CN101797508B - Coking oven gas hydrodesulfurization catalyst and method for preparing same - Google Patents
Coking oven gas hydrodesulfurization catalyst and method for preparing same Download PDFInfo
- Publication number
- CN101797508B CN101797508B CN 200910273123 CN200910273123A CN101797508B CN 101797508 B CN101797508 B CN 101797508B CN 200910273123 CN200910273123 CN 200910273123 CN 200910273123 A CN200910273123 A CN 200910273123A CN 101797508 B CN101797508 B CN 101797508B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- oxide
- hours
- oven gas
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 89
- 238000004939 coking Methods 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000011068 loading method Methods 0.000 claims abstract description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 38
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 36
- 238000002803 maceration Methods 0.000 claims description 34
- 229910052742 iron Inorganic materials 0.000 claims description 24
- 229910052750 molybdenum Inorganic materials 0.000 claims description 24
- 238000005303 weighing Methods 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000005470 impregnation Methods 0.000 claims description 17
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- 150000007524 organic acids Chemical class 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 13
- 229910017052 cobalt Inorganic materials 0.000 claims description 13
- 239000010941 cobalt Substances 0.000 claims description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 13
- 239000011733 molybdenum Substances 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- 235000015165 citric acid Nutrition 0.000 claims description 12
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 11
- 229940010552 ammonium molybdate Drugs 0.000 claims description 11
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 11
- 239000011609 ammonium molybdate Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052792 caesium Inorganic materials 0.000 claims description 9
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 9
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 8
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 8
- 150000001868 cobalt Chemical class 0.000 claims description 7
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- 238000001802 infusion Methods 0.000 claims description 5
- YWECOPREQNXXBZ-UHFFFAOYSA-N praseodymium(3+);trinitrate Chemical compound [Pr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YWECOPREQNXXBZ-UHFFFAOYSA-N 0.000 claims description 5
- 206010013786 Dry skin Diseases 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 15
- 238000007323 disproportionation reaction Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910000428 cobalt oxide Inorganic materials 0.000 abstract 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 abstract 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- 238000007654 immersion Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 20
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 14
- 238000009826 distribution Methods 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 6
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 125000001741 organic sulfur group Chemical group 0.000 description 5
- 238000007086 side reaction Methods 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 235000001508 sulfur Nutrition 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910017116 Fe—Mo Inorganic materials 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000003009 desulfurizing effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- 206010067484 Adverse reaction Diseases 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910273123 CN101797508B (en) | 2009-12-08 | 2009-12-08 | Coking oven gas hydrodesulfurization catalyst and method for preparing same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910273123 CN101797508B (en) | 2009-12-08 | 2009-12-08 | Coking oven gas hydrodesulfurization catalyst and method for preparing same |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101797508A CN101797508A (en) | 2010-08-11 |
CN101797508B true CN101797508B (en) | 2013-02-13 |
Family
ID=42593439
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200910273123 Active CN101797508B (en) | 2009-12-08 | 2009-12-08 | Coking oven gas hydrodesulfurization catalyst and method for preparing same |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101797508B (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105312057B (en) * | 2014-07-11 | 2018-02-13 | 中国石油化工股份有限公司 | Ethylidene diacetate catalyst and ethylidene diacetate synthetic method |
CN104548926B (en) * | 2015-01-12 | 2017-07-25 | 北京三聚环保新材料股份有限公司 | A kind of organic sulfur removal technique |
CN104607197B (en) * | 2015-01-12 | 2017-07-25 | 北京三聚环保新材料股份有限公司 | A kind of Organic sulphur hydrogenation catalyst and preparation method thereof |
CN104624197B (en) * | 2015-01-30 | 2017-01-25 | 武汉科林精细化工有限公司 | Deoxygenating and desulfurization double-function fine desulfurization agent and preparation method thereof |
CN106268848A (en) * | 2016-07-22 | 2017-01-04 | 西安向阳航天材料股份有限公司 | A kind of coke-stove gas Hydrobon catalyst and preparation method thereof |
CN108212168A (en) * | 2016-12-22 | 2018-06-29 | 中国石油天然气股份有限公司 | A kind of Hydrobon catalyst of modification and preparation method and application |
CN108246303B (en) * | 2016-12-28 | 2021-03-30 | 中国石油天然气股份有限公司 | Catalyst for hydrogenation hydrolysis of Claus tail gas and preparation method and application thereof |
CN107486223B (en) * | 2017-08-17 | 2020-05-19 | 江苏天东新材料科技有限公司 | Preparation method and application of high-efficiency organic sulfur hydroconversion catalyst |
CN112742362B (en) * | 2019-10-31 | 2023-05-02 | 中国石油化工股份有限公司 | Coke oven gas hydrodesulfurization catalyst and preparation method and application thereof |
CN115254132B (en) * | 2021-04-30 | 2024-03-12 | 中国石油化工股份有限公司 | Coke oven gas hydrodesulfurization catalyst and application thereof |
CN115106095A (en) * | 2022-06-14 | 2022-09-27 | 昆明理工大学 | Catalyst for preparing methane by synchronously hydrogenating carbon monoxide and organic sulfur and preparation method and application thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2880171A (en) * | 1954-10-04 | 1959-03-31 | Gulf Research Development Co | Hydrodesulfurization of hydrocarbons with catalyst composed of molybdenum and two members of the iron group metals |
US5244858A (en) * | 1990-03-23 | 1993-09-14 | Cosmo Research Institute | Catalyst composition for hydrodesulfurization of hydrocarbon oil and process for producing the same |
CN1302686A (en) * | 2001-01-09 | 2001-07-11 | 华东理工大学 | Deoxidizing agent of molybdenum oxide and its preparing process |
CN1778873A (en) * | 2004-11-26 | 2006-05-31 | 中国石油天然气股份有限公司 | Inferior diesel hydrogenation catalyst |
-
2009
- 2009-12-08 CN CN 200910273123 patent/CN101797508B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2880171A (en) * | 1954-10-04 | 1959-03-31 | Gulf Research Development Co | Hydrodesulfurization of hydrocarbons with catalyst composed of molybdenum and two members of the iron group metals |
US5244858A (en) * | 1990-03-23 | 1993-09-14 | Cosmo Research Institute | Catalyst composition for hydrodesulfurization of hydrocarbon oil and process for producing the same |
CN1302686A (en) * | 2001-01-09 | 2001-07-11 | 华东理工大学 | Deoxidizing agent of molybdenum oxide and its preparing process |
CN1778873A (en) * | 2004-11-26 | 2006-05-31 | 中国石油天然气股份有限公司 | Inferior diesel hydrogenation catalyst |
Non-Patent Citations (2)
Title |
---|
侯远东.Co-Mo/γ-Al2O3催化剂的改性和FCC汽油选择性加氢研究.《中国优秀硕士学位论文全文数据库》.2008,22-26. * |
彭峰等.烟气直接还原脱硫催化剂研究.《复旦学报(自然科学版)》.2003,第42卷(第03期),435-437. * |
Also Published As
Publication number | Publication date |
---|---|
CN101797508A (en) | 2010-08-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101797508B (en) | Coking oven gas hydrodesulfurization catalyst and method for preparing same | |
CN102259003B (en) | Coke-oven gas methanation catalyst and preparation method thereof | |
CN108014781A (en) | A kind of hydrogenation catalyst and its preparation method and application | |
CN101439289A (en) | Preparation of hydrogenation catalyst | |
CN101214442A (en) | Sulphur resistant carbon monoxide transfer catalyst and preparation thereof | |
CN101262928A (en) | Desulfurizing agent for removing organic sulfur compounds, preparation method thereof and method for removing organic sulfur compounds using the same | |
CN101733131A (en) | Metal sulfide catalyst for hydrogenation treatment of fuel oil | |
CN106512984B (en) | A kind of preparation method of high activity diesel hydrogenation for removal sulphur catalyst | |
CN104437074A (en) | Desulfurizing agent for removing hydrogen sulfide and carbonyl sulfide at the same time | |
CN109569699A (en) | Sulfurized hydrogenation catalyst and its preparation method and application | |
CN105618061A (en) | Slurry bed carbon dioxide methanation bimetallic catalyst and preparation method and application thereof | |
CN102847548B (en) | Method for preparing hydrodesulfurization catalyst for oil product under mild condition | |
CN101797513A (en) | Catalyst used for hydrodesulphurization of coke-oven gas and preparation method thereof | |
CN109894125A (en) | A kind of preparation method and application of supported sulfided state Co-Mo/ γ-Al2O3 bimetallic catalyst | |
CN106552649B (en) | Presulfurization sulfur-resistant transformation catalyst and preparation method thereof | |
CN102008960A (en) | Oxide carrier-loaded cobalt catalyst and preparation method and application thereof | |
CN102896001A (en) | Preparation method for cascade porous ZIFs and hydrogen desulfurization catalyst | |
US8846564B2 (en) | Process for sulfiding catalysts for a sour gas shift process | |
CN100490978C (en) | Pre-sulfurizing process of hydrogenation catalyst | |
CN104624197B (en) | Deoxygenating and desulfurization double-function fine desulfurization agent and preparation method thereof | |
CN101590408B (en) | Thiols conversion catalyst and preparation method thereof | |
CN108940248A (en) | A kind of organic sulfur hydroconversion catalyst and its preparation method and application | |
CN104549542A (en) | Carrier, carbonyl sulfide hydrolysis catalyst based on carrier and preparation method of carbonyl sulfide hydrolysis catalyst | |
CN111054366A (en) | Organic sulfur conversion catalyst and its preparation method | |
CN1916121B (en) | Method for preparing diene selective hydrotreating catalyst for gasoline |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: WUHAN UNIVERSITY OF TECHNOLOGY Effective date: 20130619 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20130619 Address after: Wuchang Wuluo road 430070 Hubei city of Wuhan Province, No. 543-2 Patentee after: WUHAN KELIN FINE CHEMICAL Co.,Ltd. Address before: Wuchang Wuluo road 430070 Hubei city of Wuhan Province, No. 543-2 Patentee before: WUHAN KELIN FINE CHEMICAL Co.,Ltd. Patentee before: Wuhan University of Technology |
|
CP01 | Change in the name or title of a patent holder |
Address after: Wuchang Wuluo road 430070 Hubei city of Wuhan province 543-2 Patentee after: Wuhan Kelin Chemical Industry Group Co.,Ltd. Address before: Wuchang Wuluo road 430070 Hubei city of Wuhan province 543-2 Patentee before: WUHAN KELIN FINE CHEMICAL Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A catalyst for coke oven gas hydrodesulfurization and its preparation method Granted publication date: 20130213 Pledgee: China Postal Savings Bank Co.,Ltd. Wuhan Branch Pledgor: Wuhan Kelin Chemical Industry Group Co.,Ltd. Registration number: Y2024980006156 |