CN100338791C - 用于过电压保护的有机元件及相关电路 - Google Patents
用于过电压保护的有机元件及相关电路 Download PDFInfo
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- CN100338791C CN100338791C CNB038200430A CN03820043A CN100338791C CN 100338791 C CN100338791 C CN 100338791C CN B038200430 A CNB038200430 A CN B038200430A CN 03820043 A CN03820043 A CN 03820043A CN 100338791 C CN100338791 C CN 100338791C
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
- H01C7/12—Overvoltage protection resistors
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K7/00—Methods or arrangements for sensing record carriers, e.g. for reading patterns
- G06K7/0008—General problems related to the reading of electronic memory record carriers, independent of its reading method, e.g. power transfer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
- H01C7/105—Varistor cores
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Abstract
本发明涉及一种主要由有机材料构成的并为电子电路提供过电压保护的元件和一种电路,利用该电路可以实现单个元件阈值电压的成倍增加。
Description
技术领域
本发明涉及一种主要由有机材料构成的元件,其为电子电路提供过电压保护。
背景技术
众所周知,用于过电压保护的电子元件是基于在传统硅半导体技术基础上发展的无机电路的。作为例子,这里可以提到的是齐纳二极管和隧道二极管。
正在开发关于诸如RFID-标签(射频识别)、票据、可穿戴电子产品(结合到织物中的电子电路)等等的最低成本应用的有机电子元件和基于其的电路。它们价格不高而且可以利用简单的印刷工艺在大表面面积上生产。这些电路需要恒定的电压供应,在这种情况下必须要避免因电压巅值造成的损坏,例如,如果电路离发射天线太近或如果RFID-标签过快通过交变电磁场。迄今还未见过能与有机场效应晶体管相比的、主要包括有机材料的电子元件。
发明内容
因此,本发明的目的是提供一种电子元件,该元件主要包括有机材料并提供过电压保护,即,当电压下降低于或超过一可调阈值电压时,该元件起到截断电流流动的电阻器的作用并反之亦然,其中该元件的电容很低。
本发明的主题是一种用于过电压保护的电子元件,其主要包括有机功能高分子,该元件至少具有如下诸层:
衬底,
主要电极,
有机半导电功能层,和
次级电极,其中阈值电压可以通过选择电极材料和/或半导电功能层的材料加以调节。此外,本发明的主题是一种电路,其包括至少两个串联在一起用于过电压保护的主要包括有机材料的元件,其中该串联电路提供相应于单个元件的阈值电压的倍数的阈值电压。
根据本发明的一实施例,该元件包括在所述电极之一和所述有机半导体层之间的至少一个中间层。该中间层可以例如主要由有机和/或氧化材料构成。通过将至少一个中间层包括在内,可以在几伏之内对阈值电压进行调节。
该元件正向工作,即,一直到阈值电压之前没有电流(或者只有小到可忽略的电流)流过,然而高于阈值电压时则有很高的电流流过,这样功率受限的电流源的电压就会崩溃。在反向时,没有电流(或者只有小到可忽略的电流)流过。
根据一实施例,至少串联连接两个元件。通过这种方式,有可能实现相应于单个元件的阈值电压的倍数的所需阈值电压。
该元件简单的导电和半导电功能层结构允许其被集成到有机电路中。在这种情况下导电和/或半导电功能层可以通过一种工艺和/或通过公共工艺步骤(例如印刷工艺)生产。
以下将以实施例的方式更加详细地描述本发明。
附图说明
图1示出了没有中间层的、依据本发明的元件的简单结构;
图2示出了具有两个中间层的实施例;
图3示出了两个串联连接的元件;
图4示出了对应于图3的相应电流-电压曲线;以及
图5最后示出了一种包括横向结构的元件。
具体实施方式
图1示出了衬底1、和置于其上的(垂直结构的实施)主要电极2、置于主要电极上的半导电功能层3和半导电功能层3上的次级电极4,其中,衬底1例如包括诸如聚酯膜的柔性膜,主要电极2举例来说由诸如聚苯胺(Pani)、聚亚乙基二氧噻吩(Pedot)的有机材料或诸如金、铜、铝或钛的金属或合金构成,半导电功能层3是例如聚噻吩和/或聚芴的有机基的,而次级电极的材料还是例如Pani、Pedot或诸如金、铜、铝或钛的金属或合金。与传统元件相比,该元件具有高阈值电压,该阈值电压可以通过选择电极材料和半导体材料加以调节。
图2示出了一元件,对于层2到4以及衬底1而言,其具有可比于图1的层结构,但是在这种情况下,在主要电极2和半导电功能层3之间以及在半导电功能层3和次级电极4之间设置了各自中间层(5、6),通过中间层可以偏移阈值电压。中间层5、6可以是变化最宽的材料,例如诸如聚噻吩、聚芴(两种材料可以掺杂或不掺杂)、Pani、Pedot的有机材料或诸如金属氧化物或硅氧化物的氧化材料。
图3示出了串联连接的两个元件,其中在本实施例中的层结构与图1中的单个元件的层结构相同。
图4示出了串联元件的电流-电压特性。可以看出,在这种情况下,多个元件的串联(图3)是如何还使获得相应于单个元件的阈值电压的倍数的阈值电压成为可能的。
最后,图5示出了如图1基本得知的元件的横向结构。这里可以再次看到衬底1、主要电极2、半导电功能层3和次级电极4。
阈值电压可以通过选择合适的电极和/或半导体材料加以很好地调节。同样,阈值电压可以通过诸如薄绝缘层或氧化物的一个或不同半导体材料的两个附加中间层加以偏移。多个元件的串联还允许对相关各自要求的粗略适应。
该元件的电容取决于层厚和有机半导体与材料有关的介电常数。通过适当厚度的层的方式可以保持低的电容。
该元件利用已知工艺制造。单个层通过溅射和/或气相淀积涂布,或者然而在处理诸如高分子的可溶性材料时,通过旋涂和/或其他涂布工艺和/或印刷工艺涂布。结构化一方面可以通过诸如蚀刻和浮脱的传统工艺结合光刻法来实现,或者另一方面可以通过印刷程序实现。
用专门术语描述,该元件,例如图1所示的,可以如下制造:在一柔性聚酯膜1上溅射一金属层2(例如金)并利用光刻和蚀刻将该金属层结构化。然后通过旋涂来涂布溶于溶液中的半导电高分子(例如聚噻吩)。在蒸发掉溶剂之后,所得的产物为一同质半导体层3。在其上溅射次级电极4(例如铝)-利用荫罩进行结构化-。
术语“有机”、“有机材料”或“功能高分子”或“高分子”这里包括各种各样的有机、金属有机和/或有机-无机塑料材料(混合物),特别是英语中由例如“plastics(塑料)”表示的材料。这包括除构成传统二极管的半导体(锗、硅)和典型金属导体之外的各种物质。因此并没有教条地将有机材料局限在含碳材料的意思,而是同样承认例如硅酮的广泛使用。此外,本术语不受任何分子大小方面的限制,特别对高分子和/或低聚材料更是如此,而是肯定也可能使用小分子的。表达“功能高分子”中的单词成分“高分子”受到历史影响,从该方面来说,并不说明存在真实的高分子键合。
本发明首次提供了一种起过电压保护功能且能够集成到有机电路中的有机元件。
Claims (3)
1.一种用于过电压保护的电子元件,所述电子元件至少具有如下诸层:
衬底,
主要电极,
有机半导电功能层,和
次级电极,其中阈值电压能够通过选择所述主要和次级电极的材料和/或所述有机半导电功能层的材料加以调节,
其中至少所述有机半导电功能层包括有机功能聚合物。
2.如权利要求1所述的电子元件,其具有在所述电极之一和所述有机半导电功能层之间的至少一个中间层,且所述中间层由有机和/或氧化材料组成。
3.一种电路,其包括至少两个串联在一起用于过电压保护的如权利要求1和2之一所述的电子元件,其中所述电路提供相应于单个所述电子元件的阈值电压的倍数的阈值电压。
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DE10238800 | 2002-08-23 | ||
DE10238800.8 | 2002-08-23 |
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CN1679043A CN1679043A (zh) | 2005-10-05 |
CN100338791C true CN100338791C (zh) | 2007-09-19 |
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US (1) | US7414513B2 (zh) |
EP (1) | EP1532570B1 (zh) |
JP (1) | JP2005537637A (zh) |
CN (1) | CN100338791C (zh) |
AT (1) | ATE355566T1 (zh) |
DE (1) | DE50306683D1 (zh) |
ES (1) | ES2282722T3 (zh) |
HK (1) | HK1075524A1 (zh) |
WO (1) | WO2004021256A1 (zh) |
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DE102005031448A1 (de) | 2005-07-04 | 2007-01-11 | Polyic Gmbh & Co. Kg | Aktivierbare optische Schicht |
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- 2003-08-04 CN CNB038200430A patent/CN100338791C/zh not_active Expired - Fee Related
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- 2003-08-04 JP JP2004531439A patent/JP2005537637A/ja active Pending
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- 2003-08-04 US US10/524,646 patent/US7414513B2/en not_active Expired - Fee Related
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JP2005537637A (ja) | 2005-12-08 |
WO2004021256A1 (de) | 2004-03-11 |
ES2282722T3 (es) | 2007-10-16 |
HK1075524A1 (en) | 2005-12-16 |
CN1679043A (zh) | 2005-10-05 |
DE50306683D1 (de) | 2007-04-12 |
ATE355566T1 (de) | 2006-03-15 |
EP1532570B1 (de) | 2007-02-28 |
US20060098362A1 (en) | 2006-05-11 |
EP1532570A1 (de) | 2005-05-25 |
US7414513B2 (en) | 2008-08-19 |
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