CN101065474A - 香料组合物 - Google Patents
香料组合物 Download PDFInfo
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- CN101065474A CN101065474A CNA2005800408359A CN200580040835A CN101065474A CN 101065474 A CN101065474 A CN 101065474A CN A2005800408359 A CNA2005800408359 A CN A2005800408359A CN 200580040835 A CN200580040835 A CN 200580040835A CN 101065474 A CN101065474 A CN 101065474A
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- Prior art keywords
- composition
- compositions
- perfume
- ester
- acid
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 186
- 239000002304 perfume Substances 0.000 title claims abstract description 45
- 238000004140 cleaning Methods 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000000796 flavoring agent Substances 0.000 claims description 44
- 235000019634 flavors Nutrition 0.000 claims description 44
- 150000002148 esters Chemical class 0.000 claims description 37
- 102000004190 Enzymes Human genes 0.000 claims description 34
- 108090000790 Enzymes Proteins 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 30
- 238000005406 washing Methods 0.000 claims description 28
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 22
- 150000002576 ketones Chemical class 0.000 claims description 21
- 150000001299 aldehydes Chemical class 0.000 claims description 17
- 150000002632 lipids Chemical class 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 150000002825 nitriles Chemical class 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 4
- 150000002596 lactones Chemical class 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000012876 carrier material Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000002775 capsule Substances 0.000 claims description 2
- 150000001721 carbon Chemical group 0.000 claims description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 3
- 239000000194 fatty acid Substances 0.000 abstract description 3
- 229930195729 fatty acid Natural products 0.000 abstract description 3
- 150000004665 fatty acids Chemical class 0.000 abstract description 3
- 150000004666 short chain fatty acids Chemical class 0.000 abstract description 3
- 235000019645 odor Nutrition 0.000 abstract 3
- 230000000873 masking effect Effects 0.000 abstract 1
- -1 collutory Substances 0.000 description 42
- 229940088598 enzyme Drugs 0.000 description 32
- 239000003795 chemical substances by application Substances 0.000 description 30
- 108090001060 Lipase Proteins 0.000 description 17
- 102000004882 Lipase Human genes 0.000 description 17
- 239000004367 Lipase Substances 0.000 description 17
- 235000019421 lipase Nutrition 0.000 description 17
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 16
- 235000013599 spices Nutrition 0.000 description 14
- 150000004965 peroxy acids Chemical class 0.000 description 13
- 239000003599 detergent Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 10
- 239000000975 dye Substances 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 10
- 108091005804 Peptidases Proteins 0.000 description 9
- 239000002585 base Substances 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 8
- 239000003352 sequestering agent Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 8
- 239000004382 Amylase Substances 0.000 description 7
- 108010065511 Amylases Proteins 0.000 description 7
- 102000013142 Amylases Human genes 0.000 description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- 235000019418 amylase Nutrition 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 108010059892 Cellulase Proteins 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229940077388 benzenesulfonate Drugs 0.000 description 6
- 229940106157 cellulase Drugs 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 5
- 239000013543 active substance Substances 0.000 description 5
- AKGGYBADQZYZPD-UHFFFAOYSA-N benzylacetone Chemical compound CC(=O)CCC1=CC=CC=C1 AKGGYBADQZYZPD-UHFFFAOYSA-N 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 5
- JPZROSNLRWHSQQ-UHFFFAOYSA-N furan-2,5-dione;prop-2-enoic acid Chemical compound OC(=O)C=C.O=C1OC(=O)C=C1 JPZROSNLRWHSQQ-UHFFFAOYSA-N 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- FINOAUDUYKVGDS-UHFFFAOYSA-N (2-tert-butylcyclohexyl) acetate Chemical compound CC(=O)OC1CCCCC1C(C)(C)C FINOAUDUYKVGDS-UHFFFAOYSA-N 0.000 description 4
- HLCSDJLATUNSSI-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCC\C(C)=C\C#N HLCSDJLATUNSSI-JXMROGBWSA-N 0.000 description 4
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 description 4
- OHRBQTOZYGEWCJ-UHFFFAOYSA-N 3-(3-propan-2-ylphenyl)butanal Chemical compound CC(C)C1=CC=CC(C(C)CC=O)=C1 OHRBQTOZYGEWCJ-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- 239000004365 Protease Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 4
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 150000003624 transition metals Chemical class 0.000 description 4
- 230000002087 whitening effect Effects 0.000 description 4
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 4
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 3
- ZWKNLRXFUTWSOY-QPJJXVBHSA-N (e)-3-phenylprop-2-enenitrile Chemical compound N#C\C=C\C1=CC=CC=C1 ZWKNLRXFUTWSOY-QPJJXVBHSA-N 0.000 description 3
- WSTQLNQRVZNEDV-CSKARUKUSA-N (e)-4-methyldec-3-en-5-ol Chemical compound CCCCCC(O)C(\C)=C\CC WSTQLNQRVZNEDV-CSKARUKUSA-N 0.000 description 3
- UEGBWDUVDAKUGA-UHFFFAOYSA-N 2,6,10-trimethylundec-9-enal Chemical compound CC(C)=CCCC(C)CCCC(C)C=O UEGBWDUVDAKUGA-UHFFFAOYSA-N 0.000 description 3
- LUZDYPLAQQGJEA-UHFFFAOYSA-N 2-Methoxynaphthalene Chemical compound C1=CC=CC2=CC(OC)=CC=C21 LUZDYPLAQQGJEA-UHFFFAOYSA-N 0.000 description 3
- GVONPEQEUQYVNH-SNAWJCMRSA-N 2-Methyl-3-(2-pentenyl)-2-cyclopenten-1-one Chemical compound CC\C=C\CC1=C(C)C(=O)CC1 GVONPEQEUQYVNH-SNAWJCMRSA-N 0.000 description 3
- YPZUZOLGGMJZJO-UHFFFAOYSA-N Ambronide Chemical compound C1CC2C(C)(C)CCCC2(C)C2C1(C)OCC2 YPZUZOLGGMJZJO-UHFFFAOYSA-N 0.000 description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- HZPKNSYIDSNZKW-UHFFFAOYSA-N Ethyl 2-methylpentanoate Chemical compound CCCC(C)C(=O)OCC HZPKNSYIDSNZKW-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- DUKPKQFHJQGTGU-UHFFFAOYSA-N Hexyl salicylic acid Chemical compound CCCCCCOC(=O)C1=CC=CC=C1O DUKPKQFHJQGTGU-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 238000005282 brightening Methods 0.000 description 3
- MIZGSAALSYARKU-UHFFFAOYSA-N cashmeran Chemical compound CC1(C)C(C)C(C)(C)C2=C1C(=O)CCC2 MIZGSAALSYARKU-UHFFFAOYSA-N 0.000 description 3
- 229960004106 citric acid Drugs 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 3
- BLBJUGKATXCWET-UHFFFAOYSA-N cyclaprop Chemical compound C12CC=CC2C2CC(OC(=O)CC)C1C2 BLBJUGKATXCWET-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- WFEISWUNAJPLRX-ONNFQVAWSA-N dupical Chemical compound C12CCCC2C2C\C(=C/CCC=O)C1C2 WFEISWUNAJPLRX-ONNFQVAWSA-N 0.000 description 3
- 238000007046 ethoxylation reaction Methods 0.000 description 3
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- IPBFYZQJXZJBFQ-UHFFFAOYSA-N gamma-octalactone Chemical compound CCCCC1CCC(=O)O1 IPBFYZQJXZJBFQ-UHFFFAOYSA-N 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- BFBPISPWJZMWJN-UHFFFAOYSA-N methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1N=CCC(C)CCCC(C)(C)O BFBPISPWJZMWJN-UHFFFAOYSA-N 0.000 description 3
- IPWBXORAIBJDDQ-UHFFFAOYSA-N methyl 2-hexyl-3-oxocyclopentane-1-carboxylate Chemical compound CCCCCCC1C(C(=O)OC)CCC1=O IPWBXORAIBJDDQ-UHFFFAOYSA-N 0.000 description 3
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
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- 238000007493 shaping process Methods 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 3
- 238000002470 solid-phase micro-extraction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
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- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 2
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- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- 102100032487 Beta-mannosidase Human genes 0.000 description 2
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
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- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
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- 240000002505 Pogostemon cablin Species 0.000 description 2
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- OEYQBKYISMRWQB-UHFFFAOYSA-N Santal Chemical compound C=1C(OC)=CC(O)=C(C2=O)C=1OC=C2C1=CC=C(O)C(O)=C1 OEYQBKYISMRWQB-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
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- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 108010055059 beta-Mannosidase Proteins 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Abstract
本发明涉及香料组合物，该组合物尤其可用于遮蔽脂肪酸气味，尤其是短链脂肪酸气味，例如丁酸的气味。本发明还涉及包含这些香料组合物的消费品(例如清洁和/或处理组合物)以及这些组合物和消费品的制备和使用方法。
Description
发明领域
本发明涉及用于遮蔽气味的香料组合物、包含上述组合物的清洁和/或处理组合物、以及它们的制备和使用方法。
发明背景
消费者希望制品例如衣服尽可能地干净。这些消费者典型地将清洁或处理过的制品的气味与这些制品的清洁程度相关联。因此，从消费者的观点来看，清洁和/或处理组合物的有效性典型地直接与该组合物赋予用该组合物清洁或处理过的制品的气味有关。申请人已认识到，某些物质例如酯酶和脂肪酶可产生难闻的脂肪酸气味，尤其是短链脂肪酸气味，例如丁酸的气味。然而，这些物质可以是尤其有效的清洁剂。不幸的是，消费者典型地将使用这些试剂产生的气味与不洁净相关联。因此，仍需要一种可覆盖脂肪酸气味的香料组合物、包含上述组合物的清洁和/或处理组合物、以及它们的制备和使用方法。
发明概述
本发明涉及可用于遮蔽脂肪酸气味的香料组合物、包含上述组合物的清洁和/或处理组合物、以及它们的制备和使用方法。
发明详述
定义
本文所用消费品包括制品及清洁和处理组合物。
除非另外指明，本文所用术语“清洁和/或护理组合物”包括片状、颗粒状或粉状多功能洗涤剂或“重垢型”洗涤剂，尤其是衣物洗涤剂；液体状、凝胶状或糊状多功能洗涤剂，尤其是通常所说的重垢型液体类；液体精细织物洗涤剂；手洗餐具洗涤剂或轻垢型餐具洗涤剂，尤其是高泡型的那些；机器用餐具洗涤剂，包括各种在家庭和公共场所使用的片状、颗粒状、液体状和漂洗助剂型洗涤剂；液体清洁剂和杀菌剂，包括抗菌手洗型清洁剂、洗衣皂、漱口水、假牙清洁剂、汽车或地毯清洁剂、浴室清洁剂；洗发香波和润发乳；洗浴凝胶和泡沫浴液以及金属清洗剂；以及清洁助剂，如漂白助剂和“去污棒”或预处理型助剂。
本文所用“表1香料组分”是指列于表1中的那些香料组分，该表1见于本说明书中。
本文所用短语“独立地选自由下列...组成的组”是指从所参照的Markush组中选出的部分或元素可以相同、可以不同或可以是元素的任意组合。
本文所用术语“一个”和“一种”当用在说明书或权利要求中时，被理解为是指一个或多个受权利要求书保护或描述的物质。
必须使用本申请中测试方法部分中所公开的测试方法来测定申请者发明的各个参数值。
除非另外指明，所有组分或组合物含量均是关于该组分或组合物的活性物质含量，不包括可能存在于市售源中的杂质，例如残余溶剂或副产品。
除非另外指明，所有百分比和比率均按重量计算。除非另外指明，所有百分比和比率均基于总组合物计算。
应当理解，在本说明书中给出的每一上限值包括每一个下限值，如同该下限值在本文中也被明确表示。在本说明书全文中给出的每一个下限值将包括每一个上限值，如同该上限值在本文也有明确的表示。在本说明书全文中给出的每一数值范围将包括包含于该较宽数值范围内的所有较窄数值范围，如同该较窄的数值范围在本文也有明确的表示。
所有引用文献的相关部分均引入本文以供参考。任何文献的引用不可解释为是对其作为本发明的现有技术的认可。
香料组合物
本文公开的香料组合物尤其可用于遮蔽气味，尤其是脂肪酸气味、更具体地讲，短链脂肪酸气味，例如丁酸的气味，这些香料组合物尤其可用于洗涤剂粉末。
在本发明的一个方面，所述香料组合物包含至少10％、20％、30％、40％、50％、60％、70％、80％或甚至90％ 的一种或多种香料组分，所述香料组分具有的分子量大于0但小于或等于5.8E-22g(350道尔顿)，约1.7E-22g(100道尔顿)至约5.8E-22g(350道尔顿)，约2.1E-22g(130道尔顿)至约4.4E-22g(270道尔顿)，或甚至约2.3E-22g(140道尔顿)至约3.8E-22g(230道尔顿)；至少80％、85％、90％或甚至95％的所述一种或多种香料组分，所述香料组分具有的cLogP为至少2.4，约2.75至约8.0或甚至约2.9至约6.0，所述香料组合物包含至少5％、15％、25％、35％、45％、55％、65％、75％、85％或甚至95％的所述一种或多种香料组分，所述香料组分具有的cLogP在至少2.4，约2.75至约8.0或甚至约2.9至约6.0的范围内。在本发明的所述方面中，所述一种或多种香料组分可选自由下列物质组成的组：席夫碱、醚、酚、酮、醇、酯、内酯、醛、腈、天然油或它们的混合物。在上文所述的本发明的某个方面，所述一种或多种香料组分可包括表1香料组分或甚至表1香料组分1至28。
在本发明的另一个方面，所述香料组合物包含至少10％、20％、30％、40％、50％、60％、70％、80％，或甚至90％的香料组分，所述组分选自由下表1中所列组分组成的组以及它们的混合物。
表1
| 化学名 | CAS | 官能度 | 分子量 | clogP | |
| 1 | 2-甲氧基萘 | 93-04-9 | 醚 | 158 | 3.24 |
| 2 | 二苯基醚 | 101-84-8 | 醚 | 170 | 4.24 |
| 3 | 2-甲氧基-4-丙烯基苯酚 | 120-11-6 | 苯酚 | 164 | 4.63 |
| 4 | 2-甲氧基-4-烯丙基苯酚 | 97-53-0 | 苯酚 | 164 | 2.40 |
| 5 | 1-(5，5-二甲基-1-环己烯-1-基)-4-戊烯-1-酮 | 56973-85-4 | 酮 | 192 | 4.0 |
| 6 | (1α(E)，2β)-1-(2，6，6-三甲基-环己-3-烯-1-基)丁-2-烯-1-酮 | 71048-82-3 | 酮 | 192 | 3.62 |
| 7 | 3-甲基-4-(2，6，6-三甲基-2-环己烯-1-基)-3-丁烯-2-酮 | 127-51-5 | 酮 | 206 | 4.0 |
| 8 | 2-(2-(4-甲基-3-环己烯-1-基)丙基)环戊酮 | 95962-14-4 | 酮 | 220 | 4.44 |
| 9 | 4-[(2，6，6-三甲基-1-环己-2-烯基)]丁-3-烯-2-酮 | 127-41-3 | 酮 | 192 | 3.71 |
| 10 | 2-乙基-4-(2，2，3-三甲基-3-环戊基-1-基)-1-丁烯-1-醇 | 28219-61-6 | 醇 | 208 | 4.43 |
| 11 | 2-乙基-4-(2，2，3-三甲基环戊-3-烯基-1)-2-丁烯-1-醇 | 28219-61-6 | 醇 | 208 | 4.43 |
| 12 | 环戊乙酸-3-氧代-2-戊基甲酯 | 24851-98-7 | 酯 | 226 | 2.42 |
| 13 | 2-己基-3-氧代环戊羧酸甲酯 | 37172-53-5 | 酯 | 226 | 3.09 |
| 14 | 丙酸三环癸烯酯 | 17511-60-3 | 酯 | 206 | 2.89 |
| 15 | 乙酸三环癸烯酯 | 2500-83-6 | 酯 | 190 | 2.36 |
| 16 | 水杨酸正戊酯 | 2050-08-0 | 酯 | 208 | 4.56 |
| 17 | 苯并呲喃-2-酮或1，2-苯并呲喃酮 | 91-64-5 | 内酯 | 146 | 1.41 |
| 18 | 4-(三环(5，2，1，0)癸亚叉基-8)丁醛 | 30168-23-1 | 醛 | 204 | 3.63 |
| 19 | 3-(3-异丙基苯基)丁醛 | 125109-85-5 | 醛 | 190 | 3.55 |
| 20 | 对叔丁基-α-甲基二氢肉桂醛 | 80-54-6 | 醛 | 204 | 3.86 |
| 21 | α-己基肉桂醛 | 101-86-0 | 醛 | 216 | 4.85 |
| 22 | 正辛醛 | 124-13-0 | 醛 | 128 | 2.95 |
| 23 | 正壬醛 | 124-19-6 | 醛 | 142 | 3.98 |
| 24 | 正癸醛 | 10486-19-8 | 醛 | 156 | 5.60 |
| 25 | 十二烷醛 | 112-54-9 | 醛 | 184 | 5.07 |
| 26 | α-乙烯基-α-甲基苯丙腈 | 97384-48-0 | 腈 | 171 | 2.31 |
| 27 | 2-环己亚叉基-2-苯乙腈 | 104621-98-0 | 腈 | 197 | 无 |
| 28 | 绿叶刺蕊草 | 无 | 天然油 | 无 | 无 |
| 29 | 十二氢-3a，6，6，9a-四甲基萘并[2，1-b]呋喃 | 3738-00-9 | 醚 | 236 | 5.26 |
| 30 | 2-戊基环戊酮 | 4819-67-4 | 酮 | 154 | 2.94 |
| 31 | 1-(1，2，3，4，5，6，7，8-八氢-2，3，8，8-四甲基-2-萘基)乙酮 | 54464-57-2 | 酮 | 234 | 4.84 |
| 32 | 3-甲基-4(5)-环十五烯酮 | 82356-51-2 | 酮 | 236 | 5.60 |
| 33 | 5-庚基二氢-2(3H)-呋喃酮 | 104-67-6 | 内酯 | 184 | 3.83 |
| 34 | 甲基紫罗兰酮(混合物) | 1335-46-2 | 酮 | 206 | 4.23 |
| 35 | 六氢-1′，1′，5′，5′-四甲基-[2′S-(2′.α.，4′a.α.，8′a.α.)]-螺[1，3-二氧戊环-2，8′(5′H)-[2H-2，4a]桥亚甲基萘] | 154171-77-4 | 酮 | 无 | 5.67 |
| 36 | 2-甲基十一醛 | 110-41-8 | 醛 | 184 | 4.85 |
| 37 | 10-十一烯醛 | 112-45-8 | 醛 | 168 | 4.05 |
| 38 | 4-甲基-3-癸烯-5-醇 | 81782-77-6 | 醇 | 170 | |
| 39 | 2-羟基苯甲酸环己酯 | 25485-88-5 | 酯 | 220 | 4.48 |
| 40 | 1，2，3，5，6，7-六氢-1，1，2，3，3-五甲基-4H-二氢茚-4-酮 | 33704-61-9 | 酮 | 206 | 3.99 |
| 41 | N-2，4-二甲基-3-环己烯亚甲基氨茴酸甲酯 | 68738-99-8 | 席夫碱 | 无 | 4.78 |
| 42 | 2-乙基-4-(2，2，3-三甲基-3-环戊烯-1-基)-2-丁烯-1-醇 | 28219-61-6 | 醇 | 208 | 4.43 |
| 43 | 乙酸己酯 | 142-92-7 | 酯 | 144 | 2.83 |
| 44 | 3，7-二甲基-1，6-辛二烯-3-醇 | 78-70-6 | 醇 | 154 | 2.55 |
| 45 | 2-(1，1-二甲基乙基)-环己醇乙酸酯 | 88-41-5 | 酯 | 198 | 4.06 |
| 46 | 4-(4-羟基苯基)-2-丁酮 | 5471-51-2 | 酮 | 164 | 1.07 |
| 47 | 1-(2，3，4，7，8，8a-六氢-3，6，8，8-四甲基-1H-3a，7-亚甲基甘菊环-5-基)-[3R-(3.α.，3a.β.，7.β.，8a.α.)]-乙酮 | 32388-55-9 | 酮 | 246 | 4.75 |
| 48 | 乙氧甲氧基环十二烷 | 58567-11-6 | 醚 | 242 | 5.48 |
| 49 | 顺式-3-乙氧基-1，1，5-三甲基-环己烷 | 24691-15-4 | 醚 | 156 | 3.93 |
| 50 | 1，3-苯并间二氧杂环戊烯-5-甲醛 | 120-57-0 | 醚/醛 | 150 | 1.14 |
| 51 | 2-羟基苯甲酸苯甲酯 | 118-58-1 | 酯 | 228 | 4.22 |
| 52 | 2-甲基-3-(2-戊烯基)-2-环戊烯-1-酮 | 11050-62-7 | 酮 | 164 | 2.64 |
| 53 | 氧杂环十六烯-2-酮 | 34902-57-3 | 内酯 | 238 | 5.40 |
| 54 | (Z)-4-环十五碳烯-1-酮 | 0014595-54-1 | 酮 | 222 | 无 |
| 55 | 2-[(7-羟基-3，7-二甲基辛亚叉基)氨基]甲基苯甲酸 | 89-43-0 | 席夫碱 | 305 | 4.17 |
| 56 | (3a.α.，4.β.，7.β.，7a.α.)-八氢-4，7-亚甲基-3aH-茚-3a-羧酸乙酯 | 80623-07-0 | 酯 | 209 | 3.37 |
| 57 | (Z)-2-羟基苯甲酸-3-己烯酯 | 65405-77-8 | 酯 | 220 | 4.61 |
| 58 | 2-氨基苯甲酸甲酯 | 134-20-3 | 酯 | 151 | 2.02 |
| 59 | 2-羟基苯甲酸己酯 | 6259-76-3 | 酯 | 222 | 5.09 |
| 60 | 碳酸-4-环辛烯-1-基甲酯 | 87731-18-8 | 酯 | 184 | 2.77 |
| 61 | 5-环十六碳烯-1-酮 | 37609-25-9 | 酮 | 236 | 5.97 |
| 62 | 环己丙酸-2-丙烯酯 | 705-87-5 | 酯 | 196 | 3.93 |
| 63 | (S)-2-甲基戊酸乙酯 | 28959-02-6 | 酯 | 144 | 2.61 |
| 64 | (E)-4-(2，6，6-三甲基-1-环己烯-1-基)-3-丁烯-2-酮 | 79-77-6 | 酮 | 192 | 3.77 |
| 65 | 顺式-2，4-二甲基-2-(5，6，7，8-四氢-5，5，8，8-四甲基-2-萘基)-1，3-二氧戊环 | 131812-51-6 | 醚 | 288 | 6.27 |
| 66 | 3，7-二甲基-2，6-辛二烯腈 | 5146-66-7 | 腈 | 227 | 3.25 |
| 67 | 3，7-二甲基-2，6-壬二烯腈 | 61792-11-8 | 腈 | 163 | 3.78 |
| 68 | 二甲基-3-环己烯-1-甲醛 | 27939-60-2 | 醛 | 138 | 2.53 |
| 69 | 氧杂环十六-2-酮 | 106-02-5 | 内酯 | 240 | 6.29 |
| 70 | 甲基-2-甲基-3-(4-叔丁基苯基)丙亚叉基氨基苯甲酸酯 | 91-51-0 | 席夫碱 | 337 | 6.31 |
| 71 | 3-甲基丁氧基乙酸-2-丙烯酯 | 67634-00-8 | 酯 | 186 | 2.38 |
| 72 | 2，6，10-三甲基-9-十一醛 | 141-13-9 | 醛 | 210 | 5.16 |
| 73 | 3-甲基-2-戊基环戊酮 | 13074-63-0 | 酮 | 168 | 3.46 |
在本发明的另一个方面，所述香料组合物包含至少10％、20％、30％、40％、50％、60％、70％、80％、或甚至90％的香料组分，所述香料选自由上表1所列香料组分1至28组成的组、以及它们的混合物。
在所述香料组合物的任一上述方面，所述香料组合物可包含具有下式的酯香料组分：
其中R1和R2独立地包括至少一个α碳并且可具有β和/或γ碳。R1和R2可分别独立地为任何有机部分，所述有机部分具有一种或多种以下特性：支环或侧环在R1和/或R2的α、β或γ位置中的至少一个位置；支环或侧环在R1和/或R2的α或β位置中的至少一个位置；或至少一个叔碳原子在R1和/或R2的α位置。不受理论的束缚，据信当所述香料酯存在于一种可水解酯键的酶(例如，酶分类号为3.1.1的酶如脂肪酶)中时，上述香料酯特性会导致增加香料酯的稳定性，从而增加香料组合物的稳定性。当依照本申请的实施例8中公开的方法测试时，这种酯香料可显示小于80％，小于50％并且甚至小于20％的降解特性。
在本发明的任一上述方面，所述香料组合物典型地包含不超过约5％的香料组分或甚至不含香料组分，所述香料组分选自由下列物质组成的组：乙酸苯基甲基酯、苯乙醇、2-甲基丁酸乙酯、2-乙基-3-羟基-4H-吡喃-4-酮、4-羟基-3-甲氧基苯甲醛、3-乙氧基-4-羟基苯甲醛、(Z)-3-己烯-1-醇乙酸酯、2-甲基丁酸-1-甲基乙酯、1-羟基-3-癸酮、2-庚酮、苯甲醛、(Z)-3-(3-己烯氧)-丙腈、4-苯基-2-丁酮、2-己烯-1-醇、5-丁基二氢-2(3H)-呋喃酮。
用于生产本文公开的香料组合物的合适的香料物质可获自以下供应商：Argeville Kantcheff GmbH Nerotal 45，D 6200 Wiesbaden，德国；Biolandes Parfumerie 44 Route de Plascassier BP156-06336 GRASSECEDEX，法国；CAPUA s.r.l.Zona Industriale 89052 Campo Calabro(RC)，意大利；CHARABOT 10，Avenue Yves-Emmanuel Baudoin 06130Grasse，法国；Drom International Inc 2776 Camden Court，Lisle Illinois60532美国；Fragrance Resources Inc.275 Clark Street P.O.Box 110Keyport，New Jersey 07735美国；Firmenich S.A.1，Route Des JeunesCH-1211，Geneva瑞士；Firmenich Incorporated PO Box 5880Princeton，New Jersey 08543美国；Givaudan法国S.A.19-23 Voie desBans BP 98 95101 Argenteuil Cedex法国；Givaudan S.A.CorporateHeadquarters BP 985 Chemin de la Parfumerie 1214 Vernier瑞士；Henkel KgaA CFC Fragrance Division Henkelstrasse 67 D-40191Dusseldorf德国；International Flavors & Fragrances IFFLiebergerweg 72-98 PO Box 309 1200 AH Hilversum荷兰；IFF(法国)47 Rue Victor-Hugo 92270 Bois-Colombes法国；International Flavors& Fragrances IFF Daksa 12580 Benicarlo(Castellon)西班牙；International Flavors & Fragrances IFF The Creative Center 650 StateHWY，36 Hazlet，New Jersey 07730美国；Kantcheff GmbH Nerotal 45，D 6200 Wiesbaden德国；V.Mane Fils SA，法国620 Route de Grasse06620 Le Bar-sur-Loup法国；Mane Ltd Concorde House BalcombeRoad Haywards Heath Sussex RH16 1NS；Millenium 141 Rue SaintLambert，Bte 2 1200 Brussels比利时；Millennium PO Box 389Jacksonville，Florida 32201-0389美国；Noville 2B Cardigan RoadRichmond Surrey TW10 6BJ；Noville 3 Empire Boulevard SouthHackensack New Jersey 07606-1806美国；PFW Aroma Chemicals B.V.Nijverheidsweg 60 P.O.Box 414 3770 AK Barneveld荷兰；SymriseGmbH Muhlenfeldstrasse D-37603 Holzminden德国；QuestInternational P.O.Box 2 Naarden-Bussum荷兰；Quest InternationalFragrance Company 400 International Drive，PO Box 901 Mount Olive，New Jersey 07828美国；Quest International Ashford Kent TN24 0LTEngland；Rhodia Organique Fine Ltd PO Box 46，St Andrews RoadAvonmouth Bristol BS11 9YF；Soda Aromatic CO.，Ltd.Soda BuildingNo 15-9，Nihonbashi Honcho 4-Chrome，Chuo-Ku，Tokyo 103日本；Synarome 40 rue Raspail，BP 20 92270 Bois Colombes法国；TakasagoInt.Corp.11 Volvo Drive，Rockleigh New Jersey 07647-0932美国；和Takasago Int.(NEDERLAND)B.V.Gooimeer 9 1411 DD Naarden荷兰。
制备香料组合物的方法
本发明的香料组合物可通过混合香料原料(典型地为液体)来制备。某些香料原料为固体物质并且需要微热以与其余香料匀化。该香料共混物还可包含显著比例的稀释剂(例如，双丙甘醇)、抗氧化剂或增溶物质。增溶剂是尤其有利的，其中表面活性剂含量较低，以分散主要亲水的基质(例如含水液体清洁剂)中的香料。
香料递送方法
所述香料组合物的任一个上述方面可由其它物质组合以产生以下任一种递送体系：淀粉胶囊包封的递送体系、多孔载体材料递送体系、涂敷的多孔载体材料递送体系、微胶囊包封的递送体系。生产上述递送体系的合适方法存在于以下专利中的一项或多项中：美国专利6,458,754、5,656,584、6,172,037、5,955,419和5,691,383以及WIPO公布WO 94/28017、WO 98/41607、WO 98/52527。这些递送体系可在消费品中单独使用、彼此组合使用或甚至与自身喷洒在本发明的香料组合物上或混和该组合物组合使用。
消费品
在申请人发明的第一个方面中，申请人的发明包括消费品。所述产品包含至少0.05％重量或甚至约0.05％重量至约30％重量的本发明的香料组合物，所述组合物的任何余量为一种或多种助剂物质。所述消费品可包含脂肪酸气味或产生脂肪酸气味的物质或其组合。
在申请人发明的第二个方面中，申请人发明包括清洁和/或处理组合物，所述组合物包括约0.05％至约5％重量，约0.05％至约2％重量，约0.05％至约1％重量的所述香料组合物和脂肪酸气味、产生脂肪酸(例如，丁酸)气味的物质(例如，脂肪酶)、或脂肪酸气味或产生脂肪酸气味的物质的组合。所述组合物的任何余量为一种或多种助剂物质。
在申请人发明的所述第一和第二方面中，所述可产生脂肪酸气味的物质可选自由如下分类的酶组成的组：酶分类号3.1(能够水解酯键的酶)，酶分类号3.1.1(水解羧酸酯键的酶)，酶分类号3.1.1.3(脂肪酶)，酶分类号3.1.1.50(蜡酯水解酶)和酶分类号3.1.1.74(角质酶)。酶分类号为3.1.1.3脂肪酶的实例包括描述于WIPO公布WO00/60063、WO 99/42566、WO 02/062973、WO 97/04078、WO 97/04079和US 5,869,438的那些。脂肪酶的实例包括LIPEX、LIPOLASEULTRA和LIPOPRIME和LIPOLASE(Novozymes的注册商品名)和LIPASE P“AMANO”(购自Areario Pharmaceutical Co.Ltd.，Nagoya，Japan)，AMANO-CES(商购自Toyo Jozo Co.，Tagata，Japan)，并且还包括粘稠色杆菌脂肪酶(购自U.S.Biochemical Corp.，U.S.A.和Diosynth Co.，Netherlands)，以及其它脂肪酶，例如唐菖蒲假单胞菌。其他有用的脂肪酶描述于WIPO公布WO 2004/101759、WO 2004/101760和WO 2004/101763。
辅助物质
虽然对于本发明而言不是必需的，但下文所举例说明的助剂物质的非限制性列表适用于本发明的组合物，并且可期望将其结合到本发明的某些实施方案中，以例如有助于或提高处理待清洁基底的清洁性能，或在含着色剂、染料等的情况下调节清洁组合物的美观性。这些附加组分的明确性质及加入量将取决于组合物的物理形式以及其应用的清洁操作的性质。合适的助剂物质包括但不限于：表面活性剂、助洗剂、螯合剂、染料转移抑制剂、分散剂、酶和酶稳定剂、催化物质、漂白活化剂、过氧化氢、过氧化氢源、预成形过酸、聚合分散剂、粘土污垢移除/抗再沉淀剂、增白剂、抑泡剂、染料、结构弹性剂、织物软化剂、载体、水溶助长剂、加工助剂、溶剂和/或颜料。除了以下公开内容之外，上述其它助剂及用量的合适实例还存在于美国专利5,576,282、6,306,812 B1和6,326,348 B1中，这些文献被引入本文以供参考。
如所声明，辅助成分不是申请人的组合物所必需的。因此，申请人的组合物的某些实施方案不包含一种或多种下列助剂物质：表面活性剂、助洗剂、螯合剂、染料转移抑制剂、分散剂、酶和酶稳定剂、催化物质、漂白活化剂、过氧化氢、过氧化氢源、预成形过酸、聚合分散剂、粘土污垢移除/抗再沉淀剂、增白剂、抑泡剂、染料、结构弹性剂、织物软化剂、载体、水溶助长剂、加工助剂、溶剂和/或颜料。然而，当存在一种或多种助剂时，这些一种或多种助剂可如下详述存在：
漂白剂-本发明清洁组合物可包括一种或多种漂白剂。不同于漂白催化剂的合适漂白剂包括光漂白剂、漂白活化剂、过氧化氢、过氧化氢源、预成形过酸以及它们的混合物。通常，当使用漂白剂时，本发明的组合物可包括按所述受试清洁组合物的重量计约0.1％至约50％或者甚至约0.1％至约25％的漂白剂。合适漂白剂的示例包括：
(1)光漂白剂如磺化酞菁锌；
(2)预成形的过酸：合适的预成形的过酸包括但不限于选自由下列物质组成的化合物：过羧酸及其盐、过碳酸及其盐、过亚氨酸及其盐、过一硫酸及其盐(例如Oxzone)、以及它们的混合物。合适的过羧酸包括具有分子式R-(C＝O)O-O-M的疏水和亲水过酸，其中R为烷基，任选支链烷基，当过酸疏水时，其具有6至14个碳原子或者8至12个碳原子；当过酸亲水时，其具有小于6个碳原子或者甚至小于4个碳原子；并且M为抗衡离子，例如钠、钾或氢；
(3)过氧化氢源，例如无机过氢化合物盐，包括以下碱金属盐如钠盐：过硼酸盐(通常为一水合物或四水合物)、过碳酸盐、过硫酸盐、过磷酸盐、过硅酸盐以及它们的混合物。在本发明的一个方面，无机过氢化合物盐选自由下列物质组成的组：过硼酸钠盐、过碳酸钠盐以及它们的混合物。如果被采用，无机过氢化合物盐典型地以总组合物的0.05至40％重量或者1至30％重量的含量存在，并典型地作为可被涂敷的结晶固体掺入到这种组合物中。合适的涂层包括：无机盐如碱金属硅酸盐、碳酸盐或硼酸盐或它们的混合物，或有机物如水溶性或可分散聚合物、蜡、油或脂肪皂；和
(4)具有R-(C＝O)-L的漂白活化剂，其中R为烷基，任选支链烷基，当漂白活化剂疏水时，其具有6至14个碳原子或者8至12个碳原子，当漂白活化剂亲水时，其具有小于6个碳原子或者甚至小于4个碳原子；且L为离去基团。合适的离去基团的实施例为苯甲酸及其衍生物-尤其是苯磺酸盐。合适的漂白活化剂包括十二烷酰氧基苯磺酸盐、癸酰氧基苯磺酸盐、癸酰氧基苯甲酸及其盐、3，5，5-三甲基己酰氧基苯磺酸盐、四乙酰基乙二胺(TAED)和壬酰氧基苯磺酸盐(NOBS)。合适的漂白活化剂还描述于WO 98/17767中。尽管可采用任何适宜的漂白活化剂，在本发明的一个方面中，受试清洁组合物可包含NOBS、TAED或它们的混合物。
如果存在，过酸和/或漂白活化剂通常以基于所述组合物约0.1至约10％重量，约0.5至约60％重量或者甚至约0.6至约40％重量的含量存在于所述组合物中。一种或多种疏水过酸或其前体可与一种或多种亲水过酸或其前体联合使用。
可选择过氧化氢源与过酸或漂白活化剂的量，使得可用氧(来自过氧化物源)与过酸的摩尔比为1∶1至35∶1，或者甚至2∶1至10∶1。
表面活性剂-如本发明所述的清洁组合物可包括表面活性剂或表面活性剂体系，其中所述表面活性剂可选自非离子表面活性剂、阴离子表面活性剂、阳离子表面活性剂、两性表面活性剂、两性离子表面活性剂、半极性非离子表面活性剂以及它们的混合物。如果存在的话，表面活性剂典型地以按所述受试组合物的重量计约0.1％至约60％，约1％至约50％或者甚至约5％至约40％的含量存在。
助洗剂-本发明清洁组合物可包括一种或多种洗涤剂助剂或助洗剂体系。当使用助洗剂时，受试组合物将典型地包括按所述受试组合物的重量计至少约1％，约5％至约60％或者甚至约10％至约40％的助洗剂。助洗剂包括但不限于：聚磷酸的碱金属盐、铵盐和链烷醇铵盐、碱金属硅酸盐、碱土金属和碱金属碳酸盐、硅铝酸盐助洗剂和聚羧酸盐化合物、醚羟基聚羧酸盐、马来酸酐与乙烯或乙烯基甲基醚的共聚物、1，3，5-三羟基苯-2，4，6-三磺酸、和羧甲基苹果酸、多元乙酸(如乙二胺四乙酸和氨三乙酸)以及多元羧酸(如苯六甲酸、琥珀酸、柠檬酸、氧联二琥珀酸、多元马来酸、1，3，5-三苯甲酸、羧甲基苹果酸)的各种碱金属盐、铵盐和取代铵盐、以及它们的可溶性盐。
螯合剂-本文清洁组合物可包含螯合剂。合适的螯合剂包括铜、铁和/或锰螯合剂以及它们的混合物。当使用螯合剂时，受试组合物可包括按所述受试组合物的重量计约0.005％至约15％或者甚至约3.0％至约10％的螯合剂。
染料转移抑制剂-本发明的清洁组合物还可包含一种或多种染料转移抑制剂。适宜的聚合染料转移抑制剂包括但不限于：聚乙烯吡咯烷酮聚合物、聚胺N-氧化物聚合物、N-乙烯基吡咯烷酮和N-乙烯基咪唑的共聚物、聚乙烯基噁唑烷酮和聚乙烯基咪唑、或它们的混合物。当存在于受试组合物中时，染料转移抑制剂可以按所述组合物的重量计约0.0001％至约10％，约0.01％至约5％或者甚至约0.1％至约3％的含量存在。
增白剂-本发明清洁组合物也可包含可为制品着色的附加组分，如荧光增白剂。合适的荧光增白剂含量包括从约0.01％重量，约0.05％重量，约0.1％重量，或甚至约0.2％重量的较低含量至0.5％重量或甚至0.75％重量的较高含量。
分散剂-本发明的组合物还可包含分散剂。合适的水溶性有机物包括均聚或共聚酸或其盐，其中多元羧酸包含至少两个相隔不超过两个碳原子的羧基。
酶-清洁组合物可包含一种或多种酶，该酶提供清洁性能和/或织物护理有益效果。合适的酶的实施例包括但不限于：半纤维素酶，过氧化物酶、蛋白酶、纤维素酶、木聚糖酶、脂肪酶、磷脂酶、酯酶、角质酶、果胶酶、甘露聚糖酶、果胶裂解酶、角蛋白酶、还原酶、氧化酶、酚氧化酶、脂氧合酶、木素酶、支链淀粉酶、鞣酸酶、戊聚糖酶、malanases、β-葡聚糖酶、阿拉伯糖酶、透明质酸酶、软骨素酶、漆酶和淀粉酶、或它们的混合物。典型的组合是可包含例如与淀粉酶结合的蛋白酶和脂肪酶的酶组合。当存在于清洁组合物中时，上述酶可以按所述组合物的重量计约0.00001％至约2％，约0.0001％至约1％或者甚至约0.001％至约0.5％酶蛋白的含量存在。
酶稳定剂-可使用多种技术来稳定用于洗涤剂的酶。本发明使用的酶可由最终组合物中存在的钙和/或镁离子水溶性源来稳定，最终产物将这种离子提供给酶。在含水组合物包含蛋白酶的情况下，可加入可逆蛋白酶抑制剂例如硼化合物以进一步改善稳定性。
催化金属配合物-申请人的清洁组合物可包括催化金属配合物。一类含金属的漂白催化剂是这样的催化剂体系，该体系包含具有确定漂白催化活性的过渡金属阳离子，如铜阳离子、铁阳离子、钛阳离子、钌阳离子、钨阳离子、钼阳离子或锰阳离子；包含具有很低的或者没有漂白催化活性的辅助金属阳离子，如锌阳离子或铝阳离子；以及包含对于催化的和辅助的金属阳离子有确定稳定性常数的螯合剂，尤其是乙二胺四乙酸、乙二胺四(亚甲基膦酸)以及它们的水溶性盐。上述催化剂公开于U.S.4,430,243中。
如果需要，本发明组合物可借助锰化合物进行催化。上述化合物和用量是本领域熟知的，并且包括例如公开于U.S.5,576,282中的基于锰的催化剂。
可用于本发明的钴漂白催化剂为人们所知并描述于例如U.S.5,597,936、U.S.5,595,967中。这种钴催化剂容易通过已知步骤制备，例如U.S.5,597,936和U.S.5,595,967中所提出的。
本文的组合物还可适宜地包括配体的过渡金属配合物，所述配体例如bispidones(WO 05/042532 A1)和/或大多环刚性配体(简写为“MRL”)。作为实施项，而不受限制，可调节本文的组合物和方法，使得在含水洗涤介质中提供大约至少一亿分之一的活性MRL物质，并且在洗涤液体中将典型地提供为约0.005ppm至约25ppm，约0.05ppm至约10ppm，或甚至约0.1ppm至约5ppm的MRL。
本发明过渡金属漂白催化剂中合适的过渡金属包括例如锰、铁和铬。合适的MRL包括5，12-二乙基-1，5，8，12-四氮杂双环[6.6.2]十六烷。通过已知步骤易于制备合适的过渡金属MRL，例如在WO00/32601和U.S.6,225,464中所提出的。
溶剂-合适的溶剂包括水与其它溶剂如亲脂性流体。合适的亲脂性流体的实施例包括硅氧烷、其它硅氧烷、烃、二元醇醚、甘油衍生物如甘油醚、全氟胺、全氟化和氢氟醚溶剂、低挥发性无氟有机溶剂、二醇溶剂、其它对环境友好的溶剂以及它们的混合物。
制备清洁和/或处理组合物的方法
本发明的清洁和/或处理组合物可配制成任何适宜的形式并且通过配制人员所选的任何方法制备，其非限制性实施例描述于申请人实施例以及美国专利5,879,584、5,691,297、5,574,005、5,569,645、5,565,422、5,516,448、5,489,392、5,486,303中。
使用方法
本发明包括一种清洁、处理和/或遮蔽某区域(例如，表面或织物)气味的方法。所述方法包括以下步骤：任选地洗涤和/或漂洗某区域，然后将申请人的香料组合物的实施方案或包含这种组合物的消费品以未稀释的形式或稀释在洗涤液体中，与至少一部分的所述区域接触，然后任选漂洗所述区域。可使所述区域在上述漂洗步骤之前进行洗涤步骤。对本发明而言，洗涤包括但不限于擦洗和机械搅拌。如本领域的技术人员所认可的，本发明的消费品的方面理想地适用于洗涤用途。因此，本发明包括一种洗涤织物的方法。所述方法包括将待洗涤的织物与清洁洗涤溶液相接触的步骤，所述洗涤溶液包含至少一种申请人的清洁和/或处理组合物、清洁助剂或它们的混合物的实施方案。织物可包括任何能够在正常消费者使用条件下洗涤的大部分任何织物。优选地，溶液具有的pH值为约8至约10.5。所述消费品在溶液中使用的浓度可为约500ppm至约15,000ppm。水温典型地为约5℃至约90℃。水与织物的比率典型地为约1∶1至约30∶1。
测试方法
1.)cLogP：香料组分的cLogP依据美国专利6,916,769中描述的方案测定，并且当香料组合物被描述和/或叙述至少80％的所述香料组分具有某个cLogP值时，这意味着例如10分之8或5分之4等的所述香料组分具有所述的cLogP。
实施例1：依据本发明的香料组合物
| 常用名 | CAS | 组成 | |||
| 1 | 2 | 3 | 4 | ||
| Yara Yara | 93-04-9 | 5 | |||
| 二苯基氧化物 | 101-84-8 | 2 | 7 | 5 | |
| 异丁子香酚 | 120-11-6 | 6 | |||
| 丁子香酚 | 97-53-0 | 4 | 5 | ||
| Dynascone | 56973-85-4 | 1 | 1.5 | ||
| δ-二氢大马酮 | 71048-82-3 | 2 | 4 | ||
| γ-甲基紫罗兰酮 | 127-51-5 | 20 | 5 | ||
| 桃酮(Nectaryl) | 95962-14-4 | 20 | |||
| α-紫罗兰酮 | 127-41-3 | 4 | |||
| 大唐檀香(Dartanol) | 28219-61-6 | 8 | |||
| Levosandol | 28219-61-6 | 8 | |||
| Hedione | 24851-98-7 | 25 | 40 | ||
| Dihydro IsoJasmonate | 37172-53-5 | 10 | 12 | 5 | |
| Frutene | 17511-60-3 | 25 | |||
| Flor Acetate | 2500-83-6 | 25 | |||
| 水杨酸戊酯 | 2050-08-0 | 20 | |||
| 香豆素 | 91-64-5 | 4 | |||
| 道必卡尔(Dupical) | 30168-23-1 | 1 | |||
| Florhydral | 125109-85-5 | 2 | |||
| 铃兰醛 | 80-54-6 | 20 | 20 | ||
| 己基肉桂醛 | 101-86-0 | 40 | |||
| 癸醛 | 10486-19-8 | 5 | |||
| 月桂醛 | 112-54-9 | 1.5 | |||
| Peonile | 104621-98-0 | 15 | 12 | ||
| 绿叶刺蕊草 | 10 | ||||
| 余量 | 100 | 100 | 100 | 100 | |
实施例2：用依照本发明的组合物制备的香料
| 香料实施例 | |||||
| 常用名 | CAS | A | B | C | D |
| 组合物1 | 无 | 61 | |||
| 组合物2 | 无 | 45 | |||
| 组合物3 | 无 | 26 | |||
| 组合物4 | 无 | 10 | |||
| 超级龙涎醚(Cetalox) | 3738-00-9 | 0.5 | |||
| 2-戊基环戊酮(Delphone) | 4819-67-4 | 2 | |||
| δ-麝香烯酮 | 82356-51-2 | 1 | |||
| 十一烷酸内酯 | 104-67-6 | 1 | |||
| 甲基壬乙醛(AldehydeMNA) | 110-41-8 | 2 | |||
| 甲基癸烯醇 | 81782-77-6 | 2 | |||
| 水杨酸环己酯 | 25485-88-5 | 3 | |||
| Cashmeran | 33704-61-9 | 1 | |||
| Agrumea | 68738-99-8 | 3 | |||
| 乙酸己酯 | 142-92-7 | 5 | |||
| 乙酸邻叔丁基环己酯(Verdox) | 88-41-5 | 10 | |||
| 甲基柏木酮 | 32388-55-9 | 2 | |||
| 胡椒醛 | 120-57-0 | 1 | |||
| 水杨酸苄基酯 | 118-58-1 | 4 | |||
| 异茉莉酮 | 11050-62-7 | 1 | |||
| Habanolide | 34902-57-3 | 5 | 5 | ||
| 橙花素 | 89-43-0 | 1 | |||
| 水杨酸顺式-3-己烯酯 | 65405-77-8 | 3 | |||
| 氨茴酸甲酯 | 134-20-3 | 1 | |||
| 水杨酸己酯 | 6259-76-3 | 4 | |||
| 2-甲基戊酸乙酯 | 28959-02-6 | 1 | |||
| (Manzanate) | |||||
| 香叶腈 | 5146-66-7 | 2 | |||
| 女贞醛 | 27939-60-2 | 1 | 2 | ||
| 乙醇酸烯丙基戊酯 | 67634-00-8 | 1 | |||
| 阿道克醛(Adoxal) | 141-13-9 | 0.5 | |||
| Jasmylone | 13074-63-0 | 1 | |||
| 乙酸苄酯 | 140-11-4 | 10 | 58 | ||
| 苯乙醇 | 60-12-8 | 34 | |||
| 香草醛 | 121-33-5 | 1 | |||
| 乙基香草醛 | 121-32-4 | 0.5 | |||
| 乙酸顺式-3-己烯酯 | 3681-71-8 | 1 | |||
| 肉桂腈(Cinnamalva) | 1885-38-7 | 1 | |||
| 苄基丙酮 | 2550-26-7 | 20 | 20 | ||
| β-γ-己烯醇 | 2305-21-7 | 1 | 2 | 1 | |
| γ-辛内酯 | 104-50-7 | 0.5 | 1 | ||
| D-柠檬烯 | 138-86-3 | 15 | 26 | ||
| 总计 | 100 | 100 | 100 | 100 |
在以下洗涤剂组合物中，酶的含量以每100克总组合物的纯酶的百分数给出，并且香料组分为依照本发明和/或上述实施例1和2的香料。实施例3至6中使用的香料为依照本发明的香料组合物，例如实施例1和2的香料组合物。除非其它另外指明，实施例3至6的组合物的余量为水和微量组分，例如，抑泡剂等。实施例3至6的缩写组分识别如下：
LAS 直链C11-13烷基苯磺酸钠。
CxyAS C1x-C1y烷基硫酸钠。
CxyEzS 与平均zmol环氧乙烷缩合的C1x-C1y烷基硫酸钠。
CxEOy 具有平均y乙氧基化的Cx醇
QAS R2.N+(CH3)2(C2H4OH)，其中R2＝C10-C12
皂 衍生自牛油与椰子脂肪酸的80/20混合物的直链烷基羧酸
钠。
硅酸盐 无定形硅酸钠(SiO2∶Na2O的比率为1.6∶1至3.2∶1)。
沸石A 分子式为Na12(AlO2SiO2)12.27H2O的水合硅铝酸钠，具有
0.1至10微米范围内的原生粒度(重量基于无水表述)。
(Na-)SKS-6 结晶层状硅酸盐，分子式为δ-Na2Si2O5。
柠檬酸盐 二水合柠檬酸三钠
柠檬酸 无水柠檬酸。
碳酸盐 无水碳酸钠。
硫酸盐 无水硫酸钠。
MA/AA 4∶1的丙烯酸酯/马来酸酯的无规共聚物，平均分子量为约
70,000至80,000。
AA聚合物 聚丙烯酸钠聚合物，平均分子量为约4,500。
PB1/PB4 无水过硼酸钠一水合物/四水合物。
PC3 无水过碳酸钠[2.74Na2CO3.3H2O2]
TAED 四乙酰基乙二胺。
NOBS 壬酰羟苯磺酸钠。
DTPA 亚乙基三胺五醋酸。
HEDP 羟乙烷二膦酸盐
HEDMP 羟乙烷二(亚甲基)膦酸盐
DETPMP 二乙基三胺五(亚甲基)膦酸盐
EDDS 1，2-乙二胺-N，N′-二琥珀酸的钠盐，(S，S)异构体
STPP 三聚磷酸钠
蛋白酶 蛋白分解酶，以商品名Savinase、Alcalase、Everlase、
Coronase、Polarzyme售自Novozymes A/S，以商品名
Properase、Purafect、Purafect MA和Purafect Ox售自
Genencor，以及在专利WO 91/06637和/或WO 95/10591和
/或EP 0 251 446中描述的蛋白酶。
淀粉酶 以商品名Purastar、Purafect Oxam售自 Genencor；
Termamyl、FungamylDuramyl、Stainzyme和Natalase
售自Novozymes A/S的淀粉分解酶。
脂肪酶 脂解酶，以商品名Lipolase、Lipolase Ultra、Lipex售自
Novozymes A/S。
纤维素酶 以商品名Carezyme、Celluzyme和/或Endolase售自
Novozymes A/S的纤维素酶或葡聚糖酶
果胶裂解 售自Novozymes的Pectawash、Pectaway
酶
甘露聚糖 售自Novozymes的Mannaway
酶
CMC 或 羧甲基或羟基乙基或酯改性的纤维素
HEC 或
EMC
SS附聚物 12％的硅氧烷/二氧化硅、18％的硬脂醇、70％的颗粒形式
的淀粉[抑泡剂附聚物]。
TEPAE 四亚乙基五胺乙氧基化物
光漂白剂 磺化酞菁锌
PH值 20℃时在1％的蒸馏水溶液中测定。
实施例3：制备漂白重垢型衣物洗涤剂组合物：
| 吹制粉末 | I | II | III | IV | V | VI | VII | VIII |
| 沸石A硫酸钠LASQASMA/AAEDDS增白剂硫酸镁HEDMP附聚物1QAS | 13.6522.676.21-1.420.190.070.650.17- | 13.6522.676.21-1.420.190.070.650.17- | -24.435.65-3.500.190.060.390.170.9 | -30.13-2.954.250.230.080.480.21- | ---------- | ---------- | ---------- | ---------- |
| I | II | III | IV | V | VI | VII | VIII | |
| 碳酸盐硫酸钠附聚物2C14-15EO7硫酸钠附聚物3LAS沸石A附聚物4LAS硫酸钠碳酸钠干燥助剂LASMA/AA(颗粒)TAEDNOBSLAS(薄片)硅酸盐R 2.0柠檬酸/柠檬酸盐碳酸钠HEDPPC3或PB1蛋白酶淀粉酶脂肪酶果胶裂解酶纤维素酶SS附聚物皂 | -----------3.58--3.853.587.72-11.010.0090.005--0.0030.360.40 | -----------3.58--3.853.587.72-11.010.0090.005---0.360.40 | 2.452.452.796.65-----6.400.893.80--3.853.5813.84-11.010.0090.0050.001-0.0010.360.40 | --2.216.84------0.892.70-27.02.803.58--8.000.0090.005---0.550.40 | ----13.6321.42----0.955.89---3.8012.350.488.550.0390.0130.0020.0030.00050.620.48 | ----14.9623.51----0.955.89---3.80-0.488.550.0390.0130.0020.003-0.620.48 | ------8.1223.548.12-0.996.14---3.9612.870.508.910.0390.0130.0020.003-0.640.50 | ----13.6321.42----0.95-5.50--3.8012.350.488.550.0390.0130.0020.003-0.620.48 |
| I | II | III | IV | V | VI | VII | VIII | |
| 增白剂香料硫酸钠喷涂C12-14EO7粉化沸石A密度(g/L) | -0.54.484.00-600 | -0.44.484.00-600 | -0.2---600 | -0.7---600 | 0.100.414.303.002.00800 | 0.100.522.853.002.00800 | 0.100.414.901.00-800 | 0.100.614.303.002.00800 |
实施例4：制备具有下式的洗涤颗粒和片剂：
| 基础产物 | I | II | III | IV | V |
| C14-C15 AS/牛油ASLASC12C15AE3SC12C15AE5/AE3QAS沸石A(Na-)SKS-6(I)(干加)MA/AAAA聚合物柠檬酸盐柠檬酸DTPAEDDSHEDPPB1过碳酸盐NOBSTAED | 8.08.00.52.0-20.0-2.0--2.00.2--3.0-3.0- | 5.0-2.0--18.0-2.0-2.0-0.2--5.0-4.0- | 3.08.01.05.0-11.09.02.0--1.5-0.50.210.0--2.0 | 3.0--2.01.0-----2.0-0.10.1-18.0-5.0 | 3.07.0-2.01.010.0--4.0-----4.0-4.0- |
| I | II | III | IV | V | |
| 碳酸盐硫酸盐香料硅酸盐蛋白酶脂肪酶淀粉酶纤维素酶 | 15.05.00.8-0.0330.0030.0010.0014 | 18.012.00.61.00.0330.0020.0010.0014 | 8.02.00.4-0.0330.0050.0010.0014 | 15.017.00.5-0.0460.0080.00140.01 | 15.03.00.38.00.0330.0060.001- |
实施例5：制备以下颗粒状洗涤剂：
| I | II | III | IV | V | VI | VII | |
| LASQASC14-15EO7C12-14AE3SC12-14-N+(CH3)2(C2H4OH)三聚磷酸钠沸石A柠檬酸硅酸钠碳酸钠硫酸盐CMCAA/MAAA聚合物胺乙氧基化聚合物环状聚胺聚合物过碳酸盐PB1/PB4 | 7.230.753.500.25-18.62-1.293.1018.0417.58-2.15-0.600.0713.15- | 8.465.17--25.00--8.0011.003.98-1.50----9.0/9.0 | 6.500.603.50--18.620.791.294.2618.0419.93-1.85-0.490.0710.77- | 7.090.603.70--24.00--3.8718.9815.48-1.60----10.45/0 | 11.131.003.50--45.00--10.000.4210.13-1.94----2.37/0 | 16.0--0.700.5015.00.18-8.014.530.00.200.1----- | 16.0--1.00.5018.00.3-6.016.030.00.200.051.201.25--- |
| I | II | III | IV | V | VI | VII | |
| TAEDDTPA硫酸镁蛋白酶淀粉酶纤维素酶增白剂脂肪酶香料 | 2.500.341.370.0050.0010.00030.100.0020.4 | 5.000.341.430.0110.0030.00020.170.0020.6 | 1.580.371.370.0060.0010.00030.080.0040.5 | 1.520.391.41-0.0010.00030.080.010.7 | 0.660.240.58---0.080.0060.6 | -0.30-0.006--0.230.0040.4 | -0.30-0.0030.001-0.150.0030.3 |
实施例6：制备以下液体洗涤剂制剂
| I | II | III | IV | V | VI | |
| LAS烷基醚硫酸钠烷基乙氧基化物氧化胺脂肪酸柠檬酸(50％)甲酸钙和甲酸钠异丙基苯磺酸钠硼酸盐MEA硼酸盐氢氧化钠乙醇1，2-丙二醇山梨醇乙醇胺TEPAE蛋白酶脂肪酶 | 7.8-5.71.05.31.1-0.8-1.53.21.44.9-0.50.40.02- | 12.2-8.81.58.36.8-2-2.43.21.45.0-0.80.40.0280.001 | 4.414.42.20.73.02.00.2-1.5-3.02.56.6-1.50.04- | 12.2-8.81.58.33.4-2.02.4-4.91.44.9-0.80.0280.004 | 5.79.28.1--1.9--2.9-1.91.54.04.00.10.040.002 | 1.35.43.4--1.0----1.0------ |
| I | II | III | IV | V | VI | |
| 淀粉酶PVNO增白剂聚硅氧烷消泡剂甘露聚糖酶纤维素酶胺乙氧基化聚合物AA或MA/AADTPMP、DTPA、EDTA混合物香料 | 0.001-0.1-0.00040.00030.8-0.30.7 | 0.002-0.14-0.00060.00021.3-0.30.4 | 0.00020.15--0.00031.8-0.10.2 | 0.010.20.05--2.1--0.3 | -0.12----0.6-0.5 | -0.12----0.20.10.6 |
实施例#7：实施例3至6的组合物被如下使用：
将每种组合物与溶剂的单独等分试样组合以得到包括约500ppm至约15,000ppm各自组合物的单独溶液。将包含衣服或硬质表面的制品与各溶液接触。当制品为衣服时，溶剂与织物的质量比率为约1∶1至约100∶1，并且溶液温度为约5℃至约90℃。然后，任选地洗涤和/或漂洗制品。所得制品的气味、外观和/或颜色被改善和/或保持。
实施例#8
香料酯的稳定性以下列方式测定。本申请中公开的香料酯的共混物可通过以相等的重量百分比混合本申请公开的香料酯原料来制备。以0.3％的含量将所得的香料加至以商品名TIDE销售的液体洗涤剂。酯降解在20℃至25℃下在储存后0和24小时时被监测，均以产品的形式和以通过将1.5g的上述液体洗涤剂加至1升的水中制得的洗涤溶液的形式。所得液体和溶液的酯含量通过标准顶空气相色谱法测定，所述方法例如在Janusz Pawliszyn“Application of SolidPhase Micro-extraction”，RS.C，第26章，第349至457页(1999)中所述。具体地讲，顶空固相微萃取(SPME)之后接着进行热解吸GC/MS分析。SPME纤维被涂有100％聚二甲基硅氧烷(PDMS)。聚合物膜在纤维上的厚度为100-um。将样品放入20-mL用隔膜密封的顶层空间取样瓶中，并且在分析前平衡60分钟。为了取样，将纤维置于样品瓶的顶部空间，并进行吸收20分钟。然后，将注射器中的样品在240℃下注射至GC柱5分钟。用于这项工作的GC/MS体系是一种连有6890GC的5973MS，二者均得自Agilenttechnologies。PRM组分的分离通过使用涂有1-um PDMS相的60-mx250-um内径的毛细管柱完成。该香料酯显示出小于80％，小于50％，甚至小于20％的降解特性。
Claims (7)
1.一种香料组合物，所述组合物包含至少10％，优选20％，更优选30％的一种或多种香料组分，优选地所述一种或多种香料组分选自由下列物质组成的组：醚、酚、酮、醇、酯、内酯、醛、腈、天然油、席夫碱或它们的混合物，所述一种或多种香料组分具有大于0但小于或等于350道尔顿，优选100至350道尔顿，更优选130至270道尔顿，最优选140道尔顿至230道尔顿的分子量，至少80％的所述一种或多种香料组分具有至少2.4，优选2.75至8.0，更优选2.9至6.0的cLogP，所述香料组合物包含至少5％的cLogP为至少2.4的所述一种或多种香料组分，优选地所述一种或多种香料组分具有2.75至8.0的cLogP，更优选地所述一种或多种香料组分具有2.9至6.0的cLogP。
2.如权利要求1所述的香料组合物，其中所述一种或多种香料组分包含酯香料组分，所述酯香料组分具有下式：
其中R1和R2独立地包含α、β和/或γ碳，所述R1和R2分别独立地为具有支环或侧环的有机部分，所述支环或侧环在R1和/或R2的α、β或γ位置中的至少一个位置，所述酯香料组分具有在R1和/或R2的α或β位置中的至少一个位置的支环或侧环，更优选地所述酯香料组分具有至少一个在R1和/或R2的α位置的叔碳原子。
3.如前述任一项权利要求所述的香料组合物，所述组合物包含至少10％的香料组分，所述香料组分选自由表1香料组分组成的组或它们的混合物，优选地所述香料组分选自由表1香料组分1至28组成的组、以及它们的混合物。
4.如前述任一项权利要求所述的香料组合物，所述香料组合物被淀粉胶囊包封，被载入涂敷的或未涂敷的多孔载体材料，或被微胶囊包封。
5.一种消费品，所述消费品包含如前述任一项权利要求所述的香料组合物，并且优选一种可产生脂肪酸气味的物质和/或脂肪酸气味，优选一种酶分类号为3.1的酶。
6.如权利要求4所述的消费品，所述消费品包含助剂清洁或处理组合物成分。
7.一种清洁、处理和/或遮盖某区域气味的方法，所述方法包括任选地洗涤和/或漂洗所述区域，将所述区域与如前述任一项权利要求所述的组合物或消费品接触，然后任选地洗涤和/或漂洗所述区域。
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| US5656584A (en) * | 1996-02-06 | 1997-08-12 | The Procter & Gamble Company | Process for producing a particulate laundry additive composition for perfume delivery |
| CA2249291A1 (en) * | 1996-03-22 | 1997-09-25 | The Procter & Gamble Company | Delivery system having release inhibitor loaded zeolite and method for making same |
| MA24137A1 (fr) * | 1996-04-16 | 1997-12-31 | Procter & Gamble | Fabrication d'agents de surface ramifies . |
| EP0973855B1 (en) * | 1997-03-07 | 2003-08-06 | The Procter & Gamble Company | Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids |
| ES2245020T3 (es) * | 1997-03-07 | 2005-12-16 | THE PROCTER & GAMBLE COMPANY | Metodos mejorados de producir macropoliciclos con puente cruzado. |
| AU7440098A (en) * | 1997-05-21 | 1998-12-11 | Quest International B.V. | Perfume fixatives comprising polyvinylpyrrolidone and hydroxypropyl cellulose |
| AU3247699A (en) * | 1998-02-17 | 1999-09-06 | Novo Nordisk A/S | Lipase variant |
| US6458754B1 (en) * | 1998-04-23 | 2002-10-01 | The Procter & Gamble Company | Encapsulated perfume particles and detergent compositions containing said particles |
| ATE367845T1 (de) * | 1998-06-15 | 2007-08-15 | Procter & Gamble | Riechstoffzusammensetzungen |
| WO2000060063A1 (en) * | 1999-03-31 | 2000-10-12 | Novozymes A/S | Lipase variant |
| US6833346B1 (en) * | 1999-06-21 | 2004-12-21 | The Procter & Gamble Company | Process for making detergent particulates |
| US6790814B1 (en) * | 1999-12-03 | 2004-09-14 | Procter & Gamble Company | Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes |
| EP1111034A1 (en) * | 1999-12-22 | 2001-06-27 | The Procter & Gamble Company | Laundry and cleaning and/or fabric care compositions |
| DE10012949A1 (de) * | 2000-03-16 | 2001-09-27 | Henkel Kgaa | Kieselsäureester-Mischungen |
| US20020016269A1 (en) * | 2000-07-06 | 2002-02-07 | The Procter & Gamble Co. | Particle perfume delivery system |
| GB0025442D0 (en) * | 2000-10-17 | 2000-11-29 | Unilever Plc | Fabric conditioning compositions |
| CA2432329C (en) | 2001-02-07 | 2012-04-10 | Novozymes A/S | Lipase variants |
| WO2002064722A2 (en) * | 2001-02-14 | 2002-08-22 | The Procter & Gamble Company | Automatic dishwashing compositions comprising diacyl peroxide bleach and blooming perfume |
| DE10140787A1 (de) * | 2001-08-20 | 2003-03-06 | Haarmann & Reimer Gmbh | Depotpräparate |
| GB2382586A (en) * | 2001-12-03 | 2003-06-04 | Procter & Gamble | Fabric treatment compositions |
-
2004
- 2004-11-29 EP EP04257384A patent/EP1661977A1/en not_active Withdrawn
-
2005
- 2005-11-28 MX MX2007006315A patent/MX2007006315A/es active IP Right Grant
- 2005-11-28 AU AU2005309453A patent/AU2005309453A1/en not_active Abandoned
- 2005-11-28 US US11/287,659 patent/US20060116304A1/en not_active Abandoned
- 2005-11-28 MX MX2007006316A patent/MX2007006316A/es unknown
- 2005-11-28 EP EP05852300A patent/EP1817400A1/en not_active Withdrawn
- 2005-11-28 CN CN2005800408382A patent/CN101065473B/zh active Active
- 2005-11-28 DE DE602005026620T patent/DE602005026620D1/de active Active
- 2005-11-28 WO PCT/US2005/042942 patent/WO2006058297A1/en active Application Filing
- 2005-11-28 US US11/287,943 patent/US7569528B2/en active Active
- 2005-11-28 JP JP2007543572A patent/JP2008521974A/ja not_active Withdrawn
- 2005-11-28 CA CA002586054A patent/CA2586054A1/en not_active Abandoned
- 2005-11-28 CA CA002588677A patent/CA2588677A1/en not_active Abandoned
- 2005-11-28 AR ARP050104972A patent/AR051972A1/es unknown
- 2005-11-28 CN CNA2005800408359A patent/CN101065474A/zh active Pending
- 2005-11-28 AT AT05025877T patent/ATE500314T1/de not_active IP Right Cessation
- 2005-11-28 BR BRPI0518692-7A patent/BRPI0518692A2/pt not_active Application Discontinuation
- 2005-11-28 WO PCT/US2005/042941 patent/WO2006058296A1/en active Application Filing
- 2005-11-28 JP JP2007543571A patent/JP2008520819A/ja active Pending
- 2005-11-28 BR BRPI0516645-4A patent/BRPI0516645A/pt not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102695491A (zh) * | 2009-12-18 | 2012-09-26 | 宝洁公司 | 香料和香料包封物 |
| CN107028801A (zh) * | 2009-12-18 | 2017-08-11 | 宝洁公司 | 香料和香料包封物 |
| CN109715774A (zh) * | 2016-10-03 | 2019-05-03 | 宝洁公司 | 低pH衣物洗涤剂组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE602005026620D1 (de) | 2011-04-14 |
| EP1817400A1 (en) | 2007-08-15 |
| CA2588677A1 (en) | 2006-06-01 |
| CN101065473A (zh) | 2007-10-31 |
| AR051972A1 (es) | 2007-02-21 |
| ATE500314T1 (de) | 2011-03-15 |
| JP2008520819A (ja) | 2008-06-19 |
| BRPI0516645A (pt) | 2008-09-16 |
| US7569528B2 (en) | 2009-08-04 |
| AU2005309453A1 (en) | 2006-06-01 |
| US20060116304A1 (en) | 2006-06-01 |
| JP2008521974A (ja) | 2008-06-26 |
| US20060128586A1 (en) | 2006-06-15 |
| MX2007006315A (es) | 2007-06-19 |
| CA2586054A1 (en) | 2006-06-01 |
| CN101065473B (zh) | 2012-01-18 |
| BRPI0518692A2 (pt) | 2008-12-02 |
| MX2007006316A (es) | 2007-06-19 |
| EP1661977A1 (en) | 2006-05-31 |
| WO2006058297A1 (en) | 2006-06-01 |
| WO2006058296A1 (en) | 2006-06-01 |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Open date: 20071031 |