier and structural layer for the desiccant. The underlayment may further comprise a skin layer between the desiccant and ventilation Attorney Docket No.: R-9441 channel, the skin layer having a porosity controlled by microperforation or needle punch.
The porosity may comprise micropores that are configured to permit water vapor to pass therethrough but the micropores do not transmit liquid water.
100621 The fire retardant may comprise materials used to form a structure for the ventilation channel, such that the fire retardant and the ventilation channel are combined in a single layer. The fire retardant may comprise an accessory that is applied to the underlayment near an entry or exit of the ventilation channel. The fire retardant may be located along a single edge of the underlayment. The underlayment may have a planar area and the fire retardant may comprise an area that is less than the planar area, such that the fire retardant is located adjacent only a portion of the ventilation channel.
100631 In yet another embodiment, an underlayment may be configured to be located on a roof between a roof product and a roof deck. The underlayment may comprise a desiccant configured to transport moisture to and from the roof deck, and thereby heat is released and absorbed by the desiccant to effect a thermal management of the roof The underlayment also may be configured as described for the other embodiments.
100641 Embodiments of a method of making a roof component may comprise preparing a carrier layer in a web process: providing a desiccant to the carrier layer, the desiccant being adapted to absorb heat: fixing the desiccant to the carrier layer:
cutting the desiccant and carrier layer into selected dimensions: and packav_inv, a plurality of the cut desiccant and carrier layers.
100651 The method may comprise depositing the desiccant on or in the carrier layer, the desiccant comprising a solid material that is dispersed in a thermoplastic matrix that is extruded and then tentered to disband the solid material from the thermoplastic matrix to form a porous sheet that carries the desiccant. The method may further comprise laminating the fixed desiccant and carrier layer onto another layer after fixing. The method also may further comprise adhering the fixed desiccant and carrier layer onto a rooting article after fixing.

Attorney Docket No R-9441 100661 Other embodiments of the method may further comprise packing or calendaring the fixed desiccant and carrier layer: and/or forming a ventilation channel in the roof component: and/or adding to the carrier layer an additive, a fire retardant, an anti-microbial addition, a UV stabilizer, a UV protection layer, or any combination thereof:
and/or forming the desiccant and the fire retardant as a unitary structure;
and/or forming a skin layer adjacent the desiccant, and providing the skin layer with a moisture permeability that varies with at least one of temperature and relative humidity; and/or forming an uppermost layer and a lowermost layer and locating the desiccant therebetween.
100671 Embodiments of a method of managing thermal energy in a roof of a building may comprise providing a roof having a roof deck, a roof barrier and a roof product with a desiccant located between the roof deck and roof barrier; releasing moisture and absorbing thermal energy with the desiccant during a heating cycle; adsorbing moisture and releasing thermal energy with the desiccant into the building during a cooling cycle, such that the heat absorbed and released by the desiccant effects thermal management of the roof. The method may further comprise many other features and elements as described elsewhere herein for the other embodiments.
100681 In another embodiment, a kit for equipping a roof for thermal management may comprise a plurality of roof products, each of the roof products comprising a desiccant and a ventilation channel having channels to transfer moisture to and from the desiccant, and the heat released and absorbed by the desiccant is adapted to effect a thermal management of the roof; the roof products are adapted to form continuous air vents with the channels from adjacent an eave of the roof to adjacent a ridge of the roof; and attachment means for securing each of the roof products to a roof deck.
100691 The roof products may comprise lower edge eave elements, roof plane elements, and upper edge ridge elements. A fire retardant may be located along at least one of the lower edge eave elements and the upper edge ridge elements, or located in at least some of each of the lower edge eave elements, roof plane elements and upper edge ridge elements. The channels of the ventilation channels may form contiguous, uninterrupted Attorney Docket No R-9441 air flow paths between abutting roof products having inlets only adjacent an eave of the roof and outlets only adjacent a ridge of the roof.
[0070] The roof products may comprise rolls of material that extend continuously from adjacent an eave of the roof to adjacent a ridge of the roof to form continuous, uninterrupted air flow paths having inlets only adjacent the eave and outlets only adjacent the ridge, and there is no air flow communication in the channels between adjacent lateral rolls. The ventilation channels may be configured to ventilate an entire length of the roof. The kit may further comprise many other features and elements as described elsewhere herein for the other embodiments.
[0071] Example [0072] Referring now to FIGS. 10-15, two test huts were constructed for an experiment.
The test huts were identical with regard to their floors, walls, ceilings and attics, but their roof decks differed from each other. One of the test huts was a control and had a conventional roof deck construction. The other test hut was experimental and constructed in accordance with an embodiment herein, including a roof deck system containing a thermal management system. Each test hut included equipment to measure their attic temperatures and heat flux into the ceiling. For the experimental test hut, the roof deck included an air gap of about one inch and a layer of desiccant material. The details of the test hut configurations are listed in Table 1.
[0073] Table 1 Control Experimental Roof Assembly shingle Gray colored shingles* Gray colored shingles*
venting channel No 1" PC board desiccant material No Yes underlayment #30 felt #30 felt roof deck 7/16" OSB 7/16" OSB
attic insulation R-33 fiberglass batt R-33 fiberglass batt rafter 2x6 @ 16" O.C. 2x6 @ 16" O.C.
Ceiling Assembly joist 2x6 @ 16" O.C.

Attorney Docket No R-9441 gypsum board Wall Assembly siding fiber cement shiplap 5/16"
house wrap DuPont Tyvek sheathing 7/16" OSB
joists 2x4 @ 16" O.C.
insulation R-13 wall board Gypsum 5/8"
window 2'x3' PVC window Floor Assembly exterior sheathing Celotex sheathing/2 joists 2x6 @ 16" O.C.
insulation R-30 fiberglass batt decking plywood 3/4"
additional insulation board insulation R-10 (2") Space conditioning Through-the-wall AC: GE model AJCQ06LCD at capacity of 6400 BTU/hr and 9.9 EER
*Landmark Solaris shingle, available from CertainTeed Corp., Portland, OR
[0074] The architecture and dimensions of the test huts are illustrated in FIGS. 10A-10D, and their framing structure is depicted in FIG. 11. Approximate internal dimensions of each finished test hut are 6.2 feet high, 11.3 feet wide, and 7.0 feet deep.
The internal floor of each hut was about 79 ft2 and the roof pitch was approximately 200 with an overhang of 6.5 inches over the south-facing wall. The orientation of each roof faced south as well. The roof deck configurations are shown schematically in FIG.
12. Both test huts included roof decks 111, felt 113, shingles 115, thermistors 117 and a heat flux sensor 119. The experimental hut further included venting layer 121, desiccant materials 123 and additional thermistors 117 and heat flux sensor 119, as shown.
[0075] The desiccant materials 123 for the experimental test hut comprised LiquidBlock 44-0C, from Emerging Technologies, Greensboro, NC, and montmorillonite clay from Multisorb Technologies, Buffalo, NY. The desiccant materials were mixed and then packaged in a honeycomb sheet (available from Plascore Inc., Zeeland, MI). The sheet was then covered by laminating a nonwoven fabric having a vapor permeability of greater than 5 perm. The amount of desiccant material used was about 0.5 lb/ft2. The Attorney Docket No R-9441 sheet was elevated 1/8-inch above the roof deck with plastic spacers located between the sheet and the roof deck. This small air gap allows for moisture migration into and out of the desiccant materials.
[0076] The test huts were constructed and placed in an outdoor environment with a south facing orientation in Albuquerque, NM. The test huts were spaced apart from each other to ensure no shadowing effects on each other. The room inside each test hut was maintained at a constant 20 C with an air conditioning (AC) unit during the daytime.
The test huts were not occupied nor did they contain any furniture. Each test hut had a window that measured 2 feet by 3 feet to simulate their solar heat gain into the room.
The roof shingle temperature, roof deck temperature, attic temperature at both the inner side of the roof deck and at the attic floor, ceiling temperature, room temperature, and wall temperatures were measured by thermistors and thermocouples. The energy consumption, start time, and the run duration of the AC unit were recorded to determine the energy impact. The data was collected with a data acquisition system connected to a computer located inside each of the test huts.
[0077] During September and October of 2012, the data was collected in each test hut.
The results are shown in FIGS. 13-15. The temperatures of the roof decks (FIG.
13) show that the experimental test hut provided a reduction of about 10 to 15 C
compared to the control. This affected the attic air temperatures (FIG. 14) which also show a significant reduction of about 15 C in peak temperatures and improvement in night time temperatures. This reduction of peak temperatures had a significant delaying effect for reducing the peak hour energy demands (FIG. 15) and also significantly reduced the AC
load. The overall AC energy consumption was reduced by an average of about 115 Wh per day during the test period for the experimental test hut compared to the conventional test hut. Other examples will be apparent to those who are skilled in the art.
[0078] This written description uses examples to disclose the embodiments, including the best mode, and also to enable those of ordinary skill in the art to make and use the invention. The patentable scope is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be Attorney Docket No R-944!
within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.
[0079] Note that not all of the activities described above in the general description or the examples are required, that a portion of a specific activity may not be required, and that one or more further activities may be performed in addition to those described. Still further, the orders in which activities are listed are not necessarily the order in which they are performed.
[0080] In the foregoing specification, the concepts have been described with reference to specific embodiments. However, one of ordinary skill in the art appreciates that various modifications and changes can be made without departing from the scope of the invention as set forth in the claims below. Accordingly, the specification and figures are to be regarded in an illustrative rather than a restrictive sense, and all such modifications are intended to be included within the scope of invention.
[0081] As used herein, the terms "comprises," "comprising," "includes,"
"including,"
"has," "having" or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a process, method, article, or apparatus that comprises a list of features is not necessarily limited only to those features but may include other features not expressly listed or inherent to such process, method, article, or apparatus. Further, unless expressly stated to the contrary, "or" refers to an inclusive-or and not to an exclusive-or. For example, a condition A or B is satisfied by any one of the following: A
is true (or present) and B is false (or not present), A is false (or not present) and B is true (or present), and both A and B are true (or present).
[0082] Also, the use of "a" or "an" are employed to describe elements and components described herein. This is done merely for convenience and to give a general sense of the scope of the invention. This description should be read to include one or at least one and the singular also includes the plural unless it is obvious that it is meant otherwise.

Attorney Docket No R-9441 [0083] Benefits, other advantages, and solutions to problems have been described above with regard to specific embodiments. However, the benefits, advantages, solutions to problems, and any feature(s) that may cause any benefit, advantage, or solution to occur or become more pronounced are not to be construed as a critical, required, or essential feature of any or all the claims.
[0084] After reading the specification, skilled artisans will appreciate that certain features are, for clarity, described herein in the context of separate embodiments, may also be provided in combination in a single embodiment. Conversely, various features that are, for brevity, described in the context of a single embodiment, may also be provided separately or in any subcombination. Further, references to values stated in ranges include each and every value within that range.

Claims (127)

WHAT IS CLAIMED IS:

1. A roof system, comprising:
a roof deck on a building;
a roof product secured to the roof deck; and a thermal energy absorbing product (TEAP) comprising a desiccant located between the roof deck and the roof product, whereby the desiccant reversibly absorbs moisture, and in response thereto heat is released and absorbed, respectively, by the desiccant to effect a thermal management of the roof system.

2. A roof system according to Claim 1, wherein the desiccant comprises a powder or sheet form.

3. A roof system according to Claim 1. wherein the TEAP comprises a non-woven mat. glass mat, woven mat, scrim. felt. Kraft paper, honeycomb board, channeled panel, industrial fabric, recycled mat, porous ceramic board, cementitious board, wood composite, plastic wood, inorganic bonded composite. gypsum board, or any combination thereof

4. A roof system according to Claim 1, further comprising an additive, a fire retardant, an anti-microbial addition, a UV stabilizer, a UV protection layer, or any combination thereof.

5. A roof system according to Claim 4, wherein the desiccant and fire retardant form a unitary structure.

6. A roof system according to Claim 5, wherein the unitary structure comprises less than about 25% of the fire retardant, less than about 10% of the fire retardant, or less than about 5% of the fire retardant.

7. A roof system according to Claim 4, wherein the fire retardant comprises expandable clay, expandable carbon black, expandable graphite, intumescent silicates, hydrated metal silicates, bromated compounds, halocarbons, aluminum hydroxide, magnesium hydroxide, hydromagnesite, antimony trioxide, various hydrates, red phosphorus, boron compounds, phosphonium salts, or any combination thereof.

8. A roof system according to Claim 1, further comprising a skin layer adjacent the desiccant, and the skin layer has a moisture permeability of greater than 2 perm, greater than 5 perm, or greater than 10 perm.

9. A roof system according to Claim 8, wherein the skin layer comprises an uppermost layer and a lowermost layer, between which are located the desiccant.

10. A roof system according to Claim 1, wherein the TEAP comprises a rigid sheet, a rigid panel or a flexible roll.

11. A roof system according to Claim 1, wherein the desiccant comprises clay, nano-clay, montmorillonite clay, synthetic zeolite, surface modified carbon, carbon molecular sieve, activated carbon, calcium oxide, calcium sulfate, salt, inorganic salt, silica gel, activated alumina, polymeric desiccant material, cellulose material, metal silicate, or any combination thereof

12. A roof system according to Claim 1, wherein the TEAP has an effective heat of absorption to regulate at least 5% of solar energy incident thereon, at least 10% of solar energy incident thereon, or greater than 20% of solar energy incident thereon, or greater than 30% of solar energy incident thereon.

13. A roof system according to Claim 1, wherein the desiccant is a powder or in an encapsulated form with a size in a range of about U.S. mesh #10 to about U.S.
mesh #325, or about U.S. mesh #60 to about U.S. mesh #325, or about U.S. mesh #100 to about U.S. mesh #325.

14. A roof system according to Claim 1, further comprising a ventilation channel adjacent the desiccant, whereby air having a humidity flowing through the ventilation channel transports moisture to and from the desiccant, and the heat released and absorbed by the desiccant effects thermal management of the roof system.

15. A roof system according to Claim 1, wherein the TEAP is flexible in lower temperatures about 0°C, and remains structurally sound for a roof walkable surface in higher temperatures where a roof surface temperature exceeds about 70°C.

16. A roof system according to Claim 1, wherein the TEAP is directly nailable for roofing shingles on top thereof without affecting an overall thickness and functionality of the TEAP.

17. A roof system according to Claim 1, wherein the desiccant has a heat of absorption of greater than about 20 kJ/mol-H2O, greater than about 25 kJ/mol-H2O, greater than about 30 kJ/mol-H2O, greater than about 35 kJ/mol-H2O, or greater than about 40 kJ/mol-H2O to store solar heat during a heating cycle, and has a thermal emittance of greater than about 0.70 that re-radiates stored heat during a cooling cycle.

18. A roof system according to Claim 1, wherein the desiccant has a heat of absorption of less than about 70 kJ/mol-H2O, less than about 65 kJ/mol-H2O, or less than about 50 kJ/mol-H2O to store solar heat during a heating cycle, and a heat absorbing range of about 10°C to about 50°C, or about 20°C to about 40°C.

19. A roof system according to Claim 1, wherein the TEAP has a plurality of cells configured to be penetrated by roofing fasteners, and the cells are void of the dessicant.

20. A roof system according to Claim 1, wherein the TEAP includes an upper radiant barrier and a lower moisture barrier, and the TEAP comprises the only material located between a roof deck and a roof product.

21. A roof system according to Claim 1, wherein the TEAP has a thickness of about 0.75 inches to about 2.5 inches, or about 0.25 inches to about 1 inch.

22. A roof system according to Claim 1, wherein the TEAP has a weight in a range of about 1 pound per square foot to about 10 pounds per square foot.

23, An underlayment configured to be located on a roof between a roof product and a roof deck, the underlayment comprising:
a desiccant; and a ventilation channel adjacent the desiccant and is adapted to have air with a humidity flow through the ventilation channel, and the ventilation channel is configured to reversibly transport moisture to and from the desiccant, and in response thereto heat is released and absorbed by the desiccant to effect a thermal management of the roof,

24, An underlayment according to Claim 23, wherein the ventilation channel is adapted to ventilate an entire length of the roof,

25, An underlayment according to Claim 23, further comprising a fire retardant to suppress fire through the ventilation channel,

26, An underlayment according to Claim 25, wherein the desiccant, ventilation channel and fire retardant form a unitary structure.

27, An underlayment according to Claim 23, wherein the desiccant comprises a powder or sheet form, and the ventilation channel comprises a carrier and structural layer for the desiccant.

28, An underlayment according to Claim 27, wherein the carrier comprises an array of honeycomb cavities with vertical axes.

29, An underlayment according to Claim 23, further comprising an additive, a fire retardant, an anti-microbial addition, a UV stabilizer, a UV protection layer, or any combination thereof.

30, An underlayment according to Claim 23,wherein the underlayment comprises a non-woven mat, glass mat, woven mat, scrim, felt, Kraft paper, honeycomb board, channeled panel, industrial fabric, recycled mat, porous ceramic board, cementitious board, wood composite, plastic wood, inorganic bonded composite, gypsum board, or any combination thereof.

31. An underlayment according to Claim 23, further comprising a skin layer adjacent the desiccant, and the skin layer has a moisture permeability of greater than 2 perm, greater than 5 perm, or greater than 10 perm.

32. An underlayment according to Claim 31, wherein the skin layer comprises an uppermost layer and a lowermost layer, between which are located the desiccant and the ventilation channel.

33. An underlayment according to Claim 23, further comprising a skin layer between the desiccant and ventilation channel, the skin layer having a porosity controlled by microperforation or needle punch.

34. An underlayment according to Claim 33, wherein the porosity comprises micropores that are configured to permit water vapor to pass therethrough but the micropores do not transmit liquid water.

35. An underlayment according to Claim 23, wherein the desiccant comprises clay, nano-clay, montmorillonite clay, synthetic zeolite, surface modified carbon, carbon molecular sieve, activated carbon, calcium oxide, calcium sulfate, salt, inorganic salt, silica gel, activated alumina, polymeric desiccant material, cellulose material, metal silicate, or any combination thereof.

36. An underlayment according to Claim 23, wherein the desiccant has an effective heat of absorption to regulate at least 5% of solar energy incident thereon, at least 10%
of solar energy incident thereon, or greater than 20% of solar energy incident thereon, or greater than 30% of solar energy incident thereon.

37. An underlayment according to Claim 23, wherein the desiccant is a powder or in an encapsulated form with sizes that is in a range of about U.S. mesh #10 to about U.S.
mesh #325, or about U.S. mesh #60 to about U.S. mesh #325, or about U.S. mesh #100 to about U.S. mesh #325.

38. An underlayment according to Claim 23, wherein the ventilation channel comprises thermoplastic, thermoplastic elastomer, aluminum, thermoset resin, cellulous composite, wood composite, rubber, or any combination thereof.

39. An underlayment according to Claim 23, wherein the ventilation channel comprises a filler, functional filler, fire retardant, intumescent agent, biocide, fungicide or any combination thereof.

40. An underlayment according to Claim 39, wherein the fire retardant is combined with the desiccant, and the fire retardant comprises an intumescent that expands into the ventilation channel at a temperature in a range of about 175°C to about 280°C.

41. An underlayment according to Claim 39, wherein the fire retardant comprises materials used to form a structure for the ventilation channel, such that the fire retardant and the ventilation channel are combined in a single layer.

42. An underlayment according to Claim 39, wherein the fire retardant is located on the underlayment near an entry or exit of the ventilation channel.

43. An underlayment according to Claim 39, wherein the fire retardant comprises expandable clay, expandable carbon black, expandable graphite, intumescent silicates, hydrated metal silicates, bromated compounds, halocarbons, aluminum hydroxide, magnesium hydroxide, hydromagnesite, antimony trioxide, various hydrates, red phosphorus, boron compounds, phosphonium salts, or any combination thereof.

44. An underlayment according to Claim 23, wherein the ventilation channel is adapted to vent excess heat from an eave of a roof up to a ridge of the roof and out to atmosphere.

45. An underlayment according to Claim 23, wherein the ventilation channel is adapted to vent excess heat via natural air flow from a lower eave of the roof up to a ridge of the roof.

46. An underlayment according to Claim 23, wherein the underlayment is flexible in temperatures of about 0°C, and is structurally sound for a roof walkable surface where a roof surface temperature exceeds about 70°C.

47. An underlayment according to Claim 23, wherein the underlayment is directly nailable for roofing shingles on top thereof without affecting an overall thickness and functionality of the underlayment.

48. An underlayment according to Claim 23, further comprising an uppermost layer that is UV resistant and comprises a radiant barrier.

49. An underlayment according to Claim 23, wherein the desiccant has a heat of absorption of at least about 30 kJ/mol-H2O that stores solar heat during a heating cycle, and has a thermal emittance of greater than about 0.70 that re-radiates stored heat during a cooling cycle.

50. An underlayment according to Claim 23, wherein the desiccant has a heat of absorption greater than about 30kJ/mol-H2O, and a heat absorbing range of about 10°C to about 50°C, or about 20°C to about 40°C.

51. An underlayment according to Claim 23, wherein the ventilation channel has openings, and each opening has an effective area of about 0.01 in2 to about 1 in2, or about 0.05 in2 to about 0.5 in2.

52. An underlayment according to Claim 23, wherein the underlayment has a plurality of cells adapted to be penetrated by roofing fasteners, and the cells are void of the desiccant.

53. An underlayment according to Claim 23, wherein the underlayment includes an upper radiant barrier and a lower moisture barrier, such that the underlayment is configured to comprise the only material located between a roof deck and a roof barrier.

54. An underlayment according to Claim 23, wherein the underlayment has a thickness of about 0.75 inches to about 2.5 inches, the desiccant has a thickness of about 0.25 inches to about 1 inch, and the ventilation channel has a thickness of about 0.25 inches to about 1 inch.

55. An underlayment according to Claim 39, wherein the underlayment has a planar area and the fire retardant comprises an area that is less than the planar area, such that the fire retardant is located adjacent only a portion of the ventilation channel.

56. An underlayment according to Claim 39, wherein the fire retardant is located along a single edge of the underlayment.

57. An underlayment according to Claim 23, wherein the underlayment has a weight in a range of about 1 pound per square foot to about 10 pounds per square foot.

58. An underlayment configured to be located on a roof between a roof product and a roof deck, the underlayment comprising:
a desiccant configured to transport moisture to and from the roof deck, and in response thereto heat is released and absorbed by the desiccant is adapted to effect a thermal management of the roof.

59. An underlayment according to Claim 58, wherein the desiccant comprises a powder or sheet form, and further comprising a carrier and structural layer for the desiccant.

60. An underlayment according to Claim 59, wherein the carrier further comprises an additive, a fire retardant, an anti-microbial addition. a UV stabilizer, a UV
protection layer, or any combination thereof

61. An underlayment according to Claim 60, wherein the additive comprises a non-woven mat, glass mat, woven mat. scrim. felt. Kraft paper. honeycomb board, channeled panel, industrial fabric, recycled mat. porous ceramic board, cementitious board, wood composite, plastic wood, inorganic bonded composite. gypsum board, or any combination thereof.

62. An underlayment according to Claim 58, further comprising a skin layer adjacent the desiccant, and the skin layer has a moisture permeability of greater than 2 perm, greater than 5 perm, or greater than 10 perm.

63. An underlayment according to Claim 62, wherein the skin layer comprises an uppermost layer and a lowermost layer, between which is located the desiccant.

64. An underlayment according to Claim 58, further comprising a skin layer having a porosity controlled by microperforation or needle punch.

65. An underlayment according to Claim 64, wherein the porosity comprises micropores that are configured to permit water vapor to pass therethrough but the micropores do not transmit liquid water.

66. An underlayment according to Claim 58, wherein the desiccant comprises clay, nano-clay, montmorillonite clay, synthetic zeolite, surface modified carbon, carbon molecular sieve, activated carbon, calcium oxide, calcium sulfate, salt, inorganic salt, silica gel, activated alumina, polymeric desiccant material, cellulose material, metal silicate, or any combination thereof.

67. An underlayment according to Claim 58, wherein the desiccant has an effective heat of absorption to regulate at least 5% of solar energy incident thereon, at least 10%
of solar energy incident thereon, or greater than 20% of solar energy incident thereon, or greater than 30% of solar energy incident thereon.

68. An underlayment according to Claim 58, wherein the desiccant is a powder or in an encapsulated form with sizes that is in a range of about U.S. mesh #10 to about U.S.
mesh #325, or about U.S. mesh #60 to about U.S. mesh #325, or about U.S. mesh #100 to about U.S. mesh #325.

69. An underlayment according to Claim 58, further comprising a fire retardant, and the desiccant and the fire retardant form a unitary structure.

70. An underlayment according to Claim 69, wherein the fire retardant comprises an intumescent that expands at a temperature in a range of about 175°C to about 280°C.

71. An underlayment according to Claim 69, wherein the fire retardant comprises expandable clay, expandable carbon black, expandable graphite, intumescent silicates, hydrated metal silicates, bromated compounds, halocarbons, aluminum hydroxide, magnesium hydroxide, hydromagnesite, antimony trioxide, various hydrates, red phosphorus, boron compounds, phosphonium salts, or any combination thereof.

72. An underlayment according to Claim 58, wherein the underlayment is flexible in temperatures of about 0°C, and is a roof walkable surface where a roof surface temperature exceeds about 70°C.

73. An underlayment according to Claim 58, wherein the underlayment is directly nailable for roofing shingles on top thereof without affecting an overall thickness and functionality of the underlayment.

74. An underlayment according to Claim 58, further comprising an uppermost layer that is UV resistant and comprises a radiant barrier.

75. An underlayment according to Claim 58, wherein the desiccant has a heat of absorption of at least about 30 kJ/mol-H20 that stores solar heat during a heating cycle, and has a thermal emittance of greater than about 0.70 that re-radiates stored heat during a cooling cycle.

76. An underlayment according to Claim 58, wherein the desiccant has a heat of absorption greater than about 30kJ/mol-H2O, and a heat absorbing range of about 10°C to about 50°C, or about 20°C to about 40°C.

77. An underlayment according to Claim 58, wherein the underlayment includes an upper radiant barrier and a lower moisture barrier, such that the underlayment is configured to comprise the only material located between a roof deck and a roof barrier.

78. An underlayment according to Claim 58, wherein the underlayment has a thickness of about 0.75 inches to about 2.5 inches, the desiccant has a thickness of about 0.25 inches to about 1 inch, and the underlayment has a weight in a range of about 1 pound per square foot to about 10 pounds per square foot.

79. A method of making a roof component, comprising:
(a) preparing a carrier layer in a web process;
(b) providing a desiccant to the carrier layer, the desiccant being adapted to absorb heat;
(c) fixing the desiccant to the carrier layer;
(d) cutting the desiccant and carrier layer into selected dimensions; and (e) packaging a plurality of the cut desiccant and carrier layers.

80. A method according to Claim 79, wherein step (b) comprises depositing the desiccant on or in the carrier layer, the desiccant comprising a solid material that is dispersed in a thermoplastic matrix that is extruded and then tentered to disband the solid material from the thermoplastic matrix to form a porous sheet that carries the desiccant.

81. A method according to Claim 79. further comprising laminating the fixed desiccant and carrier layer onto another layer after step (c).

82. A method according to Claim 79, further comprising adhering the fixed desiccant and carrier layer onto a roofing article after step (c).

83. A method according to Claim 79, further comprising packing or calendaring the fixed desiccant and carrier layer.

84. A method according to Claim 79, further comprising forming a ventilation channel in the roof component, and the ventilation channel is constructed by extruding, injection molding. compression molding, pultruding. laminating, or thermal forming.

85. A method according to Claim 79, further comprising adding to the carrier layer an additive, a fire retardant, an anti-microbial addition, a UV stabilizer, a UV
protection layer, or any combination thereof

86. A method according to Claim 85, further comprising forming the desiccant and the fire retardant as a unitary structure.

87. A method according to Claim 79, further comprising forming a skin layer adjacent the desiccant, and the skin layer has a moisture permeability of greater than 2 perm, greater than 5 perm, or greater than 10 perm.

88. A method according to Claim 79, further comprising forming an uppermost layer and a lowermost layer and locating the desiccant therebetween.

89. A method of managing thermal energy in a roof of a building, comprising:
providing a roof having a roof deck, a roof barrier and a roof product with a desiccant located between the roof deck and roof barrier;
releasing moisture and absorbing thermal energy with the desiccant during a heating cycle;
adsorbing moisture and releasing thermal energy with the desiccant into the building during a cooling cycle, such that the heat absorbed and released by the desiccant effects thermal management of the roof.

90. A method according to Claim 89, further comprising providing the roof product with an additive, a fire retardant, an anti-microbial addition, a UV
stabilizer, a UV
protection layer, or any combination thereof.

91. A method according to Claim 89, further comprising providing the roof product with a skin layer adjacent the desiccant, and a skin layer adjacent the desiccant, and the skin layer has a moisture permeability of greater than 2 perm, greater than 5 perm, or greater than 10 perm.

92. A method according to Claim 89, further comprising regulating at least 20% of solar energy incident on the roof product.

93. A method according to Claim 89, further comprising providing the roof product with a ventilation channel adjacent the desiccant, whereby air having a humidity flowing through the ventilation channel transports moisture to and from the desiccant, and the desiccant releases and absorbs heat, respectively, to effect thermal management of the roof.

94. A method according to Claim 89, further comprising providing the desiccant with a heat of absorption greater than about 30kJ/mol-H2O, and a heat absorbing range of about 10°C to about 50°C, or about 20°C to about 40°C.

95. A method according to Claim 89, further comprising providing the roof product with an upper radiant barrier and a lower moisture barrier, such that the roof product comprises the only material located between the roof deck and the roof barrier.

96. A kit for equipping a roof for thermal management, comprising:
a plurality of roof products, each of the roof products comprising a desiccant and a ventilation channel having channels to transfer moisture to and from the desiccant, and in response thereto heat is released and absorbed by the desiccant to effect a thermal management of the roof;
the roof products are adapted to form continuous air vents with the channels from adjacent an eave of the roof to adjacent a ridge of the roof; and attachment means for securing each of the roof products to a roof deck.

97. A kit according to Claim 96, wherein the roof products comprise lower edge eave elements, roof plane elements, and upper edge ridge elements, and the ventilation channels are configured to ventilate an entire length of the roof

98. A kit according to Claim 96, wherein a fire retardant is located along at least one of the lower edge eave elements and the upper edge ridge elements, or the fire retardant is located in at least some of each of the lower edge eave elements, roof plane elements and upper edge ridge elements.

99. A kit according to Claim 96, wherein the channels of the ventilation channels form contiguous, uninterrupted air flow paths between abutting roof products having inlets only adjacent an eave of the roof and outlets only adjacent a ridge of the roof

100. A kit according to Claim 96, wherein the roof products comprise rolls of material configured to extend continuously from adjacent an eave of the roof to adjacent a ridge of the roof to form continuous, uninterrupted air flow paths having inlets only adjacent the eave and outlets only adjacent the ridge, and there is no air flow communication in the channels between adjacent lateral rolls.

101. A kit according to Claim 96, wherein the desiccant and ventilation channels form unitary structures.

102. A kit according to Claim 96, wherein the desiccant comprises a powder or sheet form, and the ventilation channels comprise carriers and structural layers for the desiccant.

103. A kit according to Claim 96, wherein each of the roof products further comprises an additive, a fire retardant, an anti-microbial addition, a UV stabilizer, a UV protection layer, or any combination thereof.

104. A kit according to Claim 96, wherein each of the roof products comprises a non-woven mat, glass mat, woven mat, scrim, felt, Kraft paper, honeycomb board, channeled panel, industrial fabric, recycled mat. porous ceramic board, cementitious board, wood composite, plastic wood, inorganic bonded composite, gypsum board, or any combination thereof.

105. A kit according to Claim 96, wherein each of the roof products further comprises a skin layer adjacent the desiccant, and the skin layer has a moisture permeability of greater than 2 perm, greater than 5 perm, or greater than 10 perm.

106. A kit according to Claim 105, wherein the skin layer comprises an uppermost layer and a lowermost layer, between which are located the desiccant and the ventilation channel.

107. A kit according to Claim 96, wherein each of the roof products further comprises a skin layer between the desiccant and ventilation channels, the skin layer having a porosity controlled by microperforation or needle punch.

108. A kit according to Claim 107, wherein the porosity comprises micropores that are configured to permit water vapor to pass therethrough but the micropores do not transmit liquid water.

109. A kit according to Claim 96, wherein the desiccant comprises clay, nano-clay, montmorillonite clay, synthetic zeolite, surface modified carbon, carbon molecular sieve, activated carbon, calcium oxide, calcium sulfate, salt, inorganic salt, silica gel, activated alumina, polymeric desiccant material, cellulose material, metal silicate, or any combination thereof.

110. A kit according to Claim 96, wherein the desiccant has an effective heat of absorption to regulate at least 5% of solar energy incident thereon, at least 10% of solar energy incident thereon, or greater than 20% of solar energy incident thereon, or greater than 30% of solar energy incident thereon.

111. A kit according to Claim 96, wherein the desiccant is a powder or in an encapsulated form with sizes that is in a range of about U.S. mesh #10 to about U.S.
mesh #325, or about U.S. mesh #60 to about U.S. mesh #325, or about U.S. mesh #100 to about U.S. mesh #325.

112. A kit according to Claim 96, wherein the ventilation channels comprise thermoplastic, thermoplastic elastomer, aluminum, thermoset resin, cellulous composite, wood composite, rubber, or any combination thereof.

113. A kit according to Claim 96, wherein the ventilation channels comprise a filler, functional filler, fire retardant, intumescent agent, biocide, fungicide or any combination thereof.

114. A kit according to Claim 113, wherein the fire retardant is combined with the desiccant, and the fire retardant comprises an intumescent that expands into the ventilation channels at a temperature in a range of about 175°C to about 280°C.

115. A kit according to Claim 113, wherein the fire retardant comprises materials used to form a structure for the ventilation channel, such that the fire retardant and the ventilation channel are combined in a single layer.

116. A kit according to Claim 113, wherein the fire retardant comprises an accessory that is applied to the roof products near entries or exits of the ventilation channels.

117. A kit according to Claim 113, wherein the fire retardant comprises expandable clay, expandable carbon black, expandable graphite, intumescent silicates, hydrated metal silicates, bromated compounds, halocarbons, aluminum hydroxide, magnesium hydroxide, hydromagnesite, antimony trioxide, various hydrates, red phosphorus, boron compounds, phosphonium salts, or any combination thereof.

118. A kit according to Claim 96, wherein the roof products are flexible in temperatures of about 0°C, and remain structurally sound for a roof walkable surface at a roof surface temperature in excess of about 70°C.

119. A kit according to Claim 96, wherein the roof products are directly nailable for roofing shingles on top thereof without affecting an overall thickness and functionality of the roof products.

120. A kit according to Claim 96, wherein the desiccant has a heat of absorption greater than about 30 kJ/mol-H20 that stores solar heat during a heating cycle, and has a thermal emittance of greater than about 0.70 that re-radiates stored heat during a cooling cycle.

121. A kit according to Claim 96, wherein the desiccant has a heat of absorption greater than about 30 kJ/mol-H20, and a heat absorbing range of about 10°C to about 50°C, or about 20°C to about 40°C.

122. A kit according to Claim 96, wherein the ventilation channels have openings, and each opening has an effective area of about 0.01 in2 to about 1 in2, or about 0.05 in2 to about 0.5 in2.

123. A kit according to Claim 96, wherein each of the roof products has a plurality of cells adapted to be penetrated by roofing fasteners, and the cells are void of the desiccant.

124. A kit according to Claim 96, wherein each of the roof products includes an upper radiant barrier and a lower moisture barrier, such that the roof products are configured to comprise the only material located between the roof deck and a roof barrier.

125. A kit according to Claim 96, wherein each of the roof products has a thickness of about 0.75 inches to about 2.5 inches, the desiccant has a thickness of about 0.25 inches to about 1 inch, and each of the ventilation channels has a thickness of about 0.25 inches to about 1 inch.

126. A kit according to Claim 96, wherein the roof products have a weight in a range of about 1 pound per square foot to about 10 pounds per square foot.

127. A roof system according to Claim 1, wherein the TEAP has an effective heat of absorption to regulate at least 5% of ambient thermal energy incident thereon, at least 10% of ambient thermal energy incident thereon, or greater than 20% of ambient thermal energy incident thereon, or greater than 30% of ambient thermal energy incident thereon.