CN102199869B - Oxidation bleaching stabilizer and use thereof - Google Patents
Oxidation bleaching stabilizer and use thereof Download PDFInfo
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- CN102199869B CN102199869B CN2011100834993A CN201110083499A CN102199869B CN 102199869 B CN102199869 B CN 102199869B CN 2011100834993 A CN2011100834993 A CN 2011100834993A CN 201110083499 A CN201110083499 A CN 201110083499A CN 102199869 B CN102199869 B CN 102199869B
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- hydrogen peroxide
- bleaching stabilizer
- peroxide bleaching
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- stabilizer
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Abstract
The invention relates to an oxidation bleaching stabilizer and use thereof, and belongs to the field of assistants for used in a textile before-dyeing treatment process. The oxidation bleaching stabilizer is prepared from the following components in percentage by weight: 50 to 70 percent of organic phosphate, 20 to 30 percent of polycarboxylic acid dispersant and 10 to 20 percent of polyether surfactant. The oxidation bleaching stabilizer of the invention can inhibit decomposition of ineffective oxygen and increase the ratio of hydrogen peroxide participating in reaction to a maximum degree. Therefore, a one-bath scouring agent prepared by using the oxidation bleaching stabilizer further shortens time of a desizing, scouring and bleaching process and further reduced water and power consumption; and the quality of the process semi-finished products is high.
Description
Technical field
The present invention relates to a kind of hydrogen peroxide bleaching stabilizer and application thereof, belong to the auxiliary agent field in the textile dyeing pre-treatment process.
Background technology
The dyeing and finishing process of textiles before staining procedure, carry out pre-treatment to textiles, adds the component that produce or add man-hour to remove preceding working procedure, and such as slurry, wax etc., these components can have a strong impact on the dyeing processing of postorder, therefore will carry out pre-treatment.At present, conventional pre-treatment process flow process comprises the steps: that former cloth prepares → singe → destarch → washing → kiering → washing → bleaching → washing → oven dry.This pre-treatment process long flow path, energy consumption is large, sewage is many.Therefore, Dyeing-finishing Industry begins to pay attention to the research of short-flow pre-treating process, and the one-bath DSB method is born at this point.The key technology of one-bath DSB method is that one bathes the use of scouring agent.One bath scouring agent is mainly formulated by components such as hydrogen peroxide bleaching stabilizer, pH buffers.In the application of reality, be used the one-bath DSB method of a bath scouring agent, its processing time and energy consumption are still waiting further improvement.
Summary of the invention
The invention provides a kind of hydrogen peroxide bleaching stabilizer and application thereof, the bath scouring agent with this hydrogen peroxide bleaching stabilizer is prepared has out further shortened to move back and has boiled the processing time of floating operation, and further reduced water, power consumption, and treated semi-products excellent quality.
For achieving the above object, the technical solution adopted in the present invention is:
A kind of hydrogen peroxide bleaching stabilizer, formulated by the component of following percentage by weight: 50 ~ 70% organic phosphate, 20 ~ 30% polycarboxylic acid dispersant, 10 ~ 20% polyether surfactant.
As the further setting of such scheme, described organic phosphate is 60%, and polycarboxylic acid dispersant is 30%, and polyether surfactant is 10%.
Described organic phosphate adopts any one in diethylene triamine pentamethylene phosphonic five sodium, ethylene diamine tetra methylene phosphonic acid five sodium.The product that diethylene triamine pentamethylene phosphonic five sodium, ethylene diamine tetra methylene phosphonic acid five sodium all adopt Shandong Taihe Water Treatment Co., Ltd. to produce.
Described polycarboxylic acid dispersant adopts polyacrylic acid.Polyacrylic acid adopts the product of Suzhou good boat Chemical Manufacture.
Described polyether surfactant adopts any one in Phosphate of Polyoxyethylene Isooctyl Ether, the fatty alcohol-polyoxyethylene ether carboxylic acid sodium.Phosphate of Polyoxyethylene Isooctyl Ether adopts the product of pool, Baoji day chemical industry Co., Ltd production, and the fatty alcohol-polyoxyethylene ether carboxylic acid sodium adopts the road, Guangzhou to contain the product that chemicals Co., Ltd produces.
The application of hydrogen peroxide bleaching stabilizer can be used for preparing one and bathes scouring agent, and this bath scouring agent is formulated by the component of following percentage by weight:
20 ~ 40% hydrogen peroxide bleaching stabilizer, 50 ~ 60% pH buffer, 5 ~ 10% tetraacetyl ethylene diamine, 5 ~ 10% urea.
As the further setting of such scheme, described hydrogen peroxide bleaching stabilizer is 20%, the pH buffer is 60%, tetraacetyl ethylene diamine is 10%, urea is 10%.The pH buffer adopts the product of Wal Chemical Manufacture.The product that tetraacetyl ethylene diamine adopts Zhejiang Shidai Jinke Peroxides Co., Ltd. to produce.The product that urea adopts power Dehua, Huanghua City worker Co., Ltd to produce.
Hydrogen peroxide bleaching stabilizer of the present invention, but maximum ground suppresses the decomposition of invalid oxygen, increases the ratio that hydrogen peroxide participates in reactive moieties.Therefore, the bath scouring agent with hydrogen peroxide bleaching stabilizer of the present invention is prepared has out further shortened to move back and has boiled the processing time of floating operation, and further reduced water, power consumption, and treated semi-products excellent quality.
The specific embodiment
Embodiment 1
A kind of hydrogen peroxide bleaching stabilizer, formulated by the component of following percentage by weight: 50% organic phosphate, 30% polycarboxylic acid dispersant, 20% polyether surfactant.Wherein, organic phosphate adopts diethylene triamine pentamethylene phosphonic five sodium, and polycarboxylic acid dispersant adopts polyacrylic acid, and polyether surfactant adopts Phosphate of Polyoxyethylene Isooctyl Ether.
Hydrogen peroxide bleaching stabilizer of the present invention can be used for preparing one and bathes scouring agent, and this bath scouring agent is formulated by the component of following percentage by weight:
40% hydrogen peroxide bleaching stabilizer, 50% pH buffer, 5% tetraacetyl ethylene diamine, 5% urea.
Embodiment 2
A kind of hydrogen peroxide bleaching stabilizer, formulated by the component of following percentage by weight: 70% organic phosphate, 20% polycarboxylic acid dispersant, 10% polyether surfactant.Wherein, organic phosphate adopts ethylene diamine tetra methylene phosphonic acid five sodium, and polycarboxylic acid dispersant adopts polyacrylic acid, and polyether surfactant adopts the fatty alcohol-polyoxyethylene ether carboxylic acid sodium.
Hydrogen peroxide bleaching stabilizer of the present invention can be used for preparing one and bathes scouring agent, and this bath scouring agent is formulated by the component of following percentage by weight:
30% hydrogen peroxide bleaching stabilizer, 55% pH buffer, 5% tetraacetyl ethylene diamine, 10% urea.
Embodiment 3
A kind of hydrogen peroxide bleaching stabilizer, formulated by the component of following percentage by weight: 60% organic phosphate, 30% polycarboxylic acid dispersant, 10% polyether surfactant.Wherein, organic phosphate adopts diethylene triamine pentamethylene phosphonic five sodium, and polycarboxylic acid dispersant adopts polyacrylic acid, and polyether surfactant adopts Phosphate of Polyoxyethylene Isooctyl Ether.
Hydrogen peroxide bleaching stabilizer of the present invention can be used for preparing one and bathes scouring agent, and this bath scouring agent is formulated by the component of following percentage by weight:
20% hydrogen peroxide bleaching stabilizer, 60% pH buffer, 10% tetraacetyl ethylene diamine, 10% urea.
Embodiment 4
A kind of hydrogen peroxide bleaching stabilizer, formulated by the component of following percentage by weight: 65% organic phosphate, 25% polycarboxylic acid dispersant, 10% polyether surfactant.Wherein, organic phosphate adopts ethylene diamine tetra methylene phosphonic acid five sodium, and polycarboxylic acid dispersant adopts polyacrylic acid, and polyether surfactant adopts the fatty alcohol-polyoxyethylene ether carboxylic acid sodium.
Hydrogen peroxide bleaching stabilizer of the present invention can be used for preparing one and bathes scouring agent, and this bath scouring agent is formulated by the component of following percentage by weight:
40% hydrogen peroxide bleaching stabilizer, 50% pH buffer, 5% tetraacetyl ethylene diamine, 5% urea.
Above-described embodiment only is used for explaining inventive concept of the present invention, but not to the restriction of rights protection of the present invention, allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should fall into protection scope of the present invention.
Claims (4)
1. hydrogen peroxide bleaching stabilizer is characterized in that by the component of following percentage by weight formulated: 50 ~ 70% organic phosphate, 20 ~ 30% polycarboxylic acid dispersant, 10 ~ 20% polyether surfactant;
Described organic phosphate adopts any one in diethylene triamine pentamethylene phosphonic five sodium, ethylene diamine tetra methylene phosphonic acid five sodium;
Described polycarboxylic acid dispersant adopts polyacrylic acid;
Described polyether surfactant adopts any one in Phosphate of Polyoxyethylene Isooctyl Ether, the fatty alcohol-polyoxyethylene ether carboxylic acid sodium.
2. hydrogen peroxide bleaching stabilizer as claimed in claim 1, it is characterized in that: described organic phosphate is 60%, and polycarboxylic acid dispersant is 30%, and polyether surfactant is 10%.
3. the application of a hydrogen peroxide bleaching stabilizer claimed in claim 1 is characterized in that can be used for preparing one bathes scouring agent, and this bath scouring agent is formulated by the component of following percentage by weight:
20 ~ 40% hydrogen peroxide bleaching stabilizer, 50 ~ 60% pH buffer, 5 ~ 10% tetraacetyl ethylene diamine, 5 ~ 10% urea.
4. the as claimed in claim 3 application of hydrogen peroxide bleaching stabilizer is characterized in that: described hydrogen peroxide bleaching stabilizer is 20%, the pH buffer is 60%, tetraacetyl ethylene diamine is 10%, urea is 10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100834993A CN102199869B (en) | 2011-04-02 | 2011-04-02 | Oxidation bleaching stabilizer and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2011100834993A CN102199869B (en) | 2011-04-02 | 2011-04-02 | Oxidation bleaching stabilizer and use thereof |
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| CN102199869A CN102199869A (en) | 2011-09-28 |
| CN102199869B true CN102199869B (en) | 2013-02-06 |
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| CN2011100834993A Active CN102199869B (en) | 2011-04-02 | 2011-04-02 | Oxidation bleaching stabilizer and use thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102644195B (en) * | 2012-04-01 | 2014-03-12 | 祝洪哲 | Functional additive for fibrilia modification and one-bath bleaching and preparation method thereof |
| CN103321032A (en) * | 2013-05-16 | 2013-09-25 | 陈林美 | Wool textile fabric oxygen bleaching stabilizing agent |
| CN104532541B (en) * | 2014-12-30 | 2016-07-13 | 四川益欣科技有限责任公司 | A kind of efficient alkaline-resisting non-silicone oxidation blkeach Stabilizer and its preparation method and application |
| CN106149347A (en) * | 2016-07-12 | 2016-11-23 | 广州先盈生物科技有限公司 | The low temperature of a kind of composite catalyst is scouringed and bleaching agent and application thereof |
| CN107313271A (en) * | 2017-06-26 | 2017-11-03 | 王蒙 | A kind of dispersant |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4259200A (en) * | 1979-04-06 | 1981-03-31 | Lever Brothers Company | Bleaching and cleaning compositions |
| US4448705A (en) * | 1982-05-20 | 1984-05-15 | Colgate-Palmolive Company | Monoperoxyphthalic acid bleaching composition containing DTPMP |
| CN1057077A (en) * | 1990-05-28 | 1991-12-18 | 孙绍宣 | High-efficiency refining agent and preparation method |
| CN101487183A (en) * | 2009-02-17 | 2009-07-22 | 宁波广源纺织品有限公司 | Method for environment-friendly low-temperature scouring and bleaching in spinning dyeing and finishing |
| CN101643997A (en) * | 2009-09-03 | 2010-02-10 | 辽宁恒星精细化工（集团）有限公司 | Textile hydrogen peroxide bleaching stabilizer |
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2011
- 2011-04-02 CN CN2011100834993A patent/CN102199869B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4259200A (en) * | 1979-04-06 | 1981-03-31 | Lever Brothers Company | Bleaching and cleaning compositions |
| US4448705A (en) * | 1982-05-20 | 1984-05-15 | Colgate-Palmolive Company | Monoperoxyphthalic acid bleaching composition containing DTPMP |
| CN1057077A (en) * | 1990-05-28 | 1991-12-18 | 孙绍宣 | High-efficiency refining agent and preparation method |
| CN101487183A (en) * | 2009-02-17 | 2009-07-22 | 宁波广源纺织品有限公司 | Method for environment-friendly low-temperature scouring and bleaching in spinning dyeing and finishing |
| CN101643997A (en) * | 2009-09-03 | 2010-02-10 | 辽宁恒星精细化工（集团）有限公司 | Textile hydrogen peroxide bleaching stabilizer |
Non-Patent Citations (3)
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| 唐育民等.退、煮、漂三合一前处理剂TL的研制与应用.《染整技术》.2000,第22卷(第6期),第29-31页. * |
| 孙晓日等.氧漂稳定剂的稳定性理论及其制备.《潍坊学院学报》.2005,第5卷(第6期),第101-104页. * |
| 王银银.纯棉织物漂白技术.《纺织科技进展》.2009,(第4期),第12-15页. * |
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| CN102199869A (en) | 2011-09-28 |
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Inventor after: Liu Jianping Inventor after: Xiao Junming Inventor before: Xiao Junming Inventor before: Liu Jianping |
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Free format text: CORRECT: INVENTOR; FROM: XIAO JUNMING LIU JIANPING TO: LIU JIANPING XIAO JUNMING |
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Address after: 312030 Shaoxing City, Zhejiang Province, Keqiao Province east high tech Development Zone Patentee after: Keqiao Shaoxing International Assistant Co., Ltd. Address before: 312030 Shaoxing City, Zhejiang Province, east of the new and high technology development zone Patentee before: Shaoxing County Youbang Auxiliaries Co., Ltd. |