CN102047899A - Pest control composition and pest control method - Google Patents
Pest control composition and pest control method Download PDFInfo
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- CN102047899A CN102047899A CN2010105312904A CN201010531290A CN102047899A CN 102047899 A CN102047899 A CN 102047899A CN 2010105312904 A CN2010105312904 A CN 2010105312904A CN 201010531290 A CN201010531290 A CN 201010531290A CN 102047899 A CN102047899 A CN 102047899A
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Abstract
The invention relates to a pest control composition and a pest control method. The pest control composition has an efficient control effect on pests. The pest control composition comprises an ester compound represented by the following formula (I) and a combination of ester compounds represented by the following formula (II).
Description
Technical field
The present invention relates to the method for preventing and treating of pest control composition (pest control composition) and insect.
Background technology
Known by the ester compounds of following formula (I) expression is the effective ingredient (for example, referring to JP 57-123146A and CN 101306997A) of control of insect preparation:
In addition, also known by the ester compounds of following formula (II) expression is the effective ingredient (for example, referring to JP 60-9715B) of control of insect preparation:
But, in some situation, depend on application-specific and the insect that is prevented and treated, need compare control of insect preparation with this type of known formulations with more superior control efficiency.
Summary of the invention
Will be by the problem of the present invention's solution
An object of the present invention is to provide the pest control composition and the insect pest control method that insect are had outstanding control efficiency.
Be used to solve the means of described problem
Because the intensive research of the inventor has been found that by the ester compounds of formula (I) expression and being used in combination of being represented by formula (II) of ester compounds to demonstrate outstanding pest controling effect.Finished the present invention thus.
That is to say, the invention provides:
(1) pest control composition, it comprises the combination as the following material of effective ingredient: by the ester compounds of following formula (I) expression:
(hereinafter referred to as ester compounds A of the present invention) and the ester compounds of representing by following formula (II):
(hereinafter referred to as ester compounds B of the present invention);
(2) according to above (1) described pest control composition (preventing and treating composition hereinafter referred to as the present invention), the weight ratio of ester compounds A wherein of the present invention and ester compounds B of the present invention is 50: 1 to 1: 50;
(3) insect pest control method, it comprises to insect or insect survival zone and applies the ester compounds A of the present invention of effective dose and the combination of ester compounds B of the present invention; With
(4) combination of ester compounds A of the present invention and ester compounds B of the present invention is used for the purposes of pest control.
Effect of the present invention
Control composition of the present invention and the method for preventing and treating demonstrate outstanding pest controling effect.
Embodiment
The present invention prevents and treats composition and is characterised in that it comprises ester compounds A of the present invention and ester compounds B of the present invention.
For example method manufacturing of ester compounds A of the present invention by describing among the JP 57-123146A.
For example method manufacturing of ester compounds B of the present invention by describing among the JP 60-9715B.
Among ester compounds A of the present invention and the ester compounds B of the present invention each all has the isomer based on two asymmetric carbon atoms on its cyclopropane ring.Among the present invention, can use the described ester compounds of the active isomer that comprises any ratio.
The present invention prevent and treat compositions display go out control efficiency at the example of insect comprise harmful arthropod (arthropods), for example insect pest (insect pests) and acarian insect (acarine pests).Its instantiation is as follows.
Lepidoptera (Lepidoptera) insect pest:
Snout moth (Pyralid moths) (Pyralidae (Pyralidae)) is rice-stem borer (rice stem borer) (striped rice borer (Chilo suppressalis)), rice leaf roller (rice leafroller) (cnaphalocrocis medinalls guenee (Cnaphalocrocis medinalis)) and Indian meal moth (Indian meal moth) (Indian meal moth (Plodia interpunctella)) for example; Noctuid (owlet moths) (Noctuidae (Noctuidae)) is prodenia litura (common cutworm) (prodenia litura (Spodoptera litura)), beet armyworm (beet armyworm) (beet armyworm (Spodoptera exigua)), paddy rice mythimna separata (rice armyworm) (mythimna separata (Pseudaletia separata)) and tomato moth (cabbage armyworm) (tomato moth (Mamestra brassicae)) for example; White butterfly (white butterflies) (Sulfur butterfly (Pieridae)) for example common white butterfly (common white) (pieris rapae (Pieris rapae)); Leaf roller (tortricid moths) (Tortricidae (Tortricidae)) for example Adoxophyes spp belongs to (Adoxophyes spp.); Fruit worm moth (fruitworm moths) (Carposinidae (Carposinidae)); Lyonetid (lyonetiid moths) (lyonetid section (Lyonetiidae)); Poison moth (tussock moths) (Lymantriidae (Lymantriidae)); Plussid belongs to (Plusiae); Agrotis (Agrotis spp.) is white line dart moth of turnip (cutworm) (white line dart moth of turnip (Agrotis segetum)) and black cutworm (bluck cutworm) (black cutworm (Agrotis ipsilon)) for example; Heliothis (Helicoverpa spp.); Heliothis (Heliothis spp.); Diamond-back moth (diamondback) (diamond-back moth (Plutella xylostella); Straight burr rice hesperiidae (common straight swift) (straight burr rice hesperiidae (Pamara guttata)); Pale yellow casemaking clothes moth (casemaking clothes moth) (casemaking clothes moth (Tinea translucens)); And webbing clothes moth (webbing clothes moth) (casemaking clothes moth (Tineola bisselliella)).
Diptera (Diptera) insect pest:
Mosquito (Mosquitos) (Dulicidae (Calicidae)) is common mosquito (Culex pipiens pallens (Culex pipiens pallens)), Culex tritaeniorhynchus (Culex tritaeniorhynchus) and northern house five band subspecies (Southern house mosquito) (northern house five band subspecies (Culex quinquefasciatus)) for example; Aedes (Aedes spp.) is yellow fever yellow-fever mosquito (yellow fever mosquito) (Aedes aegypti (Aedes aegypti)) and Asia tiger mosquito (Asian tiger mosquito) (aedes albopictus (Aedes albopictus)) for example; Anopheles (Anopheles spp.) is Anopheles sinensis (Anopheles sinensis) for example; Midge (midges) (Chironomidae (Chironomidae)); Housefly (houseflies) (Nuscidae (Muscidae)) is housefly (housefly) (housefly (Musca domestica)), Musca bezzi, false stable fly (false stable fly) (false stable fly (Muscina stabulans)) and lesser hosefly (lesser housefly) (Fannia canicularis (Fannia canicularis)) for example; Calliphorid (blow flies) (Calliphoridae (Calliphoridae)); Sarcophagid (flesh flies) (Flesh flies (Sarcophagidae)); Flowerfly (anthomyiid flies) (Anthomyiidae (Anthomyiidae)) is delia platura (seedcorn maggot) (delia platura (Delia platura)) and onion fly (onion maggot) (onion fly (Delia antiqua)) for example; Sepsidae (black scavenger flies) (Sepsidae (Sepidae)); Trypetid (fruit flies) (Tephritidae (Tephritidae)); Liriomyza (leaf-miner flies) (Agromyzidae (Agromyzidae)); The for example common fruit bat of Drosophilidae (small fruit flies) (Drosophilidae (Drosophilidae)) (common fruit fly) (Drosophila melanogaster (Drosophila melanogaster)); Moth fly (moth flies) (Moth files (Psychodidae)); Eye fly (Phorid flies) (Phoridae (Phoridae)) is eye fly (humpbacked fly) (eye fly (Megasalia spiracularis)) for example; Black fly (black flies) (buffalo gnat subfamily (Simuliidae)); Horsefly (horse flies) (Tabanidae (Tabanidae)); Sting fly (stable flies) (stinging Nuscidae (Stomoxyidae)); And midge (biting midges) (Heleidae (Ceratopogonidae)).
Dictyoptera (Dictyoptera) insect pest:
Blattaria (Cockroaches) (Lian section (Blattariae)) is blatta germanica (German cockroach) (blatta germanica (Blattella germanica)) for example, smoke Perilpaneta americana (smokybrown cockroach) (smoke Perilpaneta americana (Periplaneta fuliginosa)), American cockroach (American cockroach) (American cockroach (Periplaneta americana)), the big Lian of foxiness (blown cockroach) (the big Lian of foxiness (Periplaneta brunnea)), and oriental cockroach (oriental cockroach) (oriental cockroach (Blatta orientalia)).
Hymenoptera (Hymenoptera) insect pest:
Ant (Ants) (Formicidae (Formicidae)); Wasp (hornets) (Vespidae (Vespidae)); Swollen leg honeybee (Bethylid wasps) (Bethylidae (Betylidae)); And sawfly (sawflies) (swaflies (Tenthredinidae)) cabbage sawfly (cabbage sawfly) (cabbage sawfly (Athalia rosae)) for example.
Siphonaptera (Aphaniptera) insect pest:
Dog flea (Dog flea) (ctenocephalides canis (Ctenocephalides canis)), cat flea (cat flea) (ctenocephalides felis nominate subspecies (Ctenocephalides feils)) and Pulex irritans (human flea) (Pulex irritans (Purex irritans)).
Anoplura (Anoplura) insect pest:
Humanlice (Human louse) (humanlice (Pediculus humans)), crab louse (crab louse) (crab louse (Phthirus pubis)), head louse (head louse) (head louse (Pediculus humans capitis)) and body louse (human body louse) (body louse (Pediculus humanus corporis)).
Isoptera (Isoptera) insect pest:
Eastern subterranean termite (Japanese subterranean termite) (eastern subterranean termite (Reticulitermes speratus)) and Taiwan formosanes (Formosan subterranean termite) (coptotermes formosanus (Coptotermes formosanus)).
Semiptera (Hemiptera) insect pest:
Plant hopper (Planthoppers) (Delphacidae (Delphacidae)) is small brown rice planthopper (small brown planthopper) (small brown rice planthopper (Laodelphax striatellus)), brown planthopper (brown rice planthopper) (brown planthopper (Nilaparvata lugens)) and white-backed planthopper (white-backed rice planthopper) (white-backed planthopper (Sogatella furcifera)) for example; Leafhopper (leafhoppers) (angle top cicada subfamily (Deltocephalidae)) is rice leafhopper (green rice leafhopper) (rice leafhopper (Nephotettix cincticeps)) and Taiwan rice leafhopper (Taiwan green rice leafhopper) (nephotettix bipunctatus (Nephotettix virescens)) for example; Aphid (aphids) (Aphidiadae (Aphididae)); Stinkbug (stink bugs) (Pentatomiddae (Pentatomidae)); Aleyrodid (whiteflies) (Aleyrodidae (Aleyrodidae)); A red-spotted lizard (scales) (a red-spotted lizard section (Coccidae)); Bedbug (Cimices) is bed bug (Cimex lectularius) for example; Lace bug (lace bugs) (Tingidae (Tingidae)); And wood louse (psyllids) (Psyllidae (Psyllidae)).
Coleoptera (Coleoptera) insect pest:
Chrysomelid (Corn root worms) (chrysomelid genus (Diabrotica spp.)) be black wool khapra beetle (black carpet beetle) (black japan khapra beetle (Attagenus japonicus)) for example, roundlet khapra beetle (varied carpet beetle) (roundlet khapra beetle (Anthreus verbasci)), corn root leaf A (Western corn root worm) (corn root leaf A (Diabrotica virgifera)), with cucumber 11 asterophyllite first food root subspecies (Southern corn root worm) (cucumber 11 asterophyllite first food root subspecies (Diabrotica undecimpunctata howardi)); Chafer (scarabs) (Scarabaeidae (Scarabaeidae)) is Anomala cuprea Hope (cupreous chafer) (Anomala cuprea Hope (Anomala cuprea)) and red metal rutelian (soybean beetle) (red metal rutelian (Anomala rufocuprea)) for example; Weevil (weevils) (Culculionidae (Curculionidae)) is corn weevil (maize weevil) (corn weevil (Sitophilus zeamais)), rice root weevil (rice water weevil) (rice root weevil (Lissorhoptrus oryzophilus)), boll weevil (boll weevil) (cotton boll resembles (Anthonomus grandis)) and adzuki bean weevil (azuki bean weevil) (adzuki bean weevil (Callosobruchus chinensis)) for example; Intend ground beetle (darkling beetles) (TRenebrionidae (Tenebrionidae)) for example yellow mealworm (yellow mealworm) (yellow mealworm (Tenebrio molitor)) and red flour beetle (red flour beetle) (red flour beetle (Tribolium castaneum)); Chrysomelid (leaf beetles) (Chrysomelidae (Chrysomelidae)) be Oulema oryzae (rice leaf beetle) (Oulema oryzae (Oulema oryzae)), phyllotreta striolata (striped flea beetle) (phyllotreta striolata (Phyllotreta striolata)) and aulacophora femoralis (cucurbit leaf beetle) (aulacophora femoralis (Aulacophora femoralis)) for example; Death watch beetle (drugstore beetles) (Anobiidae (Anobiidae)); Epilachna genus (Epilachna spp.) is potato ladybug (twenty-eight-spotted ladybird) (ladybug of eggplant 28 stars (Epilachna vigintioctopunctata)) for example; Powder moth (powder post beetles) (Lyctidae (Lyctinae)); Bostrichidae (false powder post beetles) (Bostrichidae (Bostrichidae)); Longicorn (longhorn beetles) (Cerambycidae (Cerambycidae)); And rove beetle (rove beetle) (Paederus fuscipes Curtis (Paederus fuscipes)).
Thrips (Thysanoptera) insect pest:
Joint melon thrips (Melon thrips) (palm thrips (Thrips palmi)), citrus thrips (yellow citrus thrips) (Frankliniella occidentalis (Frankliniella occidentalis)) and flower thrips (flower thrips) (flower thrips (Frankliniella intonsa)).
Orthoptera (Orthoptera) insect pest:
Mole cricket (Mole crickets) (Gryllotalpidae (Gryllotalpidae)) and locust (grasshoppers) (locust section (Acrididae)).
Acarina (Acarina):
Dermatophagoides pteronyssinus (House dust mites) (dirt mite section (Pyroglyphidae)) for example dust mite (Dermatophagoides farinae) and spy is had a liking for skin mite (Dermatophagoides ptrenyssnus); Flour mite (Acarid mites) (Tyroglyphidae (Acaridae)) is tyrophagus putrescentiae (mold mite) (tyrophagus putrescentiae (Tyrophagus putrescentiae)) and oval baking soda mite (Aleuroglyphus ovatus) for example; The for example concealed sweet mite of sweet mite (Glycyphagid mites) (Glycyphagus privatus), family have a liking for sweet mite (Glycyphagus domesticus) and commonly have a liking for sweet mite (Glycyphagus destructgor); Cheyletid mite (Cheyletide mites) (cheyletidae (Cheyletidae)) is Malacca cheyletid mite (Cheyletus malaccensis) and strong cheyletid mite (Cheyletus fortis) for example; Tarsonemid (Tarsonemid mites) (Tarsonemidae (Tarsonemidae)); Have a liking for slag mite (Chortoglyphid mites) (having a liking for slag mite section (Chortoglyphidae)); Haplochthoniid mites (single first mite section (Haplochthoniidae)); Tetranychid (spider mites) (Tetranychidae (Tetranychidae)) is two-spotted spider mite (two-spotted spider mite) (cotton spider mites (Tetranychus urticae)) for example, refreshing Ze Shi tetranychid (Kanzawa spider mite) (kamisawa tetranychus (Tetranychus kanzawai)), citrus red mite (citrus red mite) (tangerine Panonychus citri (Panonychus citri)), and European red mite (European red mite) (elm Panonychus citri (Panonychus ulmi)); Ixodoidea (ticks) (hard tick section (Ixodidae)) is haemaphysalis longicornis (Haemaphysalis longicornis) for example; With prickle mite (parasitoid mites) (Dermanyssidae (Dermanyssidae)) for example northern fowl mite (northern fowl mite) (northern fowl mite (Ornithonyssus sylviarum)) and poultry two spotted spider mite (poultry red mite) (Dermanyssus gallinae (Dermanyssus gallinae)).
Especially, the present invention prevents and treats composition the dipteral insect insect is demonstrated outstanding control efficiency, and housefly (Nuscidae) is demonstrated more outstanding control efficiency.
Prevent and treat in the composition in the present invention, the weight ratio of ester compounds A of the present invention and ester compounds B of the present invention is not particularly limited, as long as keep the outstanding control efficiency of the present invention.Usually, described weight ratio is 50: 1 to 1: 50, preferred 10: 1 to 1: 10.
The present invention prevents and treats the simple mixtures that composition can be ester compounds A of the present invention and ester compounds B of the present invention.But it uses with the form of various preparatons usually.The example of described preparaton comprises oil solution, emulsifiable concentrate, wetting powder, suspending concentrate (for example suspension in water and the emulsion in water), the microcapsules preparaton, powder, granula, tablet, aerosol, the carbonic acid gas preparaton, heating evaporation preparaton (mosquito repellent coil disc for example, electric mat, with absorption of fluids core pattern insecticide), the pressure-type spray insecticide, heating fumigating agent (fumigant) (spontaneous combustion fumigant for example, chemical reaction type fumigant and porous ceramic plate fumigant), non-heating fumigating agent (resin fumigant for example, the paper fumigant, the adhesive-bonded fabric fumigant, the Woven fabric fumigant, with the sublimation tablet), sootiness preparaton (for example aerosol), directly (for example sheet type contacts preparaton to the contact preparaton, strip-type contact preparaton, contact preparaton with network-type), ULV preparaton and poison bait.
Described preparaton can for example prepare by the following method.
(1) ester compounds A of the present invention and ester compounds B of the present invention and solid carrier, liquid-carrier, carrier gas or feed and other auxiliary agent such as the surfactant that if necessary are used for preparaton are mixed.
(2) with ester compounds A of the present invention and ester compounds B impregnation matrix material of the present invention.
(3) ester compounds A of the present invention, ester compounds B of the present invention and matrix material are mixed, molded then.
These preparatons comprise ester compounds A of the present invention and the ester compounds B of the present invention that total amount is 0.001-98 weight % usually.
The example that is used for the solid carrier of described preparaton comprises fine powder and particle, clay (for example kaolin, diatomite, bentonite, Fubasami clay and acid white clay) for example, synthetic hydrated silica, talcum, pottery, other inorganic mineral (for example sericite, quartz (quarts), sulphur, active carbon, calcium carbonate and hydrated SiO 2), and chemical fertilizer (for example ammonium sulfate, ammonium phosphate, ammonium nitrate, ammonium chloride and urea); With at normal temperature be solid material (for example 2,4,6-triisopropyl-1,3,5-three
Alkane, naphthalene, paracide, camphor, and adamantane) with by one or more felts of forming, fiber, cloth, Woven fabric, sheet material, paper, silk thread, foam, porous material and multifilament in the following material: wool, silk, cotton, hemp, paper pulp, synthetic resin (for example polyvinyl resin, for example low density polyethylene (LDPE), linear low density of polyethylene, and high density polyethylene (HDPE); Ethylene-vinyl ester copolymer is vinyl-vinyl acetate copolymer for example; Ethylene-methyl acrylate copolymer, for example ethylene-methyl methacrylate methyl terpolymer and ethylene-methyl methacrylate ethyl ester copolymer; Vinyl-acrylate copolymer, for example ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; Ethene-vinyl carboxylate copolymer, for example ethylene-acrylic acid copolymer; Ethene-tetracyclododecane copolymer; Acrylic resin, for example Noblen and propylene-ethylene copolymers; Poly--4-methylpentene-1; PB Polybutene-1; Polybutadiene; Polystyrene; Acrylonitrile-styrene resin; Styrenic elastomer, for example acrylonitrile-butadiene-styrene resin, styrene-conjugated diene block copolymer and hydrogenated styrene-conjugated diene block copolymer; Fluoroplastics; Acrylic resin, for example polymethyl methacrylate; Polyamide, for example nylon 6 and nylon 66; Mylar, for example PETG, PEN, polybutylene terephthalate (PBT) and poly terephthalic acid cyclohexanedimethanoester ester (polycyclohexylene dimethyleneterephthalate); Merlon; Polyacetals; Polyarylsulfone (PAS) (polyacrylsulfone); Polyarylate (polyarylate); Poly-hydroxybenzoate; PEI; Polyestercarbonate; Polyphenylene oxide resin; Polyvinyl chloride; Polyvinylidene chloride; Polyurethane; With porous resin such as polyurathamc, expanded polypropylene and polyethylene foamed), glass, metal and pottery.
The example of liquid-carrier comprises aromatics or aliphatic hydrocarbon (dimethylbenzene for example, toluene, Fluhyzon, phenyl xylyl ethane, kerosene, light oil, hexane, and cyclohexane), halogenated hydrocarbons (for example chlorobenzene, carrene, dichloroethane, and trichloroethanes), alcohol (methyl alcohol for example, ethanol, isopropyl alcohol, butanols, hexanol, phenmethylol, and ethylene glycol), ether (diethyl ether for example, glycol dimethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, oxolane, and dioxane), ester (for example ethyl acetate, and butyl acetate), ketone (acetone for example, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), and cyclohexanone), nitrile (for example acetonitrile, and isobutyronitrile), sulfoxide (for example methyl-sulfoxide), acid amides (N for example, dinethylformamide, N,N-dimethylacetamide and N-methyl-pyrrolidones), alkylene carbonates (for example propylene carbonate), vegetable oil (for example soya-bean oil, and cottonseed oil), plants essential oil (for example orange oil, oil of hyssop (hyssop oil), and lemon oil) and water.
The example of carrier gas comprises butane gas, Chlorofluorocarbons (CFCs) gas, liquefied petroleum gas (LPG), dimethyl ether and carbonic acid gas.
The example of surfactant comprises alkyl sulfate salt, alkyl sulfonic ester/salt, alkyl aryl sulfonate/salt, alkyl aryl ether, the alkyl aryl ether of polyoxyethyleneization, polyglycol ether, polyol ester, and sugar alcohol derivant.
The example that is used for other auxiliary agent of preparaton comprises binding agent, dispersant and stabilizing agent.Its instantiation comprises casein, gelatin, polysaccharide (starch for example, gum Arabic, cellulose derivatives, and alginic acid (arginic acid)), lignin derivative, bentonite, sugar, synthetic water-soluble polymer (polyvinyl alcohol for example, PVP(polyvinyl pyrrolidone), and polyacrylic acid), BHT (2, and BHA (mixture of the 2-tert-butyl group-4-metoxyphenol and the 3-tert-butyl group-4-metoxyphenol) the 6-di-tert-butyl-4-methy phenol).
The example of mosquito repellent coil disc matrix material comprises the mixture of plant powder (for example timber powder and Dalmatian chrysanthemum) and binding agent (powder, starch and the glutelin of for example red nanmu (Machilus thunbergii)).
The example of electric mat matrix material comprises and ties, compresses and be compressed to the velveteen of plate shape, and and ties, compresses and be compressed to the composite fibre of the velveteen and the paper pulp of plate shape.
The example of spontaneous combustion fumigant matrix material comprises combustion heat developer (combustion heat-developing agents) as nitrate, nitrite, guanidinesalt, potassium chlorate, nitrocellulose, ethyl cellulose, and timber powder; Thermolysis stimulant such as alkali metal salt, alkali salt, bichromate, and chromate; Oxygen supplying such as potassium nitrate; Combustion adjuvant such as melamine, and wheaten starch; Filler such as diatomite; And binding agent such as composite adhesives.
The example of the matrix material of chemical reaction type fumigant comprises the heat development agent, for example alkali-metal sulphide, polysulfide and sulfhydrate, and calcium oxide; Catalyzer, for example carbonaceous material, cementite and activated clay; Organic foam agent, for example azodicarboamide (azodicarbonamide), benzene sulfonyl hydrazide, dinitropentamethylenetetramine, polystyrene and polyurethane; And filler, for example native fiber and synthetic fibers.
For example be used for that the example of the resin of resin fumigant comprises polyvinyl resin, for example low density polyethylene (LDPE), linear low density of polyethylene and high density polyethylene (HDPE); Ethylene-vinyl ester copolymer is vinyl-vinyl acetate copolymer for example; Ethylene-methyl acrylate copolymer, for example ethylene-methyl methacrylate methyl terpolymer and ethylene-methyl methacrylate ethyl ester copolymer; Vinyl-acrylate copolymer, for example ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; Ethene-vinyl carboxylate copolymer, for example ethylene-acrylic acid copolymer; Ethene-tetracyclododecane copolymer; Acrylic resin, for example Noblen and propylene-ethylene copolymers; Poly--4-methylpentene-1; PB Polybutene-1; Polybutadiene; Polystyrene; Acrylonitrile-styrene resin; Styrenic elastomer, for example acrylonitrile-butadiene-styrene resin, styrene-conjugated diene block copolymer and hydrogenated styrene-conjugated diene block copolymer; Fluoroplastics; Acrylic resin, for example polymethyl methacrylate; Polyamide, for example nylon 6 and nylon 66; Mylar, for example PETG, PEN, polybutylene terephthalate (PBT) and poly terephthalic acid cyclohexanedimethanoester ester; Merlon; Polyacetals; Polyarylsulfone (PAS) (polyacrylsulfone); Polyarylate; Poly-hydroxybenzoate; PEI; Polyestercarbonate; Polyphenylene oxide resin; Polyvinyl chloride; Polyvinylidene chloride; And polyurethane.They can use separately or in the mode of its combination.In addition, if necessary, can for example phthalic acid ester (for example repefral and dioctyl phthalate), adipate ester and stearic acid be added in these matrix materials with plasticizer.Enter in the matrix material by ester compounds A of the present invention and ester compounds B of the present invention are mediated, by injection moulding, extrusion modling or extrusion forming it is moldedly prepared described resin fumigant then.Gained resin preparaton can experience further processing, and for example molded and cutting if necessary is processed as the form of plate, film, band, net or rope.These resin preparatons can be processed as for example Animal neck ring, animal ear tag, sheet material preparaton, conductor rope (guide strings) and gardening supporter.
The example of poison bait matrix material comprises feed ingredient, such as grain powder, vegetable oil, sugar and avicel cellulose; Antioxidant is dibutyl hydroxy toluene and nordihydroguaiaretic acid for example; Preservative is dehydroactic acid for example; Children and pet accidental ingestion prevent for example capsicum of agent; With insect attractability flavouring agent (flavors) for example cheese flavor agent, onion flavouring agent and peanut oil.
Insect pest control method of the present invention is prevented and treated composition and is carried out by apply the present invention to insect and/or insect survival zone (for example plant corpus, soil, indoor and animal body).In addition, insect pest control method of the present invention also can be by applying ester compounds A of the present invention separately to insect and/or insect survival zone and ester compounds B of the present invention carries out.
Particularly, prevent and treat the applying method of composition as the present invention, the following method of can giving an example, and these methods can be for example according to the form of control composition with apply the selection of location-appropriate ground.
(1) the present invention is prevented and treated composition and be applied to insect and/or insect survival zone as it is.
(2) with solvent for example water dilution the present invention prevent and treat composition, put on insect and/or insect survival zone then.
Usually, in this case, dilution for example makes the total concentration of ester compounds A of the present invention and ester compounds B of the present invention become 0.01-1000ppm for the present invention of emulsifiable concentrate, wetting powder, suspending concentrate or microcapsule formulation form prevents and treats composition.
(3) prevent and treat composition so that the effective ingredient evaporation in the heating the present invention of insect survival zone.
In this case, the rate that applies of ester compounds A of the present invention and ester compounds B of the present invention and concentration can according to for example the present invention prevent and treat composition form, apply the cycle, apply the position, applying method and failure condition and suitably determine.
When utilizing the present invention to prevent and treat composition to be used for preventative purpose (preventative purpose), the rate that applies is 0.0001-1000mg/m usually when putting on the space with regard to the total amount of ester compounds A of the present invention and ester compounds B of the present invention
3, and be 0.0001-1000mg/m when putting on the plane
2Heating evaporation preparaton for example mosquito repellent coil disc and electric mat evaporates effective ingredient and applies by suitably heating according to the preparaton form.Non-heating fumigating agent for example resin fumigant, paper fumigant, tablet, adhesive-bonded fabric fumigant, Woven fabric fumigant and sheet material preparaton can be for example by described preparaton is retained in position to be applied as it is, or by using towards described preparaton blowing.
Applying the present invention prevents and treats composition and comprises closet, dressing table, bin, wardrobe, cabinet, toilet, bathroom, storeroom, living room, dining room, warehouse and vehicle interior with the example of the position that is used for preventative purpose.In addition, described composition can also be applied to outside open-air place.
When preventing and treating composition, the present invention is used for domestic animal such as ox, horse, pig, sheep, goat and chicken, and small animal such as dog, cat, rat and mouse, during with the control epizoa, to described animal applications animal doctor's known method.Particularly, be intended to general when control, described preparaton via tablet, be mixed in the feed, suppository and injection (comprise that muscle is interior, subcutaneous, intravenous and intraperitoneal injection) give.On the other hand, when being intended to the control of non-whole body, it uses via following mode: the spray oils solution or the aqueous solution, sprinkle to water or be coated with and hold up processings, wear necklace or the ear tag of being made by the resin preparaton with shampoo preparaton cleaning animal or to animal.The accumulated dose of ester compounds A of the present invention and ester compounds B of the present invention is the per 1 kilogram of animal body of 0.01-1000 milligram normally.
The present invention prevents and treats composition and can use with other mixture of ingredients with other composition combination or conduct, and described other composition for example is pest control agent such as other insecticides, miticide and pest repellant, synergist and pigment.
Hereinafter, the present invention will be described in more detail by preparaton embodiment and test implementation example.But the present invention is not limited.
At first, will the preparaton embodiment that the present invention prevents and treats composition be described.In preparaton embodiment, all " umbers " all are by weight, except as otherwise noted.
Preparaton embodiment 1
At 37.5 parts of dimethylbenzene and 37.5 parts of N, in the dinethylformamide, dissolve 9 parts of ester compounds A of the present invention and 0.9 part of ester compounds B of the present invention.In gained solution, add 9.1 parts of polyoxyethylene styryl phenyl ethers and 6 parts of calcium salt of dodecylbenzene sulfonate, fully mix gold then to obtain emulsifiable concentrate.
Preparaton embodiment 2
In 20 parts of ester compounds A of the present invention and 20 parts of ester compounds B of the present invention, add 5 parts of SORPOL 5060 (TOHO Chemical Industry Co., the registration mark of Ltd.), fully mix then.In the gained mixture, add 32 parts of CARPLEX#80 (Shionogi ﹠amp; Co., the registration mark of Ltd., synthetic hydrated SiO 2 powder) and 23 part of 300 order diatomite, use juice blender (juice mixer) to mix then to obtain wetting powder.
Preparaton embodiment 3
In 3 parts of ester compounds A of the present invention and 0.3 part of ester compounds B of the present invention, add 5 parts of synthetic hydrated SiO 2 powder, 5 parts of pelopon As, 30 parts of bentonites and 56.7 parts of clays, fully stir then and mix.Then, the water with appropriate amount is added in the gained mixture.Mixture is further stirred, use the comminutor granulation, and air-dry to obtain granular formulation.
Preparaton embodiment 4
In mortar, fully mix 5 parts of ester compounds A of the present invention, 0.5 part of ester compounds B of the present invention, 5 parts of synthetic hydrated SiO 2 powder, 1 part of DORILES B (trade name, Daiichi Sankyo Co., Ltd. make) as flocculant and 7 parts of clays, stir and mixing with the juice blender then.In the gained mixture, add 85.5 parts of cut clays (cut clay), fully stir then and mixing, to obtain powder formulation.
Preparaton embodiment 5
Mixture by 10 parts of ester compounds A of the present invention of wet lapping method fine grinding, 1 part of ester compounds B of the present invention, the 35 parts of white carbons of polyoxyethylene alkyl ether ammonium sulfate that comprise half amount and 54 parts of water is to obtain powder formulation.
Preparaton embodiment 6
In 10 parts of carrene, dissolve 0.05 part of ester compounds A of the present invention and 0.1 part of ester compounds B of the present invention, and gained solution and 89.85 parts of isoparaffic solvents (ISOPAR M, Exxon Chemical Co., the registration mark of Ltd.) are mixed to obtain oil solution.
Preparaton embodiment 7
In aerosol can, place 0.1 part of ester compounds A of the present invention, 0.05 part of ester compounds B of the present invention and 49.85 parts of Neothiozole (Chuo Kasei Co., Ltd.).After aerosol valve is installed, fill 25 parts of dimethyl ether and 25 parts of LPG, shake and further install actuator then to obtain the oiliness aerosol.
Preparaton embodiment 8
(Atomos 300 with 0.5 part of ester compounds A of the present invention, 0.05 part of ester compounds B of the present invention, 0.01 part of BHT, 5 parts of dimethylbenzene, 3.44 parts of deodorized kerosines and 1 part of emulsifier, Atomos Chemical Co., Ltd. mixture registration mark) and 50 parts of distilled water are filled in the aerosol container, and connect valve part.Then, under pressure via valve toward wherein filling 40 parts of propellants (LPG) to obtain aqueous aerosol.
Preparaton embodiment 9
With a paper workpiece (paper work) (it has honeycomb structure) of 0.5 cm thick, 69 centimeter length and 0.2 centimetre wide, roll with 5.5 centimetres of preparation diameters and high 0.2 centimetre cylindrical carrier from the one end.Applying 5 parts of ester compounds A of the present invention of dissolving and 0.5 part of solution that ester compounds B of the present invention prepares in 94.5 parts of acetone of passing through of appropriate amount on the above-mentioned carrier equably, and evaporating preparaton to obtain paper by air-dry evaporation acetone.
Preparaton embodiment 10
With the three dimensional needle fabric (trade name: FUSION, model: AKE69440, distributors: Asahi Kasei Fibers Corporation, thickness: 4.3 millimeters, fibre density: 321g/m
2, make by polyamide) and be cut into the round-shaped of 5 cm diameters.On above-mentioned circular three dimensional needle fabric, apply 5 parts of ester compounds A of the present invention of dissolving and 0.5 part of solution that ester compounds B of the present invention prepares in 94.5 parts of acetone of passing through of appropriate amount equably, and evaporate preparaton to obtain knitted fabric by air-dry evaporation acetone.
Preparaton embodiment 11
With 97.8 parts of ethylene-methyl methacrylate methyl terpolymers (methyl methacrylate content: 10 weight %, MFR=2[gram/10 minutes]), the mixture of 2 parts of ester compounds A of the present invention and 0.2 part of ester compounds B of the present invention be used in the equidirectional rotation 45 millimeters Φ double screw extruders 130 ℃ of fusions and mediate, and further also mediate with the fusion of 40 millimeters Φ extruders at 150 ℃, extrude with sheet form from the T die head then, and evaporate preparaton to obtain resin with the chill roll cooling.
Preparaton embodiment 12
With 97.8 parts of vinyl-vinyl acetate copolymers (vinyl acetate content: 10 weight %, MFR=2[gram/10 minutes]), the mixture of 2 parts of ester compounds A of the present invention and 0.2 part of ester compounds B of the present invention is used in 45 millimeters Φ double screw extruders fusions of equidirectional rotation and mediates at 130 ℃, and further also mediate with the fusion of 40 millimeters Φ extruders at 150 ℃, extrude with sheet form from the T die head then, and evaporate preparaton to obtain resin with the chill roll cooling.
Preparaton embodiment 13
In 94.5 parts of acetone, dissolve 5 parts of ester compounds A of the present invention and 0.5 part of ester compounds B of the present invention, the gained solution of appropriate amount is applied to the paper (2000cm with folding structure
2) on, and by air-dry evaporation acetone to obtain paper evaporation preparaton.
Preparaton embodiment 14
Prepare solution by 3 parts of ester compounds A of the present invention of dissolving and 0.3 part of ester compounds B of the present invention in 14.6 parts of acetone.In this solution, add 0.2 part of zinc oxide, 1.0 parts of α starch and 42.8 parts of azodicarboamides.In addition, add 38.1 parts of water, and mixture is mediated with extruder, be molded as granular shape to it, and dry to obtain particle.Heart part is cut off in the container separately by aluminium therein, described particle is placed on it in the portion space, and places 50 gram calcium oxide to obtain fumigant in lower space.
Preparaton embodiment 15
In the mixture of 0.5 part of zinc oxide, 2 parts of α starch and 975 parts of azodicarboamides, add entry, and mixture mediates and is molded as granular shape with extruder, and dry to obtain particle.Then, the acetone soln of the described particle of 2 grams with 0.58 gram ester compounds A of the present invention and 0.058 gram ester compounds B of the present invention flooded equably, and dry to obtain particle.Therein in the container that heart part separates by aluminium, described particle is placed on it in the portion space, and in lower space, places 50 gram calcium oxide with the acquisition fumigant.
Preparaton embodiment 16
In 20 milliliters of acetone, dissolving 0.5 gram ester compounds A of the present invention and 0.05 gram ester compounds B of the present invention, and gained solution is added in the mixture of 99.4 gram mosquito repellent coil disc matrix materials (red nanmu powder, Dalmatian chrysanthemum and timber powder are in the mixture of 4: 3: 3 ratios) and 0.3 gram viridine green.After fully mixing, be added to 120 ml waters in the mixture and fully kneading.The gained mixture is molded and dry to obtain mosquito repellent coil disc.
Preparaton embodiment 17
By mixing 10 parts of ester compounds A of the present invention, 1 part of ester compounds B of the present invention, 39.5 parts of acetyl tributyl citrate tributyl esters, 39.5 parts of different nonyl esters of adipic acid, 5 parts of blue pigments and 5 parts of flavouring agents prepare solution.The matrix material of the electric mat of 2.1 centimetres of 3.4 cm x and 0.22 cm thick (with the fiber and the knot of velveteen and pulp mixture, concentrate and be compressed to the plate shape) is flooded with the acquisition electric mat equably with above-mentioned solution.
Preparaton embodiment 18
Prepare solution by 0.1 part of ester compounds A of the present invention of dissolving and 0.01 part of ester compounds B of the present invention in 99.89 parts of deodorized kerosines.Solution is placed in the vinyl chloride container, absorption of fluids core (by also then it being carried out the sintering preparation with adhesive cures (firming) organic powder) (its treated making is heated with heater at an upper portion thereof) is inserted wherein evaporate the part of preparaton to obtain the absorption of fluids core pattern.
Preparaton embodiment 19
In aerosol can, place 0.2 part of ester compounds A of the present invention, 0.02 part of ester compounds B of the present invention and 49.78 parts of Neothiozole (Chuo Kasei Co., Ltd.).After aerosol valve is installed, fill 25 parts of dimethyl ether and 25 parts of LPG, shake and further install whole inclusion injection-type aerosol actuators then, to obtain the aerosol preparaton.
Preparaton embodiment 20
In 0.2 part of ester compounds A of the present invention and 0.02 part of ester compounds B of the present invention, add 99.78 parts of diethylene glycol monoethyl ethers, fully mix to obtain to be coated with the holding up agent preparaton then, be used to prevent and treat epizoa.
Preparaton embodiment 21
Prepare solution by dissolving 3 parts of ester compounds A of the present invention and 0.3 part of ester compounds B of the present invention in 96.7 parts of acetone, and 1 milliliter of this solution is applied to equably by at pressure (4t/cm
2) lower mould 4 grams 2,4,6-triisopropyl-1,3,5-three
On the solid material (3 cm diameters and 3 millimeters thick) of the disk shape that alkane obtains, dry then to obtain tablet.
Preparaton embodiment 22
With 0.2 gram ester compounds A of the present invention, 0.02 gram ester compounds B of the present invention and 4 grams 2,4,6-triisopropyl-1,3,5-three
The homogeneous mixture of alkane is made as disk shape (3 cm diameters and 3 millimeters thick) to obtain tablet at the pressure counterdie.
Preparaton embodiment 23
With 0.2 gram ester compounds A of the present invention, 0.02 gram ester compounds B of the present invention and 4 grams 2,4,6-triisopropyl-1,3,5-three
The mixture of alkane is placed in 50 milliliters of screwed pipes, and heat fusing also is cooled to room temperature subsequently to obtain tablet.
Then, following test implementation example has shown that the present invention prevents and treats composition and has outstanding pest controling effect.
In the following test implementation example, use (1R)-trans-3-(2, the 2-dichloroethylene)-2,2-dinethyl cyclopropane carboxylic acid [2,3,5,6-tetrafluoro-4-(methoxy) phenyl] methyl ester is as ester compounds A of the present invention.
In addition, use (1R)-cis/trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid [2,5-dioxo-3-(2-propynyl)-1-imidazolidinyl] methyl ester is as ester compounds B of the present invention.
Test implementation example 1
By preparing the oil solution (hereinafter, being called Comparative composition (1) and (3)) that is in concentration shown in the following table 1 with isoparaffic solvent (ISOPAR M, Exxon Chemical Co., the registration mark of Ltd.) the dilution ester compounds B of the present invention of specified rate.Similarly, isoparaffic solvent (ISOPAR M with specified rate, Exxon Chemical Co., the registration mark of Ltd.) dilution ester compounds A of the present invention is in the oil solution (hereinafter, being called Comparative composition (2) and (4)) of concentration shown in the following table 1 with preparation.
In addition, isoparaffic solvent (ISOPAR M with specified rate, Exxon Chemical Co., Ltd. registration mark) dilution ester compounds A of the present invention and ester compounds B of the present invention is shown in oil solution (hereinafter, being called the present composition (1), (2) and (3)) in the following table 1 with preparation effective ingredient concentration.
In cubic chamber with 70 centimetres of length of sides (sides), discharge 10 houseflies (Musca domestica) (5 male and 5 female), and with spray gun (atomisation pressure: 0.9kg/cm
2) from the 0.7 milliliter of present composition (1) of spraying at the fenestella family of this chamber porch.In given period after spraying, investigation is eliminated the number of (knocked down) insect and is calculated elimination rate (KD leads).According to same way as, the KD of after date led (twice operation) when the application of the invention composition (2) and (3) and Comparative composition (1)-(4) calculating were given.
The result is presented in the table 1.
Table 1
As described above, the present invention can provide pest control composition and the insect pest control method that insect is had outstanding effect.
Claims (4)
1. pest control composition, it comprises the combination as the following material of effective ingredient: by the ester compounds of following formula (I) expression:
With the ester compounds by following formula (II) expression:
2. pest control composition according to claim 1, wherein the weight ratio by formula (I) ester compounds of representing and the ester compounds of being represented by formula (II) is 50: 1 to 1: 50.
3. insect pest control method, it comprise to insect or insect survival zone apply effective dose by the ester compounds of following formula (I) expression with by the combination of the ester compounds of following formula (II) expression:
4. by the ester compounds of following formula (I) expression be used for the purposes of pest control by the combination of the ester compounds of following formula (II) expression:
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009250308 | 2009-10-30 | ||
| JP2009-250308 | 2009-10-30 |
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| Publication Number | Publication Date |
|---|---|
| CN102047899A true CN102047899A (en) | 2011-05-11 |
Family
ID=43952970
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105312904A Pending CN102047899A (en) | 2009-10-30 | 2010-10-29 | Pest control composition and pest control method |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JP5652080B2 (en) |
| CN (1) | CN102047899A (en) |
| AR (1) | AR079020A1 (en) |
| AU (1) | AU2010236007A1 (en) |
| BR (1) | BRPI1010466A2 (en) |
| MX (1) | MX2010011914A (en) |
| RU (1) | RU2010144525A (en) |
| TR (1) | TR201008917A2 (en) |
| TW (1) | TW201124080A (en) |
| ZA (1) | ZA201007757B (en) |
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| JP6001947B2 (en) * | 2012-07-31 | 2016-10-05 | アース製薬株式会社 | 匍匐 Pest control formulation and pesticidal method |
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|---|---|---|---|---|
| US4176189A (en) * | 1977-06-20 | 1979-11-27 | Sumitomo Chemical Company, Limited | Insecticidal and acaricidal hydantoin N-methylol esters |
| CN101049101A (en) * | 2007-05-16 | 2007-10-10 | 刘军伍 | Insect aerosol of aircraft, and preparation method |
| CN101306997A (en) * | 2008-04-29 | 2008-11-19 | 江苏扬农化工股份有限公司 | Optically active pyrethroid compounds, method for preparing same and applications |
| CN101524084A (en) * | 2009-04-30 | 2009-09-09 | 江苏扬农化工股份有限公司 | Muscicide incense and preparation method and application thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3170890D1 (en) * | 1980-12-17 | 1985-07-11 | Ici Plc | Fluorobenzyl cyclopropane carboxylates, their preparation, compositions comprising them and their use as insecticides |
| JP4994702B2 (en) * | 2005-04-21 | 2012-08-08 | 住友化学株式会社 | Pest control agent |
| JP3909717B1 (en) * | 2006-07-04 | 2007-04-25 | 大日本除蟲菊株式会社 | Flies and mosquito coils |
| JP2009019015A (en) * | 2007-07-12 | 2009-01-29 | Sumitomo Chemical Co Ltd | Molded article for insect pest control |
| JP5407224B2 (en) * | 2007-09-05 | 2014-02-05 | 住友化学株式会社 | Pest control composition and pest control method |
| JP2009235040A (en) * | 2008-03-28 | 2009-10-15 | Sumitomo Chemical Co Ltd | Method for controlling fly |
| JP5598204B2 (en) * | 2009-10-30 | 2014-10-01 | 住友化学株式会社 | Pest control composition and pest control method |
| JP2011116737A (en) * | 2009-10-30 | 2011-06-16 | Sumitomo Chemical Co Ltd | Harmful organism-controlling composition and method for controlling harmful organism |
| JP5589712B2 (en) * | 2009-10-30 | 2014-09-17 | 住友化学株式会社 | Pest control composition and pest control method |
-
2010
- 2010-09-22 JP JP2010211930A patent/JP5652080B2/en not_active Expired - Fee Related
- 2010-10-25 AU AU2010236007A patent/AU2010236007A1/en not_active Abandoned
- 2010-10-27 TR TR2010/08917A patent/TR201008917A2/en unknown
- 2010-10-28 AR ARP100103955 patent/AR079020A1/en unknown
- 2010-10-28 BR BRPI1010466 patent/BRPI1010466A2/en not_active Application Discontinuation
- 2010-10-28 TW TW99136901A patent/TW201124080A/en unknown
- 2010-10-29 MX MX2010011914A patent/MX2010011914A/en not_active Application Discontinuation
- 2010-10-29 RU RU2010144525/13A patent/RU2010144525A/en not_active Application Discontinuation
- 2010-10-29 CN CN2010105312904A patent/CN102047899A/en active Pending
- 2010-10-29 ZA ZA2010/07757A patent/ZA201007757B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4176189A (en) * | 1977-06-20 | 1979-11-27 | Sumitomo Chemical Company, Limited | Insecticidal and acaricidal hydantoin N-methylol esters |
| CN101049101A (en) * | 2007-05-16 | 2007-10-10 | 刘军伍 | Insect aerosol of aircraft, and preparation method |
| CN101306997A (en) * | 2008-04-29 | 2008-11-19 | 江苏扬农化工股份有限公司 | Optically active pyrethroid compounds, method for preparing same and applications |
| CN101524084A (en) * | 2009-04-30 | 2009-09-09 | 江苏扬农化工股份有限公司 | Muscicide incense and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2010236007A1 (en) | 2011-05-19 |
| MX2010011914A (en) | 2011-04-29 |
| TW201124080A (en) | 2011-07-16 |
| ZA201007757B (en) | 2011-08-31 |
| BRPI1010466A2 (en) | 2012-11-27 |
| RU2010144525A (en) | 2012-05-10 |
| JP5652080B2 (en) | 2015-01-14 |
| TR201008917A2 (en) | 2011-05-23 |
| AR079020A1 (en) | 2011-12-21 |
| JP2011116741A (en) | 2011-06-16 |
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