CN101607504B - Method for transfer printing of underglaze logo of bone porcelain and transfer printing ink system - Google Patents
Method for transfer printing of underglaze logo of bone porcelain and transfer printing ink system Download PDFInfo
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- CN101607504B CN101607504B CN 200910108684 CN200910108684A CN101607504B CN 101607504 B CN101607504 B CN 101607504B CN 200910108684 CN200910108684 CN 200910108684 CN 200910108684 A CN200910108684 A CN 200910108684A CN 101607504 B CN101607504 B CN 101607504B
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- transfer printing
- underglaze
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- supporting body
- porcelain
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Abstract
The invention discloses a method for transfer printing of an underglaze logo of bone porcelain and belongs to the technical field of ceramics decoration. The method comprises the following steps: preparing a supporting body which has the same biscuit shape as the bone porcelain with the underglaze logo to be transfer printed; forming a pattern of the underglaze logo to be transfer printed which does not deform on the supporting body and filling the pattern with transfer printing ink; transferring the ink pattern on the supporting body to a biscuit of the bone porcelain with the underglaze logo to be transfer printed with a transfer printing washer; fully drying the biscuit of the bone porcelain to be decorated with the transfer printed ink patterns, spray painting with a bone porcelain glaze material, burning for 2-8h at the temperature of 1,080 DEG C to 1,160 DEG C to form the underglaze logo of the bone porcelain to be transfer printed. The invention further discloses a printing inksystem for transfer printing of an underglaze logo of bone porcelain. The method and the system can help accurately print decorate and burn on objects having an irregular or a complicated surface such as porcelain, can help make satisfactory patterns on the extremely irregular surface of the porcelain, and can be widely applied to fabrication of the underglaze logo of a bone porcelain substrate.
Description
Technical field
The invention belongs to the ceramic decoration technical field, especially relate to a kind of method for transfer printing of underglaze logo of bone porcelain and transfer printing ink system thereof and equipment.
Background technology
China is at first in Britain's research and development, and its Main Ingredients and Appearance is that the bone meal after the calcining ox bone is bone black, and characteristics are that whiteness is good, and transparency is strong, and hardness is good; The first step is carried out biscuiting under the temperature of 1280 degree Celsius, then glazing and glaze firing between 1080 degree Celsius are spent to 1160.The pore of china base substrate itself can stop water color ink to infiltrate, so this printing ink always is wet in billet surface; Because the impact of surface texture and glaze generally can't re-start accurate Integral decoration to the china base substrate.In bake process and/or the one-tenth mold process, or for example variation of clay of other situation, the variation of china biscuit planar structure can both be caused.And, ceramic object with its accurately device shape usually do not conform to.
According to above situation, at the bottom of the direct transfer printing in center, the ceramic object biscuit back side, mark and often can meet difficulty.The reaction of glaze and pigment causes going wrong in bake process possibly, and therefore traditional water transfer printing is difficult to make mark of this end; After a kind of so-called fixative is used on the biscuit surface of spraying glaze, can carry out transfer printing, but glaze flows during baking, and beginning and the pigment that infiltrates reacts, can occur distortion after therefore burning till and crimp phenomenon.
Summary of the invention
One of purpose of the present invention is to provide the method that imprints the rough surface (china biscuit surface) of object after a kind of design (subscript) inking that will be formed at forme by the bat printing circle pad that is fit to, the special character of this technology is that it can be at forme creation single-image layout (subscript), it is impressed can not deform behind the ceramic surface, solves the defective that prior art exists.
For achieving the above object, the present invention adopts following technical scheme:
1, a kind of method for transfer printing of underglaze logo of bone porcelain comprises the steps:
1.1) make one and go to the bottom with glaze to be transferred and to mark the identical supporting body of china object biscuit shape;
1.2) form the glaze to be transferred that deformation can the not occur target pattern of going to the bottom at supporting body;
1.3) to the glaze to be transferred target pattern fills transfer ink of going to the bottom;
1.4) shift inking pattern on the supporting body with the transfer printing packing ring, the inking pattern is impressed into glaze to be transferred goes to the bottom on the mark china object biscuit;
1.5) fully behind the china object biscuit of dry transfer printing inking pattern to be decorated, the spraying bone china glaze, 1080 degree Celsius were fired 2-8 hour to 1160 degree are lower, naturally cooled off, and formed the china glaze to be transferred mark of going to the bottom.
Preferred scheme is: described supporting body is the metal supporting body, and described transfer printing packing ring is the silicone gasket of domed shape or arched roof shape.
More preferred scheme is: the pattern that described step 1.2) forms on the supporting body is that engraving or engraving method are made.
Two of purpose of the present invention is to provide a kind of transfer printing china glaze target transfer printing ink system of going to the bottom, and solves the defective that prior art exists.
For achieving the above object, the present invention adopts following technical scheme:
A kind of for the described transfer printing ink system of the arbitrary scheme of one of goal of the invention, comprising:
(a) inorganic component pigment or the colorant of at least a stable storage;
(b) weight ratio is 10% to 25% printing varnish, described printing varnish is that clear solution or gel are dissolved in the polymerization organic bond system that organic solvent forms, and this organic solvent comprises that 70w% is to trimethylbenzene or the trimethylbenzene derivative of at least a boiling spread between 150 degree Celsius are spent to Celsius 250 of 100w%; 0 to 50w% at least a essential oil as the dissolving plasticizer, 0 to 30w% at least a solvent that contains alcohols, ethers or ester class group;
(c) be no more than 10w% glass solvent;
(d) be no more than the conventional adjuvants of 10w%;
Wherein, the component of solid is more than the whole transfer printing ink system 70w%.
Preferred scheme is: described adhesive system also comprises the similar or/and copolymer of at least one or a plurality of (C3-C2)-acrylate; Described organic solvent comprise 70w% at least a boiling spread of 100w% at 150 degree Celsius are above between spending to Celsius 250 trimethylbenzene derivative, the Venice turpentine of 0 to 30w% conduct circle pad adhesive, and 0 to the 30w% at least a solvent that contains alcohols, ethers or ester class group.
Three of purpose of the present invention is to provide a kind of transfer printing china glaze target equipment of going to the bottom, and solves the defective that prior art exists.
For achieving the above object, the present invention adopts following technical scheme:
A kind ofly comprise a supporting body fixture for the described equipment of the arbitrary scheme of one of goal of the invention, a china object biscuit fixture, a transfer printing packing ring bogey, and one be transferred to the transfer device of china object biscuit with the inking pattern from supporting body.
Transferring system among the present invention has used the depression metallic plate, and metallic plate can be the chromium plating copper coin, and the chromium plating copper coin is carved with the design space of a whole page, and the opposite other end of metal plate carved region is with manually filling up mill base.The moving ink scraper, Non-design region on the cleaner plate face; In order to shift, also need to use the dome-type transfer packing ring that is consisted of by silica gel, in general, packing ring is conical; Be used for the profile of packing ring of machine and the character that diameter depends on decorated ceramic surface.Stick up stage of pigment pattern at packing ring, shift packing ring and be driven plain at the planographic plate; But in the transfer printing stage, packing washer deforms it on the china surface, covers the outline of decorated matrix.
Concrete operation step is as follows:
Move forward scraper plate, allow printing ink fill up engraving or the corrosion area of galley; In the drawback movement, scrape off the mill base of planar section on the printed panel with scraper, make mill base only stay sunk area; Reduce to shift to enclose and fill up to printed panel, stick up mill base from sunk area, when the transfer packing ring is moved toward ceramic object, scrape printing ink at printed panel, allow printing ink fill up sunk area, for next circulation is prepared; At last, packing ring is moved to ceramic object place, the downward modulation packing ring is also pressed at the irregular of object or rough surface loam cake, and gasket deforms meets external form or other irregular contour of object depression, and the design on the printed panel has just been transferred to the surface of decorated object fully like this.
Although only be directed to the china ceramic matrix about description of the invention, it also is fit to target transfer printing under other type tableware or the ceramic surface fully.
The present invention compared with prior art has the following advantages and beneficial effect:
The present invention adopts circle seal system in order to decorate or to impress at irregular surface such as convex surface, concave surface or coarse matrix surface, and circle seal system comprises the use of using and shift the circle pad of depression metal supporting body.Design or decoration at ceramic crude green body (especially china) irregular surface impression are metal supporting bodies consistent with china crude green body shape of design, and at the pattern of its surface engraving or the described transfer printing of etching; In the operation, mobile scraper makes mill base fill up carving area (effect of scraper plate is exactly to repeat to deliver mill base); The downward modulation silicone gasket sticks up the dispersible pigment color paste pattern to printed panel from carving area, then guarantees that with doctor cleaning galley surface non-decorative zones do not leave over any mill base; At last, shift packing ring contact target object, all pigment all has been transferred to the target object surface; After the transfer printing, thoroughly cleaning circle pad does not stay any remnants.
A key character of the present invention is for can accurately carrying out the first impression on this object that has irregular or a complex surface of similar pottery, decorate, burning till very large possibility is provided, and before this, these are considered to unpractical, special value of the present invention is that it can be used for making monochromatic pattern, i.e. end mark.
Shifting the circle pad is to make of soft silicon rubber, dome type structure, smooth surface; The lower clamping ring pad is to engraving or during corrosion area, the flatten layout of carrying inking of dome type circle pad; Then, press down extremely decorated object surface of soft circle pad, the circle pad is through after the more complicated distortion, and the surface can conform to the irregular surface of decorated object, is carried on like this surface that the inking pattern that encloses on the pad just has been transferred to decorative object; The viscosity pottery mill base that is specifically designed to transfer printing is transferred to the irregular surface of object by suitable transfer circle pad, after 4 to 5 of the lower bakings of 1160 degree Celsius as a child, can not deform, can produce gratifying pattern at very irregular ceramic surface.
The specific embodiment
Below in conjunction with specific embodiment the present invention is described in further details:
Embodiment 1
Varnish in the transfer printing ink system
Shellsol AB
19.9% (percentage by weight)
Larchturpentine
2 41％
DEGALAN 5402L
3 41.5％
Butyllactat
4 7.6％
Annotate: 1, SHELLSOL/SHELL, Type AB, boiling spread: 186-216 ℃;
2, Larchturpentine is the essential oil that extracts in the needle larch trees;
3, DEGALAN 5402L/EVONIK, key component is isobutyl methacrylate (basedon iso-Butylmethacrylate);
4, butyl lactate, solvent, boiling point: 188 degree Celsius.
Above raw material stirred 30 minutes with agitator, without cooling after mixing.
Embodiment 2
Transfer printing ink system
Ceramic paint, (GC 80 for a kind of underglaze colour that is made of gray paint and unleaded borosilicate dyestuff based on tin and the painted thing of antimony, grey, Japan NIKKEN) mix with varnish, an amount of glass solvent and conventional adjuvants among the embodiment 1, mixed mill base is applicable to enclose seal/tampon pad printing system.
Underglaze colour 70% (percentage by weight)
Varnish, an amount of glass solvent and conventional adjuvants 30% (wherein varnish is not less than 25%)
Pigment and varnish, an amount of glass solvent and conventional adjuvants mixing homogenize by three roller tumbling mills.
Embodiment 3
Form " auratic " trade (brand) name in china tableware (such as service plate) bottom.
Making one is gone to the bottom with glaze to be transferred and is marked the identical metal supporting body of china object biscuit shape, and the metal supporting body can be the chromium plating copper coin, the chromium plating copper coin; Form the glaze to be transferred that deformation can not occur mark " auratic " pattern of going to the bottom at the metal supporting body; To the glaze to be transferred target pattern fills embodiment 2 described transfer inks of going to the bottom; Shift inking pattern on the supporting body with the transfer printing packing ring, the inking pattern is impressed into glaze to be transferred goes to the bottom on the mark china object biscuit; Fully behind the china object biscuit of dry transfer printing inking pattern to be decorated, the spraying bone china glaze, 1080 degree Celsius were fired several hours to 1160 degree are lower, naturally cooled off formation " auratic " china glaze to be transferred mark of going to the bottom.
Concrete operation step is as follows:
Move forward scraper plate, allow printing ink fill up engraving or the corrosion area of galley; In the drawback movement, scrape off the mill base of planar section on the printed panel with scraper, make mill base only stay sunk area; Reduce to shift to enclose and fill up to printed panel, stick up mill base from sunk area, when the transfer packing ring is moved toward ceramic object, scrape printing ink at printed panel, allow printing ink fill up sunk area, for next circulation is prepared; At last, packing ring is moved to ceramic object place, the downward modulation packing ring is also pressed at the irregular of object or rough surface loam cake, and gasket deforms meets external form or other irregular contour of object depression, and the design on the printed panel has just been transferred to the surface of decorated object fully like this.
Above content is the further description of the present invention being done in conjunction with concrete preferred embodiment, can not assert that implementation of the present invention is confined to these explanations.For the general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, can also make some simple deduction or replace, all should be considered as belonging to the protection domain of inventing type.
Claims (5)
1. a method for transfer printing of underglaze logo of bone porcelain comprises the steps:
1.1) make one and go to the bottom with glaze to be transferred and to mark the identical supporting body of china object biscuit shape;
1.2) form the glaze to be transferred that deformation can the not occur target pattern of going to the bottom at supporting body;
1.3) to the glaze to be transferred target pattern fills transfer ink of going to the bottom;
1.4) shift inking pattern on the supporting body with the transfer printing packing ring, the inking pattern is impressed into glaze to be transferred goes to the bottom on the mark china object biscuit;
1.5) fully behind the china object biscuit of dry transfer printing inking pattern to be decorated, the spraying bone china glaze, 1080 degree Celsius were fired 2-8 hour to 1160 degree, naturally cooled off, and formed the china glaze to be transferred mark of going to the bottom.
2. method for transfer printing of underglaze logo of bone porcelain as claimed in claim 1, it is characterized in that: described supporting body is the metal supporting body, described transfer printing packing ring is the silicone gasket of domed shape or arched roof shape.
3. method for transfer printing of underglaze logo of bone porcelain as claimed in claim 2 is characterized in that: the pattern that described step 1.2) forms on the supporting body is made for engraving or engraving method.
4. transfer printing ink system that is used for each described method of claim 1～3 comprises:
(a) the inorganic component pigment of at least a stable storage;
(b) weight ratio is 10% to 25% printing varnish, described printing varnish is that clear solution or gel are dissolved in the polymerization organic bond system that organic solvent forms, and this organic solvent comprises that 70w% is to trimethylbenzene or the trimethylbenzene derivative of at least a boiling spread between 150 degree Celsius are spent to Celsius 250 of 100w%; 0 to 50w% at least a essential oil as the dissolving plasticizer, 0 to 30w% at least a solvent that contains alcohols, ethers or ester class group;
(c) be no more than 10w% glass solvent;
(d) be no more than the conventional adjuvants of 10w%;
Wherein, the component of solid is more than the whole transfer printing ink system 70w%.
5. transfer printing ink system as claimed in claim 4, it is characterized in that: described adhesive composition also comprises the similar of at least one (C3-C2)-acrylate or/and copolymer; Described organic solvent comprise 70w% at least a boiling spread of 100w% at 150 degree Celsius are above between spending to Celsius 250 trimethylbenzene derivative, the Venice turpentine of 0 to 30w% conduct circle pad adhesive replaces 0 to 50w% at least a essential oil as the dissolving plasticizer, and 0 to the 30w% at least a solvent that contains alcohols, ethers or ester class group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910108684 CN101607504B (en) | 2009-07-14 | 2009-07-14 | Method for transfer printing of underglaze logo of bone porcelain and transfer printing ink system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910108684 CN101607504B (en) | 2009-07-14 | 2009-07-14 | Method for transfer printing of underglaze logo of bone porcelain and transfer printing ink system |
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| Publication Number | Publication Date |
|---|---|
| CN101607504A CN101607504A (en) | 2009-12-23 |
| CN101607504B true CN101607504B (en) | 2013-01-02 |
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| CN 200910108684 Active CN101607504B (en) | 2009-07-14 | 2009-07-14 | Method for transfer printing of underglaze logo of bone porcelain and transfer printing ink system |
Country Status (1)
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5698016A (en) * | 1996-06-14 | 1997-12-16 | Cabot Corporation | Compositions of modified carbon products and amphiphilic ions and methods of using the same |
| CN101172885A (en) * | 2007-10-11 | 2008-05-07 | 南平市延城陶瓷研究所 | Method for sintering colorful porcelain figure on porcelain plate surface |
| CN101255065A (en) * | 2008-03-26 | 2008-09-03 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Low-temperature glaze leadless cadmium-free ceramic pigment flux |
-
2009
- 2009-07-14 CN CN 200910108684 patent/CN101607504B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5698016A (en) * | 1996-06-14 | 1997-12-16 | Cabot Corporation | Compositions of modified carbon products and amphiphilic ions and methods of using the same |
| CN101172885A (en) * | 2007-10-11 | 2008-05-07 | 南平市延城陶瓷研究所 | Method for sintering colorful porcelain figure on porcelain plate surface |
| CN101255065A (en) * | 2008-03-26 | 2008-09-03 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Low-temperature glaze leadless cadmium-free ceramic pigment flux |
Non-Patent Citations (1)
| Title |
|---|
| JP昭57-160689A 1982.10.04 |
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| CN101607504A (en) | 2009-12-23 |
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Owner name: SHENZHEN GUOCI YONGFENGYUAN CO., LTD. Free format text: FORMER NAME: SHENZHEN AURATIC INDUSTRY CO., LTD. |
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Address after: 518000 Yongfeng, Baoan District Guanlan Town, Shenzhen Industrial Park, the source of the concept of road, the south side of the road, the world's 2 Patentee after: CHINA YONGFENGYUAN Co.,Ltd. Address before: 518000, Shenzhen, Guangdong, Baoan District Guanlan Town, Ring South Road, Yongfeng Source Industrial Zone 2 (office space) Patentee before: SHENZHEN YONG FENG YUAN INDUSTRY Co.,Ltd. |
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Address after: 518000 Two Yongfengyuan Industrial Zone, Huanguannan South Road, Guanlan Town, Baoan District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Guoci Yongfengyuan Co.,Ltd. Address before: 518000 Two Yongfengyuan Industrial Zone, Huanguannan South Road, Guanlan Town, Baoan District, Shenzhen City, Guangdong Province Patentee before: CHINA YONGFENGYUAN Co.,Ltd. |
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