CN102031075B - Environmentally-friendly energy-saving cigarette adhesive and production method thereof - Google Patents
Environmentally-friendly energy-saving cigarette adhesive and production method thereof Download PDFInfo
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- CN102031075B CN102031075B CN 200910095045 CN200910095045A CN102031075B CN 102031075 B CN102031075 B CN 102031075B CN 200910095045 CN200910095045 CN 200910095045 CN 200910095045 A CN200910095045 A CN 200910095045A CN 102031075 B CN102031075 B CN 102031075B
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Abstract
The invention discloses an environmentally-friendly energy-saving cigarette adhesive, which comprises 20 to 33 percent of base material, 65 to 78 percent of water-soluble vinyl acetate elastomer (VAE) series raw materials for preparing the cigarette adhesive according to the adhesive kind needed by the cigarette adhesive and the base material, and 0.001 to 0.008 percent of antifoaming agent, 0.007 to 0.02 percent of plasticizer and 0.005 to 0.05 percent of edible ethanol in an adhesive-making process, wherein the base material is prepared by the following steps of: adding high-purity polyvinyl chloride (PVC) and deionized water according to a ratio of the water to the PVC of 4:1 into a reaction kettle, and raising the temperature to 95 DEG C for dissolving; and adding 25 to 60 weight percent of selected VAE emulsion based on the prepared product, and sealing the reaction kettle to prepare the base material. The cigarette adhesive is prepared by dripping the antifoaming agent, the plasticizer, the edible ethanol and solution of sodium carbonate and sealing the reaction kettle. Therefore, the liquidity, adhesiveness, cohesion, freezing resistance and corrosion resistance of the adhesive are improved.
Description
Technical field
The invention belongs to a kind of environmental protection and energy saving cigarette glue and production method thereof.
Background technology
Cigarette glue is the tackiness agent that uses in the production of cigarettes, and along with the development of cigarette machine technology, cigarette machine speed brings up to 8000 by 6000 of original per minutes---16000 cigarette speed.The cigarette glue that original synthesis technology is produced is difficult to adapt to high-speed cigarette machine to the bonding requirement of cigarette, and the production time is long, power consumption is high.Along with the raising of environmental requirement, also more and more stricter to the requirement of the harmful substance contents in the glue.Need to use the cigarette glue that does not contain the oxious components such as benzene, lead, arsenic.Thereby, have the new demand that cigarette glue product energy-conservation in high speed cohesiveness, environmental protection and the production has become cigarette industry.
Summary of the invention
Purpose of the present invention discloses exactly and a kind ofly can adapt to high speed cigarette bonding, environmental protection, energy-conservation and the simple environmental protection and energy saving cigarette glue of technique and production method thereof.
The environmental protection and energy saving cigarette glue, comprise base-material, be deployed into the defoamer of using in the water-soluble VAE series raw material of cigarette glue and the adhesive-preparing technology by the required glue kind of cigarette glue and base-material, softening agent, edible ethanol, the base-material that comprises 20-33% in the constituent, VAE65-78%, defoamer: 0.001-0.008%, softening agent: 0.007-0.02%, edible ethanol: 0.005-0.05%, wherein base-material is by high purity PVA and deionized water, by water: PVA=4: 1 enters reactor, dissolve under temperature rise to the 95 ℃ condition, by the 25-60% of formulated product weight, add selected VAE emulsion again, sealed reactor makes.According to the overlapping glue in the cigarette working procedure, connecing mouth glue, centre-line glue, capsule packing glue, barrel packing colloidality can requirement, taken amount is sealed in the cigarette glue that makes above-mentioned application target requirement in the reactor in proportion.Improved glue flowability, binding property, hold viscosity, frost resistance and antiseptic property.
The production method of environmental protection and energy saving cigarette glue:
Method one, the production method of environmental protection and energy saving cigarette glue, comprise that base-material is made and the preparation of glue kind, the base-material blending process is high purity PVA and the deionized water that selects Sweet natural gas synthetic, by water: PVA=4: 1 enters reactor, through soaking, the still skin adds the steam rising temperature for dissolving, dissolve under temperature rise to the 95 ℃ condition, in still, press the speed that per minute 10-50 rises, kind by the glue of producing, 25-60% by formulated product weight, add selected VAE emulsion, and the speed titration 0.001-0.008% defoamer that rises with per minute 0.1-1, the 0.007-0.02% softening agent, the 0.005-0.05% edible ethanol, sealed reactor, extract residual monomer ethanol, ethene is cooled to normal temperature, and strainer filtering and detection obtain base-material.
Press the solids content of the cigarette glue of required kind, viscosity, the requirement of pH value, select the nontoxic water-soluble VAE705 that meets environmental requirement, VAE707, the VAE-I type, the VAE-II type, 149, in 8265 raw materials two to three kinds, with above-mentioned synthetic base-material, by the technical requirements of required glue kind, in gross weight, get base-material 20-33%, VAE65-78%, add again by product weight, edible ethanol 0.005-0.05%, defoamer 0.001-0.008%, softening agent 0.007-0.02%, yellow soda ash 0.5-1.5%, these auxiliary material total amounts are not more than 2%, adjust pH 4-6, with conventional dispensing mode, be deployed into the cigarette glue of various performance requriementss by the kind technical requirements of required glue.
Press such scheme, get base-material be no less than 25% with any 2 to 3 kinds that are not more than in 73% the VAE series raw material, adding is not more than 2% edible ethanol, defoamer, softening agent, yellow soda ash, and adjust pH 4-6 can be mixed with the cigarette glue that is fit to various performance requriementss.
Method 2, be the PVA lysate of 10-30% with solids content, with in water-soluble VAE705, VAE707, VAE-I type, VAE-II type, 149, the raw materials such as 8265 two to three kinds, by weight with PVA lysate 10-23%, VAE75-88%, add again by product weight, edible ethanol 0.005-0.05%, defoamer 0.001-0.008%, softening agent 0.007-0.02%, yellow soda ash 0.5-1.5%, these auxiliary material total amounts are not more than 2%, adjust pH 4-6, the direct cigarette glue that is deployed into various performance requriementss by the kind technical requirements of required glue.
This Technology has changed original synthesis technique, cancelled and used vinyl acetate between to for plastic to add the reaction process of the raw materials such as ammonium persulphate and OP-10 in the former technique, reduced objectionable impurities, all used nontoxic PVA and VAE series emulsion, calculated to prepare 1000 kilograms of cigarette glues, old explained hereafter needs 12 hours, novel process only needs 5 hours, makes that technique is simple, constant product quality, and it is bonding to adapt to high speed, save the energy consumptions such as water, electricity, gas, bonding, environmental protection, energy-saving effect are remarkable.
Embodiment
1, the environmental protection and energy saving cigarette glue is selected the synthetic high purity polyethylene alcohol (PVA) of Sweet natural gas, uses first deionized water, and by water: PVA=4: 1 enters reactor soaks and is no less than 4 hours, in the outer adding of still steam rising temperature for dissolving gradually.Temperature rises to dissolves after 1 hour under 95 ℃ of conditions, press the speed that per minute 10-50 rises, the VAE emulsion that slowly adds formulated product weight 25-60% in the still, cancel by weight proportion the amount of infusion 0.001-0.008%, softening agent 0.007-0.02%, edible ethanol 0.5-5%, the flow titration that rises with per minute 0.1-1 adds in the still; Sealed reactor extracts residual ethanol, vinyl monomer 1 hour, is cooled to 20-28 ℃, filters with the 160-200 mesh filter screen, detects viscosity, solids content is for subsequent use as base-material.
2, by technical requirementss such as the dry powder weight of the solid content solids content 25-55% of required cigarette glue, viscosity 80-6500mpa.spH value 4-6, by 100 kilograms of glue of preparation, get 25 kilograms of the synthetic base-materials of 73 kilograms of any two to three kinds of raw materials and step 1 in the nontoxic water-soluble VAE705, the VAE707 that meet environmental requirement, VAE-I type, VAE-II type, 149, the raw materials such as 8265, add 2 kilograms of defoamer, softening agent, edible ethanol and yellow soda ash sums.By 100 kilograms of glue amounts, wherein edible ethanol 0.005-0.05%, defoamer 0.001-0.008%, softening agent 0.007-0.02%, yellow soda ash 0.5-1.5%, adjust pH 4-6.Be mixed with high tack, high workability by the overlapping glue that uses in the cigarette process, the technological standard that connects mouth glue, centre-line glue, packing glue and performance requriements, the machine speed that adapts to high speed cigarette is that 8000-16000 props up/cigarette glue of minute mentioned kind that bonding is good.
The same technique, the parts by weights meter, according to VAE: base-material, get respectively 75 kilograms: 23 kilograms, 70 kilograms: 28 kilograms, 71 kilograms: 27 kilograms, 68 kilograms: 30 kilograms, 65 kilograms: 33 kilograms, press again overall control at 2 kilograms, add edible ethanol defoamer, softening agent, yellow soda ash.Adjust pH 4-6 is deployed into the cigarette glue of various performance requriementss by the kind technical requirements of required glue.
3, with solids content be the PVA lysate of 10-30%, with in water-soluble VAE705, VAE707, VAE-I type, VAE-II type, 149, the raw materials such as 8265 two to three kinds, by 100 kilograms of glue of preparation, get 15 kilograms of PVA lysates, the VAE83 kilogram, add again by product weight, edible ethanol 0.005-0.05%, defoamer 0.001-0.008%, softening agent 0.007-0.02%, yellow soda ash 0.5-1.5%, these auxiliary material total amounts are not more than 2 kilograms, adjust pH 4-6, directly the kind technical requirements by required glue is deployed into cigarette glue.
With above-mentioned identical technique, to prepare 100 kilograms, according to PVA: VAE, get respectively PVA and the VAE of 12: 86,18: 70,20: 78,11: 87,23: 75 kilogram numbers, adding edible ethanol, defoamer, softening agent, yellow soda ash are made auxiliary material, total amount is not more than 2 kilograms, and adjust pH 4-6 is deployed into desired cigarette glue.
Claims (5)
1. environmental protection and energy saving cigarette glue, it is characterized in that comprising base-material, be deployed into defoamer, softening agent, the edible ethanol of using in the water-soluble VAE series raw material of cigarette glue and the adhesive-preparing technology by the required glue kind of cigarette glue and base-material, the base-material that comprises 20-33% in the constituent, VAE 65-78%, defoamer: 0.001-0.008%, softening agent: 0.007-0.02%, edible ethanol: 0.005-0.05%; Wherein base-material is by high purity PVA and deionized water, by water: PVA=4: 1 enters reactor, dissolve under temperature rise to the 95 ℃ condition, press again the 25-60% of formulated product weight, add solids content, viscosity, the requirement of pH value by the cigarette glue of required kind, two to three kinds of VAE emulsions, sealed reactors selected from the nontoxic water-soluble VAE705, the VAE707 that meet environmental requirement, VAE-I type, VAE-II type, 149,8265 raw materials make.
2. the production method of environmental protection and energy saving cigarette glue, comprise that base-material is made and the preparation of glue kind, it is characterized in that: the base-material blending process is high purity PVA and the deionized water that selects Sweet natural gas synthetic, by water: PVA=4: 1 enters reactor, through soaking, the still skin adds the steam rising temperature for dissolving, dissolve under temperature rise to the 95 ℃ condition, in still, press the speed that per minute 10-50 rises, kind by the glue of producing, 25-60% by formulated product weight, add the solids content by the cigarette glue of required kind, viscosity, the requirement of pH value, from the nontoxic water-soluble VAE705 that meets environmental requirement, VAE707, the VAE-I type, the VAE-II type, 149, two to three kinds of VAE emulsions selecting in 8265 raw materials, and the speed titration 0.001-0.008% defoamer that rises with per minute 0.1-1, the 0.007-0.02% softening agent, the 0.005-0.05% edible ethanol, sealed reactor, extract residual monomer ethanol, ethene, be cooled to normal temperature, strainer filtering and detection obtain base-material.
3. the production method of environmental protection and energy saving cigarette glue according to claim 2, it is characterized in that the solids content by the cigarette glue of required kind, viscosity, the requirement of pH value, select the nontoxic water-soluble VAE705 that meets environmental requirement, VAE707, the VAE-I type, the VAE-II type, 149, in 8265 raw materials two to three kinds, with above-mentioned synthetic base-material, by the technical requirements of required glue kind, in gross weight, get base-material 20-33%, VAE65-78%, add again by product weight, edible ethanol 0.005-0.05%, defoamer 0.001-0.008%, softening agent 0.007-0.02%, yellow soda ash 0.5-1.5%, these auxiliary material total amounts are not more than 2%, adjust pH 4-6 with conventional dispensing mode, is deployed into the cigarette glue of various performance requriementss by the kind technical requirements of required glue.
4. the production method of environmental protection and energy saving cigarette glue according to claim 3, it is characterized in that by weight percentage meter, get base-material be not more than 33% with any 2 to 3 kinds that are not more than in 78% the VAE series raw material, add total amount and be not more than 2% edible ethanol, defoamer, softening agent, yellow soda ash, adjust pH 4-6 can be mixed with the cigarette glue that is fit to various performance requriementss.
5. the production method of environmental protection and energy saving cigarette glue according to claim 3, it is characterized in that with solids content being the PVC lysate of 10-30%, with water-soluble VAE705, VAE707, the VAE-I type, the VAE-II type, 149, in 8265 raw materials two to three kinds, press restatement, get PVA lysate 10-23%, VAE 75-88%, add again by product weight, edible ethanol 0.005-0.05%, defoamer 0.001-0.008%, softening agent 0.007-0.02%, yellow soda ash 0.5-1.5%, these auxiliary material total amounts are not more than 2%, adjust pH 4-6, the direct cigarette glue that is deployed into various performance requriementss by the kind technical requirements of required glue.
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| CN102031075B true CN102031075B (en) | 2013-02-27 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
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| CN103773273B (en) * | 2012-10-20 | 2016-02-24 | 中国烟草总公司郑州烟草研究院 | A kind of based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization |
| CN102965056B (en) * | 2012-10-31 | 2014-12-03 | 刘斐 | Water-based adhesive and preparation method thereof |
| CN103059774B (en) * | 2012-12-26 | 2015-01-28 | 海南必凯水性涂料有限公司 | Waterproof environment-friendly cigarette plug molding glue and preparing method thereof |
| CN103059779B (en) * | 2012-12-26 | 2015-01-21 | 海南必凯水性涂料有限公司 | Environment-friendly type lap joint port glue used for high speed cigarette making machine and preparation method thereof |
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| CN103059778B (en) * | 2012-12-26 | 2015-02-25 | 海南必凯水性涂料有限公司 | Cigarette environment-friendly high-speed packaging glue and preparation method thereof |
| CN108893084A (en) * | 2018-06-21 | 2018-11-27 | 江苏光辉粘合科技有限公司 | 399B low softening point hot melt adhesive |
| CN108913060A (en) * | 2018-06-21 | 2018-11-30 | 江苏光辉粘合科技有限公司 | Ramuscule is sprayed glue |
| CN109294488B (en) * | 2018-09-19 | 2020-11-10 | 湖北恒阳科技发展有限公司 | Water-based laser packaging adhesive for cigarettes and preparation method thereof |
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Patent Citations (5)
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| CN1081703A (en) * | 1992-07-29 | 1994-02-09 | 李有才 | A kind of preparation method of cigarette glue |
| CN1159472A (en) * | 1996-12-20 | 1997-09-17 | 田素军 | Special glue for lamination of aluminium foil |
| US6568399B1 (en) * | 1999-04-26 | 2003-05-27 | National Starch And Chemical Investment Holding Corporation | Low application temperature hot melt adhesive for cigarette preparation |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
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| CN102031075A (en) | 2011-04-27 |
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