CN101914280A - Method for producing thin films by recycled plastics - Google Patents

Method for producing thin films by recycled plastics Download PDF

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Publication number
CN101914280A
CN101914280A CN2010102405945A CN201010240594A CN101914280A CN 101914280 A CN101914280 A CN 101914280A CN 2010102405945 A CN2010102405945 A CN 2010102405945A CN 201010240594 A CN201010240594 A CN 201010240594A CN 101914280 A CN101914280 A CN 101914280A
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China
Prior art keywords
section
mixing
film
sections
plastics
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Application number
CN2010102405945A
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Chinese (zh)
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CN101914280B (en
Inventor
赖明志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIAXING NANXIONG POLYMER CO Ltd
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JIAXING NANXIONG POLYMER CO Ltd
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Priority to CN2010102405945A priority Critical patent/CN101914280B/en
Publication of CN101914280A publication Critical patent/CN101914280A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • B29C48/10Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels flexible, e.g. blown foils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/78Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/875Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895Barrel or housing

Abstract

The invention relates to a method for producing thin films by recycled plastics, which adopts recycled plastics bait after film formation by blow molding to produce thin films. After twice treatment, the physical property and the heat resistant temperature of the original plastic particles of the recycled bait are slightly lowered, the temperature set in the production process is 3-10 DEG C lower than that of normal products, and the products can be qualified after physical property test and water pressure test. The reduction of the production temperature can greatly lower the production cost and improve the energy utilization rate.

Description

Utilize the method that reclaims the plastics-production film
Technical field
The present invention relates to a kind of film-forming method, relate in particular to a kind of method that reclaims the plastics-production film of utilizing.
Background technology
Patent of invention 00109827.6 discloses a kind of recovery method of plastic waste, the plastics bag of collecting is put into have porous cylinder perhaps, adds washing composition and cleans; Plastics bag after washing is put into cutting machine, is cut into tiny plastic sheet, simultaneously water purification is drenched into, carry out secondary washing; Then by the travelling belt drop that the has aperture branch that anhydrates, and enter in three grades of process furnace, controlled temperature is 100,190,220 ℃ respectively; The moisture evaporation of frosting in the first step, plastics deliquescing in the second stage, plastic molting in the third stage.The hole that plastics after the fusing are opened from furnace outer wall is extruded, and is cooled in cold water, forms uniform plastic cord; In tablets press, plastic cord is divided into a section plastic pellet then, obtains the reworked material finished particle; Draining after twice washing reenters the drum wash plastic waste with the water that is mixed with washing composition, with the water reuse through precipitation with after handling; Reprocessed plastic(s) finished particle that obtains and polyethylene can produce plastic reclaimed product according to proportioning melting again in 7: 3.The plastic waste that this method reclaims is difficult to be directly used in the film production process.
Summary of the invention
The purpose of this invention is to provide a kind of method that reclaims the plastics-production film of utilizing, after the waste material in the production process of plastic products is reclaimed, be directly used in the production of film, reduce environmental pollution.
A kind of method that reclaims the plastics-production film of utilizing comprises the steps:
The plastics bait of 1) blowing finished film is compressed into fragment through the 45m/min high speed disintegrator.
2) plastic flakes is added tablets press; mixing by single screw rod granulation processing, 50 ℃ of the first section feeding section processing temperatures are again through 150 ℃ of second section mixing sections; 156 ℃ of three-stage mixing sections; 158 ℃ of the 4th section mixing sections, 158 ℃ of the 5th section mixing sections, 160 ℃ of the 6th section mixing sections; 175 ℃ of the 7th section metering zones; 178 ℃ of the 8th section mixing sections, 183 ℃ of the 9th section mixing sections are after by 7 poroid mould dischargings into strips, the time of each processing sections is 30 minutes.
3) after the discharging, the cutting knife platform of drum-type is cut into granular.
4) add 5-10% (w/w) step 3) plastic pellet in thermoplastic elastomer raw material (TPU), outer lubrication prescription and 8% (w/w) the cloudy surface agent of 10% (w/w) surface is after mixer stirs, and dehumidifying heat pump is dried; In the screw rod cylindrical shell, carry out 5 segmentations then and add hot milling processing, to the mixing one-tenth fluid liquid of raw material hot melt,
The first section feeding section temperature is set 150 ℃, time 12-20 minute;
Second section mixing section temperature set 165 ℃, time 12-20 minute;
Three-stage mixing section temperature is set 178 ℃, time 3-15 minute;
The 4th section high mixing section temperature set 183 ℃, time 3-15 minute;
The 5th section compute segment temperature set 185 ℃, time 1-10 minute;
The fluid liquid that makes blows north one-tenth tubular film by the inflation film manufacturing machine mould, is pressed into bilayer film by the shaping guide wheel after cooling off.
The outer lubrication prescription in surface is selected from silicon-dioxide, the two amine hydroxybenzenes of ethylene or lime carbonate.
The cloudy surface agent is vinylbenzene and divinyl serum multipolymer.
The beneficial effect that technical solution of the present invention realizes:
The invention provides a kind of method that reclaims the plastics-production film of utilizing, utilization is blown north film forming plastics bait and be used further to film production after being reclaimed.Because of reclaim the ear material through twice processing after, its rerum natura has a little with the former heat resisting temperature of moulding grain and descends, the production process design temperature can be than the low 3-10 degree of the temperature of producing general normal product, and finished product can both be by testing through rerum natura and hydraulic pressure test.The reduction of production temperature has significantly reduced production cost and has improved energy utilization.
Embodiment
Below describe technical scheme of the present invention in detail.
Embodiment 1
By the ear material of blowing finished film strip that downcut both sides be rolled into via ear material reeling machine cylindric after, with many reel ear material, hanging on the brandreth by four is that one group of tie rod is compressed into plastic flakes via high speed disintegrator 45m/min speed.
Then; plastic flakes is added tablets press, divide 9 sections, processed in 30 minutes for every section: 50 ℃ of the first section feeding section processing temperatures by single screw rod granulation; again through 150 ℃ of second section mixing sections; 156 ℃ of three-stage mixing sections, 158 ℃ of the 4th section mixing sections, 158 ℃ of the 5th section mixing sections; 160 ℃ of the 6th section mixing sections; 175 ℃ of the 7th section metering zones, 178 ℃ of the 8th section mixing sections, 183 ℃ of the 9th section mixing sections are after by 7 poroid mould dischargings into strips.
After the discharging, through two 3 meters long cooling troughes and water absorber cooling forming, getting rid of behind the moisture content again, the cutting knife platform to drum-type is cut into granular.
Add the granular plastics of 6.2% (w/w) in the thermoplastic elastomer raw material, 10% (w/w) silicon-dioxide and 8% (w/w) vinylbenzene and divinyl serum multipolymer are after mixer stirs, and dehumidifying heat pump is dried; In the screw rod cylindrical shell, carry out 5 segmentations then and add hot milling processing, to the mixing one-tenth fluid liquid of raw material hot melt,
The first section feeding section temperature is set 150 ℃, 12 minutes time;
Second section mixing section temperature set 165 ℃, 12 minutes time;
Three-stage mixing section temperature is set 178 ℃, 3 minutes time;
The 4th section high mixing section temperature set 183 ℃, 3 minutes time;
The 5th section compute segment temperature set 185 ℃, 1 minute time.
The fluid liquid that makes blows north one-tenth tubular film by the inflation film manufacturing machine mould, is pressed into bilayer film by the shaping guide wheel after cooling off.
Embodiment 2
By the ear material of blowing finished film strip that downcut both sides be rolled into via ear material reeling machine cylindric after, with many reel ear material, hanging on the brandreth by four is that one group of tie rod is compressed into plastic flakes via high speed disintegrator 45m/min speed.
Then; plastic flakes is added tablets press, divide 9 sections, processed in 30 minutes for every section: 50 ℃ of the first section feeding section processing temperatures by single screw rod granulation; again through 150 ℃ of second section mixing sections; 156 ℃ of three-stage mixing sections, 158 ℃ of the 4th section mixing sections, 158 ℃ of the 5th section mixing sections; 160 ℃ of the 6th section mixing sections; 175 ℃ of the 7th section metering zones, 178 ℃ of the 8th section mixing sections, 183 ℃ of the 9th section mixing sections are after by 7 poroid mould dischargings into strips.
After the discharging, through two 3 meters long cooling troughes and water absorber cooling forming, getting rid of behind the moisture content again, the cutting knife platform to drum-type is cut into granular.
Add the granular plastics of 7% (w/w) in the thermoplastic elastomer raw material, 10% (w/w) silicon-dioxide and 8% (w/w) vinylbenzene and divinyl serum multipolymer are after mixer stirs, and dehumidifying heat pump is dried; In the screw rod cylindrical shell, carry out 5 segmentations then and add hot milling processing, to the mixing one-tenth fluid liquid of raw material hot melt,
The first section feeding section temperature is set 150 ℃, 13 minutes time;
Second section mixing section temperature set 165 ℃, 13 minutes time;
Three-stage mixing section temperature is set 178 ℃, 4 minutes time;
The 4th section high mixing section temperature set 183 ℃, 4 minutes time;
The 5th section compute segment temperature set 185 ℃, 2 minutes time.
The fluid liquid that makes blows north one-tenth tubular film by the inflation film manufacturing machine mould, is pressed into bilayer film by the shaping guide wheel after cooling off.

Claims (3)

1. one kind is utilized the method that reclaims the plastics-production film, comprises the steps:
The plastics bait of 1) blowing finished film is compressed into fragment through the 45m/min high speed disintegrator;
2) plastic flakes is added tablets press, mixing by single screw rod granulation processing, 50 ℃ of the first section feeding section processing temperatures are again through 150 ℃ of second section mixing sections, 156 ℃ of three-stage mixing sections, 158 ℃ of the 4th section mixing sections, 158 ℃ of the 5th section mixing sections, 160 ℃ of the 6th section mixing sections, 175 ℃ of the 7th section metering zones, 178 ℃ of the 8th section mixing sections, 183 ℃ of the 9th section mixing sections are after by 7 poroid mould dischargings into strips, the time of each processing sections is 30 minutes;
3) after the discharging, the cutting knife platform of drum-type is cut into granular;
4) add 5-10w/w% step 3) plastic pellet in the thermoplastic elastomer raw material, lubrication prescription and the agent of 8w/w% cloudy surface are after mixer stirs outside the 10w/w% surface, and dehumidifying heat pump is dried; In the screw rod cylindrical shell, carry out 5 segmentations then and add hot milling processing, to the mixing one-tenth fluid liquid of raw material hot melt,
The first section feeding section temperature is set 150 ℃, time 12-20 minute;
Second section mixing section temperature set 165 ℃, time 12-20 minute;
Three-stage mixing section temperature is set 178 ℃, time 3-15 minute;
The 4th section high mixing section temperature set 183 ℃, time 3-15 minute;
The 5th section compute segment temperature set 185 ℃, time 1-10 minute;
The fluid liquid that makes blows north one-tenth tubular film by the inflation film manufacturing machine mould, is pressed into bilayer film by the shaping guide wheel after cooling off.
2. the method for plastics-production film is reclaimed in utilization according to claim 1, it is characterized in that lubrication prescription is selected from silicon-dioxide, the two amine hydroxybenzenes of ethylene or lime carbonate outside the described surface.
3. the method for plastics-production film is reclaimed in utilization according to claim 1, it is characterized in that described cloudy surface agent is vinylbenzene and divinyl serum multipolymer.
CN2010102405945A 2010-07-30 2010-07-30 Method for producing thin films by recycled plastics Active CN101914280B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN2010102405945A CN101914280B (en) 2010-07-30 2010-07-30 Method for producing thin films by recycled plastics

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CN101914280B CN101914280B (en) 2012-05-02

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102642312A (en) * 2012-05-21 2012-08-22 福建百宏高新材料实业有限公司 Processing method for recovering and processing PET (polyethylene glycol terephthalate) waste film in compounding way by using twin-screw extrusion melting
CN102658655A (en) * 2012-05-21 2012-09-12 福建百宏高新材料实业有限公司 Production process of single-screw extrusion recycling of waste PET (polyester) films
CN106223528A (en) * 2016-08-31 2016-12-14 湖南宝信云建筑综合服务平台股份有限公司 A kind of novel building mechanism being easily installed use

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5145617A (en) * 1990-10-15 1992-09-08 Duro-Last, Inc. Method of processing scrap roof-membrane sheet material comprising a flexible synthetic fabric substrate enveloped in a thermoplastic plastic envelope
CN1075116A (en) * 1993-01-09 1993-08-11 江苏省轻工塑料工业公司塑料研究所 The regeneration technology of card-protecting film leftover pieces
CN101033297A (en) * 2007-04-17 2007-09-12 刘军 Production method for waste recombination plastics regeneration and granulation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5145617A (en) * 1990-10-15 1992-09-08 Duro-Last, Inc. Method of processing scrap roof-membrane sheet material comprising a flexible synthetic fabric substrate enveloped in a thermoplastic plastic envelope
CN1075116A (en) * 1993-01-09 1993-08-11 江苏省轻工塑料工业公司塑料研究所 The regeneration technology of card-protecting film leftover pieces
CN101033297A (en) * 2007-04-17 2007-09-12 刘军 Production method for waste recombination plastics regeneration and granulation

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102642312A (en) * 2012-05-21 2012-08-22 福建百宏高新材料实业有限公司 Processing method for recovering and processing PET (polyethylene glycol terephthalate) waste film in compounding way by using twin-screw extrusion melting
CN102658655A (en) * 2012-05-21 2012-09-12 福建百宏高新材料实业有限公司 Production process of single-screw extrusion recycling of waste PET (polyester) films
CN102658655B (en) * 2012-05-21 2014-04-02 福建百宏高新材料实业有限公司 Production process of single-screw extrusion recycling of waste PET (polyester) films
CN102642312B (en) * 2012-05-21 2014-05-21 福建百宏高新材料实业有限公司 Processing method for recovering and processing PET (polyethylene glycol terephthalate) waste film in compounding way by using twin-screw extrusion melting
CN106223528A (en) * 2016-08-31 2016-12-14 湖南宝信云建筑综合服务平台股份有限公司 A kind of novel building mechanism being easily installed use

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