CN101048549A - 具有光感背涂层的纸 - Google Patents

具有光感背涂层的纸 Download PDF

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CN101048549A
CN101048549A CN200580037253.5A CN200580037253A CN101048549A CN 101048549 A CN101048549 A CN 101048549A CN 200580037253 A CN200580037253 A CN 200580037253A CN 101048549 A CN101048549 A CN 101048549A
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light sensation
coating
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M·拉迪克
R·J·麦芒努斯
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Hewlett Packard Development Co LP
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
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    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/84—Paper comprising more than one coating on both sides of the substrate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape
    • D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/775—Photosensitive materials characterised by the base or auxiliary layers the base being of paper
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/95—Photosensitive materials characterised by the base or auxiliary layers rendered opaque or writable, e.g. with inert particulate additives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Abstract

一种光感涂层(200)，其施加至纸(100)的表面(102)，所述表面(102)与被配置以承受印刷的表面(101)相对，所述光感涂层包含粘合剂；和具有第一和第二预定尺寸的聚乙烯颗粒。

Description

具有光感背涂层的纸
发明背景
发明领域
[0001]本发明涉及一种纸，该纸在一个表面上具有涂层，与前述表面相对的表面在其上承受印刷，并且该涂层向该纸提供一种光感(photobase feel)。
背景技术
[0002]显示出光感的纸是固有昂贵的，这是制造其所需的方法/材料造成的。例如，将聚乙烯挤出到纸张上的工艺需要专用设备，而这种设备不是一般即可获得的并且通常在最初制造该纸的工厂中是不可得的。因此，这种纸的成本增加，不仅需要专用的挤出设备而且需要将纸从制造地搬运到另一个进行涂布工序的位置。
[0003]因此需要一种制造上述纸的更简单、更廉价的技术。
附图说明
[0004]参考以下优选实施方案的具体描述和附图，本发明的各个方面和特征将被更清楚地理解，其中：
[0005]图1是本发明实施方案的示意性侧视图。
[0006]图2是图1的环II中包围的被涂布的纸张(sheet)部分的放大图，其中所述纸张包含未经处理的原纸(basestock)。
[0007]图3是图1的环II中包围的被涂布的纸张部分的放大图，其中所述纸张包含经处理的原纸。
[0008]图4是一幅流程图，其描述了根据本发明的一个实施方案进行的步骤。
示范性实施方案的详细说明
[0009]在本发明的一种实施方案中，一张纸或原纸100，其可以是未经处理的或者经处理的，用含一种或多种粘合剂和聚乙烯颗粒的“光感(photo feel)”层200涂布。这种光感涂层200在该纸的表面102上提供，与表面102相对的是印刷表面101，在后者上进行印刷。
[0010]对于未经处理的原纸，以图2中所示的方式将光感涂层200直接施加至原纸。对于经处理的原纸，其中两侧通过施用印刷强化胶印(offset)涂层而进行处理，所述印刷强化胶印涂层包括但不限于粘土、磨细的碳酸钙、沉淀碳酸钙、硫酸钡、二氧化钛、二氧化硅、三水合铝、氧化铝、勃姆石和其组合，以图3中所示的方式将光感涂层200施加至印刷强化胶印涂层102A。
[0011]涂布技术，通过其来施加光感涂层，除挤出以外，可以选自任何合适的市售可得的技术如幕帘涂布(curtain coating)、刮棒涂布(rod coating)或缝口喷注涂布(slot coating)。然而，本发明的实施方案不局限于这些设备，例如并不排除凹面涂布(gravure coating)、逆转辊涂布(reverse roll coating)、辊上刮板涂布(knife over rollcoating)。
[0012]涂层的厚度可为约3-约50gsm(克/平方米)。通常，约5-25gsm的涂层将是足够的，然后这种厚度可以变化，取决于用途和所用的纸。
[0013]纸或原纸(涂层可以施加到其上的)可以选自市售可得的原料如“Galerie one gloss”和“Galerie one silk”(由M-real of KangusFinland生产)以及#Savvy和#Influence(International Paper)。本发明的实施方案当然不限于这些选择并且可被用于不同的基材(纸)，视情况而定。
[0014]在图1中，示意性地描述了印刷设备(arrangement)300，其印刷到印刷表面101上。这种印刷设备采取墨喷式印刷机的形式，但其不限于此。例如，印刷设备可以采取电子录印、凹面印刷等形式。
[0015]在本发明一个实施方案中，纸100可具有印刷表面101，其涂布有一层或多层便于墨喷印刷的材料。然而，本发明的实施方案不局限于这类处理并且可以包括用碳酸钙或二氧化硅、粘土、氧化铝、三水合铝、二氧化钛、硅酸铝等等进行处理。
[0016]涂层或层200可以包括单一的粘合剂如丙烯酸胶乳，聚乙烯颗粒分散于其中。根据本发明的一个实施方案，这些聚乙烯颗粒具有至少两种不同的尺寸。第一组颗粒的直径可以为约25-200纳米，而第二组直径可以为约1-6微米。根据一个实施方案，第一种颗粒的更优选的颗粒尺寸为约30-70nm，而第二种颗粒的更优选的颗粒尺寸为约3-5微米。
[0017]上述粘合剂可以选自但并非局限于苯乙烯、苯乙烯-丙烯酸类、苯乙烯-丁二烯、丙烯酸类、聚乙酸乙烯酯等。使用上述粘合剂的混合物也在本发明的范围内。
[0018]在本发明进一步的实施方案中，可以将抗卷曲剂加入到涂层中。这种抗卷曲剂可以是一种粘合剂，其可以选自但不局限于聚乙烯醇、明胶、淀粉、纤维素、改性纤维素等。
[0019]大颗粒和小颗粒的组合有助于背涂层(backchat)的均匀的光感，这提供了所述光感特性。使用相似尺寸的颗粒未提供这种期望的光感，虽然未绝对确定，但是怀疑是较小颗粒往往填充较大颗粒之间的空隙并且提供了一种均匀效果，这导致了背涂层的期望的光感。
实施例
实施例#1
100份粘合剂#1  丙烯酸胶乳(Rhoplex GL618)
10份粘合剂#2   聚乙烯醇(Mowiol 20-98)
40份颗粒#1     聚乙烯颗粒4μm(Michem Guard 20)
60份颗粒#2     聚乙烯颗粒50nm(Michem Shield 251)
纸：           被涂覆的原纸
涂层厚度：     8gsm
光感           优选的
实施例#2
100份粘合剂#1  丙烯酸胶乳(Rhoplex R-253)
40份颗粒#1     聚乙烯颗粒7μm(Michem Guard 60)
60份颗粒#2     聚乙烯颗粒35nm(Michem Emulsion 39235)
纸：           未被涂覆的原纸
涂层厚度：     20gsm
光感           可接受的
实施例#3
50份粘合剂#1   苯乙烯/丁二烯胶乳(Rovene 4021)
40份颗粒#1     Teflon颗粒4μm(Michem Glide 5)
60份颗粒#2     聚丙烯颗粒45nm(Michem乳液43040)
纸：           被涂覆的原纸
涂层厚度：     3-5gsm
光感           可接受的
[0020]应当理解的是，尽管仅仅参考有限的实施方案描述了本发明，但是在给定上述公开内容的情况下，各种在不背离所附权利要求的范围的情况下能够实施的变体和改变对本发明所属或主要所属的领域的技术人员来说，会是显而易见的。

Claims (10)

1.一种光感涂层(200)，其施加至纸(100)的表面(102)，所述表面(102)与被配置以承受印刷的表面(101)相对，所述光感涂层包含：
粘合剂；和
具有第一和第二预定尺寸的聚乙烯颗粒。
2.权利要求1的光感涂层，其中第一种颗粒尺寸和第二种颗粒尺寸分别包括约25-约200纳米的第一范围和约1-约6微米的第二范围。
3.权利要求2的光感涂层，其中第一种颗粒的更优选的颗粒尺寸为约30-70nm，而第二种颗粒的更优选的颗粒尺寸为约3-5微米。
4.权利要求1的光感涂层，其中该粘合剂选自以下中的至少一种：苯乙烯、苯乙烯-丙烯酸类、苯乙烯-丁二烯、丙烯酸类、聚乙酸乙烯酯。
5.权利要求1的光感涂层，其中优选的粘合剂是丙烯酸类粘合剂。
6.权利要求1的光感涂层，其还包含第二种粘合剂，添加该第二种粘合剂以提供预定特性。
7.权利要求6的光感涂层，其中该预定特性是削弱卷曲。
8.权利要求6的光感涂层，其中第二种粘合剂选自聚乙烯醇、明胶、淀粉、纤维素、改性纤维素。
9.权利要求1的光感涂层，其中优选的第二种粘合剂是聚乙烯醇。
10.权利要求1的光感涂层，其中涂层厚度为约3-约50gsm。
CN200580037253.5A 2004-10-29 2005-09-27 具有光感背涂层的纸 Expired - Fee Related CN101048549B (zh)

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US62293504P 2004-10-29 2004-10-29
US60/622,935 2004-10-29
US11/062,482 US8088860B2 (en) 2004-10-29 2005-02-23 Paper with photo-feel backcoat
US11/062,482 2005-02-23
PCT/US2005/034906 WO2006049761A2 (en) 2004-10-29 2005-09-27 Paper with photo-feek backcoat

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JP4887303B2 (ja) 2012-02-29
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WO2006049761A2 (en) 2006-05-11
US7905986B2 (en) 2011-03-15
WO2006049761A3 (en) 2006-08-24
ATE510961T1 (de) 2011-06-15
EP1812645B1 (en) 2011-05-25
US20080152878A1 (en) 2008-06-26
US8088860B2 (en) 2012-01-03
CN101048549B (zh) 2010-12-08
EP1812645A2 (en) 2007-08-01

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