CN101308834A - 集成电路结构 - Google Patents
集成电路结构 Download PDFInfo
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Abstract
本发明涉及一种集成电路结构,包括衬底、位于衬底之中的从一端逐渐变窄的穿透硅通道、由衬底上表面延伸进入衬底的硬掩膜区,其中此硬掩膜围绕穿透硅通道的上方部分、位于衬底上的介电层、以及由介电层的上表面向穿透硅通道延伸的金属柱,其中金属柱包含与穿透硅通道的填充材料相同的材料。
Description
技术领域
本发明涉及集成电路结构,且特别涉及一种具有外形从一端逐渐变窄的穿透硅通道(Through-Silicon Via)的集成电路结构及其制造方法。
背景技术
由于电子元件(例如晶体管、二极管、电阻及电容等)的集成密度持续增加,使得集成电路发明与半导体产业持续不断地快速成长。其中,集成密度的改善最主要是源自于反复不断地降低最小关键尺寸,以允许更多元件被集成在一个特定的芯片区域中。
集成密度的改善基本上是二维的范畴,集成电路元件所占据的空间,基本上位于半导体晶片的表面。虽然光刻工艺的惊人发展,已经对二维集成电路制造提供了一定程度的改善,然而集成密度在二维中所能达到的改进程度仍然存在本质上的限制。其中一个限制条件来自于制造这些元件所需的最小尺寸。当要将更多元件纳入单一芯片时,就必须需要更复杂的设计。
另一个限制条件则来自于,当元件数量增加时,连接元件之间的内连线的数目和长度也大幅度增加。当内连线的数目和长度大幅度增加时,电路阻容延迟(RC Delay)和能量消耗也会随之增加。
解决上述限制条件的方案中,以三维集成电路和叠层芯片最常被使用。穿透硅通道在三维集成电路和叠层芯片之中,用来连接芯片。图1和图2示出一种穿透硅通道的制造方法。请参照图1,首先提供可在其上方形成集成电路(未示出)的硅衬底2。接着形成多个可以用来在其中形成金属线和过孔的介电层6,其中介电层6是一层一层地堆叠在硅衬底2上。接着使用并图案化光刻胶8。形成开口10穿过介电层6,并将硅衬底2暴露出来。接着通过开口10蚀刻硅衬底2,以形成如图2所示出的开口12。再于开口10和12的侧壁和底部形成黏着层及/或扩散阻挡层(未示出)。然后通过电镀填充铜(未示出)以形成一穿透硅通道。
传统穿透硅通道的形成工艺仍有多种缺点。由于开口10和12的深度比起其宽度显得相当深,因此黏着层和扩散阻挡层覆盖开口10和12的侧壁和底部的能力相对变差。再者想要形成无孔洞的穿透硅通道也相当的难。因此必须降低用来将铜填充入开口10和12的电镀电流,以减少在穿透硅通道中产生孔洞的机会,然而生产量也因此下降。
为了解决此问题,开口10和12,尤其是开口12较佳具有上宽下窄,且从一端逐渐变窄的外形,其中此形式可通过调整蚀刻剂的配方以增加横向蚀刻的方式来达到。然而此方式会在介电层6下方产生侧蚀缺口(Undercut)14。而侧蚀缺口14会在后续所形成的扩散阻挡层和种子铜层中产生裂口,因而对后续的铜电镀工艺产生负面影响。
因此有需要提供一种穿透硅通道结构及其制造方法,可同时具备从一端逐渐变窄外形的穿透硅通道,又可以克服传统穿透硅通道的缺点。
发明内容
因此本发明所要解决的技术问题在于提供一种集成电路结构,该集成电路结构具有外形从一端逐渐变窄的穿透硅通道,可以克服传统穿透硅通道的缺点。
为了实现上述目的,根据本发明的一个实施例,提供一种集成电路结构,包括衬底、位于衬底之中从一端逐渐变窄的穿透硅通道、由衬底的上表面延伸进入衬底内部的硬掩膜区,其中此硬掩膜围绕穿透硅通道的上方部分、位于衬底上的介电层、以及由介电层的上表面向穿透硅通道延伸的金属柱(metalpost),其中金属柱包含与穿透硅通道的填充材料相同的材料。
为了实现上述目的,根据本发明的另一个实施例,提供一种集成电路结构,包括衬底、由衬底的上表面延伸至衬底之中的浅沟槽绝缘区,且浅沟槽绝缘区形成一个环、位于浅沟槽绝缘区上方的多晶硅环、位于衬底及多晶硅环上方的低介电系数介电层、以及由低介电系数介电层上表面延伸入衬底的导电结构,其中导电结构包括位于低介电系数介电层中的第一部分,以及贯穿多晶硅环与浅沟槽绝缘区所形成的环的第二部分。
为了实现上述目的,根据本发明的又一个实施例,提供一种形成集成电路结构的方法,包括提供一衬底;形成硬掩膜,使其由衬底上表面延伸进入衬底;在硬掩膜层上形成蚀刻终止层;在衬底和蚀刻终止层上形成低介电系数的介电层;以及形成导电结构,使其由低介电系数介电层的上表面延伸进入衬底,其中导电结构包括位于低介电系数介电层中的第一部分,以及贯穿蚀刻终止层与硬掩膜层的第二部分。
为了实现上述目的,根据本发明的又一个实施例,提供一种形成集成电路结构的方法,包括提供一衬底;形成由衬底的上表面延伸至衬底之中的浅沟槽绝缘区,且浅沟槽绝缘区围绕衬底的一个上方部分;在衬底和浅沟槽绝缘区上方形成一平板,其中此平板覆盖被浅沟槽绝缘区所围绕的衬底的上方部分;在衬底、浅沟槽绝缘区以及平板上形成介电层;使用平板作为蚀刻终止层,在介电层中形成开口,通过此开口将平板的内在部分暴露出来;以及通过开口蚀刻此平板。
根据上述实施例,本发明具有优势的技术特征包含从一端逐渐变窄的穿透硅通道,同时降低侧蚀缺口现象,并改善扩散阻挡层的侧壁覆盖情况。
为让本发明的上述和其它目的、特征、优点与实施例能更明显易懂,下面结合附图详细说明。
附图说明
图1和图2示出一种制造传统穿透硅通道的工艺结构剖面图;
图3A至图9是根据本发明的一实施例的一种穿透硅通道的工艺结构剖面图及俯视图。
【主要器件符号说明】
2:硅衬底 6:介电层
10:开口 12:开口
14:侧蚀缺口 20:衬底
22:集成电路 24:浅沟槽绝缘区
25:浅沟槽绝缘区 26:开口
28:多晶硅平板 30:内连结构
32:内层介电层 34:金属层间介电层
36:钝化层 40:光刻胶
42:开口 43:虚线
44:穿透硅通道开口 46:侧蚀缺口
48:浅沟槽绝缘区暴露于外的余留部分
52:侧蚀缺口 60:扩散阻挡层
64:穿透硅通道 66:金属柱
D1:开口的直径 D2:多晶硅平板的直径
D3:浅沟槽绝缘区的外径 D4:开口的直径
ΔD:D1和D2的差 T1:浅沟槽绝缘区的厚度
T2:多晶硅平板的厚度 K1:衬底被蚀刻的深度
K2:浅沟槽绝缘区被蚀刻的深度
β:侧壁的倾斜角度 α:侧壁的倾斜角度
具体实施方式
以下内容是以一较佳实施例详述本发明的制造与使用。值得注意的是,本发明所提出的是一些可行的发明概念,可在不同的特殊实施例中得到体现。而以下所述的实施例只是描述一种制造与使用本发明的特定方式,并非用以限制本发明的范围。
下述实施例提供一种改进的穿透硅通道及其制造方法。先描述制造本发明的较佳实施例的中间步骤,再探讨不同实施例之间的差异。在本发明的所有附图与说明实施例中,相似的图标号码用以标示相似的元件。
请参照图3A,提供一衬底20,较佳为硅衬底。衬底20也可以由其它包含III族、VI族以及/或者V族元素的半导体材料所构成。另外衬底20可以由块状半导体(Bulk Semiconductor)、应变半导体(Strained Semiconductor)以及类似的材料所构成。集成电路22,以晶体管作为代表,则形成于衬底20的表面。
浅沟槽绝缘区24形成于衬底20之中,较佳是在衬底20中蚀刻浅沟槽,再使用绝缘体填充浅沟槽。典型的绝缘体包括高密度等离子体氧化硅。在本发明的一个实施之中,用来绝缘有源器件的浅沟槽绝缘区24和浅沟槽绝缘区25同时形成。在另外一个实施例之中,浅沟槽绝缘区24和浅沟槽绝缘区25分别形成,因此浅沟槽绝缘区24的最佳厚度T1与浅沟槽绝缘区25的厚度不同。在本实施例之中,厚度T1基本上小于1μm,较佳介于0.3μm至0.4μm之间。相关领域的技术人员应理解,上述尺寸仅代表其中一个示例,相关工艺技术的尺寸可依不同需要而增减。为了简化起见,集成电路22和浅沟槽绝缘区25并未在以下的附图中再做赘述。
请参照图3B,图3B示出图3A的部分结构的俯视图。在本发明的较佳实施例之中,浅沟槽绝缘区24形成一个环绕开口26的环。其中开口26的直径D1取决于穿透硅通道的预设尺寸。在本实施例之中,直径D1基本上介于201μm至301μm之间。在其它实施例中,开口26可以是其它形状,例如方形。而在说明书全文中,直径D1也可以视为开口26的宽度。
请再参照图3A,在衬底20和浅沟槽绝缘区24上形成多晶硅平板28,并且覆盖开口26。其中多晶硅平板28的厚度T2较佳是基本上小于1μm,而更佳则是基本上介于0.3μm至0.4μm之间。
多晶硅平板28较佳是覆盖于开口26之上。因此多晶硅平板28较佳是一个具有直径D2大于开口26的直径D1的圆形平板。另外直径D2小于浅沟槽绝缘区24的外径D3,但是直径D2也可能大于外径D3。直径D1和D2的差ΔD基本上大于10μm。
请参照图4A,形成内连结构30。内连结构30包括形成并覆盖在集成电路22上的蚀刻终止层(未示出)、衬底20、浅沟槽绝缘区24以及多晶硅平板28。内层介电层32则形成于蚀刻终止层上。其中金属层间介电层34较佳是由多层堆叠于内层介电层32上方的低介电系数介电层所构成。而金属线与过孔(未示出)则形成在金属层间介电层34之中。钝化层36形成于金属层间介电层34之上。另外蚀刻终止层(未示出)可以形成在两个金属层间介电层34之间。由于内连结构30的形成工艺为本领域的公知技术,因此不在此赘述。
光刻胶40形成在内连结构30上,以图案化内连结构30而形成开口42。开口42延伸贯穿内层介电层32、金属层间介电层34和钝化层36,并将多晶硅平板28暴露于外。在开口42的形成步骤中,多晶硅平板28作为蚀刻终止层。在本发明的一个实施例之中,开口42可以通过各向异性蚀刻达到基本上笔直。在其它实施例之中,开口42可以具有从一端逐渐变窄的外形,如虚线43所示。其中倾斜角度β较佳基本上小于89°,而更佳则基本上介于87°至88°之间。而此种从一端逐渐变窄的外形可通过使用部分各向异性蚀刻及部分各向同性蚀刻来形成。
请参照图4B,图4B示出图4A的结构的俯视图。开口42较佳具有与开口26相同的形状。在本发明的较佳实施例中,开口26是圆形,因此开口42的俯视图也是圆形。开口42的直径D4较佳大于开口26的直径D1,但小于多晶硅平板28的直径D2。直径D4更佳是基本上大于直径D1约10μm。
请参照图5,在检测到多晶硅平板28已暴露出来后,蚀刻工艺转而对多晶硅平板28进行蚀刻,以暴露出衬底20和浅沟槽绝缘区24。接着继续对暴露出来的衬底20进行蚀刻,以形成如图6所示的穿透硅通道开口44。其中对衬底20和浅沟槽绝缘区24所进行的蚀刻,可以在单一步骤中进行,也可以分别进行。上述蚀刻工艺,在衬底20(及多晶硅平板28)和浅沟槽绝缘区24之间具有较高的蚀刻选择性,较佳基本上为80比1。另外可调整用来蚀刻衬底20的蚀刻剂的配方,以保持或增加其蚀刻选择性。
在本实施例之中,蚀刻选择性基本上为80比1,意即是当衬底被蚀刻80μm时浅沟槽绝缘区24只被蚀刻1μm。如图5所示,由于一部分的浅沟槽绝缘区24通过开口42暴露出来,因此如图6所示,在蚀刻衬底20的时候,浅沟槽绝缘区24暴露出来的部分也会被蚀刻。然而对浅沟槽绝缘区24所进行的蚀刻速率远小于对衬底20所进行的蚀刻速率。因此,浅沟槽绝缘区24暴露于外的部分可以视为一种硬掩膜层,用来防止位于衬底20下方的位置被蚀刻。由于具有较高的蚀刻选择性,衬底20被蚀刻的深度K1与浅沟槽绝缘区24被蚀刻的深度K2两者的比例接近上述蚀刻选择性的比值。
值得注意的是,在浅沟槽绝缘区24下方有可能产生侧蚀缺口46。然而采用基本上各向异性的蚀刻工艺可降低侧蚀缺口46的宽度W。同时多晶硅平板28也可能产生侧蚀缺口52。不过由于多晶硅平板28较薄因此限制了侧蚀缺口52的宽度。另外,由于多晶硅平板28的直径D2仅稍大于开口42的宽度D4(如图4B所示),即使多晶硅平板28被完全蚀刻,位于多晶硅平板28中的侧蚀缺口52宽度也非常小。
请参照图7,随着蚀刻步骤的继续进行,浅沟槽绝缘区24暴露于外的余留部分48最后会被蚀穿,因此衬底20原先受到浅沟槽绝缘区24的余留部分48保护的部分会被暴露于蚀刻步骤中。在本实施例中,由于浅沟槽绝缘区24的厚度T1基本上为0.3μm,而蚀刻选择性为80比1。当浅沟槽绝缘区24被完全蚀穿时,穿透硅通道开口44的深度K1大约为80×0.3μm,大约等于24μm。若在浅沟槽绝缘区24被完全蚀穿之后,仍继续对衬底20进行蚀刻,穿透硅通道开口44的深度K1将会增加。与此同时,衬底20被遮盖的部分也会被逐渐蚀刻,结果使得穿透硅通道开口44最后具有由上而下逐渐变窄的外形。穿透硅通道开口44的侧壁的倾斜角度α较佳基本上介于87°到88°之间。而倾斜角度α可通过改变宽度(直径)D1、D2和D4以及改变蚀刻剂配方的方式来进行调整。相关领域的技术人员可通过实验找到最佳的参数值。
当浅沟槽绝缘区24的余留部分48(请参照图6)被基本上完全蚀刻之后,先前所形成的侧蚀缺口46会被消除,而完全并入穿透硅通道开口44。这将大幅地降低整体结构中侧蚀缺口的宽度。结果形成穿透硅通道开口44逐渐变窄的预设外形,并大幅改善侧蚀缺口的现象。当穿透硅通道开口44形成之后,即移除光刻胶40。
请参照图8,图8示出填充开口42和穿透硅通道开口44之后的结构剖面图。较佳先形成扩散阻挡层60,以覆盖于开口42和穿透硅通道开口44的侧壁以及穿透硅通道开口44的底部。然后在扩散阻挡层60上形成较佳为含铜的种子层(未示出)。其中扩散阻挡层60采用物理气相沉积技术形成,种子层也可以采用物理气相沉积或电镀技术来构成。由于穿透硅通道开口44具有从一端逐渐变窄的外形,并且降低了侧蚀缺口的现象,因此有助于使扩散阻挡层60和种子层的覆盖更为平均(与开口42和穿透硅通道开口44更加共形)。
接着,较佳采用电镀技术,以铜填充开口42和穿透硅通道开口44剩余未填满的部分。因而在衬底20之中形成穿透硅通道64,同时在内层介电层32、金属层间介电层34和钝化层36中形成金属柱66。由于扩散阻挡层60和种子层的覆盖较为平均,因此较多的电镀电流可被传导到穿透硅通道开口44较低的部分,因此大幅降低穿透硅通道64中形成孔洞的机会。
如图9所示,将衬底20的背面抛光,以露出穿透硅通道64然后进行封装工艺。
请再参照图3A,根据上述实施例所教示的内容,平板28可由非多晶硅材料所构成,以提供平板28和浅沟槽绝缘区24、内层介电层32、金属层间介电层34及钝化层36等介电结构之间较大的蚀刻选择性。形成平板28的典型材料包括氮化硅薄膜及复合金属硅化物。
虽然本发明已以较佳实施例揭露如上,然其并非用以限定本发明,任何相关技术领域的普通技术人员,在不脱离本发明的精神和范围内,当可作各种的改变与变形,因此本发明的保护范围当以后附的权利要求书所界定的为准。
Claims (14)
1、一种集成电路结构,包括:
衬底;
穿透硅通道,位于该衬底之内,其中该穿透硅通道从一端逐渐变窄;
硬掩膜,由该衬底的上表面延伸进入该衬底,其中该硬掩膜环绕该穿透硅通道的上方部分;
多个介电层,位于该衬底上方;以及
金属柱,由该介电层的上表面延伸至该穿透硅通道,其中该金属柱包括与该穿透硅通道的填充材料相同的材料。
2、根据权利要求1所述的集成电路结构,其特征在于,还包括环形的蚀刻终止层,位于该介电层与该硬掩膜之间,其中该蚀刻终止层仅环绕该金属柱的下方部分。
3、根据权利要求2所述的集成电路结构,其特征在于,该蚀刻终止层是多晶硅层,且该衬底是硅衬底。
4、根据权利要求1所述的集成电路结构,其特征在于,该硬掩膜的厚度小于该穿透硅通道的高度。
5、根据权利要求1所述的集成电路结构,其特征在于,该硬掩膜的厚度小于1μm。
6、根据权利要求1所述的集成电路结构,其特征在于,该穿透硅通道的侧壁具有小于90°的倾斜角度。
7、根据权利要求1所述的集成电路结构,其特征在于,还包括一浅沟槽绝缘区,用来绝缘多个有源器件,其中该硬掩膜与该浅沟槽绝缘区具有相同的厚度,并且由相同材料所构成。
8、根据权利要求1所述的集成电路结构,其特征在于,该金属柱的侧壁从一端逐渐变窄,且该金属柱上方部分的宽度大于该金属柱下方部分的宽度。
9、一种集成电路结构,包括:
衬底;
浅沟槽绝缘区,由该衬底的上表面向该衬底内部延伸,且该浅沟槽绝缘区形成一环;
多晶硅环,位于该浅沟槽绝缘区上;
多个低介电系数介电层,位于该衬底与该多晶硅环之上;以及
导电结构,由该低介电系数介电层的上表面延伸进入该衬底,其中该导电结构包括位于该低介电系数介电层之中的第一部分,以及贯穿该多晶硅环和该浅沟槽绝缘区所形成的环的第二部分。
10、根据权利要求9所述的集成电路结构,其特征在于,该第二部分的外形从一端逐渐变窄,且该第二部分的上方部分的宽度大于该第二部分的下方部分的宽度。
11、根据权利要求9所述的集成电路结构,其特征在于,该导电结构的该第二部分具有一高度,该高度大于该浅沟槽绝缘区的厚度。
12、根据权利要求9所述的集成电路结构,其特征在于,该浅沟槽绝缘区的厚度小于1μm,且该多晶硅环的厚度小于1μm。
13、根据权利要求9所述的集成电路结构,其特征在于,该多晶硅环的内侧侧壁与该浅沟槽绝缘区的内侧侧壁连续相连。
14、根据权利要求9所述的集成电路结构,其特征在于,该多晶硅环和该浅沟槽绝缘区均是圆环。
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TWI456729B (zh) * | 2011-11-29 | 2014-10-11 | Advanced Semiconductor Eng | 具有屏蔽導通柱之半導體元件及其製造方法 |
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US20080283959A1 (en) | 2008-11-20 |
US20090269905A1 (en) | 2009-10-29 |
US7564115B2 (en) | 2009-07-21 |
US7816227B2 (en) | 2010-10-19 |
CN101308834B (zh) | 2012-01-04 |
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