CN101014695B - Cleaning implement - Google Patents
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- CN101014695B CN101014695B CN200580029970.3A CN200580029970A CN101014695B CN 101014695 B CN101014695 B CN 101014695B CN 200580029970 A CN200580029970 A CN 200580029970A CN 101014695 B CN101014695 B CN 101014695B
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Abstract
A dry-type cleaning tool for use indoors having a fibrous base material, which is imparted with an antigenicity reducing composition containing an antigenicity reducing component for reducing the antigenicity of a substance inducing allergy, an oil agent and a surfactant is imparted. Preferably, the antigenicity-reducing component is an extract of an Olea or a Ligustrum plant extracted with wateror an organic solvent.
Description
Technical field
The present invention relates to a kind of burnisher that comprises fibrous substrate.More particularly, the present invention relates to a kind of antigenic burnisher that can reduce the material that causes allergic reaction.
The application requires the right of priority of following application: Japanese patent application 2004-262896 (September 9 2004 applying date); Japanese patent application 2004-262897 (September 9 2004 applying date); Japanese patent application 2004-341804 (November 26 2004 applying date); Japanese patent application 2004-358952 (December 10 2004 applying date) is incorporated herein by reference in this content with these applications.
Background technology
In recent years, suffer from anaphylactic disease for example the number of allergic rhinitis and bronchial asthma in stable increase.The material that causes anaphylaxis is called as sensibiligen, has had been found that about 200 kinds now.Acarid, dead acarid part, pet hair and pollen are typical examples.Through with Body contact or get into body interior, these materials can produce various anaphylaxis.
In these materials, removing to kill the material that acarid etc. can cause allergic reaction with chemical etc. is not a terms of settlement completely, this be because dead acarid part also be have antigenic.Therefore, in order to reduce anaphylaxis and to prevent to produce new susceptibility, thereby this just needs from the living space, to remove up hill and dale sensibiligen or reduces the antigenicity of the material that causes allergic reaction through sensibiligen etc. being carried out sex change etc.
The disclosed example that can reduce antigenic medicament of the material that causes allergic reaction as stated comprises the allergen inactivator (the open 2003-55122 of Japanese patent application is called patent documentation 1 at this) for preparing from Fructus oleae europaeae (Olea europaea) and/or philharmonic water La Shu (Ligustrum obtusifolium).
Also have; Also disclose with aqueous form and used or be distributed to the sensibiligen depressant on floor, carpet and the car mat; They are to contain Tai-Ace S 150 and the sodium sulfate aqueous solution (the open 2003-334240 of Japanese patent application, this paper is called patent documentation 2) as activeconstituents.
When using burnisher for example dust removing cloth (dust cloths), mop and rag are removed indoor dust and particle, in cleaning course, sensibiligen will be attached on the burnisher and will on burnisher, be kept for some time.As stated, in order to reduce or to prevent allergenic response, just need to reduce the antigenicity of the sensibiligen on the burnisher.
But the place that possibly follow health directly to contact, for example car mat, carpet, floor and clothes are all directly used or be distributed to the medicament in the patent documentation 1 and 2.This just need wipe after using or remove the medicament of being used with vacuum cleaner, and this can cause burden to the user.For frequent cleaning dust and particulate floor and furniture, also how research does not remove sensibiligen reduction material easily.Also have, because traditional method needs the moistening object that is cleaned, this just need carry out drying to this object.Also do not report the cleaning method of doing that is used to reduce the allergen-induced material.And, do not have about how reducing the report of the antigenic research that is collected in the allergen-induced material that dried burnisher for example comprised in the dust in the mop and the particle yet.
More particularly, the indoor cleaning instrument of doing, promptly disposable and the interchangeable and burnisher that is substantially devoid of moisture that be equipped with the fibrous substrate of sheet or Brush Shapes receives welcome widely on market.A requirement for these burnishers of doing is that antigenicity reduction compsn must be able to be attached on the fibrous substrate and can be penetrated in the fibrous substrate, and said composition must be minimum to the transfer of the object that is cleaned.
Summary of the invention
An object of the present invention is to overcome these problems and a kind of antigenic burnisher that can reduce the allergen-induced material of being attached on the burnisher is provided.
In order to overcome above-mentioned problem, contriver of the present invention has carried out careful research, discovery can through to contain finish (lubricant) thus the administered antigenicity of predetermined compound reduce composition and solve the above problems, thereby also obtained the present invention.More particularly, the invention provides following technical scheme.
(1) a kind of burnisher that is used for indoor cleaning comprises: a kind of dried fibrous substrate; A kind of antigenic antigenicity reduction composition that is used to reduce the allergy-induced material; With a kind of finish.
Contain the antigenicity reduction compsn that antigenicity reduces composition because burnisher has used, so burnisher can reduce the antigenicity of the hypersensitive response elicitor matter of being attached on the burnisher.In addition, reducing antigenicity reduction composition and finish also can be administered on " dry type " fibrous substrate at an easy rate.And, use every kind of composition through reducing, can prevent that every kind of composition is from the transfer of fibrous substrate to the object that is cleaned in use.
In the present invention, " dry type " burnisher refers to the ratio (weight) of the finish that is contained than washy burnisher, and wherein suitable moisture ratio is 5% or still less.Moisture must be dissolved in the finish.If finish is by emulsive, then its dust capacity gauge will descend, and makes that it no longer is needed.
(2) according to the burnisher with fibrous substrate of (1), comprising: the first step fibrous substrate that obtains through administration of antigens property reduction composition; With through using the second stage fibrous substrate that finish obtains.
Wherein, provide antigenicity to reduce composition or finish to each fibrous substrate respectively, there is no need to mix in advance every kind of composition.Therefore, every kind of composition can be administered on the burnisher equably, even might can not mix with finish equably by antigenicity reduction composition.
(3) according to the burnisher with fibrous substrate of (1), comprising: the first step fibrous substrate that obtains through administration of antigens property reduction composition; With through using the second stage fibrous substrate that finish obtains, wherein these fibers mix.
In this case, provide antigenicity to reduce composition, there is no need to mix in advance every kind of composition to each fiber.Therefore, every kind of composition can be administered on the burnisher equably, even might can not mix with finish equably by antigenicity reduction composition.
(4) any one burnisher in above-mentioned (1)-(3); Wherein, Said fibrous substrate with respect to 100 mass parts; Said antigenicity is lowered into and is divided into more than or equal to 0.001 mass parts and smaller or equal to 10 mass parts with respect to the said fibrous substrate of 100 mass parts, described finish is more than or equal to 0.001 mass parts with smaller or equal to 15 mass parts.
According to such ratio, stick ability through the dust that utilizes fibrous substrate itself and finish and just can collect dust.And antigenicity reduces the antigenicity that compsn can also reduce the allergy-induced material that is included in the collected dust.
(5) any one burnisher in above-mentioned (1)-(4), wherein to reduce composition be aqueous or hydrophilic and any one burnisher in (6) above-mentioned (1)-(5) in addition to antigenicity, wherein to reduce composition be the plant milk extract composition to antigenicity.
In these cases, antigenicity reduces composition and is aqueous or hydrophilic or derives from plant, is high safety to the people therefore.
(7) any one burnisher in above-mentioned (1)-(6), it is the extract that water or organic solvent extract from Olea or ligustrum plant that wherein said antigenicity reduces composition.
In this case, reduce performance from Olea or ligustrum plant, therefore use amount seldom just can reduce antigenicity because the extract (hereinafter being called Fructus Canrii Albi extract) that water or organic solvent extract has excellent antigenicity.And it is coloured that the antigenicity of the plant origin that some are traditional reduces composition itself, therefore possibly cause the variable color of substrate material in use.But because Fructus Canrii Albi extract itself is xanchromatic or yellowish brown, but when diluted and when being applied on the fibrous substrate, what it will become is transparent basically, so can avoid the substrate material variable color.
(8) any one burnisher in above-mentioned (1)-(7), wherein antigenicity reduction layer branch is Oleuropein.
The Oleuropein that here uses is a large amount of phenols secoiridoid glycoside compounds that exist in Olea or ligustrum plant.Therefore these secoiridoid glycoside compounds contain formyl radical and hydroxyl, thereby think that they can combine to reduce antigenicity with the amino group that contained in the allergenic protein.
(9) burnisher of above-mentioned (7) or (8), wherein fibrous substrate is white.
In this case, because the color of above-mentioned Fructus Canrii Albi extract and Oleuropein is very light, therefore do not have the problem that makes the fibrous substrate variable color.Therefore, can use the fibrous substrate of white like before, thereby can see institute's adherent dust and particle at an easy rate.
(10) any one burnisher in above-mentioned (1)-(9), wherein finish is any one burnisher in dust adhesion type finish and (11) above-mentioned (1)-(10), wherein said finish is a MO.
Through using dust adhesion type finish or MO can prevent effectively that as finish antigenicity from reducing compsn and leaving or be transferred on the object that is cleaned from separating as the fibrous substrate on the subject.And the dust capacity gauge also has enhancing, and can prevent collecting dropping of dust afterwards.
(12) burnisher of above-mentioned (11), wherein said mineral oil viscosity is more than or equal to 10mm at 30 ℃
2/ s and smaller or equal to 200mm
2/ s.
Preferably, wherein said mineral oil viscosity is more than or equal to 10mm at 30 ℃
2/ s and smaller or equal to 200mm
2/ s.More preferably, wherein said mineral oil viscosity is more than or equal to 15mm at 30 ℃
2/ s and smaller or equal to 120mm
2/ s.If viscosity is less than 10mm
2/ s, said composition possibly too much transferred on the object that is cleaned and is attached on hand.If viscosity surpasses 200mm
2/ s, then the ability of sticking to dust will descend.
The present invention provides a kind of antigenic burnisher that can reduce the hypersensitive response elicitor matter of being attached on the burnisher.
Description of drawings
Fig. 1 is an exploded view as the burnisher of example of the present invention.
Fig. 2 is the decomposition diagram of the fibrous substrate of Fig. 1.
Fig. 3 is the skeleton view as an other example of burnisher of the present invention.
Fig. 4 is the skeleton view as an other example of burnisher of the present invention.
Embodiment
The antigenicity reduction compsn that is applied on the burnisher of the present invention comprises: antigenic antigenicity that (a) can reduce hypersensitive response elicitor matter reduces composition; (b) finish.Antigenicity is reduced composition to the form that can be in advance reduces compsn with antigenicity and finish mixes.A kind of in addition selection is that antigenicity reduction composition and finish are administered to respectively, and each fiber is tied or each fiber.To introduce these composition components below.
Antigenicity reduces composition
" the antigenicity reduction composition " that the present invention uses thus be to suppress anaphylaxis through the antigenicity that reduces hypersensitive response elicitor matter.Preferably, said composition is the composition of plant origin.Hypersensitive response elicitor matter (sensibiligen) can be that the sensibiligen that for example can suck is pollen, acarid, dust within doors, animal, fungi (mould) and the insect of cdear pollen, grass for example.
Reduce composition for employed concrete antigenicity and have no particular limits, for example can be: Fructus Canrii Albi extract, glossy privet extract, Punica granatum L. extract, neem extract, persimmon extract, tea extract, bamboo extractive, Folium perillae extract, Folium Menthae extract, Japanese cypress (Chamaecyparis obtusa) extract, Thujopsis dolabrata (Thujopsis dolabrata) extract, eucalyptus extracts, tea tree extract etc.The example that extracts compound comprises: Weibull, gallic acid etc.Other example comprises: high-molecular weight compounds, and wherein the side chain of linear high molecular weight repeating unit comprises unit price or phenolic groups more at high price, for example gathers (right-vinylphenol); High-molecular weight compounds, wherein the side chain of linear high molecular weight repeating unit comprises monovalent phenolic groups, for example two oxybenzoic acid polymkeric substance; Polyoxyethylene chain is lauryl diphenyl ether disulfonic acid disodium and/or divalence or more high price and Phenylsulfonic acid that in its molecule, comprise the ethylidene chain for example; And/or hydroxy-benzoic acid for example divalence or more high price and the sulfuric acid that in its molecule, comprises the ethylidene chain; Hydroxy-benzoic acid for example 2,5-resorcylic acid etc.; Aromatic hydroxy compound; Alkaline carbonate; Alum; The lauryl Phenylsulfonic acid; Lauryl sulfate; The polyoxyethylene lauryl ether sulfuric ester; Phosphoric acid salt or ester; Zinc sulfate and/or sugar of lead etc.
In mentioned component, preferred antigens property reduction composition is based on Fructus Canrii Albi extract." Fructus Canrii Albi extract " of the present invention is meant the extract that water or organic solvent extract from Olea or ligustrum plant.And preferred antigens property reduction composition is an Oleuropein.Oleuropein is the secoiridoid glycoside compound.Therefore these secoiridoid glycoside compounds contain formyl radical and hydroxyl, thereby think that they can combine to reduce antigenicity with the amino group that contained in the allergenic protein.Pointed out a kind of example of concrete Fructus Canrii Albi extract in the above-mentioned patent documentation 1.
And, thereby think that hydroxyl and the bonding of amino in the allergenic protein or peptide moiety that Weibull passes through in the polyphenyl phenol have reduced antigenicity.
Above-mentioned antigens property reduction composition can be prepared to independent composition to be administered on the burnisher, perhaps is prepared to the solution form (antigenicity depressant hereinafter referred to as) that contains activeconstituents such as Oleuropein, its liquid extract etc.Above-mentioned Fructus Canrii Albi extract is exactly the example of an antigenicity depressant.In the antigenicity depressant, except Oleuropein, can also comprise water and ethanol.
Finish
" finish " of the present invention is used to increase to dust and particulate absorption and keeps.Type for finish has no particular limits, but preferably includes at least a in the following substances: MO, synthetic oil, silicone oil and vegetables oil.The example of MO comprises straight chain hydrocarbon, naphthenic hydrocarbon and aromatic hydrocarbon.These finishes can use separately, perhaps two kinds or more kinds ofly mix use.
Wherein, preferably use the staple of whiteruss as finish, this is because the antigenicity reduction composition and the finish that can prevent to be applied on the fibrous substrate disintegrate down and prevent to be obtained by the object that is cleaned from burnisher.
Other composition
Except antigenicity reduces composition and finish, also can other composition be used on the burnisher of the present invention, as long as they can not change the characteristic of burnisher of the present invention significantly.The composition that can in the preparation antigenicity reduces the process of compsn, add other also can reduce composition and finish is used other composition to burnisher separately with respect to antigenicity.
The example of other composition except antigenicity reduces composition and finish is a tensio-active agent.The adding of " tensio-active agent " of the present invention is in order more easily antigenicity to be reduced composition and finish is administered on the burnisher and in order to use more equably.The preferred nonionic surfactant that uses.Tensio-active agent has been arranged, and antigenicity reduces composition and just can stably mix with finish.
Have no particular limits for nonionic surfactant, but the example of preferred Voranol EP 2001 comprises: polyoxyethylene lauryl ether; T 46155 spermaceti base ether; Polyoxyethylene oleyl ether; The hard ester group ether of T 46155.The example of preferred sorb sugar ester comprises: sorbose LAURIC ACID 99 MIN monoesters; Sorbose palmitinic acid monoesters; The hard ester acid monoester of sorbose; The sorbose oleic acid monoester.Preferred glycerol fatty acid ester comprises: glyceryl list myristinate; The glyceryl single-hard ester acid ester; Glycerin mono-fatty acid ester; Glyceryl list iso stearate ester; The glyceryl dioleate.The example of preferred plants oil comprises: Jojoba oil; Lipoval A; Sweet oil; Prunus amygdalus oil; Raisin seed oil; Thistle oil and sunflower oil.The example of sorbose trioleate comprises: the hard ester acid of sorbose three esters; Sorbose oleic acid three esters.The adducts of preferred ethylene oxide (EO) and Viscotrol C or THIXCIN comprises: Polyoxyethylene hydrogenates the Oleum Ricini; The LAURIC ACID 99 MIN Polyoxyethylene hydrogenates the Oleum Ricini; Single iso stearate Polyoxyethylene hydrogenates the Oleum Ricini.These tensio-active agents can use separately, perhaps two kinds or more kinds ofly mix use.
The preparation antigenicity reduces compsn
With conventional known method above-mentioned composition mixing/vibration is reduced compsn to form antigenicity.Reduce compsn with respect to antigenicity, two kinds of neccessary compositions, promptly antigenicity reduce composition and finish ratio preferably: be no less than 0.01% quality and be not more than the antigenicity reduction composition of 50% quality; Be no less than 50% quality and be not more than the finish of 99% quality.More preferably, the antigenicity that is no less than 0.02% quality and is not more than 10% quality is lowered into; Be no less than 6% quality and be not more than the finish of 95 quality
Owing to can not reduce collected particulate antigenicity fully, therefore preferably not use the antigenicity that is less than 0.01% quality to reduce composition.If ratio is greater than 50% quality, then along with the increase of time, antigenicity reduces compsn and becomes unstable, and cost increases.
Because finish can not provide enough dust and particulate adherent are improved, it is not preferred therefore using the finish that is less than 50% quality.If the ratio of finish is greater than 99% quality, then along with the increase of time, antigenicity reduces compsn and becomes unstable, and is therefore also not preferred.
When on burnisher, using the antigenicity reduction compsn that comprises antigenicity reduction composition, finish and tensio-active agent, reduce compsn with respect to whole antigenicity, preferred ratio is: the antigenicity of 0.01-10% quality reduces composition; The tensio-active agent of the finish of 50-95% quality and 1-49.99% quality.More preferably: the antigenicity of 0.02-1% quality reduces composition; The tensio-active agent of the finish of 60-79.98% quality and 20-40% quality.
Because antigenic reduction is inadequate to collected particulate; Therefore when on burnisher, using the antigenicity reduction compsn that comprises antigenicity reduction composition, finish and tensio-active agent, it is not preferred using the antigenicity that is less than 0.01% quality to reduce composition.If ratio is greater than 10% quality, then along with the increase of time, antigenicity reduces compsn and becomes unstable, and cost increases.
When on burnisher, using the antigenicity reduction compsn that comprises antigenicity reduction composition, finish and tensio-active agent; Because finish can not provide enough dust and particulate adherent are improved, it is not preferred therefore using the finish that is less than 50% quality.If the ratio of finish is greater than 95% quality, then along with the increase of time, antigenicity reduces compsn and becomes unstable, and is therefore also not preferred.
It is not preferred that antigenicity reduction compsn uses the tensio-active agent that is less than 1% quality, because become unstable along with time increase antigenicity reduces compsn.Ratio greater than 50% quality is not preferred yet, because the finish antigenicity that can cause adding reduces.
When on burnisher, using the antigenicity reduction compsn that comprises antigenicity reduction composition, finish and tensio-active agent, the ratio that the preferred antigenicity of using reduces compsn accounts for the 1-15% quality of whole fibrous substrate.Reduce compsn through using the antigenicity that accounts for whole fibrous substrate 1% quality, just can provide enough antigenicities to reduce.Because it is the 0.001-1.5% quality that the antigenicity that need add reduces composition, therefore only need reduce the antigenicity reduction composition that comprises very small amount in the compsn in antigenicity just can provide suitable effect.
Account for 15% or still less as long as make antigenicity reduce compsn with respect to whole fibrous substrate, will prevent because excessive transfer of sticking antigenicity reduction compsn that antigenic composition causes to the object that is cleaned.
Burnisher
To introduce the burnisher that reduces the subject of compsn as above-mentioned antigenicity below.So long as the burnisher of " dry type ", the indoor cleaning instrument that promptly has the fibrous substrate that is substantially free of water gets final product, and burnisher is had no particular limits.For example, burnisher is laminar, and perhaps this thin slice is cut into strip, or is formed by multi-thread type element, or a bundle fiber (fiber assembly).Burnisher can be the instrument with fibrous substrate and handle, for example mop.Also have no particular limits for fibrous substrate, wherein fibrous substrate can be prepared by natural fiber, synthon or semi-synthetic fibre.And to the also not restriction of shape of fiber, wherein fiber can be weaving, braiding or nonwoven.
The instance of burnisher
Fig. 1 and Fig. 2 show the instance of such burnisher.Fig. 1 is the exploded view of burnisher.Fig. 2 is the decomposition diagram from the cleaned slice of Fig. 1.Burnisher 10 is a kind of " handheld " burnishers, and it is by forming like lower component: cleaned slice 11, and it is corresponding to fibrous substrate of the present invention; With grasping tool 12.Grasping tool 12 can be replaced.For example, can be mounted grasping tool shown in Figure 3 22 so that the burnisher among Fig. 1 can use in the high local or narrow place that is difficult to get at.
As shown in Figure 2, from topmost saying, cleaned slice 11 comprises following each layer: keep thin slice 1, it is processed by non-woven fabrics, and is cut into a plurality of bands in order; Substrate material thin slice 2 also is to be processed by the non-woven fabrics that is cut into a plurality of bands; First fiber is tied 3a, and it is by a branch of fibroplastic; Tie 3b by a branch of fibroplastic second fiber; Tie 3c by a branch of fibroplastic the 3rd fiber; Tie 3d by a branch of fibroplastic the 4th fiber; With band thin slice 5, a plurality of bands have wherein been formed.In this embodiment, first fiber is tied 3a, and second fiber is tied 3b, and the 3rd fiber is tied 3c and the 4th fiber and tied 3d and formed brush part of the present invention.Therefore, this brush part provides more effective cleaning.Because only need antigenicity be lowered into branch is administered to this brush part, so antigenicity reduction composition can more effectively be used." brush part " implication herein is to carry out the part of the main cleaning function of burnisher of the present invention.Brush part can be the part of fibrous substrate or they are whole.Keeping thin slice 1, substrate material thin slice 2, first fiber ties 3a, second fiber and ties 3b, the 3rd fiber and tie 3c, the 4th fiber and tie 3d and band thin slice 5 all are bonded to together at lamella joint line 6 places together.At joint line 7 places, the thin slice 1 of only withing a hook at the end, substrate material thin slice 2, first fiber are tied 3a, second fiber is tied 3b and is bonded to together.The result is, formed grasping part 13 keeping between thin slice 1 and the substrate material 2, makes it possible to insert and install grasping tool 12.In " handheld " burnisher 10 and 20 of these types, preferred only antigenicity be lowered into branch and be administered to and tie by first fiber that 3a, second fiber tie 3b, 3c tied by the 3rd fiber and the 4th fiber is tied the brush part of the present invention that 3d forms.
The another example of burnisher
Fig. 4 shows the another example of burnisher, and it is the ground template burnisher 30 that is suitable for cleaning the floor.As shown in Figure 4, in this burnisher 30, corresponding to the terminal 32a of the cleaned slice of fibrous substrate of the present invention 31 parcel grasping tools 32 and be used.Formed the projection 33 that forms by fibrous bundle (fiber in groups) in the front and back of cleaned slice 31.This just makes and is easy to for example groove of the very difficult place of cleaning of Clean-flat burnisher.Through simply burnisher 30 being contacted with floor etc., cleaned slice 31 just can collecting granules etc.The template cleaning discloses in 30 on such ground, preferably antigenicity is reduced compsn and is administered to whole cleaned slice 31.
Using on burnisher
Antigenicity is reduced compsn be administered to method on the above-mentioned burnisher and comprise spraying or antigenicity being reduced compsn and be rolled onto on the fibrous substrate, perhaps soak etc., but the present invention is not limited to these methods.
In " handheld " burnisher as shown in Figure 1, preferably to be not less than 0.001% quality with respect to whole fibrous substrate with ratio and to be not more than 10% quality administration of antigens property reduction compsn.If the ratio of using just can not be picked up dust particle fully less than 0.001% quality.If ratio is more than or equal to 10%, then compsn will too much be transferred to the object that is cleaned, but also can be transferred on hand, causes a kind of adhesion sense.But, in ground template burnisher as shown in Figure 4, preferably use more a little compsn, promptly account for the compsn of 3% to 15% quality of whole fibrous substrate, more preferably use the compsn of 0.01-15% quality.If the amount of using is less than 0.01%, dust particle just can not picked up completely.If ratio is more than or equal to 15%, then compsn will too much be transferred to the object that is cleaned, but also can be transferred on hand, causes a kind of adhesion sense.Therefore, it should be to be not less than 0.001% quality and to be not more than 10% quality that antigenicity reduces components in proportions, and the antigenicity of very small amount reduction composition just can be effective.
In addition, antigenicity reduction composition can separately use with finish.In this case, can comprise fiber production step and burnisher production stage administration of antigens property reduction composition and finish at each manufacturing step.For example, step comprises: (1) fiber production step, and wherein in described fiber production method, make fibre finishing (tensio-active agent etc.) and antigen reduce composition and mix, after drying, use finish; (2) fiber production step wherein makes fibre finishing (tensio-active agent etc.) and antigen reduce composition in described fiber production method and mixes, and in the burnisher manufacturing step, uses finish; (3) burnisher production stage is wherein produced antigen and is reduced composition, uses finish then.
In addition, can be in the burnisher production stage antigenicity be lowered into branch and be administered to that each fiber is tied or each fiber.Be administered to each fiber and tie if antigenicity is lowered into branch; With reference to above-mentioned burnisher for example shown in Figure 2; Just can produce burnisher by above-mentioned method; Be about to antigenicity and be lowered into branch and be administered to first fiber and tie 3a, finish is administered to second fiber is tied 3b and the 3rd fiber is tied 3c, and antigenicity is lowered into branch is administered to the 4th fiber and ties 3d.
When antigenicity being lowered into branch and being administered in each fiber, contain first fiber that antigenicity reduces composition and be combined together to form a fiber with second fiber that contains finish and tie.Afterwards, tie the production burnisher with such fiber again.
Antigenicity reduces the application process of composition and finish, like sprinkling, roller coat and immersion, all is similar to the method for administration of antigens property reduction compound, although method is not limited to aforesaid method.But when antigenicity reduced composition and finish and uses separately, the preferred amount of using still dropped within the scope of administration of antigens property reduction compsn.
When using the antigenicity reduction compsn that comprises antigenicity reduction composition, finish and tensio-active agent to " handheld " burnisher as shown in Figure 1; The amount of application of preferred antigens property reduction compsn is; With respect to whole fibrous substrate, account for the 1-10% quality.It is not preferred using the antigenicity reduction compsn that is less than 1% quality, and this is because it can not pick up dust particle fully.Be transferred to the object that is cleaned and on hand if amount of application, then has too much compsn greater than 10% quality, cause a kind of adhesion sense.
When using to as shown in Figure 4 " template " burnisher when comprising antigenicity that antigenicity reduces composition, finish and tensio-active agent and reducing compsn; Preferably use more a little compsn; The amount of application that is antigenicity reduction compsn is; With respect to whole fibrous substrate, account for the 3-15% quality.More preferably 3-10% quality.If the amount of being used is that to be in be in described scope, then reduces compsn and be transferred to the object that is cleaned than being easier at least a portion antigenicity.The result is, the antigenicity reduction ability of above-mentioned burnisher strengthens, and is transferred to simultaneously and is left on antigenicity on the object that is cleaned to reduce composition and also can reduce antigenicity.Therefore, itself also can reduce antigenicity the object that is cleaned.And, because the oil that antigenicity reduces in the composition is transferred to the object surfaces that is cleaned, returns floor surface and played wax.Therefore, this arrangement is suitable for ground template instrument.If the amount of the compsn of being used is less than 3% quality, the dust particle instrument that just can not be cleaned is collected completely.And it also is insufficient to the transfer of the object that is cleaned that antigenicity reduces compsn.If the amount of being used is greater than 15%, it is exactly excessive to the transfer of the object that is cleaned that antigenicity reduces compsn.And compsn can be transferred to and produce a kind of adhesion sense on hand.
Embodiment
To use embodiment and comparative example to describe the present invention in detail below.But the present invention is not limited to following described embodiment.
First to the 3rd embodiment and first comparative example
Preparation contains the antigenicity reduction medicament that antigenicity reduces composition
Fructus Canrii Albi extract
The 3rd embodiment (the fresh olive leaf of 20 grams is put into 100 gram water, use mixer mixing, filter then) water according to patent documentation 1 extracts from the olive leaf.Then, add the liquid Fructus Canrii Albi extract that ethanol preparation contains 0.6% Oleuropein.
The solution that contains Weibull
Weibull (from Wako Pure Chemical Industries, Ltd.) is dissolved in water and the ethanol Weibull of preparation 15%.
Antigenicity reduces preparation of compositions
Use two kinds of above-mentioned antigenicities to reduce composition and whiteruss, according to shown mixed of table 1 and stirred solution embodiment 1-3.And, also prepared a solution embodiment 4 who only contains the compsn of whiteruss.
Table 1
Antigenicity reduces the content (unit: % weight) of compsn
Note 1) (solution that contains Weibull): Weibull (from Wako Pure ChemicalIndustries, Ltd.) is dissolved in water and the ethanol Weibull of preparation 15%.
(Fructus Canrii Albi extract): from the olive leaf, extract according to patent documentation 1 the 3rd compound embodiment water.Then, add ethanol and contain 0.6% Oleuropein to be adjusted to.
Note 2) 30 ℃ of 50mm
2The viscosity of/s.
Antigenicity is reduced compsn to be administered on the burnisher
Next, antigenicity reduces composition solution embodiment 1-3 and composition solution embodiment 4 and is sprayed to (hereinafter referred to as " handheld ") on the burnisher as shown in Figure 1 and burnisher as shown in Figure 4 (hereinafter referred to as " template ").For every type, first to the 3rd burnisher embodiment (having used the compsn of solution embodiment 1-3 on the burnisher) and first comparative example (having used the compsn of solution embodiment 4 on the instrument) have all been done.
For handheld instrument,, used the compsn of 5% quality with respect to whole fibrous substrate (being the thin slice 11 among Fig. 1).For ground template instrument, the antigenicity of having used 7.5% quality with respect to whole fibrous substrate (thin slice 31 among Fig. 4) reduces compsn.
Evaluation test
Evaluation test 1: antigenicity reduces to be estimated
Estimated the performance of first, second, third and first comparative example according to following flow process for the antigenicity reduction of cdear pollen and dust acarid.The result is shown in table 2 and 3.In these tables; Reduced rate is to confirm like this: 100-100 * (from having used the volume of sensibiligen that antigenicity reduces the burnisher of medicament; Quantitative with the ELISA method)/(from the sensibiligen volume that does not have administration of antigens property reduction medicament, the ELISA method is quantitative).The reduced rate that symbology in the table is following:
Circle: good reduced rate (50% or more)
Trilateral: medium reduced rate (10-50%)
X: the reduced rate (0-10%) of difference.
Handheld: the rubbish that will contain about 0.05g acarid sensibiligen (dust acarid) and about 0.01g cdear pollen are placed in 9 centimetres of diameters and the high 17 centimetres vial.Give the bottle cap upper cover, rubbish and cdear pollen are distributed in the whole bottle.Remove lid, wipe rubbish and cdear pollen with handheld instrument.On burnisher, use and extract solution extraction sensibiligen, and sensibiligen is carried out quantitatively with the ELISA method.
The ground template: the rubbish that will contain about 0.05g acarid sensibiligen (dust acarid) is placed on the board of 30 centimetres of about 30 cm x with about 0.01g cdear pollen.Land used template burnisher is wiped rubbish and cdear pollen.On burnisher, use and extract solution to extract sensibiligen.With the ELISA method sensibiligen is carried out quantitatively.
Use phosphoric acid buffer agent (pH7) as extracting solution.And ELISA method (Enzyme Linked Immunoadsorbent Assay) is a kind of quantivative approach.EIA (enzyme immunoassay) produces the enzyme change in color when having utilized antigen antibody reaction.Particularly, use the sandwich method, wherein used two kinds of objects that the antibody clamping is to be detected.
Table 2
Cdear pollen-antigen property reduced rate
Table 3
Acarid antigenicity reduced rate
Result based on above-mentioned table 2 and table 3 can find out, reduces compsn for each antigenicity, and the ground template burnisher of first to the 3rd embodiment all shows the antigenicity of reduction.For handheld burnisher, but not have that not have many because the antigenicity used reduces the amount of composition, so effect is also weaker.
Evaluation test 2: estimate the reduction situation after the contact light and heat
Heating test: for the burnisher in the second and the 3rd embodiment, the fibrous substrate of handheld burnisher itself is placed in the shell of papery and is capped, and for ground template burnisher, with a pillow type shell covering of processing with film.This packing is placed in the room, avoids the direct sunshine photograph, places the thermostatic chamber of 40 ℃ and 50 ℃.Then, after one month, measure sensibiligen with method same in the evaluation test 1.
Illumination is tested: for handheld and ground template burnisher, thin slice is not packed, with the xenon lamp irradiation, made to be equivalent to shine 1 month and 6 months under the daylight.Method allergy test with same in the evaluation test is former.
The result is as shown in table 4, and the implication of reduced rate and relevant symbol is with table 2 and 3.For the burnisher of two kind second and the 3rd embodiment, after heating one month, reduced rate is still kept.After the sun exposure, reduced rate is also kept.
Table 4
Acarid antigenicity reduced rate
The the 4th to the 6th embodiment and second comparative example
The antigenicity reduction composition that is included in the antigenicity reduction compsn is applied on the 4th to the 6th embodiment and second comparative example's the fibrous substrate.Details is following.
Two kinds of antigenicities that use is used for first to the 4th embodiment and first comparative example reduce medicament, prepare antigenicity according to the ratio in the table 5 and reduce preparation embodiment 5-7.And preparation embodiment 8 does not contain the compsn that antigenicity reduces composition.
Use whiteruss and/or Thistle oil as finish.Tensio-active agent is following at least a: Voranol EP 2001, sorbose monooleate, single iso stearate glyceryl ester, sorbose oleic acid three esters and Polyoxyethylene hydrogenates the Oleum Ricini.In addition, mix with water and vibrate and reduce compsn with the preparation antigenicity.
Table 5 antigenicity reduces the content (unit: % weight) of compsn
Note 1) (solution that contains Weibull): (Wako Pure ChemicalIndustries Ltd.) is dissolved in water and the ethanol Weibull to prepare 15% to Weibull.
(Fructus Canrii Albi extract): from olive leaf, extract according to patent documentation 1 the 3rd compound embodiment water.Add ethanol and obtain containing 0.6% olive bitter principle with adjustment.
Note 2) it is 5 moles to the EO of Voranol EP 2001 addition.Carbonatoms is 12-14 in the alkyl.
Note 3) 30 ℃ of 50mm
2The viscosity of/s.
Note 4) the EO addition in Polyoxyethylene hydrogenates the Oleum Ricini is 60 moles.
Note 5) it is 3 moles to the EO of Voranol EP 2001 addition.Carbonatoms in the alkyl group is 12-14.
To burnisher administration of antigens property reduction compsn
Next, antigenicity reduces composition solution embodiment 5-7 and composition solution embodiment 8 and is sprayed to burnisher shown in Figure 1 (hereinafter referred to as " handheld ") and burnisher shown in Figure 4 (hereinafter referred to as " template ").The the 4th to the 6th burnisher embodiment (having used the instrument of solution embodiment 5-7) and second comparative example (having used the instrument of solution embodiment 8) have been obtained.
For handheld instrument,, used the compsn of 5% quality with respect to whole fibrous substrate (being the thin slice 11 among Fig. 1).For ground template instrument, the antigenicity of having used 7.5% quality with respect to whole fibrous substrate (thin slice 31 among Fig. 4) reduces compsn.
Evaluation test
Evaluation test 1: antigenicity reduces performance evaluation
Estimated the performance of the 4th, the 5th, the 6th and second comparative example according to above-mentioned identical flow process for the antigenicity reduction of cdear pollen and dust acarid.The result is shown in table 6 and 7.
Table 6
Cdear pollen-antigen property reduced rate
Table 7
Acarid antigenicity reduced rate
Result based on above-mentioned table 6 and table 7 can find out, reduces compsn for each antigenicity, and the ground template burnisher of the 4th to the 6th embodiment all shows the reduction antigenicity.For the handheld burnisher of the 5th embodiment, but not have that not have many because the antigenicity used reduces the amount of composition, so effect is also weaker.
Evaluation test 2: estimate the reduction situation after the contact light and heat
The heating test: for burnisher in the 5th and the 6th embodiment, according to above-mentioned same flow process, fibrous substrate is capped and stays within, and estimates equally by evaluation test 2.
The result is as shown in table 8, and the implication of reduced rate and relevant symbol is with table 6 and 7.For the burnisher of two kind the 5th and the 6th embodiment, after heating one month, reduced rate is still kept.After the sun exposure, reduced rate is also kept.
Table 8
Acarid antigenicity reduced rate
Industrial applicibility
The present invention is suitable for as the indoor cleaning instrument that contains fibrous substrate.
Claims (5)
1. burnisher that is used for indoor cleaning, said burnisher comprises dried fibrous substrate, wherein
The antigenic antigenicity that is used to reduce hypersensitive response elicitor matter reduces composition and finish is administered to said fibrous substrate; It is Oleuropein that wherein said antigenicity reduces composition; And wherein, with respect to the said fibrous substrate of 100 mass parts, said antigenicity is lowered into and is divided into more than or equal to 0.001 mass parts and smaller or equal to 10 mass parts; With the said fibrous substrate with respect to 100 mass parts, described finish is more than or equal to 0.001 mass parts and smaller or equal to 15 mass parts;
Said fibrous substrate is through the substrate material thin slice that piles up the reservation thin slice processed by the non-woven fabrics that cuts into a plurality of bands, processed by the non-woven fabrics that cuts into a plurality of bands, uses first fiber that described antigenicity reduces composition and tie, use second fiber of described finish and tie, use the 3rd fiber of described finish and tie, use the 4th fiber that described antigenicity reduces composition and tie and wherein formed the band thin slice of a plurality of bands and constitute, and following characteristic wherein is provided:
Thin slice, substrate material thin slice, first fiber are tied, second fiber is tied, the 3rd fiber is tied, the 4th fiber is tied and the lamella joint line of band thin slice in conjunction with keeping;
Only combine to keep thin slice, substrate material thin slice, first fiber is tied and second fiber is tied joint line;
Keeping the grasping part that forms by lamella joint line and joint line between thin slice and the substrate material thin slice; With
Insert in the grasping part and also can be installed to the grasping tool on the fibrous substrate.
2. the burnisher of claim 1, it is aqueous that wherein said antigenicity reduces composition.
3. the burnisher of claim 1, it is the plant extract composition that wherein said antigenicity reduces composition.
4. the burnisher of claim 1, it is the extract that water or organic solvent extract from Olea or ligustrum plant that described antigenicity reduces composition.
5. the burnisher of claim 1, wherein said finish is a dust adhesion type finish.
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004262896 | 2004-09-09 | ||
| JP262897/2004 | 2004-09-09 | ||
| JP2004262897A JP4688455B2 (en) | 2004-09-09 | 2004-09-09 | Cleaning tool |
| JP262896/2004 | 2004-09-09 | ||
| JP341804/2004 | 2004-11-26 | ||
| JP2004341804A JP4021893B2 (en) | 2004-09-09 | 2004-11-26 | Cleaning tool |
| JP2004358952A JP4660179B2 (en) | 2004-12-10 | 2004-12-10 | Cleaning tool |
| JP358952/2004 | 2004-12-10 | ||
| PCT/JP2005/016997 WO2006028280A1 (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101014695A CN101014695A (en) | 2007-08-08 |
| CN101014695B true CN101014695B (en) | 2012-09-12 |
Family
ID=38698017
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580029805A Expired - Fee Related CN100577082C (en) | 2004-09-09 | 2005-08-10 | Cleaning implement |
| CN200580029970.3A Expired - Fee Related CN101014695B (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
| CN200580029969.0A Expired - Fee Related CN101014694B (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580029805A Expired - Fee Related CN100577082C (en) | 2004-09-09 | 2005-08-10 | Cleaning implement |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580029969.0A Expired - Fee Related CN101014694B (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN100577082C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105464415A (en) * | 2015-11-18 | 2016-04-06 | 宁波市鄞州银鑫铝业有限公司 | Swimming pool cleaning tool of picking rod |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003055122A (en) * | 2001-08-07 | 2003-02-26 | Shinto Fine Co Ltd | Antiallergic composition and method for inactivating allergen |
| US6777064B1 (en) * | 1997-05-23 | 2004-08-17 | The Procter & Gamble Company | Cleaning sheets, implements, and articles useful for removing allergens from surfaces and methods of promoting the sale thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040007251A1 (en) * | 2002-07-10 | 2004-01-15 | Kimberly-Clark Worldwide, Inc. | Cleaners for the control and removal of allergens |
-
2005
- 2005-08-10 CN CN200580029805A patent/CN100577082C/en not_active Expired - Fee Related
- 2005-09-08 CN CN200580029970.3A patent/CN101014695B/en not_active Expired - Fee Related
- 2005-09-08 CN CN200580029969.0A patent/CN101014694B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6777064B1 (en) * | 1997-05-23 | 2004-08-17 | The Procter & Gamble Company | Cleaning sheets, implements, and articles useful for removing allergens from surfaces and methods of promoting the sale thereof |
| JP2003055122A (en) * | 2001-08-07 | 2003-02-26 | Shinto Fine Co Ltd | Antiallergic composition and method for inactivating allergen |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100577082C (en) | 2010-01-06 |
| CN101010024A (en) | 2007-08-01 |
| CN101014694B (en) | 2012-09-12 |
| CN101014694A (en) | 2007-08-08 |
| CN101014695A (en) | 2007-08-08 |
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