CN100464251C - Black carbon powder and method for preparing same - Google Patents

Black carbon powder and method for preparing same Download PDF

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Publication number
CN100464251C
CN100464251C CNB2006101614519A CN200610161451A CN100464251C CN 100464251 C CN100464251 C CN 100464251C CN B2006101614519 A CNB2006101614519 A CN B2006101614519A CN 200610161451 A CN200610161451 A CN 200610161451A CN 100464251 C CN100464251 C CN 100464251C
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China
Prior art keywords
carbon powder
powder
black carbon
black
resin
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Expired - Fee Related
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CNB2006101614519A
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Chinese (zh)
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CN1996158A (en
Inventor
王建新
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Individual
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Individual
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Priority to CNB2006101614519A priority Critical patent/CN100464251C/en
Publication of CN1996158A publication Critical patent/CN1996158A/en
Application granted granted Critical
Publication of CN100464251C publication Critical patent/CN100464251C/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention relates to a yellow carbon powder and its manufacturing method. It is made by mixing 75-98 parts resin, 1-10 parts polyacrylic wax or polyethylene wax, 1-20 yellow pigment, 0.5-10 electric charge regulator, 0.1-1 part earth silicon, through extruding, coarse crushing and fine crushing. Matching yellow carbon powders with black, red and blue ones, it can simplify printing process, improve working efficiency, and reduce printing cost, applicable for long time preservation of archives.

Description

Black carbon powder and preparation method thereof
Technical field
The present invention relates to a kind of carbon dust and preparation method thereof.Be Xerox, laser printer, facsimile recorder and printing machine black carbon powder and preparation method thereof specifically.
Background technology
At present, the carbon dust that uses on Xerox, laser printer, facsimile recorder and the printing machine is the most general with black carbon powder.The picture and text that use black carbon powder to duplicate, print, receive and print out are ater, and color is relatively more dull, can't satisfy the needs of people to colored picture and text.For this reason, the chromatic printing machine that has occurred in recent years utilizing colored ink to carry out colored printing and utilize color inks to carry out the ink-jet printer of colour print.Though use colored ink and color inks can realize colored printing and colour print, the former needs to carry out four chromatographys with the printing ink of different colours in four, but also need carry out photomechanical production, makes to be difficult to the typography more complicated increase work efficiency.Moreover used thinning agent is a toluene in the printing ink, also can bring harm to human body.Though the latter can be printed picture and text true to nature and be come, the consumption of ink is big, use cost is high, and with the picture and text color of ink printed fail easily, the holding time is short, being difficult to adapt to needs the long-time document information printing needs of preserving.
Summary of the invention
The problem to be solved in the present invention provides a kind of black carbon powder.This black carbon powder and red, yellow, blue carbon powder are used, and not only can simplify typography, increase work efficiency, and can also reduce to print cost, adapt to the document information that needs long preservation and print needs.
Another problem that the present invention will solve provides a kind of method for preparing black carbon powder.
For addressing the above problem, the present invention takes following scheme:
Black carbon powder of the present invention is made up of the raw material of following parts by weight:
75~98 parts of resins, polypropylene wax or 1~10 part of Tissuemat E, 5~20 parts of black pigments, 0.5~10 part of charge adjusting agent, 0.1~1 part of silicon dioxide.Resin wherein is according to styrene: the binary copolymerization resin that the part by weight reaction of butyl methacrylate=4:1 forms.Said charge adjusting agent is metal salicylate chromium complex or metal azo chromium complex.
The method for preparing black carbon powder may further comprise the steps successively:
(1) earlier resin, polypropylene wax or Tissuemat E, black pigment and charge adjusting agent are put together, and mix, make compound;
(2) again compound is dropped in the extruding machine, under 116~155 ℃ temperature, extrude, and be ground into powder with the meal machine;
(3) afterwards, with the fine powder machine above-mentioned powder is ground into the flour of 3~11 μ m;
(4) last, add silicon dioxide, and mix, obtain black carbon powder.
Take such scheme, have the following advantages:
Because black carbon powder of the present invention is to make with resin, polypropylene wax or Tissuemat E, black pigment, charge adjusting agent and silicon dioxide, be used on printing machine with red, yellow, blue carbon powder, do not need chromatography on the technology, need not carry out photomechanical production, thereby simplified typography, improved work efficiency.And black carbon powder of the present invention and red, yellow, blue carbon powder are used on printer, compare with ink, can reduce to consume and use cost.And the picture and text color that prints is difficult for failing, the holding time is long, can adapt to the document information that needs long preservation and print requirement.
Embodiment
Embodiment one
Select 75 parts resin, 0.5 part polypropylene wax, 5 parts black pigment, charge adjusting agent and 0.2 part of silicon dioxide of 0.5 part.Resin wherein is according to styrene: the binary copolymerization resin that the part by weight reaction of butyl methacrylate=4:1 forms.Said charge adjusting agent is the metal salicylate chromium complex.
Earlier resin, polypropylene wax, black pigment and charge adjusting agent are poured in the mixing roll together, mixed, make compound.
Again compound is dropped in the extruding machine, under 116 ℃ temperature, extrude, and be ground into powder with the meal machine.
Afterwards, with the fine powder machine above-mentioned powder is ground into the flour of 3~11 μ m;
At last, pour above-mentioned flour into mixing roll, adding silicon dioxide also mixes, and obtains black carbon powder.
Embodiment two
Select 88 parts resin, 6.5 parts Tissuemat E, 13 parts black pigment, charge adjusting agent and 0.6 part of silicon dioxide of 5 parts.Resin wherein is according to styrene: the binary copolymerization resin that the part by weight reaction of butyl methacrylate=4:1 forms.Said charge adjusting agent is a metal azo chromium complex.
Earlier resin, Tissuemat E, black pigment and charge adjusting agent are poured in the mixing roll together, mixed, make compound.
Again compound is dropped in the extruding machine, under 135 ℃ temperature, extrude, and be ground into powder with the meal machine.
Afterwards, with the fine powder machine above-mentioned powder is ground into the flour of 3~11 μ m;
At last, pour above-mentioned flour into mixing roll, adding silicon dioxide also mixes, and obtains black carbon powder.
Embodiment three
Select 98 parts resin, 10 parts polypropylene wax, 20 parts black pigment, charge adjusting agent and 1 part of silicon dioxide of 10 parts.Resin wherein is according to styrene: the binary copolymerization resin that the part by weight reaction of butyl methacrylate=4:1 forms.Said charge adjusting agent is a metal azo chromium complex.
Earlier resin, polypropylene wax, black pigment and charge adjusting agent are poured in the mixing roll together, mixed, make compound.
Again compound is dropped in the extruding machine, under 155 ℃ temperature, extrude, and be ground into powder with the meal machine.
Afterwards, with the fine powder machine above-mentioned powder is ground into the flour of 3~11 μ m;
At last, pour above-mentioned flour into mixing roll, adding silicon dioxide also mixes, and obtains black carbon powder.

Claims (3)

1. black carbon powder is characterized in that being made up of the raw material of following parts by weight:
75~98 parts of resins, polypropylene wax or 1~10 part of Tissuemat E, 5~20 parts of black pigments, 0.5~10 part of charge adjusting agent, 0.1~1 part of silicon dioxide; Resin wherein is according to styrene: the binary copolymerization resin that the part by weight reaction of butyl methacrylate=4:1 forms.
2. black carbon powder according to claim 1 is characterized in that said charge adjusting agent is metal salicylate chromium complex or metal azo chromium complex.
3. method for preparing the described black carbon powder of claim 1 is characterized in that may further comprise the steps successively:
(1) earlier resin, polypropylene wax or Tissuemat E, black pigment and charge adjusting agent are put together, and mix, make compound;
(2) again compound is dropped in the extruding machine, under 116~155 ℃ temperature, extrude, and be ground into powder with the meal machine;
(3) afterwards, with the fine powder machine above-mentioned powder is ground into the flour of 3~11 μ m;
(4) last, add silicon dioxide, and mix, obtain black carbon powder.
CNB2006101614519A 2006-12-12 2006-12-12 Black carbon powder and method for preparing same Expired - Fee Related CN100464251C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006101614519A CN100464251C (en) 2006-12-12 2006-12-12 Black carbon powder and method for preparing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006101614519A CN100464251C (en) 2006-12-12 2006-12-12 Black carbon powder and method for preparing same

Publications (2)

Publication Number Publication Date
CN1996158A CN1996158A (en) 2007-07-11
CN100464251C true CN100464251C (en) 2009-02-25

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101122756B (en) * 2007-09-24 2010-06-02 王建新 Black ink powder and its preparation method
CN111158225A (en) * 2019-12-31 2020-05-15 珠海泽鹏打印耗材有限公司 High-definition printing carbon powder preparation process
CN111607182B (en) * 2020-06-08 2022-04-22 张家港威迪森化学有限公司 Styrene-acrylic copolymer resin composition and preparation method and application thereof
CN111607184B (en) * 2020-06-10 2022-07-05 张家港威迪森化学有限公司 Styrene-acrylic copolymer resin mixture and preparation method and application thereof
CN111574653B (en) * 2020-06-10 2023-01-03 张家港威迪森化学有限公司 Multi-component styrene-acrylic copolymer resin and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5087677A (en) * 1989-07-08 1992-02-11 Hoechst Aktiengesellschaft Process for the preparation of cycloolefin polymers
CN1474237A (en) * 2003-06-12 2004-02-11 周学良 Developer and its preparing method
CN1515634A (en) * 2003-01-11 2004-07-28 王建新 Carbon powder and its preparation method
CN1707370A (en) * 2004-06-10 2005-12-14 周学良 Red carbon powder for colour laser printer and producing method thereof
CN1706895A (en) * 2004-06-10 2005-12-14 周学良 Black toner for color laser printer and its prepn process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5087677A (en) * 1989-07-08 1992-02-11 Hoechst Aktiengesellschaft Process for the preparation of cycloolefin polymers
CN1515634A (en) * 2003-01-11 2004-07-28 王建新 Carbon powder and its preparation method
CN1474237A (en) * 2003-06-12 2004-02-11 周学良 Developer and its preparing method
CN1707370A (en) * 2004-06-10 2005-12-14 周学良 Red carbon powder for colour laser printer and producing method thereof
CN1706895A (en) * 2004-06-10 2005-12-14 周学良 Black toner for color laser printer and its prepn process

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CN1996158A (en) 2007-07-11

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EE01 Entry into force of recordation of patent licensing contract

Assignee: Wuxi Mingyi Electric Apparatus Instrument Co., Ltd.

Assignor: Wang Jianxin

Contract record no.: 2011320000868

Denomination of invention: Black powdered carbon for color copier and its preparing process

Granted publication date: 20090225

License type: Exclusive License

Open date: 20070711

Record date: 20110621

EC01 Cancellation of recordation of patent licensing contract

Assignee: Wuxi Mingyi Electric Apparatus Instrument Co., Ltd.

Assignor: Wang Jianxin

Contract record no.: 2011320000868

Date of cancellation: 20110914

EE01 Entry into force of recordation of patent licensing contract

Assignee: Wuxi Research Institute of Daily Chemical Products

Assignor: Wang Jianxin

Contract record no.: 2011320001115

Denomination of invention: Black powdered carbon for color copier and its preparing process

Granted publication date: 20090225

License type: Exclusive License

Open date: 20070711

Record date: 20110914

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090225

Termination date: 20151212

EXPY Termination of patent right or utility model